Construction of a wide-frequency range double heterodyne conductance bridge and its use in the investigation of polarisation errors in conductance measurements
- Authors: Govinden, Herby Silvester
- Date: 1961
- Subjects: Electrodynamics Electrolytes -- Conductivity
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5522 , http://hdl.handle.net/10962/d1012074
- Description: (1) Developments in a.c. conductance techniques during the past ninety years have been reviewed, and a brief outline is given of the older theories regarding electrolytic polarisation. (2) A conductance bridge - incorporating the double heterodyne principle - has been constructed, capable of giving resistance readings to an accuracy of 0.01% over a range of frequencies covering the best part of 100 kc/s. It has also been found possible to calibrate the oscillator so that frequency settings can be guaranteed to an accuracy of , at least, 0.1% in the range: 2 kc/S to 50 kc/S. (3) The Wheatstone Bridge Network has been slightly modified to enable measurements at the high frequencies. (4) Resistances in the measuring arm of the bridge have been calibrated 'in situ' by the method of intercomparison. (5) A brief description is given of the modern theories regarding electrode processes and modern methods of eliminating electrode effects. (6) Two types of conductance cells, with bright Pt electrodes, have been used to carry out measurements on potassium chloride solutions: (a) Thomas- Gledhill Cell (b) Nichol-Fuoss Cell. The latter incorporates concentric, cylindrical electrodes with the lead to the outer electrode acting as an electrical shield for the lead to the inner electrode. This cell was constructed and used for the first time in this laboratory. (7) From resistance-frequency graphs plotted, it is shown that the Jones and Christian extrapolation procedure cannot be applied (with any degree of confidence) to obtain the true resistance, when measurements are effected over an extended range of frequencies. (8) The method of resistance-reactance diagrams is discussed and applied to various networks of resistances and capacitances. (9) By drawing resistance-reactance diagrams for the experimental readings obtained, equivalent circuits have been derived - for all the solutions investigated in the N-F cell, and for the approx. O.OlD solution in the T-G cell - which approximate to cell behaviour in the range: 500 c/s to 75 kc/s. The less concentrated solutions in the T-G cell show peculiar behaviour at the high frequencies. (10) Probable reasons are advanced for deviations from linearity on resistance-frequency graphs. (11) A new method is proposed for determining the true resistance of solutions measured in cells of the N-F type. Summary, p. 166-167.
- Full Text:
- Date Issued: 1961
- Authors: Govinden, Herby Silvester
- Date: 1961
- Subjects: Electrodynamics Electrolytes -- Conductivity
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5522 , http://hdl.handle.net/10962/d1012074
- Description: (1) Developments in a.c. conductance techniques during the past ninety years have been reviewed, and a brief outline is given of the older theories regarding electrolytic polarisation. (2) A conductance bridge - incorporating the double heterodyne principle - has been constructed, capable of giving resistance readings to an accuracy of 0.01% over a range of frequencies covering the best part of 100 kc/s. It has also been found possible to calibrate the oscillator so that frequency settings can be guaranteed to an accuracy of , at least, 0.1% in the range: 2 kc/S to 50 kc/S. (3) The Wheatstone Bridge Network has been slightly modified to enable measurements at the high frequencies. (4) Resistances in the measuring arm of the bridge have been calibrated 'in situ' by the method of intercomparison. (5) A brief description is given of the modern theories regarding electrode processes and modern methods of eliminating electrode effects. (6) Two types of conductance cells, with bright Pt electrodes, have been used to carry out measurements on potassium chloride solutions: (a) Thomas- Gledhill Cell (b) Nichol-Fuoss Cell. The latter incorporates concentric, cylindrical electrodes with the lead to the outer electrode acting as an electrical shield for the lead to the inner electrode. This cell was constructed and used for the first time in this laboratory. (7) From resistance-frequency graphs plotted, it is shown that the Jones and Christian extrapolation procedure cannot be applied (with any degree of confidence) to obtain the true resistance, when measurements are effected over an extended range of frequencies. (8) The method of resistance-reactance diagrams is discussed and applied to various networks of resistances and capacitances. (9) By drawing resistance-reactance diagrams for the experimental readings obtained, equivalent circuits have been derived - for all the solutions investigated in the N-F cell, and for the approx. O.OlD solution in the T-G cell - which approximate to cell behaviour in the range: 500 c/s to 75 kc/s. The less concentrated solutions in the T-G cell show peculiar behaviour at the high frequencies. (10) Probable reasons are advanced for deviations from linearity on resistance-frequency graphs. (11) A new method is proposed for determining the true resistance of solutions measured in cells of the N-F type. Summary, p. 166-167.
- Full Text:
- Date Issued: 1961
Gold fineness in hydrothermal ores : an investigation into the distribution of gold and silver in Southern Rhodesian gold ores
- Authors: Eales, Hugh V
- Date: 1961
- Subjects: Hydrothermal deposits -- Zimbabwe , Gold ores -- Zimbabwe , Silver ores -- Zimbabwe , Silver mines and mining -- Zimbabwe
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5077 , http://hdl.handle.net/10962/d1014887
- Description: This investigation is concerned with primary variations in the silver content of gold which occurs in hydrothermal deposits, particularly those of hypothermal character which are found in Basement rocks in Southern Rhodesia. The nature of the gold produced by a number of different mines has been studied by reference to production data, and microscope techniques as well as gold and silver assays have been used to determine and to explain the variations in gold fineness. The literature does not contain a great deal of information which is relevant to this topic, but an attempt has been made here to summarize the more important contributions by different writers. From this it emerges that the interpretations given by different investigators are in conflict and that paradoxes may arise when efforts are made to explain observed variations in fineness in terms of certain generalizations which have become entrenched in the literaure. In particular, it is shown that falling temperature alone cannot account for the occurrence of silver-rich gold in certain deposits. The Gwanda district of Southern Rhodesia has been selected as a typical gold belt, and the variation in fineness in 150 producers is described. The deposits are hypothermal in character, and the average fineness of the gold is high but variable, but in a small proportion the fineness is low. It is shown that the nature of the host rock and the distance of a deposit from the granite contact appear to have no influence on the fineness of the gold and that there is no zonal arrangement of fineness values. There is a suggestion that diversity of mineral species in any particular area may be accompanied by rather wide fluctuations in the gold fineness. The variations of fineness in eight typical Southern Rhodesian deposits are studied in detail, by analysis of production data, by assaying specimens of the ore and by the examination of polished specimens of gold-bearing ore. Briefer reference is made to two other deposits in the territory, and to deposits in other countries which appear to bear out the conclusions reached in this section. It emerges that there are two factors which can commonly be correlated with variations in fineness. The first of these is the grade of the ore: high-grade ore generally contains purer gold than low-grade ore. Secondly, the textural evidence indicates that gold which separates relatively early in the paragenesis contains more silver than that which is deposited in the final stages of metallization. A general survey which draws on the literature as well as on the writer's examinations of deposits in the territory indicates that, in general, gold which is associated with late-stage minerals such as tellurides, antimony, bismuth and bismuthinite is silver-poor. Gold associated with galena may be either silver-rich or silver-poor, whereas gold which is of the same age as chalcopyrite or sphalerite is very frequently rich in silver. The difficulty which is encountered in establishing the age of gold which is intimately associated with pyrite and arsenopyrite renders uncertain the correlation between fineness and age of gold in these latter cases. There are, however, indications that gold which is truly contemporaneous with either pyrite or arsenopyrite is silver-rich. In the discussion, the objections to the common practice of singling out temperature as the most potent factor controlling gold fineness are listed. Chief amongst these objections is the fact that gold does not in all deposits increase in fineness with increasing depth: examples are quoted where fineness was found to decrease as deeper levels of the ore body were exploited. It is shown that there is no consistent relationship between the size of gold grains and their silver content. It is the writer's conclusion that in hydrothermal deposits in this territory the high fineness of the gold is due to increasing solubility of silver in the ore fluids in the late states, and that where hydrothermal deposits are characterized by gold with low average fineness, an unusually large proportion of the gold has been deposited early in the paragenotic sequence. In the majority of hypothermal deposits, however, the bulk of tho gold separates late in the sequence and the fineness is accordingly high. It is believed that the relationship which exists between fineness and tenor in many deposits is due to protracted crystallization of gold in those portions of the ore body which remained permeable to the latest stages. These portions of the ore body, which represent either valuable ore shoots or ore shoots in miniature, are likely to contain gold of variable character, but the average silver content will be low because a large proportion of the gold is "late" gold. The factors which might cause epithermal gold to have a lower fineness than mesothermal or hypothermal gold are briefly discussed. Some possible applications of this study are indicated in the final chapter. It is claimed that records of gold fineness might constitute a valuable addition to mill records. Tentative suggestions are made regarding a method whereby the approaching exhaustion of a deposit might in some cases be predicted. With regard to the origin of the gold in the Witwatersrand sediments, it is pointed out that the modified placer hypothesis is not fully equipped to explain certain of the variations in the composition of the gold.
- Full Text:
- Date Issued: 1961
- Authors: Eales, Hugh V
- Date: 1961
- Subjects: Hydrothermal deposits -- Zimbabwe , Gold ores -- Zimbabwe , Silver ores -- Zimbabwe , Silver mines and mining -- Zimbabwe
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5077 , http://hdl.handle.net/10962/d1014887
- Description: This investigation is concerned with primary variations in the silver content of gold which occurs in hydrothermal deposits, particularly those of hypothermal character which are found in Basement rocks in Southern Rhodesia. The nature of the gold produced by a number of different mines has been studied by reference to production data, and microscope techniques as well as gold and silver assays have been used to determine and to explain the variations in gold fineness. The literature does not contain a great deal of information which is relevant to this topic, but an attempt has been made here to summarize the more important contributions by different writers. From this it emerges that the interpretations given by different investigators are in conflict and that paradoxes may arise when efforts are made to explain observed variations in fineness in terms of certain generalizations which have become entrenched in the literaure. In particular, it is shown that falling temperature alone cannot account for the occurrence of silver-rich gold in certain deposits. The Gwanda district of Southern Rhodesia has been selected as a typical gold belt, and the variation in fineness in 150 producers is described. The deposits are hypothermal in character, and the average fineness of the gold is high but variable, but in a small proportion the fineness is low. It is shown that the nature of the host rock and the distance of a deposit from the granite contact appear to have no influence on the fineness of the gold and that there is no zonal arrangement of fineness values. There is a suggestion that diversity of mineral species in any particular area may be accompanied by rather wide fluctuations in the gold fineness. The variations of fineness in eight typical Southern Rhodesian deposits are studied in detail, by analysis of production data, by assaying specimens of the ore and by the examination of polished specimens of gold-bearing ore. Briefer reference is made to two other deposits in the territory, and to deposits in other countries which appear to bear out the conclusions reached in this section. It emerges that there are two factors which can commonly be correlated with variations in fineness. The first of these is the grade of the ore: high-grade ore generally contains purer gold than low-grade ore. Secondly, the textural evidence indicates that gold which separates relatively early in the paragenesis contains more silver than that which is deposited in the final stages of metallization. A general survey which draws on the literature as well as on the writer's examinations of deposits in the territory indicates that, in general, gold which is associated with late-stage minerals such as tellurides, antimony, bismuth and bismuthinite is silver-poor. Gold associated with galena may be either silver-rich or silver-poor, whereas gold which is of the same age as chalcopyrite or sphalerite is very frequently rich in silver. The difficulty which is encountered in establishing the age of gold which is intimately associated with pyrite and arsenopyrite renders uncertain the correlation between fineness and age of gold in these latter cases. There are, however, indications that gold which is truly contemporaneous with either pyrite or arsenopyrite is silver-rich. In the discussion, the objections to the common practice of singling out temperature as the most potent factor controlling gold fineness are listed. Chief amongst these objections is the fact that gold does not in all deposits increase in fineness with increasing depth: examples are quoted where fineness was found to decrease as deeper levels of the ore body were exploited. It is shown that there is no consistent relationship between the size of gold grains and their silver content. It is the writer's conclusion that in hydrothermal deposits in this territory the high fineness of the gold is due to increasing solubility of silver in the ore fluids in the late states, and that where hydrothermal deposits are characterized by gold with low average fineness, an unusually large proportion of the gold has been deposited early in the paragenotic sequence. In the majority of hypothermal deposits, however, the bulk of tho gold separates late in the sequence and the fineness is accordingly high. It is believed that the relationship which exists between fineness and tenor in many deposits is due to protracted crystallization of gold in those portions of the ore body which remained permeable to the latest stages. These portions of the ore body, which represent either valuable ore shoots or ore shoots in miniature, are likely to contain gold of variable character, but the average silver content will be low because a large proportion of the gold is "late" gold. The factors which might cause epithermal gold to have a lower fineness than mesothermal or hypothermal gold are briefly discussed. Some possible applications of this study are indicated in the final chapter. It is claimed that records of gold fineness might constitute a valuable addition to mill records. Tentative suggestions are made regarding a method whereby the approaching exhaustion of a deposit might in some cases be predicted. With regard to the origin of the gold in the Witwatersrand sediments, it is pointed out that the modified placer hypothesis is not fully equipped to explain certain of the variations in the composition of the gold.
- Full Text:
- Date Issued: 1961
Pineapples in the Eastern Cape : a study of the farm economy and marketing patterns
- Authors: Strauss, Conrad B
- Date: 1961
- Subjects: Pineapple industry -- South Africa -- Eastern Cape , Agriculture -- Economic aspects -- South Africa , Farm produce -- Marketing
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1103 , http://hdl.handle.net/10962/d1013318
- Description: The major objective of this study was to seek a better knowledge and greater understanding of the factors associated with successful pineapple farming in the Eastern Cape Region of the Union of South Africa. As no previous · investigation equally representative of commercial pineapple farming patterns in the Eastern Cape has been made, this study can be regarded as a pilot survey of the labour structures, rates of production, combination of enterprises; marketing channels and the suitability of various districts in the region of study for the production of pineapples. In addition, the history of the pineapple in South Africa will be traced briefly, and the position the Union holds as a supplier of pineapples on the world market, will be investigated. the importance of the Eastern Cape as a producer of pineapples in South Africa is well known, but is also unequivocally illustrated by the information in Table 1. According to estimates made by the Division of Economics and Markets for 1955/56 season, no less than 86.5 percent of the total acreage planted to pineapples in South Africa, was located in this area. Bathurst, East London and Albany, three of the six districts included in the estimate, were particularly prominent. Taken together, they cultivated more than three-quarters of the total area planted to pineapples in the Eastern Cape, and nearly 70 per cent of the total for South Africa. The remaining quarter of the area cultivated in the Eastern Cape was located in the districts of Peddie, Komgha and Alexandria.
- Full Text:
- Date Issued: 1961
- Authors: Strauss, Conrad B
- Date: 1961
- Subjects: Pineapple industry -- South Africa -- Eastern Cape , Agriculture -- Economic aspects -- South Africa , Farm produce -- Marketing
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1103 , http://hdl.handle.net/10962/d1013318
- Description: The major objective of this study was to seek a better knowledge and greater understanding of the factors associated with successful pineapple farming in the Eastern Cape Region of the Union of South Africa. As no previous · investigation equally representative of commercial pineapple farming patterns in the Eastern Cape has been made, this study can be regarded as a pilot survey of the labour structures, rates of production, combination of enterprises; marketing channels and the suitability of various districts in the region of study for the production of pineapples. In addition, the history of the pineapple in South Africa will be traced briefly, and the position the Union holds as a supplier of pineapples on the world market, will be investigated. the importance of the Eastern Cape as a producer of pineapples in South Africa is well known, but is also unequivocally illustrated by the information in Table 1. According to estimates made by the Division of Economics and Markets for 1955/56 season, no less than 86.5 percent of the total acreage planted to pineapples in South Africa, was located in this area. Bathurst, East London and Albany, three of the six districts included in the estimate, were particularly prominent. Taken together, they cultivated more than three-quarters of the total area planted to pineapples in the Eastern Cape, and nearly 70 per cent of the total for South Africa. The remaining quarter of the area cultivated in the Eastern Cape was located in the districts of Peddie, Komgha and Alexandria.
- Full Text:
- Date Issued: 1961
The border region : a geographical study of land utilization
- Authors: Board, Christopher
- Date: 1961
- Subjects: Land use -- South Africa -- Cape of Good Hope , Vegetation and climate -- South Africa -- Cape of Good Hope , Geology -- South Africa -- Cape of Good Hope , Cape of Good Hope (South Africa) -- Environmental conditions
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4884 , http://hdl.handle.net/10962/d1013512
- Description: From Summary: This is a geographical study of land use in the Eastern Cape Province. The land use pattern, although related closely to the features of the natural environment, is perhaps even more closely related to the spatial variations of the man-made environment, particularly to the disposition of the different racial groups with their different cultures and economies, and to the kaleidoscopic character of the settlement pattern.
- Full Text:
- Date Issued: 1961
- Authors: Board, Christopher
- Date: 1961
- Subjects: Land use -- South Africa -- Cape of Good Hope , Vegetation and climate -- South Africa -- Cape of Good Hope , Geology -- South Africa -- Cape of Good Hope , Cape of Good Hope (South Africa) -- Environmental conditions
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4884 , http://hdl.handle.net/10962/d1013512
- Description: From Summary: This is a geographical study of land use in the Eastern Cape Province. The land use pattern, although related closely to the features of the natural environment, is perhaps even more closely related to the spatial variations of the man-made environment, particularly to the disposition of the different racial groups with their different cultures and economies, and to the kaleidoscopic character of the settlement pattern.
- Full Text:
- Date Issued: 1961
The geology of the Miami Mica field (Urungwe District)
- Authors: Wiles, J W
- Date: 1961
- Subjects: Geology -- Zimbabwe -- Urungwe District , Mines and mineral resources -- Zimbabwe -- Urungwe District , Mica -- Zimbabwe -- Urungwe District
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5071 , http://hdl.handle.net/10962/d1013503
- Description: [Preface] The detailed geological survey of the country described in this bulletin commenced in 1953 and was completed in 1956 with the mapping of 1,480 square miles of country. Information is supplied on 227 mines which produced mica alone or both mica and beryl, and 134 mines which produced only beryl. In addition, wolfram, gold, graphite, kyanite and rutile deposits and mines are described. Mineral outputs are given up to end of 1959. The field mapping and writing of the bulletin is entirely the work of Mr. Wiles. Mapping of the Field has established that, with a few exceptions, a metamorphic control has operated in the development of economic sheet mica and has led to the conclusion that very many of these pegmatites are composite bodies which have derived their material from two sources: one metamorphic and the other igneous. This conclusion was arrived at after a detailed petrographic investigation of the metamorphic rocks. The map at the end of this bulletin was drawn by Mr.A. H. Barrie and the diagrams are largely the work of Mr. D. O. L. Levy. Chemical analyses are by Messrs. A. J. Radford and E. Golding and were made in the Geological Survey Laboratory. Some of the photographs are by H. J. Cotterel of the Geological Survey while the remainder were taken by the Planning and Technical Services of the Federal Ministry of Home Affairs (formerly the Federal Information Department). It gives me pleasure to acknowledge the assistance and facilities offered the Department by mining men and residents in the district.
- Full Text:
- Date Issued: 1961
- Authors: Wiles, J W
- Date: 1961
- Subjects: Geology -- Zimbabwe -- Urungwe District , Mines and mineral resources -- Zimbabwe -- Urungwe District , Mica -- Zimbabwe -- Urungwe District
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5071 , http://hdl.handle.net/10962/d1013503
- Description: [Preface] The detailed geological survey of the country described in this bulletin commenced in 1953 and was completed in 1956 with the mapping of 1,480 square miles of country. Information is supplied on 227 mines which produced mica alone or both mica and beryl, and 134 mines which produced only beryl. In addition, wolfram, gold, graphite, kyanite and rutile deposits and mines are described. Mineral outputs are given up to end of 1959. The field mapping and writing of the bulletin is entirely the work of Mr. Wiles. Mapping of the Field has established that, with a few exceptions, a metamorphic control has operated in the development of economic sheet mica and has led to the conclusion that very many of these pegmatites are composite bodies which have derived their material from two sources: one metamorphic and the other igneous. This conclusion was arrived at after a detailed petrographic investigation of the metamorphic rocks. The map at the end of this bulletin was drawn by Mr.A. H. Barrie and the diagrams are largely the work of Mr. D. O. L. Levy. Chemical analyses are by Messrs. A. J. Radford and E. Golding and were made in the Geological Survey Laboratory. Some of the photographs are by H. J. Cotterel of the Geological Survey while the remainder were taken by the Planning and Technical Services of the Federal Ministry of Home Affairs (formerly the Federal Information Department). It gives me pleasure to acknowledge the assistance and facilities offered the Department by mining men and residents in the district.
- Full Text:
- Date Issued: 1961
The spectrochemical determination of certain minor trace elements in plant material
- Authors: Eve, Desmond John
- Date: 1961
- Subjects: Trace elements Spectrum analysis Plants -- Analysis Plants -- Effect of trace elements on Trace elements in agriculture
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4469 , http://hdl.handle.net/10962/d1011773
- Description: A study has been made of three organic complexing reagents , namely dithizone, oxine and cupferron with a view to developing suitable methods for the separation and concentration of Zn, Co, Ni, Pb, Cu, Mn, Ti , V and Mo prior to the spectrometric determination of their concentrations. In particular the influence of pH on the chloroform extraction of ditihizonates, oxinates and cupferrates from aqueous tartrate and citrate solutions and the separation of iron by oxine extraction has been investigated. The development of a method for the chemical concentration and spectrcgraphic determination of Zn, Co, Ni, Pb, Ti, V and Mo is described and the possibility of determining Nn and Cu flame photometrically as part of the analysis scheme is demonstrated. A specially designed slide rule for the calculation of spectrographic results is described. A direct reading spectrometric method for the determination of Zn, Pb and Cu in plant material is presented. The analysis of plant ash for zinc using the 2138 . 6A spectrum line has been studied and a simple, rapid analysis method is described.
- Full Text:
- Date Issued: 1961
- Authors: Eve, Desmond John
- Date: 1961
- Subjects: Trace elements Spectrum analysis Plants -- Analysis Plants -- Effect of trace elements on Trace elements in agriculture
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4469 , http://hdl.handle.net/10962/d1011773
- Description: A study has been made of three organic complexing reagents , namely dithizone, oxine and cupferron with a view to developing suitable methods for the separation and concentration of Zn, Co, Ni, Pb, Cu, Mn, Ti , V and Mo prior to the spectrometric determination of their concentrations. In particular the influence of pH on the chloroform extraction of ditihizonates, oxinates and cupferrates from aqueous tartrate and citrate solutions and the separation of iron by oxine extraction has been investigated. The development of a method for the chemical concentration and spectrcgraphic determination of Zn, Co, Ni, Pb, Ti, V and Mo is described and the possibility of determining Nn and Cu flame photometrically as part of the analysis scheme is demonstrated. A specially designed slide rule for the calculation of spectrographic results is described. A direct reading spectrometric method for the determination of Zn, Pb and Cu in plant material is presented. The analysis of plant ash for zinc using the 2138 . 6A spectrum line has been studied and a simple, rapid analysis method is described.
- Full Text:
- Date Issued: 1961
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