A study of the fluorescence excitation spectrum of crystalline anthracene
- Authors: Driver, Adrian Stanford
- Date: 1960
- Subjects: Fluorimetry , Anthracene crystals -- Spectra
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5518 , http://hdl.handle.net/10962/d1011463 , Fluorimetry , Anthracene crystals -- Spectra
- Description: The work described in this thesis was performed at the Physics Department, Rhodes University during 1958 and 1959 under the supervision of Professor J.A. Gledhill. Use was made of a vacuum ultra-violet spectrograph which had been constructed in the Physics Department (1.1) and modifications to be described were made to this instrument. The instrument was used for studying the effects of oxygen on the fluorescence excitation spectrum of Anthracene.
- Full Text:
- Date Issued: 1960
- Authors: Driver, Adrian Stanford
- Date: 1960
- Subjects: Fluorimetry , Anthracene crystals -- Spectra
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5518 , http://hdl.handle.net/10962/d1011463 , Fluorimetry , Anthracene crystals -- Spectra
- Description: The work described in this thesis was performed at the Physics Department, Rhodes University during 1958 and 1959 under the supervision of Professor J.A. Gledhill. Use was made of a vacuum ultra-violet spectrograph which had been constructed in the Physics Department (1.1) and modifications to be described were made to this instrument. The instrument was used for studying the effects of oxygen on the fluorescence excitation spectrum of Anthracene.
- Full Text:
- Date Issued: 1960
An investigation of the profiles of bursts of solar radio noise
- Wild, Peter Anthony Thornton
- Authors: Wild, Peter Anthony Thornton
- Date: 1960
- Subjects: Solar radio emission , Radio noise , Solar noise storms , Radio astronomy
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5551 , http://hdl.handle.net/10962/d1013504
- Description: [Summary] Chapter I . The general characteristics of solar radiation at metre wavelengths are described, with reference to data published in the literature. A brief description of some aspects of solar physics relevant to the study of solar noise is given, and the literature relating to the correlation of radio effects with solar disturbances is reviewed. Chapter II. A concise description of the apparatus constructed for the continuous recording of the flux density of solar radio noise at a frequency of 300 Mc/s is given, with some mention of difficulties experienced, and how these were overcome. Full circuit diagrams of electronic apparatus, and illustrative photographs, are supplied. Chapter III. The development of theories of the origin and propagation of solar noise radiation is historically reviewed and the success of each theory in explaining or predicting observed phenomena, is assessed. A working model is chosen from among these theories, and reasons for its adoption are given. Chapter IV. Observations made by the author of solar radiation at a frequency of 300 Mc/s are described, together with a description of the objects and methods, of analysis of the records. Chapter V. Phenomena observed by the author are compared with those observed by other workers. It is concluded that storm bursts are caused by transients similar to those producing Type II and Type ITI bursts, and a model for the production of storm bursts is tentatively suggested. Chapter VI. Suggestions for further research, including suggestions for methods of testing the author's conclusions, are made.
- Full Text:
- Date Issued: 1960
- Authors: Wild, Peter Anthony Thornton
- Date: 1960
- Subjects: Solar radio emission , Radio noise , Solar noise storms , Radio astronomy
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5551 , http://hdl.handle.net/10962/d1013504
- Description: [Summary] Chapter I . The general characteristics of solar radiation at metre wavelengths are described, with reference to data published in the literature. A brief description of some aspects of solar physics relevant to the study of solar noise is given, and the literature relating to the correlation of radio effects with solar disturbances is reviewed. Chapter II. A concise description of the apparatus constructed for the continuous recording of the flux density of solar radio noise at a frequency of 300 Mc/s is given, with some mention of difficulties experienced, and how these were overcome. Full circuit diagrams of electronic apparatus, and illustrative photographs, are supplied. Chapter III. The development of theories of the origin and propagation of solar noise radiation is historically reviewed and the success of each theory in explaining or predicting observed phenomena, is assessed. A working model is chosen from among these theories, and reasons for its adoption are given. Chapter IV. Observations made by the author of solar radiation at a frequency of 300 Mc/s are described, together with a description of the objects and methods, of analysis of the records. Chapter V. Phenomena observed by the author are compared with those observed by other workers. It is concluded that storm bursts are caused by transients similar to those producing Type II and Type ITI bursts, and a model for the production of storm bursts is tentatively suggested. Chapter VI. Suggestions for further research, including suggestions for methods of testing the author's conclusions, are made.
- Full Text:
- Date Issued: 1960
Some aspects of the chemistry of zirconium compounds relating to their combination with collagen
- Williams-Wynn, David Ernest Arthur
- Authors: Williams-Wynn, David Ernest Arthur
- Date: 1960
- Subjects: Zirconium compounds , Collagen
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4513 , http://hdl.handle.net/10962/d1013456
- Description: [Summary] Some properties of zirconium compounds in aqueous solution have been determined using physico-chemical techniques. Zirconium oxychloride was used as the source of zirconium in all detailed investigations; zirconium sulphate was used in a few cases for comparative purposes. The Stokes diaphragm cell method has been used to determine the diffusion coefficient of zirconium in hydrochloric acid solution. It was found that the diffusion coefficient fell progressively with time, a limiting value being reached 4 to 5 weeks after dissolving the salt, and it was demonstrated that particles in the aged solutions were more homogeneous than in freshly prepared solutions. The limiting values were concentration dependent; dilute solutions had a lower diffusion coefficient than the more concentrated solutions when measured at the natural pH. In the presence of added acid the rate of diffusion was increased until a limiting value was reached in 0.5 M acid. The addition of alkali or complexing acids reduced the rate of diffusion.
- Full Text:
- Date Issued: 1960
- Authors: Williams-Wynn, David Ernest Arthur
- Date: 1960
- Subjects: Zirconium compounds , Collagen
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4513 , http://hdl.handle.net/10962/d1013456
- Description: [Summary] Some properties of zirconium compounds in aqueous solution have been determined using physico-chemical techniques. Zirconium oxychloride was used as the source of zirconium in all detailed investigations; zirconium sulphate was used in a few cases for comparative purposes. The Stokes diaphragm cell method has been used to determine the diffusion coefficient of zirconium in hydrochloric acid solution. It was found that the diffusion coefficient fell progressively with time, a limiting value being reached 4 to 5 weeks after dissolving the salt, and it was demonstrated that particles in the aged solutions were more homogeneous than in freshly prepared solutions. The limiting values were concentration dependent; dilute solutions had a lower diffusion coefficient than the more concentrated solutions when measured at the natural pH. In the presence of added acid the rate of diffusion was increased until a limiting value was reached in 0.5 M acid. The addition of alkali or complexing acids reduced the rate of diffusion.
- Full Text:
- Date Issued: 1960
The thermal decomposition of silver oxide
- Authors: Herley, Patrick James
- Date: 1960
- Subjects: Silver oxide -- Thermal properties , Decomposition (Chemistry)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4525 , http://hdl.handle.net/10962/d1015017
- Description: [From Introduction]. The thermal decomposition of solids is characterized by the formation and growth of nuclei at sites on the surface of the solid or within the crystal lattice. Such nuclear formation is favoured by disorganisation of the crystal either by mechanical damage, or by the presence of impurities. Disorganisation results in positions which have a high thermodynamic instability. The nuclei are likely to be formed initially at the corners and the edges of the crystal since these are more prone to damage. Careful handling and storage in vacuo often leads to a large reduction in their number, while deliberate scratching of the surface facilitates their production. The number of potential sites for nuclear formation is also increased by pre-irradiation with ultra-violet light, though there are indications that a different type of nucleus may be produced. Nucleation can be facilitated by pre-irradiation with electrons, neutrons, X-rays, gamma-rays and atomic particles. The nature of the nuclei is not always clearly defined, but it is generally accepted that they are composed of solid reaction products e.g. in the decomposition of barium azide and silver oxalate, nuclei of metallic barium and silver, respectively, are formed.
- Full Text:
- Date Issued: 1960
- Authors: Herley, Patrick James
- Date: 1960
- Subjects: Silver oxide -- Thermal properties , Decomposition (Chemistry)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4525 , http://hdl.handle.net/10962/d1015017
- Description: [From Introduction]. The thermal decomposition of solids is characterized by the formation and growth of nuclei at sites on the surface of the solid or within the crystal lattice. Such nuclear formation is favoured by disorganisation of the crystal either by mechanical damage, or by the presence of impurities. Disorganisation results in positions which have a high thermodynamic instability. The nuclei are likely to be formed initially at the corners and the edges of the crystal since these are more prone to damage. Careful handling and storage in vacuo often leads to a large reduction in their number, while deliberate scratching of the surface facilitates their production. The number of potential sites for nuclear formation is also increased by pre-irradiation with ultra-violet light, though there are indications that a different type of nucleus may be produced. Nucleation can be facilitated by pre-irradiation with electrons, neutrons, X-rays, gamma-rays and atomic particles. The nature of the nuclei is not always clearly defined, but it is generally accepted that they are composed of solid reaction products e.g. in the decomposition of barium azide and silver oxalate, nuclei of metallic barium and silver, respectively, are formed.
- Full Text:
- Date Issued: 1960
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