Ligand substitution effects in uranyl ο-hydroxyarylcarbonyl complexes

Title: Ligand substitution effects in uranyl ο-hydroxyarylcarbonyl complexes
Creator: Haigh, John M
Date Issued: 1974
Date: 1974
Type: text
Type: Article
Identifier: vital:6372
Identifier: http://hdl.handle.net/10962/d1006075
Description: Twenty-two base adducts of uranyl o-hydroxyarylcarbonyl complexes [UO2L2B] (L = o-hydroxyarylcarbonyl compound, B = H2O, pyridine, pyridine N-oxide) have been prepared. Pure field substituent parameters are used to derive a quantitative order of the electronic effects of the chelate ring substituents. Values of v(U=O) correlate well with these values. Evidence is cited suggesting almost complete non-aromaticity of the chelate ring, and the transmission of the electronic effects of the chelate ring substituent through the uranium atom in the pyridine and pyridine N-oxide base adducts.
Format: 8 pages
Format: pdf
Language: English
Relation: Haigh, J.M. (1974) Ligand substitution effects in uranyl ο-hydroxyarylcarbonyl complexes. Journal of Molecular Structure, 23 (2). pp. 281-288. Available: http://dx.doi.org/10.1016/0022-2860(74)85042-8

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RU Department of Pharmacy

Haigh, JM (Prof)

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