A critical study of the curcumin method for the determination of boron in plant material
- Authors: Davidson, Raymond John
- Date: 1958
- Subjects: Plants -- Nutrition , Boron , Turmeric
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4458 , http://hdl.handle.net/10962/d1011003
- Description: Methods for the determination of boron are reviewed. A thorough investigation of the curcumin method was undertaken. Factors such as spectral absorption, boron volatilisation and the effects of pH, the stability of reagents and colour solutions, the drying of reaction products and the interference from certain elements, were investigated. A study of the efficiency of extracting boron from plant material using an ashing procedure is presented. The modified curcumin method for the determination of boron in plant material is described. The statistical accuracy and precision of the modified method is presented. The modified method was used to determine the boron content in citrus and pineapple leaf samples obtained from various parts of the Eastern Cape.
- Full Text:
- Date Issued: 1958
- Authors: Davidson, Raymond John
- Date: 1958
- Subjects: Plants -- Nutrition , Boron , Turmeric
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4458 , http://hdl.handle.net/10962/d1011003
- Description: Methods for the determination of boron are reviewed. A thorough investigation of the curcumin method was undertaken. Factors such as spectral absorption, boron volatilisation and the effects of pH, the stability of reagents and colour solutions, the drying of reaction products and the interference from certain elements, were investigated. A study of the efficiency of extracting boron from plant material using an ashing procedure is presented. The modified curcumin method for the determination of boron in plant material is described. The statistical accuracy and precision of the modified method is presented. The modified method was used to determine the boron content in citrus and pineapple leaf samples obtained from various parts of the Eastern Cape.
- Full Text:
- Date Issued: 1958
A statistical study of the errors involved in the sampling and chemical analysis of soils and plants, with particular reference to citrus and pineapples
- Steyn, Willem Johannes Abraham
- Authors: Steyn, Willem Johannes Abraham
- Date: 1958
- Subjects: Soil chemistry , Plants -- Analysis , Soils -- Analysis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4506 , http://hdl.handle.net/10962/d1013291
- Description: 1. Accurate and reproducible methods for the determination of N and acid- extractable P in soils are described. The variations in N, P, and K found by intensive sampling of three different soil types are presented. 3. Suggestions for the adequate sampling of soils for various purposes arc given. 4. A study is presented of the preparative stages in leaf analysis (washing, drying, grinding and storage) as applied to citrus and pineapple leaf material. Likely errors are pointed out and procedures whereby these may be minimised are described. 5. A reliable wet-ashing procedure for obtaining leaf solutions is described. 6. Accurate and reproducible methods for the determination of total N, P,. K, Ca, Mg, Na, Fe, Mn, Zn and Cu in citrus and pineapple leaves are presented. 7. It is shown that diurnal variations in nutrient concentrations occur in citrus and pineapple leaves. 8. The variations in N, P, K, Ca, Mg, Na, Fe, Mn, Zn and Cu, occurring from tree to tree in 3 different Navel orange blocks are presented. It is shown that if all these elements are to be represented . to within 10% of the mean values on a 19 : 1 probability level, all the trees in the blocks would have to be sampled. Reasonable sampling procedures for various purposes are suggested. 9. The variations in N, P, K, Ca, Mg, Fe, Mn, Zn and Cu, occurring in 3 different Cayenne pineapple plantations are presented and described. Suitable sampling procedures are suggested.
- Full Text:
- Date Issued: 1958
- Authors: Steyn, Willem Johannes Abraham
- Date: 1958
- Subjects: Soil chemistry , Plants -- Analysis , Soils -- Analysis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4506 , http://hdl.handle.net/10962/d1013291
- Description: 1. Accurate and reproducible methods for the determination of N and acid- extractable P in soils are described. The variations in N, P, and K found by intensive sampling of three different soil types are presented. 3. Suggestions for the adequate sampling of soils for various purposes arc given. 4. A study is presented of the preparative stages in leaf analysis (washing, drying, grinding and storage) as applied to citrus and pineapple leaf material. Likely errors are pointed out and procedures whereby these may be minimised are described. 5. A reliable wet-ashing procedure for obtaining leaf solutions is described. 6. Accurate and reproducible methods for the determination of total N, P,. K, Ca, Mg, Na, Fe, Mn, Zn and Cu in citrus and pineapple leaves are presented. 7. It is shown that diurnal variations in nutrient concentrations occur in citrus and pineapple leaves. 8. The variations in N, P, K, Ca, Mg, Na, Fe, Mn, Zn and Cu, occurring from tree to tree in 3 different Navel orange blocks are presented. It is shown that if all these elements are to be represented . to within 10% of the mean values on a 19 : 1 probability level, all the trees in the blocks would have to be sampled. Reasonable sampling procedures for various purposes are suggested. 9. The variations in N, P, K, Ca, Mg, Fe, Mn, Zn and Cu, occurring in 3 different Cayenne pineapple plantations are presented and described. Suitable sampling procedures are suggested.
- Full Text:
- Date Issued: 1958
Synthetic ion exchange resins, incorporating asymmetric groups, as resolving agents
- Authors: O'Sullivan, Diarmid John
- Date: 1958
- Subjects: Ion exchange resins -- Synthesis
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4485 , http://hdl.handle.net/10962/d1012991
- Description: The object of this research is to further investigate the possiblitiy of resolving racemic bases on an optically active cation exchange resin. Any success in this direction would help to explain the reason for Bunnett and Mark's failure, since the general assumption that selective adsorption of one enantimorph of a racemic compound on an active exchanger should occur has been verified by Grubhofer and Schleith. The work can be conveniently divided into two sections. a) The preparation of optically active cation exchange resins and, b) the use of these as resolving agents. P. 8
- Full Text:
- Date Issued: 1958
- Authors: O'Sullivan, Diarmid John
- Date: 1958
- Subjects: Ion exchange resins -- Synthesis
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4485 , http://hdl.handle.net/10962/d1012991
- Description: The object of this research is to further investigate the possiblitiy of resolving racemic bases on an optically active cation exchange resin. Any success in this direction would help to explain the reason for Bunnett and Mark's failure, since the general assumption that selective adsorption of one enantimorph of a racemic compound on an active exchanger should occur has been verified by Grubhofer and Schleith. The work can be conveniently divided into two sections. a) The preparation of optically active cation exchange resins and, b) the use of these as resolving agents. P. 8
- Full Text:
- Date Issued: 1958
- «
- ‹
- 1
- ›
- »