- Title
- Nonlinear optical behavior of neodymium mono-and bi-nuclear phthalocyanines linked to zinc oxide nanoparticles and incorporated into poly acrylic acid
- Creator
- Sekhosana, Kutloano E
- Creator
- Amuhaya, Edith K
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 2016
- Date
- 2016
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/188766
- Identifier
- vital:44783
- Identifier
- xlink:href="https://doi.org/10.1016/j.poly.2015.12.045"
- Description
- Syntheses of bis{23-(3,4-di-yloxybenzoic acid)-(2(3), 9(10), 16(17), 23(24))-(hexakis-pyridin-3-yloxy phthalocyaninato)} dineodymium (III) acetate (3) and 2(3), 9(10), 16(17), 23(24)-(tetrapyridin-3-yloxy phthalocyaninato) neodymium (III) acetate (4) as well as their conjugates with ZnO nanoparticles (conjugates 6, 7 and 8) are presented. Thin films of conjugate 6 (where complex 3 is linked to ZnO nanoparticles via an amide bond) gave the best third-order susceptibility (5.89 × 10−8 esu), second-order hyperpolarizability (2.53 × 10−25 esu) and the lowest limiting threshold values (0.12 J cm−2). The nonlinear behavior is enhanced in solid state when compared to solution.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (11 pages)
- Format
- Publisher
- Elsevier
- Language
- English
- Relation
- Polyhedron
- Relation
- Sekhosana, K.E., Amuhaya, E. and Nyokong, T., 2016. Nonlinear optical behavior of neodymium mono-and bi-nuclear phthalocyanines linked to zinc oxide nanoparticles and incorporated into poly acrylic acid. Polyhedron, 105, pp.159-169
- Relation
- Polyhedron volume 105 p. 159 2016 0277-5387
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Nonlinear optical behavior of neodymium mono-and bi-nuclear phthalocyanines.pdf | 820 KB | Adobe Acrobat PDF | View Details Download |