- Title
- Electrochemical and catalytic properties of chromium tetraaminophthalocyanine
- Creator
- Obirai, Joe
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 2004
- Date
- 2004
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/300310
- Identifier
- vital:57915
- Identifier
- xlink:href="https://doi.org/10.1016/j.jelechem.2004.06.026"
- Description
- Chromium tetraaminophthalocyanine (CrIIITAPc) has been synthesized and its electrochemical and spectroelectrochemical properties reported. The first reduction and oxidation in this complex occur at the central metal, giving CrIITAPc and CrIVTAPc complexes, respectively, the latter having been observed for the first time. The CrIIITAPc species was polymerized onto glassy carbon (GCE) or indium tin oxide (ITO) electrodes and the polymer evolution confirmed by UV/Visible spectroscopy and by scanning electron microscopy. The polymers were employed for the catalytic oxidation of nitrite or nitric oxide, and the catalysis involved the CrIVTAPc−1 species.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (9 pages)
- Format
- Publisher
- Elsevier
- Language
- English
- Relation
- Journal of Electroanalytical Chemistry
- Relation
- Obirai, J. and Nyokong, T., 2004. Electrochemical and catalytic properties of chromium tetraaminophthalocyanine. Journal of Electroanalytical Chemistry, 573(1), pp.77-85
- Relation
- Journal of Electroanalytical Chemistry volume 573 number 1 p. 77 2004 1873-2569
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Electrochemical and catalytic properties of chromium tetraaminophthalocyanine.pdf | 767 KB | Adobe Acrobat PDF | View Details Download |