- Title
- Kinetics of the reaction of cyanide with ruthenium phthalocyanine complexes
- Creator
- Nyokong, Tebello
- Creator
- Guthrie-Strachan, Jeffry
- Subject
- To be catalogued
- Date Issued
- 1993
- Date
- 1993
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/295509
- Identifier
- vital:57348
- Identifier
- xlink:href="https://doi.org/10.1016/S0020-1693(00)85128-2"
- Description
- Kinetic studies of the reaction of cyanide with (CO)(DMF)RuPc and (DMSO)2RuPc in DMF are reported. In the presence of a large excess of cyanide, the (CN)2RuPc complex is formed by pseudo first order kinetics. The reaction is first order in both cyanide and phthalocyanine, with specific rate constants of 5.2×10−2 and 7.2×10−2 M−1 s−1 for reactions of cyanide with (CO)(DMF)RuPc and (DMSO)2RuPc, respectively. The rate constants correspond to the coordination of the second cyanide ligand to the ruthenium phthalocyanine species.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (4 pages)
- Format
- Publisher
- Elsevier
- Language
- English
- Relation
- Inorganica Chimica Acta
- Relation
- Nyokong, T. and Guthrie-Strachan, J., 1993. Kinetics of the reaction of cyanide with ruthenium phthalocyanine complexes. Inorganica chimica acta, 208(2), pp.239-242
- Relation
- Inorganica Chimica Acta volume 208 number 2 p. 239 1993 1873-3255
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Kinetics of the reaction of cyanide with ruthenium phthalocyanine complexes.pdf | 669 KB | Adobe Acrobat PDF | View Details Download |