Birima Remix
- Ndeye Mbaye, Djiema Djinema, Wyclif Jean, Marie Antonette, Youssou N'Dour (written by), Wyclef Jean (vocals), Wyclef Jean
- Authors: Ndeye Mbaye, Djiema Djinema, Wyclif Jean, Marie Antonette, Youssou N'Dour (written by) , Wyclef Jean (vocals) , Wyclef Jean
- Date: 2000
- Subjects: Rhythm and blues music , Popular music--Africa, West , Africa Senegal Dakar f-sg
- Language: English , Wolof
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/130543 , vital:36435 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC44-05
- Description: Fusion of rap music with Senegalese desert music and voices
- Full Text: false
- Date Issued: 2000
- Authors: Ndeye Mbaye, Djiema Djinema, Wyclif Jean, Marie Antonette, Youssou N'Dour (written by) , Wyclef Jean (vocals) , Wyclef Jean
- Date: 2000
- Subjects: Rhythm and blues music , Popular music--Africa, West , Africa Senegal Dakar f-sg
- Language: English , Wolof
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/130543 , vital:36435 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC44-05
- Description: Fusion of rap music with Senegalese desert music and voices
- Full Text: false
- Date Issued: 2000
Boul ma mine
- Didier Sourou Awadi aka DJ Awadi (performer, author), Amadou Barry aka Doug E. Tee, Duggy Tee (performer, author), Palm Tree Enter/Africa with P.B.S. Production
- Authors: Didier Sourou Awadi aka DJ Awadi (performer, author) , Amadou Barry aka Doug E. Tee, Duggy Tee (performer, author) , Palm Tree Enter/Africa with P.B.S. Production
- Date: 2000
- Subjects: Rap (Music) , Popular music--Africa, West , Africa Senegal Dakar f-sg
- Language: Wolof , English , French
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/131464 , vital:36583 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC53-02
- Description: Hip hop song sung in English, French and Wolof, accompanied by traditional Senegalese kora and tama musical instruments, as well as Western instruments
- Full Text: false
- Date Issued: 2000
- Authors: Didier Sourou Awadi aka DJ Awadi (performer, author) , Amadou Barry aka Doug E. Tee, Duggy Tee (performer, author) , Palm Tree Enter/Africa with P.B.S. Production
- Date: 2000
- Subjects: Rap (Music) , Popular music--Africa, West , Africa Senegal Dakar f-sg
- Language: Wolof , English , French
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/131464 , vital:36583 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC53-02
- Description: Hip hop song sung in English, French and Wolof, accompanied by traditional Senegalese kora and tama musical instruments, as well as Western instruments
- Full Text: false
- Date Issued: 2000
Bread and honour: white working class women and Afrikaner Nationalism in the 1930s
- Authors: Vincent, Louise
- Date: 2000
- Language: English
- Type: text , Article
- Identifier: vital:6205 , http://hdl.handle.net/10962/d1008575
- Description: Women have occupied a central place in the ideological formulations of nationalist movements. In particular, the figure of woman as mother recurs throughout the history of nationalist political mobilizations. In Afrikaner nationalism, this symbolic female identity takes the form of the volksmoeder (mother of the nation) icon, commonly assumed to describe a highly circumscribed set of women's social roles, created for women by men. The academic orthodoxy holds that middle-class Afrikaner women submitted to the volksmoeder ideology early on in the development of Afrikaner nationalism but that the working class Afrikaner women of the Garment Workers' Union (GWU) represented an enclave of resistance to dominant definitions of ethnic identity. They chose instead to ally themselves with militant, class-conscious trade unionism. This paper argues that Afrikaner women of different classes helped to shape the contours of the volksmoeder icon. Whilst middle class Afrikaner women questioned the idea that their social contribution should remain restricted to narrow familial and charitable concerns, prominent working class women laid claim to their own entitlement to the volksmoeder heritage. In doing so, the latter contributed to the popularization and reinterpretation of an ideology that was at this time seeking a wider audience. The paper argues that the incorporation of Afrikaner women into the socialist milieu of the GWU did not result in these women simply discarding the ethnic components of their identity. Rather their self-awareness as Afrikaner women with a recent rural past was grafted onto their new experience as urban factory workers. The way in which leading working class Afrikaner women articulated this potent combination of 'derived' and 'inherent' ideology cannot be excluded from the complex process whereby Afrikaner nationalism achieved success as a movement appealing to its imagined community across boundaries of class and gender.
- Full Text:
- Date Issued: 2000
- Authors: Vincent, Louise
- Date: 2000
- Language: English
- Type: text , Article
- Identifier: vital:6205 , http://hdl.handle.net/10962/d1008575
- Description: Women have occupied a central place in the ideological formulations of nationalist movements. In particular, the figure of woman as mother recurs throughout the history of nationalist political mobilizations. In Afrikaner nationalism, this symbolic female identity takes the form of the volksmoeder (mother of the nation) icon, commonly assumed to describe a highly circumscribed set of women's social roles, created for women by men. The academic orthodoxy holds that middle-class Afrikaner women submitted to the volksmoeder ideology early on in the development of Afrikaner nationalism but that the working class Afrikaner women of the Garment Workers' Union (GWU) represented an enclave of resistance to dominant definitions of ethnic identity. They chose instead to ally themselves with militant, class-conscious trade unionism. This paper argues that Afrikaner women of different classes helped to shape the contours of the volksmoeder icon. Whilst middle class Afrikaner women questioned the idea that their social contribution should remain restricted to narrow familial and charitable concerns, prominent working class women laid claim to their own entitlement to the volksmoeder heritage. In doing so, the latter contributed to the popularization and reinterpretation of an ideology that was at this time seeking a wider audience. The paper argues that the incorporation of Afrikaner women into the socialist milieu of the GWU did not result in these women simply discarding the ethnic components of their identity. Rather their self-awareness as Afrikaner women with a recent rural past was grafted onto their new experience as urban factory workers. The way in which leading working class Afrikaner women articulated this potent combination of 'derived' and 'inherent' ideology cannot be excluded from the complex process whereby Afrikaner nationalism achieved success as a movement appealing to its imagined community across boundaries of class and gender.
- Full Text:
- Date Issued: 2000
Cape Town talks about sex workers
- Sex Workers’ Education & Advocacy Taskforce (SWEAT)
- Authors: Sex Workers’ Education & Advocacy Taskforce (SWEAT)
- Date: 2000
- Subjects: SWEAT
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/168829 , vital:41651
- Description: On Monday 25 September,, as- part of the One City Festival, the Black Arts Collective hosted a debate about sex work. Natasha from SWEAT spoke about the why the government should decriminalize sex work. Khadija Magardie, a journalist from the Mail and Guardian newspaper, sent a speech talking about how sex work should be abolished by changing the law to make the clients criminals, so they can be arrested for buying sex from sex workers. Members of the public came to the debate, and talked about their feelings about sex work, and asked questions and gave comments. Generally most people were supportive of the fact that sex workers deserve human rights, even if they didn’t like the idea that people sell sex for a living. The city is starting to talk about sex work and sex workers, which is very exciting. It is a chance for SWEAT to talk about the realities of the industry, and to break down some of the stereotypes that many members of the public have about sex workers and sex work. One element that is missing from these discussions is the voices of sex workers themselves. SWEAT points out that it is very difficult for sex workers to talk publicly because of the stigmatization they suffer, and because sex work is still illegal. If you are interested in talking to the public about your experiences and opinions, please contact SWEAT and let us know, so that next time there is a chance to speak to the public we can invite you along.
- Full Text:
- Date Issued: 2000
- Authors: Sex Workers’ Education & Advocacy Taskforce (SWEAT)
- Date: 2000
- Subjects: SWEAT
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/168829 , vital:41651
- Description: On Monday 25 September,, as- part of the One City Festival, the Black Arts Collective hosted a debate about sex work. Natasha from SWEAT spoke about the why the government should decriminalize sex work. Khadija Magardie, a journalist from the Mail and Guardian newspaper, sent a speech talking about how sex work should be abolished by changing the law to make the clients criminals, so they can be arrested for buying sex from sex workers. Members of the public came to the debate, and talked about their feelings about sex work, and asked questions and gave comments. Generally most people were supportive of the fact that sex workers deserve human rights, even if they didn’t like the idea that people sell sex for a living. The city is starting to talk about sex work and sex workers, which is very exciting. It is a chance for SWEAT to talk about the realities of the industry, and to break down some of the stereotypes that many members of the public have about sex workers and sex work. One element that is missing from these discussions is the voices of sex workers themselves. SWEAT points out that it is very difficult for sex workers to talk publicly because of the stigmatization they suffer, and because sex work is still illegal. If you are interested in talking to the public about your experiences and opinions, please contact SWEAT and let us know, so that next time there is a chance to speak to the public we can invite you along.
- Full Text:
- Date Issued: 2000
Cardiac responses under diverse combinations of marching speed and backpack load
- Scott, Patricia A, Christie, Candice J
- Authors: Scott, Patricia A , Christie, Candice J
- Date: 2000
- Language: English
- Type: Article
- Identifier: vital:6755 , http://hdl.handle.net/10962/d1009457
- Description: Thirty seasoned foot-soldiers were exposed to a total of 16 combinations of marching speed and backpack load, each soldier experiencing 8 of the combinations between 3.5km.h-1 with a 20kg load and 6.5km.h-1 with a 65kg load. Detailed physiological analyses were conducted, of which the heart rate responses are reported here. Steady state was achieved with all combinations under 5.5km.h-1 speed and 35kg load. Excessively elevated heart rates were elicited by all loads over 20kg at 6.5km.h-1 marching speed; by loads over 35kg at 5.5km.h-1 marching speed and by the 65kg load even at 4.5km.h-1 marching speed.
- Full Text:
- Date Issued: 2000
- Authors: Scott, Patricia A , Christie, Candice J
- Date: 2000
- Language: English
- Type: Article
- Identifier: vital:6755 , http://hdl.handle.net/10962/d1009457
- Description: Thirty seasoned foot-soldiers were exposed to a total of 16 combinations of marching speed and backpack load, each soldier experiencing 8 of the combinations between 3.5km.h-1 with a 20kg load and 6.5km.h-1 with a 65kg load. Detailed physiological analyses were conducted, of which the heart rate responses are reported here. Steady state was achieved with all combinations under 5.5km.h-1 speed and 35kg load. Excessively elevated heart rates were elicited by all loads over 20kg at 6.5km.h-1 marching speed; by loads over 35kg at 5.5km.h-1 marching speed and by the 65kg load even at 4.5km.h-1 marching speed.
- Full Text:
- Date Issued: 2000
Characterization of amide bond hydrolysis in novel hydantoinase-producing bacteria
- Authors: Skepu, Zoleka G
- Date: 2000
- Subjects: Amides , Hydrolysis , Hydantoin , Imides
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3911 , http://hdl.handle.net/10962/d1003970 , Amides , Hydrolysis , Hydantoin , Imides
- Description: This thesis describes a series of investigations into the amide bond-hydrolyzing activity of bacterial strains RU-KM1, RU-KM3L, RU-KM3S, and RU-OR, which were previously isolated for their ability to hydrolyze hydantoins to amino acids. The main aim of the study was to develop biotransformations with potential application in the production of enantiomerically pure amino acids and related compounds. Several compounds may be used as substrates by biocatalysts for the production of amino acids, such as hydantoins, amino nitriles, and amides. These compounds are not only important for amino acid production, but they may be used for production of other industrially important compounds, such as 2- arylpropionic acids, which are non-steroidal anti-inflammatory drugs. Thus, the ability of the above-mentioned strains to hydrolyze these substrates was investigated, with the view to utilizing the maximum potential of these biocatalysts. The compounds used as substrates in the investigation are all essentially amides. Thus, the ability of the strains to hydrolyze imides, hydantoins, and amides, was investigated. In particular, imides have a structure which is very similar to that of hydantoins, and thus it was an objective of the study to determine whether these strains could hydrolyze imides. Imidehydrolyzing activity has only recently been discovered in microorganisms. Hydantoin conversion involves a two-step hydrolysis reaction which yields, initially, an Ncarbamylamino acid intermediate, and subsequently, an "-amino acid. The hydantoinhydrolyzing enzymes of a Pseudomonas putida strain, RU-KM3S, were characterized in a crude extract preparation and reaction conditions for its biocatalytic application were optimized. The optimum conditions for conversion of 5-methylhydantoin were found to be 3 hours at 40°C, with conversion yields greater than 50% achieved. The enzymes of RU-KM3S demonstrated considerable stability, retaining 80% of their activity after incubation at 40°C for 3 hours. The activities of the enzymes were increased by the addition of a detergent to the extraction medium, suggesting that the enzymes might be membrane-bound. The results of the determination of the metal-dependence of the hydantoinase and N-carbamylase of RUKM3S suggested that these enzymes required metal ions for activity, with metal ions such as Mg²⁺, Mn²⁺, Zn²⁺, and Co²⁺ resulting in activation of the enzymes. However, Cu²⁺ and Fe²⁺ caused inactivation of these enzymes. The stereoselectivity of the enzymes was investigated, and the results suggested that the hydantoinase was non-selective, whereas the N-carbamylase was L-selective. The hydantoin substrate selectivity of RU-KM3S was compared to that of three other hydantoinase-producing bacteria, RU-KM1, RU-KM3L, and RU-OR. The four strains were able to hydrolyze all of the seven substrates tested. However, there was a difference in activity levels between crude extract preparations and whole cells, with crude extracts generally showing higher activity than whole cells, except in the case of RU-KM1. Some difference was also observed in the order of preference of substrates between whole cells and crude extracts. The preferred substrate for RU-KM1 whole cells was isopropylhydantoin, whereas the crude extract preparation preferentially hydrolyzed p-hydroxyphenylhydantoin. RU-KM3L whole cells achieved a higher conversion yield with isobutylhydantoin, whereas the crude extract achieved a higher yield with 5-t-butylhydantoin. RU-KM3S whole cells and crude extract preferentially hydrolyzed 5-n-butylhydantoin, although the yield was greater with the crude extract. The highest conversion yields were observed with RU-KM3S crude extract, with conversion yields of 71.6% and 100% for n-butylhydantoin and phydroxyphenylhydantoin, respectively.The ability of RU-KM1, RU-KM3L, and RU-KM3S to hydrolyze nitriles, initially to amides and subsequently to carboxylic acids, was investigated. These strains were demonstrated to be unable to utilize acrylonitrile, propionitrile and benzonitrile as nitrogen sources, but were able to hydrolyze acrylonitrile, propionitrile and acetonitrile, in resting cell reactions. Nitrile hydrolysis was demonstrated to be inducible in all three strains, and the enzyme system responsible for nitrile hydrolysis was proposed to be a nitrile hydratase-amidase system. Amidase activity in the four bacterial strains was investigated. The ability of RU-KM1, RUKM3L, RU-KM3S, and RU-OR to utilize amides as a nitrogen source was investigated, and the results showed that propionamide was a good nitrogen source for all four of the strains. Amide-hydrolyzing activity, by resting cells, was shown to be inducible by propionamide in all four strains. RU-KM3S demonstrated superior amide-hydrolyzing ability in that it hydrolyzed propionamide, acetamide, and acrylamide to a greater extent than the other strains. Resting cells of RU-KM1 and RU-OR were demonstrated to have the ability to hydrolyze the imide substrate, succinimide, and this imidase activity was found to be inducible. These strains were also able to utilize this imide as the sole source of nitrogen for growth, which is a novel finding, as to date, bacteria have only be reported to utilize imides as a carbon source. The identity of the enzyme system responsible for succinimide hydrolysis is not yet clear. In conclusion, the hydantoin-hydrolyzing enzymes of RU-KM3S have been shown to be possibly membrane associated, which is a novel finding that has also been proposed in three other hydantoinase-producing strains in our laboratory. This study has shown that the Ncarbamylase of RU-KM3S is L-stereoselective, which, to our knowledge, is the first report of an L-stereospecific N-carbamylase in a Pseudomonas putida. Publication of these findings is already in progress. This is the first report on the study of imide hydrolysis in either an Agrobacterium tumefaciens or a Pseudomonas sp., and publications reporting these results are in preparation.
- Full Text:
- Date Issued: 2000
- Authors: Skepu, Zoleka G
- Date: 2000
- Subjects: Amides , Hydrolysis , Hydantoin , Imides
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3911 , http://hdl.handle.net/10962/d1003970 , Amides , Hydrolysis , Hydantoin , Imides
- Description: This thesis describes a series of investigations into the amide bond-hydrolyzing activity of bacterial strains RU-KM1, RU-KM3L, RU-KM3S, and RU-OR, which were previously isolated for their ability to hydrolyze hydantoins to amino acids. The main aim of the study was to develop biotransformations with potential application in the production of enantiomerically pure amino acids and related compounds. Several compounds may be used as substrates by biocatalysts for the production of amino acids, such as hydantoins, amino nitriles, and amides. These compounds are not only important for amino acid production, but they may be used for production of other industrially important compounds, such as 2- arylpropionic acids, which are non-steroidal anti-inflammatory drugs. Thus, the ability of the above-mentioned strains to hydrolyze these substrates was investigated, with the view to utilizing the maximum potential of these biocatalysts. The compounds used as substrates in the investigation are all essentially amides. Thus, the ability of the strains to hydrolyze imides, hydantoins, and amides, was investigated. In particular, imides have a structure which is very similar to that of hydantoins, and thus it was an objective of the study to determine whether these strains could hydrolyze imides. Imidehydrolyzing activity has only recently been discovered in microorganisms. Hydantoin conversion involves a two-step hydrolysis reaction which yields, initially, an Ncarbamylamino acid intermediate, and subsequently, an "-amino acid. The hydantoinhydrolyzing enzymes of a Pseudomonas putida strain, RU-KM3S, were characterized in a crude extract preparation and reaction conditions for its biocatalytic application were optimized. The optimum conditions for conversion of 5-methylhydantoin were found to be 3 hours at 40°C, with conversion yields greater than 50% achieved. The enzymes of RU-KM3S demonstrated considerable stability, retaining 80% of their activity after incubation at 40°C for 3 hours. The activities of the enzymes were increased by the addition of a detergent to the extraction medium, suggesting that the enzymes might be membrane-bound. The results of the determination of the metal-dependence of the hydantoinase and N-carbamylase of RUKM3S suggested that these enzymes required metal ions for activity, with metal ions such as Mg²⁺, Mn²⁺, Zn²⁺, and Co²⁺ resulting in activation of the enzymes. However, Cu²⁺ and Fe²⁺ caused inactivation of these enzymes. The stereoselectivity of the enzymes was investigated, and the results suggested that the hydantoinase was non-selective, whereas the N-carbamylase was L-selective. The hydantoin substrate selectivity of RU-KM3S was compared to that of three other hydantoinase-producing bacteria, RU-KM1, RU-KM3L, and RU-OR. The four strains were able to hydrolyze all of the seven substrates tested. However, there was a difference in activity levels between crude extract preparations and whole cells, with crude extracts generally showing higher activity than whole cells, except in the case of RU-KM1. Some difference was also observed in the order of preference of substrates between whole cells and crude extracts. The preferred substrate for RU-KM1 whole cells was isopropylhydantoin, whereas the crude extract preparation preferentially hydrolyzed p-hydroxyphenylhydantoin. RU-KM3L whole cells achieved a higher conversion yield with isobutylhydantoin, whereas the crude extract achieved a higher yield with 5-t-butylhydantoin. RU-KM3S whole cells and crude extract preferentially hydrolyzed 5-n-butylhydantoin, although the yield was greater with the crude extract. The highest conversion yields were observed with RU-KM3S crude extract, with conversion yields of 71.6% and 100% for n-butylhydantoin and phydroxyphenylhydantoin, respectively.The ability of RU-KM1, RU-KM3L, and RU-KM3S to hydrolyze nitriles, initially to amides and subsequently to carboxylic acids, was investigated. These strains were demonstrated to be unable to utilize acrylonitrile, propionitrile and benzonitrile as nitrogen sources, but were able to hydrolyze acrylonitrile, propionitrile and acetonitrile, in resting cell reactions. Nitrile hydrolysis was demonstrated to be inducible in all three strains, and the enzyme system responsible for nitrile hydrolysis was proposed to be a nitrile hydratase-amidase system. Amidase activity in the four bacterial strains was investigated. The ability of RU-KM1, RUKM3L, RU-KM3S, and RU-OR to utilize amides as a nitrogen source was investigated, and the results showed that propionamide was a good nitrogen source for all four of the strains. Amide-hydrolyzing activity, by resting cells, was shown to be inducible by propionamide in all four strains. RU-KM3S demonstrated superior amide-hydrolyzing ability in that it hydrolyzed propionamide, acetamide, and acrylamide to a greater extent than the other strains. Resting cells of RU-KM1 and RU-OR were demonstrated to have the ability to hydrolyze the imide substrate, succinimide, and this imidase activity was found to be inducible. These strains were also able to utilize this imide as the sole source of nitrogen for growth, which is a novel finding, as to date, bacteria have only be reported to utilize imides as a carbon source. The identity of the enzyme system responsible for succinimide hydrolysis is not yet clear. In conclusion, the hydantoin-hydrolyzing enzymes of RU-KM3S have been shown to be possibly membrane associated, which is a novel finding that has also been proposed in three other hydantoinase-producing strains in our laboratory. This study has shown that the Ncarbamylase of RU-KM3S is L-stereoselective, which, to our knowledge, is the first report of an L-stereospecific N-carbamylase in a Pseudomonas putida. Publication of these findings is already in progress. This is the first report on the study of imide hydrolysis in either an Agrobacterium tumefaciens or a Pseudomonas sp., and publications reporting these results are in preparation.
- Full Text:
- Date Issued: 2000
Colonial photography in nineteenth century Grahamstown: an analysis of the Dr W.G. Atherstone Bequest
- Authors: Waters, Hywell George
- Date: 2000
- Subjects: Atherstone, W. G. (William Guybon), 1814-1898 Art and photography Photography -- Technique
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: vital:2426 , http://hdl.handle.net/10962/d1002222
- Description: The research for this degree comprises of a theoretical dissertationand a practicalcomponent of exhibited photographs. The theoretical research investigates the original photographic prints and glass-plate negatives taken betweenthe 1840's and 1890's, by the late Dr. W.G. Atherstone - an enthusiastic, Grahamstown amateur photographer. Dr W. G Atherstone's prints and negatives were examined by the author to deduce and establish his photographic abilities, his numerous techniques, diverse subject matter and the pictorialconstructionof his images. Selected works will be examined in order to interpret and illustrate his diverse interests and approaches towards photography. The selection of these photographs was determined by their pertinence to subject matter, and to the pictorial and historical considerations of the candidate. These issues are finally examined in relation to the candidates's own approach to photography today.
- Full Text:
- Date Issued: 2000
- Authors: Waters, Hywell George
- Date: 2000
- Subjects: Atherstone, W. G. (William Guybon), 1814-1898 Art and photography Photography -- Technique
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: vital:2426 , http://hdl.handle.net/10962/d1002222
- Description: The research for this degree comprises of a theoretical dissertationand a practicalcomponent of exhibited photographs. The theoretical research investigates the original photographic prints and glass-plate negatives taken betweenthe 1840's and 1890's, by the late Dr. W.G. Atherstone - an enthusiastic, Grahamstown amateur photographer. Dr W. G Atherstone's prints and negatives were examined by the author to deduce and establish his photographic abilities, his numerous techniques, diverse subject matter and the pictorialconstructionof his images. Selected works will be examined in order to interpret and illustrate his diverse interests and approaches towards photography. The selection of these photographs was determined by their pertinence to subject matter, and to the pictorial and historical considerations of the candidate. These issues are finally examined in relation to the candidates's own approach to photography today.
- Full Text:
- Date Issued: 2000
Comparative Spectroscopic and Electrochemical Properties of Bis (octakis (dodecylthio) naphthalocyaninato) europium (III) and Bis (tetra-tert-butylnaphthalocyaninato) europium (III) Complexes
- Nyokong, Tebello, Furuya, Fumio, Kobayashi, Nagao, Du, Daming, Liu, Wei, Jiang, Jianzhuang
- Authors: Nyokong, Tebello , Furuya, Fumio , Kobayashi, Nagao , Du, Daming , Liu, Wei , Jiang, Jianzhuang
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293174 , vital:57062 , xlink:href="https://doi.org/10.1021/ic990483b"
- Description: Bis(substituted-2,3-naphthalocyaninato)europium(III) complexes: bis(octakis(dodecylthio)-2,3-naphthalocyaninato)europium(III) {Eu[2,3-Nc(SC12H25)8]2, 1} and bis(tetra-tert-butyl-2,3-naphthalocyaninato)europium(III) {Eu[2,3-Nc(t-Bu)4]2, 2} have been synthesized by cyclic tetramerization of naphthalonitriles with Eu(acac)3·H2O in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in refluxing n-octanol. These compounds were characterized by UV−visible, magnetic circular dichroism (MCD), near-IR, IR, EPR, and mass spectroscopies. The absorption and MCD spectra of 1 showed splitting of the Q band, with peaks at 700 and 784 nm, red shifted from the Q band of 2 at 763 nm. The absorption and MCD spectral band deconvolution calculations of complex 1 gave two A terms in the Q-band region. The A terms are assigned to 2A2 → 2E1 transitions. Cyclic voltammograms of 1 and 2 showed reversible oxidation couples at E1/2 = −0.28 V (for 2) and −0.25 V (for 1) vs ferrocenium/ferrocene (Fc+/Fc). The second oxidation exhibited a complicated behavior for both complexes. The reduction couples for 2 were observed at E1/2 = −0.61, −1.64, −1.97, and −2.42 V, and for 1 they were observed at E1/2 = −0.62, −1.60, −1.86, and −2.27 V vs Fc+/Fc. Spectral changes observed on chemical oxidation and reduction of the complexes are presented, and the behaviors of 1 and 2 are compared.
- Full Text:
- Date Issued: 2000
- Authors: Nyokong, Tebello , Furuya, Fumio , Kobayashi, Nagao , Du, Daming , Liu, Wei , Jiang, Jianzhuang
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293174 , vital:57062 , xlink:href="https://doi.org/10.1021/ic990483b"
- Description: Bis(substituted-2,3-naphthalocyaninato)europium(III) complexes: bis(octakis(dodecylthio)-2,3-naphthalocyaninato)europium(III) {Eu[2,3-Nc(SC12H25)8]2, 1} and bis(tetra-tert-butyl-2,3-naphthalocyaninato)europium(III) {Eu[2,3-Nc(t-Bu)4]2, 2} have been synthesized by cyclic tetramerization of naphthalonitriles with Eu(acac)3·H2O in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in refluxing n-octanol. These compounds were characterized by UV−visible, magnetic circular dichroism (MCD), near-IR, IR, EPR, and mass spectroscopies. The absorption and MCD spectra of 1 showed splitting of the Q band, with peaks at 700 and 784 nm, red shifted from the Q band of 2 at 763 nm. The absorption and MCD spectral band deconvolution calculations of complex 1 gave two A terms in the Q-band region. The A terms are assigned to 2A2 → 2E1 transitions. Cyclic voltammograms of 1 and 2 showed reversible oxidation couples at E1/2 = −0.28 V (for 2) and −0.25 V (for 1) vs ferrocenium/ferrocene (Fc+/Fc). The second oxidation exhibited a complicated behavior for both complexes. The reduction couples for 2 were observed at E1/2 = −0.61, −1.64, −1.97, and −2.42 V, and for 1 they were observed at E1/2 = −0.62, −1.60, −1.86, and −2.27 V vs Fc+/Fc. Spectral changes observed on chemical oxidation and reduction of the complexes are presented, and the behaviors of 1 and 2 are compared.
- Full Text:
- Date Issued: 2000
Comparative study on the biological performance of progenies of Western Sanga x Afrikaner and Bonsmara cattle in the sourish mixed bushveld of the North West Province
- Authors: Moraka, Joseph Ntlhoki
- Date: 2000
- Subjects: Beef cattle breeds , Bonsmara cattle , Afrikaner cattle
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10947 , http://hdl.handle.net/10948/21 , Beef cattle breeds , Bonsmara cattle , Afrikaner cattle
- Description: The study compares the biological performance of progenies of the Afrikaner x Western Sanga crossbred (small frame) and the Bonsmara (medium frame) cattle on the following traits: calving and growth rates as well as mortalities. The study was conducted in the Sourish Mixed Bushveld of the North West province. The objective was to identify a lowcare cattle breed, which can withstand unfavourable conditions under which most farmers in the North West Province operate. The results of this study indicated that, under good management, the Bonsmara cattle have higher growth rates compared to the Sanga cattle. There were statistical differences with regards to birth, pre-wean and wean masses, (P< 0.0001). Sanga cattle however were able to maintain higher calving rates under all varying conditions (Bonsmara 77% average and Sanga 84% average). The Sanga, due to its lower nutritional requirements, on average requires 15% less of the surface area required by the Bonsmara. Sanga cattle also returned better yields in terms of kilogram weaned calf per LSU and per hectare. With regard to herd mortalities, there was no significant difference (P = 0.03329).
- Full Text:
- Date Issued: 2000
- Authors: Moraka, Joseph Ntlhoki
- Date: 2000
- Subjects: Beef cattle breeds , Bonsmara cattle , Afrikaner cattle
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10947 , http://hdl.handle.net/10948/21 , Beef cattle breeds , Bonsmara cattle , Afrikaner cattle
- Description: The study compares the biological performance of progenies of the Afrikaner x Western Sanga crossbred (small frame) and the Bonsmara (medium frame) cattle on the following traits: calving and growth rates as well as mortalities. The study was conducted in the Sourish Mixed Bushveld of the North West province. The objective was to identify a lowcare cattle breed, which can withstand unfavourable conditions under which most farmers in the North West Province operate. The results of this study indicated that, under good management, the Bonsmara cattle have higher growth rates compared to the Sanga cattle. There were statistical differences with regards to birth, pre-wean and wean masses, (P< 0.0001). Sanga cattle however were able to maintain higher calving rates under all varying conditions (Bonsmara 77% average and Sanga 84% average). The Sanga, due to its lower nutritional requirements, on average requires 15% less of the surface area required by the Bonsmara. Sanga cattle also returned better yields in terms of kilogram weaned calf per LSU and per hectare. With regard to herd mortalities, there was no significant difference (P = 0.03329).
- Full Text:
- Date Issued: 2000
Comparison of plant diversity in protected and communal lands in the Bushbuckridge lowveld savanna, South Africa
- Authors: Shackleton, Charlie M
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181885 , vital:43777 , xlink:href="https://doi.org/10.1016/S0006-3207(00)00001-X"
- Description: Patterns of higher plant species richness and beta diversity were assessed using standard Modified-Whittaker plots in relation to land use, slope position and mean annual rainfall across a rainfall gradient in the savanna areas of the Bushbuckridge lowveld, South Africa. In particular, comparison of communal areas with adjacent protected areas was important in showing the impacts of potential changes in land use within an overarching catchment management plan. Although most of the protected areas considered preservation of biodiversity as their primary goal, they were characterised by significantly fewer plant species than the adjacent, highly utilised, communal lands, at both the plot and point scale. Slope position also had a significant effect on plant species richness, with eutrophic bottomlands having c. 30% more species than the dystrophic toplands. This adds weight to the need for greater public awareness for the judicious use and management of the sensitive bottomlands, which fringe the primary drainage lines that are vital for sustained supplies of good quality surface water in this semi-arid environment. The total number of species increased with increasing mean annual rainfall across the rainfall gradient. This suggests that, if the catchment management plan aims to identify additional areas for conservation, the higher rainfall areas should be the first to be assessed. Species turnover was greater along the rainfall gradient than the catenal gradient between toplands and bottomlands.
- Full Text:
- Date Issued: 2000
- Authors: Shackleton, Charlie M
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181885 , vital:43777 , xlink:href="https://doi.org/10.1016/S0006-3207(00)00001-X"
- Description: Patterns of higher plant species richness and beta diversity were assessed using standard Modified-Whittaker plots in relation to land use, slope position and mean annual rainfall across a rainfall gradient in the savanna areas of the Bushbuckridge lowveld, South Africa. In particular, comparison of communal areas with adjacent protected areas was important in showing the impacts of potential changes in land use within an overarching catchment management plan. Although most of the protected areas considered preservation of biodiversity as their primary goal, they were characterised by significantly fewer plant species than the adjacent, highly utilised, communal lands, at both the plot and point scale. Slope position also had a significant effect on plant species richness, with eutrophic bottomlands having c. 30% more species than the dystrophic toplands. This adds weight to the need for greater public awareness for the judicious use and management of the sensitive bottomlands, which fringe the primary drainage lines that are vital for sustained supplies of good quality surface water in this semi-arid environment. The total number of species increased with increasing mean annual rainfall across the rainfall gradient. This suggests that, if the catchment management plan aims to identify additional areas for conservation, the higher rainfall areas should be the first to be assessed. Species turnover was greater along the rainfall gradient than the catenal gradient between toplands and bottomlands.
- Full Text:
- Date Issued: 2000
Computers in science teaching: a reality or dream; The role of computers in effective science education: a case of using a computer to teach colour mixing; Career oriented science education for the next millennium
- Authors: Nadarajah, Kumaravel
- Date: 2000
- Subjects: Science -- Study and teaching Computer-assisted instruction Education -- Data processing
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1460 , http://hdl.handle.net/10962/d1003341
- Description: Science education in South Africa is not improving much. Many science educators do not have appropriate science qualifications. Majority of the learners have limited facilities to learn science. In this dilemma the move to OBE may result in further substantial deterioration of science education. A possible way out is to use computers in science education to facilitate the learning process. This study was designed to investigate how computers contribute to learners’ skills development in a physics course. A series of interactive computer simulations of colour mixing and a number of closely related traditional practical activities are aimed to promote learners’ understanding of colour. It was concluded that while computer environments have greater potentialas learning tools, they also limit interactions in significant ways.
- Full Text:
- Date Issued: 2000
- Authors: Nadarajah, Kumaravel
- Date: 2000
- Subjects: Science -- Study and teaching Computer-assisted instruction Education -- Data processing
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1460 , http://hdl.handle.net/10962/d1003341
- Description: Science education in South Africa is not improving much. Many science educators do not have appropriate science qualifications. Majority of the learners have limited facilities to learn science. In this dilemma the move to OBE may result in further substantial deterioration of science education. A possible way out is to use computers in science education to facilitate the learning process. This study was designed to investigate how computers contribute to learners’ skills development in a physics course. A series of interactive computer simulations of colour mixing and a number of closely related traditional practical activities are aimed to promote learners’ understanding of colour. It was concluded that while computer environments have greater potentialas learning tools, they also limit interactions in significant ways.
- Full Text:
- Date Issued: 2000
Constitutional frameworks and democratization in Africa since independence
- Authors: Neirynck, Karim
- Date: 2000
- Subjects: Democracy -- Africa , Constitutions -- Africa , Africa -- Politics and government -- 1960-
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2816 , http://hdl.handle.net/10962/d1003026 , Democracy -- Africa , Constitutions -- Africa , Africa -- Politics and government -- 1960-
- Description: The subject of this thesis is international studies, specifically a study of constitutional frameworks in Africa in the second half of the 20th century, focussing on a statistical correlation between constitutional frameworks, party systems, electoral systems and the Index of Democracy. The struggle to consolidate new democracies - especially those in Eastern Europe, Latin America and Asia - has given rise to a wide-ranging debate about the hard choices concerning democratic political institutions and political markets. According to Stepan and Skach " this literature has produced provocative hypotheses about the effects of institutions on democracy" (Stepan and Skach, 1993 : 1). It forms part of the' new institutionalism I literature in comparative politics that'holds as a premise that political democracy depends not only on economic and social conditions but also on the design of political institutions (Koelble, 1995 : 231-243). " One fundamental political-institutional question that has only received serious scholarly attention concerns the impact of different constitutional frameworks on democratic consolidation. Although the topic has been increasingly debated and discussed, little systematic cross-regional evidence [especially for our field of research: Africa] has been brought to bear on it " (Stepan and Skach, 1993 : 1-2). So far, only the book"on regime transitions in Africa written by Bratton and Van De Walle seeks to fill this empirical gap (Bratton and Van De Walle, 1997, preface xiii). In this thesis, we paid particular attention to the dichotomy between (pure) parliamentarism and (pure) presidentialism. Each type has fundamental characteristics, and for the purposes of classification these characteristics are necessary and sufficient. It was not our purpose to weigh the benefits and drawbacks of parliamentarism and presidentialism. Our intention was to report and analyse different sources of data, and we based our case exclusively on statistic correlatiohs between regime type and the record of democratic success and failure. We collected a data set about constitutional frameworks (matrix1), democracy indices (matrix2), party systems (matrix3) and election systems (matrix4). The basis for matrix 1 was the constitutions of the African countries (over time) and relevant literature. The basis for matrix 2 was the annual Freedom House ratings made by Raymond D. Gastil and others. The basis for matrix 3 and 4 was relevant literature. Once these matrices had been composed, we compared them and calculated statistic correlations. This long-dyration model allowed us to estimate whether African constitutional frameworks, party systems and electoral systems exhibit positive or negative correlation with the index of democracy.
- Full Text:
- Date Issued: 2000
- Authors: Neirynck, Karim
- Date: 2000
- Subjects: Democracy -- Africa , Constitutions -- Africa , Africa -- Politics and government -- 1960-
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2816 , http://hdl.handle.net/10962/d1003026 , Democracy -- Africa , Constitutions -- Africa , Africa -- Politics and government -- 1960-
- Description: The subject of this thesis is international studies, specifically a study of constitutional frameworks in Africa in the second half of the 20th century, focussing on a statistical correlation between constitutional frameworks, party systems, electoral systems and the Index of Democracy. The struggle to consolidate new democracies - especially those in Eastern Europe, Latin America and Asia - has given rise to a wide-ranging debate about the hard choices concerning democratic political institutions and political markets. According to Stepan and Skach " this literature has produced provocative hypotheses about the effects of institutions on democracy" (Stepan and Skach, 1993 : 1). It forms part of the' new institutionalism I literature in comparative politics that'holds as a premise that political democracy depends not only on economic and social conditions but also on the design of political institutions (Koelble, 1995 : 231-243). " One fundamental political-institutional question that has only received serious scholarly attention concerns the impact of different constitutional frameworks on democratic consolidation. Although the topic has been increasingly debated and discussed, little systematic cross-regional evidence [especially for our field of research: Africa] has been brought to bear on it " (Stepan and Skach, 1993 : 1-2). So far, only the book"on regime transitions in Africa written by Bratton and Van De Walle seeks to fill this empirical gap (Bratton and Van De Walle, 1997, preface xiii). In this thesis, we paid particular attention to the dichotomy between (pure) parliamentarism and (pure) presidentialism. Each type has fundamental characteristics, and for the purposes of classification these characteristics are necessary and sufficient. It was not our purpose to weigh the benefits and drawbacks of parliamentarism and presidentialism. Our intention was to report and analyse different sources of data, and we based our case exclusively on statistic correlatiohs between regime type and the record of democratic success and failure. We collected a data set about constitutional frameworks (matrix1), democracy indices (matrix2), party systems (matrix3) and election systems (matrix4). The basis for matrix 1 was the constitutions of the African countries (over time) and relevant literature. The basis for matrix 2 was the annual Freedom House ratings made by Raymond D. Gastil and others. The basis for matrix 3 and 4 was relevant literature. Once these matrices had been composed, we compared them and calculated statistic correlations. This long-dyration model allowed us to estimate whether African constitutional frameworks, party systems and electoral systems exhibit positive or negative correlation with the index of democracy.
- Full Text:
- Date Issued: 2000
Criteria social workers employ in making child custody recommendations
- Authors: Froneman, Anna Petronella
- Date: 2000
- Subjects: Custody of children -- South Africa Social work with children -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:696 , http://hdl.handle.net/10962/d1006414
- Description: During this study, an attempt was made to investigate the process employed by social workers in conducting child custody evaluations and making decisions related to the process, as well as to provide insight into which criteria are currently being used. The goal was to explore the perceived usefulness of these criteria from the perspective of social work, and to assess the adequacy of the requirements of the custody report in reflecting the above process and decision-making. In order to meet this goal, literature and empirical studies were conducted. The literature study focuses on the history of child custody matters, custody decision-making and legislation, types of custody arrangements, criteria social workers employ in making child custody recommendations, evaluator bias and custody evaluation reports. During the empirical research phase, a non-probability purposive sampling procedure was adopted. Five family counsellors from the office of the family advocate serving the Eastern Cape were selected. After an interview schedule was compiled to cover certain topics and their sequence, semi-structured interviews were conducted with the family counsellors. In order to compare the criteria stated in the interviews with the criteria applied in the custody reports, three cases from each family counsellor were selected and the final custody report and recommendation were studied. This study has revealed the following: some of the family counsellors experience proqlems with the process of custody evaluations; certain aspects regarding the process are not in line with some ofthe literature; some of the criteria used by the family counsellors are not evident in the custody reports and are not discussed in detail; a lack of training exists for the family counsellors; and the family counsellors experience some form of bias. Finally, based on the research findings, recommendations were made regarding the process of custody evaluation, the criteria social workers employ when conducting child custody evaluations, training and bias of family counsellors, the role of the family advocate and possible future research.
- Full Text:
- Date Issued: 2000
- Authors: Froneman, Anna Petronella
- Date: 2000
- Subjects: Custody of children -- South Africa Social work with children -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:696 , http://hdl.handle.net/10962/d1006414
- Description: During this study, an attempt was made to investigate the process employed by social workers in conducting child custody evaluations and making decisions related to the process, as well as to provide insight into which criteria are currently being used. The goal was to explore the perceived usefulness of these criteria from the perspective of social work, and to assess the adequacy of the requirements of the custody report in reflecting the above process and decision-making. In order to meet this goal, literature and empirical studies were conducted. The literature study focuses on the history of child custody matters, custody decision-making and legislation, types of custody arrangements, criteria social workers employ in making child custody recommendations, evaluator bias and custody evaluation reports. During the empirical research phase, a non-probability purposive sampling procedure was adopted. Five family counsellors from the office of the family advocate serving the Eastern Cape were selected. After an interview schedule was compiled to cover certain topics and their sequence, semi-structured interviews were conducted with the family counsellors. In order to compare the criteria stated in the interviews with the criteria applied in the custody reports, three cases from each family counsellor were selected and the final custody report and recommendation were studied. This study has revealed the following: some of the family counsellors experience proqlems with the process of custody evaluations; certain aspects regarding the process are not in line with some ofthe literature; some of the criteria used by the family counsellors are not evident in the custody reports and are not discussed in detail; a lack of training exists for the family counsellors; and the family counsellors experience some form of bias. Finally, based on the research findings, recommendations were made regarding the process of custody evaluation, the criteria social workers employ when conducting child custody evaluations, training and bias of family counsellors, the role of the family advocate and possible future research.
- Full Text:
- Date Issued: 2000
Cuba's revolutionist and anti-imperialist foreign policy in Southern Africa: the case of Angola and Namibia
- Authors: Othieno, Timothy
- Date: 2000
- Subjects: Cuba -- Foreign Relations -- Africa, Southern , Cuba -- Dependency on foreign countries -- History , Cuba -- Foreign relations -- Angola , Cuba -- Foreign relations -- Namibia , Cuba -- Politics and government
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2819 , http://hdl.handle.net/10962/d1003029 , Cuba -- Foreign Relations -- Africa, Southern , Cuba -- Dependency on foreign countries -- History , Cuba -- Foreign relations -- Angola , Cuba -- Foreign relations -- Namibia , Cuba -- Politics and government
- Description: This study examines Cuba’s role in the two southern African countries of Angola and Namibia during the Cold War period. It argues that Cuba’s ideological motivations have been embodied in the mutually reinforcing concepts of proletarian internationalism and anti-imperialism. These conceptual perspectives constitute some of the central variables that influence Cuba’s foreign policy behaviour in international relations. It is within this context that one can understand Cuba’s involvement in Southern Africa. This study also attempts to explain that Cuban foreign policy towards Africa was based on two complementary and contextual objectives namely, promoting nationalism at home and nurturing revolutionary Marxist-Leninist governments, as well as supporting anti-colonial and anti-imperialist movements abroad. For the purpose of achieving these foreign policy objectives, Cuba not only engaged in state-to-state relations with Angola and Namibia; but had cordial relations with the rest of the continent and in particular Southern Africa, which also became a direct military testing ground for Cuba’s commitment to an anti-colonial and anti-imperialist revolutionary stance. Furthermore, the thesis shows that Cuba’s relentless hatred of imperialism is rooted in its historical relationship with the United States because from the turn of the century till 1958, the Americans interfered in Cuba’s internal affairs by supporting corrupt administrations and exploited the country. These practices by the United States laid the foundation for Cuba’s anti-colonialism and antiimperialism abroad. Ultimately, this thesis shows that Cuban involvement in Angola and Namibia can be conceptualised within these contexts (anti-imperialism, anti-colonialism, proletarian internationalism and revolutionary Marxism-Leninism). The role of Cuban nationalism in the realisation of these objectives and ideals, as well as its role in perpetuating and consolidating her foreign policy is assessed in this study. This nationalism and ideals of internationalism constitutes the central idea in the Cuban revolution. Finally, this thesis asserts that Cuban motives for getting involved in the politics of Southern Africa were not motivated by economic or imperialistic reasons. Rather, the historical similarity and colonial experiences between Africa and Cuba were some of the central causal factors.
- Full Text:
- Date Issued: 2000
- Authors: Othieno, Timothy
- Date: 2000
- Subjects: Cuba -- Foreign Relations -- Africa, Southern , Cuba -- Dependency on foreign countries -- History , Cuba -- Foreign relations -- Angola , Cuba -- Foreign relations -- Namibia , Cuba -- Politics and government
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2819 , http://hdl.handle.net/10962/d1003029 , Cuba -- Foreign Relations -- Africa, Southern , Cuba -- Dependency on foreign countries -- History , Cuba -- Foreign relations -- Angola , Cuba -- Foreign relations -- Namibia , Cuba -- Politics and government
- Description: This study examines Cuba’s role in the two southern African countries of Angola and Namibia during the Cold War period. It argues that Cuba’s ideological motivations have been embodied in the mutually reinforcing concepts of proletarian internationalism and anti-imperialism. These conceptual perspectives constitute some of the central variables that influence Cuba’s foreign policy behaviour in international relations. It is within this context that one can understand Cuba’s involvement in Southern Africa. This study also attempts to explain that Cuban foreign policy towards Africa was based on two complementary and contextual objectives namely, promoting nationalism at home and nurturing revolutionary Marxist-Leninist governments, as well as supporting anti-colonial and anti-imperialist movements abroad. For the purpose of achieving these foreign policy objectives, Cuba not only engaged in state-to-state relations with Angola and Namibia; but had cordial relations with the rest of the continent and in particular Southern Africa, which also became a direct military testing ground for Cuba’s commitment to an anti-colonial and anti-imperialist revolutionary stance. Furthermore, the thesis shows that Cuba’s relentless hatred of imperialism is rooted in its historical relationship with the United States because from the turn of the century till 1958, the Americans interfered in Cuba’s internal affairs by supporting corrupt administrations and exploited the country. These practices by the United States laid the foundation for Cuba’s anti-colonialism and antiimperialism abroad. Ultimately, this thesis shows that Cuban involvement in Angola and Namibia can be conceptualised within these contexts (anti-imperialism, anti-colonialism, proletarian internationalism and revolutionary Marxism-Leninism). The role of Cuban nationalism in the realisation of these objectives and ideals, as well as its role in perpetuating and consolidating her foreign policy is assessed in this study. This nationalism and ideals of internationalism constitutes the central idea in the Cuban revolution. Finally, this thesis asserts that Cuban motives for getting involved in the politics of Southern Africa were not motivated by economic or imperialistic reasons. Rather, the historical similarity and colonial experiences between Africa and Cuba were some of the central causal factors.
- Full Text:
- Date Issued: 2000
Cumulative mild head injury in contact sport: a comparison of the cognitive profiles of rugby players and non-contact sport controls with normative data
- Authors: Bold, Lisa Clare
- Date: 2000
- Subjects: Head -- Wounds and injuries -- Psychology , Neuropsychological tests , Head -- Wounds and injuries , Sports injuries -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2935 , http://hdl.handle.net/10962/d1002444 , Head -- Wounds and injuries -- Psychology , Neuropsychological tests , Head -- Wounds and injuries , Sports injuries -- Psychological aspects
- Description: This study investigates the effects of cumulative mild head injury on the cognitive functioning of elite rugby players. A comprehensive battery of neuropsychological tests was administered to top national (Springbok) rugby players (n=26), national Under 21 rugby players (n= 19), and a non-contact sport control group of national hockey players (n=21). The test results of the Total Rugby group (Springbok Rugby and Under 21 Rugby players), the Under 21 Rugby group, the hockey controls, and the Total Rugby and Under 21 Rugby forward and backline players respectively, were each compared with established normative data. Results showed significant differences in the direction of a poorer performance relative to the norms for the Total Rugby and Under 21 Rugby groups, and for the Total Rugby Forwards and Under 21 Rugby Forwards, on tests sensitive to the effects of diffuse brain damage. On the other hand, the Hockey Control group and the Total Rugby Backs and Under 21 Rugby Backs tended to perform within the normal range or better than the norm on some tests. These results confirm the hypothesis that rugby players, and the forward players in particular, are at risk of adverse cognitive effects consequent on cumulative mild head injury. The theoretical implications are that the aggregate effects of multiple exposures to mild head injuries in the rugby players served to reduce their brain reserve capacities and acted as a threshold-lowering influence associated with symptom onset.
- Full Text:
- Date Issued: 2000
- Authors: Bold, Lisa Clare
- Date: 2000
- Subjects: Head -- Wounds and injuries -- Psychology , Neuropsychological tests , Head -- Wounds and injuries , Sports injuries -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2935 , http://hdl.handle.net/10962/d1002444 , Head -- Wounds and injuries -- Psychology , Neuropsychological tests , Head -- Wounds and injuries , Sports injuries -- Psychological aspects
- Description: This study investigates the effects of cumulative mild head injury on the cognitive functioning of elite rugby players. A comprehensive battery of neuropsychological tests was administered to top national (Springbok) rugby players (n=26), national Under 21 rugby players (n= 19), and a non-contact sport control group of national hockey players (n=21). The test results of the Total Rugby group (Springbok Rugby and Under 21 Rugby players), the Under 21 Rugby group, the hockey controls, and the Total Rugby and Under 21 Rugby forward and backline players respectively, were each compared with established normative data. Results showed significant differences in the direction of a poorer performance relative to the norms for the Total Rugby and Under 21 Rugby groups, and for the Total Rugby Forwards and Under 21 Rugby Forwards, on tests sensitive to the effects of diffuse brain damage. On the other hand, the Hockey Control group and the Total Rugby Backs and Under 21 Rugby Backs tended to perform within the normal range or better than the norm on some tests. These results confirm the hypothesis that rugby players, and the forward players in particular, are at risk of adverse cognitive effects consequent on cumulative mild head injury. The theoretical implications are that the aggregate effects of multiple exposures to mild head injuries in the rugby players served to reduce their brain reserve capacities and acted as a threshold-lowering influence associated with symptom onset.
- Full Text:
- Date Issued: 2000
Cyanide-induced free radical production and lipid peroxidation in rat brain homogenate is reduced by aspirin
- Daya, Santylal, Walker, Roderick B, Anoopkumar-Dukie, Shailendra
- Authors: Daya, Santylal , Walker, Roderick B , Anoopkumar-Dukie, Shailendra
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184346 , vital:44210 , xlink:href="https://doi.org/10.1007/BF02674529"
- Description: The neuroprotective properties of aspirin were investigated using cyanide-induced neurotoxicity as model. Cyanide, a known neurotoxic agent significantly increased lipid peroxidation and superoxide anion levels in rat brain homogenate in a concentration-dependent manner (0.25–1.0 mM). When homogenate, containing 1.0 mM KCN was cotreated with aspirin (1.0 mM) there was a significant decrease in lipid peroxidation. Aspirin (0.5 mM and 1.0 mM) also significantly reduced KCN-induced superoxide anion generation. The results of the present report therefore indicate a neuroprotective role for aspirin.
- Full Text:
- Date Issued: 2000
- Authors: Daya, Santylal , Walker, Roderick B , Anoopkumar-Dukie, Shailendra
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184346 , vital:44210 , xlink:href="https://doi.org/10.1007/BF02674529"
- Description: The neuroprotective properties of aspirin were investigated using cyanide-induced neurotoxicity as model. Cyanide, a known neurotoxic agent significantly increased lipid peroxidation and superoxide anion levels in rat brain homogenate in a concentration-dependent manner (0.25–1.0 mM). When homogenate, containing 1.0 mM KCN was cotreated with aspirin (1.0 mM) there was a significant decrease in lipid peroxidation. Aspirin (0.5 mM and 1.0 mM) also significantly reduced KCN-induced superoxide anion generation. The results of the present report therefore indicate a neuroprotective role for aspirin.
- Full Text:
- Date Issued: 2000
Desert
- Authors: Harper, Sean Julian
- Date: 2000
- Subjects: Rawls, John, 1921-2002 , Rawls, John, 1921-2002 Theory of justice , Ethics
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2710 , http://hdl.handle.net/10962/d1002840 , Rawls, John, 1921-2002 , Rawls, John, 1921-2002 Theory of justice , Ethics
- Description: This thesis examines the idea of desert as expounded in the work of John Rawls, and some of the implications of this conception of desert for moral and political philosophy. In this work, I analyse a series of arguments against retaining this particular conception of desert.I argue that none of these arguments sufficiently diminishes the force of Rawls’ argument for desert, while many of them do state, and I argue that they are correct in doing so, that this conception of desert is dangerous for political or moral philosophy to maintain. I argue that the moral, political and legal implications of accepting this account of desert severely undermine various institutions of differential treatment, and indeed, moral assessment. I regard it as obvious that societies must, on occasion, treat members of those societies differently, for moral, as well as practical reasons. The Rawlsian account of desert, and the account of responsibility on which it rests, however, will endanger the legitimacy of such procedures. I argue further that the Rawlsian account of desert requires that differences in wealth, and inheritance of wealth, influence and privilege be diminished, if not abolished, if we are to talk of any form of desert meaningfully. I argue that this is a strength of Rawls’ account, and further that any account of desert that is true to the philosophical tradition of the concept will require similar steps to be taken. The primary aim of this thesis is to show that Rawls’ arguments against desert are serious ones, both in terms of strength and scope, and that they must be addressed. I intend to show that these arguments are founded on strong moral intuitions, and that it is plausible that these intuitions may need revision. Finally,I intend to show that desert is an important moral and political concept, and that the disciplines of moral and political philosophy will be impoverished by the absence this concept. This absence, I will argue, is a natural consequence of the acceptance of the Rawlsian arguments.
- Full Text:
- Date Issued: 2000
- Authors: Harper, Sean Julian
- Date: 2000
- Subjects: Rawls, John, 1921-2002 , Rawls, John, 1921-2002 Theory of justice , Ethics
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2710 , http://hdl.handle.net/10962/d1002840 , Rawls, John, 1921-2002 , Rawls, John, 1921-2002 Theory of justice , Ethics
- Description: This thesis examines the idea of desert as expounded in the work of John Rawls, and some of the implications of this conception of desert for moral and political philosophy. In this work, I analyse a series of arguments against retaining this particular conception of desert.I argue that none of these arguments sufficiently diminishes the force of Rawls’ argument for desert, while many of them do state, and I argue that they are correct in doing so, that this conception of desert is dangerous for political or moral philosophy to maintain. I argue that the moral, political and legal implications of accepting this account of desert severely undermine various institutions of differential treatment, and indeed, moral assessment. I regard it as obvious that societies must, on occasion, treat members of those societies differently, for moral, as well as practical reasons. The Rawlsian account of desert, and the account of responsibility on which it rests, however, will endanger the legitimacy of such procedures. I argue further that the Rawlsian account of desert requires that differences in wealth, and inheritance of wealth, influence and privilege be diminished, if not abolished, if we are to talk of any form of desert meaningfully. I argue that this is a strength of Rawls’ account, and further that any account of desert that is true to the philosophical tradition of the concept will require similar steps to be taken. The primary aim of this thesis is to show that Rawls’ arguments against desert are serious ones, both in terms of strength and scope, and that they must be addressed. I intend to show that these arguments are founded on strong moral intuitions, and that it is plausible that these intuitions may need revision. Finally,I intend to show that desert is an important moral and political concept, and that the disciplines of moral and political philosophy will be impoverished by the absence this concept. This absence, I will argue, is a natural consequence of the acceptance of the Rawlsian arguments.
- Full Text:
- Date Issued: 2000