A framework for designing ambient assisted living services for disabled individuals
- Authors: Kyazze, Michael
- Date: 2018
- Subjects: Assistive computer technology , Computers and people with disabilities Self-help devices for people with disabilities People with disabilities -- Means of communication -- Technological innovations Communication devices for people with disabilities
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/31240 , vital:31347
- Description: Physically disabled individuals face a number of challenges when carrying out their everyday activities such as moving around, communicating with others, and their personal care. One way of overcoming these challenges is by using personal assistants. An alternative is to enable independence through assistive technology. This research aimed to investigate how physically disabled individuals experience these challenges, and how assistive technology can enable them to be more independent. In order to achieve the goal of this research, existing literature was reviewed on disability, assisted living, and interaction techniques. The literature study on disability identified some of the challenges faced by disabled individuals in their daily lives. In order to contextualize these challenges, interview studies with eighteen disabled individuals, and twelve personal assistants were carried out in Kampala, Uganda and Port Elizabeth, South Africa. The participants from both Uganda and South Africa were limited to those living in urban areas. The Ugandan participants noted that, whereas technology may assist their daily lives, their most essential needs are basic disability support aids such as wheelchairs and better long canes. This was in contrast with the South African participants, who have access to basic disability support aids. The South African participants identified their key needs as controlling an electronic environment without assistance, e.g. house lights, using a mobile phone, and using a computer without assistance. The interviews narrowed down the scope to focus on individuals with quadriplegia, specifically individuals who have limited hand use, but can comfortably speak and move their heads, and make gestures such as head shake and nod. Literature on assisted living technologies and frameworks, provided the technical foundation for the research. The literature review of interaction techniques identified a number of possible ways in which individuals with quadriplegia can interact with technology. An appropriate set of interaction techniques, namely head shake and nod, voice, and facial feature tracking were identified. Evaluations of the interaction techniques excluded head shake and nod, because of an inconsistency in detecting an individual’s head pose in different lighting conditions, when using a Microsoft Kinect. Voice and facial feature tracking using a standard computer camera were identified as the most suitable interaction techniques for this study. A framework for designing assisted living software services was developed. The framework allows disability researchers and solution developers to understand the needs of a given disability group, and design relevant solutions. To demonstrate that the proposed framework iii | P a g e addresses the main aim of this research, a prototype was developed that enables users to control smart lights (Phillips hue), a Smart TV (Samsung), and carry out basic navigation and webbrowsing on a computer. Users could interact with the software using voice and facial feature commands. A usability study was carried out with fifteen physically disabled individuals in Port Elizabeth, South Africa. The results of the evaluation study were highly positive. The successful evaluation of the prototype provided empirical evidence that the proposed framework does assist in the design of relevant and useful software services, to meet the unique needs of physically disabled individuals.
- Full Text:
- Date Issued: 2018
- Authors: Kyazze, Michael
- Date: 2018
- Subjects: Assistive computer technology , Computers and people with disabilities Self-help devices for people with disabilities People with disabilities -- Means of communication -- Technological innovations Communication devices for people with disabilities
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/31240 , vital:31347
- Description: Physically disabled individuals face a number of challenges when carrying out their everyday activities such as moving around, communicating with others, and their personal care. One way of overcoming these challenges is by using personal assistants. An alternative is to enable independence through assistive technology. This research aimed to investigate how physically disabled individuals experience these challenges, and how assistive technology can enable them to be more independent. In order to achieve the goal of this research, existing literature was reviewed on disability, assisted living, and interaction techniques. The literature study on disability identified some of the challenges faced by disabled individuals in their daily lives. In order to contextualize these challenges, interview studies with eighteen disabled individuals, and twelve personal assistants were carried out in Kampala, Uganda and Port Elizabeth, South Africa. The participants from both Uganda and South Africa were limited to those living in urban areas. The Ugandan participants noted that, whereas technology may assist their daily lives, their most essential needs are basic disability support aids such as wheelchairs and better long canes. This was in contrast with the South African participants, who have access to basic disability support aids. The South African participants identified their key needs as controlling an electronic environment without assistance, e.g. house lights, using a mobile phone, and using a computer without assistance. The interviews narrowed down the scope to focus on individuals with quadriplegia, specifically individuals who have limited hand use, but can comfortably speak and move their heads, and make gestures such as head shake and nod. Literature on assisted living technologies and frameworks, provided the technical foundation for the research. The literature review of interaction techniques identified a number of possible ways in which individuals with quadriplegia can interact with technology. An appropriate set of interaction techniques, namely head shake and nod, voice, and facial feature tracking were identified. Evaluations of the interaction techniques excluded head shake and nod, because of an inconsistency in detecting an individual’s head pose in different lighting conditions, when using a Microsoft Kinect. Voice and facial feature tracking using a standard computer camera were identified as the most suitable interaction techniques for this study. A framework for designing assisted living software services was developed. The framework allows disability researchers and solution developers to understand the needs of a given disability group, and design relevant solutions. To demonstrate that the proposed framework iii | P a g e addresses the main aim of this research, a prototype was developed that enables users to control smart lights (Phillips hue), a Smart TV (Samsung), and carry out basic navigation and webbrowsing on a computer. Users could interact with the software using voice and facial feature commands. A usability study was carried out with fifteen physically disabled individuals in Port Elizabeth, South Africa. The results of the evaluation study were highly positive. The successful evaluation of the prototype provided empirical evidence that the proposed framework does assist in the design of relevant and useful software services, to meet the unique needs of physically disabled individuals.
- Full Text:
- Date Issued: 2018
Advanced high speed data and clock transmission over optical fibre for square kilometre telescope array
- Authors: Isoe, George Mosoti
- Date: 2018
- Subjects: Very large array telescopes -- South Africa , Semiconductor lasers Optical communications Optical amplifiers
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/30375 , vital:30935
- Description: There is an ever present need from Internet users for more bandwidth. This is manifested by continuous increase in bandwidth demanding applications such as 5G wireless, new end user consumer links like thunderbolt, video conferencing, high definition video-on-demand transmitted over the Internet and massive data transfers required with and within data centres for backup, storage and data processing in cloud computing. Fibre optic communications technologies are playing a pivotal role in communication, being a major enabling technology in our increasingly Internet-centric society. As network services continue to become more dynamic and diverse, Internet service providers are faced with a challenge of cost reduction in the transmission network, power and spectral efficiency as well as scalability of the optical network infrastructure to support incremental expansions and virtual machines. Intelligent design of terrestrial optical networks to allow for simultaneous signal transmission through shared network infrastructure, and the use of low cost, power efficient, high bandwidth transmitters such as vertical surface emitting lasers (VCSELs) as well as exploitation of spectral efficient in-complex advanced modulation formats is a viable approach to this situation. In this study, techniques for spectral efficiency upgrade and simultaneous transmission of data signal, reference frequency (RF) clock signal and pulse-per-second (PPS) over shared infrastructure have experimentally been optimized in a laboratory environment for adoption in next-generation telescope array networks such as the Square Kilometre Array (SKA), time keeping systems such as banking systems, Coordinated Universal Time(UTC) timing and Global Positioning Systems (GPS), as well as high capacity spectral efficient short reach optical fibre networks such as data centres. This work starts by experimentally optimizing VCSEL technology for simultaneous transmission of 10 Gbps data and 1.712 GHz RF clock signal over a single G. 655 optical fibre of length 24.75 Km at different channel spacing and different propagation direction for implementation in a cost effective next-generation telescope array network. The wavelength tuneability property of VCSEL transmitters allows for wavelength adjustment, a key requirement for simultaneous data and RF clock signal transmission over a single optical fibre. A receiver sensitivity of -19.19 dBm was experimentally achieved at back-to-back analysis. A 24.75 Km of simultaneous data and RF clock signal transmission performed at 0.4 nm channel spacing introduced a transmission penalty of 1.07 dB and 1.63 dB for counter and co-propagation scheme respectively. This work mainly utilized direct modulation and direct detection using a positive intrinsic negative (PIN) due to its simplicity and cost effectiveness. A novel modulation technique for simultaneous data and polarization-based pulse-per-second timing clock signal transmission using a single VCSEL carrier is experimentally demonstrated. Two signal types, a directly modulated 10 Gbps data signal and a polarization-based pulse per second (PPS) clock signal are modulated onto a single mode 10 GHz bandwidth VCSEL carrier at 1310 nm. Spectral efficiency is maximized by exploiting the inherent orthogonal polarization switching of the xiv VCSEL with changing bias in transmission of the PPS signal. A 10 Gbps VCSEL transmission with PPS over 11 Km of G.652 fibre introduced a transmission penalty of 0.52 dB. The contribution of PPS clock signal to this penalty was found to be 0.08 dB. A technique for simultaneous directly modulated data and phase modulated reference clock signal transmission over a signal channel in wavelength division multiplexing (WDM) solutions is experimentally demonstrated. This is to prepare solutions to the ever-increasing demand over gigabit/s, terabit/s and gigahertz capacities in WDM-based terrestrial optical fibre transmission systems such as telescope array networks. a total capacity of 30 Gbps (310 Gbps) data and 12 GHz ( 4 3 GHz) reference clock signal are multiplexed at a channel spacing of 100 GHz and simultaneously transmitted over a single mode G.655 fibre of length 24.73 Km. The recovery of the phase modulated RF clock signal using a differential delay line interferometry technique is experimentally demonstrated. A 625 Gbps (2525 Gbps) DWDM data transmission system is further implemented in simulation by multiplexing 25 channels at 25 Gbps per channel using 50 GHz channel spacing. A four level pulse amplitude modulation (4-PAM) data modulation format employing VCSELs is experimentally demonstrated for adoption in high bitrate networks such as big data science projects and data centre networks. 4-PAM offers a good trade-off between complexity, efficiency, reach, and sensitivity. A software defined digital signal processing (DSP) receiver is designed and implemented in MATLAB to recover the transmitted 4-PAM data signal cost effectively without the necessity of costly receiver hardware. A novel technique for maximizing carrier spectral efficiency through simultaneous 20 Gbps 4-PAM data and phase modulated 2 GHz RF clock signal transmission on a single mode 10 GHz bandwidth VCSEL carrier at 1310 nm is experimentally demonstrated for the first time to the best of our knowledge. Data transmission and clock stability performance of the designed high spectral efficient VCSEL-based link network is evaluated through BER curve plots, phase noise measurements and Allan variance analysis respectively. VCSEL-based Raman amplification is experimentally demonstrated as a viable approach for RF clock signal distribution in extended reach astronomical telescope array networks and other extended reach terrestrial optical fibre network application. This is achieved by adopting two pumping techniques namely forward pumping and backward pumping. A maximum on off gain of 5.7 dB and 1.5 dB was experimentally attained for forward pumping and backward pumping at 24 dBm pump power respectively, while a maximum 100.8 Km fibre transmission achieved experimentally. In summary, this study has successfully demonstrated in-complex, spectral efficient, low cost and power efficient simultaneous data signal, reference frequency (RF) clock signal and pulse-per-second (PPS) transmission techniques over shared network infrastructure. Simultaneous transmission of data, RF clock and PPS timing signal is relevant in nextgeneration telescope array networks such as the Square Kilometre Array (SKA), time keeping systems such as banking systems, Coordinated Universal Time (UTC) timing and Global Positioning Systems (GPS), as well as high capacity spectral efficient short reach optical fibre networks such as data centres.
- Full Text:
- Date Issued: 2018
- Authors: Isoe, George Mosoti
- Date: 2018
- Subjects: Very large array telescopes -- South Africa , Semiconductor lasers Optical communications Optical amplifiers
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/30375 , vital:30935
- Description: There is an ever present need from Internet users for more bandwidth. This is manifested by continuous increase in bandwidth demanding applications such as 5G wireless, new end user consumer links like thunderbolt, video conferencing, high definition video-on-demand transmitted over the Internet and massive data transfers required with and within data centres for backup, storage and data processing in cloud computing. Fibre optic communications technologies are playing a pivotal role in communication, being a major enabling technology in our increasingly Internet-centric society. As network services continue to become more dynamic and diverse, Internet service providers are faced with a challenge of cost reduction in the transmission network, power and spectral efficiency as well as scalability of the optical network infrastructure to support incremental expansions and virtual machines. Intelligent design of terrestrial optical networks to allow for simultaneous signal transmission through shared network infrastructure, and the use of low cost, power efficient, high bandwidth transmitters such as vertical surface emitting lasers (VCSELs) as well as exploitation of spectral efficient in-complex advanced modulation formats is a viable approach to this situation. In this study, techniques for spectral efficiency upgrade and simultaneous transmission of data signal, reference frequency (RF) clock signal and pulse-per-second (PPS) over shared infrastructure have experimentally been optimized in a laboratory environment for adoption in next-generation telescope array networks such as the Square Kilometre Array (SKA), time keeping systems such as banking systems, Coordinated Universal Time(UTC) timing and Global Positioning Systems (GPS), as well as high capacity spectral efficient short reach optical fibre networks such as data centres. This work starts by experimentally optimizing VCSEL technology for simultaneous transmission of 10 Gbps data and 1.712 GHz RF clock signal over a single G. 655 optical fibre of length 24.75 Km at different channel spacing and different propagation direction for implementation in a cost effective next-generation telescope array network. The wavelength tuneability property of VCSEL transmitters allows for wavelength adjustment, a key requirement for simultaneous data and RF clock signal transmission over a single optical fibre. A receiver sensitivity of -19.19 dBm was experimentally achieved at back-to-back analysis. A 24.75 Km of simultaneous data and RF clock signal transmission performed at 0.4 nm channel spacing introduced a transmission penalty of 1.07 dB and 1.63 dB for counter and co-propagation scheme respectively. This work mainly utilized direct modulation and direct detection using a positive intrinsic negative (PIN) due to its simplicity and cost effectiveness. A novel modulation technique for simultaneous data and polarization-based pulse-per-second timing clock signal transmission using a single VCSEL carrier is experimentally demonstrated. Two signal types, a directly modulated 10 Gbps data signal and a polarization-based pulse per second (PPS) clock signal are modulated onto a single mode 10 GHz bandwidth VCSEL carrier at 1310 nm. Spectral efficiency is maximized by exploiting the inherent orthogonal polarization switching of the xiv VCSEL with changing bias in transmission of the PPS signal. A 10 Gbps VCSEL transmission with PPS over 11 Km of G.652 fibre introduced a transmission penalty of 0.52 dB. The contribution of PPS clock signal to this penalty was found to be 0.08 dB. A technique for simultaneous directly modulated data and phase modulated reference clock signal transmission over a signal channel in wavelength division multiplexing (WDM) solutions is experimentally demonstrated. This is to prepare solutions to the ever-increasing demand over gigabit/s, terabit/s and gigahertz capacities in WDM-based terrestrial optical fibre transmission systems such as telescope array networks. a total capacity of 30 Gbps (310 Gbps) data and 12 GHz ( 4 3 GHz) reference clock signal are multiplexed at a channel spacing of 100 GHz and simultaneously transmitted over a single mode G.655 fibre of length 24.73 Km. The recovery of the phase modulated RF clock signal using a differential delay line interferometry technique is experimentally demonstrated. A 625 Gbps (2525 Gbps) DWDM data transmission system is further implemented in simulation by multiplexing 25 channels at 25 Gbps per channel using 50 GHz channel spacing. A four level pulse amplitude modulation (4-PAM) data modulation format employing VCSELs is experimentally demonstrated for adoption in high bitrate networks such as big data science projects and data centre networks. 4-PAM offers a good trade-off between complexity, efficiency, reach, and sensitivity. A software defined digital signal processing (DSP) receiver is designed and implemented in MATLAB to recover the transmitted 4-PAM data signal cost effectively without the necessity of costly receiver hardware. A novel technique for maximizing carrier spectral efficiency through simultaneous 20 Gbps 4-PAM data and phase modulated 2 GHz RF clock signal transmission on a single mode 10 GHz bandwidth VCSEL carrier at 1310 nm is experimentally demonstrated for the first time to the best of our knowledge. Data transmission and clock stability performance of the designed high spectral efficient VCSEL-based link network is evaluated through BER curve plots, phase noise measurements and Allan variance analysis respectively. VCSEL-based Raman amplification is experimentally demonstrated as a viable approach for RF clock signal distribution in extended reach astronomical telescope array networks and other extended reach terrestrial optical fibre network application. This is achieved by adopting two pumping techniques namely forward pumping and backward pumping. A maximum on off gain of 5.7 dB and 1.5 dB was experimentally attained for forward pumping and backward pumping at 24 dBm pump power respectively, while a maximum 100.8 Km fibre transmission achieved experimentally. In summary, this study has successfully demonstrated in-complex, spectral efficient, low cost and power efficient simultaneous data signal, reference frequency (RF) clock signal and pulse-per-second (PPS) transmission techniques over shared network infrastructure. Simultaneous transmission of data, RF clock and PPS timing signal is relevant in nextgeneration telescope array networks such as the Square Kilometre Array (SKA), time keeping systems such as banking systems, Coordinated Universal Time (UTC) timing and Global Positioning Systems (GPS), as well as high capacity spectral efficient short reach optical fibre networks such as data centres.
- Full Text:
- Date Issued: 2018
An investigation of the combustion kinetics of coal-microalgae composite
- Ejesieme, Obialo Vitus, Dugmore, Gary
- Authors: Ejesieme, Obialo Vitus , Dugmore, Gary
- Date: 2018
- Subjects: Microalgae -- Biotechnology , Biomass energy -- South Africa Coal -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/34777 , vital:33447
- Description: Coal mining and handling generate sizeable quantities of ultra-fine coal particles which are heaped as discard material. Use of the ultra-fine coal for co-firing with microalgae biomass appears to be a promising option that would improve combustion of the discard. There is no available traditional biomass binder that can be used to agglomerate, reclaim, and co-fire the discard ultra-fine coal to generate heat. In a recent research, microalgae biomass was identified as an effective natural binder for discard ultra-fine coal. Biomass is a renewable resource, and many have been co-fired on a large scale except microalgae biomass. Researchers have studied co-firing of dry mixed coal-microalgae, however, the kinetics of a wet mix of microalgae biomass and ultra-fine coal, “Coalgae®” patented recently by the Nelson Mandela University needs to be explored. The study aimed at investigating in some detail the oxidation mechanism of coal-microalgae composites. The objective is to understand the impact of microalgae on the kinetic properties of coal which will inform on the application of “Coalgae®”. It involves correlating the small and large-scale combustion properties that will establish the co-firing option on an industrial scenario. The goal is to utilize all grades of discard ultra-fine resource using microalgae biomass as binder and a renewable component which enhances the combustion of coal to supply heat and electricity. The use of microalgae for fuel preparation and upgrading is on the increase due to its high growth potential, reactivity, and ability to store energy more than other biomasses. This research hypothesized that blending of discard ultra-fine coal with live microalgae biomass would improve the kinetic properties of the coal more than expected from linear combination of the dry materials. Thermogravimetric combustion of “Coalgae®” was studied under non-isothermal conditions from 40 °C to 900°C at a heating rate of 15 °C/min and air flow rate of 20 ml/min. The thermogravimetric combustion properties i.e. small-scale was related to the large-scale, John Thompson’s fixed-bed reactor under the above condition. Thermal profiles were transformed into a differential function to reveal overlapped combustion events. The Coat-Redferns kinetic model was applied on the non-de-Ejesieme, O.V. PhD Chemistry (Research), Nelson Mandela Univ. Email: ejevit@yahoo.com , s211266744@live.nmmu.ac.za convoluted reactions set to obtain some of kinetic parameters. The Fraser-Suzuki equation was used to de-convolute the overlapped combustion. Then, rate law combined with Arrhenius equation was used to derive the activation energy E a and pre-exponential factor A, while the integral form of solid states reaction model, g (∝) was applied to deduce the oxidation mechanism. The composite formed a strong and partly renewable blend under controlled temperature conditions, unlike assorted dried biomass mixed with coal. Microalgae biomass upgraded the fuel and kinetics properties of ultra-fine coal more than what was expected from a linear combination. It released heat that promoted the oxidation mechanism of the discard coal. The main effect is that the “Coalgae®” is significantly (p = 0.0570) more reactive than the coal. The co-firing approach is partly renewable and contributes to the utilization of high and low-quality available discard ultra-fine coal. It advances the combustion of coal resources and reduces carbon dioxide, CO2 emission attributed to global warming as well as preserves the natural biomass sources. The combustion of “Coalgae® “will improve economy, environment, and health, heat, and electricity supply to the society.
- Full Text:
- Date Issued: 2018
- Authors: Ejesieme, Obialo Vitus , Dugmore, Gary
- Date: 2018
- Subjects: Microalgae -- Biotechnology , Biomass energy -- South Africa Coal -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/34777 , vital:33447
- Description: Coal mining and handling generate sizeable quantities of ultra-fine coal particles which are heaped as discard material. Use of the ultra-fine coal for co-firing with microalgae biomass appears to be a promising option that would improve combustion of the discard. There is no available traditional biomass binder that can be used to agglomerate, reclaim, and co-fire the discard ultra-fine coal to generate heat. In a recent research, microalgae biomass was identified as an effective natural binder for discard ultra-fine coal. Biomass is a renewable resource, and many have been co-fired on a large scale except microalgae biomass. Researchers have studied co-firing of dry mixed coal-microalgae, however, the kinetics of a wet mix of microalgae biomass and ultra-fine coal, “Coalgae®” patented recently by the Nelson Mandela University needs to be explored. The study aimed at investigating in some detail the oxidation mechanism of coal-microalgae composites. The objective is to understand the impact of microalgae on the kinetic properties of coal which will inform on the application of “Coalgae®”. It involves correlating the small and large-scale combustion properties that will establish the co-firing option on an industrial scenario. The goal is to utilize all grades of discard ultra-fine resource using microalgae biomass as binder and a renewable component which enhances the combustion of coal to supply heat and electricity. The use of microalgae for fuel preparation and upgrading is on the increase due to its high growth potential, reactivity, and ability to store energy more than other biomasses. This research hypothesized that blending of discard ultra-fine coal with live microalgae biomass would improve the kinetic properties of the coal more than expected from linear combination of the dry materials. Thermogravimetric combustion of “Coalgae®” was studied under non-isothermal conditions from 40 °C to 900°C at a heating rate of 15 °C/min and air flow rate of 20 ml/min. The thermogravimetric combustion properties i.e. small-scale was related to the large-scale, John Thompson’s fixed-bed reactor under the above condition. Thermal profiles were transformed into a differential function to reveal overlapped combustion events. The Coat-Redferns kinetic model was applied on the non-de-Ejesieme, O.V. PhD Chemistry (Research), Nelson Mandela Univ. Email: ejevit@yahoo.com , s211266744@live.nmmu.ac.za convoluted reactions set to obtain some of kinetic parameters. The Fraser-Suzuki equation was used to de-convolute the overlapped combustion. Then, rate law combined with Arrhenius equation was used to derive the activation energy E a and pre-exponential factor A, while the integral form of solid states reaction model, g (∝) was applied to deduce the oxidation mechanism. The composite formed a strong and partly renewable blend under controlled temperature conditions, unlike assorted dried biomass mixed with coal. Microalgae biomass upgraded the fuel and kinetics properties of ultra-fine coal more than what was expected from a linear combination. It released heat that promoted the oxidation mechanism of the discard coal. The main effect is that the “Coalgae®” is significantly (p = 0.0570) more reactive than the coal. The co-firing approach is partly renewable and contributes to the utilization of high and low-quality available discard ultra-fine coal. It advances the combustion of coal resources and reduces carbon dioxide, CO2 emission attributed to global warming as well as preserves the natural biomass sources. The combustion of “Coalgae® “will improve economy, environment, and health, heat, and electricity supply to the society.
- Full Text:
- Date Issued: 2018
Assessment of the host potential of TETROL [(+)-(2R,3R)-1,1,4,4- tetraphenylbutane-1,2,3,4-TETROL] for the separation of isomers and related compounds
- Authors: Dorfling, Sasha-Lee
- Date: 2018
- Subjects: Chemistry, Organic , Thermal analysis Hydrogen bonding
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/22060 , vital:29817
- Description: In this study, we investigated the potential of a host compound, (+)-(2R,3R)-1,1,4,4- tetraphenylbutane-1,2,3,4-tetrol (TETROL), for use in the separation of isomers and related compounds using host-guest chemistry. The synthesis of this host was carried out using a standard Grignard procedure, reacting naturally-occurring optically active tartaric acid with phenylmagnesium bromide. The feasibility of this host for separating isomers and structurally-related compounds was investigated by recrystallizing it from various potential cyclic, aromatic and aliphatic guest compounds. The extent of host inclusion and guest separation were determined using 1H-NMR spectroscopy and GCMS analyses. Competition studies were conducted to establish the selectivity of TETROL for the various guest species and whether this host would be able to discriminate between them. In this instance, the host was recrystallized from equimolar amounts of binary, ternary, quaternary or quinary mixtures of the guests present in each target study. Subsequent binary or ternary competitions were conducted where the molar ratios of the guest species were varied beyond equimolar, and the guest selectivity of TETROL thus evaluated by means of selectivity profiles. Further analyses included single crystal X-ray diffraction (SCXRD), thermal analysis and Hirshfeld surface analysis. Any crystalline inclusion complex formed between host and guest, with suitable crystal quality, was analysed using SCXRD in order to determine the nature of any significant host–guest interactions present. Thermogravimetric and differential scanning calorimetry experiments provided further insight into complex stability by analysing the thermal events experienced by the complexes as they were heated at 10 °C/min. The data obtained from Hirshfeld surface analyses were used to determine whether host selectivity and/or thermal stability of the complexes were related to the number and types of interactions, observed from SCXRD, between host and guest. The ability of TETROL to discriminate between related compounds was favourable. This host proved to have selective preference for aniline over its methylated derivatives, N-methylaniline and N,N-dimethylaniline. It was also selective for cyclohexylamine over cyclohexanol and cyclohexanone, and discriminated against the pyridine, piperidine and dioxane heterocyclics in favour of morpholine. Furthermore, this host was successful in the selective separation of isomers; for example, it selectively showed discrimination between the three toluidine isomers (p-toluidine > m-toluidine > o-toluidine) and the cresols (p-cresol > m-cresol > o-cresol). Each guest mixture was selected based on data from experiments using either the industrial significance of its separation or because the mixture would add to the knowledge base of the host compound’s preferences and selectivities. In a separate study, TETROL and its derivative, (–)-(2R,3R)-2,3-dimethoxy-1,1,4,4- tetraphenylbutane-1,4-diol (DMT), were also allowed to compete for the inclusion of the guest cyclohexanone, where TETROL demonstrated superior ability. This host, in addition, showed potential for the separation of cis- and trans- 2-methylcyclohexanol.
- Full Text:
- Date Issued: 2018
- Authors: Dorfling, Sasha-Lee
- Date: 2018
- Subjects: Chemistry, Organic , Thermal analysis Hydrogen bonding
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/22060 , vital:29817
- Description: In this study, we investigated the potential of a host compound, (+)-(2R,3R)-1,1,4,4- tetraphenylbutane-1,2,3,4-tetrol (TETROL), for use in the separation of isomers and related compounds using host-guest chemistry. The synthesis of this host was carried out using a standard Grignard procedure, reacting naturally-occurring optically active tartaric acid with phenylmagnesium bromide. The feasibility of this host for separating isomers and structurally-related compounds was investigated by recrystallizing it from various potential cyclic, aromatic and aliphatic guest compounds. The extent of host inclusion and guest separation were determined using 1H-NMR spectroscopy and GCMS analyses. Competition studies were conducted to establish the selectivity of TETROL for the various guest species and whether this host would be able to discriminate between them. In this instance, the host was recrystallized from equimolar amounts of binary, ternary, quaternary or quinary mixtures of the guests present in each target study. Subsequent binary or ternary competitions were conducted where the molar ratios of the guest species were varied beyond equimolar, and the guest selectivity of TETROL thus evaluated by means of selectivity profiles. Further analyses included single crystal X-ray diffraction (SCXRD), thermal analysis and Hirshfeld surface analysis. Any crystalline inclusion complex formed between host and guest, with suitable crystal quality, was analysed using SCXRD in order to determine the nature of any significant host–guest interactions present. Thermogravimetric and differential scanning calorimetry experiments provided further insight into complex stability by analysing the thermal events experienced by the complexes as they were heated at 10 °C/min. The data obtained from Hirshfeld surface analyses were used to determine whether host selectivity and/or thermal stability of the complexes were related to the number and types of interactions, observed from SCXRD, between host and guest. The ability of TETROL to discriminate between related compounds was favourable. This host proved to have selective preference for aniline over its methylated derivatives, N-methylaniline and N,N-dimethylaniline. It was also selective for cyclohexylamine over cyclohexanol and cyclohexanone, and discriminated against the pyridine, piperidine and dioxane heterocyclics in favour of morpholine. Furthermore, this host was successful in the selective separation of isomers; for example, it selectively showed discrimination between the three toluidine isomers (p-toluidine > m-toluidine > o-toluidine) and the cresols (p-cresol > m-cresol > o-cresol). Each guest mixture was selected based on data from experiments using either the industrial significance of its separation or because the mixture would add to the knowledge base of the host compound’s preferences and selectivities. In a separate study, TETROL and its derivative, (–)-(2R,3R)-2,3-dimethoxy-1,1,4,4- tetraphenylbutane-1,4-diol (DMT), were also allowed to compete for the inclusion of the guest cyclohexanone, where TETROL demonstrated superior ability. This host, in addition, showed potential for the separation of cis- and trans- 2-methylcyclohexanol.
- Full Text:
- Date Issued: 2018
Disputes, relationships and identity: analysing human-human conflicts as a basis for human-wildlife conflicts in the mid-Zambezi valley, northern Zimbabwe
- Authors: Jani, Vincent
- Date: 2018
- Subjects: Environmental geography , Wildlife management Wildlife conservation Human-animal relationships
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/30364 , vital:30934
- Description: This study analysed how human-human conflicts (HHCs) underlie human-wildlife conflicts (HWCs) in Chapoto Ward in the mid-Zambezi valley, northern Zimbabwe. The analytical framework entailed the use of the Levels of Conflict Model (LCM) – a model that seeks to expose different levels of conflict. To gain a rich understanding of the conflicts under investigation, a qualitative research design was employed with triangulation at its core in order to ensure the necessary quality and rigour of the findings. In this case, four different types of data were used, namely, in-depth interviews with heads of households, key informant interviews, focus group sessions, and document analysis. Thematic and content analysis were used to analyse the data which were classified into the following conflict levels: surface level disputes; an intermediate level involving ongoing conflictual relationships; and a deeper level of conflict rooted in identity. Three key findings were generated. Firstly, a substantial number of long-standing disputes were recorded during the ten-year period (2007-2016). Most of these disputes were not resolved because they had a long and complicated history which resulted in previous disputes resurfacing whenever a current one arose. Secondly, the history of unresolved conflict resulted in mistrust and failure to find common ground between the parties involved in the conflict. Lastly, the source of the disputes and unresolved conflicts was traced back to the identity level. This means that the antagonistic relationships among the stakeholders spilled over into the labelling and stigmatisation of all the groups involved in wildlife management. Thus, conflict between people and wildlife in Chapoto Ward was demonstrated to be a complex issue and underlain by HHC. These findings support the new line of thinking that HWC should not be viewed as simply a problem between people and wildlife but as a conflict between stakeholders with divergent views over wildlife management which manifests as HHC. Furthermore, the degree of polarisation between groups is substantial. In light of these findings, four major conclusions are drawn. Firstly, is the need to shift from narrowly focusing on the proximate conflicts between people and wildlife, to fully understand the complexity of conflict in order to arrive at solutions that successfully mitigate conflict between people and wildlife, and to address the underlying and deep-rooted conflict between stakeholders with divergent wildlife management goals. Secondly, the need for concerted efforts to ensure the involvement of all stakeholders, including women, in wildlife management and conservation by developing structures that enhance active participation of the local people in decision-making, v which promotes the success of conservation initiatives. Thirdly, the need to address the underlying and deep-rooted conflicts over wildlife management by building positive relationships and trust between stakeholders through the holding of regular capacity building workshops based on a more respectful and inclusive process. Fourthly, is the need to consider the interests of both ethnic groups, namely the Doma and the Chikunda by gathering information on the preferences of the identity groups in order to increase cooperation among them. Overall, the thesis introduces a new lens through which one can clearly understand the complexity of the conflict between people and wildlife.
- Full Text:
- Date Issued: 2018
- Authors: Jani, Vincent
- Date: 2018
- Subjects: Environmental geography , Wildlife management Wildlife conservation Human-animal relationships
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/30364 , vital:30934
- Description: This study analysed how human-human conflicts (HHCs) underlie human-wildlife conflicts (HWCs) in Chapoto Ward in the mid-Zambezi valley, northern Zimbabwe. The analytical framework entailed the use of the Levels of Conflict Model (LCM) – a model that seeks to expose different levels of conflict. To gain a rich understanding of the conflicts under investigation, a qualitative research design was employed with triangulation at its core in order to ensure the necessary quality and rigour of the findings. In this case, four different types of data were used, namely, in-depth interviews with heads of households, key informant interviews, focus group sessions, and document analysis. Thematic and content analysis were used to analyse the data which were classified into the following conflict levels: surface level disputes; an intermediate level involving ongoing conflictual relationships; and a deeper level of conflict rooted in identity. Three key findings were generated. Firstly, a substantial number of long-standing disputes were recorded during the ten-year period (2007-2016). Most of these disputes were not resolved because they had a long and complicated history which resulted in previous disputes resurfacing whenever a current one arose. Secondly, the history of unresolved conflict resulted in mistrust and failure to find common ground between the parties involved in the conflict. Lastly, the source of the disputes and unresolved conflicts was traced back to the identity level. This means that the antagonistic relationships among the stakeholders spilled over into the labelling and stigmatisation of all the groups involved in wildlife management. Thus, conflict between people and wildlife in Chapoto Ward was demonstrated to be a complex issue and underlain by HHC. These findings support the new line of thinking that HWC should not be viewed as simply a problem between people and wildlife but as a conflict between stakeholders with divergent views over wildlife management which manifests as HHC. Furthermore, the degree of polarisation between groups is substantial. In light of these findings, four major conclusions are drawn. Firstly, is the need to shift from narrowly focusing on the proximate conflicts between people and wildlife, to fully understand the complexity of conflict in order to arrive at solutions that successfully mitigate conflict between people and wildlife, and to address the underlying and deep-rooted conflict between stakeholders with divergent wildlife management goals. Secondly, the need for concerted efforts to ensure the involvement of all stakeholders, including women, in wildlife management and conservation by developing structures that enhance active participation of the local people in decision-making, v which promotes the success of conservation initiatives. Thirdly, the need to address the underlying and deep-rooted conflicts over wildlife management by building positive relationships and trust between stakeholders through the holding of regular capacity building workshops based on a more respectful and inclusive process. Fourthly, is the need to consider the interests of both ethnic groups, namely the Doma and the Chikunda by gathering information on the preferences of the identity groups in order to increase cooperation among them. Overall, the thesis introduces a new lens through which one can clearly understand the complexity of the conflict between people and wildlife.
- Full Text:
- Date Issued: 2018
Estuarine microalgal bloom dynamics at multiple temporal scales
- Authors: Lemley, Daniel Alan
- Date: 2018
- Subjects: Ecological integrity -- South Africa , Phytoplankton populations -- South Africa , Estuarine ecology -- South Africa , Freshwater algae -- Ecology -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/21044 , vital:29431
- Description: Microalgal communities sustain the ecological functioning of estuarine ecosystems through the provision of numerous ecosystem services. As such, gaining an understanding of the processes that govern spatio-temporal patterns of phytoplankton communities is key to the effective management of these ecosystems. However, detailed investigations of estuarine phytoplankton dynamics, and particularly harmful algal blooms (HAB), are largely absent in South Africa. Therefore, geared at addressing these knowledge gaps, this study was initiated to elucidate the processes shaping estuarine phytoplankton bloom dynamics at multiple temporal scales. Initially, five permanently open estuaries, each with varying types and levels of anthropogenic pressures, were selected to test the efficacy of an estuarine eutrophic condition index to flow variability (‘Annual’ study). Results from this study highlighted the sensitivity of the proposed index to environmental perturbations (e.g. flood events), whilst also identifying freshwater inflow variability and anthropogenic disturbance as the key processes shaping microalgal responses at an annual scale. Next, the agriculturally-influenced Gamtoos and Sundays estuaries were further investigated to elucidate the role of natural and anthropogenic drivers in defining microalgal responses (‘Seasonal’ study). Despite similarities in nutrient input and temperature patterns, phytoplankton bloom conditions (> 20 μg Chl-a l-1) were episodic and flow-dependent in the Gamtoos Estuary, whilst those in the Sundays Estuary were persistent and seasonal. Related to its reduced hydrodynamic variability – i.e. consistent nutrient-rich baseflows and reduced propensity for flushing events – persistent undesirable disturbances were highlighted for the Sundays Estuary, including: summer bottom-water hypoxia (< 2 mg l-1) and exceptional proliferations (> 550 μg Chl-a l-1) of two HAB species (Heterosigma akashiwo and Heterocapsa rotundata). Finally, fine-scale ecological research was undertaken in the Sundays Estuary to identify the processes – abiotic and biotic – that facilitate HABs (‘Daily’ and ‘Hourly’ studies). Findings from the ‘Daily’ study, identified inorganic nutrient availability (i.e. nitrate and phosphate) and mesohaline conditions (ca. 10) as the key bottom-up controls influencing the magnitude and duration of spring/summer phytoplankton blooms. Additionally, bottom-water hypoxia was explicitly linked to the decay of a single HAB species. During the ‘Hourly’ investigation, four known HAB-forming species were recorded at bloom concentrations. Model results indicated that variability in temperature, salinity profiles and nitrate concentrations were significant in facilitating the occurrence of HAB species. Finally, local biotic interactions (e.g. interspecies competition, diel vertical migration and mixotrophy) were recognized as key mechanisms shaping phytoplankton communities. The persistent occurrence of HABs is a new feature in South African estuaries and continued research is needed to recommend management responses. Ultimately, this research highlights the multitude of processes at work shaping phytoplankton variability in estuaries. From a broad perspective (i.e. seasonal and annual), processes such as freshwater inflow regimes, degree of anthropogenic disturbance, as well as seasonal temperature and nutrient supply patterns are the key processes. At a more refined scale (i.e. hourly and daily), local processes including salinity preferences, nutrient availability, diel light cycles and internal biotic interactions are the key drivers organising phytoplankton dynamics. Given the potentially severe ecological consequences of disrupting natural phytoplankton dynamics (e.g. HABs), an element of ‘unpredictability’ should be restored to the hydrological and chemical makeup of highly-regulated estuaries to prevent the continued exacerbation of eutrophic symptoms.
- Full Text:
- Date Issued: 2018
- Authors: Lemley, Daniel Alan
- Date: 2018
- Subjects: Ecological integrity -- South Africa , Phytoplankton populations -- South Africa , Estuarine ecology -- South Africa , Freshwater algae -- Ecology -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/21044 , vital:29431
- Description: Microalgal communities sustain the ecological functioning of estuarine ecosystems through the provision of numerous ecosystem services. As such, gaining an understanding of the processes that govern spatio-temporal patterns of phytoplankton communities is key to the effective management of these ecosystems. However, detailed investigations of estuarine phytoplankton dynamics, and particularly harmful algal blooms (HAB), are largely absent in South Africa. Therefore, geared at addressing these knowledge gaps, this study was initiated to elucidate the processes shaping estuarine phytoplankton bloom dynamics at multiple temporal scales. Initially, five permanently open estuaries, each with varying types and levels of anthropogenic pressures, were selected to test the efficacy of an estuarine eutrophic condition index to flow variability (‘Annual’ study). Results from this study highlighted the sensitivity of the proposed index to environmental perturbations (e.g. flood events), whilst also identifying freshwater inflow variability and anthropogenic disturbance as the key processes shaping microalgal responses at an annual scale. Next, the agriculturally-influenced Gamtoos and Sundays estuaries were further investigated to elucidate the role of natural and anthropogenic drivers in defining microalgal responses (‘Seasonal’ study). Despite similarities in nutrient input and temperature patterns, phytoplankton bloom conditions (> 20 μg Chl-a l-1) were episodic and flow-dependent in the Gamtoos Estuary, whilst those in the Sundays Estuary were persistent and seasonal. Related to its reduced hydrodynamic variability – i.e. consistent nutrient-rich baseflows and reduced propensity for flushing events – persistent undesirable disturbances were highlighted for the Sundays Estuary, including: summer bottom-water hypoxia (< 2 mg l-1) and exceptional proliferations (> 550 μg Chl-a l-1) of two HAB species (Heterosigma akashiwo and Heterocapsa rotundata). Finally, fine-scale ecological research was undertaken in the Sundays Estuary to identify the processes – abiotic and biotic – that facilitate HABs (‘Daily’ and ‘Hourly’ studies). Findings from the ‘Daily’ study, identified inorganic nutrient availability (i.e. nitrate and phosphate) and mesohaline conditions (ca. 10) as the key bottom-up controls influencing the magnitude and duration of spring/summer phytoplankton blooms. Additionally, bottom-water hypoxia was explicitly linked to the decay of a single HAB species. During the ‘Hourly’ investigation, four known HAB-forming species were recorded at bloom concentrations. Model results indicated that variability in temperature, salinity profiles and nitrate concentrations were significant in facilitating the occurrence of HAB species. Finally, local biotic interactions (e.g. interspecies competition, diel vertical migration and mixotrophy) were recognized as key mechanisms shaping phytoplankton communities. The persistent occurrence of HABs is a new feature in South African estuaries and continued research is needed to recommend management responses. Ultimately, this research highlights the multitude of processes at work shaping phytoplankton variability in estuaries. From a broad perspective (i.e. seasonal and annual), processes such as freshwater inflow regimes, degree of anthropogenic disturbance, as well as seasonal temperature and nutrient supply patterns are the key processes. At a more refined scale (i.e. hourly and daily), local processes including salinity preferences, nutrient availability, diel light cycles and internal biotic interactions are the key drivers organising phytoplankton dynamics. Given the potentially severe ecological consequences of disrupting natural phytoplankton dynamics (e.g. HABs), an element of ‘unpredictability’ should be restored to the hydrological and chemical makeup of highly-regulated estuaries to prevent the continued exacerbation of eutrophic symptoms.
- Full Text:
- Date Issued: 2018
Social learning for public participation in environmental governance: the case of Knysna Municipality
- Authors: Currie, Bianca
- Date: 2018
- Subjects: Environmental policy -- South Africa -- Knysna -- Social aspects , Environmental management -- South Africa -- Knysna
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/29852 , vital:30785
- Description: Democratic environmental governance in complex systems requires an adaptive management approach involving a diversity of stakeholders in collaborative learning and decision-making. The decisions are value-laden, and local municipalities are struggling to reconcile the diversity of values, and balance varied and diverse social and ecological needs, for sustainability. Social learning has emerged as a promising approach but the challenge lies in effective implementation, practice and assessment of social learning. This thesis explored public participation practices in environmental governance in the Knysna Municipality and went on to develop a social learning procedural model for public participation, as well as assessment criteria for monitoring social learning processes. The model and criteria provide a foundation and the tools needed to operationalise social learning for adaptive management in environmental governance in complex systems.
- Full Text:
- Date Issued: 2018
- Authors: Currie, Bianca
- Date: 2018
- Subjects: Environmental policy -- South Africa -- Knysna -- Social aspects , Environmental management -- South Africa -- Knysna
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/29852 , vital:30785
- Description: Democratic environmental governance in complex systems requires an adaptive management approach involving a diversity of stakeholders in collaborative learning and decision-making. The decisions are value-laden, and local municipalities are struggling to reconcile the diversity of values, and balance varied and diverse social and ecological needs, for sustainability. Social learning has emerged as a promising approach but the challenge lies in effective implementation, practice and assessment of social learning. This thesis explored public participation practices in environmental governance in the Knysna Municipality and went on to develop a social learning procedural model for public participation, as well as assessment criteria for monitoring social learning processes. The model and criteria provide a foundation and the tools needed to operationalise social learning for adaptive management in environmental governance in complex systems.
- Full Text:
- Date Issued: 2018
The FAST fabric objective measurement properties of commercial worsted apparel fabrics available in South Africa
- Authors: Das, Sweta
- Date: 2018
- Subjects: Textile fabrics -- Testing , Textile fabrics -- Measurement , Textile fibers -- Testing , Textile design
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/17814 , vital:28458
- Description: In the last few decades, there has been a shift globally towards the objective measurement of these textile fibre, yarn and fabric properties which determine processing performance and product quality. This shift is also very apparent in the objective measurement of fabric properties, particularly those relating to handle and making-up into a garment. This study was motivated by the fact that the adoption of fabric objective measurement (FOM), specifically the FAST system, will benefit the South African worsted apparel sector, as it has done in various other countries which produce high quality worsted apparel fabrics and garments. FAST is robust and portable, yet inexpensive. The main objective of the study was to develop a FAST referencing system which can be used for benchmarking by the local apparel industry and, as a basis for encouraging and persuading the industry to adopt this system of fabric quality measurement and assurance and thereby improve their product quality and international competitiveness. To achieve the main objective, involved sourcing and FAST testing a representative cross-section of commercial worsted apparel fabrics with the emphasis on wool and wool blends from the local fabric and clothing manufacturing industry, and determining how the various FAST properties were affected by factors such as fabric weave, fibre blend and weight, since this could impact on the specific nature and validity of the referencing system. A total of some 394 worsted type commercial fabrics, mainly in wool and wool blends, were sourced from, and with the inputs of, local apparel fabric and clothing manufacturers so as to ensure the local fabric and garment representative of the sample population and after which the fabrics were tested on the FAST system. ANOVA (regression analysis) was carried out on each of the FAST parameters in order to determine whether fabric weight, weave, thickness and fibre composition (pure wool and wool blends) had a statistically significant effect on them, since this is an important aspect which needs to be clarified prior to the development of a envisaged meaningful FAST system.
- Full Text:
- Date Issued: 2018
- Authors: Das, Sweta
- Date: 2018
- Subjects: Textile fabrics -- Testing , Textile fabrics -- Measurement , Textile fibers -- Testing , Textile design
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/17814 , vital:28458
- Description: In the last few decades, there has been a shift globally towards the objective measurement of these textile fibre, yarn and fabric properties which determine processing performance and product quality. This shift is also very apparent in the objective measurement of fabric properties, particularly those relating to handle and making-up into a garment. This study was motivated by the fact that the adoption of fabric objective measurement (FOM), specifically the FAST system, will benefit the South African worsted apparel sector, as it has done in various other countries which produce high quality worsted apparel fabrics and garments. FAST is robust and portable, yet inexpensive. The main objective of the study was to develop a FAST referencing system which can be used for benchmarking by the local apparel industry and, as a basis for encouraging and persuading the industry to adopt this system of fabric quality measurement and assurance and thereby improve their product quality and international competitiveness. To achieve the main objective, involved sourcing and FAST testing a representative cross-section of commercial worsted apparel fabrics with the emphasis on wool and wool blends from the local fabric and clothing manufacturing industry, and determining how the various FAST properties were affected by factors such as fabric weave, fibre blend and weight, since this could impact on the specific nature and validity of the referencing system. A total of some 394 worsted type commercial fabrics, mainly in wool and wool blends, were sourced from, and with the inputs of, local apparel fabric and clothing manufacturers so as to ensure the local fabric and garment representative of the sample population and after which the fabrics were tested on the FAST system. ANOVA (regression analysis) was carried out on each of the FAST parameters in order to determine whether fabric weight, weave, thickness and fibre composition (pure wool and wool blends) had a statistically significant effect on them, since this is an important aspect which needs to be clarified prior to the development of a envisaged meaningful FAST system.
- Full Text:
- Date Issued: 2018
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