Solvent promoted tautomerism in thione-containing tetraazatricyclics: evidence from 1H NMR spectroscopy and transition state studies

Odame, Felix; Tshentu, Zenixole R; Lobb, Kevin A

Title: Solvent promoted tautomerism in thione-containing tetraazatricyclics: evidence from 1H NMR spectroscopy and transition state studies
Creator: Odame, Felix
Creator: Tshentu, Zenixole R
Creator: Lobb, Kevin A
Subject: To be catalogued
Date Issued: 2022
Date: 2022
Type: text
Type: article
Identifier: http://hdl.handle.net/10962/453198
Identifier: vital:75230
Identifier: xlink:href="https://link.springer.com/article/10.1007/s00894-022-05204-w"
Description: Tautomerism in the nitro substituted thione-containing traazatricyclics has been investigated. Evidence from 1 H NMR indicating the existence of the tautomers has been augmented with computational studies providing evidence of the stability or otherwise of these tautomers. The role of water and DMSO in the formation of the tautomers has been explained. The role of the nitro group in assisting in the formation of the tautomers has been discussed.
Format: computer
Format: online resource
Format: application/pdf
Format: 1 online resource (9 pages)
Format: pdf
Publisher: Springer
Language: English
Relation: Journal of Molecular Modeling
Relation: Odame, F., Tshentu, Z.R. and Lobb, K., 2022. Solvent promoted tautomerism in thione-containing tetraazatricyclics: evidence from 1H NMR spectroscopy and transition state studies. Journal of Molecular Modeling, 28(8), p.215
Relation: Journal of Molecular Modeling volume 28 number 8 p. 215 2022 0948-5023
Rights: Publisher
Rights: Use of this resource is governed by the terms and conditions of the SpringerLink Terms of Use Statement ( https://link.springer.com/termsandconditions)
Rights: Closed Access

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