A comparison of the female characters in Plautus and in Terence
- Authors: Slatter, E M
- Date: 1966
- Subjects: Plautus, Titus Maccius Terence Plautus, Titus Maccius -- Characters -- Women Terence -- Characters -- Women Latin drama Women in literature
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3602 , http://hdl.handle.net/10962/d1002186
- Full Text:
- Date Issued: 1966
- Authors: Slatter, E M
- Date: 1966
- Subjects: Plautus, Titus Maccius Terence Plautus, Titus Maccius -- Characters -- Women Terence -- Characters -- Women Latin drama Women in literature
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3602 , http://hdl.handle.net/10962/d1002186
- Full Text:
- Date Issued: 1966
A study of irradiation effects in solids
- Authors: Brown, Michael Ewart
- Date: 1966
- Subjects: Decomposition (Chemistry) , Crystals -- Thermal properties , Oxalates -- Thermal properties , Solids -- Effect of radiation on
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4509 , http://hdl.handle.net/10962/d1013387
- Description: One of the primary objects of this research was to determine, if possible, the nature of the radiation damage prior to thermal decomposition. The X-ray study has not wholly achieved this although more information has been derived from it than from similar work on AgMnO₄ However, the diffuse reflections obtained do indicate, quite strongly, the creation of point defects during irradiation. This is of value since such assumptions have been made in the explanation of the kinetics of decomposition of a number of irradiated solids (BaN₆,CaN₆). In addition the X-ray work has suggested future research which should produce useful information; namely, a precise study of the diffuse reflections. Another object of the research was to attempt to determine what characteristics, if any, of the kinetics of the decomposition of an unirradiated solid would predetermine a marked irradiation effect. It is obvious that the type of nuclear growth which occurs e.g. branching chain, or power law, does not characterise a substance with regard to a possible irradiation effect . The photosensitivity, or otherwise, also does not determine whether there will be an irradiation effect. However, the one property that the substances which have been studied, have in common, is a polyatomic anion, but here again ammonium dichromate does not show an acceleration of the decomposition after irradiation. Consequently it is considered that it is not possible to say, a priori, whether a solid will undergo an accelerated decomposition after irradiation. Each new solid, unless it belongs to a particular class e.g. the alkaline earth azides , must be considered afresh. Nevertheless it does appear that the irradiation effect can take two forms: - (i) the production of an unstable compound e.g. nickel oxalate, the decomposition of which affects the normal pyrolysis; and (ii) the production of point defects which determine the nature of the subsequent thermal decomposition e.g . CaN₆ . It is possible that the effect requires an interaction of the created point defects with the existing line defects.
- Full Text:
- Date Issued: 1966
- Authors: Brown, Michael Ewart
- Date: 1966
- Subjects: Decomposition (Chemistry) , Crystals -- Thermal properties , Oxalates -- Thermal properties , Solids -- Effect of radiation on
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4509 , http://hdl.handle.net/10962/d1013387
- Description: One of the primary objects of this research was to determine, if possible, the nature of the radiation damage prior to thermal decomposition. The X-ray study has not wholly achieved this although more information has been derived from it than from similar work on AgMnO₄ However, the diffuse reflections obtained do indicate, quite strongly, the creation of point defects during irradiation. This is of value since such assumptions have been made in the explanation of the kinetics of decomposition of a number of irradiated solids (BaN₆,CaN₆). In addition the X-ray work has suggested future research which should produce useful information; namely, a precise study of the diffuse reflections. Another object of the research was to attempt to determine what characteristics, if any, of the kinetics of the decomposition of an unirradiated solid would predetermine a marked irradiation effect. It is obvious that the type of nuclear growth which occurs e.g. branching chain, or power law, does not characterise a substance with regard to a possible irradiation effect . The photosensitivity, or otherwise, also does not determine whether there will be an irradiation effect. However, the one property that the substances which have been studied, have in common, is a polyatomic anion, but here again ammonium dichromate does not show an acceleration of the decomposition after irradiation. Consequently it is considered that it is not possible to say, a priori, whether a solid will undergo an accelerated decomposition after irradiation. Each new solid, unless it belongs to a particular class e.g. the alkaline earth azides , must be considered afresh. Nevertheless it does appear that the irradiation effect can take two forms: - (i) the production of an unstable compound e.g. nickel oxalate, the decomposition of which affects the normal pyrolysis; and (ii) the production of point defects which determine the nature of the subsequent thermal decomposition e.g . CaN₆ . It is possible that the effect requires an interaction of the created point defects with the existing line defects.
- Full Text:
- Date Issued: 1966
An examination of the extractives of Leonotis species
- Authors: Kaplan, Errol R
- Date: 1966
- Subjects: Leonotis -- Analysis Botanical chemistry Chemistry, Analytic Chemistry, Organic
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4481 , http://hdl.handle.net/10962/d1012628
- Description: Marrubiin and the other two diterpenoids, compounds X and Y, which had previously been isolated from Leonotus leonurus have been reinvestigated. Although the structure for marrubiin is well known its stereochemistry has been the subject of protracted discussion and is by no means secure except at C₅ and C₁₀ . N.M.R. spectral evidence showed that the lactone ring was cis-fused and β-orientated. Dehydration experiments carried out by previous workers were repeated, in order to resolve the residual uncertainty regarding the stereochemistry at C₉, an attempt was made to prepare iodoacetyl marrubic acid for X-ray crystallographic studies. Compound Y, C₂₀H₂₈0₃, a triply-unsaturated compound was shown by spectral studies to contain a furan ring and an α,β- unsaturated keto-group. It possesses a hydroxyl group incapable of acetylation, but readily removed by alkali and dehydrating agents to yield a tetraunsaturated compound, anhydro~Y; the hydroxyl is thus tertiary, Isolation of 1:2:5-trimethylnaphthalene on dehydrogenation indicated a relationship with the labdane diterpene group and supported the C₂₀ formula, The position of the α,β-unsaturated keto-group was resolved by interpretation of the ultraviolet spectra of degradation products and also by isolation of 1:2:3:5- trimethylnaphthalene on dehydrogenation of a suitable grignard product, The presence of a β-substituted furan was further indicated by colour reactions and confirmed by mass and n.m.r. spectra. The skeleton of compound Y is correlated with marrubiin via "iso-ambreinolide " and its stereochemistry is discussed. Further stereochemical assignments are postulated from the study of the n.m.r. spectra. Compound X, C₂₀H₂₈0₅, was shown by spectral and chemical evidence to be a diterpenoid dilactone containing an ether bridge between C₉ and C₁₃ Isolation of 1:2:5 trimethylnaphthal ene on dehydrogenation showed it to be closely related to marrubiin, This was supported by n.m.r. spectral results. A structure for compound X is proposed and the stereochemistry discussed. The aerial portions of Leonotis leonitis were also extracted and shown to contain a new compound, compound R. Preliminary investigation showed that it was a dilactone containing a furan ring, The n.m.r. spectrum of the compound is discussed.
- Full Text:
- Date Issued: 1966
- Authors: Kaplan, Errol R
- Date: 1966
- Subjects: Leonotis -- Analysis Botanical chemistry Chemistry, Analytic Chemistry, Organic
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4481 , http://hdl.handle.net/10962/d1012628
- Description: Marrubiin and the other two diterpenoids, compounds X and Y, which had previously been isolated from Leonotus leonurus have been reinvestigated. Although the structure for marrubiin is well known its stereochemistry has been the subject of protracted discussion and is by no means secure except at C₅ and C₁₀ . N.M.R. spectral evidence showed that the lactone ring was cis-fused and β-orientated. Dehydration experiments carried out by previous workers were repeated, in order to resolve the residual uncertainty regarding the stereochemistry at C₉, an attempt was made to prepare iodoacetyl marrubic acid for X-ray crystallographic studies. Compound Y, C₂₀H₂₈0₃, a triply-unsaturated compound was shown by spectral studies to contain a furan ring and an α,β- unsaturated keto-group. It possesses a hydroxyl group incapable of acetylation, but readily removed by alkali and dehydrating agents to yield a tetraunsaturated compound, anhydro~Y; the hydroxyl is thus tertiary, Isolation of 1:2:5-trimethylnaphthalene on dehydrogenation indicated a relationship with the labdane diterpene group and supported the C₂₀ formula, The position of the α,β-unsaturated keto-group was resolved by interpretation of the ultraviolet spectra of degradation products and also by isolation of 1:2:3:5- trimethylnaphthalene on dehydrogenation of a suitable grignard product, The presence of a β-substituted furan was further indicated by colour reactions and confirmed by mass and n.m.r. spectra. The skeleton of compound Y is correlated with marrubiin via "iso-ambreinolide " and its stereochemistry is discussed. Further stereochemical assignments are postulated from the study of the n.m.r. spectra. Compound X, C₂₀H₂₈0₅, was shown by spectral and chemical evidence to be a diterpenoid dilactone containing an ether bridge between C₉ and C₁₃ Isolation of 1:2:5 trimethylnaphthal ene on dehydrogenation showed it to be closely related to marrubiin, This was supported by n.m.r. spectral results. A structure for compound X is proposed and the stereochemistry discussed. The aerial portions of Leonotis leonitis were also extracted and shown to contain a new compound, compound R. Preliminary investigation showed that it was a dilactone containing a furan ring, The n.m.r. spectrum of the compound is discussed.
- Full Text:
- Date Issued: 1966
An investigation of the judgement of a sample of South African adolescent schoolchildren in certain areas of moral behaviour
- Authors: Hayward, Fritz Reitz
- Date: 1966
- Subjects: Teenagers -- South Africa -- Attitudes , Youth -- South Africa -- Conduct of life , Multiculturalism -- Moral and ethical aspects , Moral education -- South Africa , Moral development -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1998 , http://hdl.handle.net/10962/d1015009
- Description: A. The Aims The modern adolescent is frequently accused of being morally lax; his judgement of moral issues is held in question; and parents, church and school are accused of having lost their influence on present-day youth. The writer wes lnterested in finding out whether these accusations could in fact be substantiated amongst a sample of adolescent school-children in a selected urban area. The aims of the research, therefore, were as follows :- (i) to investigate the judgement of these adolescents in certain given areas of moral behaviour, (ii) to determine whether there were any appreciable differences between the Afrikaans-speaking and English-speaking adolescents of the sample in their judgements of these moral issues, (iii) to determine whether there were any appreciable differences between adolescent boys and girls of the sample in their judgement of these moral issues, (iv) to explore the influences which caused the tested adolescents to re-act as they did.
- Full Text:
- Date Issued: 1966
- Authors: Hayward, Fritz Reitz
- Date: 1966
- Subjects: Teenagers -- South Africa -- Attitudes , Youth -- South Africa -- Conduct of life , Multiculturalism -- Moral and ethical aspects , Moral education -- South Africa , Moral development -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1998 , http://hdl.handle.net/10962/d1015009
- Description: A. The Aims The modern adolescent is frequently accused of being morally lax; his judgement of moral issues is held in question; and parents, church and school are accused of having lost their influence on present-day youth. The writer wes lnterested in finding out whether these accusations could in fact be substantiated amongst a sample of adolescent school-children in a selected urban area. The aims of the research, therefore, were as follows :- (i) to investigate the judgement of these adolescents in certain given areas of moral behaviour, (ii) to determine whether there were any appreciable differences between the Afrikaans-speaking and English-speaking adolescents of the sample in their judgements of these moral issues, (iii) to determine whether there were any appreciable differences between adolescent boys and girls of the sample in their judgement of these moral issues, (iv) to explore the influences which caused the tested adolescents to re-act as they did.
- Full Text:
- Date Issued: 1966
Genadendal and its satellites : a history of the Moravian Mission stations at the Cape, 1737-1869
- Authors: Krüger, Bernhard
- Date: 1966
- Subjects: Moravians -- Missions -- South Africa -- Genadendal , Missions -- South Africa -- History , Genadendal (South Africa) -- History , Cape of Good Hope (South Africa) -- History -- To 1795 , Cape of Good Hope (South Africa) -- History -- 1795-1872
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1284 , http://hdl.handle.net/10962/d1013470
- Description: J,F.w. Kühn, a member of the Moravian Mission Board, wrote in 1871 to the Superintendent at Genadendal that the closed settlements in South Africa were a precious and unique feature of mission work for which the brethren should be grateful. While he had been at the Gape, he had suffered under the difficulties of their management, but from the distance, and in comparison with mission work elsewhere, he had learnt to appreciate them as a great blessing. The questions arise: How dld they originate, develop and survive for so long? What were their characteristics, advantages and limitations? What factors contributed to their development? How did they fit into their milieu and influence it? The following thesis is an effort to give a detailed history of their development and an appraisal. I have endeavoured to give a vivid picture of personalities and events within the limits of historical correctness, because I consider it the noblest aim of historical research to confront us with the past in such a way that personal understanding becomes possible. In as much as we meet those who have made history. or have been part of it, in person, we can arrive at a deeper appreciation of their achievements, problems and failures.
- Full Text:
- Date Issued: 1966
- Authors: Krüger, Bernhard
- Date: 1966
- Subjects: Moravians -- Missions -- South Africa -- Genadendal , Missions -- South Africa -- History , Genadendal (South Africa) -- History , Cape of Good Hope (South Africa) -- History -- To 1795 , Cape of Good Hope (South Africa) -- History -- 1795-1872
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1284 , http://hdl.handle.net/10962/d1013470
- Description: J,F.w. Kühn, a member of the Moravian Mission Board, wrote in 1871 to the Superintendent at Genadendal that the closed settlements in South Africa were a precious and unique feature of mission work for which the brethren should be grateful. While he had been at the Gape, he had suffered under the difficulties of their management, but from the distance, and in comparison with mission work elsewhere, he had learnt to appreciate them as a great blessing. The questions arise: How dld they originate, develop and survive for so long? What were their characteristics, advantages and limitations? What factors contributed to their development? How did they fit into their milieu and influence it? The following thesis is an effort to give a detailed history of their development and an appraisal. I have endeavoured to give a vivid picture of personalities and events within the limits of historical correctness, because I consider it the noblest aim of historical research to confront us with the past in such a way that personal understanding becomes possible. In as much as we meet those who have made history. or have been part of it, in person, we can arrive at a deeper appreciation of their achievements, problems and failures.
- Full Text:
- Date Issued: 1966
Ionospheric effects in the Southern radiation anomaly
- Authors: Torr, Douglas G
- Date: 1966
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5540 , http://hdl.handle.net/10962/d1013305
- Description: From introduction: As ionosphericist on the 4th South African National Antarctic Expedition, I spent twelve months at Sanae (70°18'S, 2°2l'W, L= 4) in 1963. In the course of routine vertical incidence soundings, it was noticed with some surprise that the frequency of occurrence of ionospheric blackouts was unexpectedly high. Initially this aroused considerable concern about the reliability of the equipment. In fact it has been · observed that some stations lying in and near the Southern Radiation Anomaly report such occasions as records lost due to non-ionospheric reasons. Coincidently, however, Gledhill and van Rooyen (1963), also of Rhodes University, predicted ionospheric irregularities and other geophysical phenomena in a region around Sanae where Ginsburg et al. (1962) observed high intensities of charged particles with Sputniks 5 and 6.
- Full Text:
- Date Issued: 1966
- Authors: Torr, Douglas G
- Date: 1966
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5540 , http://hdl.handle.net/10962/d1013305
- Description: From introduction: As ionosphericist on the 4th South African National Antarctic Expedition, I spent twelve months at Sanae (70°18'S, 2°2l'W, L= 4) in 1963. In the course of routine vertical incidence soundings, it was noticed with some surprise that the frequency of occurrence of ionospheric blackouts was unexpectedly high. Initially this aroused considerable concern about the reliability of the equipment. In fact it has been · observed that some stations lying in and near the Southern Radiation Anomaly report such occasions as records lost due to non-ionospheric reasons. Coincidently, however, Gledhill and van Rooyen (1963), also of Rhodes University, predicted ionospheric irregularities and other geophysical phenomena in a region around Sanae where Ginsburg et al. (1962) observed high intensities of charged particles with Sputniks 5 and 6.
- Full Text:
- Date Issued: 1966
Johannes van Melle : realist tussen twee werelden
- Authors: Jonckheere, W F
- Date: 1966
- Subjects: Van Melle, J. (Johannes),1887-1953
- Language: Dutch
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3645 , http://hdl.handle.net/10962/d1015200
- Description: [From Introduction]. Aan het werk van Johannes Van Melle is tot dusver geen allesomvattende studie gewijd. Het is vooral in dit tekort dat het onderhavige proefschrift wil voorzien. Reeds vroeger hebben enkelen hun aandacht op onderdelen van Van Melles proza gericht maar niemand heeft eft ooit ondernomen de hele reeks van Van Melles gepubliceerde en ongepubliceerde gechriften te onderzoeken en deze zowel in hun samenhang als afzonderlijk naar waarde te schatten.
- Full Text:
- Date Issued: 1966
- Authors: Jonckheere, W F
- Date: 1966
- Subjects: Van Melle, J. (Johannes),1887-1953
- Language: Dutch
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3645 , http://hdl.handle.net/10962/d1015200
- Description: [From Introduction]. Aan het werk van Johannes Van Melle is tot dusver geen allesomvattende studie gewijd. Het is vooral in dit tekort dat het onderhavige proefschrift wil voorzien. Reeds vroeger hebben enkelen hun aandacht op onderdelen van Van Melles proza gericht maar niemand heeft eft ooit ondernomen de hele reeks van Van Melles gepubliceerde en ongepubliceerde gechriften te onderzoeken en deze zowel in hun samenhang als afzonderlijk naar waarde te schatten.
- Full Text:
- Date Issued: 1966
Studies in Gusii kinship
- Authors: Mayer, Iona
- Date: 1966
- Subjects: Gusii (African people) -- Kinship
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2119 , http://hdl.handle.net/10962/d1012846
- Description: This thesis has two aims. In Part I the aim is to present some unpublished field material on Gusii kinship, particularly on domestic relations between the generations and the sexes. In Part II the aim is to clarify a theoretical model of 'relation by kinship', and of ' kinship categories" and 'classificntion', based on an examination of the ways in which Gusii use kinship terms. Intro., p. 1.
- Full Text:
- Date Issued: 1966
- Authors: Mayer, Iona
- Date: 1966
- Subjects: Gusii (African people) -- Kinship
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2119 , http://hdl.handle.net/10962/d1012846
- Description: This thesis has two aims. In Part I the aim is to present some unpublished field material on Gusii kinship, particularly on domestic relations between the generations and the sexes. In Part II the aim is to clarify a theoretical model of 'relation by kinship', and of ' kinship categories" and 'classificntion', based on an examination of the ways in which Gusii use kinship terms. Intro., p. 1.
- Full Text:
- Date Issued: 1966
The thermal decomposition of mercuric oxalate and inorganic azides
- Authors: Moore, D J
- Date: 1966
- Subjects: Decomposition (Chemistry) , Oxalates -- Thermal properties , Mercuric Oxide -- Azides
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4483 , http://hdl.handle.net/10962/d1012878
- Description: The chemical reactivity of a solid is influenced to a marked degree by the presence of imperfections or defects in the solid. Bond strengths are considerably weaker at points of imperfection than elsewhere in the solid, and hence the initiation of reaction is favoured at these sites due to the relative ease of bond rupture. Line defects, such as edge or screw dislocations, jogs, Smekul cracks etc, are of prime importance in such changes. The surface of a solid or in intergranular boundaries, where a state of strain exists, are also favourable places for the initiation of a reaction, Point defects e.g. vacancies or interstitialions or atoms also play important roles in chemical change, often in conjuction with line defects.
- Full Text:
- Date Issued: 1966
- Authors: Moore, D J
- Date: 1966
- Subjects: Decomposition (Chemistry) , Oxalates -- Thermal properties , Mercuric Oxide -- Azides
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4483 , http://hdl.handle.net/10962/d1012878
- Description: The chemical reactivity of a solid is influenced to a marked degree by the presence of imperfections or defects in the solid. Bond strengths are considerably weaker at points of imperfection than elsewhere in the solid, and hence the initiation of reaction is favoured at these sites due to the relative ease of bond rupture. Line defects, such as edge or screw dislocations, jogs, Smekul cracks etc, are of prime importance in such changes. The surface of a solid or in intergranular boundaries, where a state of strain exists, are also favourable places for the initiation of a reaction, Point defects e.g. vacancies or interstitialions or atoms also play important roles in chemical change, often in conjuction with line defects.
- Full Text:
- Date Issued: 1966
Ultraviolet specular reflectance, electronic absorption and the excitation of fluorescence in single crystals of anthracene
- Authors: Wright, W H
- Date: 1966
- Subjects: Anthracene crystals -- Fluorescence , Ultraviolet spectroscopy -- Absorption , Reflectance
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5544 , http://hdl.handle.net/10962/d1013366
- Description: From introduction: The Fluorescence Excitation Spectrum or anthracene is known to vary considerably with the age and condition or the crystal. This thesis represents an attempt to improve the understanding of these variations. To put the problem on a quantitative basis it was found necessary to know both the ultraviolet reflection and absorption spectra. Reports of the reflection spectrum appear to have been confined to the case of polarised incident light. In addition the reflectivity measurements are always reported for a freshly cleaved surface. For these reasons the reflectivity of anthracene for various conditions of the reflecting surface was measured with unpolarised light. These varying reflectivities were used to further knowledge of the chemical processes at the crystal surface, as well as being used directly in the calculation of fluorescence excitation spectra. Reflection spectra with a- and b- crystallographic axis polarisations were also obtained. Since such spectra are reported in the literature it was possible, by comparison, to conclude that the experimental methods used in this thesis yielded valid results. The polarised measurements were used to obtain optical constants for the crystal. In the interests of readability most of the complicated process of converting the reflectivities to optical constants is dealt with in three appendices to the thesis.
- Full Text:
- Date Issued: 1966
- Authors: Wright, W H
- Date: 1966
- Subjects: Anthracene crystals -- Fluorescence , Ultraviolet spectroscopy -- Absorption , Reflectance
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5544 , http://hdl.handle.net/10962/d1013366
- Description: From introduction: The Fluorescence Excitation Spectrum or anthracene is known to vary considerably with the age and condition or the crystal. This thesis represents an attempt to improve the understanding of these variations. To put the problem on a quantitative basis it was found necessary to know both the ultraviolet reflection and absorption spectra. Reports of the reflection spectrum appear to have been confined to the case of polarised incident light. In addition the reflectivity measurements are always reported for a freshly cleaved surface. For these reasons the reflectivity of anthracene for various conditions of the reflecting surface was measured with unpolarised light. These varying reflectivities were used to further knowledge of the chemical processes at the crystal surface, as well as being used directly in the calculation of fluorescence excitation spectra. Reflection spectra with a- and b- crystallographic axis polarisations were also obtained. Since such spectra are reported in the literature it was possible, by comparison, to conclude that the experimental methods used in this thesis yielded valid results. The polarised measurements were used to obtain optical constants for the crystal. In the interests of readability most of the complicated process of converting the reflectivities to optical constants is dealt with in three appendices to the thesis.
- Full Text:
- Date Issued: 1966
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