- Title
- Isolation, characterization and functionalization of cellulose fibres derived from the waste pineapple leaf fibres by hydrolysis to produce cellulose acetate
- Creator
- Seyisi, Thulethu
- Subject
- Nonwoven fabrics -- Technological innovations
- Subject
- Pineapple fiber -- South Africa
- Subject
- Fibrous composites
- Date Issued
- 2023-04
- Date
- 2023-04
- Type
- Master's theses
- Type
- text
- Identifier
- http://hdl.handle.net/10948/61248
- Identifier
- vital:69844
- Description
- This thesis forms part of the Nelson Mandela University biomass and nanotechnology project, which aims at using agricultural waste for many applications, including biomedical applications, water treatment, and agricultural films. Pineapple leaf fiber (PALF) is one of the natural fibers with the highest cellulose content (about 80%), and they produce about 2.5–3.3% of the weight of green leaves. However, the other parts of the pineapple fruit, such as the leaves and crown, are still treated as waste due to a lack of understanding of the benefits and risks of these parts of the pineapple fruit. The transformation of PALF as a renewable and abundantly available natural residue into cellulose fibers (CFs) will reduce the waste accumulated in the atmosphere, and it will add value to the cultivation of pineapple. In the biomedical industry, CF is very promising in terms of drug delivery. Cellulose acetate is a remarkable biomaterial extensively used in biomedical applications due to its properties such as being non-toxic, non-irritant, biodegradable, heat resistant, and less hygroscopic. In this research, the isolation, functionalization, and characterization of cellulose from PALFs were conducted. The PALFs were dried and ground into small particles before being alkali treated with sodium hydroxide to remove the non-cellulosic components. Moreover, the remaining lignin in the residue was removed using sodium chlorite and acetic acid; this process is known as the bleaching process. The bleaching process resulted in white CFs, which was an indication of the successful removal of the non-cellulosic material. The obtained CFs were further functionalized using acetic acid, acetic anhydride, and sulfuric acid, and this reaction is known as the acetylation reaction. Subsequently, both treated, untreated, and functionalized CFs were characterised using the following instruments: FTIR, SEM, SPM, TGA, XRD, and XPS. In the FTIR data of raw PALFs, the following functional groups were more pronounced: C-O, C=C-O, and C=O, whereas peak C-O-C disappeared and peak CH2, C-O, were less pronounced. These FTIR results confirmed the successful removal of non-cellulosic components. The SEM and SPM images visually suggested the partial removal of hemicellulose and lignin from the raw PALFs after the chemical treatment, which are the cementing materials around the fiber bundles. The TGA studies revealed good thermal stability for the isolated CFs from PALFs. The XRD diffractograms of the PALFs showed a cellulose I crystal pattern where the peaks were located at angular positions (2θ) of around 18°, 26°, and 41°. Lastly, after the functionalization of CFs, the cellulose structure remained intact (not damaged); instead, the newly ix introduced functional groups (the acetyl group) were attached at the ends of the cellulose structure. These results are therefore confirmation of the successful removal of non-cellulose material from the PALFs after the chemical treatment.
- Description
- Thesis (MSc) -- Faculty of Science, School of Natural Resource Science and Management, 2023
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (78 pages)
- Format
- Publisher
- Nelson Mandela University
- Publisher
- Faculty of Science
- Language
- English
- Rights
- Nelson Mandela University
- Rights
- All Rights Reserved
- Rights
- Open Access
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| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Seyisi, T.pdf | 3 MB | Adobe Acrobat PDF | View Details Download |