Perceptions and use of public green space is influenced by its relative abundance in two small towns in South Africa
- Shackleton, Charlie M, Blair, Andrew
- Authors: Shackleton, Charlie M , Blair, Andrew
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181026 , vital:43688 , xlink:href="https://doi.org/10.1016/j.landurbplan.2013.01.011"
- Description: The challenges in planning and maintaining urban public green spaces in poor towns of the developing world differ markedly from those of the developed world. This paper reports on residents’ perceptions, use and willingness to get involved in urban public green space (PGS) issues in two poor towns in South Africa which differed markedly in the amount of PGS. The disparities in PGS between the two towns were also replicated in different suburbs within the two towns. We hypothesised that levels of dissatisfaction would be highest in those suburbs and the town with the least PGS. The results indicated that the distance from residents’ homesteads to the nearest PGS was similar across towns and suburbs. Most residents felt that having accessible PGS was important, and the majority agreed that there was insufficient PGS in their respective town and suburb, and that the local municipality did not do enough in providing PGS or maintaining what there was. The level of dissatisfaction with the amount and condition of PGS was generally highest in the suburbs and town with the least PGS. Many felt that the municipality had insufficient commitment and funds to adequately maintain PGS, and consequently the willingness of residents to get involved through either a commitment of time or funds was high. The more affluent town and suburbs were willing to pay more than the poorer ones, and the poorer ones were willing to provide more time than the more affluent ones.
- Full Text:
- Date Issued: 2013
- Authors: Shackleton, Charlie M , Blair, Andrew
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181026 , vital:43688 , xlink:href="https://doi.org/10.1016/j.landurbplan.2013.01.011"
- Description: The challenges in planning and maintaining urban public green spaces in poor towns of the developing world differ markedly from those of the developed world. This paper reports on residents’ perceptions, use and willingness to get involved in urban public green space (PGS) issues in two poor towns in South Africa which differed markedly in the amount of PGS. The disparities in PGS between the two towns were also replicated in different suburbs within the two towns. We hypothesised that levels of dissatisfaction would be highest in those suburbs and the town with the least PGS. The results indicated that the distance from residents’ homesteads to the nearest PGS was similar across towns and suburbs. Most residents felt that having accessible PGS was important, and the majority agreed that there was insufficient PGS in their respective town and suburb, and that the local municipality did not do enough in providing PGS or maintaining what there was. The level of dissatisfaction with the amount and condition of PGS was generally highest in the suburbs and town with the least PGS. Many felt that the municipality had insufficient commitment and funds to adequately maintain PGS, and consequently the willingness of residents to get involved through either a commitment of time or funds was high. The more affluent town and suburbs were willing to pay more than the poorer ones, and the poorer ones were willing to provide more time than the more affluent ones.
- Full Text:
- Date Issued: 2013
Perceptions of barriers to women's upward mobility in the Butterworth District Education Department
- Mxunyelwa, Nontsingiselo Victoria
- Authors: Mxunyelwa, Nontsingiselo Victoria
- Date: 2013
- Subjects: Sex discrimination against women -- South Africa -- Gcuwa , Career development -- South Africa -- Gcuwa , Women educators -- South Africa -- Gcuwa
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: vital:8354 , http://hdl.handle.net/10948/d1020910
- Description: The aim of the present study explores barriers to women educators’ upward mobility in the Department of Education, using the Butterworth Education District as the area of study. Women as human beings, too, have a valid case regarding recognition of their legitimate aspirations because in striving for them, they are exercising their rights similar to their male counterpart. It must also be understood that the same legislative prescripts apply to both male and female educators and the necessary intellectual and physical capacity plus skills commitment and perseverance are understood to be important criteria for promotions. The question of perception of barriers to upward mobility of women in the education department and the wider public sector in South Africa is topical and continues to engender research and policy guidelines. However, conclusive findings and solutions are far from being realised. Empirical research and other scholarly writings posit that despite a suite of legislation and policy guidelines introduced in South Africa since 1994, women continue to encounter barriers in their effort to move up their career ladder. It is argued women are under-represented in management positions in comparison to men all over the world. Unequal representation of women in public sectors, nationally, provincially and locally has illustrated the need for gender equity and mainstreaming in senior management. In research done for the Department of Education in South Africa it was also found that although the teaching environment is made up of both men and women, men in management are acceptable, but women in management experience problems not only from male employees, but from female employees as well.
- Full Text:
- Date Issued: 2013
- Authors: Mxunyelwa, Nontsingiselo Victoria
- Date: 2013
- Subjects: Sex discrimination against women -- South Africa -- Gcuwa , Career development -- South Africa -- Gcuwa , Women educators -- South Africa -- Gcuwa
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: vital:8354 , http://hdl.handle.net/10948/d1020910
- Description: The aim of the present study explores barriers to women educators’ upward mobility in the Department of Education, using the Butterworth Education District as the area of study. Women as human beings, too, have a valid case regarding recognition of their legitimate aspirations because in striving for them, they are exercising their rights similar to their male counterpart. It must also be understood that the same legislative prescripts apply to both male and female educators and the necessary intellectual and physical capacity plus skills commitment and perseverance are understood to be important criteria for promotions. The question of perception of barriers to upward mobility of women in the education department and the wider public sector in South Africa is topical and continues to engender research and policy guidelines. However, conclusive findings and solutions are far from being realised. Empirical research and other scholarly writings posit that despite a suite of legislation and policy guidelines introduced in South Africa since 1994, women continue to encounter barriers in their effort to move up their career ladder. It is argued women are under-represented in management positions in comparison to men all over the world. Unequal representation of women in public sectors, nationally, provincially and locally has illustrated the need for gender equity and mainstreaming in senior management. In research done for the Department of Education in South Africa it was also found that although the teaching environment is made up of both men and women, men in management are acceptable, but women in management experience problems not only from male employees, but from female employees as well.
- Full Text:
- Date Issued: 2013
Perceptions of fortune and misfortune in older South African households: social assistance and the ‘Good Life’
- Moller, Valerie, Radloff, Sarah E
- Authors: Moller, Valerie , Radloff, Sarah E
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67165 , vital:29043 , https://doi.org/10.1007/s11205-012-0026-8
- Description: publisher version , It is commonly assumed that better living standards will boost subjective well-being. The post-apartheid South African government subscribes to this idea; its social policies aim to provide ‘a better life for all’. Since the coming of democracy in 1994, the state has built over 3 million houses and supplied electricity and clean water to poor households. By 2009, an estimated 43 % of households were beneficiaries of social grants. The question is whether this investment in services and social assistance translates into higher well-being of citizens. It is argued that older people’s experience of positive change in their life circumstances can be taken as a litmus test of progress in society. The paper reports results of a sample survey conducted in 2009 that inquired into the living circumstances and well-being of 1,000 older low-income households in two provinces linked by a labour migration route. Older households were defined as ones with a member 55 years and older. The sample was drawn among three approximately equal-sized subgroups: Rural black households in the former ‘homelands’ of the Eastern Cape Province, and black and coloured households in Cape Town in the Western Cape Province. The majority of the households in the survey had been interviewed in an earlier survey conducted in late 2002. Both material and non-material changes had occurred in the household situation over the 6-year period between 2002 and 2009. Access to housing and infrastructure had improved but financial difficulties and debts continued to plague many of the surveyed households. Rural black households appeared to be worst off among the three categories of older households with the lowest level of living; coloured households best situated with the highest level of living. Urban black households, many of whom were immigrants to Cape Town, appeared to have experienced the greatest fluctuations in their material circumstances between 2002 and 2009 and a mix of fortune and misfortune. Results indicated that social grants, which provided a modicum of financial security and peace of mind, made the crucial difference between fortune and misfortune for vulnerable households. Securing a social pension and other grants appeared to be the main route to good fortune for the rural households in the study. Households in Cape Town required wage income in addition to grant income to get by in the city. This mix of income sources diluted urban households’ dependence on social assistance. Regression model results suggest that income and financial security play a significantly more important role in boosting the well-being of low-income older households than access to services. Pooling of income, a common practice in pensioner households, contributed significantly to household satisfaction.
- Full Text: false
- Date Issued: 2013
- Authors: Moller, Valerie , Radloff, Sarah E
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67165 , vital:29043 , https://doi.org/10.1007/s11205-012-0026-8
- Description: publisher version , It is commonly assumed that better living standards will boost subjective well-being. The post-apartheid South African government subscribes to this idea; its social policies aim to provide ‘a better life for all’. Since the coming of democracy in 1994, the state has built over 3 million houses and supplied electricity and clean water to poor households. By 2009, an estimated 43 % of households were beneficiaries of social grants. The question is whether this investment in services and social assistance translates into higher well-being of citizens. It is argued that older people’s experience of positive change in their life circumstances can be taken as a litmus test of progress in society. The paper reports results of a sample survey conducted in 2009 that inquired into the living circumstances and well-being of 1,000 older low-income households in two provinces linked by a labour migration route. Older households were defined as ones with a member 55 years and older. The sample was drawn among three approximately equal-sized subgroups: Rural black households in the former ‘homelands’ of the Eastern Cape Province, and black and coloured households in Cape Town in the Western Cape Province. The majority of the households in the survey had been interviewed in an earlier survey conducted in late 2002. Both material and non-material changes had occurred in the household situation over the 6-year period between 2002 and 2009. Access to housing and infrastructure had improved but financial difficulties and debts continued to plague many of the surveyed households. Rural black households appeared to be worst off among the three categories of older households with the lowest level of living; coloured households best situated with the highest level of living. Urban black households, many of whom were immigrants to Cape Town, appeared to have experienced the greatest fluctuations in their material circumstances between 2002 and 2009 and a mix of fortune and misfortune. Results indicated that social grants, which provided a modicum of financial security and peace of mind, made the crucial difference between fortune and misfortune for vulnerable households. Securing a social pension and other grants appeared to be the main route to good fortune for the rural households in the study. Households in Cape Town required wage income in addition to grant income to get by in the city. This mix of income sources diluted urban households’ dependence on social assistance. Regression model results suggest that income and financial security play a significantly more important role in boosting the well-being of low-income older households than access to services. Pooling of income, a common practice in pensioner households, contributed significantly to household satisfaction.
- Full Text: false
- Date Issued: 2013
Perceptions of organisations on how the ward committee impacts on their participation on environmental sustainability in Ward 5 Knysna Municipality
- Authors: Boyce, Marlene
- Date: 2013
- Subjects: Sustainable development -- South Africa -- Knysna , Economic development -- Environmental aspects -- South Africa -- Knysna , Local government -- South Africa -- Knysna
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9199 , http://hdl.handle.net/10948/d1020393
- Description: This guided research report presents the findings of a study on how conservancies perceive the impact of the ward committee on their participation. The research was conducted with the objective of gaining insight into participation in sustainable development in Ward 5 in Knysna Municipality. The study was qualitative and involved a mix of methods including interviews, a survey and documentary review. The analysis shows that the impact of the ward committee on participation is indirect, in that there is a rigid approach to participation by the municipality which focusses only on participation through the ward committees. A change in paradigm that will extend the participation space and accommodate changing media in communication is recommended. The research results will be shared with all the stakeholders in this particular participation relationship, with the view to enhancing participation in sustainable development issues in the ward.
- Full Text:
- Date Issued: 2013
- Authors: Boyce, Marlene
- Date: 2013
- Subjects: Sustainable development -- South Africa -- Knysna , Economic development -- Environmental aspects -- South Africa -- Knysna , Local government -- South Africa -- Knysna
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9199 , http://hdl.handle.net/10948/d1020393
- Description: This guided research report presents the findings of a study on how conservancies perceive the impact of the ward committee on their participation. The research was conducted with the objective of gaining insight into participation in sustainable development in Ward 5 in Knysna Municipality. The study was qualitative and involved a mix of methods including interviews, a survey and documentary review. The analysis shows that the impact of the ward committee on participation is indirect, in that there is a rigid approach to participation by the municipality which focusses only on participation through the ward committees. A change in paradigm that will extend the participation space and accommodate changing media in communication is recommended. The research results will be shared with all the stakeholders in this particular participation relationship, with the view to enhancing participation in sustainable development issues in the ward.
- Full Text:
- Date Issued: 2013
Perceptions of school principals on their role in the implementation of the national school nutrition programme: case of four school principals in the King William’s Town education district
- Authors: Paulos, Sibusiso Big-Boy
- Date: 2013
- Language: English
- Type: Thesis , Masters , M Ed
- Identifier: vital:16207 , http://hdl.handle.net/10353/d1016259
- Description: The purpose of the study was to look at the Perceptions of School Principals on their Role in the Implementation of the National School Nutrition Programme in the King Williams Town Education District. The areas that were deemed to be the most important in this regard were, (i) The role of principals in the implementation of the National School Nutrition Programme. Challenges faced by principals in the implementation of the National School Nutrition Programme. The views of principals on the training received for the implementation of the programme. Assistance provided to schools by the district offices. The study was situated in the interpretive paradigm which seeks to construct detailed descriptions of reality. Qualitative methods were employed for data collection purposes because they allow the use of interviews and document analysis for data collection. This was the most suitable method for the study which seeks to understand the perceptions of principals on their role in the implementation of the National School Nutrition Programme. The study found out that, there were a lot of positives with regard to the implementation of the programme and principals were satisfied with its positive impact on teaching and learning. However, principals raised serious concerns regarding some aspects of the programme such as, lack of infrastructure, budget constraints, lack of capacity of the School Nutrition Committees and food handlers. Also, the study revealed that, there is non-compliance by schools with the 10H00 feeding time, menu guidelines and five day feeding requirement of the programme. Furthermore, the study found out that, lack of training and support from the district offices were other challenges facing the programme. Community involvement was missing and this was having a negative impact on the implementation of the programme. The study recommends that, the department must embark on a mobilization drive to educate communities about the benefits of participating in the programme. It is further recommended that, the department should develop partnerships with other departments such as Social Development and Health, form partnerships with Universities, Non-Governmental Organisations and corporate businesses. This must be done so as to ensure that issues of lack of capacity and budgetary constraints are addressed. Furthermore, the study recommends that, the number of food handlers be increased and the department should ensure that budget allocations to schools are transferred on time. Training and monitoring should be consolidated through employment and training of district officials.
- Full Text:
- Date Issued: 2013
- Authors: Paulos, Sibusiso Big-Boy
- Date: 2013
- Language: English
- Type: Thesis , Masters , M Ed
- Identifier: vital:16207 , http://hdl.handle.net/10353/d1016259
- Description: The purpose of the study was to look at the Perceptions of School Principals on their Role in the Implementation of the National School Nutrition Programme in the King Williams Town Education District. The areas that were deemed to be the most important in this regard were, (i) The role of principals in the implementation of the National School Nutrition Programme. Challenges faced by principals in the implementation of the National School Nutrition Programme. The views of principals on the training received for the implementation of the programme. Assistance provided to schools by the district offices. The study was situated in the interpretive paradigm which seeks to construct detailed descriptions of reality. Qualitative methods were employed for data collection purposes because they allow the use of interviews and document analysis for data collection. This was the most suitable method for the study which seeks to understand the perceptions of principals on their role in the implementation of the National School Nutrition Programme. The study found out that, there were a lot of positives with regard to the implementation of the programme and principals were satisfied with its positive impact on teaching and learning. However, principals raised serious concerns regarding some aspects of the programme such as, lack of infrastructure, budget constraints, lack of capacity of the School Nutrition Committees and food handlers. Also, the study revealed that, there is non-compliance by schools with the 10H00 feeding time, menu guidelines and five day feeding requirement of the programme. Furthermore, the study found out that, lack of training and support from the district offices were other challenges facing the programme. Community involvement was missing and this was having a negative impact on the implementation of the programme. The study recommends that, the department must embark on a mobilization drive to educate communities about the benefits of participating in the programme. It is further recommended that, the department should develop partnerships with other departments such as Social Development and Health, form partnerships with Universities, Non-Governmental Organisations and corporate businesses. This must be done so as to ensure that issues of lack of capacity and budgetary constraints are addressed. Furthermore, the study recommends that, the number of food handlers be increased and the department should ensure that budget allocations to schools are transferred on time. Training and monitoring should be consolidated through employment and training of district officials.
- Full Text:
- Date Issued: 2013
Perceptions of students regarding the information literacy programme: a case study of Walter Sisulu University
- Authors: Badi, Mzwanele
- Date: 2013
- Subjects: Information literacy -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: vital:8311 , http://hdl/handle.net/10948/d1020080
- Description: Information literacy is universally considered one of effective means through which one’s information skills are developed, more especially at higher education Institutions. It has been part of the WSU library’s tradition to promote and offer units of Information Literacy instruction to all students at WSU, although it was initially on ad-hoc bases until 2010 when the Faculty of Education introduced it as a module or a program as a credit-bearing subject to all first year level Bachelor of Education students. The study is intended to understand the perceptions of students that are currently enrolled in Bachelor of Education Degree level one regarding the Information Literacy Program at Walter Sisulu University. The Information Literacy Program is offered in two campuses of WSU, that is Mthatha and Butterworth campuses. This study was conducted using first year level B. Ed students in Butterworth campus only. This may be regarded as a limitation of the study. The study is largely informed by a literature review of scholarly journal articles, books, internet sources and academic libraries in South Africa. The study applied quantitative method using semi-structured questionnaires as the main data gathering instrument. The sample was drawn from 80 first year B Ed students. A total of 80 questionnaires were distributed and 65 were received back. In the study the significant changes in the higher education in the post-apartheid South Africa are discussed. The historical evolution of information literacy as a course in South Africa and internationally is also discussed. The study reveals that information literacy has contributed positively to students’ study approaches. It has helped the students to learn how to apply computing and internet skills to improve on their studies. More importantly, the study reveals that information literacy has helped the students to learn different ways to search for and use information for the purpose of working on their assignments and enhancing their knowledge generally. Furthermore, the study reveals that it has helped the students to know how to tailor their search for information using specific databases such as OPAC, PROQUEST, EBSCOHOST, and SABINET etc.
- Full Text:
- Date Issued: 2013
- Authors: Badi, Mzwanele
- Date: 2013
- Subjects: Information literacy -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: vital:8311 , http://hdl/handle.net/10948/d1020080
- Description: Information literacy is universally considered one of effective means through which one’s information skills are developed, more especially at higher education Institutions. It has been part of the WSU library’s tradition to promote and offer units of Information Literacy instruction to all students at WSU, although it was initially on ad-hoc bases until 2010 when the Faculty of Education introduced it as a module or a program as a credit-bearing subject to all first year level Bachelor of Education students. The study is intended to understand the perceptions of students that are currently enrolled in Bachelor of Education Degree level one regarding the Information Literacy Program at Walter Sisulu University. The Information Literacy Program is offered in two campuses of WSU, that is Mthatha and Butterworth campuses. This study was conducted using first year level B. Ed students in Butterworth campus only. This may be regarded as a limitation of the study. The study is largely informed by a literature review of scholarly journal articles, books, internet sources and academic libraries in South Africa. The study applied quantitative method using semi-structured questionnaires as the main data gathering instrument. The sample was drawn from 80 first year B Ed students. A total of 80 questionnaires were distributed and 65 were received back. In the study the significant changes in the higher education in the post-apartheid South Africa are discussed. The historical evolution of information literacy as a course in South Africa and internationally is also discussed. The study reveals that information literacy has contributed positively to students’ study approaches. It has helped the students to learn how to apply computing and internet skills to improve on their studies. More importantly, the study reveals that information literacy has helped the students to learn different ways to search for and use information for the purpose of working on their assignments and enhancing their knowledge generally. Furthermore, the study reveals that it has helped the students to know how to tailor their search for information using specific databases such as OPAC, PROQUEST, EBSCOHOST, and SABINET etc.
- Full Text:
- Date Issued: 2013
Perceptions of the doctors working in labour wards related to the use of cardiotocograph as an intrapartum monitoring tool
- Authors: Mabenge, Mfundiso Samson
- Date: 2013
- Subjects: Fetal heart rate monitoring , Labor (Obstetrics)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:10061 , http://hdl.handle.net/10948/d1020345
- Description: Monitoring of women in labour is an important aspect of the practice of the health care professionals working in the labour ward. The pregnancy of a woman mightappear to be normal but it is not possible to predict the positive outcome of labour until the baby is born because foetal distress can occur suddenly or other problems can arise during the course of labour. Doctors need to closely monitor the progress of labour of all the women regardless of whether he pregnancy is rated low risk or not. The use of Cardiotocography (CTG) during labour thus becomes critical. In the current study the perceptions of the doctors working in labour ward units will be explored and described in order to recommend activities that could optimize the use of CTG by doctors as an intrapartum monitoring tool. A qualitative research design will be used and the data collection method will be by means of semi-structured audio-taped one-on-one interviews.
- Full Text:
- Date Issued: 2013
- Authors: Mabenge, Mfundiso Samson
- Date: 2013
- Subjects: Fetal heart rate monitoring , Labor (Obstetrics)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:10061 , http://hdl.handle.net/10948/d1020345
- Description: Monitoring of women in labour is an important aspect of the practice of the health care professionals working in the labour ward. The pregnancy of a woman mightappear to be normal but it is not possible to predict the positive outcome of labour until the baby is born because foetal distress can occur suddenly or other problems can arise during the course of labour. Doctors need to closely monitor the progress of labour of all the women regardless of whether he pregnancy is rated low risk or not. The use of Cardiotocography (CTG) during labour thus becomes critical. In the current study the perceptions of the doctors working in labour ward units will be explored and described in order to recommend activities that could optimize the use of CTG by doctors as an intrapartum monitoring tool. A qualitative research design will be used and the data collection method will be by means of semi-structured audio-taped one-on-one interviews.
- Full Text:
- Date Issued: 2013
Perceptions of the Reconstruction and Development Programme (RDP) housing beneficiaries in South Africa on the extent to which the project meet their housing needs: the case of golf course estate in Alice town, Eastern Cape Province
- Authors: Manomano, Tatenda
- Date: 2013
- Subjects: Economic assistance, Domestic -- South Africa -- Eastern Cape , Poverty -- Government policy -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Poverty -- Economic aspects -- South Africa -- Eastern Cape , Alice (South Africa)
- Language: English
- Type: Thesis , Masters , M SW
- Identifier: vital:11765 , http://hdl.handle.net/10353/d1005996 , Economic assistance, Domestic -- South Africa -- Eastern Cape , Poverty -- Government policy -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Poverty -- Economic aspects -- South Africa -- Eastern Cape , Alice (South Africa)
- Description: The aim of this study was to explore the perceptions of RDP beneficiaries on the extent to which the RDP housing project meets their housing needs in South Africa through a case study of Golf Course Estate in Alice Town with the following specific objectives; to assess the extent to which the Alice Golf Course housing project has achieved the RDP programme objectives; to establish beneficiaries‟ perceptions on the extent the RDP Alice Golf Course houses meet their needs; and to explore the level of satisfaction on the RDP houses by beneficiaries. This study utilized triangulation of both quantitative and qualitative methodologies with qualitative as the dominant approach while quantitative was less dominant. The qualitative design took the form of a case study while the quantitative took the form of mini survey. The study sampled 72 participants from the study population. The study utilized an interview guide and a questionnaire as instruments of data collection. The findings indicated that the gender representation of the beneficiaries was skewed. This is because there were more females heading the houses than males; unemployment was also high; most participants were unmarried and most were adults. This study also discovered that most people residing in these houses are not the real owners who were allocated the houses. There were qualitative problems associated with the components of these houses such as poor roofing, doors, windows, floors and walls. Service delivery complaints were based on inadequate access to clean water, small size and spacing of the RDP house. Security was also a challenge because all the houses did not have street lights and the roads were very bad. Though it is commendable that drainage and sewer facilities are available, but they are not serving their purpose since there is no water in these houses. The findings also indicated that there were discrepancies in allocation of the houses; pervasiveness of social ills; inadequate consultative meetings between the RDP Administrator or social worker and the beneficiaries; as well as the pervasiveness of HIV/AIDS among other issues. This researcher recommended that the government needs to promote economic empowerment to deal with unemployment; to improve the quality of the material building the houses; improvement on service delivery gaps; to beef up infrastructure; renovation and revamping of current houses; to establish commissions of inquiry to deal with corruption; to honour and monitor waiting lists. Partnership with other stakeholders was also critical, in addressing access to social services and helps deal with social ills and run behaviour modification campaigns. This researcher also recommended that there is a need to carry out further research on the role played by the municipalities in the RDP housing project as well as conducting a purely qualitative research to further explore the perceptions of other stakeholders, NGOs, traditional leaders, church leaders, and police on the implementation of the housing project. This researcher advises that such a research could be carried out through focus group discussions and also since this study was bound by a case study it is also necessary for similar research to be carried out in different places in South Africa.
- Full Text:
- Date Issued: 2013
- Authors: Manomano, Tatenda
- Date: 2013
- Subjects: Economic assistance, Domestic -- South Africa -- Eastern Cape , Poverty -- Government policy -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Poverty -- Economic aspects -- South Africa -- Eastern Cape , Alice (South Africa)
- Language: English
- Type: Thesis , Masters , M SW
- Identifier: vital:11765 , http://hdl.handle.net/10353/d1005996 , Economic assistance, Domestic -- South Africa -- Eastern Cape , Poverty -- Government policy -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Poverty -- Economic aspects -- South Africa -- Eastern Cape , Alice (South Africa)
- Description: The aim of this study was to explore the perceptions of RDP beneficiaries on the extent to which the RDP housing project meets their housing needs in South Africa through a case study of Golf Course Estate in Alice Town with the following specific objectives; to assess the extent to which the Alice Golf Course housing project has achieved the RDP programme objectives; to establish beneficiaries‟ perceptions on the extent the RDP Alice Golf Course houses meet their needs; and to explore the level of satisfaction on the RDP houses by beneficiaries. This study utilized triangulation of both quantitative and qualitative methodologies with qualitative as the dominant approach while quantitative was less dominant. The qualitative design took the form of a case study while the quantitative took the form of mini survey. The study sampled 72 participants from the study population. The study utilized an interview guide and a questionnaire as instruments of data collection. The findings indicated that the gender representation of the beneficiaries was skewed. This is because there were more females heading the houses than males; unemployment was also high; most participants were unmarried and most were adults. This study also discovered that most people residing in these houses are not the real owners who were allocated the houses. There were qualitative problems associated with the components of these houses such as poor roofing, doors, windows, floors and walls. Service delivery complaints were based on inadequate access to clean water, small size and spacing of the RDP house. Security was also a challenge because all the houses did not have street lights and the roads were very bad. Though it is commendable that drainage and sewer facilities are available, but they are not serving their purpose since there is no water in these houses. The findings also indicated that there were discrepancies in allocation of the houses; pervasiveness of social ills; inadequate consultative meetings between the RDP Administrator or social worker and the beneficiaries; as well as the pervasiveness of HIV/AIDS among other issues. This researcher recommended that the government needs to promote economic empowerment to deal with unemployment; to improve the quality of the material building the houses; improvement on service delivery gaps; to beef up infrastructure; renovation and revamping of current houses; to establish commissions of inquiry to deal with corruption; to honour and monitor waiting lists. Partnership with other stakeholders was also critical, in addressing access to social services and helps deal with social ills and run behaviour modification campaigns. This researcher also recommended that there is a need to carry out further research on the role played by the municipalities in the RDP housing project as well as conducting a purely qualitative research to further explore the perceptions of other stakeholders, NGOs, traditional leaders, church leaders, and police on the implementation of the housing project. This researcher advises that such a research could be carried out through focus group discussions and also since this study was bound by a case study it is also necessary for similar research to be carried out in different places in South Africa.
- Full Text:
- Date Issued: 2013
Perceptions on ante-mortem welfare, quantitation of pain and pregnancy biomarkers, muscular fibre architecture and quality of Dohne Merino offal
- Authors: Fayemi, Peter Olutope
- Date: 2013
- Subjects: Merino sheep , Slaughtering and slaughter-houses -- By-products , Biochemical markers , Meat -- Quality , Consumers' preferences , Cooking (Variety meats) , Livestock -- Transportation
- Language: English
- Type: Thesis , Doctoral , PhD (Animal Science)
- Identifier: vital:11824 , http://hdl.handle.net/10353/d1007573 , Merino sheep , Slaughtering and slaughter-houses -- By-products , Biochemical markers , Meat -- Quality , Consumers' preferences , Cooking (Variety meats) , Livestock -- Transportation
- Description: Sheep farming is practiced extensively in South Africa for its significant contributions to the livestock, wool and meat industries. The sheep farming sector in the country has approximately 13,800 farmers with commercial and communal sheep farmers making up 58 percent and 42 percent of the entire work force (Directorate of Agricultural Information Services, 2008). An estimate of 28.8 million sheep and flock size ranging between ≤ 50 and ≥ 1800 exist in various South African provinces. Although the national herd size is unevenly distributed provincially most of the herds are found in the Eastern Cape (30 percent) followed by the Northern Cape (25 percent), Free State (20 percent) and the Western Cape (11 percent) respectively (Agriculture, Forestry and Fisheries, 2011). Over twenty indigenous and locally developed sheep breeds are managed where about 69 percent of the land area is available for their grazing nation-wide (Campher et al., 1998; Palmer and Ainslie, 2006). Common among the indigenous breeds are the Afrikaner, Blackhead Persian, Blackhead Speckled Persian, Blinkhaar Ronderib, Damara, Karakul, Namaqua Afrikaner, Pedi, Redhead Persian, Redhead Speckled, Swazi and Zulu. The locally developed breeds include Dorper, Van Rooy and Merinos. The local breeds developed from Merinos consist of the Afrino, Dormer, Dohne Merino and South African mutton Merino (Hammond, 2000; Pranisha, 2004; Hinton, 2006; Sorma et al., 2012). All these sheep breeds are best suited for providing by-products such as wool, meat, hide, milk or a combination of products (Dave and Meadowcroft, 1996; Jensen, 2009). The indigenous and locally developed sheep were bred to meet the growing demand for its by-products (Peters et al., 2010). Expectedly, sheep farmers therefore, make use of the products from these sheep as a means of livelihood and sustenance of a viable local society (Cloete and Olivier, 2010).
- Full Text:
- Date Issued: 2013
- Authors: Fayemi, Peter Olutope
- Date: 2013
- Subjects: Merino sheep , Slaughtering and slaughter-houses -- By-products , Biochemical markers , Meat -- Quality , Consumers' preferences , Cooking (Variety meats) , Livestock -- Transportation
- Language: English
- Type: Thesis , Doctoral , PhD (Animal Science)
- Identifier: vital:11824 , http://hdl.handle.net/10353/d1007573 , Merino sheep , Slaughtering and slaughter-houses -- By-products , Biochemical markers , Meat -- Quality , Consumers' preferences , Cooking (Variety meats) , Livestock -- Transportation
- Description: Sheep farming is practiced extensively in South Africa for its significant contributions to the livestock, wool and meat industries. The sheep farming sector in the country has approximately 13,800 farmers with commercial and communal sheep farmers making up 58 percent and 42 percent of the entire work force (Directorate of Agricultural Information Services, 2008). An estimate of 28.8 million sheep and flock size ranging between ≤ 50 and ≥ 1800 exist in various South African provinces. Although the national herd size is unevenly distributed provincially most of the herds are found in the Eastern Cape (30 percent) followed by the Northern Cape (25 percent), Free State (20 percent) and the Western Cape (11 percent) respectively (Agriculture, Forestry and Fisheries, 2011). Over twenty indigenous and locally developed sheep breeds are managed where about 69 percent of the land area is available for their grazing nation-wide (Campher et al., 1998; Palmer and Ainslie, 2006). Common among the indigenous breeds are the Afrikaner, Blackhead Persian, Blackhead Speckled Persian, Blinkhaar Ronderib, Damara, Karakul, Namaqua Afrikaner, Pedi, Redhead Persian, Redhead Speckled, Swazi and Zulu. The locally developed breeds include Dorper, Van Rooy and Merinos. The local breeds developed from Merinos consist of the Afrino, Dormer, Dohne Merino and South African mutton Merino (Hammond, 2000; Pranisha, 2004; Hinton, 2006; Sorma et al., 2012). All these sheep breeds are best suited for providing by-products such as wool, meat, hide, milk or a combination of products (Dave and Meadowcroft, 1996; Jensen, 2009). The indigenous and locally developed sheep were bred to meet the growing demand for its by-products (Peters et al., 2010). Expectedly, sheep farmers therefore, make use of the products from these sheep as a means of livelihood and sustenance of a viable local society (Cloete and Olivier, 2010).
- Full Text:
- Date Issued: 2013
Performance management of veterinarians : a case study of veterinary services in the Eastern Cape
- Authors: Mutero, Gabriel
- Date: 2013
- Subjects: Performance management Veterinarians -- South Africa -- Rating of
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:719 , http://hdl.handle.net/10962/d1001873
- Description: In recent years, challenging economic conditions have stressed organizations, some to breaking point. Rather than waiting for external improvements, such as market growth or technological advances, many organizations are looking internally for performance and productivity gains (Boxall and Purcell, 2003). Consequently, the concept of performance management is receiving increased attention as a route to improved results and organisational growth (Boxall and Purcell, 2003). Likewise, increasing public pressure on governments to improve service delivery and account for the public purse have also forced many governments worldwide to implement a performance management system in one form or another (Ohemeng, 2009; Cameron and Sewell, 2003; Williams, 2005; Sehested, 2008). The South African Public Service has undergone much transformation since 2000. The transformation has been motivated by the Government’s realisation that, as with governments throughout the world, there is a need to modernise and professionalise all spheres of Government. The guiding principles for this transformation are contained in the White Paper on the Transformation of the Public Service (1995) and the Batho Pele White Paper (1997). This has informed the Public Service Act: Act 32 of 2000 of which stipulates that public service organisations should have a performance management system to promote a culture of performance management amongst all staff. The performance management system must ensure that the public service administers its affairs in an economical, effective, efficient and accountable manner. Whereas performance management systems have been in existence in some parts of the world since the early 1970s (Armstrong and Baron, 2005), in the Eastern Cape Provincial Government (ECPG) the Performance Management and Development System (PMDS) can be considered to still be in its infancy stage. It was introduced slightly over a decade ago, with the objective of managing performance in a consultative, supportive and non-discriminatory manner (ECPG, 2001). The PMDS also aims to provide clarity to all employees on their role in the achievement of departmental and provincial goals. This was anticipated to result in enhanced organisational efficiency and effectiveness, accountability for the use of resources and the achievement of results (ECPG, 2001). 4 A literature review contained in this research indicates that internationally and locally, implementing performance management systems is beset with challenges such as conflicting interests between different groups such as professionals wanting autonomy, organisational culture, poor implementation, lack of capacity and resources, lack of institutional and leadership support, changing workplace environments and many others. However it has also been shown that performance management systems are one way of ensuring that employees are focused, goals are met and organisation move forward toward meeting their mission. This research, which has been grounded within a post positivist paradigm, describes the impact of the PMDS on veterinarians in their professional conduct. Semi-structured interviews were conducted with ten veterinarians within the Department, culminating in a total of seven and a half hours of interviewing time. The findings of this study were that the PMDS was minimally effective in achieving organisational goals and mission because of several reasons such as inconsistency in application, perceived unfairness, a lack of ownership of the system amongst workers and management, a lack of involvement, a dichotomy between policy and actual practice, geographical remoteness of subordinates resulting in dilution of information and influence, lack of resources and finally, the type and validity of indicators used. A significant finding was that having a non-veterinarian as a supervisor, impacted negatively on professional conduct. This was perceived to affect planning and goal setting, review and feedback discussions, as well as career advancement. The research ends with recommendations for practice and further research such as exploring management of professionals in multidisciplinary organisations. This research paper is organised and presented in three sections; the first section is in the format of an academic paper, and in addition to a concise review of the literature, will detail the findings, their discussion and conclusion. The second section contains a more expanded literature review of performance management of professionals and the third and last section describes and justifies the design of the study and how it was conducted.
- Full Text:
- Date Issued: 2013
- Authors: Mutero, Gabriel
- Date: 2013
- Subjects: Performance management Veterinarians -- South Africa -- Rating of
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:719 , http://hdl.handle.net/10962/d1001873
- Description: In recent years, challenging economic conditions have stressed organizations, some to breaking point. Rather than waiting for external improvements, such as market growth or technological advances, many organizations are looking internally for performance and productivity gains (Boxall and Purcell, 2003). Consequently, the concept of performance management is receiving increased attention as a route to improved results and organisational growth (Boxall and Purcell, 2003). Likewise, increasing public pressure on governments to improve service delivery and account for the public purse have also forced many governments worldwide to implement a performance management system in one form or another (Ohemeng, 2009; Cameron and Sewell, 2003; Williams, 2005; Sehested, 2008). The South African Public Service has undergone much transformation since 2000. The transformation has been motivated by the Government’s realisation that, as with governments throughout the world, there is a need to modernise and professionalise all spheres of Government. The guiding principles for this transformation are contained in the White Paper on the Transformation of the Public Service (1995) and the Batho Pele White Paper (1997). This has informed the Public Service Act: Act 32 of 2000 of which stipulates that public service organisations should have a performance management system to promote a culture of performance management amongst all staff. The performance management system must ensure that the public service administers its affairs in an economical, effective, efficient and accountable manner. Whereas performance management systems have been in existence in some parts of the world since the early 1970s (Armstrong and Baron, 2005), in the Eastern Cape Provincial Government (ECPG) the Performance Management and Development System (PMDS) can be considered to still be in its infancy stage. It was introduced slightly over a decade ago, with the objective of managing performance in a consultative, supportive and non-discriminatory manner (ECPG, 2001). The PMDS also aims to provide clarity to all employees on their role in the achievement of departmental and provincial goals. This was anticipated to result in enhanced organisational efficiency and effectiveness, accountability for the use of resources and the achievement of results (ECPG, 2001). 4 A literature review contained in this research indicates that internationally and locally, implementing performance management systems is beset with challenges such as conflicting interests between different groups such as professionals wanting autonomy, organisational culture, poor implementation, lack of capacity and resources, lack of institutional and leadership support, changing workplace environments and many others. However it has also been shown that performance management systems are one way of ensuring that employees are focused, goals are met and organisation move forward toward meeting their mission. This research, which has been grounded within a post positivist paradigm, describes the impact of the PMDS on veterinarians in their professional conduct. Semi-structured interviews were conducted with ten veterinarians within the Department, culminating in a total of seven and a half hours of interviewing time. The findings of this study were that the PMDS was minimally effective in achieving organisational goals and mission because of several reasons such as inconsistency in application, perceived unfairness, a lack of ownership of the system amongst workers and management, a lack of involvement, a dichotomy between policy and actual practice, geographical remoteness of subordinates resulting in dilution of information and influence, lack of resources and finally, the type and validity of indicators used. A significant finding was that having a non-veterinarian as a supervisor, impacted negatively on professional conduct. This was perceived to affect planning and goal setting, review and feedback discussions, as well as career advancement. The research ends with recommendations for practice and further research such as exploring management of professionals in multidisciplinary organisations. This research paper is organised and presented in three sections; the first section is in the format of an academic paper, and in addition to a concise review of the literature, will detail the findings, their discussion and conclusion. The second section contains a more expanded literature review of performance management of professionals and the third and last section describes and justifies the design of the study and how it was conducted.
- Full Text:
- Date Issued: 2013
Performance monitoring and evaluation for sustainable low-cost housing delivery: the case of Lukhanji and Malahleni local Municipalities in the Eastern Cape Province South Africa
- Authors: Gomomo, Mzwakhe Gugu
- Date: 2013
- Language: English
- Type: Thesis , Doctoral , PhD (in Public Administration)
- Identifier: vital:11747 , http://hdl.handle.net/10353/d1018529
- Description: One of the serious problems facing South Africa is that of the provision of adequate low-cost housing for the poorest of poor. Only about 56% lived in fully-owned formal dwellings in 2009. (Stats SA: 2009). The problem is not only about the inability of the government to decrease backlogs in the provision of adequate low-cost houses. These contributory factors include the standard of construction, land as well as continuous urbanisation. International commitments such as the UN’s Millennium Goals put further pressure on government to permanently resolve the issue. Adequate housing is recognised globally as a basic human right. This includes access to running water and sanitation and electricity. The aim of the study is not to investigate construction techniques or methods, specific choices of location or any other planning-related issues, but to find an approach that is more appealing to the challenge of the provision of housing as per the afore-mentioned challenges combined with, amongst others, the provision of the necessary resources and relevant political processes as well as monitoring and evaluation. The provision of low-cost housing is unique in nature as it can never be fully resolved. To assist the process because of its nature, future studies suggest systems theory as a best recognised and more successful way to address wicked problems. By investigating low-cost housing programmes in Chile and Australia, identifying the elements of systems theory used, it was possible to find pointers to help formulate a set of steps (or actions) to use to address South Africa’s low-cost housing challenge. This research report proposes that, while the challenge of housing provision in a country like South Africa will most probably always be present, it can be alleviated by applying systems thinking to the problem. The study therefore puts forth Participatory Housing Delivery Monitoring Model (PHDMM). The model will assist in providing the beneficiaries of low-cost houses space to participate in the housing process and projects. It will also necessitate accountability by various participants in housing development. Capacity building will also be part of the package.
- Full Text:
- Date Issued: 2013
- Authors: Gomomo, Mzwakhe Gugu
- Date: 2013
- Language: English
- Type: Thesis , Doctoral , PhD (in Public Administration)
- Identifier: vital:11747 , http://hdl.handle.net/10353/d1018529
- Description: One of the serious problems facing South Africa is that of the provision of adequate low-cost housing for the poorest of poor. Only about 56% lived in fully-owned formal dwellings in 2009. (Stats SA: 2009). The problem is not only about the inability of the government to decrease backlogs in the provision of adequate low-cost houses. These contributory factors include the standard of construction, land as well as continuous urbanisation. International commitments such as the UN’s Millennium Goals put further pressure on government to permanently resolve the issue. Adequate housing is recognised globally as a basic human right. This includes access to running water and sanitation and electricity. The aim of the study is not to investigate construction techniques or methods, specific choices of location or any other planning-related issues, but to find an approach that is more appealing to the challenge of the provision of housing as per the afore-mentioned challenges combined with, amongst others, the provision of the necessary resources and relevant political processes as well as monitoring and evaluation. The provision of low-cost housing is unique in nature as it can never be fully resolved. To assist the process because of its nature, future studies suggest systems theory as a best recognised and more successful way to address wicked problems. By investigating low-cost housing programmes in Chile and Australia, identifying the elements of systems theory used, it was possible to find pointers to help formulate a set of steps (or actions) to use to address South Africa’s low-cost housing challenge. This research report proposes that, while the challenge of housing provision in a country like South Africa will most probably always be present, it can be alleviated by applying systems thinking to the problem. The study therefore puts forth Participatory Housing Delivery Monitoring Model (PHDMM). The model will assist in providing the beneficiaries of low-cost houses space to participate in the housing process and projects. It will also necessitate accountability by various participants in housing development. Capacity building will also be part of the package.
- Full Text:
- Date Issued: 2013
Persistence and virulence of promising entomopathogenic fungal isolates for use in citrus orchards in South Africa
- Coombes, Candice A, Hill, Martin P, Moore, Sean D, Dames, Joanna F, Fullard, T
- Authors: Coombes, Candice A , Hill, Martin P , Moore, Sean D , Dames, Joanna F , Fullard, T
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416893 , vital:71394 , xlink:href="https://doi.org/10.1080/09583157.2013.819489"
- Description: Thaumatotibia leucotreta (Meyrick) (1912) (Lepidoptera: Tortricidae) is a key economic pest of citrus in South Africa. Although a variety of control options are available, none currently registered target the soil-dwelling life stages of the pest. Three fungal isolates, two Metarhizium anisopliae sensu lato Metschnikoff (Sorokin) isolates (G 11 3 L6 and FCM Ar 23 B3) and one Beauveria bassiana sensu lato Balsamo (Vuillemin) isolate (G Ar 17 B3) have been identified as showing the greatest potential against T. leucotreta soil-dwelling life stages. Since environmental persistence is an important factor in the success of entomopathogenic fungi against soil pests, the isolates, along with two commercial isolates (B. bassiana Eco-Bb® and M. anisopliae ICIPE 69), were subjected to a six-month field persistence trial. Every month after burial of the fungal isolates, inside net bags, in orchard soil, the number of colony forming units (CFUs) per gram of soil was measured and the viability of the conidia was assessed using bioassays. All isolates investigated were capable of persisting in the soil for the duration of the trial period and in addition, were capable of initiating infection in T. leucotreta late fifth instar larvae and subsequent pupae. However, with the exception of the commercial isolates which showed some correlation, no correlation was found between the number of CFUs recorded and percentage T. leucotreta mycosis. Persistence of entomopathogenic fungi in the field is affected by a series of factors, and although the effect of these factors was not measured, the data have provided preliminary evidence towards the persistence capability of these candidate biopesticides against T. leucotreta.
- Full Text:
- Date Issued: 2013
- Authors: Coombes, Candice A , Hill, Martin P , Moore, Sean D , Dames, Joanna F , Fullard, T
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416893 , vital:71394 , xlink:href="https://doi.org/10.1080/09583157.2013.819489"
- Description: Thaumatotibia leucotreta (Meyrick) (1912) (Lepidoptera: Tortricidae) is a key economic pest of citrus in South Africa. Although a variety of control options are available, none currently registered target the soil-dwelling life stages of the pest. Three fungal isolates, two Metarhizium anisopliae sensu lato Metschnikoff (Sorokin) isolates (G 11 3 L6 and FCM Ar 23 B3) and one Beauveria bassiana sensu lato Balsamo (Vuillemin) isolate (G Ar 17 B3) have been identified as showing the greatest potential against T. leucotreta soil-dwelling life stages. Since environmental persistence is an important factor in the success of entomopathogenic fungi against soil pests, the isolates, along with two commercial isolates (B. bassiana Eco-Bb® and M. anisopliae ICIPE 69), were subjected to a six-month field persistence trial. Every month after burial of the fungal isolates, inside net bags, in orchard soil, the number of colony forming units (CFUs) per gram of soil was measured and the viability of the conidia was assessed using bioassays. All isolates investigated were capable of persisting in the soil for the duration of the trial period and in addition, were capable of initiating infection in T. leucotreta late fifth instar larvae and subsequent pupae. However, with the exception of the commercial isolates which showed some correlation, no correlation was found between the number of CFUs recorded and percentage T. leucotreta mycosis. Persistence of entomopathogenic fungi in the field is affected by a series of factors, and although the effect of these factors was not measured, the data have provided preliminary evidence towards the persistence capability of these candidate biopesticides against T. leucotreta.
- Full Text:
- Date Issued: 2013
Perspectives of communities on use of alcohol among children in rural areas
- Authors: Noganta, Nandi Manako
- Date: 2013
- Subjects: Children -- Alcohol use -- South Africa -- Eastern Cape , Substance abuse -- South Africa -- Eastern Cape , Rural development -- South Africa -- Eastern Cape , Families -- South Africa -- Eastern Cape , Alcohol use , Community development , Ecosystems approach , Rural areas , Children
- Language: English
- Type: Thesis , Masters , M SW
- Identifier: vital:11760 , http://hdl.handle.net/10353/d1005631 , Children -- Alcohol use -- South Africa -- Eastern Cape , Substance abuse -- South Africa -- Eastern Cape , Rural development -- South Africa -- Eastern Cape , Families -- South Africa -- Eastern Cape , Alcohol use , Community development , Ecosystems approach , Rural areas , Children
- Description: Globalisation raises hopes that communities will become self reliant through development success and thus become an integrated whole (Offiong 2001). But the creation of global village leads to fragmentation of communities, a loss of norms and local values. This study focuses on communities of the Eastern Cape Province, exploring the nature of and extent to which children use alcohol as a consequence of cultural rituals. The researcher aims to develop a culturally sensitive psycho-social approach to address alcohol use among children. The purpose of the research was to investigate the extent to which certain cultural practices contribute towards alcohol use among children in the rural areas of the Eastern Cape Province. Thus exploring the nature and extent to which children use alcohol as a consequence of cultural rituals and to explore whether families and communities are aware of the impact of alcohol use by children in the community. The research was qualitative in nature and through semi-structured interview schedules the researcher was able to gain insight in the area of substance use amongst children in the rural areas of the Eastern Cape Province. Community members, learners from schools, educators and probation officers formed part of the research sample. The research findings suggest that community members are aware that the traditional rituals that are carried out in the rural areas have been contributing to the issue of children using alcohol. However, the community members feel challenged as they become conflicted by their traditional rituals and this impacts upon children using alcohol.
- Full Text:
- Date Issued: 2013
- Authors: Noganta, Nandi Manako
- Date: 2013
- Subjects: Children -- Alcohol use -- South Africa -- Eastern Cape , Substance abuse -- South Africa -- Eastern Cape , Rural development -- South Africa -- Eastern Cape , Families -- South Africa -- Eastern Cape , Alcohol use , Community development , Ecosystems approach , Rural areas , Children
- Language: English
- Type: Thesis , Masters , M SW
- Identifier: vital:11760 , http://hdl.handle.net/10353/d1005631 , Children -- Alcohol use -- South Africa -- Eastern Cape , Substance abuse -- South Africa -- Eastern Cape , Rural development -- South Africa -- Eastern Cape , Families -- South Africa -- Eastern Cape , Alcohol use , Community development , Ecosystems approach , Rural areas , Children
- Description: Globalisation raises hopes that communities will become self reliant through development success and thus become an integrated whole (Offiong 2001). But the creation of global village leads to fragmentation of communities, a loss of norms and local values. This study focuses on communities of the Eastern Cape Province, exploring the nature of and extent to which children use alcohol as a consequence of cultural rituals. The researcher aims to develop a culturally sensitive psycho-social approach to address alcohol use among children. The purpose of the research was to investigate the extent to which certain cultural practices contribute towards alcohol use among children in the rural areas of the Eastern Cape Province. Thus exploring the nature and extent to which children use alcohol as a consequence of cultural rituals and to explore whether families and communities are aware of the impact of alcohol use by children in the community. The research was qualitative in nature and through semi-structured interview schedules the researcher was able to gain insight in the area of substance use amongst children in the rural areas of the Eastern Cape Province. Community members, learners from schools, educators and probation officers formed part of the research sample. The research findings suggest that community members are aware that the traditional rituals that are carried out in the rural areas have been contributing to the issue of children using alcohol. However, the community members feel challenged as they become conflicted by their traditional rituals and this impacts upon children using alcohol.
- Full Text:
- Date Issued: 2013
Petrogenesis and metallogenesis of the Panzhihua Fe-Ti oxide ore-bearing mafic layered intrusion, SW China
- Authors: Howarth, Geoffrey Hamilton
- Date: 2013
- Subjects: Petrogenesis Metallogeny Intrusions (Geology) -- China -- Panzhihua Metallogenic provinces -- China -- Panzhihua Igneous rocks -- China -- Panzhihua Geochemistry Iron Titanium Oxides Ores Magmas
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4915 , http://hdl.handle.net/10962/d1001810
- Description: The Panzhihua intrusion is one of several large Fe-Ti oxide ore bearing intrusions related to the major flood volcanism of the Emeishan Large Igneous Province (ELIP), SW China. The Panzhihua intrusion in particular has recently become the focus of numerous studies owing to the excellent exposure in large open pit mining operations. The formation of Fe-Ti oxide ore layers has been the focus of these studies and has become a somewhat controversial topic with three separate models currently proposed for ore formation. The gabbroic Panzhihua intrusion extends for ± 19 km along strike, has a maximum thickness of 3000 m and hosts extensive (up to 60 m thick) Fe-Ti oxide ore layers in the lower portions of the intrusion. The intrusion has been divided into five zones: marginal zone (MGZ), lower zone (LZ), middle zone A (MZa), middle zone b (MZb) and the upper zone (UZ). The gabbroic rocks are comprised of plagioclase, clinopyroxene and interstitial Fe-Ti oxides with minor olivine. Apatite is present within the MZb only and shows no correlation with Fe-Ti oxide ore layers. Fe-Ti oxides are present throughout the stratigraphy of the intrusion. This is unlike typical layered intrusions where significant Fe-enrichment through fractionation of Fe-poor silicate phases (i.e. plagioclase) is required before Fe-Ti oxide saturation. There are no oxide-free cumulate rocks at the Panzhihua intrusion, implying either an evolved parent magma or very high Fe content of the source rocks. I present here new mineral composition data, whole-rock major and trace element geochemistry along with whole-rock Sr-Nd isotopes and PGEs in order to constrain the evolution of the Panzhihua parent magma en route from source to chamber and the formation of Fe-Ti oxide ore layers. Furthermore an initial pilot study using O-isotope data is conducted on Ti-magnetite and plagioclase separates from gabbroic vs. ore rocks. Results are coupled with detailed thermodynamic modeling using the software PELE in order to further constrain Fe-Ti oxide ore layer formation. The intrusion is characterised by extreme depletion of PGEs relative to the coeval flood basalts and picrites. High Cu/Pd and Pd/Pt imply two separate stages of S-saturated and S-undersaturated depletion of PGEs. Pd is highly compatible in sulphide and is quickly scavenged by sulphide liquids resulting in an increase in Cu/Pd of the residual liquid. Furthermore decoupling of Pd and Pt can be achieved by either late stage hydrothermal alteration or through S-undersaturated stage of PGE depletion where Pt is scavenged by Pt-rich alloys or oxide minerals. I show that the latter is more likely. Fractionation modeling suggests that the Panzhihua parent magma formed at depth from original picritic magma. This is consistent with several other recent studies on other layered intrusions of the ELIP. Sr-Nd isotopic ratios indicate very little crustal contamination has occurred en route to the current chamber. Sr and Nd concentrations of footwall rocks are too low to produce any significant change in initial Sr and Nd isotopic ratios of the intruding basaltic magmas, indicating that crustal contamination will not be indicated by Sr-Nd isotopic ratios. Gradational change in the Sr-Nd isotope ratios across the MGZ provides strong evidence for formation in an open system by multiple replenishments of progressively less contaminated magmas from depth. Contamination is difficult to constrain but must be occurring prior to emplacement at the current level (low Sr and Nd contents of footwall). A gradational upward decrease in highly incompatible element across the MGZ can then be explained by continuous magma flow, which effectively removes the evolved intercumulus liquids from the growing cumulate pile at the base of the chamber. The initial stages of formation of the Panzhihua intrusion are interpreted to result from prolonged low volume pulses of magma into a slowly opening chamber. The timing of Fe-Ti oxide crystallisation is fundamental in the understanding of the petrogenesis of ore layers. Distinct geochemical variation in whole-rock Fe2O3/TiO2 and Zr/Nb indicates that Timagnetite is the dominant oxide within the lower ± 270 m of the intrusion whereas above this level both Ti-magnetite and ilmenite are present as cumulus phases. This is interpreted to indicate a variation in the fO2 where the lower intrusion crystallises at higher fO2 relative to that above this level. Silicates within the ore layers, in particular plagioclase, are highly embayed and resorped where in contact with Fe-Ti oxides. This characteristic of the silicate grains implies early crystallisation prior to Fe-Ti oxides with subsequent disequilibrium conditions resulting in resorption. Furthermore distinct reaction rims of kaersutite amphibole, Fo-enriched olivine, An-enriched plagioclase and pleonaste are observed. The abundance of amphibole suggests H2O involvement in this reaction and consumption of silicates. A model for parent magma crystallisation at various H2O contents indicates that plagioclase crystallisation temperature is very sensitive to H2O content of the parent magma. Plagioclase crystallises early for “dry” compositions but significantly later for “wet” compositions. Fe-Ti oxide ore layers are generally well layered, contain gabbroic xenoliths and are observed raversing/cross-cutting the cumulate stratigraphy. I present here a new model for ore layer formation in order to account for these distinct features of the ore layers. A model invoking multiple replenishments of magma with variable oxide microphenocryst content, H2O content and volume is proposed. Magma evolving in the plumbing system and fed to the Panzhihua chamber is variably enriched in H2O, which results in significantly different crystallisation paths. High H2O magmas (> 2 wt %) crystallise Fe-Ti oxides early whereas low H2O magmas (< 1 wt %) crystallise oxides late. Early pulses of H2O-poor magma crystallise a sequence of plag+cpx+Fe-Ti oxide (±ol). Later pulses of H2Orich magma subsequently intrude the partially crystallised cumulate sequence incorporating and consuming previously crystallised silicates with subsequent early crystallisation of Ti-magnetite and formation of ore layers. H2O-rich magmas likely have suspended Ti-magnetite microphenocrysts as well, which crystallise at depth in the plumbing system. This model can account for the various characteristic features of the Fe-Ti oxide ore layers at the Panzhihua intrusion as well as other Fe-Ti oxide ore bearing intrusions in the region.
- Full Text:
- Date Issued: 2013
- Authors: Howarth, Geoffrey Hamilton
- Date: 2013
- Subjects: Petrogenesis Metallogeny Intrusions (Geology) -- China -- Panzhihua Metallogenic provinces -- China -- Panzhihua Igneous rocks -- China -- Panzhihua Geochemistry Iron Titanium Oxides Ores Magmas
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4915 , http://hdl.handle.net/10962/d1001810
- Description: The Panzhihua intrusion is one of several large Fe-Ti oxide ore bearing intrusions related to the major flood volcanism of the Emeishan Large Igneous Province (ELIP), SW China. The Panzhihua intrusion in particular has recently become the focus of numerous studies owing to the excellent exposure in large open pit mining operations. The formation of Fe-Ti oxide ore layers has been the focus of these studies and has become a somewhat controversial topic with three separate models currently proposed for ore formation. The gabbroic Panzhihua intrusion extends for ± 19 km along strike, has a maximum thickness of 3000 m and hosts extensive (up to 60 m thick) Fe-Ti oxide ore layers in the lower portions of the intrusion. The intrusion has been divided into five zones: marginal zone (MGZ), lower zone (LZ), middle zone A (MZa), middle zone b (MZb) and the upper zone (UZ). The gabbroic rocks are comprised of plagioclase, clinopyroxene and interstitial Fe-Ti oxides with minor olivine. Apatite is present within the MZb only and shows no correlation with Fe-Ti oxide ore layers. Fe-Ti oxides are present throughout the stratigraphy of the intrusion. This is unlike typical layered intrusions where significant Fe-enrichment through fractionation of Fe-poor silicate phases (i.e. plagioclase) is required before Fe-Ti oxide saturation. There are no oxide-free cumulate rocks at the Panzhihua intrusion, implying either an evolved parent magma or very high Fe content of the source rocks. I present here new mineral composition data, whole-rock major and trace element geochemistry along with whole-rock Sr-Nd isotopes and PGEs in order to constrain the evolution of the Panzhihua parent magma en route from source to chamber and the formation of Fe-Ti oxide ore layers. Furthermore an initial pilot study using O-isotope data is conducted on Ti-magnetite and plagioclase separates from gabbroic vs. ore rocks. Results are coupled with detailed thermodynamic modeling using the software PELE in order to further constrain Fe-Ti oxide ore layer formation. The intrusion is characterised by extreme depletion of PGEs relative to the coeval flood basalts and picrites. High Cu/Pd and Pd/Pt imply two separate stages of S-saturated and S-undersaturated depletion of PGEs. Pd is highly compatible in sulphide and is quickly scavenged by sulphide liquids resulting in an increase in Cu/Pd of the residual liquid. Furthermore decoupling of Pd and Pt can be achieved by either late stage hydrothermal alteration or through S-undersaturated stage of PGE depletion where Pt is scavenged by Pt-rich alloys or oxide minerals. I show that the latter is more likely. Fractionation modeling suggests that the Panzhihua parent magma formed at depth from original picritic magma. This is consistent with several other recent studies on other layered intrusions of the ELIP. Sr-Nd isotopic ratios indicate very little crustal contamination has occurred en route to the current chamber. Sr and Nd concentrations of footwall rocks are too low to produce any significant change in initial Sr and Nd isotopic ratios of the intruding basaltic magmas, indicating that crustal contamination will not be indicated by Sr-Nd isotopic ratios. Gradational change in the Sr-Nd isotope ratios across the MGZ provides strong evidence for formation in an open system by multiple replenishments of progressively less contaminated magmas from depth. Contamination is difficult to constrain but must be occurring prior to emplacement at the current level (low Sr and Nd contents of footwall). A gradational upward decrease in highly incompatible element across the MGZ can then be explained by continuous magma flow, which effectively removes the evolved intercumulus liquids from the growing cumulate pile at the base of the chamber. The initial stages of formation of the Panzhihua intrusion are interpreted to result from prolonged low volume pulses of magma into a slowly opening chamber. The timing of Fe-Ti oxide crystallisation is fundamental in the understanding of the petrogenesis of ore layers. Distinct geochemical variation in whole-rock Fe2O3/TiO2 and Zr/Nb indicates that Timagnetite is the dominant oxide within the lower ± 270 m of the intrusion whereas above this level both Ti-magnetite and ilmenite are present as cumulus phases. This is interpreted to indicate a variation in the fO2 where the lower intrusion crystallises at higher fO2 relative to that above this level. Silicates within the ore layers, in particular plagioclase, are highly embayed and resorped where in contact with Fe-Ti oxides. This characteristic of the silicate grains implies early crystallisation prior to Fe-Ti oxides with subsequent disequilibrium conditions resulting in resorption. Furthermore distinct reaction rims of kaersutite amphibole, Fo-enriched olivine, An-enriched plagioclase and pleonaste are observed. The abundance of amphibole suggests H2O involvement in this reaction and consumption of silicates. A model for parent magma crystallisation at various H2O contents indicates that plagioclase crystallisation temperature is very sensitive to H2O content of the parent magma. Plagioclase crystallises early for “dry” compositions but significantly later for “wet” compositions. Fe-Ti oxide ore layers are generally well layered, contain gabbroic xenoliths and are observed raversing/cross-cutting the cumulate stratigraphy. I present here a new model for ore layer formation in order to account for these distinct features of the ore layers. A model invoking multiple replenishments of magma with variable oxide microphenocryst content, H2O content and volume is proposed. Magma evolving in the plumbing system and fed to the Panzhihua chamber is variably enriched in H2O, which results in significantly different crystallisation paths. High H2O magmas (> 2 wt %) crystallise Fe-Ti oxides early whereas low H2O magmas (< 1 wt %) crystallise oxides late. Early pulses of H2O-poor magma crystallise a sequence of plag+cpx+Fe-Ti oxide (±ol). Later pulses of H2Orich magma subsequently intrude the partially crystallised cumulate sequence incorporating and consuming previously crystallised silicates with subsequent early crystallisation of Ti-magnetite and formation of ore layers. H2O-rich magmas likely have suspended Ti-magnetite microphenocrysts as well, which crystallise at depth in the plumbing system. This model can account for the various characteristic features of the Fe-Ti oxide ore layers at the Panzhihua intrusion as well as other Fe-Ti oxide ore bearing intrusions in the region.
- Full Text:
- Date Issued: 2013
Petrogenesis of the Bysteek and Koenap Formation Migmatites, Central Namaqualand
- Authors: Moodley, Jason Anthony
- Date: 2013
- Subjects: Petrogenesis -- South Africa -- Namaqualand Migmatite -- South Africa -- Namaqualand Granulite -- South Africa -- Namaqualand Thermodynamics Geology, Stratigraphic -- Proterozoic Geology, Stratigraphic -- Proterozoic -- South Africa -- Namaqualand
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4914 , http://hdl.handle.net/10962/d1001574
- Description: The Mesoproterozoic rocks of the Bysteek and Koenap Formations of the Arribees Group are exposed within a NW-SE striking antiformal structure comprised of mafic granulites and metapelitic diatexites, and a number of marble and calc-silicate rock layers. The mafic granulites of the Bysteek Formation show a typological variety of anatectic features, including nebulitic, stromatitic mesosomes, melanosomes, quartz syenitic leucocratic vein networks and syenitic pools. Melanosomes consist of hedenbergitic to diopside-rich clinopyroxene (XMg: 0.40), anorthitic plagioclase (An90), with some quartz, minor apatite and titanite. Anatexis was caused by biotite dehydration melting and formed a melt of probably granitic composition. The leucosome composition ranges from either alkali-feldspar-granitic to plagioclase rich or granitic. This variation is interpreted as a result of variable extraction of melt from the source to granitic pools. The diatexites of the Koenap Formation are most likely of metapelitic or meta-greywacke origin. They are texturally variable but always contain high modal contents of alkali feldspar and quartz which generally form magmatic textures. Almandine-rich garnet (XMg: 0.18-0.25), cordierite (XMg: 0.71) form secondary biotite, sillimanite and magnetite during retrograde breakdown. Thermodynamic modelling of mafic granulite compositions suggests peak P-T conditions of ~865 °C and 8.6 kbar. Occasionally, garnet rich in ferric iron (XAdr: 0.55) forms by plagioclase-clinopyroxene breakdown under oxidising conditions at ~6 kilobar and ~ 800 °C. At the same stage amphibole forms in some melanosomes. P-T estimations for the diatexites based on thermodynamic modelling suggest the equilibration of the assemblage garnet, cordierite, alkali feldspar and melt at ~860 °C and 5.5 kbar. Conditions comparable to the peak pressure in the mafic granulites could not be established. However, since the diatexites and the mafic granulites are closely related in the field and no evidence of juxtaposition after the thermal peak exists, the P-T record of the diatexites might be incomplete
- Full Text:
- Date Issued: 2013
- Authors: Moodley, Jason Anthony
- Date: 2013
- Subjects: Petrogenesis -- South Africa -- Namaqualand Migmatite -- South Africa -- Namaqualand Granulite -- South Africa -- Namaqualand Thermodynamics Geology, Stratigraphic -- Proterozoic Geology, Stratigraphic -- Proterozoic -- South Africa -- Namaqualand
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4914 , http://hdl.handle.net/10962/d1001574
- Description: The Mesoproterozoic rocks of the Bysteek and Koenap Formations of the Arribees Group are exposed within a NW-SE striking antiformal structure comprised of mafic granulites and metapelitic diatexites, and a number of marble and calc-silicate rock layers. The mafic granulites of the Bysteek Formation show a typological variety of anatectic features, including nebulitic, stromatitic mesosomes, melanosomes, quartz syenitic leucocratic vein networks and syenitic pools. Melanosomes consist of hedenbergitic to diopside-rich clinopyroxene (XMg: 0.40), anorthitic plagioclase (An90), with some quartz, minor apatite and titanite. Anatexis was caused by biotite dehydration melting and formed a melt of probably granitic composition. The leucosome composition ranges from either alkali-feldspar-granitic to plagioclase rich or granitic. This variation is interpreted as a result of variable extraction of melt from the source to granitic pools. The diatexites of the Koenap Formation are most likely of metapelitic or meta-greywacke origin. They are texturally variable but always contain high modal contents of alkali feldspar and quartz which generally form magmatic textures. Almandine-rich garnet (XMg: 0.18-0.25), cordierite (XMg: 0.71) form secondary biotite, sillimanite and magnetite during retrograde breakdown. Thermodynamic modelling of mafic granulite compositions suggests peak P-T conditions of ~865 °C and 8.6 kbar. Occasionally, garnet rich in ferric iron (XAdr: 0.55) forms by plagioclase-clinopyroxene breakdown under oxidising conditions at ~6 kilobar and ~ 800 °C. At the same stage amphibole forms in some melanosomes. P-T estimations for the diatexites based on thermodynamic modelling suggest the equilibration of the assemblage garnet, cordierite, alkali feldspar and melt at ~860 °C and 5.5 kbar. Conditions comparable to the peak pressure in the mafic granulites could not be established. However, since the diatexites and the mafic granulites are closely related in the field and no evidence of juxtaposition after the thermal peak exists, the P-T record of the diatexites might be incomplete
- Full Text:
- Date Issued: 2013
Photodegradation of Orange-G using zinc octacarboxyphthalocyanine supported on Fe3O4 nanoparticles
- Modisha, Phillimon, Nyokong, Tebello, Antunes, Edith M
- Authors: Modisha, Phillimon , Nyokong, Tebello , Antunes, Edith M
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241653 , vital:50958 , xlink:href="https://doi.org/10.1016/j.molcata.2013.09.030"
- Description: Zinc octacarboxy phthalocyanine (ZnOCPc) was covalently immobilized on the surface of magnetite nanoparticles (MNPs) for the photocatalytic degradation of Orange G (OG) under visible light irradiation. It is noteworthy that the catalyst can be easily recovered using an external magnet and that it is reusable. The ZnOCPc remained bound to the MNP surface even after 25 min of photolysis as confirmed by the FT-IR and X-ray diffraction spectra. Kinetic analysis shows that the photodegradation rates of OG can be approximated to be pseudo-first order, according to the Langmuir–Hinshelwood kinetics model.
- Full Text:
- Date Issued: 2013
- Authors: Modisha, Phillimon , Nyokong, Tebello , Antunes, Edith M
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241653 , vital:50958 , xlink:href="https://doi.org/10.1016/j.molcata.2013.09.030"
- Description: Zinc octacarboxy phthalocyanine (ZnOCPc) was covalently immobilized on the surface of magnetite nanoparticles (MNPs) for the photocatalytic degradation of Orange G (OG) under visible light irradiation. It is noteworthy that the catalyst can be easily recovered using an external magnet and that it is reusable. The ZnOCPc remained bound to the MNP surface even after 25 min of photolysis as confirmed by the FT-IR and X-ray diffraction spectra. Kinetic analysis shows that the photodegradation rates of OG can be approximated to be pseudo-first order, according to the Langmuir–Hinshelwood kinetics model.
- Full Text:
- Date Issued: 2013
Photophysical and photochemical properties of a novel thiol terminated low symmetry zinc phthalocyanine complex and its gold nanoparticles conjugate
- Mthethwa, Thandekile P, Durmus, Mahmut, Nyokong, Tebello
- Authors: Mthethwa, Thandekile P , Durmus, Mahmut , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/231474 , vital:49891 , xlink:href="https://doi.org/10.1039/C3DT32698E"
- Description: A novel thiol functionalized zinc phthalocyanine complex (ZnPcSH) is reported in this work. This complex was conjugated to gold nanoparticles. The photophysical and photochemical properties of the complex and the conjugate were investigated. Upon conjugation a blue shift was observed from the UV-Vis spectra. The conjugate showed a decrease in the fluorescence quantum yield and lifetime. An increase in the triplet quantum yield and lifetime was observed for ZnPcSH following conjugation to gold nanoparticles. Both ZnPcSH and its conjugate with gold nanoparticles showed high singlet oxygen quantum yields with the conjugate being higher than the Pc alone.
- Full Text:
- Date Issued: 2013
- Authors: Mthethwa, Thandekile P , Durmus, Mahmut , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/231474 , vital:49891 , xlink:href="https://doi.org/10.1039/C3DT32698E"
- Description: A novel thiol functionalized zinc phthalocyanine complex (ZnPcSH) is reported in this work. This complex was conjugated to gold nanoparticles. The photophysical and photochemical properties of the complex and the conjugate were investigated. Upon conjugation a blue shift was observed from the UV-Vis spectra. The conjugate showed a decrease in the fluorescence quantum yield and lifetime. An increase in the triplet quantum yield and lifetime was observed for ZnPcSH following conjugation to gold nanoparticles. Both ZnPcSH and its conjugate with gold nanoparticles showed high singlet oxygen quantum yields with the conjugate being higher than the Pc alone.
- Full Text:
- Date Issued: 2013
Photophysical properties of zinc carboxy phthalocyanine-quantum dot conjugates
- Authors: Sekhosana, Kutloano Edward
- Date: 2013 , 2013-03-27
- Subjects: Phthalocyanines , Quantum dots , Zinc , Photochemistry , Atomic force microscopy , Transmission electron microscopy , Raman spectroscopy , Infrared spectroscopy , X-ray photoelectron spectroscopy
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4276 , http://hdl.handle.net/10962/d1001652 , Phthalocyanines , Quantum dots , Zinc , Photochemistry , Atomic force microscopy , Transmission electron microscopy , Raman spectroscopy , Infrared spectroscopy , X-ray photoelectron spectroscopy
- Description: This thesis presents work based on the interactions of water soluble caboxylated zinc phthalocyanines (Pcs) and coreshell quantum dots (QDs). The Pcs are ZnPc(COOH)₈ and ZnPc(COOH)₄ and coreshell QDs are CdTe@ZnS-GSH. GSH = L-glutathione. Characterization and photophysical studies of conjugates were carried out. The approach of coordinating Pcs to QDs was achieved using an organic cross linker, N-N’-dicyclohexylcarbodiimide (DCC) at pH 10 at room temperature. Employing atomic force microscopy (AFM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Raman, infrared and X-ray photoelectron spectroscopies, the formation of the conjugates was confirmed. Upon conjugation with Pc derivatives, the fluorescence quantum yield of CdTe@ZnS-GSH decreased due to energy transfer from the QDs to the Pc. The average fluorescence lifetime of the CdTe@ZnS-GSH QD also decreased upon conjugation. The föster resonance energy transfer (FRET) behaviour of CdTe@ZnS-GSH-ZnPc(COOH)₄ conjugates was compared to that of CdTe@ZnS-GSH-ZnPc(COOH)₈. Higher FRET efficiencies were observed for CdTe@ZnS-GSH-ZnPc(COOH)₄-mixed or CdTe@ZnS-GSH-ZnPc(COOH)₄-linked compared to the corresponding CdTe@ZnS-GSH-ZnPc(COOH)₈-mixed or CdTe@ZnS-GSH-ZnPc(COOH)₈-linked. Triplet quantum yield (ΦT) and lifetime (ΤT) of ZnPc(COOH)₈ were found to increase in the presence of coreshell QDs. Though the singlet quantum yield (ΦΔ) value of ZnPc(COOH)8 was lower than ΦT , there was a slight upsurge in the ΦT in the presence of QDs. , Microsoft� Word 2010 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 2013
- Authors: Sekhosana, Kutloano Edward
- Date: 2013 , 2013-03-27
- Subjects: Phthalocyanines , Quantum dots , Zinc , Photochemistry , Atomic force microscopy , Transmission electron microscopy , Raman spectroscopy , Infrared spectroscopy , X-ray photoelectron spectroscopy
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4276 , http://hdl.handle.net/10962/d1001652 , Phthalocyanines , Quantum dots , Zinc , Photochemistry , Atomic force microscopy , Transmission electron microscopy , Raman spectroscopy , Infrared spectroscopy , X-ray photoelectron spectroscopy
- Description: This thesis presents work based on the interactions of water soluble caboxylated zinc phthalocyanines (Pcs) and coreshell quantum dots (QDs). The Pcs are ZnPc(COOH)₈ and ZnPc(COOH)₄ and coreshell QDs are CdTe@ZnS-GSH. GSH = L-glutathione. Characterization and photophysical studies of conjugates were carried out. The approach of coordinating Pcs to QDs was achieved using an organic cross linker, N-N’-dicyclohexylcarbodiimide (DCC) at pH 10 at room temperature. Employing atomic force microscopy (AFM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Raman, infrared and X-ray photoelectron spectroscopies, the formation of the conjugates was confirmed. Upon conjugation with Pc derivatives, the fluorescence quantum yield of CdTe@ZnS-GSH decreased due to energy transfer from the QDs to the Pc. The average fluorescence lifetime of the CdTe@ZnS-GSH QD also decreased upon conjugation. The föster resonance energy transfer (FRET) behaviour of CdTe@ZnS-GSH-ZnPc(COOH)₄ conjugates was compared to that of CdTe@ZnS-GSH-ZnPc(COOH)₈. Higher FRET efficiencies were observed for CdTe@ZnS-GSH-ZnPc(COOH)₄-mixed or CdTe@ZnS-GSH-ZnPc(COOH)₄-linked compared to the corresponding CdTe@ZnS-GSH-ZnPc(COOH)₈-mixed or CdTe@ZnS-GSH-ZnPc(COOH)₈-linked. Triplet quantum yield (ΦT) and lifetime (ΤT) of ZnPc(COOH)₈ were found to increase in the presence of coreshell QDs. Though the singlet quantum yield (ΦΔ) value of ZnPc(COOH)8 was lower than ΦT , there was a slight upsurge in the ΦT in the presence of QDs. , Microsoft� Word 2010 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 2013
Photophysicochemical and photodynamic antimicrobial chemotherapeutic studies of novel phthalocyanines conjugated to silver nanoparticles
- Authors: Rapulenyane, Nomasonto
- Date: 2013 , 2013-06-10
- Subjects: Phthalocyanines , Photochemistry , Photochemotherapy , Cancer -- Photochemotherapy , Anti-infective agents , Escherichia coli , Nanoparticles , Silver , Zinc
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4291 , http://hdl.handle.net/10962/d1003912 , Phthalocyanines , Photochemistry , Photochemotherapy , Cancer -- Photochemotherapy , Anti-infective agents , Escherichia coli , Nanoparticles , Silver , Zinc
- Description: This work reports on the synthesis, characterization and the physicochemical properties of novel unsymmetrically substituted zinc phthalocyanines: namely tris{11,19, 27-(1,2- diethylaminoethylthiol)-2-(captopril) phthalocyanine Zn ((ZnMCapPc (1.5)), hexakis{8,11,16,19,42,27-(octylthio)-1-(4-phenoxycarboxy) phthalocyanine} Zn (ZnMPCPc(1.7)) and Tris {11, 19, 27-(1,2-diethylaminoethylthiol)-1,2(caffeic acid) phthalocyanine} Zn ((ZnMCafPc (1.3)). Symmetrically substituted counterparts (tetrakis(diethylamino)zinc phthalocyaninato (3.8), octakis(octylthio)zinc phthalocyaninato (3.9) and tetrakis (carboxyphenoxy)zinc phthalocyaninato (3.10) complexes) were also synthesized for comparison of the photophysicochemical properties and to investigate the effect of the substituents on the low symmetry Pcs. The complexes were successfully characterized by IR, NMR, mass spectral and elemental analyses. All the complexes showed the ability to produce singlet oxygen, while the highest triplet quantum yields were obtained for 1.7, 1.5 and 3.9 (0.80, 0.65 and 0.62 respectively and the lowest were obtained for 1.3 and 3.10 (0.57 and 0.47 respectively). High triplet lifetimes (109-286 μs) were also obtained for all complexes, with 1.7 being the highest (286 μs) which also corresponds to its triplet and singlet quantum yields (0.80 and 0.77 respectively). The photosensitizing properties of low symmetry derivatives, ZnMCapPc and ZnMCafPc were investigated by conjugating glutathione (GSH) capped silver nanoparticles (AgNP). The formation of the amide bond was confirmed by IR and UV-Vis spectroscopies. The photophysicochemical behaviour of the novel phthalocyanine-GSH-AgNP conjugates and the simple mixture of the Ag NPs with low the symmetry phthalocyanines were investigated. It was observed that upon conjugation of the phthalocyanines to the GSH-AgNPs, a blue shift in the Q band was induced. The triplet lifetimes and quantum yields improved upon conjugation as compared to the phthalocyanines (Pc) alone. Complex 1.5 triplet lifetimes increased from 109 to 148 and triplet quantum yield from 0.65 to 0.86 upon conjugation. Fluorescence lifetimes and quantum yields decreased for the conjugates compared to the phthalocyanines alone, due to the quenching caused by the Ag NPs. The antimicrobial activity of the zinc phthalocyanines (complexes 1.3 and 1.5) and their conjugates against Escherichia coli was investigated. Only 1.3 and 1.5 complexes were investigated because of the availability of the sample. In general phthalocyanines showed increase in antibacterial activity with the increase in phthalocyanines concentration in the presence and absence of light. The Pc complexes and their Ag NP conjugates showed an increase in antibacterial activity, due to the synergistic effect afforded by Ag NP and Pcs. Improved antibacterial properties were obtained upon irradiation. 1.5-AgNPs had the highest antibacterial activity compared to 1.3-AgNPs conjugate; these results are in agreement with the photophysical behaviour. This work demonstrates improved photophysicochemical properties of low symm
- Full Text:
- Date Issued: 2013
- Authors: Rapulenyane, Nomasonto
- Date: 2013 , 2013-06-10
- Subjects: Phthalocyanines , Photochemistry , Photochemotherapy , Cancer -- Photochemotherapy , Anti-infective agents , Escherichia coli , Nanoparticles , Silver , Zinc
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4291 , http://hdl.handle.net/10962/d1003912 , Phthalocyanines , Photochemistry , Photochemotherapy , Cancer -- Photochemotherapy , Anti-infective agents , Escherichia coli , Nanoparticles , Silver , Zinc
- Description: This work reports on the synthesis, characterization and the physicochemical properties of novel unsymmetrically substituted zinc phthalocyanines: namely tris{11,19, 27-(1,2- diethylaminoethylthiol)-2-(captopril) phthalocyanine Zn ((ZnMCapPc (1.5)), hexakis{8,11,16,19,42,27-(octylthio)-1-(4-phenoxycarboxy) phthalocyanine} Zn (ZnMPCPc(1.7)) and Tris {11, 19, 27-(1,2-diethylaminoethylthiol)-1,2(caffeic acid) phthalocyanine} Zn ((ZnMCafPc (1.3)). Symmetrically substituted counterparts (tetrakis(diethylamino)zinc phthalocyaninato (3.8), octakis(octylthio)zinc phthalocyaninato (3.9) and tetrakis (carboxyphenoxy)zinc phthalocyaninato (3.10) complexes) were also synthesized for comparison of the photophysicochemical properties and to investigate the effect of the substituents on the low symmetry Pcs. The complexes were successfully characterized by IR, NMR, mass spectral and elemental analyses. All the complexes showed the ability to produce singlet oxygen, while the highest triplet quantum yields were obtained for 1.7, 1.5 and 3.9 (0.80, 0.65 and 0.62 respectively and the lowest were obtained for 1.3 and 3.10 (0.57 and 0.47 respectively). High triplet lifetimes (109-286 μs) were also obtained for all complexes, with 1.7 being the highest (286 μs) which also corresponds to its triplet and singlet quantum yields (0.80 and 0.77 respectively). The photosensitizing properties of low symmetry derivatives, ZnMCapPc and ZnMCafPc were investigated by conjugating glutathione (GSH) capped silver nanoparticles (AgNP). The formation of the amide bond was confirmed by IR and UV-Vis spectroscopies. The photophysicochemical behaviour of the novel phthalocyanine-GSH-AgNP conjugates and the simple mixture of the Ag NPs with low the symmetry phthalocyanines were investigated. It was observed that upon conjugation of the phthalocyanines to the GSH-AgNPs, a blue shift in the Q band was induced. The triplet lifetimes and quantum yields improved upon conjugation as compared to the phthalocyanines (Pc) alone. Complex 1.5 triplet lifetimes increased from 109 to 148 and triplet quantum yield from 0.65 to 0.86 upon conjugation. Fluorescence lifetimes and quantum yields decreased for the conjugates compared to the phthalocyanines alone, due to the quenching caused by the Ag NPs. The antimicrobial activity of the zinc phthalocyanines (complexes 1.3 and 1.5) and their conjugates against Escherichia coli was investigated. Only 1.3 and 1.5 complexes were investigated because of the availability of the sample. In general phthalocyanines showed increase in antibacterial activity with the increase in phthalocyanines concentration in the presence and absence of light. The Pc complexes and their Ag NP conjugates showed an increase in antibacterial activity, due to the synergistic effect afforded by Ag NP and Pcs. Improved antibacterial properties were obtained upon irradiation. 1.5-AgNPs had the highest antibacterial activity compared to 1.3-AgNPs conjugate; these results are in agreement with the photophysical behaviour. This work demonstrates improved photophysicochemical properties of low symm
- Full Text:
- Date Issued: 2013
Photophysicochemical properties of aluminium phthalocyanine-platinum conjugates
- Authors: Malinga, Nduduzo Nkanyiso
- Date: 2013 , 2013-04-05
- Subjects: Phthalocyanines , Photochemistry , Photochemotherapy , Aluminium , Platinum , Nanoparticles , Cancer -- Photochemotherapy
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4285 , http://hdl.handle.net/10962/d1002954 , Phthalocyanines , Photochemistry , Photochemotherapy , Aluminium , Platinum , Nanoparticles , Cancer -- Photochemotherapy
- Description: The combination of chemotherapy and photodynamic therapy was investigated by synthesis and characterization of octacarboxy phthalocyanine covalent conjugates with platinum complexes. This work presents the synthesis, characterization and photophysicochemical properties of aluminium (diaquaplatinum) octacarboxyphthalocyanine and aluminium (diammine) octacarboxyphthalocyanine. The conjugates were prepared by conjugating aluminium octacarboxy phthalocyanine with potassium tetrachloro platinate to yield aluminium tetrakis and trikis (diaquaplatinum) octacarboxy phthalocyanine. The aluminium octacarboxy phthalocyanine was also conjugated with cis-diamminedichloroplatinum to yield aluminium bis and tris (diaquaplatinum) octacarboxy phthalocyanine. From the characterization of the conjugates it was discovered that the aluminium (diaquaplatinum) octacarboxy phthalocyanine had formed platinum nanoparticles with the Pc acting as a capping agent. The triplet lifetimes decreased with the increasing number of platinum complexesconjugated to the Pc. The heavy atom effect improved the overall photophysicochemical properties.
- Full Text:
- Date Issued: 2013
- Authors: Malinga, Nduduzo Nkanyiso
- Date: 2013 , 2013-04-05
- Subjects: Phthalocyanines , Photochemistry , Photochemotherapy , Aluminium , Platinum , Nanoparticles , Cancer -- Photochemotherapy
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4285 , http://hdl.handle.net/10962/d1002954 , Phthalocyanines , Photochemistry , Photochemotherapy , Aluminium , Platinum , Nanoparticles , Cancer -- Photochemotherapy
- Description: The combination of chemotherapy and photodynamic therapy was investigated by synthesis and characterization of octacarboxy phthalocyanine covalent conjugates with platinum complexes. This work presents the synthesis, characterization and photophysicochemical properties of aluminium (diaquaplatinum) octacarboxyphthalocyanine and aluminium (diammine) octacarboxyphthalocyanine. The conjugates were prepared by conjugating aluminium octacarboxy phthalocyanine with potassium tetrachloro platinate to yield aluminium tetrakis and trikis (diaquaplatinum) octacarboxy phthalocyanine. The aluminium octacarboxy phthalocyanine was also conjugated with cis-diamminedichloroplatinum to yield aluminium bis and tris (diaquaplatinum) octacarboxy phthalocyanine. From the characterization of the conjugates it was discovered that the aluminium (diaquaplatinum) octacarboxy phthalocyanine had formed platinum nanoparticles with the Pc acting as a capping agent. The triplet lifetimes decreased with the increasing number of platinum complexesconjugated to the Pc. The heavy atom effect improved the overall photophysicochemical properties.
- Full Text:
- Date Issued: 2013