- Title
- Behavior of palladium nanoparticles in the absence or presence of cobalt tetraaminophthalocyanine for the electrooxidation of hydrazine
- Creator
- Maringa, Audacity
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 2014
- Date
- 2014
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/189796
- Identifier
- vital:44932
- Identifier
- xlink:href="https://doi.org/10.1002/elan.201400028"
- Description
- We report on the electrodeposition of palladium nanoparticles (PdNPs) on a glassy carbon electrode (GCE) and onto a poly-CoTAPc-GCE (CoTAPc=cobalt tetraamino phthalocyanine) surface. The electrodes are denoted as PdNPs-GCE and PdNPs/poly-CoTAPc-GCE, respectively. PdNPs/poly-CoTAPc-GCE showed the best activity for the oxidation of hydrazine at the lowest potential of −0.28 V and with the highest currents. The results were further supported by electrochemical impedance spectroscopy (EIS) which showed that there was less resistance to charge transfer for PdNPs/poly-CoTAPc-GCE compared to PdNPs-GCE. The catalytic rate constant for hydrazine oxidation was 6.12×108 cm3 mol−1 s−1 using PdNPs/poly-CoTAPc-GCE.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (10 pages)
- Format
- Publisher
- Wiley Library Online
- Language
- English
- Relation
- Electroanalysis
- Relation
- Maringa, A. and Nyokong, T., 2014. Behavior of palladium nanoparticles in the absence or presence of cobalt tetraaminophthalocyanine for the electrooxidation of hydrazine. Electroanalysis, 26(5), pp.1068-1077
- Relation
- Electroanalysis volume 26 number 5 p. 1068 2014 1521-4109
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Wiley Library Online Terms of Use Statement (https://onlinelibrary.wiley.com/terms-and-conditions)
- Rights
- Closed Access
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Collections
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
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| View Details Download | SOURCE1 | Behavior of palladium nanoparticles in the absence or presence of cobalt tetraaminophthalocyanine.pdf | 679 KB | Adobe Acrobat PDF | View Details Download |