Development of manganese phthalocyanine decorated with silver nanoparticles nanocomposite for improved electrocatalytic oxidation of hydrazine:

Mpeta, Lekhetho S; Sen, Pinar; Nyokong, Tebello

Title: Development of manganese phthalocyanine decorated with silver nanoparticles nanocomposite for improved electrocatalytic oxidation of hydrazine:
Creator: Mpeta, Lekhetho S
Creator: Sen, Pinar
Creator: Nyokong, Tebello
Date Issued: 2020
Date: 2020
Type: text
Type: article
Identifier: http://hdl.handle.net/10962/148472
Identifier: vital:38742
Identifier: https://doi.org/10.1016/j.jelechem.2020.114173
Description: In this study we report on the synthesis of tetrakis [4-(4-(5-chloro-1H-benzo [d]imidazol-2-yl) phenoxy phthalocyaninato] manganese (III) chloride (MnPc). The MnPc was first used to modify a glassy carbon electrode, followed by the growth of silver nanoparticles (AgNPs) onto the MnPc modified electrode to form MnPc-AgNPs modified electrode. The modified electrode was characterized using cydic voltammetry, chronoamperometry, scanning electrochemical microscopy and electrochemical impedance spectroscopy. The modified MnPc-AgNPs electrode was employed for the detection of hydrazine. The MnPc-AgNPs gave better current responses for electrooxidation of hydrazine relative to MnPc and AgNPs, individually. The catalytic rate constant was 1.90 x 10(5 )M(-1) S-1, with the detection limit (LoD) of 2.42 pM (using 3 sigma notation), and sensitivity of 61.56 mu A mM(-1), for MnPc-AgNPs. (C) 2020 Elsevier B.V. All rights reserved.
Format: 9 pages
Format: pdf
Language: English
Relation: Journal of Electroanalytical Chemistry
Relation: Mpeta, L.S., Sen, P. and Nyokong, T., 2020. Development of manganese phthalocyanine decorated with silver nanoparticles nanocomposite for improved electrocatalytic oxidation of hydrazine. Journal of Electroanalytical Chemistry, 866. p.114173.
Relation: Journal of Electroanalytical Chemistry volume 866 number June 2020 1572-6657
Rights: Publisher
Rights: Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)

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RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology

Nyokong, Tebello (Distinguished Professor)

RU Department of Chemistry

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