A contribution to the theory of prime modules
- Authors: Ssevviiri, David
- Date: 2013
- Subjects: Modules (Algebra) , Radical theory , Rings (Algebra)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10510 , http://hdl.handle.net/10948/d1019923
- Description: This thesis is aimed at generalizing notions of rings to modules. In par-ticular, notions of completely prime ideals, s-prime ideals, 2-primal rings and nilpotency of elements of rings are respectively generalized to completely prime submodules and classical completely prime submodules, s-prime submodules, 2-primal modules and nilpotency of elements of modules. Properties and rad-icals that arise from each of these notions are studied.
- Full Text:
- Date Issued: 2013
- Authors: Ssevviiri, David
- Date: 2013
- Subjects: Modules (Algebra) , Radical theory , Rings (Algebra)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10510 , http://hdl.handle.net/10948/d1019923
- Description: This thesis is aimed at generalizing notions of rings to modules. In par-ticular, notions of completely prime ideals, s-prime ideals, 2-primal rings and nilpotency of elements of rings are respectively generalized to completely prime submodules and classical completely prime submodules, s-prime submodules, 2-primal modules and nilpotency of elements of modules. Properties and rad-icals that arise from each of these notions are studied.
- Full Text:
- Date Issued: 2013
Analysis of temporal and spatial variations in water storage by means of gravimetric and hydrologic methods in the region around the South African gravimetric observation station
- Authors: Mahed, Gaathier
- Date: 2013
- Subjects: Ground water -- South Africa , Geology -- South Africa , Hydrogeology -- South Africa , Water-supply -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/6714 , vital:21137
- Description: This work examines the use of gravity data and its application to subsurface water reservoirs in the immediate vicinity of the South African Geodynamic Observatory, Sutherland (SAGOS), situated in a semi-arid region of the Karoo region of South Africa, and underlain by the Karoo sedimentary rocks intruded by dolerite dykes and sills. SAGOS houses the only supergravity metre (SG) in Africa, and this thesis sets out to test its use in monitoring groundwater dynamics using hydrological and gravity data. The main aim of this work is the application of the SG data, in conjunction with hydrological data, to better understand episodic recharge of subsurface reservoirs. The importance of water as a resource, globally and specifically the Karoo, is reviewed in conjunction with supply and demand of water. This is to contextualise the socio-economic, technical as well as policy issues related to water resource management. Applicable technologies for water resource management and efficient water use are highlighted and the application of gravity to hydrology is introduced, including satellite as well as ground based tools. In addition, arid zone hydrology as well as recharge and its mechanisms are analysed in order to better understand these processes when examined from gravity measurements. Issues related to understanding flow within the vadose zone as well as in secondary aquifers are examined, and gravity residuals and subsurface hydrology are highlighted. Thereafter, a conceptual groundwater flow modelof the study area is developed using multiple tools. First, the geology around SAGOS was mapped using SPOT 5 imagery and then ground truthed. Second, stable isotopes and water chemistry analysis was undertaken on water samples from selected boreholes. The results allude to preferential flow acting as the main mechanism for groundwater recharge. Follow-up pump-tests illustrate that fracture connectivity is greatest at close proximity to the dyke. Soil mapping, using aerial photography was also undertaken. Duplex soils, enriched with clay at depth, dominate the study area. Using in-situ infiltration tests, it is shown that the alluvium, which lines the river beds, has a higher hydraulic conductivity than the other soils, confirming that these streams act as preferential conduits for subsurface recharge. Precipitation events were correlated against gravity residuals at 4 wells, over different time periods. The results are examined using time series analyses. Gravity residuals from well SA BK07, over a period of 24 hours after the rainfall event, delineate instances of negative correlations, as well as strong positive correlations (of up to 0.9). On the whole however, correlations between gravity and groundwater at SA BK07 are variable and weak, and in conjunction with water level measurements and water chemistry, the data suggest that this well is located in a dynamic conduit (throughflow) and not in a permanent groundwater reservoir. By contrast, other wells show strong positive correlations between gravity residuals and water levels following episodic recharge events for a later time series. Correlations between the water levels and gravity residuals in wells SA BK04, SA BK05 and SA BK 01 are in excess of 0.7 for specific rainfall events. In summary, the results suggests that gravity is an excellent tool for measuring episodic groundwater recharge within the immediate vicinity of the SAGOS. This implies that gravity can aid in monitoring groundwater losses/gains in arid and semi-arid areas. Recommendations for future work are highlighted at the end; these include the possible use of hydrological modelling of reservoirs at various scales and then comparing these results to the SG as well as GOCE and GRACE satellites data, and then improving numerical modelling of the groundwater dynamics for sites like Sutherland and the surrounding arid Karoo region, where sparse water shortages, and potential pollution related to fracking for shale-gas, are likely to compete with established water needs for farming and human consumption. It is also suggested that the gravity modelling be examined to better understand site specific scenarios and thus aid in improving the processing of the gravity signal.
- Full Text:
- Date Issued: 2013
- Authors: Mahed, Gaathier
- Date: 2013
- Subjects: Ground water -- South Africa , Geology -- South Africa , Hydrogeology -- South Africa , Water-supply -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/6714 , vital:21137
- Description: This work examines the use of gravity data and its application to subsurface water reservoirs in the immediate vicinity of the South African Geodynamic Observatory, Sutherland (SAGOS), situated in a semi-arid region of the Karoo region of South Africa, and underlain by the Karoo sedimentary rocks intruded by dolerite dykes and sills. SAGOS houses the only supergravity metre (SG) in Africa, and this thesis sets out to test its use in monitoring groundwater dynamics using hydrological and gravity data. The main aim of this work is the application of the SG data, in conjunction with hydrological data, to better understand episodic recharge of subsurface reservoirs. The importance of water as a resource, globally and specifically the Karoo, is reviewed in conjunction with supply and demand of water. This is to contextualise the socio-economic, technical as well as policy issues related to water resource management. Applicable technologies for water resource management and efficient water use are highlighted and the application of gravity to hydrology is introduced, including satellite as well as ground based tools. In addition, arid zone hydrology as well as recharge and its mechanisms are analysed in order to better understand these processes when examined from gravity measurements. Issues related to understanding flow within the vadose zone as well as in secondary aquifers are examined, and gravity residuals and subsurface hydrology are highlighted. Thereafter, a conceptual groundwater flow modelof the study area is developed using multiple tools. First, the geology around SAGOS was mapped using SPOT 5 imagery and then ground truthed. Second, stable isotopes and water chemistry analysis was undertaken on water samples from selected boreholes. The results allude to preferential flow acting as the main mechanism for groundwater recharge. Follow-up pump-tests illustrate that fracture connectivity is greatest at close proximity to the dyke. Soil mapping, using aerial photography was also undertaken. Duplex soils, enriched with clay at depth, dominate the study area. Using in-situ infiltration tests, it is shown that the alluvium, which lines the river beds, has a higher hydraulic conductivity than the other soils, confirming that these streams act as preferential conduits for subsurface recharge. Precipitation events were correlated against gravity residuals at 4 wells, over different time periods. The results are examined using time series analyses. Gravity residuals from well SA BK07, over a period of 24 hours after the rainfall event, delineate instances of negative correlations, as well as strong positive correlations (of up to 0.9). On the whole however, correlations between gravity and groundwater at SA BK07 are variable and weak, and in conjunction with water level measurements and water chemistry, the data suggest that this well is located in a dynamic conduit (throughflow) and not in a permanent groundwater reservoir. By contrast, other wells show strong positive correlations between gravity residuals and water levels following episodic recharge events for a later time series. Correlations between the water levels and gravity residuals in wells SA BK04, SA BK05 and SA BK 01 are in excess of 0.7 for specific rainfall events. In summary, the results suggests that gravity is an excellent tool for measuring episodic groundwater recharge within the immediate vicinity of the SAGOS. This implies that gravity can aid in monitoring groundwater losses/gains in arid and semi-arid areas. Recommendations for future work are highlighted at the end; these include the possible use of hydrological modelling of reservoirs at various scales and then comparing these results to the SG as well as GOCE and GRACE satellites data, and then improving numerical modelling of the groundwater dynamics for sites like Sutherland and the surrounding arid Karoo region, where sparse water shortages, and potential pollution related to fracking for shale-gas, are likely to compete with established water needs for farming and human consumption. It is also suggested that the gravity modelling be examined to better understand site specific scenarios and thus aid in improving the processing of the gravity signal.
- Full Text:
- Date Issued: 2013
Assemblage dynamics of larval fishes associated with various shallow water nursery habitats in Algoa Bay, South Africa
- Authors: Pattrick, Paula
- Date: 2013
- Subjects: Spawning -- South Africa -- Algoa Bay , Fishes -- Larvae -- South Africa -- Algoa Bay
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: vital:10727 , http://hdl.handle.net/10948/d1021042
- Description: The success of the larval stage in fishes plays a critical role in structuring adult fish populations. It is well understood that juveniles of many marine fish species are closely associated with nearshore and coastal habitats that serve as nursery areas while adult assemblages are more widely distributed. The larval phase however, particularly pertaining to nursery habitat use, remains poorly understood in South Africa. A mixed-method, larval and juvenile fish study was conducted in the warm-temperate shallow coastal waters of Algoa Bay, South Africa. Two years (2010 – 2012) of seasonal sampling at 27 stations at various habitat types revealed distinct spatio-temporal patterns in larval fish composition and abundance. In total, 164 species from 50 families were collected in the nearshore (<30 m), over reef and sand, in the surf zone and large estuarine habitats in Algoa Bay. Engraulidae dominated the larval fish catch in the nearshore (38.4 percent) and over the selected reef and sand habitats (37.8 percent). Cynoglossidae (28.1 percent) and Sparidae (8.4 percent) were the second and third most abundant fish families in the nearshore. In subtidal reef and sand habitats, Gobiidae (23.4 percent) and Clupeidae (9.2 percent) were the second and third most abundant families respectively. Sparidae dominated (71.4 percent) surf zones followed by Soleidae (10.8 percent) and Mugilidae (5.3 percent), while in the mouth area of two permanently open estuaries in Algoa Bay, Gobiidae (35.9 percent) Sparidae (30.1 percent) and Mugilidae (12.4 percent) dominated. Several species from the Blenniidae, Gobiesocidae, Gobiidae, Scorpaenidae and Tripterygiidae fish families complete their pelagic larval phase in the reef habitats in Algoa Bay. These reef habitats therefore serve as important nursery areas for the larvae of benthic species. The sand and nearshore habitats serve as nursery areas for Clupeidae and Engraulidae. Highest densities of Carangidae, Sciaenidae and Sparidae larvae were observed at the subtidal reef habitats indicating that this area is important for accumulation of the early developmental stages of these fishes. The nearshore serves as an important accumulation habitat for species in the Haemulidae and Soleidae families whose juveniles are known to recruit into estuarine nursery areas. The nearshore therefore is a specific area of presettlement buildup of larvae prior to settlement of larvae or juveniles in estuarine nursery areas. Cynoglossidae larvae are also using the nearshore as an accumulation area prior to settlement and recruitment into adult populations occurring in shallow water habitats. In the surf zone, not only are estuary-dependent fish species utilizing this habitat as a nursery area, but marinespecies whose adults are either associated with rocky shores or surf zones are similarly using these areas as nursery habitats. In addition, estuary-dependent fish species which spawn in the marine environment are actively recruiting into estuarine nursery areas on both tides. Active recruitment against the outgoing ebb tide flow was a conclusive finding in this study. These larvae and juveniles are actively swimming against the ebb tide in the shallower, slower-flowing marginal areas where current flow is reduced. Strong environmental gradients on multiple temporal and spatial scales occur in Algoa Bay. Seasonal patterns were evident in larval densities, richness and diversity. Peaks in density, richness and diversity occurred during spring and summer (September to February) associated with increasing water temperatures and a high productivity providing a good food environment for larval fishes. Thereafter densities declined steadily as a result of natural mortality, settlement or adult spawning activity, until autumn when numbers dropped suddenly as the surviving larvae moved to settlement habitats. The relationship between larval fish and environmental variables provides information useful to determine distributions. Therefore the Bay is particularly suited for modelling larval fish distributions. Using generalized linear models, larval fish density in the nearshore of Algoa Bay responded to different ocean features to varying degrees. Larval fish density responded positively to both upwelling and when warm water plumes, originating from an Agulhas Current meander, entered Algoa Bay. On subtidal reefs, habitat complexity played an important role in determining larval fish composition and diversity. The less structurally complex, reefassociated sand habitats, yielded higher species richness and diversity than the high and low profile reef habitats. Therefore, it is likely that the importance of less structurally complex habitats has been overlooked relative to other habitats in terms of their function for larval fishes. In the surf zone, wave period and wave height, which can be related to exposure, were the most significant environmental factors influencing larval fish assemblages. Greatest species diversity was observed in the surf zone habitats heavily influenced by wave action in the windward sector of Algoa Bay. The identification of spawning areas and the mapping of distributions of early developmental stages of fishes are important in providing data pertaining to the protection of these habitats. This is particularly relevant as a new marine protected area MPA)is planned for the eastern sector of Algoa Bay. Results from retrogressive plots indicate that the spawning locations of several species of coastal and pelagic fishes are occurring outside of the Bay, with the bay therefore serving as an accumulation area. Furthermore, distribution modelling results demonstrate that the early developmental stages of fishes in the shallow coastal habitats of Algoa Bay exhibit high spatial variability in their distributions. Results presented in this thesis help fill the knowledge gaps critical to the understanding of larval fish nursery areas of several economically and ecologically important fish species in Algoa Bay.
- Full Text:
- Date Issued: 2013
- Authors: Pattrick, Paula
- Date: 2013
- Subjects: Spawning -- South Africa -- Algoa Bay , Fishes -- Larvae -- South Africa -- Algoa Bay
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: vital:10727 , http://hdl.handle.net/10948/d1021042
- Description: The success of the larval stage in fishes plays a critical role in structuring adult fish populations. It is well understood that juveniles of many marine fish species are closely associated with nearshore and coastal habitats that serve as nursery areas while adult assemblages are more widely distributed. The larval phase however, particularly pertaining to nursery habitat use, remains poorly understood in South Africa. A mixed-method, larval and juvenile fish study was conducted in the warm-temperate shallow coastal waters of Algoa Bay, South Africa. Two years (2010 – 2012) of seasonal sampling at 27 stations at various habitat types revealed distinct spatio-temporal patterns in larval fish composition and abundance. In total, 164 species from 50 families were collected in the nearshore (<30 m), over reef and sand, in the surf zone and large estuarine habitats in Algoa Bay. Engraulidae dominated the larval fish catch in the nearshore (38.4 percent) and over the selected reef and sand habitats (37.8 percent). Cynoglossidae (28.1 percent) and Sparidae (8.4 percent) were the second and third most abundant fish families in the nearshore. In subtidal reef and sand habitats, Gobiidae (23.4 percent) and Clupeidae (9.2 percent) were the second and third most abundant families respectively. Sparidae dominated (71.4 percent) surf zones followed by Soleidae (10.8 percent) and Mugilidae (5.3 percent), while in the mouth area of two permanently open estuaries in Algoa Bay, Gobiidae (35.9 percent) Sparidae (30.1 percent) and Mugilidae (12.4 percent) dominated. Several species from the Blenniidae, Gobiesocidae, Gobiidae, Scorpaenidae and Tripterygiidae fish families complete their pelagic larval phase in the reef habitats in Algoa Bay. These reef habitats therefore serve as important nursery areas for the larvae of benthic species. The sand and nearshore habitats serve as nursery areas for Clupeidae and Engraulidae. Highest densities of Carangidae, Sciaenidae and Sparidae larvae were observed at the subtidal reef habitats indicating that this area is important for accumulation of the early developmental stages of these fishes. The nearshore serves as an important accumulation habitat for species in the Haemulidae and Soleidae families whose juveniles are known to recruit into estuarine nursery areas. The nearshore therefore is a specific area of presettlement buildup of larvae prior to settlement of larvae or juveniles in estuarine nursery areas. Cynoglossidae larvae are also using the nearshore as an accumulation area prior to settlement and recruitment into adult populations occurring in shallow water habitats. In the surf zone, not only are estuary-dependent fish species utilizing this habitat as a nursery area, but marinespecies whose adults are either associated with rocky shores or surf zones are similarly using these areas as nursery habitats. In addition, estuary-dependent fish species which spawn in the marine environment are actively recruiting into estuarine nursery areas on both tides. Active recruitment against the outgoing ebb tide flow was a conclusive finding in this study. These larvae and juveniles are actively swimming against the ebb tide in the shallower, slower-flowing marginal areas where current flow is reduced. Strong environmental gradients on multiple temporal and spatial scales occur in Algoa Bay. Seasonal patterns were evident in larval densities, richness and diversity. Peaks in density, richness and diversity occurred during spring and summer (September to February) associated with increasing water temperatures and a high productivity providing a good food environment for larval fishes. Thereafter densities declined steadily as a result of natural mortality, settlement or adult spawning activity, until autumn when numbers dropped suddenly as the surviving larvae moved to settlement habitats. The relationship between larval fish and environmental variables provides information useful to determine distributions. Therefore the Bay is particularly suited for modelling larval fish distributions. Using generalized linear models, larval fish density in the nearshore of Algoa Bay responded to different ocean features to varying degrees. Larval fish density responded positively to both upwelling and when warm water plumes, originating from an Agulhas Current meander, entered Algoa Bay. On subtidal reefs, habitat complexity played an important role in determining larval fish composition and diversity. The less structurally complex, reefassociated sand habitats, yielded higher species richness and diversity than the high and low profile reef habitats. Therefore, it is likely that the importance of less structurally complex habitats has been overlooked relative to other habitats in terms of their function for larval fishes. In the surf zone, wave period and wave height, which can be related to exposure, were the most significant environmental factors influencing larval fish assemblages. Greatest species diversity was observed in the surf zone habitats heavily influenced by wave action in the windward sector of Algoa Bay. The identification of spawning areas and the mapping of distributions of early developmental stages of fishes are important in providing data pertaining to the protection of these habitats. This is particularly relevant as a new marine protected area MPA)is planned for the eastern sector of Algoa Bay. Results from retrogressive plots indicate that the spawning locations of several species of coastal and pelagic fishes are occurring outside of the Bay, with the bay therefore serving as an accumulation area. Furthermore, distribution modelling results demonstrate that the early developmental stages of fishes in the shallow coastal habitats of Algoa Bay exhibit high spatial variability in their distributions. Results presented in this thesis help fill the knowledge gaps critical to the understanding of larval fish nursery areas of several economically and ecologically important fish species in Algoa Bay.
- Full Text:
- Date Issued: 2013
Assessing soil carbon and carbon dioxide effluxes under different vegetation cover conditions in the Eastern Cape Province, South Africa
- Authors: Zengeni, Rebecca
- Date: 2013
- Subjects: Soils -- Carbon content -- Measurement , Carbon dioxide mitigation -- South Africa , Greenhouse gas mitigation -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10665 , http://hdl.handle.net/10948/d1018676
- Description: Albany thicket is prevalent in the Eastern Cape Province of South Africa. Its spread has diminished through overgrazing and heavy browsing by animals, land clearance and urban expansion. The result is highly degraded land characterized by invasion of alien species. There is a wealth of documented evidence on the high carbon sequestration ability of thicket biome, but not much has been done to assess its effect on carbon dioxide emissions from the soil. Given that the concentration of atmospheric greenhouse gases has been constantly rising since the industrial era, it is imperative to assess the influence of thicket biome as a source or sink of these gases. There is evidence of shifts in the climate in southern Africa as reflected by changes in rainfall patterns, increased temperatures, recurrent droughts and fires. As such, the historical rainfall variability in an Albany thicket region and its interaction with the temporal land use / cover changes was studied. This served to give some background information about the study area for more detailed study on C and carbon dioxide effluxes in thicket vegetation under different levels of degradation. This study thus aimed to determine the influence of thicket vegetation at various levels of degradation on soil carbon and carbon dioxide fluxes. The impact of plant photosynthetic pathway on soil C residence time and gas effluxes were analysed to elucidate on the land-use and cover patterns occurring in the area. All this was done to shed some light on the role of soil and thicket vegetation on carbon dioxide emissions and C storage in the spectrum of a shifting climate. The main area of research was Amakhala reserve in an Albany thicket in Eastern Cape Province; and it concentrated on three land cover types namely intact thicket, degraded thicket and grassland. The objectives mentioned above were achieved by assessing historical rainfall variability from 1970 to 2010 through trend and time series analysis at nine rainfall stations located at Amakhala reserve, Grahamstown, Bathurst, Port Alfred, Uitenhage and Port Elizabeth. The land use changes that have occurred in the Albany thicket region covering Amakhala reserve, Grahamstown, Bathurst and Port Alfred were also assessed for 1989, 1999 and 2009 through satellite image analysis with Idrisi Andes GIS software; then their interaction with rainfall variability were determined. To elucidate on the vegetation species composition and land use / cover changes that have occurred in the study area, plant biomass as well carbon (C) and nitrogen (N) isotope measurements were done. Plant biomass was assessed for the dominant species through use of pre-existing allometric equations that required data on plant basal diameter, canopy area, stem numbers and height. The plant carbon was then estimated through use of a conversion factor of 0.48 on above-ground biomass, while soil organic C was determined through the modified Walkely - Black method. Carbon and N isotope ratios were determined from the foliar material of three replicate samples of dominant plant species then analyzed through mass spectrometry. Soil carbon dioxide effluxes were then monitored in each of the intact thicket (IT), degraded thicket (DT) and grassland (G) over a 10 month period; by measuring the net carbon dioxide exchange rate (NCER) through the dynamic chamber method. An automated carbon dioxide exchange analyzer, coupled to a soil temperature probe and photosynthetic active radiation (PAR) sensor was used; with NCER measurements taken every 20-30 days. Soil temperature, moisture, penetration resistance and PAR readings were taken during each assay and later used to interpret the NCER. Results showed that long term variability in annual rainfall had a declining trend at Grahamstown (r = -0.59), Uitenhage and Bathurst stations (r = -0.32 at both stations), but was not significant at Amakhala, Port Alfred and Port Elizabeth stations. Most reductions in rainfall occurred in the 1980s and 1990s with the autumn, winter and summer rainfalls, the daily rainfall index and the daily rainfall subclasses of 10 mm and above showing a similar trend. The land use change detection gave a significant increase in proportion of degraded and transformed (moderately degraded) land between 1989 and 2009 with most of the increases occurring from 1989 to 1999, while farmland area decreased by 1.8 percent over the years. Thus the Albany region had over 30 percent of its land occupied by transformed vegetation, with heavy browsing and uncontrolled grazing being attributed to the destruction of pristine vegetation. Land-use change to game ranching and goat pastoralism was attributed to the reduction in farmland. Rainfall variability – land use change linkages were most significant in 1999 that recorded the least rainfall and had the lowest mean, maximum and sum of the NDVI. Grahamstown had the most significant rainfall-NDVI trends as it had the lowest NDVIs in 1999 when rainfall was lowest, the highest NDVI in 1989 when rainfall was highest and moderate NDVIs in 2009 when rainfall was moderate. Vegetation at the IT was characterized by a dense thicket with diverse growth forms of canopy trees, woody shrubs, succulent shrubs and ephemerals which mostly had the C3 type of pathway. This was in contrast with the IT soil isotopy that showed more positive C isotope ratios, indicating a switch between C3 and CAM photosynthesis in original vegetation. Most of the canopy trees had disappeared in the DT to be replaced by herbs, shrubs and grasses. As such, there was a huge difference in isotope ratios between DT plants and soils with the plants having mostly C3 metabolism while the soil showed a predominance of CAM plants in previous vegetation, indicating significant changes in land cover. The G site mostly comprised the grasses Themeda triandra and Panicum maximum and a few herbs. It maintained a dominance of C4 metabolism in both plants and soils showing very little change in species composition over the years. Because of the higher species diversity at IT, its soil organic C was quite high reaching levels of 3.4 percent (i.e. 3.4 t C / ha) in the top 10 cm then decreasing with depth (p < 0.001); but was moderate at DT (1.1-1.3 percent) and very low at G ( 0.5 percent C) (p < 0.001). In the same manner above-ground biomass was highest at IT i.e. 330 000 kg/ha; but was only 22 000 kg/ha in DT and as low as 6 700 kg/ha in G vegetation. High biomass at IT was mostly attributed to the succulent shrub Portulacaria afra and the canopy trees Euclea undulate, Rhus longispina and Schotia afra. This above-ground biomass translated to biomass C amounts of 158 000 kg/ha at IT, 10 600 kg/ha at DT and 3 200 kg/ha at G. Thus the IT had the highest while G the least and DT moderate plant and soil C sequestration ability. In all, the conversion of IT to DT led to a net loss of 147 000 Kg of biomass C / ha and 12 000kg less organic C / ha of land. Soil carbon dioxide effluxes were however variable between seasons as they were affected by differences in soil properties and seasonal weather patterns. High soil moisture levels (up to 16 percent gravimetric moisture) resulted in reduced soil penetration resistance (1 to 4 Kg/cm2) which raised effluxes at G and DT sites (up to 1.2 μmols m-2 sec-1) in winter, while low moisture (2 percent) resulted in hard dry soil (14 Kgm-2 penetration resistance) with suppressed CO2 effluxes in spring (0.2 μmols m-2 sec-1) especially in DT and G soils. Rising temperature generally caused accelerated gas emissions but only when moisture was not limiting (as was the case in IT). Thus the high summer temperatures (up to 40oC) gave lower effluxes especially in DT and G (< 1 μm-2sec-1) due to limited moisture supply (< 10 percent); while the Autumn period that had very high temperature (up to 48 oC) and good moisture (up to 16 percent) saw accelerated soil CO2 emissions (averaging 2 μmols m-2 sec-1) from all cover types. The high biomass and litter fall at IT served as ready substrate for soil respiration as long as moisture was not limiting and temperatures were favourable, while reduced cover at DT resulted in poor moisture conservation and creation of hard dry soils in spring and summer with reduced respiration. It was concluded that the DT had high CO2 effluxes in winter and reduced emissions in summer; while the opposite was true for the IT. All the cover types had minimal CO2 effluxes in spring and accelerated emissions in autumn. The grassland on the other hand was a fairly moderate source or sink of CO2 in most seasons compared with the other two covers. It was observed that an environment of good moisture and low-moderate temperatures (such as that in the winter) minimises effluxes while maintaining good plant productivity. It was concluded that thicket vegetation is a good sink of carbon that should be preserved in its natural condition to optimize its carbon sequestration potential. All three land covers served as sources or sinks of CO2 depending on soil and seasonal conditions. Thus high moisture and low penetration resistance generally increased effluxes of thicket ecosystems. The effect of increasing temperature on effluxes was only significant when moisture was not limiting. Conditions of good moisture and low-moderate temperatures gave reasonable amounts of effluxes while maintaining good plant productivity. Though the dry soil conditions significantly reduced effluxes in all land covers; they were not desirable since they decreased plant productivity and ultimately its C sequestration potential. Moreover, prolonged dry conditions only serve to exacerbate recovery of thicket plants as they increase mortality of canopy species in degraded and transformed areas in comparison with intact thicket.
- Full Text:
- Date Issued: 2013
- Authors: Zengeni, Rebecca
- Date: 2013
- Subjects: Soils -- Carbon content -- Measurement , Carbon dioxide mitigation -- South Africa , Greenhouse gas mitigation -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10665 , http://hdl.handle.net/10948/d1018676
- Description: Albany thicket is prevalent in the Eastern Cape Province of South Africa. Its spread has diminished through overgrazing and heavy browsing by animals, land clearance and urban expansion. The result is highly degraded land characterized by invasion of alien species. There is a wealth of documented evidence on the high carbon sequestration ability of thicket biome, but not much has been done to assess its effect on carbon dioxide emissions from the soil. Given that the concentration of atmospheric greenhouse gases has been constantly rising since the industrial era, it is imperative to assess the influence of thicket biome as a source or sink of these gases. There is evidence of shifts in the climate in southern Africa as reflected by changes in rainfall patterns, increased temperatures, recurrent droughts and fires. As such, the historical rainfall variability in an Albany thicket region and its interaction with the temporal land use / cover changes was studied. This served to give some background information about the study area for more detailed study on C and carbon dioxide effluxes in thicket vegetation under different levels of degradation. This study thus aimed to determine the influence of thicket vegetation at various levels of degradation on soil carbon and carbon dioxide fluxes. The impact of plant photosynthetic pathway on soil C residence time and gas effluxes were analysed to elucidate on the land-use and cover patterns occurring in the area. All this was done to shed some light on the role of soil and thicket vegetation on carbon dioxide emissions and C storage in the spectrum of a shifting climate. The main area of research was Amakhala reserve in an Albany thicket in Eastern Cape Province; and it concentrated on three land cover types namely intact thicket, degraded thicket and grassland. The objectives mentioned above were achieved by assessing historical rainfall variability from 1970 to 2010 through trend and time series analysis at nine rainfall stations located at Amakhala reserve, Grahamstown, Bathurst, Port Alfred, Uitenhage and Port Elizabeth. The land use changes that have occurred in the Albany thicket region covering Amakhala reserve, Grahamstown, Bathurst and Port Alfred were also assessed for 1989, 1999 and 2009 through satellite image analysis with Idrisi Andes GIS software; then their interaction with rainfall variability were determined. To elucidate on the vegetation species composition and land use / cover changes that have occurred in the study area, plant biomass as well carbon (C) and nitrogen (N) isotope measurements were done. Plant biomass was assessed for the dominant species through use of pre-existing allometric equations that required data on plant basal diameter, canopy area, stem numbers and height. The plant carbon was then estimated through use of a conversion factor of 0.48 on above-ground biomass, while soil organic C was determined through the modified Walkely - Black method. Carbon and N isotope ratios were determined from the foliar material of three replicate samples of dominant plant species then analyzed through mass spectrometry. Soil carbon dioxide effluxes were then monitored in each of the intact thicket (IT), degraded thicket (DT) and grassland (G) over a 10 month period; by measuring the net carbon dioxide exchange rate (NCER) through the dynamic chamber method. An automated carbon dioxide exchange analyzer, coupled to a soil temperature probe and photosynthetic active radiation (PAR) sensor was used; with NCER measurements taken every 20-30 days. Soil temperature, moisture, penetration resistance and PAR readings were taken during each assay and later used to interpret the NCER. Results showed that long term variability in annual rainfall had a declining trend at Grahamstown (r = -0.59), Uitenhage and Bathurst stations (r = -0.32 at both stations), but was not significant at Amakhala, Port Alfred and Port Elizabeth stations. Most reductions in rainfall occurred in the 1980s and 1990s with the autumn, winter and summer rainfalls, the daily rainfall index and the daily rainfall subclasses of 10 mm and above showing a similar trend. The land use change detection gave a significant increase in proportion of degraded and transformed (moderately degraded) land between 1989 and 2009 with most of the increases occurring from 1989 to 1999, while farmland area decreased by 1.8 percent over the years. Thus the Albany region had over 30 percent of its land occupied by transformed vegetation, with heavy browsing and uncontrolled grazing being attributed to the destruction of pristine vegetation. Land-use change to game ranching and goat pastoralism was attributed to the reduction in farmland. Rainfall variability – land use change linkages were most significant in 1999 that recorded the least rainfall and had the lowest mean, maximum and sum of the NDVI. Grahamstown had the most significant rainfall-NDVI trends as it had the lowest NDVIs in 1999 when rainfall was lowest, the highest NDVI in 1989 when rainfall was highest and moderate NDVIs in 2009 when rainfall was moderate. Vegetation at the IT was characterized by a dense thicket with diverse growth forms of canopy trees, woody shrubs, succulent shrubs and ephemerals which mostly had the C3 type of pathway. This was in contrast with the IT soil isotopy that showed more positive C isotope ratios, indicating a switch between C3 and CAM photosynthesis in original vegetation. Most of the canopy trees had disappeared in the DT to be replaced by herbs, shrubs and grasses. As such, there was a huge difference in isotope ratios between DT plants and soils with the plants having mostly C3 metabolism while the soil showed a predominance of CAM plants in previous vegetation, indicating significant changes in land cover. The G site mostly comprised the grasses Themeda triandra and Panicum maximum and a few herbs. It maintained a dominance of C4 metabolism in both plants and soils showing very little change in species composition over the years. Because of the higher species diversity at IT, its soil organic C was quite high reaching levels of 3.4 percent (i.e. 3.4 t C / ha) in the top 10 cm then decreasing with depth (p < 0.001); but was moderate at DT (1.1-1.3 percent) and very low at G ( 0.5 percent C) (p < 0.001). In the same manner above-ground biomass was highest at IT i.e. 330 000 kg/ha; but was only 22 000 kg/ha in DT and as low as 6 700 kg/ha in G vegetation. High biomass at IT was mostly attributed to the succulent shrub Portulacaria afra and the canopy trees Euclea undulate, Rhus longispina and Schotia afra. This above-ground biomass translated to biomass C amounts of 158 000 kg/ha at IT, 10 600 kg/ha at DT and 3 200 kg/ha at G. Thus the IT had the highest while G the least and DT moderate plant and soil C sequestration ability. In all, the conversion of IT to DT led to a net loss of 147 000 Kg of biomass C / ha and 12 000kg less organic C / ha of land. Soil carbon dioxide effluxes were however variable between seasons as they were affected by differences in soil properties and seasonal weather patterns. High soil moisture levels (up to 16 percent gravimetric moisture) resulted in reduced soil penetration resistance (1 to 4 Kg/cm2) which raised effluxes at G and DT sites (up to 1.2 μmols m-2 sec-1) in winter, while low moisture (2 percent) resulted in hard dry soil (14 Kgm-2 penetration resistance) with suppressed CO2 effluxes in spring (0.2 μmols m-2 sec-1) especially in DT and G soils. Rising temperature generally caused accelerated gas emissions but only when moisture was not limiting (as was the case in IT). Thus the high summer temperatures (up to 40oC) gave lower effluxes especially in DT and G (< 1 μm-2sec-1) due to limited moisture supply (< 10 percent); while the Autumn period that had very high temperature (up to 48 oC) and good moisture (up to 16 percent) saw accelerated soil CO2 emissions (averaging 2 μmols m-2 sec-1) from all cover types. The high biomass and litter fall at IT served as ready substrate for soil respiration as long as moisture was not limiting and temperatures were favourable, while reduced cover at DT resulted in poor moisture conservation and creation of hard dry soils in spring and summer with reduced respiration. It was concluded that the DT had high CO2 effluxes in winter and reduced emissions in summer; while the opposite was true for the IT. All the cover types had minimal CO2 effluxes in spring and accelerated emissions in autumn. The grassland on the other hand was a fairly moderate source or sink of CO2 in most seasons compared with the other two covers. It was observed that an environment of good moisture and low-moderate temperatures (such as that in the winter) minimises effluxes while maintaining good plant productivity. It was concluded that thicket vegetation is a good sink of carbon that should be preserved in its natural condition to optimize its carbon sequestration potential. All three land covers served as sources or sinks of CO2 depending on soil and seasonal conditions. Thus high moisture and low penetration resistance generally increased effluxes of thicket ecosystems. The effect of increasing temperature on effluxes was only significant when moisture was not limiting. Conditions of good moisture and low-moderate temperatures gave reasonable amounts of effluxes while maintaining good plant productivity. Though the dry soil conditions significantly reduced effluxes in all land covers; they were not desirable since they decreased plant productivity and ultimately its C sequestration potential. Moreover, prolonged dry conditions only serve to exacerbate recovery of thicket plants as they increase mortality of canopy species in degraded and transformed areas in comparison with intact thicket.
- Full Text:
- Date Issued: 2013
Atmospheric pressure metal-organic vapour phase epitaxial growth of InAs/GaSb strained layer superlattices
- Authors: Miya, Senzo Simo
- Date: 2013
- Subjects: Gallium arsenide semiconductors , Organometallic compounds , Compound semiconductors , Metal organic chemical vapor deposition , Superlattices as materials , Epitaxy
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10557 , http://hdl.handle.net/10948/d1020866
- Description: The importance of infrared (IR) technology (for detection in the 3-5 μm and 8-14 μm atmospheric windows) has spread from military applications to civilian applications since World War II. The commercial IR detector market in these wavelength ranges is dominated by mercury cadmium telluride (MCT) alloys. The use of these alloys has, however, been faced with technological difficulties. One of the materials that have been tipped to be suitable to replace MCT is InAs/InxGa1-xSb strained layer superlattices (SLS’s). Atmospheric pressure metal-organic vapour phase epitaxy (MOVPE) has been used to grow InAs/GaSb strained layer superlattices (SLS’s) at 510 °C in this study. This is a starting point towards the development of MOVPE InAs/InxGa1-xSb SLS’s using the same system. Before the SLS’s could be attempted, the growth parameters for GaSb were optimised. Growth parameters for InAs were taken from reports on previous studies conducted using the same reactor. Initially, trimethylgallium, a source that has been used extensively in the same growth system for the growth of GaSb and InxGa1-xSb was intended to be used for gallium species. The high growth rates yielded by this source were too large for the growth of SLS structures, however. Thus, triethylgallium (rarely used for atmospheric pressure MOVPE) was utilized. GaSb layers (between 1 and 2 μm thick) were grown at two different temperatures (550 °C and 510 °C) with a varying V/III ratio. A V/III ratio of 1.5 was found to be optimal at 550 °C. However, the low incorporation efficiency of indium into GaSb at this temperature was inadequate to obtain InxGa1-xSb with an indium mole fraction (x) of around 0.3, which had previously been reported to be optimal for the performance of InAs/InxGa1-xSb SLS’s, due to the maximum splitting of the valence mini bands for this composition. The growth temperature was thus lowered to 510 °C. This resulted in an increase in the optimum V/III ratio to 1.75 for GaSb and yielded much higher incorporation efficiencies of indium in InxGa1-xSb. However, this lower growth temperature also produced poorer surface morphologies for both the binary and ternary layers, due to the reduced surface diffusion of the adsorbed species. An interface control study during the growth of InAs/GaSb SLS’s was subsequently conducted, by investigating the influence of different gas switching sequences on the interface type and quality. It was noted that the growth of SLS’s without any growth interruptions at the interfaces leads to tensile strained SLS’s (GaAs-like interfaces) with a rather large lattice mismatch. A 5 second flow of TMSb over the InAs surface and a flow of H2 over GaSb surface yielded compressively strained SLS’s. Flowing TMIn for 1 second and following by a flow of TMSb for 4 seconds over the GaSb surface, while flowing H2 for 5 seconds over the InAs surface, resulted in SLS’s with GaAs-like interfacial layers and a reduced lattice mismatch. Temperature gradients across the surface of the susceptor led to SLS’s with different structural quality. High resolution x-ray diffraction (HRXRD) was used to determine the thicknesses as well as the type of interfacial layers. The physical parameters of the SLS’s obtained from simulating the HRXRD spectra were comparable to the parameters obtained from cross sectional transmission electron microscopy (XTEM) images. The thicknesses of the layers and the interface type played a major role in determining the cut-off wavelength of the SLS’s.
- Full Text:
- Date Issued: 2013
- Authors: Miya, Senzo Simo
- Date: 2013
- Subjects: Gallium arsenide semiconductors , Organometallic compounds , Compound semiconductors , Metal organic chemical vapor deposition , Superlattices as materials , Epitaxy
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10557 , http://hdl.handle.net/10948/d1020866
- Description: The importance of infrared (IR) technology (for detection in the 3-5 μm and 8-14 μm atmospheric windows) has spread from military applications to civilian applications since World War II. The commercial IR detector market in these wavelength ranges is dominated by mercury cadmium telluride (MCT) alloys. The use of these alloys has, however, been faced with technological difficulties. One of the materials that have been tipped to be suitable to replace MCT is InAs/InxGa1-xSb strained layer superlattices (SLS’s). Atmospheric pressure metal-organic vapour phase epitaxy (MOVPE) has been used to grow InAs/GaSb strained layer superlattices (SLS’s) at 510 °C in this study. This is a starting point towards the development of MOVPE InAs/InxGa1-xSb SLS’s using the same system. Before the SLS’s could be attempted, the growth parameters for GaSb were optimised. Growth parameters for InAs were taken from reports on previous studies conducted using the same reactor. Initially, trimethylgallium, a source that has been used extensively in the same growth system for the growth of GaSb and InxGa1-xSb was intended to be used for gallium species. The high growth rates yielded by this source were too large for the growth of SLS structures, however. Thus, triethylgallium (rarely used for atmospheric pressure MOVPE) was utilized. GaSb layers (between 1 and 2 μm thick) were grown at two different temperatures (550 °C and 510 °C) with a varying V/III ratio. A V/III ratio of 1.5 was found to be optimal at 550 °C. However, the low incorporation efficiency of indium into GaSb at this temperature was inadequate to obtain InxGa1-xSb with an indium mole fraction (x) of around 0.3, which had previously been reported to be optimal for the performance of InAs/InxGa1-xSb SLS’s, due to the maximum splitting of the valence mini bands for this composition. The growth temperature was thus lowered to 510 °C. This resulted in an increase in the optimum V/III ratio to 1.75 for GaSb and yielded much higher incorporation efficiencies of indium in InxGa1-xSb. However, this lower growth temperature also produced poorer surface morphologies for both the binary and ternary layers, due to the reduced surface diffusion of the adsorbed species. An interface control study during the growth of InAs/GaSb SLS’s was subsequently conducted, by investigating the influence of different gas switching sequences on the interface type and quality. It was noted that the growth of SLS’s without any growth interruptions at the interfaces leads to tensile strained SLS’s (GaAs-like interfaces) with a rather large lattice mismatch. A 5 second flow of TMSb over the InAs surface and a flow of H2 over GaSb surface yielded compressively strained SLS’s. Flowing TMIn for 1 second and following by a flow of TMSb for 4 seconds over the GaSb surface, while flowing H2 for 5 seconds over the InAs surface, resulted in SLS’s with GaAs-like interfacial layers and a reduced lattice mismatch. Temperature gradients across the surface of the susceptor led to SLS’s with different structural quality. High resolution x-ray diffraction (HRXRD) was used to determine the thicknesses as well as the type of interfacial layers. The physical parameters of the SLS’s obtained from simulating the HRXRD spectra were comparable to the parameters obtained from cross sectional transmission electron microscopy (XTEM) images. The thicknesses of the layers and the interface type played a major role in determining the cut-off wavelength of the SLS’s.
- Full Text:
- Date Issued: 2013
Characterisation and biotic classification of Eastern Cape mixed substrate shores
- Authors: Garner, Cornelia Johanna
- Date: 2013
- Subjects: Coastal sediments -- South Africa -- Eastern Cape , Coastal biodiversity --- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10641 , http://hdl.handle.net/10948/d1020825
- Description: A significant proportion of the South African coastline is composed of both soft (mostly sand) and hard (mostly bedrock) substrata, i.e. “mixed”. This study described and classified macrobenthic assemblages of 20 Eastern Cape mixed substrate shores that differed in shore topography and the extent and position of intertidal rock and sand. A stratified random approach was used. Species richness, composition, abundance and environmental variables were determined. Commonly used beach indices were calculated. A total of 78 macrofaunal and 172 macroalgal species from rock substrate assemblages and 205 macrofauna species from sediment were recorded. Total species richness and richness per substratum exceeded that of sandy beaches devoid of rock and rocky shores with no sand. Rhodophyta were the most diverse and abundant algae, dominating all low-elevation rock surfaces as midlittoral and infralittoral turfs. Chlorophyta diversity was higher than at rocky shores, contributing more to cover-abundance at study sites and in microhabitats with an increased sand load. Sessile macrofauna species richness and abundance was lower than that of rocky shores. Polychaetes and crustaceans were the most diverse and abundant beach infauna. Species richness of both substrates declined from the low shore towards the high shore, but abundance trends varied substantially. The presence and extent of an intertidal biotope/subzone at either substrate depended on substrate availability.The supralittoral fringe in both substrate types was most often affected. Zonal overlap was evident on rock substrate: assemblages of raised midlittoral rock surfaces were enriched by species from lower surfaces sometimes leading to elimination of character taxa. Classification and ordination identified three potential mixed substrate shore biotic types: Biotic type A (Jania-Corallina- Polysiphonia turf) was characterised by robustly-textured algal turfs, a lowered predominance and diversity of polychaetes and an increase in crustacean abundance and diversity in sediment. Biotic type B (Polysiphonia-Tayloriella-Caulacanthus turf) had intermediately and biotic type C (Arthrocardia-Laurencia turf) the most sheltered eulittoral zones and beaches. DCCA identified the major environmental parameters affecting the macrobiota as: the level of wave energy, geological control of waves by hard substrate, sediment grain size and sediment inundation. A strong cross-shore wave attenuation results in sheltered sediments and midshore rock surfaces. Beach macrofauna were highly variable and diverse, which directly opposes previous perceptions about the sediment-bound biota of mixed substrate shores. The hierarchical cluster analysis produced a biotic classification of mixed substrate shores that was indicative of a biotic response to the total effects of leading environmental parameters. Macrobenthos of rock surfaces and sediment therefore showed potential to be used as an alternative or complementary to physical characteristics in classifying mixed substrate shores.
- Full Text:
- Date Issued: 2013
- Authors: Garner, Cornelia Johanna
- Date: 2013
- Subjects: Coastal sediments -- South Africa -- Eastern Cape , Coastal biodiversity --- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10641 , http://hdl.handle.net/10948/d1020825
- Description: A significant proportion of the South African coastline is composed of both soft (mostly sand) and hard (mostly bedrock) substrata, i.e. “mixed”. This study described and classified macrobenthic assemblages of 20 Eastern Cape mixed substrate shores that differed in shore topography and the extent and position of intertidal rock and sand. A stratified random approach was used. Species richness, composition, abundance and environmental variables were determined. Commonly used beach indices were calculated. A total of 78 macrofaunal and 172 macroalgal species from rock substrate assemblages and 205 macrofauna species from sediment were recorded. Total species richness and richness per substratum exceeded that of sandy beaches devoid of rock and rocky shores with no sand. Rhodophyta were the most diverse and abundant algae, dominating all low-elevation rock surfaces as midlittoral and infralittoral turfs. Chlorophyta diversity was higher than at rocky shores, contributing more to cover-abundance at study sites and in microhabitats with an increased sand load. Sessile macrofauna species richness and abundance was lower than that of rocky shores. Polychaetes and crustaceans were the most diverse and abundant beach infauna. Species richness of both substrates declined from the low shore towards the high shore, but abundance trends varied substantially. The presence and extent of an intertidal biotope/subzone at either substrate depended on substrate availability.The supralittoral fringe in both substrate types was most often affected. Zonal overlap was evident on rock substrate: assemblages of raised midlittoral rock surfaces were enriched by species from lower surfaces sometimes leading to elimination of character taxa. Classification and ordination identified three potential mixed substrate shore biotic types: Biotic type A (Jania-Corallina- Polysiphonia turf) was characterised by robustly-textured algal turfs, a lowered predominance and diversity of polychaetes and an increase in crustacean abundance and diversity in sediment. Biotic type B (Polysiphonia-Tayloriella-Caulacanthus turf) had intermediately and biotic type C (Arthrocardia-Laurencia turf) the most sheltered eulittoral zones and beaches. DCCA identified the major environmental parameters affecting the macrobiota as: the level of wave energy, geological control of waves by hard substrate, sediment grain size and sediment inundation. A strong cross-shore wave attenuation results in sheltered sediments and midshore rock surfaces. Beach macrofauna were highly variable and diverse, which directly opposes previous perceptions about the sediment-bound biota of mixed substrate shores. The hierarchical cluster analysis produced a biotic classification of mixed substrate shores that was indicative of a biotic response to the total effects of leading environmental parameters. Macrobenthos of rock surfaces and sediment therefore showed potential to be used as an alternative or complementary to physical characteristics in classifying mixed substrate shores.
- Full Text:
- Date Issued: 2013
Exploring interventions for participation of emerging farmers in the Eastern Cape ostrich-industry supply chain
- Authors: Pittaway, Timothy
- Date: 2013
- Subjects: Farmers -- South Africa -- Eastern Cape , Ostrich products industry -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10596 , http://hdl.handle.net/10948/d1021008
- Description: The changing agricultural environment (dualistic agricultural landscape, land reform programme, market liberalisation and globalisation) has caused emerging ostrich farmers to become increasingly isolated. Governmental agriculture reforms and public sector interventions have been insufficient to address all the challenges faced by rural ostrich farmers in the Eastern Cape. Participation in the ostrich supply chain for emerging farmers in the Eastern Cape is currently unsustainable as a result of avian influenza, control and registration protocols for ostriches (VPN04), structural barriers in marketing, technical constraints and a lack of market participation. People in the rural areas of the Eastern Cape are challenged by inferior infrastructure, poor site conditions, low earnings, poor access to health services and unreliable water sources. The marginal conditions and prevalent complexities in which agriculture is practised require costly resource intervention. Intensive ostrich production necessitates continuous genetic improvement, methodical record keeping, intensive egg incubation methods and highmaintenance chick rearing and ostrich handling while minimising feed costs throughout this process. Rural farmers have not embraced ostrich farming in the same way as they have done with other livestock farming because it does not offer the anthropological functions that traditional livestock farming provides. The ostrich supply chain requires a wide range of activities to bring products to the final consumer. The worth of ostrich production lies mainly in the higher returns which are achieved only through the export markets. Today the ostrich industry has become vulnerable to market cannibalism, a lack of market development, unregulated numbers of ostriches and recurring international meat bans. The deregulation of the ostrich single-channel marketing system had a substantial effect on the value chain on which farmers depended for market access and market protection. As the majority of ostrich products are being exported to the European Union, the role of intermediary agencies is becoming an important factor influencing entry into the high-end markets. This agent structure that represents the South African ostrich industry is vital for the distribution, market penetration and regulation of the ostrich products. The ostrich leather, which is today the main product line, is primarily used for luxury goods and is susceptible to economic downturn and over-supply. The ostrich meat industry has been severely influenced by outbreaks of avian influenza and processors now pre-heat the meat in order to maintain export. However, this preheating meat facility is only for export produce and available to farmers who conform to VPN04 and have officially registered farms. The relevant South African government departments played a crucial role in identifying avian influenza outbreaks and liaising with the European Union about avian influenza isolation strategies. No previous studies have been conducted on the participation of emerging farmers in the Eastern Cape ostrich-industry supply chain and on the interventions required to address the multiple constraints and forces in this sector. This led to a study with research emphasis on the required capacity for supply-chain participation and the supporting mechanisms that would be required for emerging ostrich farmers to integrate successfully into this supply chain. An exploratory research approach was chosen for the investigation, as no earlier research has been undertaken that could serve as a source of reliable data or reference. A triangulation research methodology using both the quantitative and the qualitative approach was applied. The qualitative research entailed an interpretive approach associated with using grounded theory and content analysis for interpreting data. The comparative case study design was the main qualitative research instrument for the multiple-case studies on emerging ostrich farmers in the Eastern Cape. The study was undertaken at five different sites, namely, the Peddie Ostrich Programme, the Rockhurst Ostrich Programme, the Hlumani Co-operative farm, the Zamukwanda Ostrich farm near Pearston and the Mimosadale Ostrich farm. The quantitative methods were applied to capture all the measurable components and representations of the stakeholders and participants, through interviews, questionnaires and focus group interviews. The quantitative study also included an experimental instrument to measure the capacity of emerging farmer programmes for supply chain participation. It was found that the main driver for three of the case studies pertained to land ownership and that ostrich farming was incidental and only seen as means of activity for income. These three humanitarian farming projects had limited capacity for intensive management requirements for ostrich farming. It was found that the VPN04 bio-security protocols and disease control require a higher level of record keeping for EU markets and is prohibitively expensive for poor rural emerging farmers. The study established that the emerging ostrich farming programmes contributed value to the industry and government rural development in land redistribution programmes, vehicles for reduction of poverty and job creation in the rural areas and by acting as out-grower programmes for commercial farmers. The researcher’s observation is that through strategic interventions the programmes have potential to become commercial players in the industry. The following interventions were recommended from this study: Feasibility study of programmes and review of location selection before initiation. Providing supportive interventions for programme start-ups; Improved selection of programme beneficiaries; Improved structure of emerging farmers’ co-operatives; On-going and appropriate training for emerging ostrich farmers; The role of government and mentors needs to be defined; Reducing feed costs; Establishing programmes linkages to informal markets and facilitating increased self-consumption; Developing new export markets; Alternative finance for the no-income months; Alternative marketing channels to export markets; Representation of emerging farmers in the ostrich-industry leadership structures.
- Full Text:
- Date Issued: 2013
- Authors: Pittaway, Timothy
- Date: 2013
- Subjects: Farmers -- South Africa -- Eastern Cape , Ostrich products industry -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10596 , http://hdl.handle.net/10948/d1021008
- Description: The changing agricultural environment (dualistic agricultural landscape, land reform programme, market liberalisation and globalisation) has caused emerging ostrich farmers to become increasingly isolated. Governmental agriculture reforms and public sector interventions have been insufficient to address all the challenges faced by rural ostrich farmers in the Eastern Cape. Participation in the ostrich supply chain for emerging farmers in the Eastern Cape is currently unsustainable as a result of avian influenza, control and registration protocols for ostriches (VPN04), structural barriers in marketing, technical constraints and a lack of market participation. People in the rural areas of the Eastern Cape are challenged by inferior infrastructure, poor site conditions, low earnings, poor access to health services and unreliable water sources. The marginal conditions and prevalent complexities in which agriculture is practised require costly resource intervention. Intensive ostrich production necessitates continuous genetic improvement, methodical record keeping, intensive egg incubation methods and highmaintenance chick rearing and ostrich handling while minimising feed costs throughout this process. Rural farmers have not embraced ostrich farming in the same way as they have done with other livestock farming because it does not offer the anthropological functions that traditional livestock farming provides. The ostrich supply chain requires a wide range of activities to bring products to the final consumer. The worth of ostrich production lies mainly in the higher returns which are achieved only through the export markets. Today the ostrich industry has become vulnerable to market cannibalism, a lack of market development, unregulated numbers of ostriches and recurring international meat bans. The deregulation of the ostrich single-channel marketing system had a substantial effect on the value chain on which farmers depended for market access and market protection. As the majority of ostrich products are being exported to the European Union, the role of intermediary agencies is becoming an important factor influencing entry into the high-end markets. This agent structure that represents the South African ostrich industry is vital for the distribution, market penetration and regulation of the ostrich products. The ostrich leather, which is today the main product line, is primarily used for luxury goods and is susceptible to economic downturn and over-supply. The ostrich meat industry has been severely influenced by outbreaks of avian influenza and processors now pre-heat the meat in order to maintain export. However, this preheating meat facility is only for export produce and available to farmers who conform to VPN04 and have officially registered farms. The relevant South African government departments played a crucial role in identifying avian influenza outbreaks and liaising with the European Union about avian influenza isolation strategies. No previous studies have been conducted on the participation of emerging farmers in the Eastern Cape ostrich-industry supply chain and on the interventions required to address the multiple constraints and forces in this sector. This led to a study with research emphasis on the required capacity for supply-chain participation and the supporting mechanisms that would be required for emerging ostrich farmers to integrate successfully into this supply chain. An exploratory research approach was chosen for the investigation, as no earlier research has been undertaken that could serve as a source of reliable data or reference. A triangulation research methodology using both the quantitative and the qualitative approach was applied. The qualitative research entailed an interpretive approach associated with using grounded theory and content analysis for interpreting data. The comparative case study design was the main qualitative research instrument for the multiple-case studies on emerging ostrich farmers in the Eastern Cape. The study was undertaken at five different sites, namely, the Peddie Ostrich Programme, the Rockhurst Ostrich Programme, the Hlumani Co-operative farm, the Zamukwanda Ostrich farm near Pearston and the Mimosadale Ostrich farm. The quantitative methods were applied to capture all the measurable components and representations of the stakeholders and participants, through interviews, questionnaires and focus group interviews. The quantitative study also included an experimental instrument to measure the capacity of emerging farmer programmes for supply chain participation. It was found that the main driver for three of the case studies pertained to land ownership and that ostrich farming was incidental and only seen as means of activity for income. These three humanitarian farming projects had limited capacity for intensive management requirements for ostrich farming. It was found that the VPN04 bio-security protocols and disease control require a higher level of record keeping for EU markets and is prohibitively expensive for poor rural emerging farmers. The study established that the emerging ostrich farming programmes contributed value to the industry and government rural development in land redistribution programmes, vehicles for reduction of poverty and job creation in the rural areas and by acting as out-grower programmes for commercial farmers. The researcher’s observation is that through strategic interventions the programmes have potential to become commercial players in the industry. The following interventions were recommended from this study: Feasibility study of programmes and review of location selection before initiation. Providing supportive interventions for programme start-ups; Improved selection of programme beneficiaries; Improved structure of emerging farmers’ co-operatives; On-going and appropriate training for emerging ostrich farmers; The role of government and mentors needs to be defined; Reducing feed costs; Establishing programmes linkages to informal markets and facilitating increased self-consumption; Developing new export markets; Alternative finance for the no-income months; Alternative marketing channels to export markets; Representation of emerging farmers in the ostrich-industry leadership structures.
- Full Text:
- Date Issued: 2013
High performance nonwovens in technical textile applications
- Ogunleye, Christopher Olarinde
- Authors: Ogunleye, Christopher Olarinde
- Date: 2013
- Subjects: Nonwoven fabrics , Textile fabrics -- Technological innovations
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10356 , http://hdl.handle.net/10948/d1021011
- Description: The aim of this research was to establish the optimum processing conditions and parameters for producing nonwoven fabrics best suited for application in disposable and protective wear for surgical gowns, drapes and laboratory coats. Carded and crosslapped webs, of three basic weights (80, 120, and 150g/m2), from greige (unscoured and unbleached) cotton, viscose and polyester fibres, were hydroentangled, using three different waterjet pressures (60, 100 and 120 bars), on a Fleissner Aquajet hydroentanglement machine. An antibacterial agent (Ruco-Coat FC 9005) and a fluorochemical water repellent agent (Ruco Bac-AGP), were applied in one bath using the pad-dry-cure technique, to impart both antibacterial and water repellent properties to the fabrics, SEM photomicrographs indicating that the finished polymers were evenly dispersed on the fabric surface. The effect of waterjet pressure, fabric weight and type and treatment on the structure of the nonwoven produced, was evaluated by measuring the relevant characteristics of the fabrics. As expected, there was an interrelationship between fabric weight, thickness, and density, the fabric thickness and mass density increasing with fabric weight. An increase in waterjet pressure decreased the fabric thickness and increased the fabric density. The water repellent and antibacterial treatment increased the fabric weight and thickness. The antimicrobial activity of the fabrics was assessed by determining the percentage reduction in Staphylococcus aureus and Escherichia coli bacteria population. The maximum percent reduction at 24hrs contact time for both bacteria ranged from 99.5 to 99.6 percent for all the fabric types. The standard spray test ratings for the three treated fabrics ranged from 80-90 percent, whereas that of the untreated water repellent fabric was zero, while the contact angles for all the fabric types exceeded 90 degrees, indicating good resistance to wetting. It was found that the tensile strength of the fabric in the cross-machine direction was higher than that in the machine direction, for both the treated and untreated fabrics, with the tensile strengths in both the MD and CD of the treated fabrics were greater than that of the untreated fabrics, the reverse being true for the extension at break. An increase in waterjet pressure increased the tensile strength but decreased the extension at break, for both the treated and untreated fabrics. The finishing treatment decreased the mean pore size of all the fabrics, the mean pore size decreasing with an increase in fabric weight and waterjet pressure. An increase in waterjet pressure and fabric weight decreased the air and water vapour permeability, as did the finishing treatment, although the differences were not always statistically significant. The polyester fabrics had the highest water and air permeability. Hence low weight fabrics of 80 g/m2, which were hydroentangled at low water jet pressures of 60 bars, were suitable for use in this study due to their higher air and water vapour permeability as well as higher pore size distribution. These group of fabrics thus meet the requirements for surgical gowns, drapes, nurses’ uniforms and laboratory coats.
- Full Text:
- Date Issued: 2013
- Authors: Ogunleye, Christopher Olarinde
- Date: 2013
- Subjects: Nonwoven fabrics , Textile fabrics -- Technological innovations
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10356 , http://hdl.handle.net/10948/d1021011
- Description: The aim of this research was to establish the optimum processing conditions and parameters for producing nonwoven fabrics best suited for application in disposable and protective wear for surgical gowns, drapes and laboratory coats. Carded and crosslapped webs, of three basic weights (80, 120, and 150g/m2), from greige (unscoured and unbleached) cotton, viscose and polyester fibres, were hydroentangled, using three different waterjet pressures (60, 100 and 120 bars), on a Fleissner Aquajet hydroentanglement machine. An antibacterial agent (Ruco-Coat FC 9005) and a fluorochemical water repellent agent (Ruco Bac-AGP), were applied in one bath using the pad-dry-cure technique, to impart both antibacterial and water repellent properties to the fabrics, SEM photomicrographs indicating that the finished polymers were evenly dispersed on the fabric surface. The effect of waterjet pressure, fabric weight and type and treatment on the structure of the nonwoven produced, was evaluated by measuring the relevant characteristics of the fabrics. As expected, there was an interrelationship between fabric weight, thickness, and density, the fabric thickness and mass density increasing with fabric weight. An increase in waterjet pressure decreased the fabric thickness and increased the fabric density. The water repellent and antibacterial treatment increased the fabric weight and thickness. The antimicrobial activity of the fabrics was assessed by determining the percentage reduction in Staphylococcus aureus and Escherichia coli bacteria population. The maximum percent reduction at 24hrs contact time for both bacteria ranged from 99.5 to 99.6 percent for all the fabric types. The standard spray test ratings for the three treated fabrics ranged from 80-90 percent, whereas that of the untreated water repellent fabric was zero, while the contact angles for all the fabric types exceeded 90 degrees, indicating good resistance to wetting. It was found that the tensile strength of the fabric in the cross-machine direction was higher than that in the machine direction, for both the treated and untreated fabrics, with the tensile strengths in both the MD and CD of the treated fabrics were greater than that of the untreated fabrics, the reverse being true for the extension at break. An increase in waterjet pressure increased the tensile strength but decreased the extension at break, for both the treated and untreated fabrics. The finishing treatment decreased the mean pore size of all the fabrics, the mean pore size decreasing with an increase in fabric weight and waterjet pressure. An increase in waterjet pressure and fabric weight decreased the air and water vapour permeability, as did the finishing treatment, although the differences were not always statistically significant. The polyester fabrics had the highest water and air permeability. Hence low weight fabrics of 80 g/m2, which were hydroentangled at low water jet pressures of 60 bars, were suitable for use in this study due to their higher air and water vapour permeability as well as higher pore size distribution. These group of fabrics thus meet the requirements for surgical gowns, drapes, nurses’ uniforms and laboratory coats.
- Full Text:
- Date Issued: 2013
Microcystin enhances the fitness of microcystin producing cyanobacteria at high light intensities by either preventing or retarding photoinhibition
- Authors: Phelan, Richard Reginald
- Date: 2013
- Subjects: Microcystins , Microcystis , Cyanobacterial toxins
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10354 , http://hdl.handle.net/10948/d1020957
- Description: Several genera of cyanobacteria produce microcystin, a monocyclic peptide, with a unique chemical structure. To date, there have been over a 100 different structural variants of microcystin which have been identified. Microcystin production is affected by numerous environmental factors. However, the primary modulating factor for intracellular microcystin quota is the intracellular N:C ratio. No clearly defined biological role has been described for microcystin. Proposed roles for microcystin include defence against plankton grazers, metal chelation, an infochemical and a protectant against oxidative stress. There is sufficient evidence to support a biological role for microcystin in photosynthesis: microcystin is predominantly located in the thylakoid membranes, the microcystin gene cluster is differentially expressed as a function of light and a growth advantage for the microcystin producer in saturating light intensities. The purpose of this study is to investigate a possible biological role for microcystin in preventing photoinhibition and thus explaining the growth advantage observed in toxin-producers over non-toxin-producers. The uptake of exogenous microcystin was observed in Synechocystis PCC 6803 which was internalized and located in the thylakoid membranes and caused the inhibition of photosynthesis. Microcystin variants and increasing concentrations of microcystin-LR had no effect on the fluidity of the thylakoid membranes. The exposure of thylakoid membranes from Synechocystis PCC 6803 to physiologically relevant concentrations of different microcystin variants resulted in the inhibition of photosystem II activity but not photosystem I activity. The inhibition of photosystem II was variant dependent and concentration dependent for microcystin-LR and microcystin-RR. Chlorophyll a fluorescence data showed that photosystem II inhibition was caused by the inhibition of the oxygen evolving complex. Furthermore, a completion study revealed that the microcystin-producing Microcystis PCC 7806 had a competitive advantage over the non-microcystin producing ΔmcyA mutant of Microcystis PCC 7806 at high light intensities. The data indicates that microcystin protects the toxin-producer by either retarding or preventing photoinhibition and thus identifying the first data supported function for microcystin in cyanobacteria.
- Full Text:
- Date Issued: 2013
- Authors: Phelan, Richard Reginald
- Date: 2013
- Subjects: Microcystins , Microcystis , Cyanobacterial toxins
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10354 , http://hdl.handle.net/10948/d1020957
- Description: Several genera of cyanobacteria produce microcystin, a monocyclic peptide, with a unique chemical structure. To date, there have been over a 100 different structural variants of microcystin which have been identified. Microcystin production is affected by numerous environmental factors. However, the primary modulating factor for intracellular microcystin quota is the intracellular N:C ratio. No clearly defined biological role has been described for microcystin. Proposed roles for microcystin include defence against plankton grazers, metal chelation, an infochemical and a protectant against oxidative stress. There is sufficient evidence to support a biological role for microcystin in photosynthesis: microcystin is predominantly located in the thylakoid membranes, the microcystin gene cluster is differentially expressed as a function of light and a growth advantage for the microcystin producer in saturating light intensities. The purpose of this study is to investigate a possible biological role for microcystin in preventing photoinhibition and thus explaining the growth advantage observed in toxin-producers over non-toxin-producers. The uptake of exogenous microcystin was observed in Synechocystis PCC 6803 which was internalized and located in the thylakoid membranes and caused the inhibition of photosynthesis. Microcystin variants and increasing concentrations of microcystin-LR had no effect on the fluidity of the thylakoid membranes. The exposure of thylakoid membranes from Synechocystis PCC 6803 to physiologically relevant concentrations of different microcystin variants resulted in the inhibition of photosystem II activity but not photosystem I activity. The inhibition of photosystem II was variant dependent and concentration dependent for microcystin-LR and microcystin-RR. Chlorophyll a fluorescence data showed that photosystem II inhibition was caused by the inhibition of the oxygen evolving complex. Furthermore, a completion study revealed that the microcystin-producing Microcystis PCC 7806 had a competitive advantage over the non-microcystin producing ΔmcyA mutant of Microcystis PCC 7806 at high light intensities. The data indicates that microcystin protects the toxin-producer by either retarding or preventing photoinhibition and thus identifying the first data supported function for microcystin in cyanobacteria.
- Full Text:
- Date Issued: 2013
Molecular signaling in colorectal carcinogenesis : the roles and relationships of beta-catenin, PPARgamma and COX-2
- Authors: Fredericks, Ernst
- Date: 2013
- Subjects: Colon (Anatomy) -- Cancer , Cyclooxygenase 2 , Peroxisomes
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10357 , http://hdl.handle.net/10948/d1021014
- Description: Colorectal cancer (CRC) is a common disease with significant morbidity and mortality. In spite of significant advances in understanding the molecular signaling in this disorder, unanswered questions remain. Cyclooxygenase-2 (COX-2) and β-catenin have established roles in colorectal carcinogenesis, with both being upregulated early in the disease course. The role of peroxisome proliferator-activated receptor γ (PPARγ) is less clear, but has been shown to be downregulated in colon cancer models. Butyrate, a short chain fatty acid, produced by colon microbiota and transported into the colonocyte by transporter proteins, appears to be important in early carcinogenesis. The butyrate concentration is reduced in CRC and so are its transporters. Interleukin-17 (IL-17) plays a role in colitis-associated colorectal cancer (CAC), but its function in sporadic CRC is less clear. Similarly, Protein kinase C (PKC) has proven involvement in many solid tumours, including CRC, but its exact mechanistic role is still speculative. AIM: To investigate the role and possible signaling pathways of the major role players, β-catenin, COX-2 and PPARγ in early CRC. Further, to elucidate the mechanistic pathways of butyrate and its transporters, IL-17 and PKC in CRC. METHOD: Informed consent was obtained for all patients. Patients were recruited in various disease categories, including normal, irritable bowel syndrome (IBS), inflammatory bowel disease (IBD) and CRC. Colon biopsy specimens were obtained during colonoscopy and used for immunohistochemistry (IHC) and gene expression analysis of the above genes by quantitative polymerase chain reaction (qPCR). RESULTS: β-catenin mRNA and protein expression was increased in CRC and the IBD groups compared to the normal group, while it was reduced in the IBS groups. COX-2 mRNA expression showed a steady increase from normal, through IBS, IBD and CRC groups to a statistically significant degree. The COX-2 protein expression, however, did not match the mRNA expression with increased COX-2 protein expression in normal and IBS groups and reduced expression in IBD and CRC groups. PPARγ mRNA expression was unchanged in IBD and CRC groups, but significantly increased in the IBS group compared to normal. Butyrate transporter, SLC16A1 mRNA was significantly reduced in CRC, but also in the IBS groups, which was unexpected. In the IBD group, SLC16A1 mRNA was unchanged in Crohn’s disease (CD) but significantly reduced in ulcerative colitis (UC). Similarly, SLC5A8 mRNA expression was significantly reduced in the CRC as well as the IBS groups. In the IBD groups, SLC5A8 was unchanged in UC but significantly increased in CD. IL-17 mRNA expression was significantly reduced in CRC and IBS groups, but unchanged in the IBD groups. PKCε mRNA was significantly increased in CRC as expected. In the IBD groups, PKCε mRNA was unchanged in CD but significantly increased in UC. In the IBS groups, PKCε mRNA in constipation –IBS (C-IBS) was significantly reduced, but unchanged in diarrhoea – IBS (D-IBS). CONCLUSIONS: β-catenin mRNA and protein expression was increased in CRC and the CRC promoting IBD groups. COX-2 protein expression was incongruent with the COX-2 mRNA expression and this may reflect homeostatic control mechanisms. High COX-2 mRNA expression in CRC and CRC promoting IBD groups may be a secondary phenomenon reflecting the inflammatory milieu, rather than a true carcinogenesis-related event. PPARγ does not appear to play a central role in early colon carcinogenesis, in spite of available literature suggesting otherwise. Butyrate transporters showed inconsistent results and for now no firm conclusions can be drawn from this. IL-17 may play a role in CAC as confirmed in this and other studies, but its role in sporadic CRC is tenuous and requires further investigation. Likewise for PKCε, upregulation is associated with increased tumourigenecity as shown in this study, however, the mechanistic pathway(s) involved is still speculative and requires further study.
- Full Text:
- Date Issued: 2013
- Authors: Fredericks, Ernst
- Date: 2013
- Subjects: Colon (Anatomy) -- Cancer , Cyclooxygenase 2 , Peroxisomes
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10357 , http://hdl.handle.net/10948/d1021014
- Description: Colorectal cancer (CRC) is a common disease with significant morbidity and mortality. In spite of significant advances in understanding the molecular signaling in this disorder, unanswered questions remain. Cyclooxygenase-2 (COX-2) and β-catenin have established roles in colorectal carcinogenesis, with both being upregulated early in the disease course. The role of peroxisome proliferator-activated receptor γ (PPARγ) is less clear, but has been shown to be downregulated in colon cancer models. Butyrate, a short chain fatty acid, produced by colon microbiota and transported into the colonocyte by transporter proteins, appears to be important in early carcinogenesis. The butyrate concentration is reduced in CRC and so are its transporters. Interleukin-17 (IL-17) plays a role in colitis-associated colorectal cancer (CAC), but its function in sporadic CRC is less clear. Similarly, Protein kinase C (PKC) has proven involvement in many solid tumours, including CRC, but its exact mechanistic role is still speculative. AIM: To investigate the role and possible signaling pathways of the major role players, β-catenin, COX-2 and PPARγ in early CRC. Further, to elucidate the mechanistic pathways of butyrate and its transporters, IL-17 and PKC in CRC. METHOD: Informed consent was obtained for all patients. Patients were recruited in various disease categories, including normal, irritable bowel syndrome (IBS), inflammatory bowel disease (IBD) and CRC. Colon biopsy specimens were obtained during colonoscopy and used for immunohistochemistry (IHC) and gene expression analysis of the above genes by quantitative polymerase chain reaction (qPCR). RESULTS: β-catenin mRNA and protein expression was increased in CRC and the IBD groups compared to the normal group, while it was reduced in the IBS groups. COX-2 mRNA expression showed a steady increase from normal, through IBS, IBD and CRC groups to a statistically significant degree. The COX-2 protein expression, however, did not match the mRNA expression with increased COX-2 protein expression in normal and IBS groups and reduced expression in IBD and CRC groups. PPARγ mRNA expression was unchanged in IBD and CRC groups, but significantly increased in the IBS group compared to normal. Butyrate transporter, SLC16A1 mRNA was significantly reduced in CRC, but also in the IBS groups, which was unexpected. In the IBD group, SLC16A1 mRNA was unchanged in Crohn’s disease (CD) but significantly reduced in ulcerative colitis (UC). Similarly, SLC5A8 mRNA expression was significantly reduced in the CRC as well as the IBS groups. In the IBD groups, SLC5A8 was unchanged in UC but significantly increased in CD. IL-17 mRNA expression was significantly reduced in CRC and IBS groups, but unchanged in the IBD groups. PKCε mRNA was significantly increased in CRC as expected. In the IBD groups, PKCε mRNA was unchanged in CD but significantly increased in UC. In the IBS groups, PKCε mRNA in constipation –IBS (C-IBS) was significantly reduced, but unchanged in diarrhoea – IBS (D-IBS). CONCLUSIONS: β-catenin mRNA and protein expression was increased in CRC and the CRC promoting IBD groups. COX-2 protein expression was incongruent with the COX-2 mRNA expression and this may reflect homeostatic control mechanisms. High COX-2 mRNA expression in CRC and CRC promoting IBD groups may be a secondary phenomenon reflecting the inflammatory milieu, rather than a true carcinogenesis-related event. PPARγ does not appear to play a central role in early colon carcinogenesis, in spite of available literature suggesting otherwise. Butyrate transporters showed inconsistent results and for now no firm conclusions can be drawn from this. IL-17 may play a role in CAC as confirmed in this and other studies, but its role in sporadic CRC is tenuous and requires further investigation. Likewise for PKCε, upregulation is associated with increased tumourigenecity as shown in this study, however, the mechanistic pathway(s) involved is still speculative and requires further study.
- Full Text:
- Date Issued: 2013
Monitoring carbon stocks in the sub-tropical thicket biome using remote sensing and GIS techniques : the case of the Great Fish River Nature Reserve and its environs, Eastern Cape province, South Africa
- Authors: Nyamugama, Adolph
- Date: 2013
- Subjects: Fragmented landscapes -- South Africa -- Eastern Cape -- Remote sensing , Environmental degradation -- South Africa -- Eastern Cape , Remote sensing , Geographic information systems
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10672 , http://hdl.handle.net/10948/d1020303
- Description: The subtropical thicket biome in the Eastern Cape Province of South Africa has been heavily degraded and transformed due overutilization during the last century. The highly degraded and transformed areas exhibit a significant loss of above ground carbon stocks (AGC) and loss of SOC content. Information about land use /cover change and fragmentation dynamics is a prerequisite for measuring carbon stock changes. The main aim of this study is to assess the trends of land use/cover change, fragmentation dynamics, model the temporal changes of AGC stocks in the Great Fish River Nature Reserve and its environs from 1972 to 2010, quantify and map the spatial distribution of SOC concentrations in the partial subtropical thicket cover in the Great Fish River Nature Reserve and environs (communal rangelands). Multi-temporal analyses based on 1972 Landsat MSS, 1982 and 1992 Landsat TM, 2002 Landsat ETM and 2010 SPOT 5 High Resolution images were used for land use/cover change detection and fragmentation analysis. Object oriented post-classification comparison was applied for land use/cover change detection analysis. Fragmentation dynamics analysis was carried out by computing and analyzing landscape metrics in land use/cover classes. Landscape fragmentation analyses revealed that thicket vegetation has increasingly become fragmented, characterized by smaller less linked patches of intact thicket cover. Landscape metrics for intact thicket and degraded thicket classes reflected fragmentation, as illustrated by the increase in the Number of Patches (NP), Patch Density (PD), Landscape Shape Index (LSI), and a decrease in Mean Patch Size (MPS). The use of remote sensing techniques and landscape metrics was vital for the understanding of the dynamics of land use/cover change and fragmentation. Baseline land use/cover maps produced for 1972, 1982, 1992 2002 and 2010 and fragmentation analyses were then used for analyzing carbon stock changes in the study area. To model the temporal changes of AGC stocks in the Great Fish River Nature Reserve and its environs from 1972 to 2010, a method based on the integration of RS and GIS was employed for the estimation of AGC stocks in a time series. A non-linear regression model was developed using NDVI values generated from SPOT 5 HRG satellite imagery of 2010 as the independent variable and AGC stock estimates from field plots as the dependent variable. The regression model was used to estimate AGC stocks for the entire study area on the 2010 SPOT 5 HRG and also extrapolated to the 1972 Landsat MSS, 1982 and 1992 Landsat TM, and 2002 Landsat ETM. The AGC stocks for the period 1972 -1982, 1982-1992, 1992-200) and 2002-2010 were compared by means of change detection analysis. The comparison of AGC stocks was carried out at subtropical thicket class level. The results showed a decline of AGC stocks in all the classes from 1972 to 2010. Degraded and transformed thicket classes had the highest AGC stock losses. The decline of AGC stocks was attributed to thicket transformation and degradation which were caused by anthropogenic activities. To map and quantify SOC concentration in partial (fractional) thicket vegetation cover, the spectral reflectance of both thicket vegetation and bare-soils was measured in situ. Soil samples were collected from the sampling sites and transported to the laboratory for spectral reflectance and SOC measurements. Thicket vegetation and bare soil reflectance were measured using spectroscopy both in situ and under laboratory conditions. Their respective endmembers were extracted from ASTER imagery using the Pixel Purity Index (PPI). The endmembers were validated with in situ and laboratory thicket and bare-soil reflectance signatures. The spectral unmixing technique was applied to ASTER imagery to discriminate pure pixels of thicket vegetation and bare-soils; a residual spectral image was produced. The Residual Spectral Unmixing (RSU) procedure was applied to the residual spectral image to produce an RSU soil spectrum image. Partial Least Squares Regression (PSLR) model was developed using spectral signatures of a residual soil spectrum image as the independent variable and SOC concentration measured from soil samples as the dependent variable. The PSLR prediction model was used to predict SOC concentration on the RSU soil spectral image. The predicted SOC concentration was then validated with SOC concentration measured from the field plots. A Strong correlation (R2 = 0.82) was obtained between the predicted SOC concentration and the SOC concentration measured from field samples. The PSLR was then used to generate a map of SOC concentration for the Great Fish River Nature Reserve and its environs. Areas with very low SOC concentrations were found in the degraded communal villages, as opposed to the higher SOC values in the protected area. The results confirmed that RS techniques are key to estimating and mapping the spatial distribution of SOC concentration in partial subtropical thicket vegetation. Partial thicket vegetation has a huge influence on the soil spectra; it can influence the prediction of SOC concentration. The use of the RSU approach eliminates partial thicket vegetation cover from bare soil spectra. The residual soil spectrum image contains enough information for the mapping of SOC concentration. The technique has the potential to augment the applicability of airborne imaging spectroscopy for soil studies in the sub-tropical thicket biome and similar environments.
- Full Text:
- Date Issued: 2013
- Authors: Nyamugama, Adolph
- Date: 2013
- Subjects: Fragmented landscapes -- South Africa -- Eastern Cape -- Remote sensing , Environmental degradation -- South Africa -- Eastern Cape , Remote sensing , Geographic information systems
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10672 , http://hdl.handle.net/10948/d1020303
- Description: The subtropical thicket biome in the Eastern Cape Province of South Africa has been heavily degraded and transformed due overutilization during the last century. The highly degraded and transformed areas exhibit a significant loss of above ground carbon stocks (AGC) and loss of SOC content. Information about land use /cover change and fragmentation dynamics is a prerequisite for measuring carbon stock changes. The main aim of this study is to assess the trends of land use/cover change, fragmentation dynamics, model the temporal changes of AGC stocks in the Great Fish River Nature Reserve and its environs from 1972 to 2010, quantify and map the spatial distribution of SOC concentrations in the partial subtropical thicket cover in the Great Fish River Nature Reserve and environs (communal rangelands). Multi-temporal analyses based on 1972 Landsat MSS, 1982 and 1992 Landsat TM, 2002 Landsat ETM and 2010 SPOT 5 High Resolution images were used for land use/cover change detection and fragmentation analysis. Object oriented post-classification comparison was applied for land use/cover change detection analysis. Fragmentation dynamics analysis was carried out by computing and analyzing landscape metrics in land use/cover classes. Landscape fragmentation analyses revealed that thicket vegetation has increasingly become fragmented, characterized by smaller less linked patches of intact thicket cover. Landscape metrics for intact thicket and degraded thicket classes reflected fragmentation, as illustrated by the increase in the Number of Patches (NP), Patch Density (PD), Landscape Shape Index (LSI), and a decrease in Mean Patch Size (MPS). The use of remote sensing techniques and landscape metrics was vital for the understanding of the dynamics of land use/cover change and fragmentation. Baseline land use/cover maps produced for 1972, 1982, 1992 2002 and 2010 and fragmentation analyses were then used for analyzing carbon stock changes in the study area. To model the temporal changes of AGC stocks in the Great Fish River Nature Reserve and its environs from 1972 to 2010, a method based on the integration of RS and GIS was employed for the estimation of AGC stocks in a time series. A non-linear regression model was developed using NDVI values generated from SPOT 5 HRG satellite imagery of 2010 as the independent variable and AGC stock estimates from field plots as the dependent variable. The regression model was used to estimate AGC stocks for the entire study area on the 2010 SPOT 5 HRG and also extrapolated to the 1972 Landsat MSS, 1982 and 1992 Landsat TM, and 2002 Landsat ETM. The AGC stocks for the period 1972 -1982, 1982-1992, 1992-200) and 2002-2010 were compared by means of change detection analysis. The comparison of AGC stocks was carried out at subtropical thicket class level. The results showed a decline of AGC stocks in all the classes from 1972 to 2010. Degraded and transformed thicket classes had the highest AGC stock losses. The decline of AGC stocks was attributed to thicket transformation and degradation which were caused by anthropogenic activities. To map and quantify SOC concentration in partial (fractional) thicket vegetation cover, the spectral reflectance of both thicket vegetation and bare-soils was measured in situ. Soil samples were collected from the sampling sites and transported to the laboratory for spectral reflectance and SOC measurements. Thicket vegetation and bare soil reflectance were measured using spectroscopy both in situ and under laboratory conditions. Their respective endmembers were extracted from ASTER imagery using the Pixel Purity Index (PPI). The endmembers were validated with in situ and laboratory thicket and bare-soil reflectance signatures. The spectral unmixing technique was applied to ASTER imagery to discriminate pure pixels of thicket vegetation and bare-soils; a residual spectral image was produced. The Residual Spectral Unmixing (RSU) procedure was applied to the residual spectral image to produce an RSU soil spectrum image. Partial Least Squares Regression (PSLR) model was developed using spectral signatures of a residual soil spectrum image as the independent variable and SOC concentration measured from soil samples as the dependent variable. The PSLR prediction model was used to predict SOC concentration on the RSU soil spectral image. The predicted SOC concentration was then validated with SOC concentration measured from the field plots. A Strong correlation (R2 = 0.82) was obtained between the predicted SOC concentration and the SOC concentration measured from field samples. The PSLR was then used to generate a map of SOC concentration for the Great Fish River Nature Reserve and its environs. Areas with very low SOC concentrations were found in the degraded communal villages, as opposed to the higher SOC values in the protected area. The results confirmed that RS techniques are key to estimating and mapping the spatial distribution of SOC concentration in partial subtropical thicket vegetation. Partial thicket vegetation has a huge influence on the soil spectra; it can influence the prediction of SOC concentration. The use of the RSU approach eliminates partial thicket vegetation cover from bare soil spectra. The residual soil spectrum image contains enough information for the mapping of SOC concentration. The technique has the potential to augment the applicability of airborne imaging spectroscopy for soil studies in the sub-tropical thicket biome and similar environments.
- Full Text:
- Date Issued: 2013
Nonlinear effects with a focus on cross phase modulation and its impact on wavelength division multiplexing optical fibre networks
- Gamatham, Romeo Reginald Gunther
- Authors: Gamatham, Romeo Reginald Gunther
- Date: 2013
- Subjects: Wavelength division multiplexing , Optical communications , Fiber optics
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/6302 , vital:21071
- Description: The demand for faster data transmission is ever increasing. Wavelength division multiplexing (WDM) presents as a viable solution to increase the data transmission rate significantly. WDM systems are based on the ability to transmit multiple wavelengths simultaneously down the fibre. Unlike time division multiplexing (TDM) systems, WDM systems do not increase the data transfer by increasing the transmission rate of a single channel. In WDM systems the data rate per channel remains the same, only multiple channels carry data across the link. Dense wavelength division multiplexing (DWDM) promises even more wavelengths packed together in the same fibre. This multiplication of channels increases the bandwidth capacity rapidly. Networks are looking into making use of technology that will ensure no electronic signal regeneration at any point within the DWDM network. Examples are; reconfigurable optical add/drop multiplexers (ROADM) and optical cross connect (OXC) units. These components essentially enable network operators to split, combine and multiplex optical signals carried by optical fibre. WDM allows network operators to increase the capacity of existing networks without expensive re-cabling. This provides networks with the flexibility to be upgraded to larger bandwidths and for reconfiguration of network services. Further, WDM technology opens up an opportunity of marketing flexibility to network operators, where operators not only have the option to rent out cables and fibres but wavelengths as well. Cross phase modulation (XPM) poses a problem to WDM networks. The refractive index experienced by a neighbouring optical signal, not only depends on the signal’s intensity but on the intensity of the co-propagating signal as well. This effect leads to a phase change and is known as XPM. This work investigates the characteristics of XPM. It is shown that, in a two channel WDM network, a probe signal’s SOP can be steered by controlling a high intensity pump signal’s SOP. This effect could be applied to make a wavelength converter. Experimental results show that the degree of polarization (DOP) of a probe signal degrades according to a mathematical model found in literature. The pump and probe signals are shown to experience maximum interaction, for orthogonal probe-pump SOP vector orientations. This may be problematic to polarization mode dispersion compensators. Additionally, experimental results point out that the SOP of a probe signal is much more active in the presence of a high intensity pump, as compared to the single signal transmission scenario.
- Full Text:
- Date Issued: 2013
- Authors: Gamatham, Romeo Reginald Gunther
- Date: 2013
- Subjects: Wavelength division multiplexing , Optical communications , Fiber optics
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/6302 , vital:21071
- Description: The demand for faster data transmission is ever increasing. Wavelength division multiplexing (WDM) presents as a viable solution to increase the data transmission rate significantly. WDM systems are based on the ability to transmit multiple wavelengths simultaneously down the fibre. Unlike time division multiplexing (TDM) systems, WDM systems do not increase the data transfer by increasing the transmission rate of a single channel. In WDM systems the data rate per channel remains the same, only multiple channels carry data across the link. Dense wavelength division multiplexing (DWDM) promises even more wavelengths packed together in the same fibre. This multiplication of channels increases the bandwidth capacity rapidly. Networks are looking into making use of technology that will ensure no electronic signal regeneration at any point within the DWDM network. Examples are; reconfigurable optical add/drop multiplexers (ROADM) and optical cross connect (OXC) units. These components essentially enable network operators to split, combine and multiplex optical signals carried by optical fibre. WDM allows network operators to increase the capacity of existing networks without expensive re-cabling. This provides networks with the flexibility to be upgraded to larger bandwidths and for reconfiguration of network services. Further, WDM technology opens up an opportunity of marketing flexibility to network operators, where operators not only have the option to rent out cables and fibres but wavelengths as well. Cross phase modulation (XPM) poses a problem to WDM networks. The refractive index experienced by a neighbouring optical signal, not only depends on the signal’s intensity but on the intensity of the co-propagating signal as well. This effect leads to a phase change and is known as XPM. This work investigates the characteristics of XPM. It is shown that, in a two channel WDM network, a probe signal’s SOP can be steered by controlling a high intensity pump signal’s SOP. This effect could be applied to make a wavelength converter. Experimental results show that the degree of polarization (DOP) of a probe signal degrades according to a mathematical model found in literature. The pump and probe signals are shown to experience maximum interaction, for orthogonal probe-pump SOP vector orientations. This may be problematic to polarization mode dispersion compensators. Additionally, experimental results point out that the SOP of a probe signal is much more active in the presence of a high intensity pump, as compared to the single signal transmission scenario.
- Full Text:
- Date Issued: 2013
Sedimentology and sequence stratigraphy of the Congo and Kalahari basins of South Central Africa and their evolution during the formation and break-up of West Gondwana
- Authors: Linol, Bastien
- Date: 2013
- Subjects: Sedimentary basins -- Africa , Sedimentology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10655 , http://hdl.handle.net/10948/d1012148 , Sedimentary basins -- Africa , Sedimentology
- Description: The high elevated (ca. 1100 m) continental Kalahari Basin (KB) of southern Africa and the linked lower lying (ca. 400 m) Congo Basin (CB) of central Africa preserve in their interiors extensive sedimentary rock sequences and sediments that represent a unique record of the Phanerozoic geodynamic and climatic evolution of sub-Saharan Africa. In this thesis, field observations and new borehole data from the Democratic Republic of Congo (DRC) and Botswana are integrated with new paleontology and geochronology to present a substantially revised stratigraphy for the CB, and south-central Africa in general. This work also introduces a new multiphase model for the subsidence and uplift history of the CB, and improves correlations with the Cape-Karoo Basin (CKB) of South Africa and the Paraná Basin (PB) of south-east Brazil. Four deep boreholes, each between 2 and 4.5 km deep, drilled in the centre of the CB in the 1950’s and 1970’s are re-examined together with the colonial literature (in French) and available seismic data. This stratigraphic and basin analysis is complemented with new U-Pb dates of detrital zircons from core-samples of two of the boreholes (Samba and Dekese), as well as from samples collected during field work in the Kwango region of the south-west DRC. This work, for the first time, constrains the maximum ages and source provenances of the successions in the CB. Following the Pan African orogens (ca. 650-530 Ma), extensive sequences of red beds were deposited by regional paleocurrents to the south. These are now best preserved (1 km thick) along the West Congo, Oubanguides, and Lufilian Belts surrounding the CB. Overlying a hiatus that represents most of the early-Paleozoic, is a 1 to 3 km thick succession of easterly derived glacial, and then continental sequences of the Karoo Supergroup. This succession records the first main episode of subsidence [10-15 m/Ma], interrupted by a phase of uplift that is likely related to far-field intracontinental deformation within Gondwana supercontinent during the Variscan and Cape Fold orogenies (ca. 250-330 Ma) at its peripheries. Detrital zircons from the lower Karoo diamictites are dated at 1.85-2.05 Ga and 1.37- 1.42 Ga, and thus sourced from Paleoproterozoic (Eburnean) and mid-Mesoproterozoic (Kibaran type-I) basement rocks in Uganda and Tanzania. Zircons from all the other successions in the CB date predominantly at 950-1050 Ma and 500-800 Ma. These are derived from sediment recycling of late-Mesoproterozoic (Kibaran type-II) and late- Neoproterozoic (Pan African) sources in the Central African Republic (CAR) and Chad. A distinct unconformity across the Karoo Supergroup in the CB is overlain by 500- 1000 m Jurassic-Cretaceous sequences, here named the Congo Supergroup. During initial rapid subsidence [10-50 m/Ma], late-Jurassic (Kimmeridgian) shallow marine to continental sedimentation attests to a short transgression of proto-Indian Ocean waters into the northern CB (at 160 m above present day sea-level), succeeded by widespread deposition of aeolian dunes that extend from the southern CB to the PB in South America. The youngest zircons from these aeolian sediments in the CB date at 190 Ma and 240-290 Ma, and most likely indicate the influence of extensive silicic volcanic ash derived from the proto-Andes along the south-western margin of Gondwana. Two superimposed mid-Cretaceous (Albian-Cenomanian) lacustrine sequences in the central CB record a succeeding, slower [10-15 m/Ma], phase of basin subsidence during the opening of the South Atlantic (ca. 85-135 Ma). These Cretaceous sequences are in turn truncated by another regional peneplanation surface covered by Cenozoic (Eocene) silcretized sands and alluviums of the Kalahari Group, only 50-250 m thick in the centre of the CB. Southward, on top of the Kalahari Plateau in the central desert region of north-west Botswana, new boreholes intercepted laterally equivalent condensed lacustrine carbonates and calcretes (20-50 m thick) covered by sands. These terrestrial sequences are key archives of late-Mesozoic – Cenozoic paleo-climate changes, yet they remain stratigraphically unresolved. This new analysis of the Phanerozoic continental basins of south-central Africa and their equivalents in South America, opens a fresh continental-scale window into how West Gondwana break-up and concomitant epeirogenic uplifts of Kalahari (>2 km) and Congo (>200 m) are linked to interactions between the lithosphere and mantle geodynamics, and how these processes likely affected global climate changes.
- Full Text:
- Date Issued: 2013
- Authors: Linol, Bastien
- Date: 2013
- Subjects: Sedimentary basins -- Africa , Sedimentology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10655 , http://hdl.handle.net/10948/d1012148 , Sedimentary basins -- Africa , Sedimentology
- Description: The high elevated (ca. 1100 m) continental Kalahari Basin (KB) of southern Africa and the linked lower lying (ca. 400 m) Congo Basin (CB) of central Africa preserve in their interiors extensive sedimentary rock sequences and sediments that represent a unique record of the Phanerozoic geodynamic and climatic evolution of sub-Saharan Africa. In this thesis, field observations and new borehole data from the Democratic Republic of Congo (DRC) and Botswana are integrated with new paleontology and geochronology to present a substantially revised stratigraphy for the CB, and south-central Africa in general. This work also introduces a new multiphase model for the subsidence and uplift history of the CB, and improves correlations with the Cape-Karoo Basin (CKB) of South Africa and the Paraná Basin (PB) of south-east Brazil. Four deep boreholes, each between 2 and 4.5 km deep, drilled in the centre of the CB in the 1950’s and 1970’s are re-examined together with the colonial literature (in French) and available seismic data. This stratigraphic and basin analysis is complemented with new U-Pb dates of detrital zircons from core-samples of two of the boreholes (Samba and Dekese), as well as from samples collected during field work in the Kwango region of the south-west DRC. This work, for the first time, constrains the maximum ages and source provenances of the successions in the CB. Following the Pan African orogens (ca. 650-530 Ma), extensive sequences of red beds were deposited by regional paleocurrents to the south. These are now best preserved (1 km thick) along the West Congo, Oubanguides, and Lufilian Belts surrounding the CB. Overlying a hiatus that represents most of the early-Paleozoic, is a 1 to 3 km thick succession of easterly derived glacial, and then continental sequences of the Karoo Supergroup. This succession records the first main episode of subsidence [10-15 m/Ma], interrupted by a phase of uplift that is likely related to far-field intracontinental deformation within Gondwana supercontinent during the Variscan and Cape Fold orogenies (ca. 250-330 Ma) at its peripheries. Detrital zircons from the lower Karoo diamictites are dated at 1.85-2.05 Ga and 1.37- 1.42 Ga, and thus sourced from Paleoproterozoic (Eburnean) and mid-Mesoproterozoic (Kibaran type-I) basement rocks in Uganda and Tanzania. Zircons from all the other successions in the CB date predominantly at 950-1050 Ma and 500-800 Ma. These are derived from sediment recycling of late-Mesoproterozoic (Kibaran type-II) and late- Neoproterozoic (Pan African) sources in the Central African Republic (CAR) and Chad. A distinct unconformity across the Karoo Supergroup in the CB is overlain by 500- 1000 m Jurassic-Cretaceous sequences, here named the Congo Supergroup. During initial rapid subsidence [10-50 m/Ma], late-Jurassic (Kimmeridgian) shallow marine to continental sedimentation attests to a short transgression of proto-Indian Ocean waters into the northern CB (at 160 m above present day sea-level), succeeded by widespread deposition of aeolian dunes that extend from the southern CB to the PB in South America. The youngest zircons from these aeolian sediments in the CB date at 190 Ma and 240-290 Ma, and most likely indicate the influence of extensive silicic volcanic ash derived from the proto-Andes along the south-western margin of Gondwana. Two superimposed mid-Cretaceous (Albian-Cenomanian) lacustrine sequences in the central CB record a succeeding, slower [10-15 m/Ma], phase of basin subsidence during the opening of the South Atlantic (ca. 85-135 Ma). These Cretaceous sequences are in turn truncated by another regional peneplanation surface covered by Cenozoic (Eocene) silcretized sands and alluviums of the Kalahari Group, only 50-250 m thick in the centre of the CB. Southward, on top of the Kalahari Plateau in the central desert region of north-west Botswana, new boreholes intercepted laterally equivalent condensed lacustrine carbonates and calcretes (20-50 m thick) covered by sands. These terrestrial sequences are key archives of late-Mesozoic – Cenozoic paleo-climate changes, yet they remain stratigraphically unresolved. This new analysis of the Phanerozoic continental basins of south-central Africa and their equivalents in South America, opens a fresh continental-scale window into how West Gondwana break-up and concomitant epeirogenic uplifts of Kalahari (>2 km) and Congo (>200 m) are linked to interactions between the lithosphere and mantle geodynamics, and how these processes likely affected global climate changes.
- Full Text:
- Date Issued: 2013
Single-end reflectometric measurements of polarization-mode dispersion in single-mode optical fibres
- Authors: Fosuhene, Samuel Kofi
- Date: 2013
- Subjects: Fiber optics , Polarization (Light) , Optical measurements
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/6280 , vital:21069
- Description: In this thesis two novel single-end methods are applied to measure and characterize polarization mode dispersion in single mode optical fibres. Polarization mode dispersion (PMD) is an important factor negatively affecting the successful implementation of high speed long haul optical fibre networks operating at bit rates of 10Gb/s and above. PMD measurements are thus important for quality control during manufacturing and cabling processes. It is also useful for network operators planning to upgrade bitrates in existing networks to 10Gb/s and beyond. In an optical fibre link, sections with particularly high PMD may act to increase the entire PMD of the link. Identifying and replacing such sections can greatly reduce the PMD of the link. PMD measurements can be forward or single-end. In forward measurements, both ends of the fibre are used for input and detection. In single-end configuration, only one end of the fibre is used. For this reason, single-end measurements are more practical for the field where fibre ends are situated several kilometres apart. Single-end techniques can be implemented with a continuous wave for non-local PMD measurements (by Fresnel reflection). If a pulsed wave is used, local measurements can be achieved (by total power due to Rayleigh scattering). Two single-end schemes, one based on Fresnel reflection and the other due to Rayleigh scattering have been applied to measure non-local and local PMD of standard single mode optical fibres. For the non-local PMD measurements, the general interferometric technique (GINTY) was modified to operate in a round-trip configuration. In this configuration, the fibre was treated as a concatenation of two identical fibre segments. Three different sets of fibres were investigated, each set representing a particular mode coupling regime. For polarization maintaining fibres, (PMFs), with no mode coupling, a factor of two was found between forward and single-end measurements. For long single mode fibres in the long length regime, the factor was 1.4. For a combination of PMF and single mode fibres, a factor of 1.6 was obtained. The method which is accurate, repeatable, low cost and robust is very suitable for field applications. The second method is the polarization optical time domain reflectometric (P-OTDR) technique. This technique performs local birefringence measurements by measuring the evolution of the states of polarization (SOP). The birefringence information from such measurements was extracted and analysed to characterise four different fibres. Beat lengths and correlation lengths extracted from the P-OTDR were used to calculate the differential group delay (DGD) of the fibres. Next an expression for the root-mean-square differential group delay was derived and applied to the birefringence measurements to calculate the DGDs at a single wavelength. This method which operates at a single wavelength has a huge advantage. Firstly it is able to measure completely all the fibre characteristic parameters. Secondly it can measure mean DGD, root mean square DGD and instantaneous DGD. A plot of instantaneous DGD vs. length enables one to identify and eliminate sections with particularly high DGD. Finally since the P-OTDR system operates with a single wavelength, real time monitoring of PMD is possible via multiplexing. The results obtained are repeatable, accurate and are in good agreement with the standard Jones Matrix Eigenanalysis (JME) technique.
- Full Text:
- Date Issued: 2013
Single-end reflectometric measurements of polarization-mode dispersion in single-mode optical fibres
- Authors: Fosuhene, Samuel Kofi
- Date: 2013
- Subjects: Fiber optics , Polarization (Light) , Optical measurements
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/6280 , vital:21069
- Description: In this thesis two novel single-end methods are applied to measure and characterize polarization mode dispersion in single mode optical fibres. Polarization mode dispersion (PMD) is an important factor negatively affecting the successful implementation of high speed long haul optical fibre networks operating at bit rates of 10Gb/s and above. PMD measurements are thus important for quality control during manufacturing and cabling processes. It is also useful for network operators planning to upgrade bitrates in existing networks to 10Gb/s and beyond. In an optical fibre link, sections with particularly high PMD may act to increase the entire PMD of the link. Identifying and replacing such sections can greatly reduce the PMD of the link. PMD measurements can be forward or single-end. In forward measurements, both ends of the fibre are used for input and detection. In single-end configuration, only one end of the fibre is used. For this reason, single-end measurements are more practical for the field where fibre ends are situated several kilometres apart. Single-end techniques can be implemented with a continuous wave for non-local PMD measurements (by Fresnel reflection). If a pulsed wave is used, local measurements can be achieved (by total power due to Rayleigh scattering). Two single-end schemes, one based on Fresnel reflection and the other due to Rayleigh scattering have been applied to measure non-local and local PMD of standard single mode optical fibres. For the non-local PMD measurements, the general interferometric technique (GINTY) was modified to operate in a round-trip configuration. In this configuration, the fibre was treated as a concatenation of two identical fibre segments. Three different sets of fibres were investigated, each set representing a particular mode coupling regime. For polarization maintaining fibres, (PMFs), with no mode coupling, a factor of two was found between forward and single-end measurements. For long single mode fibres in the long length regime, the factor was 1.4. For a combination of PMF and single mode fibres, a factor of 1.6 was obtained. The method which is accurate, repeatable, low cost and robust is very suitable for field applications. The second method is the polarization optical time domain reflectometric (P-OTDR) technique. This technique performs local birefringence measurements by measuring the evolution of the states of polarization (SOP). The birefringence information from such measurements was extracted and analysed to characterise four different fibres. Beat lengths and correlation lengths extracted from the P-OTDR were used to calculate the differential group delay (DGD) of the fibres. Next an expression for the root-mean-square differential group delay was derived and applied to the birefringence measurements to calculate the DGDs at a single wavelength. This method which operates at a single wavelength has a huge advantage. Firstly it is able to measure completely all the fibre characteristic parameters. Secondly it can measure mean DGD, root mean square DGD and instantaneous DGD. A plot of instantaneous DGD vs. length enables one to identify and eliminate sections with particularly high DGD. Finally since the P-OTDR system operates with a single wavelength, real time monitoring of PMD is possible via multiplexing. The results obtained are repeatable, accurate and are in good agreement with the standard Jones Matrix Eigenanalysis (JME) technique.
- Full Text:
- Date Issued: 2013
Structural analysis of synthetic ferrihydrite nanoparticles and its reduction in a hydrogen atmosphere
- Authors: Masina, Colani John
- Date: 2013
- Subjects: Ferric hydroxides , Minerals -- Analysis , Nanoparticles
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10555 , http://hdl.handle.net/10948/d1020796
- Description: Ferrihydrite (FHYD), a nanocrystalline material has long been described as a poorly crystalline disordered mineral mainly due to its small crystal size which is typically 2−6 𝑛𝑚. The three-dimensional structure of the mineral has long been described by a multi-phase structural model that consists of Fe3+ only in octahedral (Oh) coordination. In this model ferrihydrite is described as a mixture of two major phases (akaganeite/goethite-like f-phase and feroxyhite-like d-phase) and a minor ultradispersed nanohematite phase. This model has been recently challenged and a new, single-phase model was proposed, having a basic structural motif closely related to the Baker-Figgs δ-Keggin cluster and is isostructural with the mineral akdalaite, Al10O14(OH)2. In its ideal form, the proposed new structure of FHYD consist of 80 % Oh and 20 % tetrahedral (Td) Fe3+ polyhedra which can be adequately described by a single-domain model with the hexagonal spacegroup 𝑃63𝑚𝑐 and unit cell dimensions 𝑎=5.95 Å and 𝑐=9.06 Å. In this study, nanoparticles of 2-line FHYD (FHYD2), 2-line FHYD deposited onto SiO2 (FHYD2/SiO2) and 6-line FHYD (FHYD6) synthesised using rapid hydrolysis of Fe(NO3)3.9H2O solutions were characterized using X-ray diffraction (XRD), Raman spectroscopy, transmission electron microscopy (TEM), Mössbauer spectroscopy (MS) as well as magnetization and magnetic susceptibility measurements. The coordination environment of iron atoms in the structure of FHYD was investigated using TEM and MS. The thermal transformation of FHYD nanoparticles was monitored through changes in the magnetization as a function of temperature and the reduction behaviour in hydrogen environment was studied using temperature programmed reduction (TPR), in-situ XRD and MS. Electron diffraction, TEM/ scanning TEM (STEM) imaging, and electron energy loss (EELS) measurements were carried out on three different microscopes viz. JEOL JEM-2100 LaB6 TEM, aberration corrected Schottky-FEG JEOL JEM-ARM200F HRTEM and cold-FEG Zeiss SESAM TEM. EELS studies were concentrated mainly on the iron 𝐿-edge of FHYD and iron oxides reference spectra with well known crystal structures. The iron oxide Fe 𝐿-edge is usually characterized by two intense sharp peaks termed “white lines”. The fine structures introduced by the crystal field effect on the 𝐿- edge contain information that is highly specific to the Fe3+ site symmetry.
- Full Text:
- Date Issued: 2013
- Authors: Masina, Colani John
- Date: 2013
- Subjects: Ferric hydroxides , Minerals -- Analysis , Nanoparticles
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10555 , http://hdl.handle.net/10948/d1020796
- Description: Ferrihydrite (FHYD), a nanocrystalline material has long been described as a poorly crystalline disordered mineral mainly due to its small crystal size which is typically 2−6 𝑛𝑚. The three-dimensional structure of the mineral has long been described by a multi-phase structural model that consists of Fe3+ only in octahedral (Oh) coordination. In this model ferrihydrite is described as a mixture of two major phases (akaganeite/goethite-like f-phase and feroxyhite-like d-phase) and a minor ultradispersed nanohematite phase. This model has been recently challenged and a new, single-phase model was proposed, having a basic structural motif closely related to the Baker-Figgs δ-Keggin cluster and is isostructural with the mineral akdalaite, Al10O14(OH)2. In its ideal form, the proposed new structure of FHYD consist of 80 % Oh and 20 % tetrahedral (Td) Fe3+ polyhedra which can be adequately described by a single-domain model with the hexagonal spacegroup 𝑃63𝑚𝑐 and unit cell dimensions 𝑎=5.95 Å and 𝑐=9.06 Å. In this study, nanoparticles of 2-line FHYD (FHYD2), 2-line FHYD deposited onto SiO2 (FHYD2/SiO2) and 6-line FHYD (FHYD6) synthesised using rapid hydrolysis of Fe(NO3)3.9H2O solutions were characterized using X-ray diffraction (XRD), Raman spectroscopy, transmission electron microscopy (TEM), Mössbauer spectroscopy (MS) as well as magnetization and magnetic susceptibility measurements. The coordination environment of iron atoms in the structure of FHYD was investigated using TEM and MS. The thermal transformation of FHYD nanoparticles was monitored through changes in the magnetization as a function of temperature and the reduction behaviour in hydrogen environment was studied using temperature programmed reduction (TPR), in-situ XRD and MS. Electron diffraction, TEM/ scanning TEM (STEM) imaging, and electron energy loss (EELS) measurements were carried out on three different microscopes viz. JEOL JEM-2100 LaB6 TEM, aberration corrected Schottky-FEG JEOL JEM-ARM200F HRTEM and cold-FEG Zeiss SESAM TEM. EELS studies were concentrated mainly on the iron 𝐿-edge of FHYD and iron oxides reference spectra with well known crystal structures. The iron oxide Fe 𝐿-edge is usually characterized by two intense sharp peaks termed “white lines”. The fine structures introduced by the crystal field effect on the 𝐿- edge contain information that is highly specific to the Fe3+ site symmetry.
- Full Text:
- Date Issued: 2013
The contribution of submerged macrophytes and macroalgae to nutrient cycling in the Great Brak Estuary
- Authors: Human, Lucienne Ryno Daniel
- Date: 2013
- Subjects: Nutrient cycles -- South Africa -- Great Brak Estuary , Microalgae -- South Africa -- Great Brak Estuary , Estuarine ecology -- South Africa -- Great Brak Estuary
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10364 , http://hdl.handle.net/10948/d1021102
- Description: An ecological reserve study by the Department of Water Affairs on the Great Brak Estuary stated that there was a need to determine how much nitrogen and phosphorus was flowing through the estuary as well as how effective the macroalgae were at removing N and P. The objective of this study was to investigate the physico-chemical characteristics in the estuary and the influence of these on the submerged macrophytes and macroalgae. A nutrient budget for the estuary was developed in order to quantify the contribution of the submerged macrophytes and macroalgae relative to other contributing sources. The Wolwedans Dam located 3 km upstream from the estuary has reduced the amount of freshwater flow to the estuary by as much as 56 percent. The estuary has been allocated 2 x 106 m3 per annum of freshwater (ecological reserve) that is used to breach the mouth once or twice a year in spring or summer. Even though this water has been made available it is not sufficient to flush the estuary. Reduced flushing has led to an accumulation of organic matter and degradation in the water quality. Physico-chemical measurements between September 2010 and July 2012 showed that dissolved oxygen values were generally below 6 mg l-1. The average NH4+ concentration in the estuary was 7 μM and increased with depth to 12 μM at 2 m depths. Concentrations >45 μM were found in February and April 2011 at the 5 m deep hole at 3.4 km upstream. Negative correlations between dissolved oxygen and NH4+ during November 2010, February 2011, April 2011 and July 2011 (r = -0.68; -0.67; -0.63; -0.96) indicated that remineralisation of organic matter had occurred. Soluble reactive phosphorus (SRP) followed a similar trend to the NH4+ and was generally below 1 μM in the water column for most months, and had peaks at 1.0 km and 3.4 km in the bottom water. The abundance of submerged macrophytes and macroalgae below the N2 bridge were mostly influenced by mouth state and river inflow. During the closed phase the dominant macroalga Cladophora glomerata had an area cover ranging from 3000 to 6000 m2 while Zostera capensis and Ruppia cirrhosa covered an area of 2000 to 3500 m2 and 1500 to 2900 m2, respectively. After an artificial breach in February 2011, water drained out of the estuary leaving the alga stranded on the marshes and as the flood tide entered the macroalga was once again redistributed in the lower reaches. The alga utilised the available nutrients in the water column and expanded its area cover from 35000 m2 in February 2011 to 64000 m2 in March 2011. However, after the floods in June 2011, Cladophora glomerata had been washed out of the system while the submerged macrophytes responded positively extending their area cover. By comparing the artificial breach with the natural breach, and the effect on the estuary, an important observation was highlighted. Increasing the current allocated ecological reserve, and using a larger volume of water to breach the mouth artificially, would result in better scouring of sediment and associated organic matter out of the estuary. This would enable better oxygenation of the water column, reduce remineralisation and minimise algal blooms.
- Full Text:
- Date Issued: 2013
- Authors: Human, Lucienne Ryno Daniel
- Date: 2013
- Subjects: Nutrient cycles -- South Africa -- Great Brak Estuary , Microalgae -- South Africa -- Great Brak Estuary , Estuarine ecology -- South Africa -- Great Brak Estuary
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10364 , http://hdl.handle.net/10948/d1021102
- Description: An ecological reserve study by the Department of Water Affairs on the Great Brak Estuary stated that there was a need to determine how much nitrogen and phosphorus was flowing through the estuary as well as how effective the macroalgae were at removing N and P. The objective of this study was to investigate the physico-chemical characteristics in the estuary and the influence of these on the submerged macrophytes and macroalgae. A nutrient budget for the estuary was developed in order to quantify the contribution of the submerged macrophytes and macroalgae relative to other contributing sources. The Wolwedans Dam located 3 km upstream from the estuary has reduced the amount of freshwater flow to the estuary by as much as 56 percent. The estuary has been allocated 2 x 106 m3 per annum of freshwater (ecological reserve) that is used to breach the mouth once or twice a year in spring or summer. Even though this water has been made available it is not sufficient to flush the estuary. Reduced flushing has led to an accumulation of organic matter and degradation in the water quality. Physico-chemical measurements between September 2010 and July 2012 showed that dissolved oxygen values were generally below 6 mg l-1. The average NH4+ concentration in the estuary was 7 μM and increased with depth to 12 μM at 2 m depths. Concentrations >45 μM were found in February and April 2011 at the 5 m deep hole at 3.4 km upstream. Negative correlations between dissolved oxygen and NH4+ during November 2010, February 2011, April 2011 and July 2011 (r = -0.68; -0.67; -0.63; -0.96) indicated that remineralisation of organic matter had occurred. Soluble reactive phosphorus (SRP) followed a similar trend to the NH4+ and was generally below 1 μM in the water column for most months, and had peaks at 1.0 km and 3.4 km in the bottom water. The abundance of submerged macrophytes and macroalgae below the N2 bridge were mostly influenced by mouth state and river inflow. During the closed phase the dominant macroalga Cladophora glomerata had an area cover ranging from 3000 to 6000 m2 while Zostera capensis and Ruppia cirrhosa covered an area of 2000 to 3500 m2 and 1500 to 2900 m2, respectively. After an artificial breach in February 2011, water drained out of the estuary leaving the alga stranded on the marshes and as the flood tide entered the macroalga was once again redistributed in the lower reaches. The alga utilised the available nutrients in the water column and expanded its area cover from 35000 m2 in February 2011 to 64000 m2 in March 2011. However, after the floods in June 2011, Cladophora glomerata had been washed out of the system while the submerged macrophytes responded positively extending their area cover. By comparing the artificial breach with the natural breach, and the effect on the estuary, an important observation was highlighted. Increasing the current allocated ecological reserve, and using a larger volume of water to breach the mouth artificially, would result in better scouring of sediment and associated organic matter out of the estuary. This would enable better oxygenation of the water column, reduce remineralisation and minimise algal blooms.
- Full Text:
- Date Issued: 2013
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