Thermoluminescence of α-Al2O3: C, Mg annealed at 1200° C
- Kalita, Jitumani M, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/111030 , vital:33365 , https://doi.org/10.1016/j.nimb.2018.03.003
- Description: Stimulated luminescence in α-Al2O3:C,Mg has thus far been studied for samples annealed at temperature no higher than 900 °C as can be seen by an examination of the literature. We report the thermoluminescence (TL) features of α-Al2O3:C,Mg annealed at 1200 °C. A glow curve measured at 1 °C/s from the samples annealed at 1200 °C shows eight peaks at 54, 80, 102, 173, 238, 290, 330 and 387 °C. Kinetic analyses show that the peak at 54 °C follows general order kinetics (b = 1.3) whereas the rest follow first order kinetics. The values of the activation energy of the peaks are between 0.77 eV and 1.90 eV and the frequency factors are of the order of 1010–1014 s−1. The intensity of the peaks at 54, 80, 102 and 173 °C increase with heating rate whereas those of the peaks at 238 and 290 °C decrease with heating rate. The decrease of intensity of the peaks at 238 and 290 °C with heating rate is due to thermal quenching whereas the increase of intensity of the peaks with heating rate indicates an inverse thermal-quenching-like behaviour. Interestingly this behaviour is observed only after annealing at 1200 °C. The activation energy for thermal quenching as calculated using the peaks at 238 and 290 °C are (1.02 ± 0.16) eV and (1.33 ± 0.15) eV respectively. Regarding the dosimetric features, the dose response of the peaks at 54, 80 and 102 °C are sublinear within 1–10 Gy and the peak at 54 °C saturates above 6 Gy. In contrast, the response of the peak at 173 °C is sublinear with 1–4 Gy and superlinear between 4 and 10 Gy. The peaks are found to fade at different rates and the rate of fading is also affected by annealing.
- Full Text: false
- Date Issued: 2018
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/111030 , vital:33365 , https://doi.org/10.1016/j.nimb.2018.03.003
- Description: Stimulated luminescence in α-Al2O3:C,Mg has thus far been studied for samples annealed at temperature no higher than 900 °C as can be seen by an examination of the literature. We report the thermoluminescence (TL) features of α-Al2O3:C,Mg annealed at 1200 °C. A glow curve measured at 1 °C/s from the samples annealed at 1200 °C shows eight peaks at 54, 80, 102, 173, 238, 290, 330 and 387 °C. Kinetic analyses show that the peak at 54 °C follows general order kinetics (b = 1.3) whereas the rest follow first order kinetics. The values of the activation energy of the peaks are between 0.77 eV and 1.90 eV and the frequency factors are of the order of 1010–1014 s−1. The intensity of the peaks at 54, 80, 102 and 173 °C increase with heating rate whereas those of the peaks at 238 and 290 °C decrease with heating rate. The decrease of intensity of the peaks at 238 and 290 °C with heating rate is due to thermal quenching whereas the increase of intensity of the peaks with heating rate indicates an inverse thermal-quenching-like behaviour. Interestingly this behaviour is observed only after annealing at 1200 °C. The activation energy for thermal quenching as calculated using the peaks at 238 and 290 °C are (1.02 ± 0.16) eV and (1.33 ± 0.15) eV respectively. Regarding the dosimetric features, the dose response of the peaks at 54, 80 and 102 °C are sublinear within 1–10 Gy and the peak at 54 °C saturates above 6 Gy. In contrast, the response of the peak at 173 °C is sublinear with 1–4 Gy and superlinear between 4 and 10 Gy. The peaks are found to fade at different rates and the rate of fading is also affected by annealing.
- Full Text: false
- Date Issued: 2018
A comparative study of the dosimetric features of α-Al2O3: C, Mg and α-Al2O3: C
- Kalita, Jitumani M, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/113058 , vital:33694 , https://doi.org/10.1093/rpd/ncx039
- Description: A comparative study of the dosimetric features of α-Al2O3:C,Mg and α-Al2O3:C relevant to thermoluminescence dosimetry is reported. A glow curve of α-Al2O3:C,Mg measured at 1°C/s after beta irradiation to 1 Gy shows two subsidiary peaks at 42°C (labelled as I) and 72°C (II) and the main peak at 161°C (III) whereas a glow curve of α-Al2O3:C measured under the same conditions shows the main peak at 178°C (II′) and a lower intensity peak at 48°C (I′). Apart from these ones, there are several other peaks at temperatures beyond that of the main peak in both α-Al2O3:C,Mg and α-Al2O3:C. However, the latter are not included in this study. We report a comparative quantitative analysis of dose response and fading of peaks I, II and III of α-Al2O3:C,Mg and peaks I′ and II′ of α-Al2O3:C. Analysis shows that the dose response of peaks I and III is sublinear within 1–10 Gy whereas that of peak II is superlinear within 1–4 Gy followed by a sublinear region within 4–10 Gy. In comparison, the dose response of peak I′ is superlinear within 1–4 Gy followed by a sublinear region within 4–10 Gy whereas that of peak II′ is sublinear within 1–4 Gy followed by a superlinear region within 4–10 Gy. As regards to fading corresponding to 1 Gy, peak I is very unstable and fades within 300 s, peak II is more stable and takes up to 43200 s to fade. In comparison, peak III fades down to 30% of its initial intensity within 2400 s. Interestingly, between 2400 and 800 s, the intensity fades by 17% only. Regarding fading in α-Al2O3:C, peak I′ fades within 600 s whereas peak II′ shows an inverse fading behaviour up to 64800 s. The rate of fading for peaks I, II and III in α-Al2O3:C,Mg was found to decrease with increase in dose. However, no such behaviour was observed in α-Al2O3:C. The fading in both samples is discussed on the basis of a charge hopping mechanism.
- Full Text:
- Date Issued: 2017
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/113058 , vital:33694 , https://doi.org/10.1093/rpd/ncx039
- Description: A comparative study of the dosimetric features of α-Al2O3:C,Mg and α-Al2O3:C relevant to thermoluminescence dosimetry is reported. A glow curve of α-Al2O3:C,Mg measured at 1°C/s after beta irradiation to 1 Gy shows two subsidiary peaks at 42°C (labelled as I) and 72°C (II) and the main peak at 161°C (III) whereas a glow curve of α-Al2O3:C measured under the same conditions shows the main peak at 178°C (II′) and a lower intensity peak at 48°C (I′). Apart from these ones, there are several other peaks at temperatures beyond that of the main peak in both α-Al2O3:C,Mg and α-Al2O3:C. However, the latter are not included in this study. We report a comparative quantitative analysis of dose response and fading of peaks I, II and III of α-Al2O3:C,Mg and peaks I′ and II′ of α-Al2O3:C. Analysis shows that the dose response of peaks I and III is sublinear within 1–10 Gy whereas that of peak II is superlinear within 1–4 Gy followed by a sublinear region within 4–10 Gy. In comparison, the dose response of peak I′ is superlinear within 1–4 Gy followed by a sublinear region within 4–10 Gy whereas that of peak II′ is sublinear within 1–4 Gy followed by a superlinear region within 4–10 Gy. As regards to fading corresponding to 1 Gy, peak I is very unstable and fades within 300 s, peak II is more stable and takes up to 43200 s to fade. In comparison, peak III fades down to 30% of its initial intensity within 2400 s. Interestingly, between 2400 and 800 s, the intensity fades by 17% only. Regarding fading in α-Al2O3:C, peak I′ fades within 600 s whereas peak II′ shows an inverse fading behaviour up to 64800 s. The rate of fading for peaks I, II and III in α-Al2O3:C,Mg was found to decrease with increase in dose. However, no such behaviour was observed in α-Al2O3:C. The fading in both samples is discussed on the basis of a charge hopping mechanism.
- Full Text:
- Date Issued: 2017
Comprehensive kinetic analysis of thermoluminescence peaks of α-Al2O3: C, Mg
- Kalita, Jitumani M, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116142 , vital:34323 , https://doi.org/10.1016/j.jlumin.2017.01.003
- Description: A comprehensive kinetic analysis of the glow peaks in α-Al2O3:C,Mg is reported. A thermoluminescence glow curve measured at 1 °C/s after beta irradiation to 1 Gy shows a high intensity peak hereafter referred to as the main peak at 161 °C and six lower intensity secondary peaks at 42, 72, 193, 279, 330, 370 °C respectively. For ease of reference, the secondary peaks are labelled as I, II, IV, V, VI and VII respectively and the main peak denoted peak III. Kinetic analysis of the glow peaks has been carried out using the initial rise, whole glow peak, peak shape, variable heating rate and glow curve deconvolution methods as well as by way of phosphorescence. Using Tm-Tstop, Tm-dose and phosphorescence analyses, the order of kinetics of the peaks has been evaluated as first order. Analysis by the peak shape, whole glow peak and deconvolution methods produce the same conclusion. The activation energy of peaks I through VII are calculated as ~0.83, 0.96, 1.37, 1.20, 1.15, 1.61 and 1.94 eV respectively. The frequency factors for all the peaks are of the order of 109 to 1014 s−1. The question of thermal quenching affecting the peaks was considered. The peaks III, IV and V, the only ones that could be conveniently studied in this regard, were found to be affected by thermal quenching. The activation energy for thermal quenching was calculated for peak III as 0.96±0.03 eV, for peak VI as 0.95±0.07 eV and for peak V as 1.26±0.08 eV. The thermal quenching phenomenon has been discussed with reference to F+ and F centres. An energy band model has been developed to discuss the luminescence mechanisms in α-Al2O3:C,Mg in light of finding in this work.
- Full Text: false
- Date Issued: 2017
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116142 , vital:34323 , https://doi.org/10.1016/j.jlumin.2017.01.003
- Description: A comprehensive kinetic analysis of the glow peaks in α-Al2O3:C,Mg is reported. A thermoluminescence glow curve measured at 1 °C/s after beta irradiation to 1 Gy shows a high intensity peak hereafter referred to as the main peak at 161 °C and six lower intensity secondary peaks at 42, 72, 193, 279, 330, 370 °C respectively. For ease of reference, the secondary peaks are labelled as I, II, IV, V, VI and VII respectively and the main peak denoted peak III. Kinetic analysis of the glow peaks has been carried out using the initial rise, whole glow peak, peak shape, variable heating rate and glow curve deconvolution methods as well as by way of phosphorescence. Using Tm-Tstop, Tm-dose and phosphorescence analyses, the order of kinetics of the peaks has been evaluated as first order. Analysis by the peak shape, whole glow peak and deconvolution methods produce the same conclusion. The activation energy of peaks I through VII are calculated as ~0.83, 0.96, 1.37, 1.20, 1.15, 1.61 and 1.94 eV respectively. The frequency factors for all the peaks are of the order of 109 to 1014 s−1. The question of thermal quenching affecting the peaks was considered. The peaks III, IV and V, the only ones that could be conveniently studied in this regard, were found to be affected by thermal quenching. The activation energy for thermal quenching was calculated for peak III as 0.96±0.03 eV, for peak VI as 0.95±0.07 eV and for peak V as 1.26±0.08 eV. The thermal quenching phenomenon has been discussed with reference to F+ and F centres. An energy band model has been developed to discuss the luminescence mechanisms in α-Al2O3:C,Mg in light of finding in this work.
- Full Text: false
- Date Issued: 2017
Dose response and kinetic analysis of thermoluminescence of Li–Zn fluoroborate glass
- Thomas, Sunil, Chithambo, Makaiko L
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116164 , vital:34326 , https://doi.org/10.1080/10420150.2017.1313844
- Description: The intention of this study is to explore the thermoluminescence properties of beta-irradiated Li–Zn fluoroborate glass. The glow-curve corresponding to 10 Gy shows two peaks when measured at 1°C/s. The dose response of the glass to beta irradiation was investigated. The trapping level parameters such as activation energy, frequency factor and order of kinetics associated with the observed glow-peak were determined using different methods. The thermoluminescence is affected by thermal quenching. A possible mechanism for the thermoluminescence is described.
- Full Text:
- Date Issued: 2017
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116164 , vital:34326 , https://doi.org/10.1080/10420150.2017.1313844
- Description: The intention of this study is to explore the thermoluminescence properties of beta-irradiated Li–Zn fluoroborate glass. The glow-curve corresponding to 10 Gy shows two peaks when measured at 1°C/s. The dose response of the glass to beta irradiation was investigated. The trapping level parameters such as activation energy, frequency factor and order of kinetics associated with the observed glow-peak were determined using different methods. The thermoluminescence is affected by thermal quenching. A possible mechanism for the thermoluminescence is described.
- Full Text:
- Date Issued: 2017
Factors influencing the shape of CW-OSL signal obtained by stimulation of very deep traps in carbon-doped aluminium oxide: an experimental study
- Nyirenda, Angel N, Chithambo, Makaiko L
- Authors: Nyirenda, Angel N , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115493 , vital:34149 , https://doi.org/10.1016/j.jlumin.2017.07.016
- Description: The optically stimulated luminescence from carbon-doped aluminium oxide (α-Al2O3:C) displays a peak with time under certain measurement conditions. In this paper, we present factors that influence the peak-like shape of continuous-wave optically stimulated luminescence (CW-OSL) signal. The report is based on the experimental study of OSL signals obtained by stimulation of very deep traps in α-Al2O3:C. Methods exploiting post-irradiation annealing, variable dose and temperature dependent OSL measurements were used in the investigation. It is found that the rising part of the CW-OSL peak is obtained when the rate of retrapping at the most optically active trap (main trap) exceeds the rate of direct radiative recombination following optical release of charges from all optically active traps. This is possible if, during optical stimulation, the primary trap responsible for OSL i.e. the main trap, is substantially unoccupied and the very deep, donor traps are substantially filled up. The rate of charge retrapping itself is deduced to depend on the occupancy of the acceptor traps i.e. shallow, main and secondary traps; concentration of charge carriers in the very deep, donor traps; the post-irradiation annealing temperature and the temperature at which the OSL is measured.
- Full Text: false
- Date Issued: 2017
- Authors: Nyirenda, Angel N , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115493 , vital:34149 , https://doi.org/10.1016/j.jlumin.2017.07.016
- Description: The optically stimulated luminescence from carbon-doped aluminium oxide (α-Al2O3:C) displays a peak with time under certain measurement conditions. In this paper, we present factors that influence the peak-like shape of continuous-wave optically stimulated luminescence (CW-OSL) signal. The report is based on the experimental study of OSL signals obtained by stimulation of very deep traps in α-Al2O3:C. Methods exploiting post-irradiation annealing, variable dose and temperature dependent OSL measurements were used in the investigation. It is found that the rising part of the CW-OSL peak is obtained when the rate of retrapping at the most optically active trap (main trap) exceeds the rate of direct radiative recombination following optical release of charges from all optically active traps. This is possible if, during optical stimulation, the primary trap responsible for OSL i.e. the main trap, is substantially unoccupied and the very deep, donor traps are substantially filled up. The rate of charge retrapping itself is deduced to depend on the occupancy of the acceptor traps i.e. shallow, main and secondary traps; concentration of charge carriers in the very deep, donor traps; the post-irradiation annealing temperature and the temperature at which the OSL is measured.
- Full Text: false
- Date Issued: 2017
Features of an annealing-induced thermoluminescence peak in α-Al2O3: C, Mg
- Kalita, Jitumani M, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116013 , vital:34289 , DOI: 10.1016/j.optmat.2017.05.034
- Description: We report the thermoluminescence glow curves of beta irradiated single crystal α-Al2O3:C,Mg after annealing at 700 and 900 °C. A glow curve measured at 1 °C/s from samples irradiated to 1 Gy following annealing at 700 and 900 °C shows a high intensity peak at 163 °C and seven secondary peaks of weaker intensity at 43, 73, 100, 195, 280, 329 and 370 °C. Comparing the position of the peaks in the annealed samples with those in an un-annealed one, it is observed that the peak at 100 °C appears only after annealing at and above 700 °C. Kinetic analysis of this annealing-induced peak was carried out using the initial rise, whole glow peak, peak shape, curve fitting and variable heating rate methods. The order of kinetics of the peak was determined as first order using various methods including the Tm-Tstop technique and the dependence of Tm on irradiation dose. The activation energy of the peak is about 1.01 eV and the frequency factor of the order of 1012 s−1. The peak was found to be affected by thermal quenching in analysis based on change of peak intensity with heating rate. The activation energy of thermal quenching was evaluated as 1.06 ± 0.08 eV. We speculate that the annealing-induced peak is due to formation of a new electron trap after destruction of the F22+(2 Mg) centre when the sample is annealed at 700 °C. The annealing-induced peak fades with storage between irradiation and measurement. It was also concluded that electrons from traps corresponding to secondary peaks get re-trapped at the main electron trap.
- Full Text: false
- Date Issued: 2017
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116013 , vital:34289 , DOI: 10.1016/j.optmat.2017.05.034
- Description: We report the thermoluminescence glow curves of beta irradiated single crystal α-Al2O3:C,Mg after annealing at 700 and 900 °C. A glow curve measured at 1 °C/s from samples irradiated to 1 Gy following annealing at 700 and 900 °C shows a high intensity peak at 163 °C and seven secondary peaks of weaker intensity at 43, 73, 100, 195, 280, 329 and 370 °C. Comparing the position of the peaks in the annealed samples with those in an un-annealed one, it is observed that the peak at 100 °C appears only after annealing at and above 700 °C. Kinetic analysis of this annealing-induced peak was carried out using the initial rise, whole glow peak, peak shape, curve fitting and variable heating rate methods. The order of kinetics of the peak was determined as first order using various methods including the Tm-Tstop technique and the dependence of Tm on irradiation dose. The activation energy of the peak is about 1.01 eV and the frequency factor of the order of 1012 s−1. The peak was found to be affected by thermal quenching in analysis based on change of peak intensity with heating rate. The activation energy of thermal quenching was evaluated as 1.06 ± 0.08 eV. We speculate that the annealing-induced peak is due to formation of a new electron trap after destruction of the F22+(2 Mg) centre when the sample is annealed at 700 °C. The annealing-induced peak fades with storage between irradiation and measurement. It was also concluded that electrons from traps corresponding to secondary peaks get re-trapped at the main electron trap.
- Full Text: false
- Date Issued: 2017
Kinetic analysis and general features of thermoluminescence of B2O3-Li2O-ZnF2 glass
- Thomas, Sunil, Chithambo, Makaiko L
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116154 , vital:34324 , https://doi.org/10.1016/j.radmeas.2017.03.038
- Description: The intention of this study is to explore the thermoluminescence of beta irradiated B2O3-Li2O-ZnF2 glass. The glow-curve corresponding to 200 Gy shows three peaks; two weak-intensity peaks at 60 and 243 °C and a more prominent one at 118 °C, when measured at 1 °C/s. The dose response of the main peak at 118 °C was found to be sublinear in the range 200–1000 Gy. Regarding the kinetic analysis of the main peak, the activation energy of the corresponding electron trap was evaluated as 0.96 eV and the frequency factor as ∼1011 s−1. It is proposed that the thermoluminescence in B2O3-Li2O-ZnF2 glass is due to recombination of electrons, thermally released from Zn+ ionic defect sites, with the holes at boron-oxygen hole centres.
- Full Text: false
- Date Issued: 2017
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116154 , vital:34324 , https://doi.org/10.1016/j.radmeas.2017.03.038
- Description: The intention of this study is to explore the thermoluminescence of beta irradiated B2O3-Li2O-ZnF2 glass. The glow-curve corresponding to 200 Gy shows three peaks; two weak-intensity peaks at 60 and 243 °C and a more prominent one at 118 °C, when measured at 1 °C/s. The dose response of the main peak at 118 °C was found to be sublinear in the range 200–1000 Gy. Regarding the kinetic analysis of the main peak, the activation energy of the corresponding electron trap was evaluated as 0.96 eV and the frequency factor as ∼1011 s−1. It is proposed that the thermoluminescence in B2O3-Li2O-ZnF2 glass is due to recombination of electrons, thermally released from Zn+ ionic defect sites, with the holes at boron-oxygen hole centres.
- Full Text: false
- Date Issued: 2017
On the sensitivity of thermally and optically stimulated luminescence of α-Al2O3: C and α-Al2O3: C, Mg
- Kalita, Jitumani M, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119803 , vital:34784 , https://doi.org/10.1016/j.radmeas.2017.03.006
- Description: The luminescence sensitivity of α-Al2O3:C and α-Al2O3:C, Mg is of interest because of the contemporary use of these materials in dosimetry related applications. We report investigations concerning the change in sensitivity of thermoluminescence (TL) and optically stimulated luminescence (OSL) from α-Al2O3:C and α-Al2O3:C, Mg with re-use. The study was carried out on a set of un-annealed samples and others annealed at 700 and 900 °C. The TL and OSL sensitivity in α-Al2O3:C and α-Al2O3:C, Mg was found to increase with sample re-use whether the intensity was monitored as peak area or peak height for the main TL peak or, in the case of OSL, as the maximum intensity or the area under a decay curve. The fractional increase in area under either the main TL peak or the OSL decay curve exceeds that of the TL peak height or maximum OSL intensity when samples are re-used. However, when un-annealed samples are used, any increase in TL peak height or peak area per measurement is less than observed in annealed samples. It is also interesting to note that the change in maximum OSL intensity or OSL area is minimal for samples annealed at 900 °C. In general, the TL sensitivity in α-Al2O3:C increases more than that in α-Al2O3:C, Mg with re-use. On the other hand, the OSL sensitivity in α-Al2O3:C, Mg increases more than that in α-Al2O3:C with re-use. These findings suggest that it is advisable to take into account the fractional increase in sensitivity per measurement when one uses α-Al2O3:C as a TL dosimeter and α-Al2O3:C, Mg as an OSL dosimeter.
- Full Text: false
- Date Issued: 2017
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119803 , vital:34784 , https://doi.org/10.1016/j.radmeas.2017.03.006
- Description: The luminescence sensitivity of α-Al2O3:C and α-Al2O3:C, Mg is of interest because of the contemporary use of these materials in dosimetry related applications. We report investigations concerning the change in sensitivity of thermoluminescence (TL) and optically stimulated luminescence (OSL) from α-Al2O3:C and α-Al2O3:C, Mg with re-use. The study was carried out on a set of un-annealed samples and others annealed at 700 and 900 °C. The TL and OSL sensitivity in α-Al2O3:C and α-Al2O3:C, Mg was found to increase with sample re-use whether the intensity was monitored as peak area or peak height for the main TL peak or, in the case of OSL, as the maximum intensity or the area under a decay curve. The fractional increase in area under either the main TL peak or the OSL decay curve exceeds that of the TL peak height or maximum OSL intensity when samples are re-used. However, when un-annealed samples are used, any increase in TL peak height or peak area per measurement is less than observed in annealed samples. It is also interesting to note that the change in maximum OSL intensity or OSL area is minimal for samples annealed at 900 °C. In general, the TL sensitivity in α-Al2O3:C increases more than that in α-Al2O3:C, Mg with re-use. On the other hand, the OSL sensitivity in α-Al2O3:C, Mg increases more than that in α-Al2O3:C with re-use. These findings suggest that it is advisable to take into account the fractional increase in sensitivity per measurement when one uses α-Al2O3:C as a TL dosimeter and α-Al2O3:C, Mg as an OSL dosimeter.
- Full Text: false
- Date Issued: 2017
Phototransferred thermoluminescence in α-Al2O3: C, Mg under 470 nm blue light stimulation
- Kalita, Jitumani M, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116026 , vital:34290 , https://doi.org/10.1016/j.jlumin.2017.04.059
- Description: Phototransferred thermoluminescence (PTTL) in α-Al2O3:C,Mg under 470 nm blue light has been investigated. Conventional thermoluminescence (TL) measured at 1 °C/s following irradiation to 10 Gy shows the main peak (labelled as III) at 163 °C and six secondary peaks I, II, IV, V, VI and VII at 45, 74, 200, 279, 328, 370 °C respectively. When a sample irradiated to 10 Gy is preheated to 220 °C at 1 °C/s to remove peaks I, II, III and IV and then exposed to 470 nm blue light for 100 s, it is found that three peaks I, II and III are reproduced under phototransfer. Kinetic analysis of the PTTL peaks shows that their kinetic parameters are similar to those of peaks I, II and III from conventional TL. Pulse annealing experiments, intended to study the dependence of PTTL peak intensity on preheating temperature, show that the electron traps corresponding to peaks V, VI and VII act as donor traps whereas the traps corresponding to peaks I, II and III act as acceptor traps. Further, it was found that no PTTL can be generated when all the traps corresponding to peaks I, II…VII are erased by preheating after irradiation. The primary conclusion here is that α-Al2O3:C,Mg does not have any deep traps beyond 400 °C sensitive to 470 nm stimulation or if there are any, their concentration is negligible. The PTTL for any of the PTTL peaks mentioned earlier increases with illumination time to a maximum within 400 s for measurements corresponding to doses between 6 and 15 Gy. The dose response of PTTL peaks II and III is linear within 1–15 Gy. Regarding fading, PTTL peak II fades to background level within 18000 s whereas in the same time, PTTL peak III fades down to 40% of its initial intensity.
- Full Text: false
- Date Issued: 2017
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116026 , vital:34290 , https://doi.org/10.1016/j.jlumin.2017.04.059
- Description: Phototransferred thermoluminescence (PTTL) in α-Al2O3:C,Mg under 470 nm blue light has been investigated. Conventional thermoluminescence (TL) measured at 1 °C/s following irradiation to 10 Gy shows the main peak (labelled as III) at 163 °C and six secondary peaks I, II, IV, V, VI and VII at 45, 74, 200, 279, 328, 370 °C respectively. When a sample irradiated to 10 Gy is preheated to 220 °C at 1 °C/s to remove peaks I, II, III and IV and then exposed to 470 nm blue light for 100 s, it is found that three peaks I, II and III are reproduced under phototransfer. Kinetic analysis of the PTTL peaks shows that their kinetic parameters are similar to those of peaks I, II and III from conventional TL. Pulse annealing experiments, intended to study the dependence of PTTL peak intensity on preheating temperature, show that the electron traps corresponding to peaks V, VI and VII act as donor traps whereas the traps corresponding to peaks I, II and III act as acceptor traps. Further, it was found that no PTTL can be generated when all the traps corresponding to peaks I, II…VII are erased by preheating after irradiation. The primary conclusion here is that α-Al2O3:C,Mg does not have any deep traps beyond 400 °C sensitive to 470 nm stimulation or if there are any, their concentration is negligible. The PTTL for any of the PTTL peaks mentioned earlier increases with illumination time to a maximum within 400 s for measurements corresponding to doses between 6 and 15 Gy. The dose response of PTTL peaks II and III is linear within 1–15 Gy. Regarding fading, PTTL peak II fades to background level within 18000 s whereas in the same time, PTTL peak III fades down to 40% of its initial intensity.
- Full Text: false
- Date Issued: 2017
Phototransferred thermoluminescence of α-Al2O3: C: experimental results and empirical models
- Chithambo, Makaiko L, Seneza, Cleophace, Kalita, Jitumani M
- Authors: Chithambo, Makaiko L , Seneza, Cleophace , Kalita, Jitumani M
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115681 , vital:34215 , https://doi.org/10.1016/j.radmeas.2017.08.009
- Description: The thermoluminescence glow curve of α-Al2O3:C consists of a prominent apparently-single peak and a number of weaker intensity secondary peaks. Phototransferred thermoluminescence (PTTL) from secondary glow peaks in α-Al2O3:C is reported. For completeness and to aid discussion, complementary results for the main peak are included. The problem studied is one of phototransferred thermoluminescence for a system of multiple acceptors and multiple donors. A TL glow curve recorded at 5 °C/s following irradiation to 0.5 Gy shows the main peak (labelled II) at 240 °C and two secondary peaks at 86 °C (peak I) and 360 °C (peak III). Peak I is reproduced under phototransfer after any preheating between 100 and 500 °C. Peak II is also reproduced as a PTTL peak after preheating to any temperature up to 800 °C. For the latter, the duration of preheating matters because if the sample is preheated at 800 °C for say, 6 min, PTTL is obtained but not when this is extended to say, 15 min. No PTTL was observed from peak III at all. A study of the time dependence of the PTTL intensity from peak III, following preheating that removes peaks I and II, shows that its electron trap acts as an acceptor when the duration of illumination to stimulate electrons from deep traps is brief but that when the illumination time is extended, the electron trap for peak III loses some of its trapped electrons to the shallower traps thus acting as a donor trap.
- Full Text: false
- Date Issued: 2017
- Authors: Chithambo, Makaiko L , Seneza, Cleophace , Kalita, Jitumani M
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115681 , vital:34215 , https://doi.org/10.1016/j.radmeas.2017.08.009
- Description: The thermoluminescence glow curve of α-Al2O3:C consists of a prominent apparently-single peak and a number of weaker intensity secondary peaks. Phototransferred thermoluminescence (PTTL) from secondary glow peaks in α-Al2O3:C is reported. For completeness and to aid discussion, complementary results for the main peak are included. The problem studied is one of phototransferred thermoluminescence for a system of multiple acceptors and multiple donors. A TL glow curve recorded at 5 °C/s following irradiation to 0.5 Gy shows the main peak (labelled II) at 240 °C and two secondary peaks at 86 °C (peak I) and 360 °C (peak III). Peak I is reproduced under phototransfer after any preheating between 100 and 500 °C. Peak II is also reproduced as a PTTL peak after preheating to any temperature up to 800 °C. For the latter, the duration of preheating matters because if the sample is preheated at 800 °C for say, 6 min, PTTL is obtained but not when this is extended to say, 15 min. No PTTL was observed from peak III at all. A study of the time dependence of the PTTL intensity from peak III, following preheating that removes peaks I and II, shows that its electron trap acts as an acceptor when the duration of illumination to stimulate electrons from deep traps is brief but that when the illumination time is extended, the electron trap for peak III loses some of its trapped electrons to the shallower traps thus acting as a donor trap.
- Full Text: false
- Date Issued: 2017
Radioluminescence of annealed synthetic quartz
- Chithambo, Makaiko L, Niyonzima, P
- Authors: Chithambo, Makaiko L , Niyonzima, P
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115504 , vital:34150 , https://doi.org/10.1016/j.radmeas.2017.02.005
- Description: The radioluminescence of synthetic quartz annealed at various temperatures up to 1000 °C is reported. The amplitude of the emission bands increases with annealing temperature. In addition, when samples are annealed at temperatures exceeding 700 °C, the intensity of the radioluminescence increases with duration of annealing. The corresponding emission spectra show seven emission bands at 2.04, 2.54, 2.77, 3.04, 3.40, 3.75 and 3.91 eV. The change in dominant emission band with annealing is consistent with annealing-induced variations in lifetimes determined previously from time-resolved optically stimulated luminescence spectra in the same samples.
- Full Text: false
- Date Issued: 2017
- Authors: Chithambo, Makaiko L , Niyonzima, P
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115504 , vital:34150 , https://doi.org/10.1016/j.radmeas.2017.02.005
- Description: The radioluminescence of synthetic quartz annealed at various temperatures up to 1000 °C is reported. The amplitude of the emission bands increases with annealing temperature. In addition, when samples are annealed at temperatures exceeding 700 °C, the intensity of the radioluminescence increases with duration of annealing. The corresponding emission spectra show seven emission bands at 2.04, 2.54, 2.77, 3.04, 3.40, 3.75 and 3.91 eV. The change in dominant emission band with annealing is consistent with annealing-induced variations in lifetimes determined previously from time-resolved optically stimulated luminescence spectra in the same samples.
- Full Text: false
- Date Issued: 2017
Relative features of the principal and secondary luminescence lifetimes in quartz
- Chithambo, Makaiko L, Ogundare, F O
- Authors: Chithambo, Makaiko L , Ogundare, F O
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125821 , vital:35820 , https://doi.10.1002/pssc.200673721
- Description: Quartz is a common natural mineral with properties that make it amenable for application in radiation dosimetry using luminescence methods [1]. The luminescence properties of quartz including its sensitivity and luminescence lifetimes undergo notable changes when the quartz is annealed, and in particular, near its phase inversion temperatures of 573 and 867 oC [2, 3]. The physical processes leading up to the emission of luminescence in quartz may be investigated using time-resolved optical stimulation. The aim of this method is to separate in time the stimulation and emission of luminescence to enable measurement of time-resolved luminescence spectra which may be resolved into associated lifetimes, defined in this sense as the delay between stimulation and emission of luminescence [4, 5]. A number of such studies show that annealing defines the detailed distribution of lifetimes with measurement temperature as well as the irradiation-dependent characteristics of the lifetimes [3, 6]. In particular, it was noted [3] that spectra measured at certain temperatures could be accurately resolved into more than one component, a scenario that pointed to the possibility of involvement of multiple luminescence centers in the emission of luminescence from quartz. The aim of this work is to build on the findings described, specifically to study the influence of measurement temperature and irradiation on the principal and subsidiary luminescence lifetimes in natural quartz.
- Full Text:
- Date Issued: 2017
- Authors: Chithambo, Makaiko L , Ogundare, F O
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125821 , vital:35820 , https://doi.10.1002/pssc.200673721
- Description: Quartz is a common natural mineral with properties that make it amenable for application in radiation dosimetry using luminescence methods [1]. The luminescence properties of quartz including its sensitivity and luminescence lifetimes undergo notable changes when the quartz is annealed, and in particular, near its phase inversion temperatures of 573 and 867 oC [2, 3]. The physical processes leading up to the emission of luminescence in quartz may be investigated using time-resolved optical stimulation. The aim of this method is to separate in time the stimulation and emission of luminescence to enable measurement of time-resolved luminescence spectra which may be resolved into associated lifetimes, defined in this sense as the delay between stimulation and emission of luminescence [4, 5]. A number of such studies show that annealing defines the detailed distribution of lifetimes with measurement temperature as well as the irradiation-dependent characteristics of the lifetimes [3, 6]. In particular, it was noted [3] that spectra measured at certain temperatures could be accurately resolved into more than one component, a scenario that pointed to the possibility of involvement of multiple luminescence centers in the emission of luminescence from quartz. The aim of this work is to build on the findings described, specifically to study the influence of measurement temperature and irradiation on the principal and subsidiary luminescence lifetimes in natural quartz.
- Full Text:
- Date Issued: 2017
Structural and optical properties of sol-gel derived α-Fe2O3 nanoparticles
- Mathevula, Langutani E, Noto, L L, Mothudi, Bakang M, Chithambo, Makaiko L, Dhlamini, M S
- Authors: Mathevula, Langutani E , Noto, L L , Mothudi, Bakang M , Chithambo, Makaiko L , Dhlamini, M S
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115467 , vital:34145 , DOI: 10.1016/j.jlumin.2017.07.055
- Description: α-Fe2O3 nanoparticles of crystallite size between 3.9 and 9.5 nm were synthesized by a simple sol-gel method using iron (III) nitrate nonahydrate (Fe(NO3)3·9H2O) as a precursor. Polyvinyl alcohol (PVA) was added as a capping agent to avoid agglomeration of the nanoparticles. A single pure phase was obtained when the sample was annealed at 300 °C and 600 °C. The purity was further confirmed with the Fourier Transform Infrared Spectroscopy. The energy band gap of the materials was extrapolated from the Kubelka-Munk relation and it ranges between 1.8 and 2.3 eV. The Photoluminescence of the 3 samples shows a broad emission spectrum centered at about 422 nm when excited by a 336 nm lamp. The emission peaks intensities increased with an increase in the annealing temperature, accept for the 576 nm peak, which was quenched as the temperature increased from 300 °C to 600 °C. The thermoluminescence glow curves were carried out at different heating rates and the samples were exposed to different beta particle doses (82–1315 Gy). The activation energy of the trapped electrons was determined.
- Full Text: false
- Date Issued: 2017
- Authors: Mathevula, Langutani E , Noto, L L , Mothudi, Bakang M , Chithambo, Makaiko L , Dhlamini, M S
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115467 , vital:34145 , DOI: 10.1016/j.jlumin.2017.07.055
- Description: α-Fe2O3 nanoparticles of crystallite size between 3.9 and 9.5 nm were synthesized by a simple sol-gel method using iron (III) nitrate nonahydrate (Fe(NO3)3·9H2O) as a precursor. Polyvinyl alcohol (PVA) was added as a capping agent to avoid agglomeration of the nanoparticles. A single pure phase was obtained when the sample was annealed at 300 °C and 600 °C. The purity was further confirmed with the Fourier Transform Infrared Spectroscopy. The energy band gap of the materials was extrapolated from the Kubelka-Munk relation and it ranges between 1.8 and 2.3 eV. The Photoluminescence of the 3 samples shows a broad emission spectrum centered at about 422 nm when excited by a 336 nm lamp. The emission peaks intensities increased with an increase in the annealing temperature, accept for the 576 nm peak, which was quenched as the temperature increased from 300 °C to 600 °C. The thermoluminescence glow curves were carried out at different heating rates and the samples were exposed to different beta particle doses (82–1315 Gy). The activation energy of the trapped electrons was determined.
- Full Text: false
- Date Issued: 2017
Temperature dependence of optically stimulated luminescence of α-Al2O3: C, Mg
- Kalita, Jitumani M, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115708 , vital:34217 , https://doi.org/10.1016/j.radmeas.2017.08.009
- Description: Thermal assistance and thermal quenching are two independently acting thermodynamic phenomena that simultaneously affect the stimulation of luminescence. We have studied thermal assistance to luminescence optically stimulated from α-Al2O3:C,Mg. Since thermal assistance causes only a minor change in the luminescence intensity, measurements were made after the sample had been pre-exposed to stimulating light to reduce its intensity significantly, that is, in the slow component of its decay curve. The luminescence intensity was monitored as a function of measurement temperature between 30 and 130 °C. The intensity goes through a peak at 60 °C due to competing effects of thermal assistance and thermal quenching. The initial increase of intensity is attributed to dominant thermal assistance whereas the subsequent decrease of intensity is ascribed to dominant thermal quenching. The activation energy for thermal assistance was calculated for the main electron trap of an un-annealed sample as 0.324 ± 0.020 eV and in a sample annealed at 900 °C as 0.416 ± 0.028 eV. Implications of such differences in the value of the activation energy for thermal assistance are considered.
- Full Text: false
- Date Issued: 2017
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115708 , vital:34217 , https://doi.org/10.1016/j.radmeas.2017.08.009
- Description: Thermal assistance and thermal quenching are two independently acting thermodynamic phenomena that simultaneously affect the stimulation of luminescence. We have studied thermal assistance to luminescence optically stimulated from α-Al2O3:C,Mg. Since thermal assistance causes only a minor change in the luminescence intensity, measurements were made after the sample had been pre-exposed to stimulating light to reduce its intensity significantly, that is, in the slow component of its decay curve. The luminescence intensity was monitored as a function of measurement temperature between 30 and 130 °C. The intensity goes through a peak at 60 °C due to competing effects of thermal assistance and thermal quenching. The initial increase of intensity is attributed to dominant thermal assistance whereas the subsequent decrease of intensity is ascribed to dominant thermal quenching. The activation energy for thermal assistance was calculated for the main electron trap of an un-annealed sample as 0.324 ± 0.020 eV and in a sample annealed at 900 °C as 0.416 ± 0.028 eV. Implications of such differences in the value of the activation energy for thermal assistance are considered.
- Full Text: false
- Date Issued: 2017
Temperature-dependence of time-resolved optically stimulated luminescence and composition heterogeneity of synthetic α-Al2O3: C
- Chithambo, Makaiko L, Costin, G
- Authors: Chithambo, Makaiko L , Costin, G
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124172 , vital:35573 , https://doi.org/10.1016/j.jlumin.2016.10.038
- Description: The relationship of pulse-width, lifetime and measurement temperature in describing intensity of time-resolved luminescence optically stimulated at 470 nm from α-Al2O3:C is reported. The change of luminescence intensity with stimulation temperature is discussed in terms of the signal integrated over a complete time-resolved luminescence spectrum or in terms of ratios of the signal emitted either during or after pulsed stimulation to the total signal obtained per spectrum. The temperature-induced change in these parameters depends on whether the pulse-width is less or more than the luminescence lifetime. This is because the lifetime in α-Al2O3:C varies with measurement temperature. We have developed and applied new models to distinguish thermal assistance from different traps and to use this information as an additional means to analyse thermal quenching by using the luminescence intensity integrated from time-resolved spectra. Using a model based on use of the throughput, the activation energy for thermal assistance was determined for the shallow trap as 0.054±0.001 eV and as 0.53±0.03 eV for the main trap. The activation energy for thermal quenching was then evaluated using luminescence yield during the pulse as 1.09±0.01 eV and as 1.12±0.01 eV using the throughput after the pulse. Using the new analytical method based on integrated intensity, the activation energy for thermal quenching was found as 1.00±0.07 eV. These values are self-consistent and show that the methods for analyzing temperature-induced changes in intensity and the attendant thermal effects, such as thermal assistance can be successfully applied. We have also reported a general mathematical model that accounts for the temperature-dependence of time-resolved luminescence from α-Al2O3:C. The luminescence study was complemented by investigation of the phase and composition heterogeneity of the samples.
- Full Text: false
- Date Issued: 2017
- Authors: Chithambo, Makaiko L , Costin, G
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124172 , vital:35573 , https://doi.org/10.1016/j.jlumin.2016.10.038
- Description: The relationship of pulse-width, lifetime and measurement temperature in describing intensity of time-resolved luminescence optically stimulated at 470 nm from α-Al2O3:C is reported. The change of luminescence intensity with stimulation temperature is discussed in terms of the signal integrated over a complete time-resolved luminescence spectrum or in terms of ratios of the signal emitted either during or after pulsed stimulation to the total signal obtained per spectrum. The temperature-induced change in these parameters depends on whether the pulse-width is less or more than the luminescence lifetime. This is because the lifetime in α-Al2O3:C varies with measurement temperature. We have developed and applied new models to distinguish thermal assistance from different traps and to use this information as an additional means to analyse thermal quenching by using the luminescence intensity integrated from time-resolved spectra. Using a model based on use of the throughput, the activation energy for thermal assistance was determined for the shallow trap as 0.054±0.001 eV and as 0.53±0.03 eV for the main trap. The activation energy for thermal quenching was then evaluated using luminescence yield during the pulse as 1.09±0.01 eV and as 1.12±0.01 eV using the throughput after the pulse. Using the new analytical method based on integrated intensity, the activation energy for thermal quenching was found as 1.00±0.07 eV. These values are self-consistent and show that the methods for analyzing temperature-induced changes in intensity and the attendant thermal effects, such as thermal assistance can be successfully applied. We have also reported a general mathematical model that accounts for the temperature-dependence of time-resolved luminescence from α-Al2O3:C. The luminescence study was complemented by investigation of the phase and composition heterogeneity of the samples.
- Full Text: false
- Date Issued: 2017
The influence of dose on the kinetic parameters and dosimetric features of the main thermoluminescence glow peak in α-Al2O3: C, Mg
- Kalita, Jitumani M, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119834 , vital:34787 , https://doi.org/10.1016/j.nimb.2016.12.027
- Description: The influence of dose (0.1–100 Gy) on the kinetic parameters and the dosimetric features of the main glow peak of α-Al2O3:C,Mg have been investigated. Thermoluminescence (TL) measured at 1 °C/s shows a very high intensity glow peak at 161 °C and six secondary peaks at 42, 72, 193, 279, 330, 370 °C respectively. Analysis shows that the main peak follows first order kinetics irrespective of the irradiation dose. The activation energy is found to be consistent at 1.37 eV and the frequency factor is of the order of 1014 s−1 for any dose between 0.1 and 100 Gy. Further, the analysis for thermal quenching of the main peak of 0.1 Gy irradiated sample shows that the activation energy for thermal quenching is (0.94 ± 0.04) eV.
- Full Text: false
- Date Issued: 2017
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119834 , vital:34787 , https://doi.org/10.1016/j.nimb.2016.12.027
- Description: The influence of dose (0.1–100 Gy) on the kinetic parameters and the dosimetric features of the main glow peak of α-Al2O3:C,Mg have been investigated. Thermoluminescence (TL) measured at 1 °C/s shows a very high intensity glow peak at 161 °C and six secondary peaks at 42, 72, 193, 279, 330, 370 °C respectively. Analysis shows that the main peak follows first order kinetics irrespective of the irradiation dose. The activation energy is found to be consistent at 1.37 eV and the frequency factor is of the order of 1014 s−1 for any dose between 0.1 and 100 Gy. Further, the analysis for thermal quenching of the main peak of 0.1 Gy irradiated sample shows that the activation energy for thermal quenching is (0.94 ± 0.04) eV.
- Full Text: false
- Date Issued: 2017
The influence of radiation-induced defects on thermoluminescence and optically stimulated luminescence of α-Al2O3: C
- Nyirenda, Angel N, Chithambo, Makaiko L
- Authors: Nyirenda, Angel N , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119818 , vital:34786 , https://doi.org/10.1016/j.nimb.2017.02.077
- Description: It is known that when α-Al2O3:C is exposed to excessive amounts of ionising radiation, defects are induced within its matrix. We report the influence of radiation-induced defects on the thermoluminescence (TL) and optically stimulated luminescence (OSL) measured from α-Al2O3:C after irradiation to 1000 Gy. These radiation-induced defects are thermally unstable in the region 450–650 °C and result in TL peaks in this range when the TL is measured at 1 °C/s. Heating a sample to 700 °C obliterates the radiation-induced defects, that is, the TL peaks corresponding to the radiation induced defects are no longer observed in the subsequent TL measurements when moderate irradiation doses below 10 Gy are used. The charge traps associated with these radiation-induced defects are more stable than the dosimetric trap when the sample is exposed to either sunlight or 470-nm blue light from LEDs. TL glow curves measured following the defect-inducing irradiation produce a dosimetric peak that is broader and positioned at a higher temperature than observed in glow curves obtained before the heavy irradiation. In addition, sample sensitization/desensitization occurs due to the presence of these radiation-induced defects. Furthermore, both the activation energy and the kinetic order of the dosimetric peak evaluated when the radiation-induced defects are present in the sample are significantly lower in value than those obtained when these defects are absent. The radiation-induced defects also affect the shape and total light sum of the OSL signal as well as the position and width of the resultant residual phototransferred thermoluminescence main peak.
- Full Text: false
- Date Issued: 2017
- Authors: Nyirenda, Angel N , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119818 , vital:34786 , https://doi.org/10.1016/j.nimb.2017.02.077
- Description: It is known that when α-Al2O3:C is exposed to excessive amounts of ionising radiation, defects are induced within its matrix. We report the influence of radiation-induced defects on the thermoluminescence (TL) and optically stimulated luminescence (OSL) measured from α-Al2O3:C after irradiation to 1000 Gy. These radiation-induced defects are thermally unstable in the region 450–650 °C and result in TL peaks in this range when the TL is measured at 1 °C/s. Heating a sample to 700 °C obliterates the radiation-induced defects, that is, the TL peaks corresponding to the radiation induced defects are no longer observed in the subsequent TL measurements when moderate irradiation doses below 10 Gy are used. The charge traps associated with these radiation-induced defects are more stable than the dosimetric trap when the sample is exposed to either sunlight or 470-nm blue light from LEDs. TL glow curves measured following the defect-inducing irradiation produce a dosimetric peak that is broader and positioned at a higher temperature than observed in glow curves obtained before the heavy irradiation. In addition, sample sensitization/desensitization occurs due to the presence of these radiation-induced defects. Furthermore, both the activation energy and the kinetic order of the dosimetric peak evaluated when the radiation-induced defects are present in the sample are significantly lower in value than those obtained when these defects are absent. The radiation-induced defects also affect the shape and total light sum of the OSL signal as well as the position and width of the resultant residual phototransferred thermoluminescence main peak.
- Full Text: false
- Date Issued: 2017
Thermally-assisted optically stimulated luminescence from deep electron traps in α-Al2O3: C, Mg
- Kalita, Jitumani M, Chithambo, Makaiko L, Polymeris, G S
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L , Polymeris, G S
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116133 , vital:34322 , https://doi.org/10.1016/j.nimb.2017.04.075
- Description: We report thermally-assisted optically stimulated luminescence (TA-OSL) in α-Al2O3:C,Mg. The OSL was measured at elevated temperatures between 50 and 240 °C from a sample preheated to 500 °C after irradiation to 100 Gy. That OSL could be measured even after the preheating is direct evidence of the existence of deep electron traps in α-Al2O3:C,Mg. The TA-OSL intensity goes through a peak with measurement temperature. The initial increase is ascribed to thermal assistance to optical stimulation whereas the subsequent decrease in intensity is deduced to reflect increasing incidences of non-radiative recombination, that is, thermal quenching. The activation energy for thermal assistance corresponding to a deep electron trap was estimated as 0.667 ± 0.006 eV whereas the activation energy for thermal quenching was calculated as 0.90 ± 0.04 eV. The intensity of the TA-OSL was also found to increase with irradiation dose. The dose response is sublinear from 25 to 150 Gy but saturates with further increase of dose. The TA-OSL dose response has been discussed by considering the competition for charges at the deep traps. This study incidentally shows that TA-OSL can be effectively used in dosimetry involving large doses.
- Full Text: false
- Date Issued: 2017
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L , Polymeris, G S
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116133 , vital:34322 , https://doi.org/10.1016/j.nimb.2017.04.075
- Description: We report thermally-assisted optically stimulated luminescence (TA-OSL) in α-Al2O3:C,Mg. The OSL was measured at elevated temperatures between 50 and 240 °C from a sample preheated to 500 °C after irradiation to 100 Gy. That OSL could be measured even after the preheating is direct evidence of the existence of deep electron traps in α-Al2O3:C,Mg. The TA-OSL intensity goes through a peak with measurement temperature. The initial increase is ascribed to thermal assistance to optical stimulation whereas the subsequent decrease in intensity is deduced to reflect increasing incidences of non-radiative recombination, that is, thermal quenching. The activation energy for thermal assistance corresponding to a deep electron trap was estimated as 0.667 ± 0.006 eV whereas the activation energy for thermal quenching was calculated as 0.90 ± 0.04 eV. The intensity of the TA-OSL was also found to increase with irradiation dose. The dose response is sublinear from 25 to 150 Gy but saturates with further increase of dose. The TA-OSL dose response has been discussed by considering the competition for charges at the deep traps. This study incidentally shows that TA-OSL can be effectively used in dosimetry involving large doses.
- Full Text: false
- Date Issued: 2017
Thermoluminescence of K-Mg-Al-Zn fluorophosphate glass
- Thomas, Sunil, Chithambo, Makaiko L
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124188 , vital:35574 , https://doi.org/10.1016/j.optmat.2016.12.035
- Description: The thermoluminescence of beta irradiated K-Mg-Al-Zn fluorophosphate glass is reported. A glow-curve corresponding to 10 Gy measured at 1 °C/s shows two peaks, a weaker-intensity one at 70 °C and a more prominent one at 235 °C, the subject of this report. The main peak was observed to fade with delay between irradiation and measurement and specifically, by 11% in 15 h. Its dose response is superlinear in the dose range 1–190 Gy although the change was linear for the initial 10 Gy. Regarding kinetic analysis, the activation energy of the higher temperature peak was evaluated as 1.31 eV and that of the lower temperature peak was found as 0.47 eV. It was also noted that the main peak is affected by thermal quenching with an activation energy for thermal quenching equal to 1.37 eV. It is proposed that the mechanism associated with the thermoluminescence in K-Mg-Al-Zn fluorophosphate glass is that electrons trapped by the metal cations are released during heating and then recombine with holes at oxygen sites.
- Full Text: false
- Date Issued: 2017
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124188 , vital:35574 , https://doi.org/10.1016/j.optmat.2016.12.035
- Description: The thermoluminescence of beta irradiated K-Mg-Al-Zn fluorophosphate glass is reported. A glow-curve corresponding to 10 Gy measured at 1 °C/s shows two peaks, a weaker-intensity one at 70 °C and a more prominent one at 235 °C, the subject of this report. The main peak was observed to fade with delay between irradiation and measurement and specifically, by 11% in 15 h. Its dose response is superlinear in the dose range 1–190 Gy although the change was linear for the initial 10 Gy. Regarding kinetic analysis, the activation energy of the higher temperature peak was evaluated as 1.31 eV and that of the lower temperature peak was found as 0.47 eV. It was also noted that the main peak is affected by thermal quenching with an activation energy for thermal quenching equal to 1.37 eV. It is proposed that the mechanism associated with the thermoluminescence in K-Mg-Al-Zn fluorophosphate glass is that electrons trapped by the metal cations are released during heating and then recombine with holes at oxygen sites.
- Full Text: false
- Date Issued: 2017
Thermoluminescence of SrAl2O4: Eu2+, Dy3+: kinetic analysis of a composite-peak
- Chithambo, Makaiko L, Wako, A H, Finch, A A
- Authors: Chithambo, Makaiko L , Wako, A H , Finch, A A
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124157 , vital:35571 , https://doi.org/10.1016/j.radmeas.2016.12.009
- Description: The kinetic analysis of thermoluminescence of beta-irradiated SrAl2O4:Eu2+,Dy3+ is reported. The glow-curve is dominated by an apparently-single peak. It has been demonstrated using a number of tests including partial dynamic-heating, isothermal heating, phosphorescence and, the effect of fading, that the peak and the glow-curve consists of a set of closely-spaced peaks. In view of the peak being complex, its first few components were abstracted and analysed and for comparison, the peak was also analysed assuming it is genuinely single.
- Full Text: false
- Date Issued: 2017
- Authors: Chithambo, Makaiko L , Wako, A H , Finch, A A
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124157 , vital:35571 , https://doi.org/10.1016/j.radmeas.2016.12.009
- Description: The kinetic analysis of thermoluminescence of beta-irradiated SrAl2O4:Eu2+,Dy3+ is reported. The glow-curve is dominated by an apparently-single peak. It has been demonstrated using a number of tests including partial dynamic-heating, isothermal heating, phosphorescence and, the effect of fading, that the peak and the glow-curve consists of a set of closely-spaced peaks. In view of the peak being complex, its first few components were abstracted and analysed and for comparison, the peak was also analysed assuming it is genuinely single.
- Full Text: false
- Date Issued: 2017