Geochemical exploration in calcrete terrains
- Authors: Krug, Mark Alan
- Date: 1995 , 2013-10-02
- Subjects: Duricrusts , Silcrete , Geochemical prospecting
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5026 , http://hdl.handle.net/10962/d1006891 , Duricrusts , Silcrete , Geochemical prospecting
- Description: This work takes a look at some of the literature on calcretes and especially the problem of geochemical exploration in calcrete terrains. The conclusion that will be reached is that exploration in calcrete terrains is not futile and that provided the explorationist is aware of the types of calcrete and their genetic implications calcrete can be used as a sampling medium and anomalies can be detected through calcrete (p.1.) , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 1995
- Authors: Krug, Mark Alan
- Date: 1995 , 2013-10-02
- Subjects: Duricrusts , Silcrete , Geochemical prospecting
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5026 , http://hdl.handle.net/10962/d1006891 , Duricrusts , Silcrete , Geochemical prospecting
- Description: This work takes a look at some of the literature on calcretes and especially the problem of geochemical exploration in calcrete terrains. The conclusion that will be reached is that exploration in calcrete terrains is not futile and that provided the explorationist is aware of the types of calcrete and their genetic implications calcrete can be used as a sampling medium and anomalies can be detected through calcrete (p.1.) , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 1995
Geological characteristics of selected disseminated sediment-hosted gold deposits in Nevada, U.S.A. : in search of an exploration model
- Authors: Skead, Michael Bethel
- Date: 1995 , 2013-10-07
- Subjects: Gold ores -- Geology -- Nevada
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5036 , http://hdl.handle.net/10962/d1007414 , Gold ores -- Geology -- Nevada
- Description: Sediment-hosted disseminated gold deposits in Nevada, western United States are major gold sources and contain reserves in excess of 1 500 metric tons of gold (Percival et aI., 1988). Discovery of these deposit types continues at a pace, with Placer Dome announcing a mojor discovery, Pipeline, to the south of the Gold Acres Mine, along the Battle Mountain - Eureka Trend in 1994 (The Northern Miner, 1994). Host sediments favoured for disseminated gold mineralisation are thinly bedded silty limestones , carbonate debris flows and to a lesser extent shale, chert and sandstone. The distribution of mineralisation is controlled essentially by the intersection of high-angle faults, which acted as conduits for hydrothermal fluids, with favourable host lithologies, anticlines, low-angle faults and other high-angle faults. Geochemical signature for these deposits is simple being Au, Ag, As, Sb, Hg, Tl, Te, F and Ba, but individual element concentrations vary greatly between and within deposits. Age of mineralisation is cause for considerable debate, and ages ranging between isotopic dates of approximately 117 Ma to early to mid-Tertiary (30-40 Ma) are proposed. Most of these deposits are situated along three major trends namely the Carlin, Battle Mountain - Eureka and Getchell trends. The Battle Mountain - Eureka trend and, to a lesser extent the Carlin trend, are defined by major linear aeromagnetic and gravity anomalies , which are believed to reflect deep-seated structures. Most deposits are hosted in autochthonous Devonian, thinly bedded, silty limestones that occur as windows through what is believed to be allochthonous Ordovician siliciclastic sediments, which were transported from west to east along the Roberts Mountains thrust during the late-Devonian Antler Orogeny. However, recent fossil dating of what were thought to be Ordivician siliciclastic sediments, gives a Devonian age. This questions the age of Ordivician sediments at the other deposits and the interpretation of the structural windows in which deposits are located. Fault-bounded, proximal, carbonate debris-flow breccias are now recognised as a major host to mineralisation. These debris flow breccias, together with interbedded carbonate and siliciclastic sediments, carbonaceous sediments and soft sediment deformation are all characteristics of lithologies in pull-apart basins which develop along a major strike slip faults. It is proposed that sediment-hosted disseminated gold mineralisation is controlled by the distribution of deep-seated long-lived, predominantly right-lateral strike-slip faults. It is along these strike-slip faults that syn-sedimentary pull-apart basins developed, within which sediments favoured by epigenetic gold mineralisation were deposited. These pull-apart basins were then overprinted by post-depositional extensional structures, such as negative flower structures. Igneous intrusions and hydrothermal cells have exploited these extensional structures in both compressional and extensional regional tectonic regimes. This model explains the characteristics of the host sediment at many of the deposits, the spatial relationship between igneous intrusion and mineralisation, spanning the period Cretaceous through to mid-Tertiary, the distribution of deposits as districts along major regional trends and why hydrothermal activity is noted between deposit districts but with no complementary mineralisation. Mineralisation is controlled predominantly by high angle structures and although the recent age for mineralisation at the Betze/Post deposit is ~ 117 Ma (Arehart et aI., 1993a), placing it in the compressional Sevier Orogeny, these high-angle structures would be developed within local extensional tectonic domains as described above. This model can, and should, be applied to other areas of the world where similar geological features exist. In exploring for these deposits in Nevada the distribution of Ordovician siliciclastic sediments should be reviewed, especially where spatially associated with deep regional structures. Ordovician sediments have historically been regarded as unfavourable, hence large areas for potential exploration have been ignored but with new ages for these sediments this opens large areas for potential discoveries. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 1995
- Authors: Skead, Michael Bethel
- Date: 1995 , 2013-10-07
- Subjects: Gold ores -- Geology -- Nevada
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5036 , http://hdl.handle.net/10962/d1007414 , Gold ores -- Geology -- Nevada
- Description: Sediment-hosted disseminated gold deposits in Nevada, western United States are major gold sources and contain reserves in excess of 1 500 metric tons of gold (Percival et aI., 1988). Discovery of these deposit types continues at a pace, with Placer Dome announcing a mojor discovery, Pipeline, to the south of the Gold Acres Mine, along the Battle Mountain - Eureka Trend in 1994 (The Northern Miner, 1994). Host sediments favoured for disseminated gold mineralisation are thinly bedded silty limestones , carbonate debris flows and to a lesser extent shale, chert and sandstone. The distribution of mineralisation is controlled essentially by the intersection of high-angle faults, which acted as conduits for hydrothermal fluids, with favourable host lithologies, anticlines, low-angle faults and other high-angle faults. Geochemical signature for these deposits is simple being Au, Ag, As, Sb, Hg, Tl, Te, F and Ba, but individual element concentrations vary greatly between and within deposits. Age of mineralisation is cause for considerable debate, and ages ranging between isotopic dates of approximately 117 Ma to early to mid-Tertiary (30-40 Ma) are proposed. Most of these deposits are situated along three major trends namely the Carlin, Battle Mountain - Eureka and Getchell trends. The Battle Mountain - Eureka trend and, to a lesser extent the Carlin trend, are defined by major linear aeromagnetic and gravity anomalies , which are believed to reflect deep-seated structures. Most deposits are hosted in autochthonous Devonian, thinly bedded, silty limestones that occur as windows through what is believed to be allochthonous Ordovician siliciclastic sediments, which were transported from west to east along the Roberts Mountains thrust during the late-Devonian Antler Orogeny. However, recent fossil dating of what were thought to be Ordivician siliciclastic sediments, gives a Devonian age. This questions the age of Ordivician sediments at the other deposits and the interpretation of the structural windows in which deposits are located. Fault-bounded, proximal, carbonate debris-flow breccias are now recognised as a major host to mineralisation. These debris flow breccias, together with interbedded carbonate and siliciclastic sediments, carbonaceous sediments and soft sediment deformation are all characteristics of lithologies in pull-apart basins which develop along a major strike slip faults. It is proposed that sediment-hosted disseminated gold mineralisation is controlled by the distribution of deep-seated long-lived, predominantly right-lateral strike-slip faults. It is along these strike-slip faults that syn-sedimentary pull-apart basins developed, within which sediments favoured by epigenetic gold mineralisation were deposited. These pull-apart basins were then overprinted by post-depositional extensional structures, such as negative flower structures. Igneous intrusions and hydrothermal cells have exploited these extensional structures in both compressional and extensional regional tectonic regimes. This model explains the characteristics of the host sediment at many of the deposits, the spatial relationship between igneous intrusion and mineralisation, spanning the period Cretaceous through to mid-Tertiary, the distribution of deposits as districts along major regional trends and why hydrothermal activity is noted between deposit districts but with no complementary mineralisation. Mineralisation is controlled predominantly by high angle structures and although the recent age for mineralisation at the Betze/Post deposit is ~ 117 Ma (Arehart et aI., 1993a), placing it in the compressional Sevier Orogeny, these high-angle structures would be developed within local extensional tectonic domains as described above. This model can, and should, be applied to other areas of the world where similar geological features exist. In exploring for these deposits in Nevada the distribution of Ordovician siliciclastic sediments should be reviewed, especially where spatially associated with deep regional structures. Ordovician sediments have historically been regarded as unfavourable, hence large areas for potential exploration have been ignored but with new ages for these sediments this opens large areas for potential discoveries. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 1995
Petrogenesis of the New Amalfi sheet a highly differentiated Karoo intrusion
- Authors: Williams, Craig Milton
- Date: 1995
- Subjects: Petrogenesis -- South Africa -- Eastern Cape -- Karoo , Geochemistry -- South Africa -- Eastern Cape -- Karoo
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4985 , http://hdl.handle.net/10962/d1005597 , Petrogenesis -- South Africa -- Eastern Cape -- Karoo , Geochemistry -- South Africa -- Eastern Cape -- Karoo
- Description: The New Amalfi Sheet is a highly differentiated tholeiitic intrusion which is situated between the towns of Matatiele and Swartberg in East Griqualand. It lies within the Central area of the Karoo Igneous Province. Rock types range from dolerites at the base and top through to a highly differentiated granophyre which is found as a 'sandwich horizon' within the top half of the sheet. The most evolved granophyre represents 15.86% of the initial liquid, which was found to be very similar in composition to the average Lesotho-type magma of Marsh and Eales (1984). The paragenetic sequence was found to be chromite → olivine → plagioclase → pigeonite and augite. Cumulus magnetite and ilmenite enter the paragenetic sequence together with immiscible sulphide droplets after 35% crystallization. In the late stages of crystallization, augite changes composition towards ferrohedenbergite. The reappearance of iron-rich olivine coincides with the disappearance of pigeonite and apatite appears as a cumulus phase for the first time after 70% crystallization. Granophyric intergrowth, which contains coarse perthitic Kfeldspar, becomes the most abundant modal entity within the most evolved granophyres. Differentiation was dominated by fractionation of plagioclase and pyroxene, with subordinate olivine and opaque-oxide fractionation. A minor amount of assimilation of country rock occurred within the topmost granophyres. The intrusion has been dated, using the Rb-Sr isochron method, at 178.37 ± 5.52 Ma. Extensive subsolidus deuteric alteration has resulted in the formation of a complete series of hydrothermally altered clinopyroxenes which are enriched in CaO but depleted in TiO₂ compared to the unaltered magmatic clinopyroxenes. It has also resulted in the formation of abundant vermiform ilmenite in the most evolved rocks, recognized by the fact that this phase is enriched in MnO compared to magmatic ilmenites. The very iron-rich orthopyroxene, ferrohypersthene, was found to have crystallized, during cooling of the sheet from the intercumulus liquid. Olivine in the dolerite re-equilibrated with the intercumulus liquid, becoming more iron-rich in composition.
- Full Text:
- Date Issued: 1995
- Authors: Williams, Craig Milton
- Date: 1995
- Subjects: Petrogenesis -- South Africa -- Eastern Cape -- Karoo , Geochemistry -- South Africa -- Eastern Cape -- Karoo
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4985 , http://hdl.handle.net/10962/d1005597 , Petrogenesis -- South Africa -- Eastern Cape -- Karoo , Geochemistry -- South Africa -- Eastern Cape -- Karoo
- Description: The New Amalfi Sheet is a highly differentiated tholeiitic intrusion which is situated between the towns of Matatiele and Swartberg in East Griqualand. It lies within the Central area of the Karoo Igneous Province. Rock types range from dolerites at the base and top through to a highly differentiated granophyre which is found as a 'sandwich horizon' within the top half of the sheet. The most evolved granophyre represents 15.86% of the initial liquid, which was found to be very similar in composition to the average Lesotho-type magma of Marsh and Eales (1984). The paragenetic sequence was found to be chromite → olivine → plagioclase → pigeonite and augite. Cumulus magnetite and ilmenite enter the paragenetic sequence together with immiscible sulphide droplets after 35% crystallization. In the late stages of crystallization, augite changes composition towards ferrohedenbergite. The reappearance of iron-rich olivine coincides with the disappearance of pigeonite and apatite appears as a cumulus phase for the first time after 70% crystallization. Granophyric intergrowth, which contains coarse perthitic Kfeldspar, becomes the most abundant modal entity within the most evolved granophyres. Differentiation was dominated by fractionation of plagioclase and pyroxene, with subordinate olivine and opaque-oxide fractionation. A minor amount of assimilation of country rock occurred within the topmost granophyres. The intrusion has been dated, using the Rb-Sr isochron method, at 178.37 ± 5.52 Ma. Extensive subsolidus deuteric alteration has resulted in the formation of a complete series of hydrothermally altered clinopyroxenes which are enriched in CaO but depleted in TiO₂ compared to the unaltered magmatic clinopyroxenes. It has also resulted in the formation of abundant vermiform ilmenite in the most evolved rocks, recognized by the fact that this phase is enriched in MnO compared to magmatic ilmenites. The very iron-rich orthopyroxene, ferrohypersthene, was found to have crystallized, during cooling of the sheet from the intercumulus liquid. Olivine in the dolerite re-equilibrated with the intercumulus liquid, becoming more iron-rich in composition.
- Full Text:
- Date Issued: 1995
The metallogeny of the Upington and Kenhardt area, northern Cape
- Authors: Boelema, Robert
- Date: 1995
- Subjects: Metallogeny -- South Africa , Metallogeny -- South Africa -- Northern Cape , Plate tectonics -- South Africa -- Northern Cape , Geology, Structural -- South Africa -- Northern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4975 , http://hdl.handle.net/10962/d1005587 , Metallogeny -- South Africa , Metallogeny -- South Africa -- Northern Cape , Plate tectonics -- South Africa -- Northern Cape , Geology, Structural -- South Africa -- Northern Cape
- Description: In the Upington region, there are three major- tectonic crustal provinces; namely the Kaapvaal Craton, Kheis and Namaqua tectonic provinces. The Eburnian-aged (early Proterozoic) Kheis Province developed along the western flank of the Archaean Kaapvaal Craton while the Kibaran-aged (middle Proterozoic) Namaqua Metamorphic Province, superimposed on the Eburnian-aged basement, developed to the east of the Kheis Province. The Namaqua Metamorphic Province is divided into the Gordonia and Bushmanland Subprovinces, the former being further subdivided into various tectonostratigraphic terranes. These are termed, from west to east, the Kakamas, Areachap, and Upington Terranes. The Upington Terrane includes fault bounded grabens with accompanied bimodal volcanism and sedimentation of the Wilgenhoutsdrif and Koras Groups. The Areachap Terrane consists predominantly of amphibolites generated in an island arc environment while the Kakamas Terrane is characterised by volcano-sedimentary sequences which have been extensively intruded by syn to late-tectonic predominantly I-type Keimoes Suite granitoids. The main styles of mineralisation correlate well with the various tectonostratigraphic terranes. Sedimentary exhalative massive sulphide deposits are characteristic of the Bushmanland Subprovince and are thought to be associated with the deposits at Aggeneys and Putsberg to the west of the area under investigation. These deposits are considered to have been deposited in an east-west-elongated intracontinental basin. The Kakamas Terrane is typified by granite-related mineralisation. In the eastern portion of the Kakamas Terrane, Sn-Wand base metal-bearing veins occur while pegmatites are developed in the western portion. These two styles of granite-related mineralisation is considered to reflect differing depths of formation due mainly to varying degrees of thrusting. The Areachap Terrane consists of volcanogenic massive sulphide deposits of the Besshi-type and is considered to have formed in a back-arc environment. In the Upington Terrane, the Wilgenhoutsdrif and Koras Groups consists essentially of minor Cu occurrences mainly disseminated within basalts and in structural trap sites. The possibility for sediment-hosted Cu deposits is not ruled out. More recent surface processes have led to uranium and gypsum deposits in pans, river beds and calcretes. Eburnian aged tectonic setting remains enigmatic. Kibaran-aged tectonics which best fits the metallogeny of the area under investigation is considered to be of a subduction zone from west to east formed by the collision of the Bushmanland "microcontinent" against the Kaapvaal Craton. Subduction fbrmed an island arc setting in which the massive sulphide deposits were formed in the Areachap Terrane while the Wilgenhoutsdrif Groups developed in a marginal basin. Further convergence led to collision of the two continents and underriding of the Bushmanland "microcontinent" which generated predominantly I-type granitoids represented by the Keimoes Suite. The level of emplacement of these granitoids is a reflection of the degree of foreland thrusting and produced shallower level Sn-W and base metal vein-type mineralisation closer to the suture zone and deeper level pegmatites further from the suture zone to the west. The final period of deformation is represented by northward lateral movement which created "pull apart" fault-bounded basins into which the Koras Group was deposited.
- Full Text:
- Date Issued: 1995
- Authors: Boelema, Robert
- Date: 1995
- Subjects: Metallogeny -- South Africa , Metallogeny -- South Africa -- Northern Cape , Plate tectonics -- South Africa -- Northern Cape , Geology, Structural -- South Africa -- Northern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4975 , http://hdl.handle.net/10962/d1005587 , Metallogeny -- South Africa , Metallogeny -- South Africa -- Northern Cape , Plate tectonics -- South Africa -- Northern Cape , Geology, Structural -- South Africa -- Northern Cape
- Description: In the Upington region, there are three major- tectonic crustal provinces; namely the Kaapvaal Craton, Kheis and Namaqua tectonic provinces. The Eburnian-aged (early Proterozoic) Kheis Province developed along the western flank of the Archaean Kaapvaal Craton while the Kibaran-aged (middle Proterozoic) Namaqua Metamorphic Province, superimposed on the Eburnian-aged basement, developed to the east of the Kheis Province. The Namaqua Metamorphic Province is divided into the Gordonia and Bushmanland Subprovinces, the former being further subdivided into various tectonostratigraphic terranes. These are termed, from west to east, the Kakamas, Areachap, and Upington Terranes. The Upington Terrane includes fault bounded grabens with accompanied bimodal volcanism and sedimentation of the Wilgenhoutsdrif and Koras Groups. The Areachap Terrane consists predominantly of amphibolites generated in an island arc environment while the Kakamas Terrane is characterised by volcano-sedimentary sequences which have been extensively intruded by syn to late-tectonic predominantly I-type Keimoes Suite granitoids. The main styles of mineralisation correlate well with the various tectonostratigraphic terranes. Sedimentary exhalative massive sulphide deposits are characteristic of the Bushmanland Subprovince and are thought to be associated with the deposits at Aggeneys and Putsberg to the west of the area under investigation. These deposits are considered to have been deposited in an east-west-elongated intracontinental basin. The Kakamas Terrane is typified by granite-related mineralisation. In the eastern portion of the Kakamas Terrane, Sn-Wand base metal-bearing veins occur while pegmatites are developed in the western portion. These two styles of granite-related mineralisation is considered to reflect differing depths of formation due mainly to varying degrees of thrusting. The Areachap Terrane consists of volcanogenic massive sulphide deposits of the Besshi-type and is considered to have formed in a back-arc environment. In the Upington Terrane, the Wilgenhoutsdrif and Koras Groups consists essentially of minor Cu occurrences mainly disseminated within basalts and in structural trap sites. The possibility for sediment-hosted Cu deposits is not ruled out. More recent surface processes have led to uranium and gypsum deposits in pans, river beds and calcretes. Eburnian aged tectonic setting remains enigmatic. Kibaran-aged tectonics which best fits the metallogeny of the area under investigation is considered to be of a subduction zone from west to east formed by the collision of the Bushmanland "microcontinent" against the Kaapvaal Craton. Subduction fbrmed an island arc setting in which the massive sulphide deposits were formed in the Areachap Terrane while the Wilgenhoutsdrif Groups developed in a marginal basin. Further convergence led to collision of the two continents and underriding of the Bushmanland "microcontinent" which generated predominantly I-type granitoids represented by the Keimoes Suite. The level of emplacement of these granitoids is a reflection of the degree of foreland thrusting and produced shallower level Sn-W and base metal vein-type mineralisation closer to the suture zone and deeper level pegmatites further from the suture zone to the west. The final period of deformation is represented by northward lateral movement which created "pull apart" fault-bounded basins into which the Koras Group was deposited.
- Full Text:
- Date Issued: 1995
The mineralogy and geochemistry of the Voëlwater banded iron-formation, Northern Cape Province
- Authors: Tsikos, Harilaos
- Date: 1995
- Subjects: Mineralogy -- South Africa -- Northern Cape , Geochemistry -- South Africa -- Northern Cape , Geology -- South Africa -- Northern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4977 , http://hdl.handle.net/10962/d1005589 , Mineralogy -- South Africa -- Northern Cape , Geochemistry -- South Africa -- Northern Cape , Geology -- South Africa -- Northern Cape
- Description: Banded iron-formations (BIFs) are chemically precipitated sedimentary rocks in which Fe-rich bands or laminae alternate with Fe-poor ones. They formed within a specific time-span of the geological record. Their occurrence is restricted between 2.3 and 1.9 Ga, and characterises virtually all the major Precambrian-aged sedimentary basins of the world. The Precambrian Transvaal Basin in Griqualand West, South Africa, is noted for its well-developed BIF units. The Kuruman and Griquatown BIFs comprising the Asbesheuwels Subgroup (up to 1000m thick) are the best known and thickest of these. As far as metallogenesis is concerned, the Kuruman BIF is of major importance, for it carries the world's largest crocidolite (blue asbestos) deposits. The uppermost, youngest member of iron-formation deposition in the Griqualand West Sequence is represented by the Voëlwater BIF. The direct association between the latter and the giant Mn-deposits of the Kalahari Field, renders the Voëlwater association unusual, if not unique, in the geological record. The Voëlwater BIF represents a typical example of the so-called "Superior-type", and in the area of study it has undergone late-diagennetic to low-grade metamorphic processes. This is evident from the mineralogical composition and textural signature of the various BIF lithologies. Specifically, the minerals that make up the Voëlwater BIF are mainly chert(quartz), Fe-oxides (magnetite and hematite), Fe-silicates (greenalite, stilpnomelane, minnesotaite, riebeckite, Fe-mica), Fe-carbonates (members of the dolomite-ankerite series and siderite), calcite and pyrite. Soft-sediment deformation structures and shear-stress indicators are abundant in carbonate-rich and granular, silicate-rich BIF lithologies respectively. The bulk chemical composition of the study rocks is relatively simple and is characterised by the abundance of essentially three elements, namely Si, Fe, and Ca, which make up more than 90% of the total chemical composition of the Voëlwater BIFs. The detrital component of the study rocks is negligible. Mn-enrichments characterise all the transitional lithologies towards the interbedded Mn-orebodies, as well as the well-developed, hematitic BIF-unit between the Ongeluk lavas and the lower Mn-horizon. In terms of trace element composition, no significant enrichments or depletions, were encountered, except for some unusually high values of Sr and Ba and Co in carbonate-rich and Mn-rich lithologies respectively. Geochemical comparisons on the basis of major, trace and light rare-earth element composition verified the similarity between the Voëlwater BIF and other major Superior-type BIFs of the world (e.g. Kuruman, Griquatown, Sokoman, Biwabik, Gunflint, Mara-Mamba, Brockman, etc.). The processes that led to the formation of the Voëlwater BIFs may have been very similar to the ones described in various genetic models proposed in recent years. They would have involved a combination of: i. hydrothermal processes related to mid-ocean ridge (MOR) or hot-spot activity that acted as major iron suppliers; ii. storm-mixing in stratified oceans (bottom, anoxic, Fe⁺² reservoir-thermo- pycnocline zone-upper, mixed, SiO₂-saturated layer), largely dictated by seasonal changes and contemporaneous volcanism; iii. periodic, convection-driven upwelling mechanisms acting as major Fe-precipitators; and, iv. organic carbon productivity that was responsible for the anoxic diagenesis of the initial sediment. However, the origin of Fe and Mn for the genesis of the Voëlwater sediments was difficult to explain with typical convection-cell models in active mid-ocean ridges, in contrast to previous hypotheses. Instead, large-scale endogenous processes in the form of magma convection, underplating, differentiation and associated degassing, may have played a critical role in the supply of metals for the formation of large amounts of BIFs in the Precambrian. The present study of the Voëlwater BIF also bears strong implications regarding the metallogenesis of Mn in the Precambrian. The common association of Mn with carbonate-bearing sediments, the transitional character of the Voëlwater BIF towards carbonate lithologies (Mooidraai dolomites) and the critical timing of the deposition of the former in terms of the Precambrian atmospheric-lithospheric- hydrospheric evolution, may be important indicators for the exploration of large Mn-deposits in Precambrian sedimentary basins of the world.
- Full Text:
- Date Issued: 1995
- Authors: Tsikos, Harilaos
- Date: 1995
- Subjects: Mineralogy -- South Africa -- Northern Cape , Geochemistry -- South Africa -- Northern Cape , Geology -- South Africa -- Northern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4977 , http://hdl.handle.net/10962/d1005589 , Mineralogy -- South Africa -- Northern Cape , Geochemistry -- South Africa -- Northern Cape , Geology -- South Africa -- Northern Cape
- Description: Banded iron-formations (BIFs) are chemically precipitated sedimentary rocks in which Fe-rich bands or laminae alternate with Fe-poor ones. They formed within a specific time-span of the geological record. Their occurrence is restricted between 2.3 and 1.9 Ga, and characterises virtually all the major Precambrian-aged sedimentary basins of the world. The Precambrian Transvaal Basin in Griqualand West, South Africa, is noted for its well-developed BIF units. The Kuruman and Griquatown BIFs comprising the Asbesheuwels Subgroup (up to 1000m thick) are the best known and thickest of these. As far as metallogenesis is concerned, the Kuruman BIF is of major importance, for it carries the world's largest crocidolite (blue asbestos) deposits. The uppermost, youngest member of iron-formation deposition in the Griqualand West Sequence is represented by the Voëlwater BIF. The direct association between the latter and the giant Mn-deposits of the Kalahari Field, renders the Voëlwater association unusual, if not unique, in the geological record. The Voëlwater BIF represents a typical example of the so-called "Superior-type", and in the area of study it has undergone late-diagennetic to low-grade metamorphic processes. This is evident from the mineralogical composition and textural signature of the various BIF lithologies. Specifically, the minerals that make up the Voëlwater BIF are mainly chert(quartz), Fe-oxides (magnetite and hematite), Fe-silicates (greenalite, stilpnomelane, minnesotaite, riebeckite, Fe-mica), Fe-carbonates (members of the dolomite-ankerite series and siderite), calcite and pyrite. Soft-sediment deformation structures and shear-stress indicators are abundant in carbonate-rich and granular, silicate-rich BIF lithologies respectively. The bulk chemical composition of the study rocks is relatively simple and is characterised by the abundance of essentially three elements, namely Si, Fe, and Ca, which make up more than 90% of the total chemical composition of the Voëlwater BIFs. The detrital component of the study rocks is negligible. Mn-enrichments characterise all the transitional lithologies towards the interbedded Mn-orebodies, as well as the well-developed, hematitic BIF-unit between the Ongeluk lavas and the lower Mn-horizon. In terms of trace element composition, no significant enrichments or depletions, were encountered, except for some unusually high values of Sr and Ba and Co in carbonate-rich and Mn-rich lithologies respectively. Geochemical comparisons on the basis of major, trace and light rare-earth element composition verified the similarity between the Voëlwater BIF and other major Superior-type BIFs of the world (e.g. Kuruman, Griquatown, Sokoman, Biwabik, Gunflint, Mara-Mamba, Brockman, etc.). The processes that led to the formation of the Voëlwater BIFs may have been very similar to the ones described in various genetic models proposed in recent years. They would have involved a combination of: i. hydrothermal processes related to mid-ocean ridge (MOR) or hot-spot activity that acted as major iron suppliers; ii. storm-mixing in stratified oceans (bottom, anoxic, Fe⁺² reservoir-thermo- pycnocline zone-upper, mixed, SiO₂-saturated layer), largely dictated by seasonal changes and contemporaneous volcanism; iii. periodic, convection-driven upwelling mechanisms acting as major Fe-precipitators; and, iv. organic carbon productivity that was responsible for the anoxic diagenesis of the initial sediment. However, the origin of Fe and Mn for the genesis of the Voëlwater sediments was difficult to explain with typical convection-cell models in active mid-ocean ridges, in contrast to previous hypotheses. Instead, large-scale endogenous processes in the form of magma convection, underplating, differentiation and associated degassing, may have played a critical role in the supply of metals for the formation of large amounts of BIFs in the Precambrian. The present study of the Voëlwater BIF also bears strong implications regarding the metallogenesis of Mn in the Precambrian. The common association of Mn with carbonate-bearing sediments, the transitional character of the Voëlwater BIF towards carbonate lithologies (Mooidraai dolomites) and the critical timing of the deposition of the former in terms of the Precambrian atmospheric-lithospheric- hydrospheric evolution, may be important indicators for the exploration of large Mn-deposits in Precambrian sedimentary basins of the world.
- Full Text:
- Date Issued: 1995
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