- Title
- Synthesis, Characterization, and Electronic Structures of Porphyrins Fused with Polycyclic Aromatic Ring Systems
- Creator
- Okujima, Tetsuo
- Creator
- Mack, John
- Creator
- Nakamura, Jun
- Creator
- Kubheka, Gugu
- Creator
- Nyokong, Tebello
- Creator
- Zhu, Hua
- Creator
- Komobuchi, Naoki
- Creator
- Ono, Noboru
- Creator
- Yamada, Hiroko
- Creator
- Uno, Hidemitsu
- Creator
- Kobayashi, Nagao
- Subject
- To be catalogued
- Date Issued
- 2016
- Date
- 2016
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/240360
- Identifier
- vital:50827
- Identifier
- xlink:href="https://doi.org/10.1002/chem.201602213"
- Description
- A series of porphyrins fused with acenaphthylene, phenanthroline, and benzofluoranthene polycyclic aromatic rings were prepared by means of a 3+1 porphyrin synthesis approach and subsequent retro-Diels–Alder reaction of bicyclo[2.2.2]octadiene-fused precursors. Analysis of the magnetic circular dichroism spectra and the results of time-dependent DFT calculations are used to identify the reasons for the trends observed in the wavelengths and relative intensities of the Q bands of the products. Michl's perimeter model is used as a conceptual framework to explain the changes in the relative energies of the frontier π-molecular orbitals.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (9 pages)
- Format
- Publisher
- Wiley Library Online
- Language
- English
- Relation
- Chemistry–A European Journal
- Relation
- Okujima, T., Mack, J., Nakamura, J., Kubheka, G., Nyokong, T., Zhu, H., Komobuchi, N., Ono, N., Yamada, H., Uno, H. and Kobayashi, N., 2016. Synthesis, Characterization, and Electronic Structures of Porphyrins Fused with Polycyclic Aromatic Ring Systems. Chemistry–A European Journal, 22(41), pp.14730-14738
- Relation
- Chemistry–A European Journal volume 22 number 41 p. 14730 2016 1521-3765
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Wiley Library Online Terms of Use Statement (https://onlinelibrary.wiley.com/terms-and-conditions)
- Rights
- Closed Access
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Collections
Mack, John (Associate Prof)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Synthesis, Characterization, and Electronic Structures of Porphyrins.pdf | 848 KB | Adobe Acrobat PDF | View Details Download |