Multi-instrument observations of ionospheric irregularities over South Africa
- Authors: Amabayo, Emirant Bertillas
- Date: 2012
- Subjects: Ionosphere -- Research , Sudden ionospheric disturbances , Ionospheric storms , Solar activity , Sunspots
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5476 , http://hdl.handle.net/10962/d1005261 , Ionosphere -- Research , Sudden ionospheric disturbances , Ionospheric storms , Solar activity , Sunspots
- Description: The occurrence of mid-latitude spread F (SF) over South Africa has not been extensively studied since the installation of the DPS-4 digisondes at Madimbo (30.88◦E, 22.38◦S), Grahamstown (33.32◦S, 26.50◦E) and Louisvale (28.51◦S, 21.24◦E). This study is intended to quantify the probability of the occurrence of F region disturbances associated with ionospheric spread F (SF) and L-band scintillation over South Africa. This study used available ionosonde data for 8 years (2000-2008) from the three South African stations. The SF events were identified manually on ionograms and grouped for further statistical analysis into frequency SF (FSF), range SF (RSF) and mixed SF (MSF). The results show that the diurnal pattern of SF occurrence peaks strongly between 23:00 and 00:00 UT. This pattern is true for all seasons and types of SF at Madimbo and Grahamstown during 2001 and 2005, except for RSF which had peaks during autumn and spring during 2001 at Madimbo. The probability of both MSF and FSF tends to increase with decreasing sunspot number (SSN), with a peak in 2005 (a moderate solar activity period). The seasonal peaks of MSF and FSF are more frequent during winter months at both Madimbo and Grahamstown. In this study SF was evident in ∼ 0.03% and ∼ 0.06% of the available ionograms at Madimbo and Grahamstown respectively during the eight year period. The presence of ionospheric irregularities associated with SF and scintillation was investigated using data from selected Global Positioning System (GPS) receiver stations distributed across South Africa. The results, based on GPS total electron content (TEC) and ionosonde measurements, show that SF over this region can most likely be attributed to travelling ionospheric disturbances (TIDs), caused by gravity waves (GWs) and neutral wind composition changes. The GWs were mostly associated with geomagnetic storms and sub-storms that occurred during periods of high and moderate solar activity (2001-2005). SF occurrence during the low solar activity period (2006-2008)can probably be attributed to neutral wind composition changes.
- Full Text:
- Date Issued: 2012
- Authors: Amabayo, Emirant Bertillas
- Date: 2012
- Subjects: Ionosphere -- Research , Sudden ionospheric disturbances , Ionospheric storms , Solar activity , Sunspots
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5476 , http://hdl.handle.net/10962/d1005261 , Ionosphere -- Research , Sudden ionospheric disturbances , Ionospheric storms , Solar activity , Sunspots
- Description: The occurrence of mid-latitude spread F (SF) over South Africa has not been extensively studied since the installation of the DPS-4 digisondes at Madimbo (30.88◦E, 22.38◦S), Grahamstown (33.32◦S, 26.50◦E) and Louisvale (28.51◦S, 21.24◦E). This study is intended to quantify the probability of the occurrence of F region disturbances associated with ionospheric spread F (SF) and L-band scintillation over South Africa. This study used available ionosonde data for 8 years (2000-2008) from the three South African stations. The SF events were identified manually on ionograms and grouped for further statistical analysis into frequency SF (FSF), range SF (RSF) and mixed SF (MSF). The results show that the diurnal pattern of SF occurrence peaks strongly between 23:00 and 00:00 UT. This pattern is true for all seasons and types of SF at Madimbo and Grahamstown during 2001 and 2005, except for RSF which had peaks during autumn and spring during 2001 at Madimbo. The probability of both MSF and FSF tends to increase with decreasing sunspot number (SSN), with a peak in 2005 (a moderate solar activity period). The seasonal peaks of MSF and FSF are more frequent during winter months at both Madimbo and Grahamstown. In this study SF was evident in ∼ 0.03% and ∼ 0.06% of the available ionograms at Madimbo and Grahamstown respectively during the eight year period. The presence of ionospheric irregularities associated with SF and scintillation was investigated using data from selected Global Positioning System (GPS) receiver stations distributed across South Africa. The results, based on GPS total electron content (TEC) and ionosonde measurements, show that SF over this region can most likely be attributed to travelling ionospheric disturbances (TIDs), caused by gravity waves (GWs) and neutral wind composition changes. The GWs were mostly associated with geomagnetic storms and sub-storms that occurred during periods of high and moderate solar activity (2001-2005). SF occurrence during the low solar activity period (2006-2008)can probably be attributed to neutral wind composition changes.
- Full Text:
- Date Issued: 2012
Municipal commonage: an undervalued national resource
- Gambiza, James, Shackleton, Charlie M, Davenport, N, Atkinson, D, Hoffman, M T, Martens, C, Puttick, J, De Groot, W
- Authors: Gambiza, James , Shackleton, Charlie M , Davenport, N , Atkinson, D , Hoffman, M T , Martens, C , Puttick, J , De Groot, W
- Date: 2012
- Subjects: Land reform -- South Africa Land use -- South Africa South Africa -- Social conditions
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/49969 , vital:25947
- Description: This policy brief will highlight the importance of municipal commonage in enhancing livelihoods of poor urban families. This will be followed by an overview of the role of municipal commonage in the land reform programme. Current challenges in securing benefits from municipal commonages are then outlined. Policy considerations to optimise benefits from commonages conclude the policy brief.
- Full Text:
- Date Issued: 2012
- Authors: Gambiza, James , Shackleton, Charlie M , Davenport, N , Atkinson, D , Hoffman, M T , Martens, C , Puttick, J , De Groot, W
- Date: 2012
- Subjects: Land reform -- South Africa Land use -- South Africa South Africa -- Social conditions
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/49969 , vital:25947
- Description: This policy brief will highlight the importance of municipal commonage in enhancing livelihoods of poor urban families. This will be followed by an overview of the role of municipal commonage in the land reform programme. Current challenges in securing benefits from municipal commonages are then outlined. Policy considerations to optimise benefits from commonages conclude the policy brief.
- Full Text:
- Date Issued: 2012
Musculoskeletal and perceptual responses of batsmen comparing high- and moderate-volume sprints between the wickets
- Authors: Sheppard, Bronwyn Jane
- Date: 2012
- Subjects: Cricket -- Batting -- Physiological aspects , Cricket injuries , Musculoskeletal system -- Wounds and injuries
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5171 , http://hdl.handle.net/10962/d1016366
- Description: Background: Literature has associated repeated eccentric muscle actions with increased muscle damage of the muscles involved. Eccentric actions are typical in sports which are ‘stop-start’ in nature requiring rapid acceleration and deceleration, typical of a batting activity in cricket. Ultra-structural damage of the skeletal muscle as a consequence of repeated decelerating activities is associated with performance decrements, particularly muscle strength and sprinting speeds. This suggests that eccentric strength decrements may provide an indication for the development of muscle strain injuries during these activities. Despite these findings, limited research has identified the specific musculoskeletal demands placed on cricket batsmen, particularly with reference to various match intensities. Objective: The present study, therefore, sought to determine the specific musculoskeletal, physiological and perceptual demands placed on specialised batsmen during two work bouts of different intensities; one representing a highintensity work bout and the other a moderate-intensity work bout. The dependent variables of interest were muscle activation, isokinetic strength changes, heart rate, ‘central’ and ‘local’ ratings of perceived exertion (RPE), body discomfort and performance. Methods: The two experimental conditions, representative of a high- (HVR) and moderate-volume running (MVR) batting protocol, required players to perform a simulated batting work bout of either twelve or six runs an over, within a laboratory setting. Selected physiological, perceptual and performance measures were collected at specific time intervals throughout the work bout while the biophysical measures were collected prior to, and following both protocols. Results: Of the variables measured, heart rate, ‘central’ and ‘local’ RPE values were observed to increase significantly (p<0.05) over time. This increase was greater as a consequence of the HVR in comparison to the MVR. No change in sprint times was documented during the MVR, in contrast, significant (p<0.05) increases over time were observed during the HVR, further highlighting the elevated demands associated with this condition. In addition, an ‘end spurt’ was observed particularly following the HVR condition, suggesting athletes were conserving themselves through the adoption of a pacing strategy. Reductions in biceps femoris and semitendinosus muscle activation levels were observed following the HVR. This was further supported by the significantly greater levels of semitendinosus activation following the MVR when compared to the HVR. Peak concentric and eccentric knee extensor (EXT) (-17.17% and -16.07% respectively) and eccentric flexor (FLEX) (- 17.49%) values decreased significantly (p<0.05) following the HVR at 60°.s-1. In addition, concentric and eccentric total work produced by the flexors and eccentric extensors resulted in significantly (p<0.05) lower values due to the HVR. Conclusion: The intermittent high-volume batting work bout elicited elevated mean heart rates, perceived ratings of cardiovascular and muscular effort and sprint times. Furthermore, hamstring activation levels and muscle strength, particularly concentric strength of the dominant lower limb were negatively affected by the HVR condition. These results suggest elevated demands were placed on the hamstring musculature as a consequence of the HVR condition, indicating a greater degree of musculoskeletal strain and increased injury risk associated with running between the wickets at this intensity, representative of an aggressive batting scenario.
- Full Text:
- Date Issued: 2012
- Authors: Sheppard, Bronwyn Jane
- Date: 2012
- Subjects: Cricket -- Batting -- Physiological aspects , Cricket injuries , Musculoskeletal system -- Wounds and injuries
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5171 , http://hdl.handle.net/10962/d1016366
- Description: Background: Literature has associated repeated eccentric muscle actions with increased muscle damage of the muscles involved. Eccentric actions are typical in sports which are ‘stop-start’ in nature requiring rapid acceleration and deceleration, typical of a batting activity in cricket. Ultra-structural damage of the skeletal muscle as a consequence of repeated decelerating activities is associated with performance decrements, particularly muscle strength and sprinting speeds. This suggests that eccentric strength decrements may provide an indication for the development of muscle strain injuries during these activities. Despite these findings, limited research has identified the specific musculoskeletal demands placed on cricket batsmen, particularly with reference to various match intensities. Objective: The present study, therefore, sought to determine the specific musculoskeletal, physiological and perceptual demands placed on specialised batsmen during two work bouts of different intensities; one representing a highintensity work bout and the other a moderate-intensity work bout. The dependent variables of interest were muscle activation, isokinetic strength changes, heart rate, ‘central’ and ‘local’ ratings of perceived exertion (RPE), body discomfort and performance. Methods: The two experimental conditions, representative of a high- (HVR) and moderate-volume running (MVR) batting protocol, required players to perform a simulated batting work bout of either twelve or six runs an over, within a laboratory setting. Selected physiological, perceptual and performance measures were collected at specific time intervals throughout the work bout while the biophysical measures were collected prior to, and following both protocols. Results: Of the variables measured, heart rate, ‘central’ and ‘local’ RPE values were observed to increase significantly (p<0.05) over time. This increase was greater as a consequence of the HVR in comparison to the MVR. No change in sprint times was documented during the MVR, in contrast, significant (p<0.05) increases over time were observed during the HVR, further highlighting the elevated demands associated with this condition. In addition, an ‘end spurt’ was observed particularly following the HVR condition, suggesting athletes were conserving themselves through the adoption of a pacing strategy. Reductions in biceps femoris and semitendinosus muscle activation levels were observed following the HVR. This was further supported by the significantly greater levels of semitendinosus activation following the MVR when compared to the HVR. Peak concentric and eccentric knee extensor (EXT) (-17.17% and -16.07% respectively) and eccentric flexor (FLEX) (- 17.49%) values decreased significantly (p<0.05) following the HVR at 60°.s-1. In addition, concentric and eccentric total work produced by the flexors and eccentric extensors resulted in significantly (p<0.05) lower values due to the HVR. Conclusion: The intermittent high-volume batting work bout elicited elevated mean heart rates, perceived ratings of cardiovascular and muscular effort and sprint times. Furthermore, hamstring activation levels and muscle strength, particularly concentric strength of the dominant lower limb were negatively affected by the HVR condition. These results suggest elevated demands were placed on the hamstring musculature as a consequence of the HVR condition, indicating a greater degree of musculoskeletal strain and increased injury risk associated with running between the wickets at this intensity, representative of an aggressive batting scenario.
- Full Text:
- Date Issued: 2012
Nanocomposites of nickel phthalocyanines as electrocatalysts for the oxidation of chlorophenols an experimental and theoretical approach
- Authors: Khene, Mielie Samson
- Date: 2012
- Subjects: Nanocomposites (Materials) -- Research Phthalocyanines -- Research Chlorophenols -- Research Electrocatalysis -- Research
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4326 , http://hdl.handle.net/10962/d1004986
- Description: In this work the interaction between peripherally (b) substituted nickel tetrahydroxyphthalocyanines (b-NiPc(OH)4 and poly-b-Ni(O)Pc(OH)4) with 4-chlorophenol is theoretically rationalized by performing calculations at the B3LYP/6-31G(d) level. Density functional theory (DFT) and molecular orbital theory are used to calculate the condensed Fukui function for phthalocyanine derivatives and 4-chlorophenol, in order to determine the reactive sites involved when 4-chlorophenol is oxidized, and to compare theoretically predicted reactivity to experimentally determined electrocatalytic activity. Electrocatalytic activities of adsorbed NiPc derivatives: OPGE-α-NiPc(OH)8 (OPGE = ordinary pyrolytic graphite electrode, α = nonperipheral substitution), OPGE-a-NiPc(OH)4 and OPGE-β- NiPc(OH)4 are compared with those of the polymerized counterparts: OPGE-poly-α-Ni(O)Pc(OH)8, OPGE poly-a-NiPc(OH)4 and OPGE-poly-β-NiPc(OH)4, respectively. β-NiPc(NH2)4, β-NiPc(OH)4, α-NiPc(OH)4, α-NiPc(OH)8, α-NiPc(C10H21)8 are adsorbed on singled walled carbon nanotube (SWCNT) and β-NiPc(NH2)4-SWCNT (linked to SWCNT), are used to modify glassy carbon electrode (GCE) and employed for the electro oxidation of chlorophenols. The β-NiPc(NH2)4-SWCNT gave the best current response for the oxidation of 4-chlorophenol. α-NiPc(OH)8-SWCNT and α-NiPc(C10H21)8 gave the best resistance to electrode fouling due to oxidation by product of 4-chlorophenol. The synthesis of conjugates of cadmium telluride quantum dots (CdTe-QDs) capped with thioglycolic acid and peripherally substituted nickel tetraamino phthalocyanine (β-NiPc(NH2)4) complex were also employed for the oxidation of chlorophenols. Separation of one of the diastereomers of 1, 2-subnaphthalocyanine (SubNPc) was achieved as well as separation of the enantiomers. The absorption and magnetic circular dichroism spectra, together with theoretical calculations, reveal rather small variations in the frontier molecular orbitals of the SubNPc compared to conventional subphthalocyanine (SubPc), except for the destabilization of the highest occupied molecular orbital (HOMO), which results in a characteristic absorption in the Soret band region. The chirality of SubNPc, including the cyclic dichroism (CD) signs and intensities, are discussed in detail.
- Full Text:
- Date Issued: 2012
- Authors: Khene, Mielie Samson
- Date: 2012
- Subjects: Nanocomposites (Materials) -- Research Phthalocyanines -- Research Chlorophenols -- Research Electrocatalysis -- Research
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4326 , http://hdl.handle.net/10962/d1004986
- Description: In this work the interaction between peripherally (b) substituted nickel tetrahydroxyphthalocyanines (b-NiPc(OH)4 and poly-b-Ni(O)Pc(OH)4) with 4-chlorophenol is theoretically rationalized by performing calculations at the B3LYP/6-31G(d) level. Density functional theory (DFT) and molecular orbital theory are used to calculate the condensed Fukui function for phthalocyanine derivatives and 4-chlorophenol, in order to determine the reactive sites involved when 4-chlorophenol is oxidized, and to compare theoretically predicted reactivity to experimentally determined electrocatalytic activity. Electrocatalytic activities of adsorbed NiPc derivatives: OPGE-α-NiPc(OH)8 (OPGE = ordinary pyrolytic graphite electrode, α = nonperipheral substitution), OPGE-a-NiPc(OH)4 and OPGE-β- NiPc(OH)4 are compared with those of the polymerized counterparts: OPGE-poly-α-Ni(O)Pc(OH)8, OPGE poly-a-NiPc(OH)4 and OPGE-poly-β-NiPc(OH)4, respectively. β-NiPc(NH2)4, β-NiPc(OH)4, α-NiPc(OH)4, α-NiPc(OH)8, α-NiPc(C10H21)8 are adsorbed on singled walled carbon nanotube (SWCNT) and β-NiPc(NH2)4-SWCNT (linked to SWCNT), are used to modify glassy carbon electrode (GCE) and employed for the electro oxidation of chlorophenols. The β-NiPc(NH2)4-SWCNT gave the best current response for the oxidation of 4-chlorophenol. α-NiPc(OH)8-SWCNT and α-NiPc(C10H21)8 gave the best resistance to electrode fouling due to oxidation by product of 4-chlorophenol. The synthesis of conjugates of cadmium telluride quantum dots (CdTe-QDs) capped with thioglycolic acid and peripherally substituted nickel tetraamino phthalocyanine (β-NiPc(NH2)4) complex were also employed for the oxidation of chlorophenols. Separation of one of the diastereomers of 1, 2-subnaphthalocyanine (SubNPc) was achieved as well as separation of the enantiomers. The absorption and magnetic circular dichroism spectra, together with theoretical calculations, reveal rather small variations in the frontier molecular orbitals of the SubNPc compared to conventional subphthalocyanine (SubPc), except for the destabilization of the highest occupied molecular orbital (HOMO), which results in a characteristic absorption in the Soret band region. The chirality of SubNPc, including the cyclic dichroism (CD) signs and intensities, are discussed in detail.
- Full Text:
- Date Issued: 2012
Narrating emergence in the curious terrain of academic development research: a realist perspective
- Authors: Niven, Penelope Mary
- Date: 2012
- Subjects: Education, Higher -- Aims and objectives -- South Africa Universities and colleges -- South Africa Educational change -- South Africa Black people -- Education (Higher) -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1675 , http://hdl.handle.net/10962/d1003558
- Description: This dissertation adopts a realist meta-perspective on a body of the scholar's own research papers written between 2005 and 2011, all either published or in press and offered for reference in the Appendices. The six papers represent the point of departure for the thesis; they are the phenomenon for further investigation into 'what must be the case' for the research events to have emerged as they did. One aspect of this study, therefore, is an auto ethnographic account of conducting research in the field of Academic Development within varied settings and over a given time frame. But alongside this personal history it narrates cycles in the Academic Development movement in South Africa over 30 years. Margaret Archer's Social Realist principle of analytical dualism (1995) is used to disaggregate the emergent properties within these histories and to enable an analysis of the underlying mechanisms that generated them. It refers to three social domains. Firstly, it describes the material structures - the institutional environments, policies, roles or professional conditions - in which the projects were conceived. Secondly, it identifies the cultural registers that the profession was drawing on - such as theories, beliefs or discourses. Thirdly, it draws attention to the agency of individuals and communities in the field as they independently activated or mediated these various conditioning structures and registers. So the study is a systematic examination of the parts and the people in research stories, of the complex interrelationship of structural and agential elements, and of how together they have generated particular forms of knowing and kinds of knowledge in Academic Development. Drawing from this 'history-within-a-history', the study makes some claims for 'what must be the case' for substantial knowledge to flourish in a newly emergent, hotly contested and relatively unstable field. It argues that Academic Development has few shared epistemological foundations and boundaries, and its roles and functions are shifting and diverse. It describes the tensions in the field between those who have been inclined to understand it as primarily concerned with redress or equity in the postapartheid state, and yet others who have prioritised Academic Development as an efficiency project within higher education. But there is a third discourse emanating from those in the profession who have consistently argued that neither of these approaches can succeed without drawing on stronger theoretical foundations. This study endorses the view that Academic Developers need to identify more coherent ontological and epistemological frames for their research work. This has important implications for building the kind of substantial knowledge base that could be more influential in addressing the troubled terrain of South African higher education. The study refers extensively to Lewis Carroll's Alice in Wonderland (1865) and Through the Looking-Glass (1871) and to Mervyn Peake's 1946 illustrations of these children's stories, finding in these texts powerful analogies and metaphors for principles in realist philosophy and theory, and for describing a researcher's journey towards a more assured identity in the curious field of Academic Development.
- Full Text:
- Date Issued: 2012
- Authors: Niven, Penelope Mary
- Date: 2012
- Subjects: Education, Higher -- Aims and objectives -- South Africa Universities and colleges -- South Africa Educational change -- South Africa Black people -- Education (Higher) -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1675 , http://hdl.handle.net/10962/d1003558
- Description: This dissertation adopts a realist meta-perspective on a body of the scholar's own research papers written between 2005 and 2011, all either published or in press and offered for reference in the Appendices. The six papers represent the point of departure for the thesis; they are the phenomenon for further investigation into 'what must be the case' for the research events to have emerged as they did. One aspect of this study, therefore, is an auto ethnographic account of conducting research in the field of Academic Development within varied settings and over a given time frame. But alongside this personal history it narrates cycles in the Academic Development movement in South Africa over 30 years. Margaret Archer's Social Realist principle of analytical dualism (1995) is used to disaggregate the emergent properties within these histories and to enable an analysis of the underlying mechanisms that generated them. It refers to three social domains. Firstly, it describes the material structures - the institutional environments, policies, roles or professional conditions - in which the projects were conceived. Secondly, it identifies the cultural registers that the profession was drawing on - such as theories, beliefs or discourses. Thirdly, it draws attention to the agency of individuals and communities in the field as they independently activated or mediated these various conditioning structures and registers. So the study is a systematic examination of the parts and the people in research stories, of the complex interrelationship of structural and agential elements, and of how together they have generated particular forms of knowing and kinds of knowledge in Academic Development. Drawing from this 'history-within-a-history', the study makes some claims for 'what must be the case' for substantial knowledge to flourish in a newly emergent, hotly contested and relatively unstable field. It argues that Academic Development has few shared epistemological foundations and boundaries, and its roles and functions are shifting and diverse. It describes the tensions in the field between those who have been inclined to understand it as primarily concerned with redress or equity in the postapartheid state, and yet others who have prioritised Academic Development as an efficiency project within higher education. But there is a third discourse emanating from those in the profession who have consistently argued that neither of these approaches can succeed without drawing on stronger theoretical foundations. This study endorses the view that Academic Developers need to identify more coherent ontological and epistemological frames for their research work. This has important implications for building the kind of substantial knowledge base that could be more influential in addressing the troubled terrain of South African higher education. The study refers extensively to Lewis Carroll's Alice in Wonderland (1865) and Through the Looking-Glass (1871) and to Mervyn Peake's 1946 illustrations of these children's stories, finding in these texts powerful analogies and metaphors for principles in realist philosophy and theory, and for describing a researcher's journey towards a more assured identity in the curious field of Academic Development.
- Full Text:
- Date Issued: 2012
Negotiating family planning radio messages among Malawian rural men of traditional authority Kadewere, Chiradzulo district
- Authors: Ntaba, Jolly Maxwell
- Date: 2012
- Subjects: Family planning -- Malawi , Birth control -- Malawi , Radio advertising -- Campaigns -- Malawi , Men -- Attitudes
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:3548 , http://hdl.handle.net/10962/d1018258
- Description: Family planning campaigns, using the media among other advocacy interventions, are produced and disseminated by both government and nongovernment organizations in Malawi, with an aim of reducing fertility and promotion of reproductive health. This qualitative audience study looks specifically at the reception by rural men of radio broadcast Public Service Announcements produced by the NGO, Banja La Mtsogolo, a leading provider of family planning services and products based in Blantyre. The aim of the study is to understand how the appropriation of these messages relates to traditional concepts of gender, masculinity and kinship within an area that has not been spared the influences, values and accoutrements of modernity. Underpinned by Hall’s encoding and decoding model, the study reveals that at most men make an oppositional reading of the texts based on their lived and shared cultural experiences. The results show that while people understand and appreciate the importance of family planning, cultural and traditional influences play a major role in how these messages are appropriated by and incorporated into the everyday lives of their listeners. Given the above understandings, the research asks what are the implications for the success of family-planning media campaigns by government and other non-governmental organisations such as Banja La Mtsogolo
- Full Text:
- Date Issued: 2012
- Authors: Ntaba, Jolly Maxwell
- Date: 2012
- Subjects: Family planning -- Malawi , Birth control -- Malawi , Radio advertising -- Campaigns -- Malawi , Men -- Attitudes
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:3548 , http://hdl.handle.net/10962/d1018258
- Description: Family planning campaigns, using the media among other advocacy interventions, are produced and disseminated by both government and nongovernment organizations in Malawi, with an aim of reducing fertility and promotion of reproductive health. This qualitative audience study looks specifically at the reception by rural men of radio broadcast Public Service Announcements produced by the NGO, Banja La Mtsogolo, a leading provider of family planning services and products based in Blantyre. The aim of the study is to understand how the appropriation of these messages relates to traditional concepts of gender, masculinity and kinship within an area that has not been spared the influences, values and accoutrements of modernity. Underpinned by Hall’s encoding and decoding model, the study reveals that at most men make an oppositional reading of the texts based on their lived and shared cultural experiences. The results show that while people understand and appreciate the importance of family planning, cultural and traditional influences play a major role in how these messages are appropriated by and incorporated into the everyday lives of their listeners. Given the above understandings, the research asks what are the implications for the success of family-planning media campaigns by government and other non-governmental organisations such as Banja La Mtsogolo
- Full Text:
- Date Issued: 2012
Normative indicators for an isiXhosa-speaking population with disadvantaged education for tests of hand motor function and verbal fluency
- Authors: Da Silva Pita, Anita
- Date: 2012
- Subjects: Neuropsychological tests Hand -- Movements People with social disabilities -- Language People with social disabilities -- Education
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2959 , http://hdl.handle.net/10962/d1002468
- Description: The aim of the study was to obtain preliminary normative data for two tests of hand motor function (Successive Finger Tapping and Purdue Pegboard tests) and two tests of verbal fluency ("S"-Words-In-One-Minute and Words-In-One-Minute), administered in English, on a non-clinical sample of black, isiXhosa-speaking unskilled workers with a background of relatively disadvantaged former DET education (N = 33). The sample was equally distributed for gender; educational level was restricted to 11 - 12 years; age range was 18 - 40 years divided further into two age categories (18 - 29 and 30 - 40 years). Results of t-test comparative analyses revealed significant age effects on both trials of the Successive Finger Tapping test in the direction of the younger age group outperforming the older age group, and a marginal but consistent tendency towards poorer performance at an earlier age stage than proposed by the available literature, for the Purdue Pegboard, "S"Words- In-One-Minute and Words-In-One-Minute. Gender effects were only in evidence on the Purdue Pegboard in the direction of females outperforming males. A descriptive comparison of the norms acquired for the present study with available normative data for English first language speaking populations with higher levels and/ or relatively advantaged quality of education revealed consistently poorer performance for the present study. The findings highlight the effect of relatively low levels and/ or poor quality of education on both verbal and non-verbal neuropsychological test performance and confirm the need for demographically specific normative data.
- Full Text:
- Date Issued: 2012
- Authors: Da Silva Pita, Anita
- Date: 2012
- Subjects: Neuropsychological tests Hand -- Movements People with social disabilities -- Language People with social disabilities -- Education
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2959 , http://hdl.handle.net/10962/d1002468
- Description: The aim of the study was to obtain preliminary normative data for two tests of hand motor function (Successive Finger Tapping and Purdue Pegboard tests) and two tests of verbal fluency ("S"-Words-In-One-Minute and Words-In-One-Minute), administered in English, on a non-clinical sample of black, isiXhosa-speaking unskilled workers with a background of relatively disadvantaged former DET education (N = 33). The sample was equally distributed for gender; educational level was restricted to 11 - 12 years; age range was 18 - 40 years divided further into two age categories (18 - 29 and 30 - 40 years). Results of t-test comparative analyses revealed significant age effects on both trials of the Successive Finger Tapping test in the direction of the younger age group outperforming the older age group, and a marginal but consistent tendency towards poorer performance at an earlier age stage than proposed by the available literature, for the Purdue Pegboard, "S"Words- In-One-Minute and Words-In-One-Minute. Gender effects were only in evidence on the Purdue Pegboard in the direction of females outperforming males. A descriptive comparison of the norms acquired for the present study with available normative data for English first language speaking populations with higher levels and/ or relatively advantaged quality of education revealed consistently poorer performance for the present study. The findings highlight the effect of relatively low levels and/ or poor quality of education on both verbal and non-verbal neuropsychological test performance and confirm the need for demographically specific normative data.
- Full Text:
- Date Issued: 2012
Of ants and cicadas: thinking and doing
- Authors: Villet, Martin H
- Date: 2012
- Language: English
- Type: Text
- Identifier: vital:588 , http://hdl.handle.net/10962/d1018948
- Full Text:
- Date Issued: 2012
- Authors: Villet, Martin H
- Date: 2012
- Language: English
- Type: Text
- Identifier: vital:588 , http://hdl.handle.net/10962/d1018948
- Full Text:
- Date Issued: 2012
On the underwater visual census of Western Indian Ocean coral reef fishes
- Authors: Wartenberg, Reece
- Date: 2012
- Subjects: Coral reef fishes -- Africa, Southern , Coral reef fishes -- Indian Ocean , Coral reef fishes -- Behavior , Fish communities -- Africa, Southern , Fish communities -- Indian Ocean , Groundfishes -- Africa, Southern , Groundfishes -- Indian Ocean , Groundfishes -- Behavior
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5308 , http://hdl.handle.net/10962/d1005153 , Coral reef fishes -- Africa, Southern , Coral reef fishes -- Indian Ocean , Coral reef fishes -- Behavior , Fish communities -- Africa, Southern , Fish communities -- Indian Ocean , Groundfishes -- Africa, Southern , Groundfishes -- Indian Ocean , Groundfishes -- Behavior
- Description: This study conducted the first high-resolution investigation of the ichthyofaunal assemblages on a high-latitude coral reef in the Western Indian Ocean (WIO). Two-Mile reef, in South Africa, is a large, accessible patch-reef, and was selected as a candidate study area. Although the effect of season in structuring coral reef fish communities is most-often overlooked, the relationship between these fish communities and their habitat structure has been investigated. In South Africa, however, neither of these potential community-level drivers has been explored. As coral reefs worldwide are faced with high levels of usage pressure, nondestructive underwater visual census (UVC) techniques were identified as the most appropriate survey methods. This study had two primary aims that were; (1) to identify the most suitable technique for the UVC of coral reef fishes, and to test variations of the selected technique for appropriateness to implementation in long-term monitoring programs, and (2) to determine if possible changes to ichthyofaunal community structure could be related to trends in season and/or habitat characteristics. A review of the literature indicated that the most appropriate UVC method for surveying epibenthic coral reef fishes is underwater transecting. To compare the traditional slate-based transects to variations that implement digital image technology, slate transects were compared to a first-attempt digital photographic transect technique, and digital videographic transects. Videographic transects produced the most favourable species richness, abundance, and standard deviations of the three techniques. Diversity was not significantly different between transect techniques. The minimum required sample size was lowest for videographic transects (17 replicates), intermediate for photographic transects (27 replicates) and highest for slate transects (37 replicates). Videographic and photographic transects required greater analysis time to generate counts, but required lower observer training time. While videographic transects produced the lowest proportion of species considered unidentifiable, all three transect techniques showed similar functionality to surveying epibenthic coral reef fishes. Videographic transects were therefore identified as the most appropriate UVC technique for this study. Videographic transects at shallow (6 – 14 m), intermediate (14 – 22 m) and deep (22 – 30 m) depths in mid-winter and mid-summer, sampled a total of 41 families consisting of 209 species and 18172 individuals, dominated by pomacentrids in abundance and labrids in richness. The fish assemblages on Two-Mile Reef were found to be similar in composition to lower-latitude WIO reefs. Overall ichthyofaunal abundance and richness was significantly higher in summer than in winter, and was higher at shallow sites than at intermediate and deep sites. A multivariate approach confirmed differences between seasons at shallow depths but not between seasons at intermediate and deep depths. The fish assemblages on Two-Mile Reef can therefore be described as being comprised of four relatively distinct communities: a shallow, winter community; a shallow, summer community; a year-round intermediate community; and a year-round deep community. The distributions of discriminating species indicated that high abundances of the algal-feeding pomacentrids are observed only at shallow and intermediate sites while high abundances of the zooplanktivorous serranid subfamily, the Anthiinae, are observed predominantly at deep sites. Assessment of all measured supplementary variables indicated that of all factor combinations, observed patterns could be ascribed most strongly to depth. Quantification of reef characteristics indicated that as depth increases, habitat complexity decreases, benthic communities shift from dense coral domination to sparse sponge domination, and algal biomass and cover decreases. The ability of the videographic transect technique to detect changes in community structure with season and depth indicates that season and depth should be accounted for in future high-latitude ichtyofaunal surveys, and that the videographic transect technique is suitable for implementation in long-term monitoring programs on coral reefs. The similarity in fish assemblages between Two-Mile Reef and lower latitude regions suggests that the protocol for surveying epibenthic coral reef fishes, resulting from this study, is relevant throughout the continental WIO.
- Full Text:
- Date Issued: 2012
- Authors: Wartenberg, Reece
- Date: 2012
- Subjects: Coral reef fishes -- Africa, Southern , Coral reef fishes -- Indian Ocean , Coral reef fishes -- Behavior , Fish communities -- Africa, Southern , Fish communities -- Indian Ocean , Groundfishes -- Africa, Southern , Groundfishes -- Indian Ocean , Groundfishes -- Behavior
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5308 , http://hdl.handle.net/10962/d1005153 , Coral reef fishes -- Africa, Southern , Coral reef fishes -- Indian Ocean , Coral reef fishes -- Behavior , Fish communities -- Africa, Southern , Fish communities -- Indian Ocean , Groundfishes -- Africa, Southern , Groundfishes -- Indian Ocean , Groundfishes -- Behavior
- Description: This study conducted the first high-resolution investigation of the ichthyofaunal assemblages on a high-latitude coral reef in the Western Indian Ocean (WIO). Two-Mile reef, in South Africa, is a large, accessible patch-reef, and was selected as a candidate study area. Although the effect of season in structuring coral reef fish communities is most-often overlooked, the relationship between these fish communities and their habitat structure has been investigated. In South Africa, however, neither of these potential community-level drivers has been explored. As coral reefs worldwide are faced with high levels of usage pressure, nondestructive underwater visual census (UVC) techniques were identified as the most appropriate survey methods. This study had two primary aims that were; (1) to identify the most suitable technique for the UVC of coral reef fishes, and to test variations of the selected technique for appropriateness to implementation in long-term monitoring programs, and (2) to determine if possible changes to ichthyofaunal community structure could be related to trends in season and/or habitat characteristics. A review of the literature indicated that the most appropriate UVC method for surveying epibenthic coral reef fishes is underwater transecting. To compare the traditional slate-based transects to variations that implement digital image technology, slate transects were compared to a first-attempt digital photographic transect technique, and digital videographic transects. Videographic transects produced the most favourable species richness, abundance, and standard deviations of the three techniques. Diversity was not significantly different between transect techniques. The minimum required sample size was lowest for videographic transects (17 replicates), intermediate for photographic transects (27 replicates) and highest for slate transects (37 replicates). Videographic and photographic transects required greater analysis time to generate counts, but required lower observer training time. While videographic transects produced the lowest proportion of species considered unidentifiable, all three transect techniques showed similar functionality to surveying epibenthic coral reef fishes. Videographic transects were therefore identified as the most appropriate UVC technique for this study. Videographic transects at shallow (6 – 14 m), intermediate (14 – 22 m) and deep (22 – 30 m) depths in mid-winter and mid-summer, sampled a total of 41 families consisting of 209 species and 18172 individuals, dominated by pomacentrids in abundance and labrids in richness. The fish assemblages on Two-Mile Reef were found to be similar in composition to lower-latitude WIO reefs. Overall ichthyofaunal abundance and richness was significantly higher in summer than in winter, and was higher at shallow sites than at intermediate and deep sites. A multivariate approach confirmed differences between seasons at shallow depths but not between seasons at intermediate and deep depths. The fish assemblages on Two-Mile Reef can therefore be described as being comprised of four relatively distinct communities: a shallow, winter community; a shallow, summer community; a year-round intermediate community; and a year-round deep community. The distributions of discriminating species indicated that high abundances of the algal-feeding pomacentrids are observed only at shallow and intermediate sites while high abundances of the zooplanktivorous serranid subfamily, the Anthiinae, are observed predominantly at deep sites. Assessment of all measured supplementary variables indicated that of all factor combinations, observed patterns could be ascribed most strongly to depth. Quantification of reef characteristics indicated that as depth increases, habitat complexity decreases, benthic communities shift from dense coral domination to sparse sponge domination, and algal biomass and cover decreases. The ability of the videographic transect technique to detect changes in community structure with season and depth indicates that season and depth should be accounted for in future high-latitude ichtyofaunal surveys, and that the videographic transect technique is suitable for implementation in long-term monitoring programs on coral reefs. The similarity in fish assemblages between Two-Mile Reef and lower latitude regions suggests that the protocol for surveying epibenthic coral reef fishes, resulting from this study, is relevant throughout the continental WIO.
- Full Text:
- Date Issued: 2012
Optimistic science: the effectiveness of economic methodology in achieving objectivity
- Authors: Holl, Ryan
- Date: 2012
- Subjects: Economics -- Methodology , Social epistemology , Knowledge, Theory of -- Science , Objectivity -- Science , Science -- Methodology , Optimism
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1105 , http://hdl.handle.net/10962/d1013393
- Description: This thesis examines the extent to which optimism has a bearing on objectivity in scientific inquiry. It is not, however, a psychological level examination into objectivity. Rather, the discussion focuses on collective attitudes, whether in the form of science or a more general public opinion. In essence, sources of optimism at the fundamental level of scientific inquiry are articulated with a careful attempt to differentiate between attitudes about the subject (methodology) and the object of study. The antithetical thread of optimism versus pessimism is teased out with the use of a joint case study of liberalism and Stalinism. The idea of antithesis, however, is contrasted by the fact that, although mirror image ideologies, these collective attitudes share a common faith in progress (albeit through different social mechanisms). This faith in progress provides the basis for the crux of the thesis as it moves to discuss scientific methodology. There is general agreement on what good science should look like and the possibility of progressive science can be articulated. However, it is also possible to highlight the conditions for degenerative science and to further link this to a degenerative social totality in which democracy and social progress are undermined. Economics is used as a case study and it is argued that dogmatic notions on progress have proved to be a major stumbling block to objectivity in the discipline. Furthermore, the implications on the real world are serious.
- Full Text:
- Date Issued: 2012
- Authors: Holl, Ryan
- Date: 2012
- Subjects: Economics -- Methodology , Social epistemology , Knowledge, Theory of -- Science , Objectivity -- Science , Science -- Methodology , Optimism
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1105 , http://hdl.handle.net/10962/d1013393
- Description: This thesis examines the extent to which optimism has a bearing on objectivity in scientific inquiry. It is not, however, a psychological level examination into objectivity. Rather, the discussion focuses on collective attitudes, whether in the form of science or a more general public opinion. In essence, sources of optimism at the fundamental level of scientific inquiry are articulated with a careful attempt to differentiate between attitudes about the subject (methodology) and the object of study. The antithetical thread of optimism versus pessimism is teased out with the use of a joint case study of liberalism and Stalinism. The idea of antithesis, however, is contrasted by the fact that, although mirror image ideologies, these collective attitudes share a common faith in progress (albeit through different social mechanisms). This faith in progress provides the basis for the crux of the thesis as it moves to discuss scientific methodology. There is general agreement on what good science should look like and the possibility of progressive science can be articulated. However, it is also possible to highlight the conditions for degenerative science and to further link this to a degenerative social totality in which democracy and social progress are undermined. Economics is used as a case study and it is argued that dogmatic notions on progress have proved to be a major stumbling block to objectivity in the discipline. Furthermore, the implications on the real world are serious.
- Full Text:
- Date Issued: 2012
Participatory mapping, learning and change in the context of biocultural diversity and resilience
- Authors: Ali, Million Belay
- Date: 2012
- Subjects: Biodiversity conservation -- Research -- Ethiopia Cultural pluralism -- Research -- Ethiopia Ethnopsychology -- Research -- Ethiopia Adult education -- Research -- Ethiopia
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1689 , http://hdl.handle.net/10962/d1003572
- Description: This study set out to investigate the learning and change that emerged in and through participatory mapping in the context of biocultural diversity and resilience in rural Ethiopia. It did this through examining the learning and agency emerging from three participatory mapping practices (Participatory 3 Dimensional Modelling, sketch mapping and eco-cultural calendars) using two case study sites, located in the Bale Mountains and the Foata Mountains in Ethiopia, and honing in on in-depth reflective processes in two community contexts located within the broader case study sites, namely Horo Soba, Dinsho wereda in Bale; and Telecho, in Wolmera wereda, in the Foata Mountain complex. This study tried to answer three research questions related to participatory mapping: its role in mobilizing knowledge related to biocultural landscape, its role in learning and change, and its value in building resilience. The study used qualitative case study research methodology underpinned by critical realist philosophy, and used photographic ‘cues’ to structure the reporting on the cases. It used four categories of analysis: biocultural diversity, educational processes, learning and agency, in the first instance to report on the interactions associated with the participatory mapping practices as they emerged in the two case study sites. This was followed by in-depth analysis and interpretation of participatory mapping and biocultural diversity, as well as participatory mapping and learning, with an emphasis on acquisition, meaning making and identity formation processes. The in-depth analysis drew on social and learning theory, and theory of biocultural diversity and social-ecological resilience. The study also included analysis of broader change processes that were related to and emerged from the social interactions in the mapping activities, and the resultant morphogenesis (change), showing that morphogenesis, while broadly temporal, is not linear, and involves ‘little iterative morphogenic cycles’. These insights were then used to interpret how participatory mapping may contribute to resilience building in a context where social-ecological resilience is increasingly required, such as the two case study sites, where socialecological degradation is highly visible and is occurring rapidly. The study’s contribution to new knowledge lies in relation to the role of participatory mapping in facilitating learning, agency and change which, to date, appears to be under-theorised and under-developed in the participatory mapping and environmental education literature. As such, the study findings provide in-depth insight into how participatory mapping methodologies may ‘work in the world’, in contexts such as those presented in the two cases under study. It has tried to demonstrate how participatory mapping has managed to mobilize knowledge related to biocultural diversity, facilitated the acquisition of knowledge and helped members of the community to engage in meaning making activities relevant to their biocultural landscape and renegotiate their identity within the wider community context. It has also shown that dissonance is an important dynamic in the learning process; and that morphogenesis (or change) occurs over time, but also in smaller cycles that interact at different levels; and that participatory mapping cannot, by itself mobilise significant structural change, at least in the short term. It has also shown, however, that learning and the desire for change can emerge from participatory mapping processes, and that this can be utilized to adapt to the changing socio-ecological environments, potentially contributing to longer term resilience of social-ecological systems.
- Full Text:
- Date Issued: 2012
- Authors: Ali, Million Belay
- Date: 2012
- Subjects: Biodiversity conservation -- Research -- Ethiopia Cultural pluralism -- Research -- Ethiopia Ethnopsychology -- Research -- Ethiopia Adult education -- Research -- Ethiopia
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1689 , http://hdl.handle.net/10962/d1003572
- Description: This study set out to investigate the learning and change that emerged in and through participatory mapping in the context of biocultural diversity and resilience in rural Ethiopia. It did this through examining the learning and agency emerging from three participatory mapping practices (Participatory 3 Dimensional Modelling, sketch mapping and eco-cultural calendars) using two case study sites, located in the Bale Mountains and the Foata Mountains in Ethiopia, and honing in on in-depth reflective processes in two community contexts located within the broader case study sites, namely Horo Soba, Dinsho wereda in Bale; and Telecho, in Wolmera wereda, in the Foata Mountain complex. This study tried to answer three research questions related to participatory mapping: its role in mobilizing knowledge related to biocultural landscape, its role in learning and change, and its value in building resilience. The study used qualitative case study research methodology underpinned by critical realist philosophy, and used photographic ‘cues’ to structure the reporting on the cases. It used four categories of analysis: biocultural diversity, educational processes, learning and agency, in the first instance to report on the interactions associated with the participatory mapping practices as they emerged in the two case study sites. This was followed by in-depth analysis and interpretation of participatory mapping and biocultural diversity, as well as participatory mapping and learning, with an emphasis on acquisition, meaning making and identity formation processes. The in-depth analysis drew on social and learning theory, and theory of biocultural diversity and social-ecological resilience. The study also included analysis of broader change processes that were related to and emerged from the social interactions in the mapping activities, and the resultant morphogenesis (change), showing that morphogenesis, while broadly temporal, is not linear, and involves ‘little iterative morphogenic cycles’. These insights were then used to interpret how participatory mapping may contribute to resilience building in a context where social-ecological resilience is increasingly required, such as the two case study sites, where socialecological degradation is highly visible and is occurring rapidly. The study’s contribution to new knowledge lies in relation to the role of participatory mapping in facilitating learning, agency and change which, to date, appears to be under-theorised and under-developed in the participatory mapping and environmental education literature. As such, the study findings provide in-depth insight into how participatory mapping methodologies may ‘work in the world’, in contexts such as those presented in the two cases under study. It has tried to demonstrate how participatory mapping has managed to mobilize knowledge related to biocultural diversity, facilitated the acquisition of knowledge and helped members of the community to engage in meaning making activities relevant to their biocultural landscape and renegotiate their identity within the wider community context. It has also shown that dissonance is an important dynamic in the learning process; and that morphogenesis (or change) occurs over time, but also in smaller cycles that interact at different levels; and that participatory mapping cannot, by itself mobilise significant structural change, at least in the short term. It has also shown, however, that learning and the desire for change can emerge from participatory mapping processes, and that this can be utilized to adapt to the changing socio-ecological environments, potentially contributing to longer term resilience of social-ecological systems.
- Full Text:
- Date Issued: 2012
Penumbra
- Authors: Mahlangu, Songeziwe
- Date: 2012
- Subjects: South African fiction (English) -- 21st century , Fiction -- Social aspects -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:5979 , http://hdl.handle.net/10962/d1015207
- Description: After failing his Post Graduate Diploma in Accounting Mangaliso Zolo takes an office job at a large insurance company in Cape Town. Anonymous and overlooked in a vast bureaucracy but with a pay check promising happiness and security, he slides into a series of personal crises that test his grip on what he believes in. When at his lowest ebb he leaves his job, grabs his bible and hits the streets his world closes in on him and he is eventually confined to a psychiatric hospital. Penumbra is a novel that explores the liminal area between faith and avarice, sanity and madness, modernity and tradition, friendship and enmity. It is set in contemporary South Africa, a society defined by alienation and excess.
- Full Text:
- Date Issued: 2012
- Authors: Mahlangu, Songeziwe
- Date: 2012
- Subjects: South African fiction (English) -- 21st century , Fiction -- Social aspects -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:5979 , http://hdl.handle.net/10962/d1015207
- Description: After failing his Post Graduate Diploma in Accounting Mangaliso Zolo takes an office job at a large insurance company in Cape Town. Anonymous and overlooked in a vast bureaucracy but with a pay check promising happiness and security, he slides into a series of personal crises that test his grip on what he believes in. When at his lowest ebb he leaves his job, grabs his bible and hits the streets his world closes in on him and he is eventually confined to a psychiatric hospital. Penumbra is a novel that explores the liminal area between faith and avarice, sanity and madness, modernity and tradition, friendship and enmity. It is set in contemporary South Africa, a society defined by alienation and excess.
- Full Text:
- Date Issued: 2012
Perceptions of commerce graduates from a selected higher education institution
- Authors: Kaliika, Michael
- Date: 2012
- Subjects: Education, Higher -- Curricula -- South Africa -- Evaluation Business education -- Curricula -- South Africa -- Evaluation Business education graduates -- South Africa -- Attitudes
- Type: Thesis , Masters , MCom
- Identifier: vital:1188 , http://hdl.handle.net/10962/d1004358
- Description: The role of higher education in developing human capital and contributing to economic growth, competitive advantage and societal progress of any country is well documented. The direct link between the economic performance of a country and the level of education of its citizens cannot be repudiated. Furthermore, the demands of a growing economy, governmental pressure and the competitive international business environment have put pressure on South African businesses. This is aggravated by a “skills crisis” and the need to deliver more goods and services to increasingly more diverse customers. There is consensus amongst experts that the shortage of skills and high-level managerial human resources in South Africa constitute a major threat to the country’s future economic development and productivity growth. As the business world becomes increasingly sophisticated and challenging, so does the need to continuously review and assess the business qualifications that equip managers to cope with the challenges facing them. The competencies that come with a Commerce degree are relevant in every corner of society from managing successful private companies, public organisations, for governments to be able to contribute to the greatest good of society, to socially effective not- for- profit organisations. Despite the importance of a degree in Commerce there are some criticisms about the degree and Commerce graduates. The problem statement of this study is therefore vested in the continuum of praise and criticisms of Commerce graduates and the Commerce curriculum and, the reported imbalances between higher education institutions and the needs of the labour market. The question is whether such praise and criticisms are justified and whether higher education institutions specifically meet the requirements and expectations of both the graduates themselves and of business practice. The primary research objective of this study was, therefore, to obtain the opinions of Commerce graduates and Commerce graduate employers on the overall perception of Commerce graduates produced by a prominent HEI in the Eastern Cape Province in South iv Africa. To achieve this objective and based on in-depth analysis of secondary sources, two independent empirical surveys, aimed at two population strata were conducted, namely: • The Commerce graduates with known email addresses (N = 1 870) were extracted from the HEI’s alumni database. A total of 231 usable questionnaires were received from these Commerce graduates. • The employers with known addresses (N = 85) were extracted from the selected HEIs Career Centre database. A total of 47 usable questionnaires were received from the employers of the Commerce graduates. The main findings in this research pertain to aspects concerning core courses in the Commerce curriculum offered by the selected HEI, management skills and traits as required in the work environment, commerce curriculum outcomes and perceived experience as a student in the Faculty of Commerce at the selected HEI and Employer perceptions on the profile of the Commerce graduate. In this regard, the main findings are therefore summarised below: • Both graduates and employers assigned high relative importance scores to seventeen of the 19 core courses, supporting the multi-functionary interdisciplinary approach to the Commerce curriculum. Concerns were expressed by the Commerce graduates with the quality of tuition they had received in most of the core courses. Likewise, employers were not always satisfied with the Commerce graduates’ proficiency in some of the core courses, relative to the importance of core courses for running a business. • The Commerce graduates and employers strongly endorsed and supported the importance of the 43 management skills and traits in the work environment. Commerce graduates expressed concerns about the extent to which their management skills and traits had been developed through tuition. Concerns about the proficiency of the Commerce graduates in all the management skills and traits, relative to the importance in the work place, were conveyed by the employers. • On average the perceptions on the outcome of studies in the Faculty of Commerce were very highly regarded by the Commerce graduates. The highest mean score was for the item “Studying in the Faculty of Commerce contributed to an increase in my knowledge and abilities.”• The perceived experience of Commerce graduates as students in the Faculty of Commerce at the selected HEI was very highly regarded, implying that the selected HEI was meeting the expectations of its Commerce graduates. • Employer perceptions of what would constitute an ideal Commerce graduate were not fully met by the profile of the actual Commerce graduate from the selected HEI.
- Full Text:
- Date Issued: 2012
- Authors: Kaliika, Michael
- Date: 2012
- Subjects: Education, Higher -- Curricula -- South Africa -- Evaluation Business education -- Curricula -- South Africa -- Evaluation Business education graduates -- South Africa -- Attitudes
- Type: Thesis , Masters , MCom
- Identifier: vital:1188 , http://hdl.handle.net/10962/d1004358
- Description: The role of higher education in developing human capital and contributing to economic growth, competitive advantage and societal progress of any country is well documented. The direct link between the economic performance of a country and the level of education of its citizens cannot be repudiated. Furthermore, the demands of a growing economy, governmental pressure and the competitive international business environment have put pressure on South African businesses. This is aggravated by a “skills crisis” and the need to deliver more goods and services to increasingly more diverse customers. There is consensus amongst experts that the shortage of skills and high-level managerial human resources in South Africa constitute a major threat to the country’s future economic development and productivity growth. As the business world becomes increasingly sophisticated and challenging, so does the need to continuously review and assess the business qualifications that equip managers to cope with the challenges facing them. The competencies that come with a Commerce degree are relevant in every corner of society from managing successful private companies, public organisations, for governments to be able to contribute to the greatest good of society, to socially effective not- for- profit organisations. Despite the importance of a degree in Commerce there are some criticisms about the degree and Commerce graduates. The problem statement of this study is therefore vested in the continuum of praise and criticisms of Commerce graduates and the Commerce curriculum and, the reported imbalances between higher education institutions and the needs of the labour market. The question is whether such praise and criticisms are justified and whether higher education institutions specifically meet the requirements and expectations of both the graduates themselves and of business practice. The primary research objective of this study was, therefore, to obtain the opinions of Commerce graduates and Commerce graduate employers on the overall perception of Commerce graduates produced by a prominent HEI in the Eastern Cape Province in South iv Africa. To achieve this objective and based on in-depth analysis of secondary sources, two independent empirical surveys, aimed at two population strata were conducted, namely: • The Commerce graduates with known email addresses (N = 1 870) were extracted from the HEI’s alumni database. A total of 231 usable questionnaires were received from these Commerce graduates. • The employers with known addresses (N = 85) were extracted from the selected HEIs Career Centre database. A total of 47 usable questionnaires were received from the employers of the Commerce graduates. The main findings in this research pertain to aspects concerning core courses in the Commerce curriculum offered by the selected HEI, management skills and traits as required in the work environment, commerce curriculum outcomes and perceived experience as a student in the Faculty of Commerce at the selected HEI and Employer perceptions on the profile of the Commerce graduate. In this regard, the main findings are therefore summarised below: • Both graduates and employers assigned high relative importance scores to seventeen of the 19 core courses, supporting the multi-functionary interdisciplinary approach to the Commerce curriculum. Concerns were expressed by the Commerce graduates with the quality of tuition they had received in most of the core courses. Likewise, employers were not always satisfied with the Commerce graduates’ proficiency in some of the core courses, relative to the importance of core courses for running a business. • The Commerce graduates and employers strongly endorsed and supported the importance of the 43 management skills and traits in the work environment. Commerce graduates expressed concerns about the extent to which their management skills and traits had been developed through tuition. Concerns about the proficiency of the Commerce graduates in all the management skills and traits, relative to the importance in the work place, were conveyed by the employers. • On average the perceptions on the outcome of studies in the Faculty of Commerce were very highly regarded by the Commerce graduates. The highest mean score was for the item “Studying in the Faculty of Commerce contributed to an increase in my knowledge and abilities.”• The perceived experience of Commerce graduates as students in the Faculty of Commerce at the selected HEI was very highly regarded, implying that the selected HEI was meeting the expectations of its Commerce graduates. • Employer perceptions of what would constitute an ideal Commerce graduate were not fully met by the profile of the actual Commerce graduate from the selected HEI.
- Full Text:
- Date Issued: 2012
Performance of defensive shares on the JSE during financial crisis: evidence from analysis of returns and volatility
- Authors: Arguile, Wayne Peter
- Date: 2012
- Subjects: Industries -- South Africa -- Finance Industries -- South Africa -- Statistics Johannesburg Stock Exchange Rational expectations (Economic theory)
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1001 , http://hdl.handle.net/10962/d1002736
- Description: This study analyses whether historically defensive sectors on the JSE have – with respect to the market – proven to be defensive during the recent global financial crisis. By withstanding the shocks of market volatility, defensive industries (such as pharmaceuticals and consumer staples) are renowned for their consistent performance throughout the business cycle. Using daily data for the period 2000–2009, the study compares the descriptive statistics of sector returns before and during the crisis. The volatility of each sector relative to the market index is calculated using the CAPM beta and a simplified volatility ratio. The same comparison is extended to the conditional volatilities of each of the sectors, which is estimated using the GARCH model and two of its extensions: the EGARCH and GJR GARCH models. While no sector experienced a positive mean return during the financial crisis, Healthcare, Consumer Goods, Consumer Services and Industrials all proved less volatile than the market. Surprisingly, Telecommunications proved more volatile than the market and experienced leverage effects during the financial crisis. Since the timing of a recession is difficult to predict, defensive securities were found to be a useful investment tool for protection against adverse movements in the stock market.
- Full Text:
- Date Issued: 2012
- Authors: Arguile, Wayne Peter
- Date: 2012
- Subjects: Industries -- South Africa -- Finance Industries -- South Africa -- Statistics Johannesburg Stock Exchange Rational expectations (Economic theory)
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1001 , http://hdl.handle.net/10962/d1002736
- Description: This study analyses whether historically defensive sectors on the JSE have – with respect to the market – proven to be defensive during the recent global financial crisis. By withstanding the shocks of market volatility, defensive industries (such as pharmaceuticals and consumer staples) are renowned for their consistent performance throughout the business cycle. Using daily data for the period 2000–2009, the study compares the descriptive statistics of sector returns before and during the crisis. The volatility of each sector relative to the market index is calculated using the CAPM beta and a simplified volatility ratio. The same comparison is extended to the conditional volatilities of each of the sectors, which is estimated using the GARCH model and two of its extensions: the EGARCH and GJR GARCH models. While no sector experienced a positive mean return during the financial crisis, Healthcare, Consumer Goods, Consumer Services and Industrials all proved less volatile than the market. Surprisingly, Telecommunications proved more volatile than the market and experienced leverage effects during the financial crisis. Since the timing of a recession is difficult to predict, defensive securities were found to be a useful investment tool for protection against adverse movements in the stock market.
- Full Text:
- Date Issued: 2012
Peripheral vision field fatigue during simulated driving : the effects of time on task and time of day on selected psychophysiological, performance and subjective responses
- Authors: Robertson, Jade Kelly
- Date: 2012 , 2012-09-22
- Subjects: Automobile driving simulators , Automobile driving -- Psychological aspects , Automobile driving -- Physiological aspects , Traffic accidents , Traffic safety , Fatigue , Peripheral vision
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5141 , http://hdl.handle.net/10962/d1007136 , Automobile driving simulators , Automobile driving -- Psychological aspects , Automobile driving -- Physiological aspects , Traffic accidents , Traffic safety , Fatigue , Peripheral vision
- Description: Worldwide, motor accidents are responsible for a large number of deaths and disabilities (Connor et al., 2001), and one of the major causes of motor accidents is driver fatigue. Although majority of drivers are aware of the dangers of fatigued driving, accidents related to this continues to contribute to a large percentage of all accidents, between 5 and 50% (Nilsson et al., 1997; Williamson et al., 2011). The purpose of the research was to establish the effect that fatigue renders on an individual’s peripheral visual field and to determine whether a decrement in driving performance occurs at the same rate as a decrement in peripheral visual performance. Fatigue was induced through time of day as well as time on task. Sixteen students from Rhodes University were recruited, subject to no previous sleep disorders, among other criteria. Each participant was required to partake in two conditions, namely a day condition (09h00–11h00) and a night condition (23h00– 01h00). Each condition consisted of a 90 minute dual task; the primary task was a tracking task, in which participants were instructed to track a white line as accurately as possible. A secondary peripheral response task was introduced, in which participants were instructed to respond as quickly as possible to the peripheral stimuli, by pressing one of two clickers located on the steering wheel. The peripheral stimuli were located at 20º, 30º and 40º visual angle. Psychophysiological, performance and subjective measures were obtained before, during and after the main task. The pre- and post-tests included core body temperature, critical flicker fusion frequency threshold, a digit span memory test, Wits Sleepiness Scale and a NASA-TLX questionnaire. The psychophysiological and performance measures of heart rate, heart rate variability, blink frequency, blink duration, lane deviation, number of saccades towards peripheral stimuli, response time to peripheral stimuli and the percentage of missed peripheral responses were all recorded throughout the 90 minute main dual task. The results revealed significant differences (p<0.05) for heart rate variability, number of saccades towards peripheral stimuli and the Wits Sleepiness Scale, with regard to time of day. For time on task, significant effects were established for lane deviation, response time to peripheral stimuli, percentage of missed peripheral responses, heart rate, heart rate variability, blink frequency, blink duration, critical flicker fusion frequency threshold, core body temperature and the Wits Sleepiness Scale. Eccentricity was analysed and found to be significant for response time to peripheral stimuli, as well as for the percentage of missed peripheral responses; there was a significant increase in both measures with an increase in the stimuli eccentricity. No significances were established for time of day or between the pre- and post-tests conducted for the digit span memory performance; however, a significant interactional effect between the two was established. When assessing the percentage rate of decrement of driving performance compared to the percentage rate in the decrement of the missed peripheral responses, it was found that the percentage rate of decrement was equal for both measures. Thus from this research it can be seen that, concurrent with a decrement in driving performance, there are adverse effects on an individuals' peripheral vision, which have great implications for the safety of workers in industry and transport, as well as motorists. It was also established that time on task is possibly a more appropriate variable to consider than time of day, when implementing work schedules and rest breaks in industry, transport and fields alike, as more significant findings were seen for time on task compared to time of day. , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 2012
- Authors: Robertson, Jade Kelly
- Date: 2012 , 2012-09-22
- Subjects: Automobile driving simulators , Automobile driving -- Psychological aspects , Automobile driving -- Physiological aspects , Traffic accidents , Traffic safety , Fatigue , Peripheral vision
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5141 , http://hdl.handle.net/10962/d1007136 , Automobile driving simulators , Automobile driving -- Psychological aspects , Automobile driving -- Physiological aspects , Traffic accidents , Traffic safety , Fatigue , Peripheral vision
- Description: Worldwide, motor accidents are responsible for a large number of deaths and disabilities (Connor et al., 2001), and one of the major causes of motor accidents is driver fatigue. Although majority of drivers are aware of the dangers of fatigued driving, accidents related to this continues to contribute to a large percentage of all accidents, between 5 and 50% (Nilsson et al., 1997; Williamson et al., 2011). The purpose of the research was to establish the effect that fatigue renders on an individual’s peripheral visual field and to determine whether a decrement in driving performance occurs at the same rate as a decrement in peripheral visual performance. Fatigue was induced through time of day as well as time on task. Sixteen students from Rhodes University were recruited, subject to no previous sleep disorders, among other criteria. Each participant was required to partake in two conditions, namely a day condition (09h00–11h00) and a night condition (23h00– 01h00). Each condition consisted of a 90 minute dual task; the primary task was a tracking task, in which participants were instructed to track a white line as accurately as possible. A secondary peripheral response task was introduced, in which participants were instructed to respond as quickly as possible to the peripheral stimuli, by pressing one of two clickers located on the steering wheel. The peripheral stimuli were located at 20º, 30º and 40º visual angle. Psychophysiological, performance and subjective measures were obtained before, during and after the main task. The pre- and post-tests included core body temperature, critical flicker fusion frequency threshold, a digit span memory test, Wits Sleepiness Scale and a NASA-TLX questionnaire. The psychophysiological and performance measures of heart rate, heart rate variability, blink frequency, blink duration, lane deviation, number of saccades towards peripheral stimuli, response time to peripheral stimuli and the percentage of missed peripheral responses were all recorded throughout the 90 minute main dual task. The results revealed significant differences (p<0.05) for heart rate variability, number of saccades towards peripheral stimuli and the Wits Sleepiness Scale, with regard to time of day. For time on task, significant effects were established for lane deviation, response time to peripheral stimuli, percentage of missed peripheral responses, heart rate, heart rate variability, blink frequency, blink duration, critical flicker fusion frequency threshold, core body temperature and the Wits Sleepiness Scale. Eccentricity was analysed and found to be significant for response time to peripheral stimuli, as well as for the percentage of missed peripheral responses; there was a significant increase in both measures with an increase in the stimuli eccentricity. No significances were established for time of day or between the pre- and post-tests conducted for the digit span memory performance; however, a significant interactional effect between the two was established. When assessing the percentage rate of decrement of driving performance compared to the percentage rate in the decrement of the missed peripheral responses, it was found that the percentage rate of decrement was equal for both measures. Thus from this research it can be seen that, concurrent with a decrement in driving performance, there are adverse effects on an individuals' peripheral vision, which have great implications for the safety of workers in industry and transport, as well as motorists. It was also established that time on task is possibly a more appropriate variable to consider than time of day, when implementing work schedules and rest breaks in industry, transport and fields alike, as more significant findings were seen for time on task compared to time of day. , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 2012
Perspectives on China's rise in Namibia: the effects on foreign policy and domestic politics
- Amadhila, Nelago Ndapandula Ndanyanyukwa
- Authors: Amadhila, Nelago Ndapandula Ndanyanyukwa
- Date: 2012
- Subjects: Namibia -- Relations -- China China -- Relations -- Namibia Namibia -- Politics and government -- Chinese influences Namibia -- Economic conditions -- Chinese influences
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2758 , http://hdl.handle.net/10962/d1002968
- Description: This thesis analyses the different levels at which China’s presence in Namibia affects Namibia’s domestic politics and foreign policy from a constructivist viewpoint. Constructivist theory is used to examine the different perceptions of the Chinese in Namibia and how these inform Namibian politics and Sino-Namibian relations. These perceptions are formed at different levels of society in formal and informal relations, state-to-state, state-to-business,business-to-business and individual-to-group relations. The way in which perceptions of Chinese involvement in Namibia at the grassroots level of society differ from those at the top increasingly has an effect on domestic Namibian politics and, as such, Sino-Namibian relations. This identifies official and non-official perceptions of China’s political, economic and social presence to determine the effects of grassroots on China vis-à-vis official perceptions in Namibian politics and the effects of grassroots views on Namibian politics and on official views and state behaviour towards China and China’s presence in the country.
- Full Text:
- Date Issued: 2012
- Authors: Amadhila, Nelago Ndapandula Ndanyanyukwa
- Date: 2012
- Subjects: Namibia -- Relations -- China China -- Relations -- Namibia Namibia -- Politics and government -- Chinese influences Namibia -- Economic conditions -- Chinese influences
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2758 , http://hdl.handle.net/10962/d1002968
- Description: This thesis analyses the different levels at which China’s presence in Namibia affects Namibia’s domestic politics and foreign policy from a constructivist viewpoint. Constructivist theory is used to examine the different perceptions of the Chinese in Namibia and how these inform Namibian politics and Sino-Namibian relations. These perceptions are formed at different levels of society in formal and informal relations, state-to-state, state-to-business,business-to-business and individual-to-group relations. The way in which perceptions of Chinese involvement in Namibia at the grassroots level of society differ from those at the top increasingly has an effect on domestic Namibian politics and, as such, Sino-Namibian relations. This identifies official and non-official perceptions of China’s political, economic and social presence to determine the effects of grassroots on China vis-à-vis official perceptions in Namibian politics and the effects of grassroots views on Namibian politics and on official views and state behaviour towards China and China’s presence in the country.
- Full Text:
- Date Issued: 2012
Photophysicochemical and photodynamic studies of phthalocyanines conjugated to selected drug delivery agents
- Authors: Nombona, Nolwazi
- Date: 2012
- Subjects: Phthalocyanines Photochemistry Photochemotherapy Drug delivery systems Magnesium Zinc Nanoparticles Staphylococcus aureus
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4333 , http://hdl.handle.net/10962/d1004994
- Description: This work reports on the successful synthesis, characterisation and photophysical properties of new asymmetric metal free, magnesium and zinc phthalocyanines. The synthesis of symmetrical phthalocyanines is also reported. A selection of phthalocyanines have been conjugated, covalently linked, encapsulated or mixed with selected of drug delivery agents which include gold or silver nanoparticles, poly-L-lysine, liposomes and folic acid. The influence of delivery agent on the photophysical and photochemical properties of conjugated phthalocyanine is investigated. The studies showed that the Au nanoparticle significantly lowered the fluorescence quantum yield values of the phthalocyanines. The photodynamic activity of Zn phthalocyanine-ε-polylysine conjugates in the presence of nanoparticles towards the inactivation of Staphylococcus aureus showed high photoinactivation in the presence of silver nanoparticles. The presence of silver nanoparticels from the minimal inhibition concentration (MIC₅₀) studies showed remarkable growth inhibition for the tested conjugates even at low concentrations. The conjugate also showed no dark toxicity when evaluated using the chick choriallantoic membrane (CAM) assay. The efficiency of selected zinc phthalocyanine as photodynamic therapy (PDT) agents was investigated. The production of reactive oxygen species (ROS) and phototoxicity of the photosensitizers were assessed. Healthy fibroblast cells and breast cancer (MCF-7) cells were treated with either free phthalocyanine or phthalocyanine bound to either gold nanoparticles or encapsulated in liposomes. Cell viability studies showed the optimum phototoxic effect on non-malignant cells to be 4.5 J.cm⁻². The PDT effect of the liposome bound phthalocyanine showed extensive damage of the breast cancer cells. Gold nanoparticles only showed a modest improvement in PDT activity.
- Full Text:
- Date Issued: 2012
- Authors: Nombona, Nolwazi
- Date: 2012
- Subjects: Phthalocyanines Photochemistry Photochemotherapy Drug delivery systems Magnesium Zinc Nanoparticles Staphylococcus aureus
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4333 , http://hdl.handle.net/10962/d1004994
- Description: This work reports on the successful synthesis, characterisation and photophysical properties of new asymmetric metal free, magnesium and zinc phthalocyanines. The synthesis of symmetrical phthalocyanines is also reported. A selection of phthalocyanines have been conjugated, covalently linked, encapsulated or mixed with selected of drug delivery agents which include gold or silver nanoparticles, poly-L-lysine, liposomes and folic acid. The influence of delivery agent on the photophysical and photochemical properties of conjugated phthalocyanine is investigated. The studies showed that the Au nanoparticle significantly lowered the fluorescence quantum yield values of the phthalocyanines. The photodynamic activity of Zn phthalocyanine-ε-polylysine conjugates in the presence of nanoparticles towards the inactivation of Staphylococcus aureus showed high photoinactivation in the presence of silver nanoparticles. The presence of silver nanoparticels from the minimal inhibition concentration (MIC₅₀) studies showed remarkable growth inhibition for the tested conjugates even at low concentrations. The conjugate also showed no dark toxicity when evaluated using the chick choriallantoic membrane (CAM) assay. The efficiency of selected zinc phthalocyanine as photodynamic therapy (PDT) agents was investigated. The production of reactive oxygen species (ROS) and phototoxicity of the photosensitizers were assessed. Healthy fibroblast cells and breast cancer (MCF-7) cells were treated with either free phthalocyanine or phthalocyanine bound to either gold nanoparticles or encapsulated in liposomes. Cell viability studies showed the optimum phototoxic effect on non-malignant cells to be 4.5 J.cm⁻². The PDT effect of the liposome bound phthalocyanine showed extensive damage of the breast cancer cells. Gold nanoparticles only showed a modest improvement in PDT activity.
- Full Text:
- Date Issued: 2012
Photophysicochemical studies of phenylthio phthalocyanines interaction with gold nanoparticles and applications in dye sensitised solar cells and optical limiting
- Authors: Forteath, Shaun
- Date: 2012
- Subjects: Phthalocyanines , Nanoparticles , Photochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4334 , http://hdl.handle.net/10962/d1004995 , Phthalocyanines , Nanoparticles , Photochemistry
- Description: The syntheses, spectroscopic characterisation, photophysical and photochemical studies have been conducted for a variety of phenylthio substituted phthalocyanines (Pcs). Comparisons have been made taking into consideration the influence of the central metal ion, solvent properties and substituent type. The optical limiting properties were also determined for all the Pcs synthesised. A low-symmetry metallophthalocyanine complex was similarly characterised and the photoelectrochemical parameters determined when used as a sensitiser of nanoporous ZnO. The symmetric analogue was conjugated to gold nanoparticles to determine the influence of interactions on its photophysical properties and distinct differences occurred in the absorption and fluorescence spectra suggesting successful formation of conjugates.
- Full Text:
- Date Issued: 2012
- Authors: Forteath, Shaun
- Date: 2012
- Subjects: Phthalocyanines , Nanoparticles , Photochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4334 , http://hdl.handle.net/10962/d1004995 , Phthalocyanines , Nanoparticles , Photochemistry
- Description: The syntheses, spectroscopic characterisation, photophysical and photochemical studies have been conducted for a variety of phenylthio substituted phthalocyanines (Pcs). Comparisons have been made taking into consideration the influence of the central metal ion, solvent properties and substituent type. The optical limiting properties were also determined for all the Pcs synthesised. A low-symmetry metallophthalocyanine complex was similarly characterised and the photoelectrochemical parameters determined when used as a sensitiser of nanoporous ZnO. The symmetric analogue was conjugated to gold nanoparticles to determine the influence of interactions on its photophysical properties and distinct differences occurred in the absorption and fluorescence spectra suggesting successful formation of conjugates.
- Full Text:
- Date Issued: 2012
Post-apartheid racial integration in Grahamstown : a time-geographical perspective
- Authors: Irvine, Philippa Margaret
- Date: 2012
- Subjects: Race discrimination -- South Africa -- Eastern Cape Grahamstown (South Africa) -- Race relations Grahamstown (South Africa) -- Social conditions
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:4845 , http://hdl.handle.net/10962/d1005521
- Description: This research is situated within the context of the post-apartheid era in South Africa, which includes the dominant ideologies and policies that have shaped the urban landscape of the past and present. It investigates the extent and patterns of integration that exist twenty years after the country’s political transition and it uses Grahamstown, a small education and cultural centre in the Eastern Cape Province, as its case study. The investigation incorporates the traditional geographical focus of residential and educational integration, using conventional means of investigation such as segregation indices, dissimilarity indices, percentages and maps. However, in identifying the broader nature of ‘segregation’ and ‘integration’, the study moves beyond these foci and approaches. It adopts the timegeographical framework to reveal the dynamic use of urban space that reflects the lived space of selected individuals from the community of Grahamstown: the extent and patterns of their behavioural integration or spatial linkages. Together, these approaches reveal that Grahamstown is still a city divided by race and, now, class. Schools and residential areas remain tied to the apartheid divisions of race and the white community exists almost entirely within the bounds of apartheid’s blueprint of urban space. Rhodes University, which is located within Grahamstown, has experienced admirable levels of integration within the student body and within the staff as a whole, but not within the staff’s different levels. In essence, where integration has occurred it has been unidirectional with the black community moving into the spaces and institutions formerly reserved for whites. The limited behavioural integration or spatial linkages are shown to be tied to city structure and, within the white group, to perceptions of ‘otherness’ held by the individuals interviewed. While the study shows limited differences in the time-spatial movements between members of different races who are resident in the former white group area, it highlights the differences between those more permanently resident in the city and the temporary educational migrants or students. The study argues that the slow pace of change is related to the nature of South Africa’s democratic transition and its attending political and economic policies.
- Full Text:
- Date Issued: 2012
- Authors: Irvine, Philippa Margaret
- Date: 2012
- Subjects: Race discrimination -- South Africa -- Eastern Cape Grahamstown (South Africa) -- Race relations Grahamstown (South Africa) -- Social conditions
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:4845 , http://hdl.handle.net/10962/d1005521
- Description: This research is situated within the context of the post-apartheid era in South Africa, which includes the dominant ideologies and policies that have shaped the urban landscape of the past and present. It investigates the extent and patterns of integration that exist twenty years after the country’s political transition and it uses Grahamstown, a small education and cultural centre in the Eastern Cape Province, as its case study. The investigation incorporates the traditional geographical focus of residential and educational integration, using conventional means of investigation such as segregation indices, dissimilarity indices, percentages and maps. However, in identifying the broader nature of ‘segregation’ and ‘integration’, the study moves beyond these foci and approaches. It adopts the timegeographical framework to reveal the dynamic use of urban space that reflects the lived space of selected individuals from the community of Grahamstown: the extent and patterns of their behavioural integration or spatial linkages. Together, these approaches reveal that Grahamstown is still a city divided by race and, now, class. Schools and residential areas remain tied to the apartheid divisions of race and the white community exists almost entirely within the bounds of apartheid’s blueprint of urban space. Rhodes University, which is located within Grahamstown, has experienced admirable levels of integration within the student body and within the staff as a whole, but not within the staff’s different levels. In essence, where integration has occurred it has been unidirectional with the black community moving into the spaces and institutions formerly reserved for whites. The limited behavioural integration or spatial linkages are shown to be tied to city structure and, within the white group, to perceptions of ‘otherness’ held by the individuals interviewed. While the study shows limited differences in the time-spatial movements between members of different races who are resident in the former white group area, it highlights the differences between those more permanently resident in the city and the temporary educational migrants or students. The study argues that the slow pace of change is related to the nature of South Africa’s democratic transition and its attending political and economic policies.
- Full Text:
- Date Issued: 2012
Pre-concentration of heavy metals in aqueous environments using electrospun polymer nanofiber sorbents
- Authors: Darko, Godfred
- Date: 2012
- Subjects: Heavy metals -- Absorption and adsorption -- Research Nanochemistry -- Research Polystyrene -- Research Polyamides -- Research
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4337 , http://hdl.handle.net/10962/d1004998
- Description: This thesis presents an alternative approach for pre-concentrating heavy metals in aqueous environments using electro spun polymer nanofiber sorbents. The conditions for electrospinning polyethersulfone, polystyrene, polysulfone and polyamide-6 were optimized. The morphologies and porosities of the electrospun nanofibers were studied using SEM and BET nitrogen gas adsorptions. The nanofibers had mesoporous morphologies with specific surface areas up to 58 m2/g. The electro spun nanofiber sorbents were characterized in terms of their tunability for both uptake and release of heavy metals. The usability of the sorbent was also assessed. The sorbents showed fast adsorption kinetics for heavy metals « 20 min for As, Cu, Ni and Pb) in different aqueous environments. The adsorption characteristics of the sorbents best fitted the Freundlich isotherm and followed the first order kinetics. The efficiencies of adsorption and desorption of heavy metals on both imidazolyl-functionalized polystyrene and amino-functionalized polysulfone sorbents were more than 95% up to the fifth cycle of usage. Reusability improved dramatically (up to 10 runs of usage) when mechanically stable amino-functionalized nylon-6 electro spun nanofibers were used. The capacity of the amino-functionalized nylon-6 sorbent to pre-concentrate heavy metals compared very favourably with those of aqua regia and HN03+H202 digestions especially in less complex matrices. Due to their highly porous nature, the electro spun nanofibers exhibited high adsorption capacities (up to 50 mg/g) for heavy metal ions. The loading capacities achieved with the imidazolyl-functionalized sorbent were higher than those for amino-functionalized mesoporous silica and biomass-based sorbents. The electro spun nanofiber sorbents presents an efficient and cost effective alternative for preconcentrating heavy metals in aqueous environments.
- Full Text:
- Date Issued: 2012
- Authors: Darko, Godfred
- Date: 2012
- Subjects: Heavy metals -- Absorption and adsorption -- Research Nanochemistry -- Research Polystyrene -- Research Polyamides -- Research
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4337 , http://hdl.handle.net/10962/d1004998
- Description: This thesis presents an alternative approach for pre-concentrating heavy metals in aqueous environments using electro spun polymer nanofiber sorbents. The conditions for electrospinning polyethersulfone, polystyrene, polysulfone and polyamide-6 were optimized. The morphologies and porosities of the electrospun nanofibers were studied using SEM and BET nitrogen gas adsorptions. The nanofibers had mesoporous morphologies with specific surface areas up to 58 m2/g. The electro spun nanofiber sorbents were characterized in terms of their tunability for both uptake and release of heavy metals. The usability of the sorbent was also assessed. The sorbents showed fast adsorption kinetics for heavy metals « 20 min for As, Cu, Ni and Pb) in different aqueous environments. The adsorption characteristics of the sorbents best fitted the Freundlich isotherm and followed the first order kinetics. The efficiencies of adsorption and desorption of heavy metals on both imidazolyl-functionalized polystyrene and amino-functionalized polysulfone sorbents were more than 95% up to the fifth cycle of usage. Reusability improved dramatically (up to 10 runs of usage) when mechanically stable amino-functionalized nylon-6 electro spun nanofibers were used. The capacity of the amino-functionalized nylon-6 sorbent to pre-concentrate heavy metals compared very favourably with those of aqua regia and HN03+H202 digestions especially in less complex matrices. Due to their highly porous nature, the electro spun nanofibers exhibited high adsorption capacities (up to 50 mg/g) for heavy metal ions. The loading capacities achieved with the imidazolyl-functionalized sorbent were higher than those for amino-functionalized mesoporous silica and biomass-based sorbents. The electro spun nanofiber sorbents presents an efficient and cost effective alternative for preconcentrating heavy metals in aqueous environments.
- Full Text:
- Date Issued: 2012