DBU-Mediated cleavage of aryl-and heteroaryl disulfides

Title: DBU-Mediated cleavage of aryl-and heteroaryl disulfides
Creator: Nyoni, Dubekile
Creator: Lobb, Kevin A
Creator: Kaye, Perry T
Creator: Cairab, Mino R
Subject: To be catalogued
Date Issued: 2012
Date: 2012
Type: text
Type: article
Identifier: http://hdl.handle.net/10962/448884
Identifier: vital:74768
Description: The capacity of the nitrogen nucleophile, 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) to reduce aryl- and heteroaryl disulfides to the corresponding mercaptans is demonstrated. While dicarboxylated disulfide analogues afford the mono-DBU disulfide salts, as confirmed by X-ray crystallography, the corresponding methyl esters are cleaved normally.
Format: computer
Format: online resource
Format: application/pdf
Format: 1 online resource (8 pages)
Format: pdf
Publisher: ARKIVOC
Language: English
Relation: Arkivoc
Relation: Nyoni, D., Lobb, K.A., Kaye, P.T. and Cairab, M.R., 2012. DBU-Mediated cleavage of aryl-and heteroaryl disulfides. Arkivoc, 6, pp.245-252
Relation: Arkivoc volume 6 p. 245 2012 1551-7012
Rights: Publisher
Rights: Use of this resource is governed by the terms and conditions of the ARKIVOC Open Access Statement (https://www.arkat-usa.org/about-arkivoc/)
Rights: Open Access

Collections

Lobb, Kevin Allan (Assoc Prof)

Kaye, Perry T (Distinguished Fellow Emeritus Professor)

RU Department of Chemistry

SDG 03. Good Health and Well-Being

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