- Title
- Zinc phthalocyanine photocatalyzed oxidation of cyclohexene
- Creator
- Sehlotho, Nthapo
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 2004
- Date
- 2004
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/289399
- Identifier
- vital:56629
- Identifier
- xlink:href="https://doi.org/10.1016/j.molcata.2004.05.010"
- Description
- Cyclohexene photooxidation catalyzed by zinc phthalocyanine (ZnPc) using either red or white light results in the formation of cyclohexenone, cyclohexenol, trans-cyclohexanediol, cyclohexene oxide and cyclohexene hydroperoxide. The product yield increased as follows: cyclohexenone > cyclohexenol > trans-cyclohexanediol > cyclohexene oxide > cyclohexene hydroperoxide. The mechanism for the formation of these products involves both singlet oxygen and radicals (Type II and Type I mechanisms, respectively). The catalyst degraded slowly when low light intensities were employed. The product yields were found to depend on the light intensity, the nature of solvent, irradiation time and the rate of photodegradation of the catalyst.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (7 pages)
- Format
- Publisher
- Elsevier
- Language
- English
- Relation
- Journal of Molecular Catalysis A: Chemical
- Relation
- Sehlotho, N. and Nyokong, T., 2004. Zinc phthalocyanine photocatalyzed oxidation of cyclohexene. Journal of Molecular Catalysis A: Chemical, 219(2), pp.201-207
- Relation
- Journal of Molecular Catalysis A: Chemical volume 219 number 2 p. 201 2004 1873-314X
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Zinc phthalocyanine photocatalyzed oxidation of cyclohexene.pdf | 126 KB | Adobe Acrobat PDF | View Details Download |