Forced degradation studies of clobetasol 17‐propionate in methanol, propylene glycol, as bulk drug and cream formulations by RP‐HPLC
- Fauzee, Ayesha F, Walker, Roderick B
- Authors: Fauzee, Ayesha F , Walker, Roderick B
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184005 , vital:44154 , xlink:href="https://doi.org/10.1002/jssc.201200969"
- Description: A rapid, simple, stability-indicating forced degradation study of clobetasol 17-propionate was conducted using RP-HPLC. The method was used to analyze clobetasol 17-propionate in methanol, propylene glycol, and a cream formulation. Isocratic elution of clobetasol and its degradation products was achieved using a Nova-Pak® 4 μm C18 150 mm × 3.9 mm id cartridge column and a mobile phase of methanol: water (68:32 v/v) at a flow rate of 0.9 mL min−1. Quantitation was achieved with UV detection at 239 nm. Nondegraded clobetasol was eluted at a retention time of 6.0 min. Clobetasol 17-propionate was subjected to different stress conditions viz., acidic, basic, heat, oxidation, light, and neutral hydrolysis. The greatest degradation occurred under strong base and oxidative conditions. Strong base-degraded clobetasol produced additional peaks at retention times of 1.8, 4.0, 5.0, and 8.0 min and clobetasol oxidation degradation peaks eluted at 2.2 and 24 min. Complete validation was performed for linearity, accuracy, and precision over the concentration range 0.15–15 μg mL−1. All data were analyzed statistically and this RP-HPLC method proved to be accurate, precise, linear, and stability indicating for the quantitation of clobetasol 17-propionate in methanol, propylene glycol, and cream formulations.
- Full Text:
- Date Issued: 2013
- Authors: Fauzee, Ayesha F , Walker, Roderick B
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184005 , vital:44154 , xlink:href="https://doi.org/10.1002/jssc.201200969"
- Description: A rapid, simple, stability-indicating forced degradation study of clobetasol 17-propionate was conducted using RP-HPLC. The method was used to analyze clobetasol 17-propionate in methanol, propylene glycol, and a cream formulation. Isocratic elution of clobetasol and its degradation products was achieved using a Nova-Pak® 4 μm C18 150 mm × 3.9 mm id cartridge column and a mobile phase of methanol: water (68:32 v/v) at a flow rate of 0.9 mL min−1. Quantitation was achieved with UV detection at 239 nm. Nondegraded clobetasol was eluted at a retention time of 6.0 min. Clobetasol 17-propionate was subjected to different stress conditions viz., acidic, basic, heat, oxidation, light, and neutral hydrolysis. The greatest degradation occurred under strong base and oxidative conditions. Strong base-degraded clobetasol produced additional peaks at retention times of 1.8, 4.0, 5.0, and 8.0 min and clobetasol oxidation degradation peaks eluted at 2.2 and 24 min. Complete validation was performed for linearity, accuracy, and precision over the concentration range 0.15–15 μg mL−1. All data were analyzed statistically and this RP-HPLC method proved to be accurate, precise, linear, and stability indicating for the quantitation of clobetasol 17-propionate in methanol, propylene glycol, and cream formulations.
- Full Text:
- Date Issued: 2013
Forensic Entomology: An introduction, D.E. Gennard: book review
- Authors: Villet, Martin H
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/451721 , vital:75072 , https://hdl.handle.net/10520/EJC141290
- Description: Dorothy Gennard's role in the fourth-year course in Forensic Science at the University of Lincoln has placed her in an excellent position to design a text that caters for this level. It was generally agreed (e.g. Villet and Richards 2008; Higley and Huntington 2009) that the first edition of her book, published in 2007, was a useful text for teaching introductory courses in forensics, and this substantially revised edition is even better suited to that niche. Other recently revised texts are either difficult to acquire (Haskell and Williams, 2008) or more expensive reference works (Amendt et al. 2010; Byrd and Castner 2010).
- Full Text:
- Date Issued: 2013
- Authors: Villet, Martin H
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/451721 , vital:75072 , https://hdl.handle.net/10520/EJC141290
- Description: Dorothy Gennard's role in the fourth-year course in Forensic Science at the University of Lincoln has placed her in an excellent position to design a text that caters for this level. It was generally agreed (e.g. Villet and Richards 2008; Higley and Huntington 2009) that the first edition of her book, published in 2007, was a useful text for teaching introductory courses in forensics, and this substantially revised edition is even better suited to that niche. Other recently revised texts are either difficult to acquire (Haskell and Williams, 2008) or more expensive reference works (Amendt et al. 2010; Byrd and Castner 2010).
- Full Text:
- Date Issued: 2013
Form over function? The practical application of the Recognition of Customary Marriages Act 1998 in South Africa
- Authors: Kruuse, Helen
- Date: 2013
- Language: English
- Type: Article , text
- Identifier: http://hdl.handle.net/10962/54094 , vital:26389 , http://journals.co.za/content/ju_jur/2013/1/EJC148455
- Description: The Recognition of Customary Marriages Act 120 of 1998 is a major legislative measure for the development of customary marriages in line with the constitutional principle of equality, specifically for women. The article explores the interactions between this ideal in the Act with empirical observations and the latest judicial decisions concerning its application. It considers various examples of the lack of protection of women in relationships of a customary nature, and it concludes that both the state and courts favour a formal or definitional approach to customary marriage. In considering alternative approaches that could adequately protect vulnerable parties, two conclusions emerge: First, the article recommends a wholesale revision of the South African family law approach from a focus on form to dependency. Second (and as a short-term measure), the article advocates for the putative marriage doctrine to be applied in the customary marriage context to protect many women who are denied access to 'customary marriage' as a form, and as a result, all of the benefits that flow from such marriage.
- Full Text:
- Date Issued: 2013
- Authors: Kruuse, Helen
- Date: 2013
- Language: English
- Type: Article , text
- Identifier: http://hdl.handle.net/10962/54094 , vital:26389 , http://journals.co.za/content/ju_jur/2013/1/EJC148455
- Description: The Recognition of Customary Marriages Act 120 of 1998 is a major legislative measure for the development of customary marriages in line with the constitutional principle of equality, specifically for women. The article explores the interactions between this ideal in the Act with empirical observations and the latest judicial decisions concerning its application. It considers various examples of the lack of protection of women in relationships of a customary nature, and it concludes that both the state and courts favour a formal or definitional approach to customary marriage. In considering alternative approaches that could adequately protect vulnerable parties, two conclusions emerge: First, the article recommends a wholesale revision of the South African family law approach from a focus on form to dependency. Second (and as a short-term measure), the article advocates for the putative marriage doctrine to be applied in the customary marriage context to protect many women who are denied access to 'customary marriage' as a form, and as a result, all of the benefits that flow from such marriage.
- Full Text:
- Date Issued: 2013
Gazing at Exhibit A
- Authors: Krueger, Anton
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229643 , vital:49696 , xlink:href="http://liminalities.net/9-1/exhibit.pdf"
- Description: Brett Bailey recently toured a new work in Europe and South Africa, called The Exhibit Series (2010-2013). In different countries the work has appeared under different titles—Exhibit A and Exhibit B, while Exhibit C will be produced in 2014. These productions replicate and parody ethnographic spectacles of the nineteenth century, interrogating European colonial atrocities in Africa, as well as contemporary xenophobia. They consist of a series of installations housed in individual rooms that audience members enter one by one. Inside these rooms one is confronted by beautifully arranged spectacles referencing historical atrocities committed in Namibia by German speaking peoples, as well as atrocities under the Belgian and French colonial regimes in the two Congos. The “exhibits” also include references to more recent incidents of European racism against migrants from Africa. The work has been both applauded and derided. In Berlin, for example, activists called it “a human zoo” and protested that this was “the wrong way to discuss a violent colonial history,”1 while others have called the work “haunting”, praising the production for its “dignity” and “beauty.”2
- Full Text:
- Date Issued: 2013
- Authors: Krueger, Anton
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229643 , vital:49696 , xlink:href="http://liminalities.net/9-1/exhibit.pdf"
- Description: Brett Bailey recently toured a new work in Europe and South Africa, called The Exhibit Series (2010-2013). In different countries the work has appeared under different titles—Exhibit A and Exhibit B, while Exhibit C will be produced in 2014. These productions replicate and parody ethnographic spectacles of the nineteenth century, interrogating European colonial atrocities in Africa, as well as contemporary xenophobia. They consist of a series of installations housed in individual rooms that audience members enter one by one. Inside these rooms one is confronted by beautifully arranged spectacles referencing historical atrocities committed in Namibia by German speaking peoples, as well as atrocities under the Belgian and French colonial regimes in the two Congos. The “exhibits” also include references to more recent incidents of European racism against migrants from Africa. The work has been both applauded and derided. In Berlin, for example, activists called it “a human zoo” and protested that this was “the wrong way to discuss a violent colonial history,”1 while others have called the work “haunting”, praising the production for its “dignity” and “beauty.”2
- Full Text:
- Date Issued: 2013
Glutathione capped CdTe@ ZnS quantum dots–zinc tetracarboxy phthalocyanine conjugates
- Sekhosana, Kutloana E, Antunes, Edith M, Nyokong, Tebello
- Authors: Sekhosana, Kutloana E , Antunes, Edith M , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193780 , vital:45395 , xlink:href="https://doi.org/10.1016/j.poly.2013.02.060"
- Description: Conjugates of zinc tetracarboxy phthalocyanine (ZnPc(COOH)4) with CdTe@ZnS–GSH quantum dots (QDs) were synthesized and characterized by several techniques including X-ray powder diffraction and infrared spectroscopy. There was an observed decrease in both the fluorescence quantum yields and lifetimes of the quantum dots when they were linked or mixed with ZnPc(COOH)4 due to Förster resonance energy transfer (FRET). The FRET behavior of CdTe@ZnS–GSH–ZnPc(COOH)4 conjugates was compared to that of CdTe@ZnS–GSH–ZnPc(COOH)8. Higher FRET efficiencies were observed for CdTe@ZnS–GSH–ZnPc(COOH)4-mixed or CdTe@ZnS–GSH–ZnPc(COOH)4-linked compared to the corresponding CdTe@ZnS–GSH–ZnPc(COOH)8-mixed or CdTe@ZnS–GSH–ZnPc(COOH)8-linked. Also CdTe@ZnS–GSH–ZnPc(COOH)4-mixed (containing coreshell QDs) showed higher FRET efficiency than CdTE–TGA–ZnPc(COOH)4-mixed containing core QDs. The FRET efficiencies were found to be 63% and 59% for the CdTe@ZnS–GSH–ZnPc(COOH)4-linked and CdTe@ZnS–GSH–ZnPc(COOH)4-mixed samples, respectively.
- Full Text:
- Date Issued: 2013
- Authors: Sekhosana, Kutloana E , Antunes, Edith M , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193780 , vital:45395 , xlink:href="https://doi.org/10.1016/j.poly.2013.02.060"
- Description: Conjugates of zinc tetracarboxy phthalocyanine (ZnPc(COOH)4) with CdTe@ZnS–GSH quantum dots (QDs) were synthesized and characterized by several techniques including X-ray powder diffraction and infrared spectroscopy. There was an observed decrease in both the fluorescence quantum yields and lifetimes of the quantum dots when they were linked or mixed with ZnPc(COOH)4 due to Förster resonance energy transfer (FRET). The FRET behavior of CdTe@ZnS–GSH–ZnPc(COOH)4 conjugates was compared to that of CdTe@ZnS–GSH–ZnPc(COOH)8. Higher FRET efficiencies were observed for CdTe@ZnS–GSH–ZnPc(COOH)4-mixed or CdTe@ZnS–GSH–ZnPc(COOH)4-linked compared to the corresponding CdTe@ZnS–GSH–ZnPc(COOH)8-mixed or CdTe@ZnS–GSH–ZnPc(COOH)8-linked. Also CdTe@ZnS–GSH–ZnPc(COOH)4-mixed (containing coreshell QDs) showed higher FRET efficiency than CdTE–TGA–ZnPc(COOH)4-mixed containing core QDs. The FRET efficiencies were found to be 63% and 59% for the CdTe@ZnS–GSH–ZnPc(COOH)4-linked and CdTe@ZnS–GSH–ZnPc(COOH)4-mixed samples, respectively.
- Full Text:
- Date Issued: 2013
Graviton multipoint functions at the AdS boundary
- Authors: Brustein, R , Medved, A J M
- Date: 2013
- Language: English
- Type: text , Article
- Identifier: vital:6819 , http://hdl.handle.net/10962/d1004425
- Description: The gauge-gravity duality can be used to relate connected multipoint graviton functions to connected multipoint correlation functions of the stress tensor of a strongly coupled fluid. Here, we show how to construct the connected graviton functions for a particular kinematic regime that is ideal for discriminating between different gravitational theories, in particular between Einstein theory and its leading-order string theory correction. Our analysis begins with the one-particle irreducible graviton amplitudes in an anti-de Sitter black brane background.We show how these can be used to calculate the connected graviton functions and demonstrate that the two types of amplitudes agree in some cases. It is then asserted on physical grounds that this agreement persists in all cases for both Einstein gravity and its leading-order correction. This outcome implies that the corresponding field-theory correlation functions can be read off directly from the bulk Lagrangian, just as can be done for the ratio of the shear viscosity to the entropy density.
- Full Text:
- Date Issued: 2013
- Authors: Brustein, R , Medved, A J M
- Date: 2013
- Language: English
- Type: text , Article
- Identifier: vital:6819 , http://hdl.handle.net/10962/d1004425
- Description: The gauge-gravity duality can be used to relate connected multipoint graviton functions to connected multipoint correlation functions of the stress tensor of a strongly coupled fluid. Here, we show how to construct the connected graviton functions for a particular kinematic regime that is ideal for discriminating between different gravitational theories, in particular between Einstein theory and its leading-order string theory correction. Our analysis begins with the one-particle irreducible graviton amplitudes in an anti-de Sitter black brane background.We show how these can be used to calculate the connected graviton functions and demonstrate that the two types of amplitudes agree in some cases. It is then asserted on physical grounds that this agreement persists in all cases for both Einstein gravity and its leading-order correction. This outcome implies that the corresponding field-theory correlation functions can be read off directly from the bulk Lagrangian, just as can be done for the ratio of the shear viscosity to the entropy density.
- Full Text:
- Date Issued: 2013
Halogenated oxindole and indoles from the South African marine ascidian Distaplia skoogi:
- Bromley, Candice L, Parker-Nance, Shirley, de la Mare, Jo-Anne, Edkins, Adrienne L, Beukes, Denzil R, Davies-Coleman, Michael T
- Authors: Bromley, Candice L , Parker-Nance, Shirley , de la Mare, Jo-Anne , Edkins, Adrienne L , Beukes, Denzil R , Davies-Coleman, Michael T
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/164918 , vital:41184
- Description: The known 3,6-dibromoindole (1), 6-bromo-3-chloroindole (2) and 6-bromo-2-oxindole (3) were isolated from the marine ascidian (sea squirt) Distapia skoogi collected from Algoa Bay, South Africa. Standard spectroscopic techniques were used to elucidate the structures of 1-3. All three compounds were found to be moderately cytotoxic to metastatic MDA-MB-231 breast cancer cells.
- Full Text:
- Date Issued: 2013
- Authors: Bromley, Candice L , Parker-Nance, Shirley , de la Mare, Jo-Anne , Edkins, Adrienne L , Beukes, Denzil R , Davies-Coleman, Michael T
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/164918 , vital:41184
- Description: The known 3,6-dibromoindole (1), 6-bromo-3-chloroindole (2) and 6-bromo-2-oxindole (3) were isolated from the marine ascidian (sea squirt) Distapia skoogi collected from Algoa Bay, South Africa. Standard spectroscopic techniques were used to elucidate the structures of 1-3. All three compounds were found to be moderately cytotoxic to metastatic MDA-MB-231 breast cancer cells.
- Full Text:
- Date Issued: 2013
Halting degradation of Southern Cape peatlands in agricultural landscapes
- Job, Nancy, Ellery, William F N
- Authors: Job, Nancy , Ellery, William F N
- Date: 2013
- Subjects: Peatlands -- South Africa -- Southern Cape Wetland ecology -- South Africa -- Southern Cape South Africa -- Social conditions
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/50013 , vital:25951
- Description: Palmiet peatlands in the agricultural landscape are viewed by farmers as problematic. They obstruct the effective passage of water along watercourses and therefore promote localized flooding of lands and infrastructure, and they trap sediment delivered along watercourses that drowns fields and infrastructure with sedimentary deposits. These events are problematic for farmers trying to make a living off the land. Wetlands are also often viewed as wastelands that should be put to more productive use. The obvious thing to do is to bring in machinery to drain the wetlands and improve the flow of water and sediment through these wetlands.
- Full Text:
- Date Issued: 2013
- Authors: Job, Nancy , Ellery, William F N
- Date: 2013
- Subjects: Peatlands -- South Africa -- Southern Cape Wetland ecology -- South Africa -- Southern Cape South Africa -- Social conditions
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/50013 , vital:25951
- Description: Palmiet peatlands in the agricultural landscape are viewed by farmers as problematic. They obstruct the effective passage of water along watercourses and therefore promote localized flooding of lands and infrastructure, and they trap sediment delivered along watercourses that drowns fields and infrastructure with sedimentary deposits. These events are problematic for farmers trying to make a living off the land. Wetlands are also often viewed as wastelands that should be put to more productive use. The obvious thing to do is to bring in machinery to drain the wetlands and improve the flow of water and sediment through these wetlands.
- Full Text:
- Date Issued: 2013
How do teachers characterise their teaching for conceptual understanding and procedural fluency?: a case study of two teachers
- Junius, Daniel Franscius, Danie Junius
- Authors: Junius, Daniel Franscius , Danie Junius
- Date: 2013
- Subjects: Mathematics -- Study and teaching (Secondary) -- Namibia Mathematics -- Study and teaching -- Case studies
- Language: English
- Type: text , Thesis , Masters , MEd
- Identifier: vital:1360 , http://hdl.handle.net/10962/d1001426
- Description: Over many years the practice or art of teaching Mathematics posed itself as, not only being different from the practice of teaching any other subject, but to have many challenges and opportunities that ask for exploration and understanding. Just after independence in 1990, Namibia has embarked upon a reform process for the entire education system. Many changes were brought about to create a uniform, equal system for all. However, many challenges still remain to be addressed. Mathematics education remains one of the key areas where Namibian teachers can contribute towards the improvement of the subject. Unsatisfactory results, under-qualified teachers, and a negative disposition towards Mathematics are some of the challenges. These challenges are not unique to Namibia. Across the globe psychologists, philosophers and educators continue to engage in debates and research projects in search of answers and solutions for the improvement of Mathematics education. Despite encountering numerous obstacles, many teachers are dedicated and achieve outstanding results with their learners. This thesis reports on a research project that focused on the Mathematics teaching practice of two teachers whose experiences can make a positive contribution to the improvement of Mathematics teaching in Namibia. Furthermore, this case study investigated and attempted to understand the Mathematics teaching practices of two proficient teachers who each claimed to have a specific and unique approach to teaching Mathematics. The one claimed to be mainly procedural in her Mathematics teaching, while the other one claimed to teach mainly in a conceptual manner. Both achieve very good results with their classes and attribute their own teaching orientations to a process of several experiences they went through as students and in their careers. The study revealed that both claims are substantiated and that each teacher was consistent in her claimed approach. Many challenges and constraints were encountered by both teachers, but in their unique and specific ways each teacher’s chosen teaching approach supported them to overcome these. It was evident from the findings that each teacher’s practice came about as an evolutionary process over an extended period of time. As many challenges and limitations are universal, it is believed that in sharing experiences, teachers can benefit from each other by improving their practice. It was clearly stated by both participants that the re-thinking of and reflecting on their own practices provided them with new insights and motivation. Peer support and sharing of practices contribute positively towards the improvement of the teachers’ classroom practices.
- Full Text:
- Date Issued: 2013
- Authors: Junius, Daniel Franscius , Danie Junius
- Date: 2013
- Subjects: Mathematics -- Study and teaching (Secondary) -- Namibia Mathematics -- Study and teaching -- Case studies
- Language: English
- Type: text , Thesis , Masters , MEd
- Identifier: vital:1360 , http://hdl.handle.net/10962/d1001426
- Description: Over many years the practice or art of teaching Mathematics posed itself as, not only being different from the practice of teaching any other subject, but to have many challenges and opportunities that ask for exploration and understanding. Just after independence in 1990, Namibia has embarked upon a reform process for the entire education system. Many changes were brought about to create a uniform, equal system for all. However, many challenges still remain to be addressed. Mathematics education remains one of the key areas where Namibian teachers can contribute towards the improvement of the subject. Unsatisfactory results, under-qualified teachers, and a negative disposition towards Mathematics are some of the challenges. These challenges are not unique to Namibia. Across the globe psychologists, philosophers and educators continue to engage in debates and research projects in search of answers and solutions for the improvement of Mathematics education. Despite encountering numerous obstacles, many teachers are dedicated and achieve outstanding results with their learners. This thesis reports on a research project that focused on the Mathematics teaching practice of two teachers whose experiences can make a positive contribution to the improvement of Mathematics teaching in Namibia. Furthermore, this case study investigated and attempted to understand the Mathematics teaching practices of two proficient teachers who each claimed to have a specific and unique approach to teaching Mathematics. The one claimed to be mainly procedural in her Mathematics teaching, while the other one claimed to teach mainly in a conceptual manner. Both achieve very good results with their classes and attribute their own teaching orientations to a process of several experiences they went through as students and in their careers. The study revealed that both claims are substantiated and that each teacher was consistent in her claimed approach. Many challenges and constraints were encountered by both teachers, but in their unique and specific ways each teacher’s chosen teaching approach supported them to overcome these. It was evident from the findings that each teacher’s practice came about as an evolutionary process over an extended period of time. As many challenges and limitations are universal, it is believed that in sharing experiences, teachers can benefit from each other by improving their practice. It was clearly stated by both participants that the re-thinking of and reflecting on their own practices provided them with new insights and motivation. Peer support and sharing of practices contribute positively towards the improvement of the teachers’ classroom practices.
- Full Text:
- Date Issued: 2013
How much its own and to what end?: SADC and the culture of security and regional organisation in Southern Africa
- Authors: Bischoff, Paul, 1954-
- Date: 2013
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/161650 , vital:40650 , ISBN 9781134118656
- Description: This book aims to examine the conceptions and practices of security adopted by Regional Organisations (ROs) across the globe. Since the end of the Cold War, there has been an increased focus on regions as a relevant realm for security, with actors within regional contexts identifying a significant degree of interdependency between one another. As a consequence, international security has taken on a distinct regionally institutionalised character, as seen by the increase in calls for greater utilisation of ‘Chapter VIII: Regional Arrangements’ of the UN, in order to create a devolved UN-led system of global security management. However, the idea of a system of global security management is a remote prospect, because divergence seems to be as important as commonality in terms of regional security.
- Full Text:
- Date Issued: 2013
- Authors: Bischoff, Paul, 1954-
- Date: 2013
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/161650 , vital:40650 , ISBN 9781134118656
- Description: This book aims to examine the conceptions and practices of security adopted by Regional Organisations (ROs) across the globe. Since the end of the Cold War, there has been an increased focus on regions as a relevant realm for security, with actors within regional contexts identifying a significant degree of interdependency between one another. As a consequence, international security has taken on a distinct regionally institutionalised character, as seen by the increase in calls for greater utilisation of ‘Chapter VIII: Regional Arrangements’ of the UN, in order to create a devolved UN-led system of global security management. However, the idea of a system of global security management is a remote prospect, because divergence seems to be as important as commonality in terms of regional security.
- Full Text:
- Date Issued: 2013
Hydrellia lagarosiphon Deeming (Diptera: Ephydridae), a potential biological control agent for the submerged aquatic weed, Lagarosiphon major (Ridl.) Moss ex Wager (Hydrocharitaceae)
- Martin, Grant D, Coetzee, Julie A, Baars, Jan-Robert
- Authors: Martin, Grant D , Coetzee, Julie A , Baars, Jan-Robert
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/103912 , vital:32322 , https://doi.org/10.4001/003.021.0118
- Description: The leaf-mining fly, Hydrellia lagarosiphon Deeming (Diptera: Ephydridae), was investigated in its native range in South Africa, to determine its potential as a biological control agent for Lagarosiphon major (Ridl.) Moss ex Wager (Hydrocharitaceae), an invasive submerged macrophyte that is weedy in many parts of the world. The fly was found throughout the indigenous range of the plant in South Africa. High larval abundance was recorded at field sites with nearly all L. major shoots sampled ontaining larvae, with densities of up to 10 larvae per shoot. Adults laid batches of up to 15 eggs, usually on the abaxial sides of L. major leaves. The larvae mined internally, leaving the epidermal tissues of the upper and lower leaves intact. The larvae underwent three instars which took an average of 24 days and pupated within the leaf tissue, from which the adults emerged. Impact studies in the laboratory showed that H. lagarosiphon larval feeding significantly restricted the formation of L. major side branches. Based on its biology and damage caused to the plant, Hydrellia lagarosiphon could be considered as a useful biological control candidate for L. major in countries where the plant is invasive.
- Full Text:
- Date Issued: 2013
- Authors: Martin, Grant D , Coetzee, Julie A , Baars, Jan-Robert
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/103912 , vital:32322 , https://doi.org/10.4001/003.021.0118
- Description: The leaf-mining fly, Hydrellia lagarosiphon Deeming (Diptera: Ephydridae), was investigated in its native range in South Africa, to determine its potential as a biological control agent for Lagarosiphon major (Ridl.) Moss ex Wager (Hydrocharitaceae), an invasive submerged macrophyte that is weedy in many parts of the world. The fly was found throughout the indigenous range of the plant in South Africa. High larval abundance was recorded at field sites with nearly all L. major shoots sampled ontaining larvae, with densities of up to 10 larvae per shoot. Adults laid batches of up to 15 eggs, usually on the abaxial sides of L. major leaves. The larvae mined internally, leaving the epidermal tissues of the upper and lower leaves intact. The larvae underwent three instars which took an average of 24 days and pupated within the leaf tissue, from which the adults emerged. Impact studies in the laboratory showed that H. lagarosiphon larval feeding significantly restricted the formation of L. major side branches. Based on its biology and damage caused to the plant, Hydrellia lagarosiphon could be considered as a useful biological control candidate for L. major in countries where the plant is invasive.
- Full Text:
- Date Issued: 2013
Identification of a uniquely southern African clade of coastal pipefishes Syngnathus spp.
- Mwale, Monica, Kaiser, Horst, Barker, Nigel P, Wilson, A B, Teske, Peter R
- Authors: Mwale, Monica , Kaiser, Horst , Barker, Nigel P , Wilson, A B , Teske, Peter R
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/445499 , vital:74393 , https://doi.org/10.1111/jfb.12130
- Description: The taxonomic status of two southern African coastal pipefish species, Syngnathus temminckii and Syngnathus watermeyeri, was investigated using a combination of morphological and genetic data. Morphological data showed that S. temminckii is distinct from the broadly distributed European pipefish Syngnathus acus, and a molecular phylogeny reconstructed using mitochondrial DNA recovered S. temminckii and S. watermeyeri as sister taxa. The southern African species share an evolutionary origin with north‐eastern Atlantic Ocean and Mediterranean Sea species, including S. acus. These data support the existence of a distinct southern African clade of Syngnathus pipefishes that has diverged in situ to form the two species present in the region today.
- Full Text:
- Date Issued: 2013
- Authors: Mwale, Monica , Kaiser, Horst , Barker, Nigel P , Wilson, A B , Teske, Peter R
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/445499 , vital:74393 , https://doi.org/10.1111/jfb.12130
- Description: The taxonomic status of two southern African coastal pipefish species, Syngnathus temminckii and Syngnathus watermeyeri, was investigated using a combination of morphological and genetic data. Morphological data showed that S. temminckii is distinct from the broadly distributed European pipefish Syngnathus acus, and a molecular phylogeny reconstructed using mitochondrial DNA recovered S. temminckii and S. watermeyeri as sister taxa. The southern African species share an evolutionary origin with north‐eastern Atlantic Ocean and Mediterranean Sea species, including S. acus. These data support the existence of a distinct southern African clade of Syngnathus pipefishes that has diverged in situ to form the two species present in the region today.
- Full Text:
- Date Issued: 2013
Identity and origins of introduced and native Azolla species in Florida
- Madeira, Paul T, Center, Ted D, Coetzee, Julie A, Pemberton, Robert W, Purcell, Matthew F, Hill, Martin P
- Authors: Madeira, Paul T , Center, Ted D , Coetzee, Julie A , Pemberton, Robert W , Purcell, Matthew F , Hill, Martin P
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/419313 , vital:71634 , xlink:href="https://doi.org/10.1016/j.aquabot.2013.07.009"
- Description: Azolla pinnata, an introduced aquatic fern, is spreading rapidly causing concern that it may displace native Azolla. It is now present in the Arthur R. Marshall Loxahatchee National Wildlife Refuge, the northernmost portion of the Florida Everglades. Because A. pinnata subspecies are native to Africa, Southeast Asia, and Australia, determining the actual geographic origin of the Florida exotic is important to the discovery of efficacious biological control agents. Both the exotic and native Azollas were examined using morphological and molecular criteria. Both criteria distinguished three A. pinnata subspecies with the Florida exotic matching the Australian A. pinnata subsp. pinnata. Molecular divergence between the A. pinnata subspecies indicates the three types should be considered separate species. The Florida native was characterized by both molecular and morphological methods as Azolla caroliniana. The discovery of a previously uncharacterized Ecuadorian Azolla, which appears to be a paternal ancestor of A. caroliniana, indicates that A. caroliniana is a hybrid species.
- Full Text:
- Date Issued: 2013
- Authors: Madeira, Paul T , Center, Ted D , Coetzee, Julie A , Pemberton, Robert W , Purcell, Matthew F , Hill, Martin P
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/419313 , vital:71634 , xlink:href="https://doi.org/10.1016/j.aquabot.2013.07.009"
- Description: Azolla pinnata, an introduced aquatic fern, is spreading rapidly causing concern that it may displace native Azolla. It is now present in the Arthur R. Marshall Loxahatchee National Wildlife Refuge, the northernmost portion of the Florida Everglades. Because A. pinnata subspecies are native to Africa, Southeast Asia, and Australia, determining the actual geographic origin of the Florida exotic is important to the discovery of efficacious biological control agents. Both the exotic and native Azollas were examined using morphological and molecular criteria. Both criteria distinguished three A. pinnata subspecies with the Florida exotic matching the Australian A. pinnata subsp. pinnata. Molecular divergence between the A. pinnata subspecies indicates the three types should be considered separate species. The Florida native was characterized by both molecular and morphological methods as Azolla caroliniana. The discovery of a previously uncharacterized Ecuadorian Azolla, which appears to be a paternal ancestor of A. caroliniana, indicates that A. caroliniana is a hybrid species.
- Full Text:
- Date Issued: 2013
Impact of insecticides on the reproductive potential of false codling moth, Thaumatotibia leucotreta (Meyrick, 1913)(Lepidoptera: Tortricidae)
- Authors: Fullard, T , Hill, Martin P
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/406092 , vital:70238 , xlink:href="https://hdl.handle.net/10520/EJC141302"
- Description: False codling moth, Thaumatotibia leucotreta(Meyrick, 1913) (Lepidoptera: Tortricidae), is animportant pest on citrus in South Africa. Several new insecticides were screened for theirpotential negative impacts onT. leucotreta’s reproduction through topical insecticide applica-tions and detached fruit bioassays. Detached fruit bioassays showed that the registeredstandard concentration of Delegate®20 g/100 l and DPX-HGW86 35 ml/100 l caused femalesto oviposit significantly fewer eggs (P= 0.0016) than the controls. The same was found forthe registered concentration of Coragen® (P is less than 0.0001). Topical insecticide trials showed thatonly concentrations of Coragen®, at the registered field rate and above had an effect on themoths’ reproductive output (P is less than 0.0001). Alsystin®and Meothrin™, which were used asindustry standards, did not negatively affect the reproductive output of the moths duringtopical or detached fruit bioassay trials. This study helps to better understand the impor-tance of the application mode,i.e.directly on moths or fruit and implies secondary benefits tosome insecticide applications.
- Full Text:
- Date Issued: 2013
- Authors: Fullard, T , Hill, Martin P
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/406092 , vital:70238 , xlink:href="https://hdl.handle.net/10520/EJC141302"
- Description: False codling moth, Thaumatotibia leucotreta(Meyrick, 1913) (Lepidoptera: Tortricidae), is animportant pest on citrus in South Africa. Several new insecticides were screened for theirpotential negative impacts onT. leucotreta’s reproduction through topical insecticide applica-tions and detached fruit bioassays. Detached fruit bioassays showed that the registeredstandard concentration of Delegate®20 g/100 l and DPX-HGW86 35 ml/100 l caused femalesto oviposit significantly fewer eggs (P= 0.0016) than the controls. The same was found forthe registered concentration of Coragen® (P is less than 0.0001). Topical insecticide trials showed thatonly concentrations of Coragen®, at the registered field rate and above had an effect on themoths’ reproductive output (P is less than 0.0001). Alsystin®and Meothrin™, which were used asindustry standards, did not negatively affect the reproductive output of the moths duringtopical or detached fruit bioassay trials. This study helps to better understand the impor-tance of the application mode,i.e.directly on moths or fruit and implies secondary benefits tosome insecticide applications.
- Full Text:
- Date Issued: 2013
Impacts of a sub-lethal dose of glyphosate on water hyacinth nutrients and its indirect effects on Neochetina weevils
- Katembo, Naweji, Hill, Martin P, Byrne, Marcus J
- Authors: Katembo, Naweji , Hill, Martin P , Byrne, Marcus J
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/417726 , vital:71481 , xlink:href="https://doi.org/10.1080/09583157.2013.839982"
- Description: A sub-lethal dose of a herbicide under field conditions was applied to determine if it stimulates an increase in water hyacinth nutrients, thereby increasing feeding intensity by Neochetina spp. weevils used as biocontrol agents of the weed. Nitrogen (N) and carbon (C) were measured and compared between sprayed plants and control plants. At one site (Delta Park), N levels were lower in the sprayed plants compared to the control plants both in the leaves and the crown. At the second site (Farm Dam), leaf N was also lower in the sprayed plants than in the control plants, while no difference was found in crown N. Mean number of feeding scars per cm2 at Delta Park was significantly higher on the sprayed plants compared to the control plants, while no significant difference was found at Farm Dam. At Delta Park, there was no correlation, however, between the number of weevil feeding scars and leaf N or C:N ratio in sprayed plants. In conclusion, the sub-lethal dose of glyphosate did not directly result in an increase in weevil feeding intensity but it can be recommended in an integrated control system to retard water hyacinth growth while conserving the weevil population.
- Full Text:
- Date Issued: 2013
- Authors: Katembo, Naweji , Hill, Martin P , Byrne, Marcus J
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/417726 , vital:71481 , xlink:href="https://doi.org/10.1080/09583157.2013.839982"
- Description: A sub-lethal dose of a herbicide under field conditions was applied to determine if it stimulates an increase in water hyacinth nutrients, thereby increasing feeding intensity by Neochetina spp. weevils used as biocontrol agents of the weed. Nitrogen (N) and carbon (C) were measured and compared between sprayed plants and control plants. At one site (Delta Park), N levels were lower in the sprayed plants compared to the control plants both in the leaves and the crown. At the second site (Farm Dam), leaf N was also lower in the sprayed plants than in the control plants, while no difference was found in crown N. Mean number of feeding scars per cm2 at Delta Park was significantly higher on the sprayed plants compared to the control plants, while no significant difference was found at Farm Dam. At Delta Park, there was no correlation, however, between the number of weevil feeding scars and leaf N or C:N ratio in sprayed plants. In conclusion, the sub-lethal dose of glyphosate did not directly result in an increase in weevil feeding intensity but it can be recommended in an integrated control system to retard water hyacinth growth while conserving the weevil population.
- Full Text:
- Date Issued: 2013
Implementation of AES-64 connection management for Ethernet Audio/Video Bridging devices
- Dibley, James, Foss, Richard
- Authors: Dibley, James , Foss, Richard
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426875 , vital:72397 , https://www.aes.org/e-lib/online/browse.cfm?elib=17014
- Description: AES-64 is a standard for the discovery, enumeration, connection management, and control of multimedia network devices. This paper describes the implementation of an AES-64 protocol stack and control application on devices that support the IEEE Ethernet Audio/Video Bridging standards for streaming multimedia, enabling connection management of network audio streams.
- Full Text:
- Date Issued: 2013
- Authors: Dibley, James , Foss, Richard
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426875 , vital:72397 , https://www.aes.org/e-lib/online/browse.cfm?elib=17014
- Description: AES-64 is a standard for the discovery, enumeration, connection management, and control of multimedia network devices. This paper describes the implementation of an AES-64 protocol stack and control application on devices that support the IEEE Ethernet Audio/Video Bridging standards for streaming multimedia, enabling connection management of network audio streams.
- Full Text:
- Date Issued: 2013
In search of the Holy Grail: youth media consumption and the construction of citizenship
- Authors: Steenveld, Lynette N
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158597 , vital:40210 , https://hdl.handle.net/10520/EJC141601
- Description: Rather than support the democratic process, as in the ideal scheme of things it should be doing, journalism has become an alienating, cynicism-inducing, narcoticising force in our political culture, turning people off citizenship rather than equipping them to fulfil their democratic potential.
- Full Text:
- Date Issued: 2013
- Authors: Steenveld, Lynette N
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158597 , vital:40210 , https://hdl.handle.net/10520/EJC141601
- Description: Rather than support the democratic process, as in the ideal scheme of things it should be doing, journalism has become an alienating, cynicism-inducing, narcoticising force in our political culture, turning people off citizenship rather than equipping them to fulfil their democratic potential.
- Full Text:
- Date Issued: 2013
Influence of nanoparticle materials on the photophysical behavior of phthalocyanines
- Nyokong, Tebello, Antunes, Edith M
- Authors: Nyokong, Tebello , Antunes, Edith M
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190450 , vital:44995 , xlink:href="https://doi.org/10.1016/j.ccr.2013.03.016"
- Description: This review presents recent data on the photophysical behavior of phthalocyanines when conjugated to quantum dots, gold and magnetic nanoparticles. In some cases such conjugates offer the possibility of being used in “combination therapy”, where two or more substances may be used for treating one disease. The review focuses on the effect that the presence of nanoparticles has on the excited and triplet state parameters of the phthalocyanines. Five tables listing these parameters are presented.
- Full Text:
- Date Issued: 2013
- Authors: Nyokong, Tebello , Antunes, Edith M
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190450 , vital:44995 , xlink:href="https://doi.org/10.1016/j.ccr.2013.03.016"
- Description: This review presents recent data on the photophysical behavior of phthalocyanines when conjugated to quantum dots, gold and magnetic nanoparticles. In some cases such conjugates offer the possibility of being used in “combination therapy”, where two or more substances may be used for treating one disease. The review focuses on the effect that the presence of nanoparticles has on the excited and triplet state parameters of the phthalocyanines. Five tables listing these parameters are presented.
- Full Text:
- Date Issued: 2013
Inkcubeko Nendalo: a bio-cultural diversity schools education project in South Africa and its implications for inclusive Indigenous Knowledge Systems (IKS) Sustainability.
- Cocks, Michelle L, Alexander, Jamie K, Dold, Anthony P
- Authors: Cocks, Michelle L , Alexander, Jamie K , Dold, Anthony P
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141187 , vital:37951 , DOI: 10.1177/0973408212475232
- Description: South Africa is currently the world’s third most biodiverse country, with one of the highest concentrations of threatened biodiversity in the world. Emerging research reveals the increasing pressure on this biodiversity with many wild resources continuing to be utilised for livelihood purposes even within urban environments. The Rio conventions, particularly the CBD, call for an integrated approach to conservation that incorporates local environmental knowledge and practices. In a bid to market itself as globally competitive, South Africa’s Curriculum 2005 (C 2005) is primarily focused on Western-based scientific knowledge, which sidelines the contribution of indigenous knowledge systems (IKS) and ignores the holistic nature of indigenous worldviews. The Inkcubeko Nendalo programme is designed to revitalise cultural identity, showing children the value of local indigenous knowledge and cultural environmental values.
- Full Text:
- Date Issued: 2013
- Authors: Cocks, Michelle L , Alexander, Jamie K , Dold, Anthony P
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141187 , vital:37951 , DOI: 10.1177/0973408212475232
- Description: South Africa is currently the world’s third most biodiverse country, with one of the highest concentrations of threatened biodiversity in the world. Emerging research reveals the increasing pressure on this biodiversity with many wild resources continuing to be utilised for livelihood purposes even within urban environments. The Rio conventions, particularly the CBD, call for an integrated approach to conservation that incorporates local environmental knowledge and practices. In a bid to market itself as globally competitive, South Africa’s Curriculum 2005 (C 2005) is primarily focused on Western-based scientific knowledge, which sidelines the contribution of indigenous knowledge systems (IKS) and ignores the holistic nature of indigenous worldviews. The Inkcubeko Nendalo programme is designed to revitalise cultural identity, showing children the value of local indigenous knowledge and cultural environmental values.
- Full Text:
- Date Issued: 2013
Insights from experimental economics on local cooperation in a small-scale fishery management system:
- Aswani, Shankar, Gurney, Georgina G, Mulville, Sara, Matera, Jaime, Gurven, Michael
- Authors: Aswani, Shankar , Gurney, Georgina G , Mulville, Sara , Matera, Jaime , Gurven, Michael
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145437 , vital:38438 , DOI: 10.1016/j.gloenvcha.2013.08.003
- Description: Cooperation is central to collective management of small-scale fisheries management, including marine protected areas. Thus an understanding of the factors influencing stakeholders’ propensity to cooperate to achieve shared benefits is essential to accomplishing successful collective fisheries management. In this paper we study stakeholders’ cooperative behavioral disposition and elucidate the role of various socio-economic factors in influencing it in the Roviana Lagoon, Western Solomon Islands. We employed a Public Goods Game from experimental economics tailored to mimic the problem of common pool fisheries management to elucidate peoples’ cooperative behavior. Using Ostrom's framework for analyzing social-ecological systems to guide our analysis, we examined how individual-scale variables (e.g., age, education, family size, ethnicity, occupational status, personal norms), in the context of village-scale variables (e.g., village, governance institutions, group coercive action), influence cooperative behavior, as indexed by game contribution. Ostrom's framework provides an effective window for conceptually peeling back the various socio-economic and governance layers which influence cooperation within these communities.
- Full Text:
- Date Issued: 2013
- Authors: Aswani, Shankar , Gurney, Georgina G , Mulville, Sara , Matera, Jaime , Gurven, Michael
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145437 , vital:38438 , DOI: 10.1016/j.gloenvcha.2013.08.003
- Description: Cooperation is central to collective management of small-scale fisheries management, including marine protected areas. Thus an understanding of the factors influencing stakeholders’ propensity to cooperate to achieve shared benefits is essential to accomplishing successful collective fisheries management. In this paper we study stakeholders’ cooperative behavioral disposition and elucidate the role of various socio-economic factors in influencing it in the Roviana Lagoon, Western Solomon Islands. We employed a Public Goods Game from experimental economics tailored to mimic the problem of common pool fisheries management to elucidate peoples’ cooperative behavior. Using Ostrom's framework for analyzing social-ecological systems to guide our analysis, we examined how individual-scale variables (e.g., age, education, family size, ethnicity, occupational status, personal norms), in the context of village-scale variables (e.g., village, governance institutions, group coercive action), influence cooperative behavior, as indexed by game contribution. Ostrom's framework provides an effective window for conceptually peeling back the various socio-economic and governance layers which influence cooperation within these communities.
- Full Text:
- Date Issued: 2013