Electrocatalytic detection of pesticides with electrodes modified with nanoparticles of phthalocyanines and multiwalled carbon nanotubes
- Authors: Siswana, Msimelelo Patrick
- Date: 2013
- Subjects: Phthalocyanines Pesticides Electrocatalysis Electrochemistry Nanotubes Nanoparticles Transmission electron microscopy Scanning electron microscopy
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4282 , http://hdl.handle.net/10962/d1002613
- Description: Three types of electrodes: carbon paste electrodes modified with nanoparticles of metallophthalocyanines (MPcNP-CPEs, M = Mn, Fe, Ni, Co), basal plane pyrolytic graphite electrodes modified with iron or nickel phthalocyanine nanoparticles and multiwalled carbon nanotube composites (FePcNP/MWCNT-BPPGE or NiPcNP/MWCNT-BPPGE),and basal plane pyrolytic graphite electrodes modified with multiwalled carbon nanotubes and electropolymerized metal tetra-aminophthalocyanines (poly-MTAPc-MWCNT-BPPGE), where M is Mn, Fe, Ni or Co, were prepared. Electrochemical characterizations showed that faster electron transfer kinetics occurred at the NiPcNP/MWCNT-BPPGE than at the FePcNP/MWCNT-BPPGE surface. SEM and electrochemical characterizations of poly-MTAPc-MWCNT-BPPGE showed that MTAPc had been deposited on the MWCNTBPPGE surface, and that the poly-CoTAPc-MWCNT-BPPGE exhibited the fastest electron transfer kinetics of all the poly-MTAPc-MWCNT-BPPGEs. Using amitrole and asulam as test analytes, electrochemical experiments showed that, amongst the CPEs, the FePcNP-CPE and NiPcNP-CPE displayed the most electrocatalytic behavior towards amitrole and asulam oxidation, respectively, and further experiments were done to obtain the electrochemical parameters associated with these electrodes and the corresponding analytes. Although, the FePcNP/MWCNT- BPPGE displayed electrocatalytic behavior towards amitrole oxidation in comparison with the bare BPPGE, it was less electrocatalytic than the FePcNP-CPE in terms of detection potential. The NiPcNP/MWCNT-BPPGE displayed the same detection potential as the NiPcNP-CPE. The poly-FeTAPc-MWCNT-BPPGE exhibited the most electrocatalytic behavior towards amitrole, of all the electrodes investigated, and the poly-CoTAPc-MWCNT-BPPGE displayed the best electrocatalytic behavior towards asulam, amongst the poly-MTAPc-MWCNT-BPPGEs.
- Full Text:
- Date Issued: 2013
- Authors: Siswana, Msimelelo Patrick
- Date: 2013
- Subjects: Phthalocyanines Pesticides Electrocatalysis Electrochemistry Nanotubes Nanoparticles Transmission electron microscopy Scanning electron microscopy
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4282 , http://hdl.handle.net/10962/d1002613
- Description: Three types of electrodes: carbon paste electrodes modified with nanoparticles of metallophthalocyanines (MPcNP-CPEs, M = Mn, Fe, Ni, Co), basal plane pyrolytic graphite electrodes modified with iron or nickel phthalocyanine nanoparticles and multiwalled carbon nanotube composites (FePcNP/MWCNT-BPPGE or NiPcNP/MWCNT-BPPGE),and basal plane pyrolytic graphite electrodes modified with multiwalled carbon nanotubes and electropolymerized metal tetra-aminophthalocyanines (poly-MTAPc-MWCNT-BPPGE), where M is Mn, Fe, Ni or Co, were prepared. Electrochemical characterizations showed that faster electron transfer kinetics occurred at the NiPcNP/MWCNT-BPPGE than at the FePcNP/MWCNT-BPPGE surface. SEM and electrochemical characterizations of poly-MTAPc-MWCNT-BPPGE showed that MTAPc had been deposited on the MWCNTBPPGE surface, and that the poly-CoTAPc-MWCNT-BPPGE exhibited the fastest electron transfer kinetics of all the poly-MTAPc-MWCNT-BPPGEs. Using amitrole and asulam as test analytes, electrochemical experiments showed that, amongst the CPEs, the FePcNP-CPE and NiPcNP-CPE displayed the most electrocatalytic behavior towards amitrole and asulam oxidation, respectively, and further experiments were done to obtain the electrochemical parameters associated with these electrodes and the corresponding analytes. Although, the FePcNP/MWCNT- BPPGE displayed electrocatalytic behavior towards amitrole oxidation in comparison with the bare BPPGE, it was less electrocatalytic than the FePcNP-CPE in terms of detection potential. The NiPcNP/MWCNT-BPPGE displayed the same detection potential as the NiPcNP-CPE. The poly-FeTAPc-MWCNT-BPPGE exhibited the most electrocatalytic behavior towards amitrole, of all the electrodes investigated, and the poly-CoTAPc-MWCNT-BPPGE displayed the best electrocatalytic behavior towards asulam, amongst the poly-MTAPc-MWCNT-BPPGEs.
- Full Text:
- Date Issued: 2013
Environmental water quality management of glyphosate-based herbicides in South Africa
- Authors: Mensah, Paul Kojo
- Date: 2013
- Subjects: Water quality management -- South Africa Water quality management -- Environmental Aspects -- South Africa Herbicides -- Environmental aspects -- South Africa Herbicides -- Toxicology -- South Africa Water -- Glyphosate content -- South Africa Water -- Pollution -- South Africa Water quality -- Measurement -- South Africa Water -- Analysis -- South Africa Freshwater ecology -- South Africa Integrated water development -- South Africa Caridina -- Effect of pollution on -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:6023 , http://hdl.handle.net/10962/d1001987
- Description: Although the use of pesticides is necessary to meet the socio-economic needs of many developing countries, especially in Africa, side effects of these bio-active chemicals have contributed to contaminating aquatic and terrestrial ecosystems. Environmental water quality degradation by pesticides interferes with ecosystem health and poses numerous risks to aquatic life. In South Africa, glyphosate-based herbicides are frequently used to control weeds and invading alien plants, but ultimately end up in freshwater ecosystems. However, there are no South African-based environmental water quality management strategies to regulate these bio-active chemicals. Therefore, this study sought to provide a sound scientific background for the environmental water quality management of glyphosate-based herbicides in South Africa, by conducting both laboratory and field investigations. In the laboratory investigations, aquatic ecotoxicological methods were used to evaluate responses of the freshwater aquatic shrimp Caridina nilotica exposed to Roundup® at different biological system scales, and the responses of multiple South African aquatic species exposed to Roundup® through species sensitivity distribution (SSD). In the field investigations, the effect of Kilo Max WSG on the physicochemical and biological conditions of three selected sites in the Swartkops River before and after a spray episode by Working for Water were evaluated through biomonitoring, using the South African Scoring System version 5 (SASS5) as a sampling protocol. Both Roundup® and Kilo Max WSG are glyphosate-based herbicides. All the data were subjected to relevant statistical analyses. Findings of this study revealed that Roundup® elicited responses at different biological system scales in C. nilotica, while SSD estimates were used to derive proposed water quality guidelines for glyphosate-based herbicides in South Africa. The biomonitoring revealed that using glyphosate-based herbicides to control water hyacinth within the Swartkops River had a negligible impact on the physicochemical and biological conditions. Based on these findings, a conceptual framework that can be used for the integrated environmental water quality management of glyphosate-based herbicides in South Africa was developed as part of integrated water resource management (IWRM). The combined data sets contribute to a sound scientific basis for the environmental water quality management of glyphosate-based herbicides in South Africa.
- Full Text:
- Date Issued: 2013
- Authors: Mensah, Paul Kojo
- Date: 2013
- Subjects: Water quality management -- South Africa Water quality management -- Environmental Aspects -- South Africa Herbicides -- Environmental aspects -- South Africa Herbicides -- Toxicology -- South Africa Water -- Glyphosate content -- South Africa Water -- Pollution -- South Africa Water quality -- Measurement -- South Africa Water -- Analysis -- South Africa Freshwater ecology -- South Africa Integrated water development -- South Africa Caridina -- Effect of pollution on -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:6023 , http://hdl.handle.net/10962/d1001987
- Description: Although the use of pesticides is necessary to meet the socio-economic needs of many developing countries, especially in Africa, side effects of these bio-active chemicals have contributed to contaminating aquatic and terrestrial ecosystems. Environmental water quality degradation by pesticides interferes with ecosystem health and poses numerous risks to aquatic life. In South Africa, glyphosate-based herbicides are frequently used to control weeds and invading alien plants, but ultimately end up in freshwater ecosystems. However, there are no South African-based environmental water quality management strategies to regulate these bio-active chemicals. Therefore, this study sought to provide a sound scientific background for the environmental water quality management of glyphosate-based herbicides in South Africa, by conducting both laboratory and field investigations. In the laboratory investigations, aquatic ecotoxicological methods were used to evaluate responses of the freshwater aquatic shrimp Caridina nilotica exposed to Roundup® at different biological system scales, and the responses of multiple South African aquatic species exposed to Roundup® through species sensitivity distribution (SSD). In the field investigations, the effect of Kilo Max WSG on the physicochemical and biological conditions of three selected sites in the Swartkops River before and after a spray episode by Working for Water were evaluated through biomonitoring, using the South African Scoring System version 5 (SASS5) as a sampling protocol. Both Roundup® and Kilo Max WSG are glyphosate-based herbicides. All the data were subjected to relevant statistical analyses. Findings of this study revealed that Roundup® elicited responses at different biological system scales in C. nilotica, while SSD estimates were used to derive proposed water quality guidelines for glyphosate-based herbicides in South Africa. The biomonitoring revealed that using glyphosate-based herbicides to control water hyacinth within the Swartkops River had a negligible impact on the physicochemical and biological conditions. Based on these findings, a conceptual framework that can be used for the integrated environmental water quality management of glyphosate-based herbicides in South Africa was developed as part of integrated water resource management (IWRM). The combined data sets contribute to a sound scientific basis for the environmental water quality management of glyphosate-based herbicides in South Africa.
- Full Text:
- Date Issued: 2013
Estuarine-dependency and multiple habitat use by dusky kob Argyrosomus Japonicus (Pisces: Sciaenidae)
- Authors: Childs, Amber-Robyn
- Date: 2013
- Subjects: Argyrosomus -- Habitat -- South Africa -- Algoa Bay , Argyrosomus -- Behavior -- South Africa -- Algoa Bay , Argyrosomus -- Migration -- South Africa -- Algoa Bay , Estuarine fishes -- South Africa -- Algoa Bay , Habitat selection -- South Africa -- Algoa Bay , Argyrosomus -- South Africa -- Sundays Estuary (Eastern Cape) , Underwater acoustic telemetry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5386 , http://hdl.handle.net/10962/d1020241
- Description: Dusky kob Argyrosomus japonicus is a wide-ranging estuarine-dependent Sciaenid and an important fishery species throughout most of its distribution. It is one of South Africa’s most valuable coastal fishery species. High levels of juvenile exploitation in estuaries and ineffective management regulations have led to stock collapse, highlighting the need to better understand the spatial and temporal aspects of estuarine-dependency and multiple habitat use. Habitat connectivity is a critical property of estuarine-associated fishes and it therefore follows that knowledge of this link is fundamental in understanding population dynamics and the nursery role of estuarine and/or marine habitats. While dusky kob occur in both estuaries and nearshore coastal zones, limited information on connectivity among these habitats exists. The aim of this study is to assess the role of estuarine nursery habitats in the life cycle of the dusky kob by examining multiple habitat connectivity and determining the drivers associated with estuarine use. A total of 96 dusky kob (237–1280 mm total length) were tagged with acoustic transmitters in both the estuarine and marine environments of Algoa Bay, Eastern Cape, South Africa between May 2008 and September 2010. Their movements were monitored using a network of automated data-logging acoustic receivers deployed in the Sundays Estuary, seven neighbouring estuarine habitats, two commercial harbours and various sites within Algoa Bay. And more...
- Full Text:
- Date Issued: 2013
- Authors: Childs, Amber-Robyn
- Date: 2013
- Subjects: Argyrosomus -- Habitat -- South Africa -- Algoa Bay , Argyrosomus -- Behavior -- South Africa -- Algoa Bay , Argyrosomus -- Migration -- South Africa -- Algoa Bay , Estuarine fishes -- South Africa -- Algoa Bay , Habitat selection -- South Africa -- Algoa Bay , Argyrosomus -- South Africa -- Sundays Estuary (Eastern Cape) , Underwater acoustic telemetry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5386 , http://hdl.handle.net/10962/d1020241
- Description: Dusky kob Argyrosomus japonicus is a wide-ranging estuarine-dependent Sciaenid and an important fishery species throughout most of its distribution. It is one of South Africa’s most valuable coastal fishery species. High levels of juvenile exploitation in estuaries and ineffective management regulations have led to stock collapse, highlighting the need to better understand the spatial and temporal aspects of estuarine-dependency and multiple habitat use. Habitat connectivity is a critical property of estuarine-associated fishes and it therefore follows that knowledge of this link is fundamental in understanding population dynamics and the nursery role of estuarine and/or marine habitats. While dusky kob occur in both estuaries and nearshore coastal zones, limited information on connectivity among these habitats exists. The aim of this study is to assess the role of estuarine nursery habitats in the life cycle of the dusky kob by examining multiple habitat connectivity and determining the drivers associated with estuarine use. A total of 96 dusky kob (237–1280 mm total length) were tagged with acoustic transmitters in both the estuarine and marine environments of Algoa Bay, Eastern Cape, South Africa between May 2008 and September 2010. Their movements were monitored using a network of automated data-logging acoustic receivers deployed in the Sundays Estuary, seven neighbouring estuarine habitats, two commercial harbours and various sites within Algoa Bay. And more...
- Full Text:
- Date Issued: 2013
Examining emergent active learning processes as transformative praxis : the case of the schools and sustainability professional development programme
- Authors: Schudel, Ingrid Joan
- Date: 2013 , 2013-09-20
- Subjects: Active learning -- Study and teaching (Elementary) -- South Africa -- Eastern Cape Student-centered learning -- Research -- South Africa -- Eastern Cape Environmental education -- Study and teaching (Elementary) -- South Africa -- Eastern Cape Environmental education -- Curricula -- South Africa -- Eastern Cape Competency-based education -- South Africa -- Eastern Cape Teachers -- Training of -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1891 , http://hdl.handle.net/10962/d1006079
- Description: This is a study on the nature of learning, particularly the emergence of active learning processes in the case of an environmental education teacher professional development programme – the Eastern Cape Border-Kei cohort of the 2008 Schools and Sustainability Course. This was a part-time, one-year course supporting teachers to qualify, strengthen and deepen opportunities for environmental learning in the South African curriculum. An active learning framework (O’Donoghue, 2001) promoting teaching and learning with information, enquiry, action and reporting/reflection dimensions was integrated into the Schools and Sustainability course design to support these environmental learning opportunities. In this study, the notion of active learning is elaborated as a situated, action-oriented, deliberative and co-engaged approach to teaching and learning, and related to Bhaskar’s (1993) notion of transformative praxis. The study used a nested case study design, considering the case of six Foundation Phase teachers in six primary schools within the Border-Kei Schools and Sustainability cohort. Interviews, observations (of workshops and lesson plan implementation in classrooms) and document review of teacher portfolios (detailing course activities, lesson plans, learners’ work and learning and teaching support materials) were used to generate the bulk of the data. A critical realist theory underpinning the methodology enables a view of agency as emergent from social structures and mechanisms as elaborated in Archer’s (1998b) model of morphogenesis and Bhaskar’s (1993) model of four-planar being. The critical realist methodology also enables a view of emergent active learning processes as open-ended, responsive to particular potential, but dependent on contingencies (such as learning and teaching support materials, tools and methodologies). The analysis of emergent active learning processes focuses particularly on Bhaskar’s (1993) ontological-axiological chain (MELD schema) as a tool for analysing change. The MELD schema highlights1M ontological questions of what is (with emphasis on structures and generative mechanisms) and what could be (real, but non-actualised possibilities). It enables reflection on what mediating and interactive agential processes either reproduce what is or have the potential to transform what is to what could be (2E). Thirdly, the MELD schema enables reflection on what should be – this is the 3L “axiological moment” (Bhaskar, 1993: 9) where questions of values and ethics in relation to the holistic whole are raised. Finally, the schema raises questions (4D) of what can be, with ontologically grounded, context-sensitive and expressively veracious considerations. The study describes the agency of course tutors, teachers and learners involved in the Schools and Sustainability course, as emergent from a social-ecological context of poverty and inequality, and from an education system with a dual transformative and progressive intent (Taylor, 1999). It uses a spiral approach to cluster-based teacher professional development (Janse van Rensburg & Mhoney, 2000) focusing on the development of autonomous (Bernstein, 1990) and reflexive teachers. With teachers well-disposed and qualified to fill a variety of roles in the classroom, these generative structures and mechanisms had the power to drive active learning processes with potential for manifestation as transformative praxis. Through the analysis of the active learning processes emergent from this context, the study shows that the manifestation of transformative praxis was contingent on relational situated learning, value-based reflexive deliberations, and an action-orientation with an emphasis on an iterative relationship between learning and doing. These findings enable a reframing of an interest in action in response to environmental issue and risk, to an interest in the processes that led up to that action. This provides a nuanced vision of active learning that does not judge an educational process by its outcome. Instead, it can be judged by the depth of the insights into absences (2E), the ability to guide moral deliberations on totality (3L), and by the degree of reality congruence (1M) in the lead up to the development of transformative agency (4D). The study also has a methodological interest. It contributes to educational and social science research in that it applies dialectical critical realist philosophy to a concrete context of active learning enquiry in environmental education. It reports on the value of the onto-axiolgical chain in describing a diachronic, emergent and open-ended process; in providing ontological grounding for analysis (1M); in understanding relationality in situated learing processes (2E); in focusing on value-based reflexive learning (3L) and in understanding transformative learning as “tensed socio-spatialising process” (Bhaskar, 1993: 160) where society is emergent from a stratified ontology, and agency and change are open-ended and flexible processes not wholly determined by the social structures from which they emerge (4D). Considering the knowledge interests defined in the 2011 South African Minimum Requirements for Teacher Education (South Africa. Department of Higher Education and Training, 2011) and the Curriculum Assessment Policy Statements (CAPS) which were implemented in South Africa from 2012 (in a phased approach), the study concludes with recommendations for exploring environmental learning in the CAPS. The study proposes working with a knowledge-focused curriculum focusing on the exploration and deepening of foundational environmental concepts, developing relational situated learning processes for meaningful local application of knowledge, supporting transformative praxis through the “unity of theory and practice in practice” (Bhaskar, 1993: 9), and implementing a spiral approach to cluster-based teacher professional development.
- Full Text:
- Date Issued: 2013
- Authors: Schudel, Ingrid Joan
- Date: 2013 , 2013-09-20
- Subjects: Active learning -- Study and teaching (Elementary) -- South Africa -- Eastern Cape Student-centered learning -- Research -- South Africa -- Eastern Cape Environmental education -- Study and teaching (Elementary) -- South Africa -- Eastern Cape Environmental education -- Curricula -- South Africa -- Eastern Cape Competency-based education -- South Africa -- Eastern Cape Teachers -- Training of -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1891 , http://hdl.handle.net/10962/d1006079
- Description: This is a study on the nature of learning, particularly the emergence of active learning processes in the case of an environmental education teacher professional development programme – the Eastern Cape Border-Kei cohort of the 2008 Schools and Sustainability Course. This was a part-time, one-year course supporting teachers to qualify, strengthen and deepen opportunities for environmental learning in the South African curriculum. An active learning framework (O’Donoghue, 2001) promoting teaching and learning with information, enquiry, action and reporting/reflection dimensions was integrated into the Schools and Sustainability course design to support these environmental learning opportunities. In this study, the notion of active learning is elaborated as a situated, action-oriented, deliberative and co-engaged approach to teaching and learning, and related to Bhaskar’s (1993) notion of transformative praxis. The study used a nested case study design, considering the case of six Foundation Phase teachers in six primary schools within the Border-Kei Schools and Sustainability cohort. Interviews, observations (of workshops and lesson plan implementation in classrooms) and document review of teacher portfolios (detailing course activities, lesson plans, learners’ work and learning and teaching support materials) were used to generate the bulk of the data. A critical realist theory underpinning the methodology enables a view of agency as emergent from social structures and mechanisms as elaborated in Archer’s (1998b) model of morphogenesis and Bhaskar’s (1993) model of four-planar being. The critical realist methodology also enables a view of emergent active learning processes as open-ended, responsive to particular potential, but dependent on contingencies (such as learning and teaching support materials, tools and methodologies). The analysis of emergent active learning processes focuses particularly on Bhaskar’s (1993) ontological-axiological chain (MELD schema) as a tool for analysing change. The MELD schema highlights1M ontological questions of what is (with emphasis on structures and generative mechanisms) and what could be (real, but non-actualised possibilities). It enables reflection on what mediating and interactive agential processes either reproduce what is or have the potential to transform what is to what could be (2E). Thirdly, the MELD schema enables reflection on what should be – this is the 3L “axiological moment” (Bhaskar, 1993: 9) where questions of values and ethics in relation to the holistic whole are raised. Finally, the schema raises questions (4D) of what can be, with ontologically grounded, context-sensitive and expressively veracious considerations. The study describes the agency of course tutors, teachers and learners involved in the Schools and Sustainability course, as emergent from a social-ecological context of poverty and inequality, and from an education system with a dual transformative and progressive intent (Taylor, 1999). It uses a spiral approach to cluster-based teacher professional development (Janse van Rensburg & Mhoney, 2000) focusing on the development of autonomous (Bernstein, 1990) and reflexive teachers. With teachers well-disposed and qualified to fill a variety of roles in the classroom, these generative structures and mechanisms had the power to drive active learning processes with potential for manifestation as transformative praxis. Through the analysis of the active learning processes emergent from this context, the study shows that the manifestation of transformative praxis was contingent on relational situated learning, value-based reflexive deliberations, and an action-orientation with an emphasis on an iterative relationship between learning and doing. These findings enable a reframing of an interest in action in response to environmental issue and risk, to an interest in the processes that led up to that action. This provides a nuanced vision of active learning that does not judge an educational process by its outcome. Instead, it can be judged by the depth of the insights into absences (2E), the ability to guide moral deliberations on totality (3L), and by the degree of reality congruence (1M) in the lead up to the development of transformative agency (4D). The study also has a methodological interest. It contributes to educational and social science research in that it applies dialectical critical realist philosophy to a concrete context of active learning enquiry in environmental education. It reports on the value of the onto-axiolgical chain in describing a diachronic, emergent and open-ended process; in providing ontological grounding for analysis (1M); in understanding relationality in situated learing processes (2E); in focusing on value-based reflexive learning (3L) and in understanding transformative learning as “tensed socio-spatialising process” (Bhaskar, 1993: 160) where society is emergent from a stratified ontology, and agency and change are open-ended and flexible processes not wholly determined by the social structures from which they emerge (4D). Considering the knowledge interests defined in the 2011 South African Minimum Requirements for Teacher Education (South Africa. Department of Higher Education and Training, 2011) and the Curriculum Assessment Policy Statements (CAPS) which were implemented in South Africa from 2012 (in a phased approach), the study concludes with recommendations for exploring environmental learning in the CAPS. The study proposes working with a knowledge-focused curriculum focusing on the exploration and deepening of foundational environmental concepts, developing relational situated learning processes for meaningful local application of knowledge, supporting transformative praxis through the “unity of theory and practice in practice” (Bhaskar, 1993: 9), and implementing a spiral approach to cluster-based teacher professional development.
- Full Text:
- Date Issued: 2013
Exploring and expanding capabilities, sustainability and gender justice in science teacher education : case studies in Zimbabwe and South Africa
- Authors: Chikunda, Charles
- Date: 2013 , 2013-08-30
- Subjects: Science teachers -- Training of -- South Africa -- Case studies Science teachers -- Training of -- Zimbabwe -- Case studies Mathematics teachers -- Training of -- South Africa -- Case studies Women in education -- South Africa -- Case studies Women in education -- Zimbabwe -- Case studies Environmental education -- Study and teaching -- Case studies Curriculum planning -- South Africa Curriculum planning -- Zimbabwe
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1887 , http://hdl.handle.net/10962/d1006026
- Description: The focus of this study was to explore and expand capabilities, sustainability and gender justice in Science, Mathematics and Technical subjects (SMTs) in teacher education curriculum practices as a process of Education for Sustainable Development in two case studies in Zimbabwe and South Africa. The study begins by discussing gender and science education discourse, locating it within Education for Sustainable Development discourse. Through this nexus, the study was able to explore gender and sustainability responsiveness of the curriculum practices of teacher educators in Science, Mathematics and Technical subjects; scrutinise underlying mechanisms that affect (promote or constrain) gender and sustainability responsive curriculum practices; and understand if and how teacher education curriculum practices consider the functionings and capabilities of females in relation to increased socio-ecological risk in a Southern African context. Influenced by a curriculum transformation commitment, an expansive learning phase was conducted to promote gender and sustainability responsive pedagogies in teacher education curriculum practices. As shown in the study, the expansive learning processes resulted in (re)conceptualising the curriculum practices (object), analysis of contradictions and developing new ways of doing work. Drawing from the sensitising concepts of dialectics, reflexivity and agency, the study worked with the three theoretical approaches of Cultural Historical Activity Theory (CHAT), feminist theory and capabilities theory. The capability and feminist lenses were used in the exploration of gender and sustainability responsiveness in science teacher education curriculum practices. CHAT, through its associated methodology of Developmental Work Research, offered the opportunity for researcher and participants in this study to come together to question and analyse curriculum practices and model new ways of doing work. Case study research was used in two case studies of teacher education curriculum practices in Science, Mathematics and Technical subjects, one in Zimbabwe and one in South Africa. Each case study is constituted with a networked activity system. The study used in-depth and focus group interviews and document analysis to explore gender and sustainability responsiveness in curriculum practices and to generate mirror data. Inductive and abductive modes of inference, and Critical Discourse Analysis were used to analyse data. This data was then used in Change Laboratory Workshops, where double stimulation and focus group discussions contributed to the expansive learning process. Findings from the exploration phase of the study revealed that most teacher educators in the two case studies had some basic levels of gender sensitivity, meaning that they had ability to perceive existing gender inequalities as it applies only to gender disaggregated data especially when it comes to enrolment and retention. However, there was no institutionalised pedagogic device in place in both case studies aimed at equipping future teachers with knowledge, skills, attitudes and values to promote aspects of capabilities (well-being achievement, wellbeing freedom, agency achievement and agency freedom) for girls in Science, Mathematics and Technical subjects. Science, Mathematics and Technical subjects teacher educators' curriculum practices were gender neutral, but in a gendered environment. This was a pedagogical tension that was visible in both case studies. On the other hand, socio-ecological issues, in cases where they were incorporated into the curriculum, were incorporated in a gender blind or gender neutral manner. Social ecological concerns such as climate change were treated as if they were not gendered both in their impact and in their mitigation and adaptation. It emerged that causal mechanisms shaping this situation were of a socio-political nature: there exist cultural differences between students and teacher educators; patriarchal ideology and hegemony; as well as other interfering binaries such as race and class. Other curriculum related constraints, though embedded in the socio-cultural-political nexus, include: rigid and content heavy curriculum, coupled with students who come into the system with inadequate content knowledge; and philosophy informing pedagogy namely scientism, with associated instrumentalist and functionalist tenets. All these led to contradictions between pedagogical practices with those expected by the Education for Sustainable Development framework. The study contributes in-depth insight into science teacher education curriculum development. By locating the study at the nexus of gender and Science, Mathematics and Technical subjects within the Education for Sustainable Development discourse, using the ontological lenses of feminist and capabilities, it was possible to interrogate aspects of quality and relevance of the science teacher education curriculum. The study also provides insight into participatory research and learning processes especially within the context of policy and curriculum development. It provides empirical evidence of mobilising reflexivity amongst both policy makers and policy implementers towards building human agency in policy translation for a curriculum transformation that is critical for responding to contemporary socio-ecological risks. , Microsoft� Word 2010 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2013
- Authors: Chikunda, Charles
- Date: 2013 , 2013-08-30
- Subjects: Science teachers -- Training of -- South Africa -- Case studies Science teachers -- Training of -- Zimbabwe -- Case studies Mathematics teachers -- Training of -- South Africa -- Case studies Women in education -- South Africa -- Case studies Women in education -- Zimbabwe -- Case studies Environmental education -- Study and teaching -- Case studies Curriculum planning -- South Africa Curriculum planning -- Zimbabwe
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1887 , http://hdl.handle.net/10962/d1006026
- Description: The focus of this study was to explore and expand capabilities, sustainability and gender justice in Science, Mathematics and Technical subjects (SMTs) in teacher education curriculum practices as a process of Education for Sustainable Development in two case studies in Zimbabwe and South Africa. The study begins by discussing gender and science education discourse, locating it within Education for Sustainable Development discourse. Through this nexus, the study was able to explore gender and sustainability responsiveness of the curriculum practices of teacher educators in Science, Mathematics and Technical subjects; scrutinise underlying mechanisms that affect (promote or constrain) gender and sustainability responsive curriculum practices; and understand if and how teacher education curriculum practices consider the functionings and capabilities of females in relation to increased socio-ecological risk in a Southern African context. Influenced by a curriculum transformation commitment, an expansive learning phase was conducted to promote gender and sustainability responsive pedagogies in teacher education curriculum practices. As shown in the study, the expansive learning processes resulted in (re)conceptualising the curriculum practices (object), analysis of contradictions and developing new ways of doing work. Drawing from the sensitising concepts of dialectics, reflexivity and agency, the study worked with the three theoretical approaches of Cultural Historical Activity Theory (CHAT), feminist theory and capabilities theory. The capability and feminist lenses were used in the exploration of gender and sustainability responsiveness in science teacher education curriculum practices. CHAT, through its associated methodology of Developmental Work Research, offered the opportunity for researcher and participants in this study to come together to question and analyse curriculum practices and model new ways of doing work. Case study research was used in two case studies of teacher education curriculum practices in Science, Mathematics and Technical subjects, one in Zimbabwe and one in South Africa. Each case study is constituted with a networked activity system. The study used in-depth and focus group interviews and document analysis to explore gender and sustainability responsiveness in curriculum practices and to generate mirror data. Inductive and abductive modes of inference, and Critical Discourse Analysis were used to analyse data. This data was then used in Change Laboratory Workshops, where double stimulation and focus group discussions contributed to the expansive learning process. Findings from the exploration phase of the study revealed that most teacher educators in the two case studies had some basic levels of gender sensitivity, meaning that they had ability to perceive existing gender inequalities as it applies only to gender disaggregated data especially when it comes to enrolment and retention. However, there was no institutionalised pedagogic device in place in both case studies aimed at equipping future teachers with knowledge, skills, attitudes and values to promote aspects of capabilities (well-being achievement, wellbeing freedom, agency achievement and agency freedom) for girls in Science, Mathematics and Technical subjects. Science, Mathematics and Technical subjects teacher educators' curriculum practices were gender neutral, but in a gendered environment. This was a pedagogical tension that was visible in both case studies. On the other hand, socio-ecological issues, in cases where they were incorporated into the curriculum, were incorporated in a gender blind or gender neutral manner. Social ecological concerns such as climate change were treated as if they were not gendered both in their impact and in their mitigation and adaptation. It emerged that causal mechanisms shaping this situation were of a socio-political nature: there exist cultural differences between students and teacher educators; patriarchal ideology and hegemony; as well as other interfering binaries such as race and class. Other curriculum related constraints, though embedded in the socio-cultural-political nexus, include: rigid and content heavy curriculum, coupled with students who come into the system with inadequate content knowledge; and philosophy informing pedagogy namely scientism, with associated instrumentalist and functionalist tenets. All these led to contradictions between pedagogical practices with those expected by the Education for Sustainable Development framework. The study contributes in-depth insight into science teacher education curriculum development. By locating the study at the nexus of gender and Science, Mathematics and Technical subjects within the Education for Sustainable Development discourse, using the ontological lenses of feminist and capabilities, it was possible to interrogate aspects of quality and relevance of the science teacher education curriculum. The study also provides insight into participatory research and learning processes especially within the context of policy and curriculum development. It provides empirical evidence of mobilising reflexivity amongst both policy makers and policy implementers towards building human agency in policy translation for a curriculum transformation that is critical for responding to contemporary socio-ecological risks. , Microsoft� Word 2010 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2013
Exploring interventions for participation of emerging farmers in the Eastern Cape ostrich-industry supply chain
- Authors: Pittaway, Timothy
- Date: 2013
- Subjects: Farmers -- South Africa -- Eastern Cape , Ostrich products industry -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10596 , http://hdl.handle.net/10948/d1021008
- Description: The changing agricultural environment (dualistic agricultural landscape, land reform programme, market liberalisation and globalisation) has caused emerging ostrich farmers to become increasingly isolated. Governmental agriculture reforms and public sector interventions have been insufficient to address all the challenges faced by rural ostrich farmers in the Eastern Cape. Participation in the ostrich supply chain for emerging farmers in the Eastern Cape is currently unsustainable as a result of avian influenza, control and registration protocols for ostriches (VPN04), structural barriers in marketing, technical constraints and a lack of market participation. People in the rural areas of the Eastern Cape are challenged by inferior infrastructure, poor site conditions, low earnings, poor access to health services and unreliable water sources. The marginal conditions and prevalent complexities in which agriculture is practised require costly resource intervention. Intensive ostrich production necessitates continuous genetic improvement, methodical record keeping, intensive egg incubation methods and highmaintenance chick rearing and ostrich handling while minimising feed costs throughout this process. Rural farmers have not embraced ostrich farming in the same way as they have done with other livestock farming because it does not offer the anthropological functions that traditional livestock farming provides. The ostrich supply chain requires a wide range of activities to bring products to the final consumer. The worth of ostrich production lies mainly in the higher returns which are achieved only through the export markets. Today the ostrich industry has become vulnerable to market cannibalism, a lack of market development, unregulated numbers of ostriches and recurring international meat bans. The deregulation of the ostrich single-channel marketing system had a substantial effect on the value chain on which farmers depended for market access and market protection. As the majority of ostrich products are being exported to the European Union, the role of intermediary agencies is becoming an important factor influencing entry into the high-end markets. This agent structure that represents the South African ostrich industry is vital for the distribution, market penetration and regulation of the ostrich products. The ostrich leather, which is today the main product line, is primarily used for luxury goods and is susceptible to economic downturn and over-supply. The ostrich meat industry has been severely influenced by outbreaks of avian influenza and processors now pre-heat the meat in order to maintain export. However, this preheating meat facility is only for export produce and available to farmers who conform to VPN04 and have officially registered farms. The relevant South African government departments played a crucial role in identifying avian influenza outbreaks and liaising with the European Union about avian influenza isolation strategies. No previous studies have been conducted on the participation of emerging farmers in the Eastern Cape ostrich-industry supply chain and on the interventions required to address the multiple constraints and forces in this sector. This led to a study with research emphasis on the required capacity for supply-chain participation and the supporting mechanisms that would be required for emerging ostrich farmers to integrate successfully into this supply chain. An exploratory research approach was chosen for the investigation, as no earlier research has been undertaken that could serve as a source of reliable data or reference. A triangulation research methodology using both the quantitative and the qualitative approach was applied. The qualitative research entailed an interpretive approach associated with using grounded theory and content analysis for interpreting data. The comparative case study design was the main qualitative research instrument for the multiple-case studies on emerging ostrich farmers in the Eastern Cape. The study was undertaken at five different sites, namely, the Peddie Ostrich Programme, the Rockhurst Ostrich Programme, the Hlumani Co-operative farm, the Zamukwanda Ostrich farm near Pearston and the Mimosadale Ostrich farm. The quantitative methods were applied to capture all the measurable components and representations of the stakeholders and participants, through interviews, questionnaires and focus group interviews. The quantitative study also included an experimental instrument to measure the capacity of emerging farmer programmes for supply chain participation. It was found that the main driver for three of the case studies pertained to land ownership and that ostrich farming was incidental and only seen as means of activity for income. These three humanitarian farming projects had limited capacity for intensive management requirements for ostrich farming. It was found that the VPN04 bio-security protocols and disease control require a higher level of record keeping for EU markets and is prohibitively expensive for poor rural emerging farmers. The study established that the emerging ostrich farming programmes contributed value to the industry and government rural development in land redistribution programmes, vehicles for reduction of poverty and job creation in the rural areas and by acting as out-grower programmes for commercial farmers. The researcher’s observation is that through strategic interventions the programmes have potential to become commercial players in the industry. The following interventions were recommended from this study: Feasibility study of programmes and review of location selection before initiation. Providing supportive interventions for programme start-ups; Improved selection of programme beneficiaries; Improved structure of emerging farmers’ co-operatives; On-going and appropriate training for emerging ostrich farmers; The role of government and mentors needs to be defined; Reducing feed costs; Establishing programmes linkages to informal markets and facilitating increased self-consumption; Developing new export markets; Alternative finance for the no-income months; Alternative marketing channels to export markets; Representation of emerging farmers in the ostrich-industry leadership structures.
- Full Text:
- Date Issued: 2013
- Authors: Pittaway, Timothy
- Date: 2013
- Subjects: Farmers -- South Africa -- Eastern Cape , Ostrich products industry -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10596 , http://hdl.handle.net/10948/d1021008
- Description: The changing agricultural environment (dualistic agricultural landscape, land reform programme, market liberalisation and globalisation) has caused emerging ostrich farmers to become increasingly isolated. Governmental agriculture reforms and public sector interventions have been insufficient to address all the challenges faced by rural ostrich farmers in the Eastern Cape. Participation in the ostrich supply chain for emerging farmers in the Eastern Cape is currently unsustainable as a result of avian influenza, control and registration protocols for ostriches (VPN04), structural barriers in marketing, technical constraints and a lack of market participation. People in the rural areas of the Eastern Cape are challenged by inferior infrastructure, poor site conditions, low earnings, poor access to health services and unreliable water sources. The marginal conditions and prevalent complexities in which agriculture is practised require costly resource intervention. Intensive ostrich production necessitates continuous genetic improvement, methodical record keeping, intensive egg incubation methods and highmaintenance chick rearing and ostrich handling while minimising feed costs throughout this process. Rural farmers have not embraced ostrich farming in the same way as they have done with other livestock farming because it does not offer the anthropological functions that traditional livestock farming provides. The ostrich supply chain requires a wide range of activities to bring products to the final consumer. The worth of ostrich production lies mainly in the higher returns which are achieved only through the export markets. Today the ostrich industry has become vulnerable to market cannibalism, a lack of market development, unregulated numbers of ostriches and recurring international meat bans. The deregulation of the ostrich single-channel marketing system had a substantial effect on the value chain on which farmers depended for market access and market protection. As the majority of ostrich products are being exported to the European Union, the role of intermediary agencies is becoming an important factor influencing entry into the high-end markets. This agent structure that represents the South African ostrich industry is vital for the distribution, market penetration and regulation of the ostrich products. The ostrich leather, which is today the main product line, is primarily used for luxury goods and is susceptible to economic downturn and over-supply. The ostrich meat industry has been severely influenced by outbreaks of avian influenza and processors now pre-heat the meat in order to maintain export. However, this preheating meat facility is only for export produce and available to farmers who conform to VPN04 and have officially registered farms. The relevant South African government departments played a crucial role in identifying avian influenza outbreaks and liaising with the European Union about avian influenza isolation strategies. No previous studies have been conducted on the participation of emerging farmers in the Eastern Cape ostrich-industry supply chain and on the interventions required to address the multiple constraints and forces in this sector. This led to a study with research emphasis on the required capacity for supply-chain participation and the supporting mechanisms that would be required for emerging ostrich farmers to integrate successfully into this supply chain. An exploratory research approach was chosen for the investigation, as no earlier research has been undertaken that could serve as a source of reliable data or reference. A triangulation research methodology using both the quantitative and the qualitative approach was applied. The qualitative research entailed an interpretive approach associated with using grounded theory and content analysis for interpreting data. The comparative case study design was the main qualitative research instrument for the multiple-case studies on emerging ostrich farmers in the Eastern Cape. The study was undertaken at five different sites, namely, the Peddie Ostrich Programme, the Rockhurst Ostrich Programme, the Hlumani Co-operative farm, the Zamukwanda Ostrich farm near Pearston and the Mimosadale Ostrich farm. The quantitative methods were applied to capture all the measurable components and representations of the stakeholders and participants, through interviews, questionnaires and focus group interviews. The quantitative study also included an experimental instrument to measure the capacity of emerging farmer programmes for supply chain participation. It was found that the main driver for three of the case studies pertained to land ownership and that ostrich farming was incidental and only seen as means of activity for income. These three humanitarian farming projects had limited capacity for intensive management requirements for ostrich farming. It was found that the VPN04 bio-security protocols and disease control require a higher level of record keeping for EU markets and is prohibitively expensive for poor rural emerging farmers. The study established that the emerging ostrich farming programmes contributed value to the industry and government rural development in land redistribution programmes, vehicles for reduction of poverty and job creation in the rural areas and by acting as out-grower programmes for commercial farmers. The researcher’s observation is that through strategic interventions the programmes have potential to become commercial players in the industry. The following interventions were recommended from this study: Feasibility study of programmes and review of location selection before initiation. Providing supportive interventions for programme start-ups; Improved selection of programme beneficiaries; Improved structure of emerging farmers’ co-operatives; On-going and appropriate training for emerging ostrich farmers; The role of government and mentors needs to be defined; Reducing feed costs; Establishing programmes linkages to informal markets and facilitating increased self-consumption; Developing new export markets; Alternative finance for the no-income months; Alternative marketing channels to export markets; Representation of emerging farmers in the ostrich-industry leadership structures.
- Full Text:
- Date Issued: 2013
Faecal source tracking and water quality in the Eastern Cape, South Africa
- Authors: Luyt, Catherine Diane
- Date: 2013
- Subjects: Water quality -- South Africa -- Grahamstown , Waterborne infection -- Management , Drinking water -- Contamination -- South Africa -- Grahamstown
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:6052 , http://hdl.handle.net/10962/d1018242
- Description: Water quality is concerning as many still lack access to safe drinking water. Alternate sources such as rivers (FC up to 1600 CFUs/100 mL) and rainwater are often polluted. Rainwater tanks require maintenance to improve water quality, but could be used for non-potable purposes or irrigation. Grahamstown infrastructural failures initiate deviations from DWAF 1996 domestic water guidelines for microorganisms within the distribution system. Frequent testing can decrease risks of waterborne diseases. Limitations to this are inaccessibility of rural areas, distances from testing centres and costs. The low cost H2S strip test able to be used onsite by communities, may aid in risk assessment. H2S strip test results are not affected by sulphate (14 to 4240 mg/L) or nitrite (up to 47 mg/L). Transportation of the H2S strip tests between 10 and 32°C does not modify results significantly. Similarly to other studies: Klebsiella spp.; Enterobacter spp. and Serratia spp. were isolated from H2S strip tests. The mH2S strip test corresponds best with HPC in treated water, while in untreated river water it has approximately 90% correspondence with FCs, while survival of FC causes discrepancies with the H2S test after 22 days. A faecal coliform inactivation rate of 0.1 CFUs/ day, may be longer than many pathogens. Faecal source tracking, not currently practised in South Africa, could aid health risk assessments for disaster management, which would improve the NMMP programme. Bacterial survival times could propose the time period for which water is unsafe. Bifidobacteria and Rhodococcus are proposed to help identify the faecal pollution source. But enumeration of Rhodococcus is too lengthy (21 days). The tracking ratio of bifidobacteria (between 0.1 to 6.25) is not source definitive. The bifidobacteria survival rate, could indicator the time since faecal pollution. The bifidobacteria average survival rate is 2.3 CFUs per day for both groups. The culturability and selectivity of agar is still poor, with total bifidobacteria less selectively culturable. Enterococci overgrowth of TB was decreased by Beerens media. SUB is still useful to identify potential human faecal inputs. A single tracking method is thus not suitable alone, but requires a combination of techniques.
- Full Text:
- Date Issued: 2013
- Authors: Luyt, Catherine Diane
- Date: 2013
- Subjects: Water quality -- South Africa -- Grahamstown , Waterborne infection -- Management , Drinking water -- Contamination -- South Africa -- Grahamstown
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:6052 , http://hdl.handle.net/10962/d1018242
- Description: Water quality is concerning as many still lack access to safe drinking water. Alternate sources such as rivers (FC up to 1600 CFUs/100 mL) and rainwater are often polluted. Rainwater tanks require maintenance to improve water quality, but could be used for non-potable purposes or irrigation. Grahamstown infrastructural failures initiate deviations from DWAF 1996 domestic water guidelines for microorganisms within the distribution system. Frequent testing can decrease risks of waterborne diseases. Limitations to this are inaccessibility of rural areas, distances from testing centres and costs. The low cost H2S strip test able to be used onsite by communities, may aid in risk assessment. H2S strip test results are not affected by sulphate (14 to 4240 mg/L) or nitrite (up to 47 mg/L). Transportation of the H2S strip tests between 10 and 32°C does not modify results significantly. Similarly to other studies: Klebsiella spp.; Enterobacter spp. and Serratia spp. were isolated from H2S strip tests. The mH2S strip test corresponds best with HPC in treated water, while in untreated river water it has approximately 90% correspondence with FCs, while survival of FC causes discrepancies with the H2S test after 22 days. A faecal coliform inactivation rate of 0.1 CFUs/ day, may be longer than many pathogens. Faecal source tracking, not currently practised in South Africa, could aid health risk assessments for disaster management, which would improve the NMMP programme. Bacterial survival times could propose the time period for which water is unsafe. Bifidobacteria and Rhodococcus are proposed to help identify the faecal pollution source. But enumeration of Rhodococcus is too lengthy (21 days). The tracking ratio of bifidobacteria (between 0.1 to 6.25) is not source definitive. The bifidobacteria survival rate, could indicator the time since faecal pollution. The bifidobacteria average survival rate is 2.3 CFUs per day for both groups. The culturability and selectivity of agar is still poor, with total bifidobacteria less selectively culturable. Enterococci overgrowth of TB was decreased by Beerens media. SUB is still useful to identify potential human faecal inputs. A single tracking method is thus not suitable alone, but requires a combination of techniques.
- Full Text:
- Date Issued: 2013
Fixed points of single-valued and multi-valued mappings with applications
- Authors: Stofile, Simfumene
- Date: 2013
- Subjects: Fixed point theory Mappings (Mathematics) Coincidence theory (Mathematics) Metric spaces Uniform spaces Set-valued maps
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5397 , http://hdl.handle.net/10962/d1002960
- Description: The relationship between the convergence of a sequence of self mappings of a metric space and their fixed points, known as the stability (or continuity) of fixed points has been of continuing interest and widely studied in fixed point theory. In this thesis we study the stability of common fixed points in a Hausdorff uniform space whose uniformity is generated by a family of pseudometrics, by using some general notations of convergence. These results are then extended to 2-metric spaces due to S. Gähler. In addition, a well-known theorem of T. Suzuki that generalized the Banach Contraction Principle is also extended to 2-metric spaces and applied to obtain a coincidence theorem for a pair of mappings on an arbitrary set with values in a 2-metric space. Further, we prove the existence of coincidence and fixed points of Ćirić type weakly generalized contractions in metric spaces. Subsequently, the above result is utilized to discuss applications to the convergence of modified Mann and Ishikawa iterations in a convex metric space. Finally, we obtain coincidence, fixed and stationary point results for multi-valued and hybrid pairs of mappings on a metric space.
- Full Text:
- Date Issued: 2013
- Authors: Stofile, Simfumene
- Date: 2013
- Subjects: Fixed point theory Mappings (Mathematics) Coincidence theory (Mathematics) Metric spaces Uniform spaces Set-valued maps
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5397 , http://hdl.handle.net/10962/d1002960
- Description: The relationship between the convergence of a sequence of self mappings of a metric space and their fixed points, known as the stability (or continuity) of fixed points has been of continuing interest and widely studied in fixed point theory. In this thesis we study the stability of common fixed points in a Hausdorff uniform space whose uniformity is generated by a family of pseudometrics, by using some general notations of convergence. These results are then extended to 2-metric spaces due to S. Gähler. In addition, a well-known theorem of T. Suzuki that generalized the Banach Contraction Principle is also extended to 2-metric spaces and applied to obtain a coincidence theorem for a pair of mappings on an arbitrary set with values in a 2-metric space. Further, we prove the existence of coincidence and fixed points of Ćirić type weakly generalized contractions in metric spaces. Subsequently, the above result is utilized to discuss applications to the convergence of modified Mann and Ishikawa iterations in a convex metric space. Finally, we obtain coincidence, fixed and stationary point results for multi-valued and hybrid pairs of mappings on a metric space.
- Full Text:
- Date Issued: 2013
Gametogenesis, gonadal recrudescence, restraint and spawning patterns in Nile perch, Lates niloticus (Linnaeus, 1758)
- Authors: Kahwa, David
- Date: 2013
- Subjects: Nile perch -- Victoria, Lake Gametogenesis Oogenesis Spermatogenesis Nile perch -- Spawning -- Victoria, Lake Nile perch -- Induced spawning -- Victoria, Lake Nile perch -- Reproduction -- Endocrine aspects -- Victoria, Lake Fish culture -- Victoria, Lake
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5182 , http://hdl.handle.net/10962/d1001834
- Description: The Nile perch, Lates niloticus (Linnaeus, 1758), is a predacious freshwater fish widely distributed throughout the Afro-tropic eco-zone. The species was introduced to Lake Victoria in the early 1950s and by 1980 it had dominated the fisheries of Lake Victoria. This was followed by a dramatic decrease in the Nile perch fisheries production due to uncontrolled exploitation. The purpose of this thesis is to provide fundamental knowledge that can be applied in aquaculture and fisheries management through the study of the reproductive biology of L. niloticus. The research was aimed at the studying of the diverse aspects of the reproductive biology of L. niloticus in the Lake Victoria, Ugandan populations. This included reproductive patterns in relation to proximate environmental conditions, size at sexual maturity, gonad and gamete structure, gametogenesis and induced ovulation. The size at 50% sexual maturity for female Nile perch was 59.4 cm, which is lower than the earlier reported size of greater than 90 cm total length. Male L. niloticus matured at 57.8 cm total length in Lake Victoria. Microscopy revealed that L. niloticus from Lake Victoria had one spawning period that started in November and ended in March. Type I atresia occurred at high frequency from March to June, and type III atresia was present from July to September and between November and December. Spermatogenesis in L. niloticus is cystic and sperm development is the result of asynchronous activation of the germ cells. Type II spermatozoa are simple, uni-flagellate aquasperm with no acrosome. Oogenesis in L. niloticus differed from that of other fishes in that no cortical alveoli were present in any stage of oogenesis. Numerous oil globules were present in the primary yolk vesicle stage. This formed one centrally positioned, large oil globule in the tertiary yolk vesicle oocytes during final oocyte maturation. Clove oil was an effective sedative and an anaesthetic for the handling of L. niloticus. Induction time was more rapid at clove oil concentrations of 50 - 100 μl L⁻¹ than in fish exposed to clove oil concentrations less than 50 μl L⁻¹. Fish exposed to high concentrations exhibited significantly short induction times of less than 240 seconds. On average, fish recovered within 673 ± 58 seconds for all the concentrations used. Prolonged exposure of L. niloticus to low clove oil concentrations of 2.5 - 10 μl L⁻¹ did not change the blood plasma cortisol, glucose, and the lactate and chloride ion concentration, relative to the control treatment. Captive breeding was attempted by conducting induced spawning experiments. Only final oocyte maturation was achieved using a decapeptide Gonadotropin Releasing Hormone (Dargin, sGnRH-MET), combined with a water-soluble dopamine receptor antagonist metoclopramide. This thesis suggests a research approach that provides a basis for aquaculture of the new species by first studying reproductive biology patterns and then linking the information to gonad and gamete structure so that spawning times can be estimated. It further provides insights into aspects of the reproductive biology of the species and the effects of hormonal intervention on oocytes by showing at which stage of oocyte development hormones should be applied in L. niloticus. Clove oil can be used to sedate and anaesthetise L. niloticus broodfish to reduce the stress related to the handling of large specimens.
- Full Text:
- Date Issued: 2013
- Authors: Kahwa, David
- Date: 2013
- Subjects: Nile perch -- Victoria, Lake Gametogenesis Oogenesis Spermatogenesis Nile perch -- Spawning -- Victoria, Lake Nile perch -- Induced spawning -- Victoria, Lake Nile perch -- Reproduction -- Endocrine aspects -- Victoria, Lake Fish culture -- Victoria, Lake
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5182 , http://hdl.handle.net/10962/d1001834
- Description: The Nile perch, Lates niloticus (Linnaeus, 1758), is a predacious freshwater fish widely distributed throughout the Afro-tropic eco-zone. The species was introduced to Lake Victoria in the early 1950s and by 1980 it had dominated the fisheries of Lake Victoria. This was followed by a dramatic decrease in the Nile perch fisheries production due to uncontrolled exploitation. The purpose of this thesis is to provide fundamental knowledge that can be applied in aquaculture and fisheries management through the study of the reproductive biology of L. niloticus. The research was aimed at the studying of the diverse aspects of the reproductive biology of L. niloticus in the Lake Victoria, Ugandan populations. This included reproductive patterns in relation to proximate environmental conditions, size at sexual maturity, gonad and gamete structure, gametogenesis and induced ovulation. The size at 50% sexual maturity for female Nile perch was 59.4 cm, which is lower than the earlier reported size of greater than 90 cm total length. Male L. niloticus matured at 57.8 cm total length in Lake Victoria. Microscopy revealed that L. niloticus from Lake Victoria had one spawning period that started in November and ended in March. Type I atresia occurred at high frequency from March to June, and type III atresia was present from July to September and between November and December. Spermatogenesis in L. niloticus is cystic and sperm development is the result of asynchronous activation of the germ cells. Type II spermatozoa are simple, uni-flagellate aquasperm with no acrosome. Oogenesis in L. niloticus differed from that of other fishes in that no cortical alveoli were present in any stage of oogenesis. Numerous oil globules were present in the primary yolk vesicle stage. This formed one centrally positioned, large oil globule in the tertiary yolk vesicle oocytes during final oocyte maturation. Clove oil was an effective sedative and an anaesthetic for the handling of L. niloticus. Induction time was more rapid at clove oil concentrations of 50 - 100 μl L⁻¹ than in fish exposed to clove oil concentrations less than 50 μl L⁻¹. Fish exposed to high concentrations exhibited significantly short induction times of less than 240 seconds. On average, fish recovered within 673 ± 58 seconds for all the concentrations used. Prolonged exposure of L. niloticus to low clove oil concentrations of 2.5 - 10 μl L⁻¹ did not change the blood plasma cortisol, glucose, and the lactate and chloride ion concentration, relative to the control treatment. Captive breeding was attempted by conducting induced spawning experiments. Only final oocyte maturation was achieved using a decapeptide Gonadotropin Releasing Hormone (Dargin, sGnRH-MET), combined with a water-soluble dopamine receptor antagonist metoclopramide. This thesis suggests a research approach that provides a basis for aquaculture of the new species by first studying reproductive biology patterns and then linking the information to gonad and gamete structure so that spawning times can be estimated. It further provides insights into aspects of the reproductive biology of the species and the effects of hormonal intervention on oocytes by showing at which stage of oocyte development hormones should be applied in L. niloticus. Clove oil can be used to sedate and anaesthetise L. niloticus broodfish to reduce the stress related to the handling of large specimens.
- Full Text:
- Date Issued: 2013
GDR development policy with special reference to Africa, c. 1960-1990
- Van der Heyden, Ulrich Klaus Helmut
- Authors: Van der Heyden, Ulrich Klaus Helmut
- Date: 2013
- Subjects: Germany -- Foreign relations -- Africa , Germany -- Foreign economic relations -- Africa , Africa -- Foreign relations -- Germany , Africa -- Foreign economic relations -- Germany , Africa -- Politics and government -- 1960- , Africa -- History -- 1960-
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2531 , http://hdl.handle.net/10962/d1001860
- Description: This thesis explores the political, economic and theoretical underpinnings of the German Democratic Republic’s (GDR’s) development policies towards the Third World between c.1960 and 1990. Particular attention is paid to Africa. Case studies of assistance to SWAPO and the ANC further focus the attention of the reader on southern Africa in particular. Aspects of both military and civilian aid are considered, including both development initiatives overseas in Africa, and development training for Africans within the GDR itself. Since German “reunification”, the GDR’s history has been explored largely from a West German perspective. The present work attempts to provide a more balanced view of successes and shortcomings of the GDR’s policies towards, and interaction with, African countries and liberation movements. It also aims to bring to the attention of English-speaking readers German archival sources, other primary sources and published works which they would otherwise have been unlikely to encounter. From its formation, the GDR made strenuous efforts to develop relations with countries which were either free from colonial dependency or were struggling for freedom. Over the course of thirty years, it followed a number of different approaches, and developed diverse objectives. These were shaped in the wider context of the cold war, the Hallstein doctrine (which established that the FRG – and, in effect, its allies - would not establish or maintain diplomatic relations with any state that recognised the GDR), the relationships between the GDR and partner socialist states, and the economic difficulties faced by the GDR. Arising from this complex situation, from time to time, both internally in the GDR and in terms of its foreign affairs, tensions and discrepancies arose between theoretical objectives and political and economic reality. Despite these severe constraints, during the period under review, the volume and range of the GDR’s relationships with developing countries increased dramatically. For example, between 1970 and 1987, the number of developing countries with which the GDR had foreign economic relations on the basis of international agreements grew from 23 to 64. Viewed within its economic context, the state was arguably far more committed to development aid than the Federal Republic of Germany. In addition, there is a great deal of evidence that “solidarity” with developing nations and the oppressed enjoyed a considerable degree of popular support.
- Full Text:
- Date Issued: 2013
- Authors: Van der Heyden, Ulrich Klaus Helmut
- Date: 2013
- Subjects: Germany -- Foreign relations -- Africa , Germany -- Foreign economic relations -- Africa , Africa -- Foreign relations -- Germany , Africa -- Foreign economic relations -- Germany , Africa -- Politics and government -- 1960- , Africa -- History -- 1960-
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2531 , http://hdl.handle.net/10962/d1001860
- Description: This thesis explores the political, economic and theoretical underpinnings of the German Democratic Republic’s (GDR’s) development policies towards the Third World between c.1960 and 1990. Particular attention is paid to Africa. Case studies of assistance to SWAPO and the ANC further focus the attention of the reader on southern Africa in particular. Aspects of both military and civilian aid are considered, including both development initiatives overseas in Africa, and development training for Africans within the GDR itself. Since German “reunification”, the GDR’s history has been explored largely from a West German perspective. The present work attempts to provide a more balanced view of successes and shortcomings of the GDR’s policies towards, and interaction with, African countries and liberation movements. It also aims to bring to the attention of English-speaking readers German archival sources, other primary sources and published works which they would otherwise have been unlikely to encounter. From its formation, the GDR made strenuous efforts to develop relations with countries which were either free from colonial dependency or were struggling for freedom. Over the course of thirty years, it followed a number of different approaches, and developed diverse objectives. These were shaped in the wider context of the cold war, the Hallstein doctrine (which established that the FRG – and, in effect, its allies - would not establish or maintain diplomatic relations with any state that recognised the GDR), the relationships between the GDR and partner socialist states, and the economic difficulties faced by the GDR. Arising from this complex situation, from time to time, both internally in the GDR and in terms of its foreign affairs, tensions and discrepancies arose between theoretical objectives and political and economic reality. Despite these severe constraints, during the period under review, the volume and range of the GDR’s relationships with developing countries increased dramatically. For example, between 1970 and 1987, the number of developing countries with which the GDR had foreign economic relations on the basis of international agreements grew from 23 to 64. Viewed within its economic context, the state was arguably far more committed to development aid than the Federal Republic of Germany. In addition, there is a great deal of evidence that “solidarity” with developing nations and the oppressed enjoyed a considerable degree of popular support.
- Full Text:
- Date Issued: 2013
Genetics and thermal biology of littorinid snails of the genera Afrolittorina, Echinolittorina and Littoraria (Gastropoda: Littorinidae) from temperate, subtropical and tropical regions
- Authors: Matumba, Tshifhiwa Given
- Date: 2013
- Subjects: Littorinidae -- South Africa Littorinidae -- Brunei Littorinidae -- Adaptation -- South Africa Littorinidae -- Adaptation -- Brunei Littorinidae -- Effect of temperature on -- South Africa Littorinidae -- Effect of temperature on -- Brunei Littorinidae -- Physiology Snails -- South Africa Snails -- Brunei Gastropoda -- South Africa Gastropoda -- Brunei Intertidal animals -- South Africa Intertidal animals -- Brunei
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5588 , http://hdl.handle.net/10962/d1001953
- Description: With the anticipated effects of climate change due to global warming, there is concern over how animals, especially ectotherms, will respond to or tolerate extreme and fluctuating environmental temperature stress. Littorinid snails are intertidal ectotherms that live high on the shore where they experience both extreme and variable conditions of temperature and desiccation stress, and are believed to live close to their tolerance limits. This study investigated the thermal biology of littorinid snails of the genera Afrolittorina, Echinolittorina and Littoraria from temperate, subtropical and tropical regions in South Africa and Brunei Darussalam using thermal tolerance, heart function, and proteome approaches. The effects of conditions, such as rate of change in temperature, acclimation, heat shock, season and starvation were also tested. In addition, the evolutionary relationships and genetic diversity between and within the South African Afrolittorina spp. were investigated using mitochondrial and nuclear markers. Genetic results confirmed that these are two distinct species, with the brown to black A. knysnaensis predominant in the cool-temperate region of South Africa and the pale blue-grey A. africana in the subtropical region. There was low genetic variation and differentiation within each species, suggesting high gene flow among populations as a result of the effects of ocean currents on the dispersal of their planktotrophic larvae. Tests using exposure to high temperatures revealed differences in the thermal tolerances, heart performance and protein profiles of species from different latitudes, regions and zones on the shore. Thermal tolerance conformed to expectations, with clear, statistically significant trends from high tolerance in subtropical species to lower tolerance in temperate species. However, for Afrolittorina spp., there were no significant differences in the thermal tolerances of conspecifics from different regions, though there was a significant difference in thermal tolerance between juveniles and adults. Overall, adults of all species showed higher thermal tolerances than juveniles. Although lethal temperatures for these species were higher in summer than winter, laboratory acclimation had no effect on heat coma temperatures. All species showed some regulation of heart rate, with a degree of independence of heart rate from temperature across mid-range temperatures. The tropical species showed quick induction and good regulation of heart rate followed by the subtropical and temperate species, which displayed mixed responses including regulation, partial regulation and lack of regulation. Overall, tropical Echinolittorina spp. showed good regulation, while the subtropical E. natalensis and Littoraria glabrata exhibited a mixture of partial regulation and regulation. The subtropical/temperate Afrolittorina spp. showed high individual variability, some animals exhibiting regulation, while others did not. These effects seem to be largely phylogenetically determined as there were no differences in the heart rate responses of Afrolittorina spp. from different regions. The temperatures at which heart rate became independent of temperature (thermoneutral zone) were within the range experienced under natural conditions. In addition, there were differences in Arrhenius breakpoint and endpoint temperatures, showing a trend from higher in tropical animals to lower for temperate animals. Conditions such as acclimation, heat shock and starvation had little or no effect on heart performance. However, a slow increase in temperature induced good regulation of heart rate with noticeable shifts of breakpoints and endpoints for Afrolittorina spp. Lastly, there were differences in the proteome responses between and within Afrolittorina spp. as a function of species, size and treatment. Although both large and small A. knysnaensis had a greater number of protein spots in their proteome than A. africana (though the difference was not significant), the later showed significantly higher differential expression of certain proteins following heat stress. In addition, juveniles of both species displayed greater numbers of protein spots in their proteome than adults. The results indicate a difference in the physiological and biochemical responses (i.e. adaptations) of these snails to temperature, and this seems to relate to differences in biogeography, phylogeny, species identity and ecology. The ability to regulate heart rate is phylogenetically determined, while thresholds and lethal limits correspond to biogeography and species ecology. The proteome seems to correspond to species ecology. The results also indicate that these littorinids can tolerate high temperature stress and in this respect they are well suited to life in the intertidal zones or habitats where temperature and other stresses or conditions are extreme and can change abruptly. However, the limited ability of these snails to acclimate to different temperatures suggests that they are already living close to their tolerance limits with small safety margins or narrow thermal windows and so may be vulnerable to small rises in substratum temperature and/or solar radiation.
- Full Text:
- Date Issued: 2013
- Authors: Matumba, Tshifhiwa Given
- Date: 2013
- Subjects: Littorinidae -- South Africa Littorinidae -- Brunei Littorinidae -- Adaptation -- South Africa Littorinidae -- Adaptation -- Brunei Littorinidae -- Effect of temperature on -- South Africa Littorinidae -- Effect of temperature on -- Brunei Littorinidae -- Physiology Snails -- South Africa Snails -- Brunei Gastropoda -- South Africa Gastropoda -- Brunei Intertidal animals -- South Africa Intertidal animals -- Brunei
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5588 , http://hdl.handle.net/10962/d1001953
- Description: With the anticipated effects of climate change due to global warming, there is concern over how animals, especially ectotherms, will respond to or tolerate extreme and fluctuating environmental temperature stress. Littorinid snails are intertidal ectotherms that live high on the shore where they experience both extreme and variable conditions of temperature and desiccation stress, and are believed to live close to their tolerance limits. This study investigated the thermal biology of littorinid snails of the genera Afrolittorina, Echinolittorina and Littoraria from temperate, subtropical and tropical regions in South Africa and Brunei Darussalam using thermal tolerance, heart function, and proteome approaches. The effects of conditions, such as rate of change in temperature, acclimation, heat shock, season and starvation were also tested. In addition, the evolutionary relationships and genetic diversity between and within the South African Afrolittorina spp. were investigated using mitochondrial and nuclear markers. Genetic results confirmed that these are two distinct species, with the brown to black A. knysnaensis predominant in the cool-temperate region of South Africa and the pale blue-grey A. africana in the subtropical region. There was low genetic variation and differentiation within each species, suggesting high gene flow among populations as a result of the effects of ocean currents on the dispersal of their planktotrophic larvae. Tests using exposure to high temperatures revealed differences in the thermal tolerances, heart performance and protein profiles of species from different latitudes, regions and zones on the shore. Thermal tolerance conformed to expectations, with clear, statistically significant trends from high tolerance in subtropical species to lower tolerance in temperate species. However, for Afrolittorina spp., there were no significant differences in the thermal tolerances of conspecifics from different regions, though there was a significant difference in thermal tolerance between juveniles and adults. Overall, adults of all species showed higher thermal tolerances than juveniles. Although lethal temperatures for these species were higher in summer than winter, laboratory acclimation had no effect on heat coma temperatures. All species showed some regulation of heart rate, with a degree of independence of heart rate from temperature across mid-range temperatures. The tropical species showed quick induction and good regulation of heart rate followed by the subtropical and temperate species, which displayed mixed responses including regulation, partial regulation and lack of regulation. Overall, tropical Echinolittorina spp. showed good regulation, while the subtropical E. natalensis and Littoraria glabrata exhibited a mixture of partial regulation and regulation. The subtropical/temperate Afrolittorina spp. showed high individual variability, some animals exhibiting regulation, while others did not. These effects seem to be largely phylogenetically determined as there were no differences in the heart rate responses of Afrolittorina spp. from different regions. The temperatures at which heart rate became independent of temperature (thermoneutral zone) were within the range experienced under natural conditions. In addition, there were differences in Arrhenius breakpoint and endpoint temperatures, showing a trend from higher in tropical animals to lower for temperate animals. Conditions such as acclimation, heat shock and starvation had little or no effect on heart performance. However, a slow increase in temperature induced good regulation of heart rate with noticeable shifts of breakpoints and endpoints for Afrolittorina spp. Lastly, there were differences in the proteome responses between and within Afrolittorina spp. as a function of species, size and treatment. Although both large and small A. knysnaensis had a greater number of protein spots in their proteome than A. africana (though the difference was not significant), the later showed significantly higher differential expression of certain proteins following heat stress. In addition, juveniles of both species displayed greater numbers of protein spots in their proteome than adults. The results indicate a difference in the physiological and biochemical responses (i.e. adaptations) of these snails to temperature, and this seems to relate to differences in biogeography, phylogeny, species identity and ecology. The ability to regulate heart rate is phylogenetically determined, while thresholds and lethal limits correspond to biogeography and species ecology. The proteome seems to correspond to species ecology. The results also indicate that these littorinids can tolerate high temperature stress and in this respect they are well suited to life in the intertidal zones or habitats where temperature and other stresses or conditions are extreme and can change abruptly. However, the limited ability of these snails to acclimate to different temperatures suggests that they are already living close to their tolerance limits with small safety margins or narrow thermal windows and so may be vulnerable to small rises in substratum temperature and/or solar radiation.
- Full Text:
- Date Issued: 2013
Green zone nation : the securitisation and militarisation of the 2010 FIFA World Cup, South Africa
- McMichael, Christopher Bryden
- Authors: McMichael, Christopher Bryden
- Date: 2013 , 2013-04-22
- Subjects: World Cup (Soccer) (2010 : South Africa) -- Safety measures -- Research Fédération internationale de football association Militarism -- Research -- South Africa Sports -- Political aspects -- Research -- South Africa Police -- South Africa South Africa -- Armed Forces Crime -- South Africa Violent crimes -- South Africa Violent crimes -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2752 , http://hdl.handle.net/10962/d1001622
- Description: This thesis explores the relationship between the safety and security measures for the 2010 FIFA World Cup and the militarisation of urban space and policing in post-apartheid South Africa. In particular, it focuses upon how the South African state and FIFA, the owners of the World Cup franchise, worked to present the World Cup as an event which required exceptional levels of security – resulting in a historically unprecedented joint police and military operation across host cities. However, in contrast with previous research on these security measures, this thesis aims to interrogate the political and commercial forces which constructed security and positions them against a backdrop of intensified state violence and social exclusion in South Africa. Concurrently, the South African case was indicative of an international militarisation of major events, with policing operations comparable to national states of emergency. This is representative of the ‘new military urbanism’ in which everyday urban life is rendered as a site of ubiquitous risk, leading to the increased diffusion of military tactics and doctrines in policing and policy. While the interpenetration between urbanism and militarism has often been studied against the context of the ‘war on terror’, in the case of South Africa this has primarily been accelerated by a pervasive social fear of violent crime, which has resulted in the securitisation of cities, the remilitarisation of policing and the intensification of a historical legacy of socio-spatial inequalities. The South African government aimed to use the World Cup to ‘rebrand’ the country’s violent international image, while promising that security measures would leave a legacy of safer cities for ordinary South Africans. The concept of legacies was also responsive to the commercial imperatives of FIFA and a range of other security actors, including foreign governments and the private security industry. However these policing measures were primarily cosmetic and designed to allay the fears of foreign tourists and the national middle class. In practice security measures pivoted around the enforcement of social control and urban marginalisation while serving as a training ground for an increasingly repressive state security apparatus. Security was as much a matter of fortifying islands of privilege and aiding a project of financial extraction as protecting the public from harm. , Microsoft� Office Word 2007 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 2013
- Authors: McMichael, Christopher Bryden
- Date: 2013 , 2013-04-22
- Subjects: World Cup (Soccer) (2010 : South Africa) -- Safety measures -- Research Fédération internationale de football association Militarism -- Research -- South Africa Sports -- Political aspects -- Research -- South Africa Police -- South Africa South Africa -- Armed Forces Crime -- South Africa Violent crimes -- South Africa Violent crimes -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2752 , http://hdl.handle.net/10962/d1001622
- Description: This thesis explores the relationship between the safety and security measures for the 2010 FIFA World Cup and the militarisation of urban space and policing in post-apartheid South Africa. In particular, it focuses upon how the South African state and FIFA, the owners of the World Cup franchise, worked to present the World Cup as an event which required exceptional levels of security – resulting in a historically unprecedented joint police and military operation across host cities. However, in contrast with previous research on these security measures, this thesis aims to interrogate the political and commercial forces which constructed security and positions them against a backdrop of intensified state violence and social exclusion in South Africa. Concurrently, the South African case was indicative of an international militarisation of major events, with policing operations comparable to national states of emergency. This is representative of the ‘new military urbanism’ in which everyday urban life is rendered as a site of ubiquitous risk, leading to the increased diffusion of military tactics and doctrines in policing and policy. While the interpenetration between urbanism and militarism has often been studied against the context of the ‘war on terror’, in the case of South Africa this has primarily been accelerated by a pervasive social fear of violent crime, which has resulted in the securitisation of cities, the remilitarisation of policing and the intensification of a historical legacy of socio-spatial inequalities. The South African government aimed to use the World Cup to ‘rebrand’ the country’s violent international image, while promising that security measures would leave a legacy of safer cities for ordinary South Africans. The concept of legacies was also responsive to the commercial imperatives of FIFA and a range of other security actors, including foreign governments and the private security industry. However these policing measures were primarily cosmetic and designed to allay the fears of foreign tourists and the national middle class. In practice security measures pivoted around the enforcement of social control and urban marginalisation while serving as a training ground for an increasingly repressive state security apparatus. Security was as much a matter of fortifying islands of privilege and aiding a project of financial extraction as protecting the public from harm. , Microsoft� Office Word 2007 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 2013
High performance nonwovens in technical textile applications
- Ogunleye, Christopher Olarinde
- Authors: Ogunleye, Christopher Olarinde
- Date: 2013
- Subjects: Nonwoven fabrics , Textile fabrics -- Technological innovations
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10356 , http://hdl.handle.net/10948/d1021011
- Description: The aim of this research was to establish the optimum processing conditions and parameters for producing nonwoven fabrics best suited for application in disposable and protective wear for surgical gowns, drapes and laboratory coats. Carded and crosslapped webs, of three basic weights (80, 120, and 150g/m2), from greige (unscoured and unbleached) cotton, viscose and polyester fibres, were hydroentangled, using three different waterjet pressures (60, 100 and 120 bars), on a Fleissner Aquajet hydroentanglement machine. An antibacterial agent (Ruco-Coat FC 9005) and a fluorochemical water repellent agent (Ruco Bac-AGP), were applied in one bath using the pad-dry-cure technique, to impart both antibacterial and water repellent properties to the fabrics, SEM photomicrographs indicating that the finished polymers were evenly dispersed on the fabric surface. The effect of waterjet pressure, fabric weight and type and treatment on the structure of the nonwoven produced, was evaluated by measuring the relevant characteristics of the fabrics. As expected, there was an interrelationship between fabric weight, thickness, and density, the fabric thickness and mass density increasing with fabric weight. An increase in waterjet pressure decreased the fabric thickness and increased the fabric density. The water repellent and antibacterial treatment increased the fabric weight and thickness. The antimicrobial activity of the fabrics was assessed by determining the percentage reduction in Staphylococcus aureus and Escherichia coli bacteria population. The maximum percent reduction at 24hrs contact time for both bacteria ranged from 99.5 to 99.6 percent for all the fabric types. The standard spray test ratings for the three treated fabrics ranged from 80-90 percent, whereas that of the untreated water repellent fabric was zero, while the contact angles for all the fabric types exceeded 90 degrees, indicating good resistance to wetting. It was found that the tensile strength of the fabric in the cross-machine direction was higher than that in the machine direction, for both the treated and untreated fabrics, with the tensile strengths in both the MD and CD of the treated fabrics were greater than that of the untreated fabrics, the reverse being true for the extension at break. An increase in waterjet pressure increased the tensile strength but decreased the extension at break, for both the treated and untreated fabrics. The finishing treatment decreased the mean pore size of all the fabrics, the mean pore size decreasing with an increase in fabric weight and waterjet pressure. An increase in waterjet pressure and fabric weight decreased the air and water vapour permeability, as did the finishing treatment, although the differences were not always statistically significant. The polyester fabrics had the highest water and air permeability. Hence low weight fabrics of 80 g/m2, which were hydroentangled at low water jet pressures of 60 bars, were suitable for use in this study due to their higher air and water vapour permeability as well as higher pore size distribution. These group of fabrics thus meet the requirements for surgical gowns, drapes, nurses’ uniforms and laboratory coats.
- Full Text:
- Date Issued: 2013
- Authors: Ogunleye, Christopher Olarinde
- Date: 2013
- Subjects: Nonwoven fabrics , Textile fabrics -- Technological innovations
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10356 , http://hdl.handle.net/10948/d1021011
- Description: The aim of this research was to establish the optimum processing conditions and parameters for producing nonwoven fabrics best suited for application in disposable and protective wear for surgical gowns, drapes and laboratory coats. Carded and crosslapped webs, of three basic weights (80, 120, and 150g/m2), from greige (unscoured and unbleached) cotton, viscose and polyester fibres, were hydroentangled, using three different waterjet pressures (60, 100 and 120 bars), on a Fleissner Aquajet hydroentanglement machine. An antibacterial agent (Ruco-Coat FC 9005) and a fluorochemical water repellent agent (Ruco Bac-AGP), were applied in one bath using the pad-dry-cure technique, to impart both antibacterial and water repellent properties to the fabrics, SEM photomicrographs indicating that the finished polymers were evenly dispersed on the fabric surface. The effect of waterjet pressure, fabric weight and type and treatment on the structure of the nonwoven produced, was evaluated by measuring the relevant characteristics of the fabrics. As expected, there was an interrelationship between fabric weight, thickness, and density, the fabric thickness and mass density increasing with fabric weight. An increase in waterjet pressure decreased the fabric thickness and increased the fabric density. The water repellent and antibacterial treatment increased the fabric weight and thickness. The antimicrobial activity of the fabrics was assessed by determining the percentage reduction in Staphylococcus aureus and Escherichia coli bacteria population. The maximum percent reduction at 24hrs contact time for both bacteria ranged from 99.5 to 99.6 percent for all the fabric types. The standard spray test ratings for the three treated fabrics ranged from 80-90 percent, whereas that of the untreated water repellent fabric was zero, while the contact angles for all the fabric types exceeded 90 degrees, indicating good resistance to wetting. It was found that the tensile strength of the fabric in the cross-machine direction was higher than that in the machine direction, for both the treated and untreated fabrics, with the tensile strengths in both the MD and CD of the treated fabrics were greater than that of the untreated fabrics, the reverse being true for the extension at break. An increase in waterjet pressure increased the tensile strength but decreased the extension at break, for both the treated and untreated fabrics. The finishing treatment decreased the mean pore size of all the fabrics, the mean pore size decreasing with an increase in fabric weight and waterjet pressure. An increase in waterjet pressure and fabric weight decreased the air and water vapour permeability, as did the finishing treatment, although the differences were not always statistically significant. The polyester fabrics had the highest water and air permeability. Hence low weight fabrics of 80 g/m2, which were hydroentangled at low water jet pressures of 60 bars, were suitable for use in this study due to their higher air and water vapour permeability as well as higher pore size distribution. These group of fabrics thus meet the requirements for surgical gowns, drapes, nurses’ uniforms and laboratory coats.
- Full Text:
- Date Issued: 2013
Improving decision making through analysing the economic impact of budget allocation at the city of Cape Town
- Authors: Kaiser, Gisela Noelle
- Date: 2013
- Subjects: Cape Town (South Africa) -- Politics and government , City planning -- South Africa --Cape Town , Budget -- South Africa -- Cape Town , Local government
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:9684 , http://hdl.handle.net/10948/d1008305 , Cape Town (South Africa) -- Politics and government , City planning -- South Africa --Cape Town , Budget -- South Africa -- Cape Town , Local government
- Description: Local government is at the forefront of engagement between the government and South Africa’s people, delivering basic services to communities. Following the transition to a democratic government in 1994, the country was demarcated in a manner that provides complete coverage by local government. Annually, managing the administration of service delivery implementation at local government level costs the country many billions. Much of the revenue used by local government in providing services is derived from income from sale of basic services and property rates, augmented by allocations from national and provincial government, equitably shared amongst municipalities. Local government has autonomy in its operations, but is strictly governed by a collection of cascading legislation, introduced to protect the interests of the people. The primary objective of the research was to investigate the efficacy of budget expenditure in local government, in particular the City of Cape Town as a metropolitan municipality. With an annual budget approaching R30 billion, the aim was to establish how the budget was determined and allocated to the service menu provided by the City, and to investigate whether better methods of allocating expenditure could be developed. A mixed research methodology was followed, relying on quantitative methods for analysing survey data statistically, while providing for detailed qualitative methods in interviewing and studying the specific case in detail. The theoretical perspective most suited to this research was found to be that of pragmatism, for its flexibility of interpretation, practicality and space for multiple perspectives. A constructivist epistemology was adopted to provide for the interplay between object and subject in constructing meaning. This research focused on examination of applicable legislation, secondary data in reports, and statistical analysis of opinion surveys of municipal officials involved in budgeting at different levels and interviews with key stakeholders. The findings indicate that budget allocation can be improved upon in a number of ways, despite complying with a myriad of restrictive and onerous regulations applicable to local government. It was found that the administration is fragmented in its operations and that the structure of necessity favours isolated service delivery rather than integration. Further, that compliance impacts negatively on time spent in planning and pursuit of strategic intent to the extent that Reporting often becomes a more important deliverable than basic services. The size of the City hinders common understanding, and introducing any change in political vision requires particular attention.
- Full Text:
- Date Issued: 2013
- Authors: Kaiser, Gisela Noelle
- Date: 2013
- Subjects: Cape Town (South Africa) -- Politics and government , City planning -- South Africa --Cape Town , Budget -- South Africa -- Cape Town , Local government
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:9684 , http://hdl.handle.net/10948/d1008305 , Cape Town (South Africa) -- Politics and government , City planning -- South Africa --Cape Town , Budget -- South Africa -- Cape Town , Local government
- Description: Local government is at the forefront of engagement between the government and South Africa’s people, delivering basic services to communities. Following the transition to a democratic government in 1994, the country was demarcated in a manner that provides complete coverage by local government. Annually, managing the administration of service delivery implementation at local government level costs the country many billions. Much of the revenue used by local government in providing services is derived from income from sale of basic services and property rates, augmented by allocations from national and provincial government, equitably shared amongst municipalities. Local government has autonomy in its operations, but is strictly governed by a collection of cascading legislation, introduced to protect the interests of the people. The primary objective of the research was to investigate the efficacy of budget expenditure in local government, in particular the City of Cape Town as a metropolitan municipality. With an annual budget approaching R30 billion, the aim was to establish how the budget was determined and allocated to the service menu provided by the City, and to investigate whether better methods of allocating expenditure could be developed. A mixed research methodology was followed, relying on quantitative methods for analysing survey data statistically, while providing for detailed qualitative methods in interviewing and studying the specific case in detail. The theoretical perspective most suited to this research was found to be that of pragmatism, for its flexibility of interpretation, practicality and space for multiple perspectives. A constructivist epistemology was adopted to provide for the interplay between object and subject in constructing meaning. This research focused on examination of applicable legislation, secondary data in reports, and statistical analysis of opinion surveys of municipal officials involved in budgeting at different levels and interviews with key stakeholders. The findings indicate that budget allocation can be improved upon in a number of ways, despite complying with a myriad of restrictive and onerous regulations applicable to local government. It was found that the administration is fragmented in its operations and that the structure of necessity favours isolated service delivery rather than integration. Further, that compliance impacts negatively on time spent in planning and pursuit of strategic intent to the extent that Reporting often becomes a more important deliverable than basic services. The size of the City hinders common understanding, and introducing any change in political vision requires particular attention.
- Full Text:
- Date Issued: 2013
International joint ventures and firm value: an empirical study of South African partner firms
- Mangwengwende, Tadiwanashe Mukudzeyi
- Authors: Mangwengwende, Tadiwanashe Mukudzeyi
- Date: 2013
- Subjects: Joint ventures Joint ventures -- South Africa Business enterprises -- Valuation International business enterprises
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1033 , http://hdl.handle.net/10962/d1004174
- Description: This study investigates international equity joint ventures (IJVs) and South African partner firm value creation at formation. In addition, it tests whether four contentious formation characteristics, namely, the geographical location of the IJV partner, the level of economic development in the IJV partner’s home country, the level of equity held by the South African firm and the industry of the South African firm, can explain when South African IJVs are value enhancing and when they are value diminishing. IJVs are a popular business mode and an important channel for infrastructure and skills investment in developing countries. However, despite their popularity and potential social benefits, these IJVs are predominantly created by the decisions of private firms to collaborate with foreign firms and governments. Consequently the preservation and development of the IJV investment channel is dependent on the encouragement of private firm IJV participation. It is at uncovering potential tools to encourage IJV participation by South African firms that IJV firm value creation becomes important because it stands as a motivator for South African firms’ involvement in IJVs. Existing literature on IJVs and partner firm value has presented conflicting evidence with support for the views that they are value enhancing, value diminishing or of no immediate consequence to their partners’ firm value. Consequently, previous research offers limited firm value support for IJVs. For South African firms considering joint ventures and national policy makers determined to promote IJVs there is a need for an investigation of South African partner IJV firm value effects. Moreover, it is also necessary to test potential explanatory variables that may help to explain when the IJVs are value enhancing and when they are not as this will inform IJV contract negotiations and how limited national government resources are used to promote IJVs. In order to assess firm value creation for South African firms this study performed event studies on IJV formation announcements from 1998 to 2011 using daily share returns from the Johannesburg Securities Exchange taking care to incorporate recent developments in the event study methodology. The study found that while the market responds to IJV announcements, its responses do not, on average, reflect that IJVs are firm value enhancing for their South African partners at formation. This stands in contrast to considerable empirical literature and IJV firm value creation theory. In addition, factoring in formation characteristics, argued to potentially help explain cases of value creation and destruction from IJVs, provided limited explanation for positive and negative wealth effectsfor South African firms entering IJVs. This result has important value for IJV participants, national economic policy makers and IJV researchers. For IJV participants and national policy makers, the results caution unfettered entry/support for IJVs and challenge the role of equity distribution in determining the value of the IJV to its partner firms. For IJV researchers, the results present new evidence questioning IJV firm value creation at formation and provide a potential explanation for the conflict in previous IJV research. The study makes four key contributions to the existing knowledge of IJV firm value creation. Firstly, it assesses IJV wealth effects for the hitherto untested South African IJVs. Secondly, in doing so it adds a new data set (South African IJVs) to the current IJV literature. Thirdly, in reviewing the literature on IJV firm value creation the study presents a disaggregated model of IJV firm value creation from which to develop IJV research and potentially solve the persistent conflict in empirical results on IJV partner wealth effects. Finally, it informs future South African IJV agreements by uncovering factors that influence and do not influence partner wealth effects for South African firms.
- Full Text:
- Date Issued: 2013
- Authors: Mangwengwende, Tadiwanashe Mukudzeyi
- Date: 2013
- Subjects: Joint ventures Joint ventures -- South Africa Business enterprises -- Valuation International business enterprises
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1033 , http://hdl.handle.net/10962/d1004174
- Description: This study investigates international equity joint ventures (IJVs) and South African partner firm value creation at formation. In addition, it tests whether four contentious formation characteristics, namely, the geographical location of the IJV partner, the level of economic development in the IJV partner’s home country, the level of equity held by the South African firm and the industry of the South African firm, can explain when South African IJVs are value enhancing and when they are value diminishing. IJVs are a popular business mode and an important channel for infrastructure and skills investment in developing countries. However, despite their popularity and potential social benefits, these IJVs are predominantly created by the decisions of private firms to collaborate with foreign firms and governments. Consequently the preservation and development of the IJV investment channel is dependent on the encouragement of private firm IJV participation. It is at uncovering potential tools to encourage IJV participation by South African firms that IJV firm value creation becomes important because it stands as a motivator for South African firms’ involvement in IJVs. Existing literature on IJVs and partner firm value has presented conflicting evidence with support for the views that they are value enhancing, value diminishing or of no immediate consequence to their partners’ firm value. Consequently, previous research offers limited firm value support for IJVs. For South African firms considering joint ventures and national policy makers determined to promote IJVs there is a need for an investigation of South African partner IJV firm value effects. Moreover, it is also necessary to test potential explanatory variables that may help to explain when the IJVs are value enhancing and when they are not as this will inform IJV contract negotiations and how limited national government resources are used to promote IJVs. In order to assess firm value creation for South African firms this study performed event studies on IJV formation announcements from 1998 to 2011 using daily share returns from the Johannesburg Securities Exchange taking care to incorporate recent developments in the event study methodology. The study found that while the market responds to IJV announcements, its responses do not, on average, reflect that IJVs are firm value enhancing for their South African partners at formation. This stands in contrast to considerable empirical literature and IJV firm value creation theory. In addition, factoring in formation characteristics, argued to potentially help explain cases of value creation and destruction from IJVs, provided limited explanation for positive and negative wealth effectsfor South African firms entering IJVs. This result has important value for IJV participants, national economic policy makers and IJV researchers. For IJV participants and national policy makers, the results caution unfettered entry/support for IJVs and challenge the role of equity distribution in determining the value of the IJV to its partner firms. For IJV researchers, the results present new evidence questioning IJV firm value creation at formation and provide a potential explanation for the conflict in previous IJV research. The study makes four key contributions to the existing knowledge of IJV firm value creation. Firstly, it assesses IJV wealth effects for the hitherto untested South African IJVs. Secondly, in doing so it adds a new data set (South African IJVs) to the current IJV literature. Thirdly, in reviewing the literature on IJV firm value creation the study presents a disaggregated model of IJV firm value creation from which to develop IJV research and potentially solve the persistent conflict in empirical results on IJV partner wealth effects. Finally, it informs future South African IJV agreements by uncovering factors that influence and do not influence partner wealth effects for South African firms.
- Full Text:
- Date Issued: 2013
Invasion of Lantana into India: analyzing introduction, spread, human adaptations and management
- Hari Krishnan, Ramesh Kannan
- Authors: Hari Krishnan, Ramesh Kannan
- Date: 2013
- Subjects: Lantana -- India Weeds -- Control -- India Plant introduction -- India Natural resources -- India Botany, Economic -- India Botany -- Social aspects -- India
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4728 , http://hdl.handle.net/10962/d1001756
- Description: Objectives and Research Questions 1. To reconstruct the history of invasion of Lantana in India from where, by who, and when was Lantana species introduced into India?, given its long history in the country, is it still spreading or has it become more or less stable? 2. To study the human adaptation to Lantana invasion: socioeconomic causes and consequences of the use of Lantana as an alternative source of livelihood for forest dependent communities in southern India; how have local communities adapted to the invasion?; what are the key determinants that may have driven communities to use Lantana?; what are the economic consequences of the use of Lantana by local communities? 3. To critically review local practices and forest policy for the management of Lantana in southern India.; how has the use of Lantana by local communities impacted its local regeneration?; does the use of Lantana in local context have implications for its management?; what has been the role of the Forest Department and its policies in managing Lantana?
- Full Text:
- Date Issued: 2013
- Authors: Hari Krishnan, Ramesh Kannan
- Date: 2013
- Subjects: Lantana -- India Weeds -- Control -- India Plant introduction -- India Natural resources -- India Botany, Economic -- India Botany -- Social aspects -- India
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4728 , http://hdl.handle.net/10962/d1001756
- Description: Objectives and Research Questions 1. To reconstruct the history of invasion of Lantana in India from where, by who, and when was Lantana species introduced into India?, given its long history in the country, is it still spreading or has it become more or less stable? 2. To study the human adaptation to Lantana invasion: socioeconomic causes and consequences of the use of Lantana as an alternative source of livelihood for forest dependent communities in southern India; how have local communities adapted to the invasion?; what are the key determinants that may have driven communities to use Lantana?; what are the economic consequences of the use of Lantana by local communities? 3. To critically review local practices and forest policy for the management of Lantana in southern India.; how has the use of Lantana by local communities impacted its local regeneration?; does the use of Lantana in local context have implications for its management?; what has been the role of the Forest Department and its policies in managing Lantana?
- Full Text:
- Date Issued: 2013
Investigation into causes of service delivery protests in municipalities :a case study of Nelson Mandela Bay Municipality
- Authors: Shaidi, Elisante Walter
- Date: 2013
- Subjects: Municipal government|zSouth Africa -- Port Elizabeth , Municipal government
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:8245 , http://hdl.handle.net/10948/d1011153 , Municipal government|zSouth Africa -- Port Elizabeth , Municipal government
- Description: This study investigates the causes of the service delivery protests in South African municipalities that occurred between 2005 to 2013. In a sense, the recent widespread service delivery protests which, in many instances, have turned violent, have sounded an alarm that cannot be ignored. The study is premised on the fact that no political democracy can survive and flourish if the mass of its people remain in poverty, and in a state of inequality and unemployed without tangible prospects for a better life. In this regard, the presence of service delivery protests, especially violent ones, is a threat to South Africa’s young democracy and its sustainability. This study is based on the assumption that the Nelson Mandela Bay Metropolitan Municipality, like other municipalities in South Africa, could be confronted with the possibility of further violent service delivery protests if the current causes were not scientifically investigated and solutions found. The study adopted a hypothesis with a view that South African municipalities could succeed in rendering effective public services if matters of poor public participation, corruption, service delivery inhibiting systemic factors, a cumbersome legislative environment, political infighting, poor intergovernmental fiscal regime and the low capacity of municipalities were adequately addressed. The study proposed to provide a brief literature review on the emergence of service delivery protests against the backdrop of a theoretical investigation on the new local government developmental mandate. The empirical survey and research methodology employed in the study is described, followed by the operationalisation of the survey questionnaire used for gathering field data. The research findings of the empirical survey are then statistically analysed, interpreted and reported. Some of the findings on the causes of service delivery protests includes slow pace of service delivery, especially in the delivery of sustainable human settlements, poor public participation and other underpinning systemic factors. Recommendations flowing from, inter alia, the results of the empirical study, are presented on how the existing status quo can be changed to enhance service delivery and development. If adopted, these recommendations will enable the Nelson Mandela Bay Municipality, as a development agent, to fulfil its developmental mandate thereby addressing the causes of the service delivery protests currently facing it.
- Full Text:
- Date Issued: 2013
- Authors: Shaidi, Elisante Walter
- Date: 2013
- Subjects: Municipal government|zSouth Africa -- Port Elizabeth , Municipal government
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:8245 , http://hdl.handle.net/10948/d1011153 , Municipal government|zSouth Africa -- Port Elizabeth , Municipal government
- Description: This study investigates the causes of the service delivery protests in South African municipalities that occurred between 2005 to 2013. In a sense, the recent widespread service delivery protests which, in many instances, have turned violent, have sounded an alarm that cannot be ignored. The study is premised on the fact that no political democracy can survive and flourish if the mass of its people remain in poverty, and in a state of inequality and unemployed without tangible prospects for a better life. In this regard, the presence of service delivery protests, especially violent ones, is a threat to South Africa’s young democracy and its sustainability. This study is based on the assumption that the Nelson Mandela Bay Metropolitan Municipality, like other municipalities in South Africa, could be confronted with the possibility of further violent service delivery protests if the current causes were not scientifically investigated and solutions found. The study adopted a hypothesis with a view that South African municipalities could succeed in rendering effective public services if matters of poor public participation, corruption, service delivery inhibiting systemic factors, a cumbersome legislative environment, political infighting, poor intergovernmental fiscal regime and the low capacity of municipalities were adequately addressed. The study proposed to provide a brief literature review on the emergence of service delivery protests against the backdrop of a theoretical investigation on the new local government developmental mandate. The empirical survey and research methodology employed in the study is described, followed by the operationalisation of the survey questionnaire used for gathering field data. The research findings of the empirical survey are then statistically analysed, interpreted and reported. Some of the findings on the causes of service delivery protests includes slow pace of service delivery, especially in the delivery of sustainable human settlements, poor public participation and other underpinning systemic factors. Recommendations flowing from, inter alia, the results of the empirical study, are presented on how the existing status quo can be changed to enhance service delivery and development. If adopted, these recommendations will enable the Nelson Mandela Bay Municipality, as a development agent, to fulfil its developmental mandate thereby addressing the causes of the service delivery protests currently facing it.
- Full Text:
- Date Issued: 2013
Investigation into the technical feasibility of biological treatment of precious metal refining wastewater
- Authors: Moore, Bronwyn Ann
- Date: 2013
- Subjects: Sewage -- Purification -- Biological treatment -- South Africa Sewage -- Purification -- Activated sludge process -- South Africa Water reuse -- South Africa Flotation -- South Africa Platinum mines and mining -- Waste disposal -- South Africa Platinum mines and mining -- Economic aspects -- South Africa Mine water -- Environmental aspects -- South Africa Platinum mines and mining -- Waste minimization -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3888 , http://hdl.handle.net/10962/d1002013
- Description: The hydrometallurgical refining of platinum group metals results in large volumes of liquid waste that requires suitable treatment before any disposal can be contemplated. The wastewater streams are characterized by extremes of pH, high inorganic ion content (such as chloride), significant residual metal loads and small amounts of entrained organic compounds. Historically these effluents were housed in evaporation reservoirs, however lack of space and growing water demands have led Anglo Platinum to consider treatment of these effluents. The aim of this study was to investigate whether biological wastewater treatment could produce water suitable for onsite reuse. Bench-scale activated sludge and anaerobic digestion for co-treatment of an acidic refinery waste stream with domestic wastewater were used to give preliminary data. Activated sludge showed better water treatment at lab scale in terms of removal efficiencies of ammonia (approximately 25%, cf. 20% in anaerobic digestion) and COD (70% cf. 43% in digestion) and greater robustness when biomass health was compared. Activated sludge was consequently selected for a pilot plant trial. The pilot plant was operated on-site and performed comparably with the bench-scale system, however challenges in the clarifier design led to losses of biomass and poor effluent quality (suspended solids washout). The pilot plant was unable to alter the pH of the feed, but a two week maturation period resulted in the pH increasing from 5.3 to 7.0. Tests on algal treatment as an alternative or follow-on unit operation to activated sludge showed it not to be a viable process. The activated sludge effluent was assessed for onsite reuse in flotation and it was found that there was no significant difference between its flotation performance and that of the process water currently used, indicating the effluent generated by the biological treatment system can be used successfully for flotation. Flotation is the method whereby minerals refining operations recover minerals of interest from ore through the addition of chemicals and aeration of the ore slurry. Target minerals adhere to the bubbles and can be removed from the process.
- Full Text:
- Date Issued: 2013
- Authors: Moore, Bronwyn Ann
- Date: 2013
- Subjects: Sewage -- Purification -- Biological treatment -- South Africa Sewage -- Purification -- Activated sludge process -- South Africa Water reuse -- South Africa Flotation -- South Africa Platinum mines and mining -- Waste disposal -- South Africa Platinum mines and mining -- Economic aspects -- South Africa Mine water -- Environmental aspects -- South Africa Platinum mines and mining -- Waste minimization -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3888 , http://hdl.handle.net/10962/d1002013
- Description: The hydrometallurgical refining of platinum group metals results in large volumes of liquid waste that requires suitable treatment before any disposal can be contemplated. The wastewater streams are characterized by extremes of pH, high inorganic ion content (such as chloride), significant residual metal loads and small amounts of entrained organic compounds. Historically these effluents were housed in evaporation reservoirs, however lack of space and growing water demands have led Anglo Platinum to consider treatment of these effluents. The aim of this study was to investigate whether biological wastewater treatment could produce water suitable for onsite reuse. Bench-scale activated sludge and anaerobic digestion for co-treatment of an acidic refinery waste stream with domestic wastewater were used to give preliminary data. Activated sludge showed better water treatment at lab scale in terms of removal efficiencies of ammonia (approximately 25%, cf. 20% in anaerobic digestion) and COD (70% cf. 43% in digestion) and greater robustness when biomass health was compared. Activated sludge was consequently selected for a pilot plant trial. The pilot plant was operated on-site and performed comparably with the bench-scale system, however challenges in the clarifier design led to losses of biomass and poor effluent quality (suspended solids washout). The pilot plant was unable to alter the pH of the feed, but a two week maturation period resulted in the pH increasing from 5.3 to 7.0. Tests on algal treatment as an alternative or follow-on unit operation to activated sludge showed it not to be a viable process. The activated sludge effluent was assessed for onsite reuse in flotation and it was found that there was no significant difference between its flotation performance and that of the process water currently used, indicating the effluent generated by the biological treatment system can be used successfully for flotation. Flotation is the method whereby minerals refining operations recover minerals of interest from ore through the addition of chemicals and aeration of the ore slurry. Target minerals adhere to the bubbles and can be removed from the process.
- Full Text:
- Date Issued: 2013
Low symmetry metallophthalocyanines and their nanoparticle conjugates for photodynamic antimicrobial chemotherapy
- Authors: Masilela, Nkosiphile
- Date: 2013
- Subjects: Nanoparticles Anti-infective agents Chemotherapy Photochemotherapy Quantum dots Gold Silver , Phthalocyanines
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4278 , http://hdl.handle.net/10962/d1001906
- Description: This thesis reports on the syntheses of novel low symmetrically substituted Zn, Sn, Ge and Ti MPc complexes containing a single carboxylic or cysteinyl group available for attachments to MNPs. The complexes were extensively characterized by various techniques to ensure their purity. Various metallic nanoparticles consisting of silver (AgNPs), gold (AuNPs) as well as quantum dots (QDs) were successfully prepared and conjugated to the low symmetry phthalocyanine complexes. The conjugates were successfully characterized using many techniques. The Q-band maxima of the MPcs were observed at completely different wavelength regions depending on the nature of the substituents and the central metal used. Blue shifting of the Q band in the absorption spectra was observed for the complexes in the presence of AuNPs, while aggregation was observed in the presence of quantum dots. The complexes were successfully electrospun into polymer fibers for the antimicrobial inhibition of bacteria. The photophysical and photochemical properties of these complexes were extensively investigated. Higher triplet and singlet oxygen quantum yields were achieved for the Ge Pc complexes, with all the complexes giving reasonable singlet oxygen quantum yields. An enhancement in triplet and singlet oxygen quantum yields was observed for all the complexes in the presence of metal nanoparticles. However, the singlet oxygen quantum yields decreased for all the complexes when incorporated into electrospun fibers. The antimicrobial behaviour of the complexes was investigated against Bacillus Subtilis and Staphylococcus Aureus in solution and in the fiber matrix. High antimicrobial inhibitions were observed for the Ge complexes followed by the ZnPc derivatives. All the low symmetry ZnPc derivatives were conjugated to AgNPs and their antimicrobial behaviour was compared to their symmetrical counterparts. The best antimicrobial inhibition behaviour was observed for the low symmetry Pcs when compared to their symmetrical counterparts. In the absence and in the presence of AgNPs, axially ligated SiPc also showed better antimicrobial activity when it was compared to the unsubstituted ZnPc complex.
- Full Text:
- Date Issued: 2013
- Authors: Masilela, Nkosiphile
- Date: 2013
- Subjects: Nanoparticles Anti-infective agents Chemotherapy Photochemotherapy Quantum dots Gold Silver , Phthalocyanines
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4278 , http://hdl.handle.net/10962/d1001906
- Description: This thesis reports on the syntheses of novel low symmetrically substituted Zn, Sn, Ge and Ti MPc complexes containing a single carboxylic or cysteinyl group available for attachments to MNPs. The complexes were extensively characterized by various techniques to ensure their purity. Various metallic nanoparticles consisting of silver (AgNPs), gold (AuNPs) as well as quantum dots (QDs) were successfully prepared and conjugated to the low symmetry phthalocyanine complexes. The conjugates were successfully characterized using many techniques. The Q-band maxima of the MPcs were observed at completely different wavelength regions depending on the nature of the substituents and the central metal used. Blue shifting of the Q band in the absorption spectra was observed for the complexes in the presence of AuNPs, while aggregation was observed in the presence of quantum dots. The complexes were successfully electrospun into polymer fibers for the antimicrobial inhibition of bacteria. The photophysical and photochemical properties of these complexes were extensively investigated. Higher triplet and singlet oxygen quantum yields were achieved for the Ge Pc complexes, with all the complexes giving reasonable singlet oxygen quantum yields. An enhancement in triplet and singlet oxygen quantum yields was observed for all the complexes in the presence of metal nanoparticles. However, the singlet oxygen quantum yields decreased for all the complexes when incorporated into electrospun fibers. The antimicrobial behaviour of the complexes was investigated against Bacillus Subtilis and Staphylococcus Aureus in solution and in the fiber matrix. High antimicrobial inhibitions were observed for the Ge complexes followed by the ZnPc derivatives. All the low symmetry ZnPc derivatives were conjugated to AgNPs and their antimicrobial behaviour was compared to their symmetrical counterparts. The best antimicrobial inhibition behaviour was observed for the low symmetry Pcs when compared to their symmetrical counterparts. In the absence and in the presence of AgNPs, axially ligated SiPc also showed better antimicrobial activity when it was compared to the unsubstituted ZnPc complex.
- Full Text:
- Date Issued: 2013
M-health user experience framework for the public healthcare sector
- Authors: Ouma, Stella
- Date: 2013
- Subjects: Communication in public health , Public health -- South Africa , Wireless communication systems in medical care
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:9827 , http://hdl.handle.net/10948/d1020793
- Description: The public healthcare sectors within developing nations face a lot of challenges because of constrained resources available to them. The South African public healthcare sector is no different. Although it serves the majority of the South African population, most of the financial resources are directed towards the private sector, which serves very few individuals when compared to the public healthcare sector. Apart from that, other challenges that the National Department of Health has to deal with include the lack of sufficiently trained healthcare employees who can work on the different levels of the public healthcare sector, as well as the burden of diseases such as HIV and Aids, tuberculosis and other chronic diseases. In order to improve service delivery, the National Department of Health is introducing Information and Communications Technology interventions that can increase efficiency and reduce costs, thereby improving the quality of service delivery. This research delivers an m-health application user experience framework to be proposed to the National Department of Health in South Africa, in order to assist in scaling up of m-health applications. The m-health applications that can benefit the South African population if scaled up successfully include those that can be used in remote data collection, treatment and compliance, accessing patients records, remote monitoring, communication and training for healthcare workers and applications that can be used for education and awareness. The study focused on three domains: the Human-Computer Interaction domain, public healthcare domain and Health Informatics domain. The proposed framework was realized by investigating mobile user experience components, mobile health requirements and the South African public healthcare domain components that contribute to the m-health user experience framework. This research was conducted through the interpretivist philosophy. Due to the exploratory nature of the study, an application of qualitative methodology was used. The conceptual theoretical framework was validated through a single case study approach by m-health user experience experts, who reside in South Africa. Data were analysed inductively. An m-health user experience framework was provided at the end of the study. An m-health user experience framework can assist the National Department of Health to look into design issues, address m-health requirements and put the domain needs in place, thus enabling the Department to successfully scale up implementations of m-health applications nationwide.
- Full Text:
- Date Issued: 2013
- Authors: Ouma, Stella
- Date: 2013
- Subjects: Communication in public health , Public health -- South Africa , Wireless communication systems in medical care
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:9827 , http://hdl.handle.net/10948/d1020793
- Description: The public healthcare sectors within developing nations face a lot of challenges because of constrained resources available to them. The South African public healthcare sector is no different. Although it serves the majority of the South African population, most of the financial resources are directed towards the private sector, which serves very few individuals when compared to the public healthcare sector. Apart from that, other challenges that the National Department of Health has to deal with include the lack of sufficiently trained healthcare employees who can work on the different levels of the public healthcare sector, as well as the burden of diseases such as HIV and Aids, tuberculosis and other chronic diseases. In order to improve service delivery, the National Department of Health is introducing Information and Communications Technology interventions that can increase efficiency and reduce costs, thereby improving the quality of service delivery. This research delivers an m-health application user experience framework to be proposed to the National Department of Health in South Africa, in order to assist in scaling up of m-health applications. The m-health applications that can benefit the South African population if scaled up successfully include those that can be used in remote data collection, treatment and compliance, accessing patients records, remote monitoring, communication and training for healthcare workers and applications that can be used for education and awareness. The study focused on three domains: the Human-Computer Interaction domain, public healthcare domain and Health Informatics domain. The proposed framework was realized by investigating mobile user experience components, mobile health requirements and the South African public healthcare domain components that contribute to the m-health user experience framework. This research was conducted through the interpretivist philosophy. Due to the exploratory nature of the study, an application of qualitative methodology was used. The conceptual theoretical framework was validated through a single case study approach by m-health user experience experts, who reside in South Africa. Data were analysed inductively. An m-health user experience framework was provided at the end of the study. An m-health user experience framework can assist the National Department of Health to look into design issues, address m-health requirements and put the domain needs in place, thus enabling the Department to successfully scale up implementations of m-health applications nationwide.
- Full Text:
- Date Issued: 2013