- Title
- Interaction of cyanide with iron (II) phthalocyanine
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 1993
- Date
- 1993
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/295497
- Identifier
- vital:57347
- Identifier
- xlink:href="https://doi.org/10.1039/DT9930003601"
- Description
- The kinetics and equilibria for the reaction between cyanide and iron (II) phthalocyanine [Fe(pc)](H2pc = phthalocyanine) in dimethyl sulfoxide (dmso) were studied at 25 °C. The complex [Fe(pc)(CN)2]2– is formed in two consecutive pseudo-first-order processes with k2f= 17.5 ± 0.8 dm3 mol–1 s–1 and k3f= 0.20 ± 0.05 dm3 mol–1 s–1, where k2f and k3f are the rate constants for the binding of the first and second cyanide ligands, respectively. The equilbrium constants were fund to be K2= 3.0 × 103 dm3 mol–1 and K3= 5.7 × 102 dm3 mol–1, for the formation of [Fe(pc)(CN)(dmso)]– and [Fe(pc)(CN)2]2–, respectively.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (4 pages)
- Format
- Publisher
- Royal Society of Chemistry
- Language
- English
- Relation
- Journal of the Chemical Society, Dalton Transactions
- Relation
- Nyokong, T., 1993. Interaction of cyanide with iron (II) phthalocyanine: kinetics and equilibria. Journal of the Chemical Society, Dalton Transactions, (23), pp.3601-3604
- Relation
- Journal of the Chemical Society, Dalton Transactions volume 23 p. 3601 1993 0300-9246
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Royal Society of Chemistry Terms and Conditions Statement (https://0-www.rsc.org.wam.seals.ac.za/help-legal/)
- Rights
- Open Access
- Hits: 235
- Visitors: 290
- Downloads: 62
Thumbnail | File | Description | Size | Format | |||
---|---|---|---|---|---|---|---|
View Details Download | SOURCE1 | Interaction of cyanide with iron (II) phthalocyanine kinetics and equilibria.pdf | 496 KB | Adobe Acrobat PDF | View Details Download |