Dose response and kinetic analysis of thermoluminescence of Li–Zn fluoroborate glass
- Thomas, Sunil, Chithambo, Makaiko L
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116164 , vital:34326 , https://doi.org/10.1080/10420150.2017.1313844
- Description: The intention of this study is to explore the thermoluminescence properties of beta-irradiated Li–Zn fluoroborate glass. The glow-curve corresponding to 10 Gy shows two peaks when measured at 1°C/s. The dose response of the glass to beta irradiation was investigated. The trapping level parameters such as activation energy, frequency factor and order of kinetics associated with the observed glow-peak were determined using different methods. The thermoluminescence is affected by thermal quenching. A possible mechanism for the thermoluminescence is described.
- Full Text:
- Date Issued: 2017
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116164 , vital:34326 , https://doi.org/10.1080/10420150.2017.1313844
- Description: The intention of this study is to explore the thermoluminescence properties of beta-irradiated Li–Zn fluoroborate glass. The glow-curve corresponding to 10 Gy shows two peaks when measured at 1°C/s. The dose response of the glass to beta irradiation was investigated. The trapping level parameters such as activation energy, frequency factor and order of kinetics associated with the observed glow-peak were determined using different methods. The thermoluminescence is affected by thermal quenching. A possible mechanism for the thermoluminescence is described.
- Full Text:
- Date Issued: 2017
Kinetic analysis and general features of thermoluminescence of B2O3-Li2O-ZnF2 glass
- Thomas, Sunil, Chithambo, Makaiko L
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116154 , vital:34324 , https://doi.org/10.1016/j.radmeas.2017.03.038
- Description: The intention of this study is to explore the thermoluminescence of beta irradiated B2O3-Li2O-ZnF2 glass. The glow-curve corresponding to 200 Gy shows three peaks; two weak-intensity peaks at 60 and 243 °C and a more prominent one at 118 °C, when measured at 1 °C/s. The dose response of the main peak at 118 °C was found to be sublinear in the range 200–1000 Gy. Regarding the kinetic analysis of the main peak, the activation energy of the corresponding electron trap was evaluated as 0.96 eV and the frequency factor as ∼1011 s−1. It is proposed that the thermoluminescence in B2O3-Li2O-ZnF2 glass is due to recombination of electrons, thermally released from Zn+ ionic defect sites, with the holes at boron-oxygen hole centres.
- Full Text: false
- Date Issued: 2017
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116154 , vital:34324 , https://doi.org/10.1016/j.radmeas.2017.03.038
- Description: The intention of this study is to explore the thermoluminescence of beta irradiated B2O3-Li2O-ZnF2 glass. The glow-curve corresponding to 200 Gy shows three peaks; two weak-intensity peaks at 60 and 243 °C and a more prominent one at 118 °C, when measured at 1 °C/s. The dose response of the main peak at 118 °C was found to be sublinear in the range 200–1000 Gy. Regarding the kinetic analysis of the main peak, the activation energy of the corresponding electron trap was evaluated as 0.96 eV and the frequency factor as ∼1011 s−1. It is proposed that the thermoluminescence in B2O3-Li2O-ZnF2 glass is due to recombination of electrons, thermally released from Zn+ ionic defect sites, with the holes at boron-oxygen hole centres.
- Full Text: false
- Date Issued: 2017
Thermoluminescence of K-Mg-Al-Zn fluorophosphate glass
- Thomas, Sunil, Chithambo, Makaiko L
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124188 , vital:35574 , https://doi.org/10.1016/j.optmat.2016.12.035
- Description: The thermoluminescence of beta irradiated K-Mg-Al-Zn fluorophosphate glass is reported. A glow-curve corresponding to 10 Gy measured at 1 °C/s shows two peaks, a weaker-intensity one at 70 °C and a more prominent one at 235 °C, the subject of this report. The main peak was observed to fade with delay between irradiation and measurement and specifically, by 11% in 15 h. Its dose response is superlinear in the dose range 1–190 Gy although the change was linear for the initial 10 Gy. Regarding kinetic analysis, the activation energy of the higher temperature peak was evaluated as 1.31 eV and that of the lower temperature peak was found as 0.47 eV. It was also noted that the main peak is affected by thermal quenching with an activation energy for thermal quenching equal to 1.37 eV. It is proposed that the mechanism associated with the thermoluminescence in K-Mg-Al-Zn fluorophosphate glass is that electrons trapped by the metal cations are released during heating and then recombine with holes at oxygen sites.
- Full Text: false
- Date Issued: 2017
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124188 , vital:35574 , https://doi.org/10.1016/j.optmat.2016.12.035
- Description: The thermoluminescence of beta irradiated K-Mg-Al-Zn fluorophosphate glass is reported. A glow-curve corresponding to 10 Gy measured at 1 °C/s shows two peaks, a weaker-intensity one at 70 °C and a more prominent one at 235 °C, the subject of this report. The main peak was observed to fade with delay between irradiation and measurement and specifically, by 11% in 15 h. Its dose response is superlinear in the dose range 1–190 Gy although the change was linear for the initial 10 Gy. Regarding kinetic analysis, the activation energy of the higher temperature peak was evaluated as 1.31 eV and that of the lower temperature peak was found as 0.47 eV. It was also noted that the main peak is affected by thermal quenching with an activation energy for thermal quenching equal to 1.37 eV. It is proposed that the mechanism associated with the thermoluminescence in K-Mg-Al-Zn fluorophosphate glass is that electrons trapped by the metal cations are released during heating and then recombine with holes at oxygen sites.
- Full Text: false
- Date Issued: 2017
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