- Title
- Tribocorrosion properties of friction stir welded and laser welded titanium alloy
- Creator
- Davoren, Brandon Hilton
- Subject
- Chemistry, Technical -- Research Materials -- Mechanical properties
- Subject
- Aluminum alloys
- Date Issued
- 2017
- Date
- 2017
- Type
- Thesis
- Type
- Masters
- Type
- MSc
- Identifier
- http://hdl.handle.net/10948/33250
- Identifier
- vital:32605
- Description
- Titanium alloy Ti6Al4V has extensive uses in aerospace, dentistry and the biomedical industry. When used in these applications there is often a need to weld two or more pieces of titanium alloy together. This can be done by either friction stir weld or laser weld methods. These welded regions are often exposed to corrosive environments in addition to factors such as induced additional mechanical wear. Thus to accurately report on the viability of the material in a specific application, the corrosion, wear and their synergistic effects need to be studied. Friction stir welding, which is a well-suited method for joining plates of Ti6Al4V, creates regions in the material that are affected differently. These regions can be described as the parent material, advancing side, retreating side and the weld zone. The tribological properties of the different friction stir weld regions were analysed in air using different loads, frequencies, experimental duration and surrounding environments. When the applied load was increased some of the weld regions showed an increase in the specific wear rate. For example, the weld zone region showed a decrease when compared to the parent material. In this tribology study the effect of the counter material was evaluated. E52100, Si3N4, SS 316 and alumina counter materials were used in the test procedure which was conducted in air on the weld regions. The parent material was found to have the highest average specific wear rates with the four counter materials when compared to the weld zone samples. The regions affected by the friction stir weld process all showed, on average, lower specific wear rates than the parent material. For the various tested samples, the coefficient of friction and material compatibility that was found to be the most stable, was the alumina ball. Owing to this as well as its chemical stability, alumina was determined to be the best material for further tribocorrosion studies. The friction stir welded samples, that were cut from a cross section of a friction stir weld plate, were analyzed in 3.5% NaCl and dilute Harrison’s solution respectively. The effect of wear on the electrochemical properties was studied under open circuit voltage (OCV) and fixed 0.2 V and 0.4 V applied potential conditions respectively. The effect of wear on the corrosion properties was studied using potentiodynamic polarization. From analyzing the friction stir weld regions in both a wear and wear-free environment, the synergistic properties, namely the effect of wear on corrosion and the effect of corrosion on wear, were able to be calculated. The first electrochemical study was performed under OCV conditions. In the presence of applied wear, the open circuit potential of the friction stir weld samples, in both 3.5% NaCl and dilute Harrison’s solution, was found to decrease from the initial stabilized value. Of interest was the rate at which the OCV recovered. It was found to follow a second order repassivation growth model which was explained in terms of an initial film growth stage, followed by a film thickening stage that results in a new OCV. The second synergized electrochemical-wear study was under fixed 0.2 V and 0.4 V applied potential conditions. In both solutions, 3.5% NaCl and dilute Harrison’s solution, a large increase in the current was observed during the applied wear experiment. The samples submerged in 3.5% NaCl were found to have higher average currents during the wear experiment than those in dilute Harrison’s solution. The rapid decrease in the current, after the applied wear ceased, was found to also follow the second order repassivation model. The electrochemical-wear synergism was done by using potentiodynamic polarization tests. The friction stir weld regions as well as the laser samples were analysed in a wear as well as a wear-free environment in order to determine the effect that wear had on the corrosion properties. In both 3.5% NaCl and dilute Harrison’s solution the corrosion rates were found to increase by 100-fold when the wear was present. The effect of the wear process on corrosion could also be described by synergistic factor, where values close to 1 would imply that applied wear had little effect on the corrosion properties and vice versa. The synergistic factors showed that the corrosion rate was greatly affected by the presence of wear with corrosion synergistic factors of 20 and upward for the friction stir welded samples. The results showed that the weld zone region had a lower corrosion rate than the parent material. This implied that the main weld zone was shown to have the least effect of wear on corrosion and would therefore show the lowest likelihood of failure due to corrosion when compared to the parent material. The wear synergistic factor was found to be between 1 and 1.6 for the friction stir weld regions. This implied that the wear rates of the friction stir welded samples were slightly affected by the presence of a corrosive environment and that the wear properties of the laser welded samples were enhanced by the presence of a corrosive environment. Similar studies performed on laser welded samples showed unusually different results due to the small nature of the laser weld region, with inconclusive results when compared to the friction stir welded samples.
- Format
- ix, 171 leaves
- Format
- Publisher
- Nelson Mandela Metropolitan University
- Publisher
- Faculty of Science
- Language
- English
- Rights
- Nelson Mandela Metropolitan University
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