Enhanced upconversion emission of Er3+-Yb3+ co-doped Ba5 (PO4) 3OH powder phosphor for application in photodynamic therapy
- Mokoena, Puseletso P, Poluwole, David O, Nyokong, Tebello, Swart, Hendrik C, Ntwaeaborwa, Odireleng M
- Authors: Mokoena, Puseletso P , Poluwole, David O , Nyokong, Tebello , Swart, Hendrik C , Ntwaeaborwa, Odireleng M
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/185035 , vital:44318 , xlink:href="https://doi.org/10.1016/j.sna.2021.113014"
- Description: Er3+-Yb3+ co-doped Ba5(PO4)3OH nanoparticle powder phosphors were successfully synthesized by urea combustion method. The resulting powder phosphors were characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), high resolution scanning electron microscopy (HRSEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS) and photoluminescence spectroscopy (PL). XRD data confirmed crystallization of pure hexagonal phase of Ba5(PO4)3OH and HRSEM images showed formation of ellipsoidal particles. XPS data combined with EDS analysis confirmed the materials composition that corresponds with identification of all the chemical elements constituting the materials. The in vitro dark cytotoxicity of the particles confirmed lack of cytocidal behaviour in the absence of light, but considerable photodynamic therapy (PDT) activity was observed upon illumination. Upon excitation using a 980 nm laser, multiple emission peaks in the green and red regions corresponding to the optical transitions of Er3+ ion were observed. Upon co-doping with Yb3+, upconverted red emission was detected and this was attributable to non-radiative energy transfer from Yb3+ to Er3+. The proposed mechanism of upconversion photoluminescence is discussed.
- Full Text:
- Date Issued: 2021
- Authors: Mokoena, Puseletso P , Poluwole, David O , Nyokong, Tebello , Swart, Hendrik C , Ntwaeaborwa, Odireleng M
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/185035 , vital:44318 , xlink:href="https://doi.org/10.1016/j.sna.2021.113014"
- Description: Er3+-Yb3+ co-doped Ba5(PO4)3OH nanoparticle powder phosphors were successfully synthesized by urea combustion method. The resulting powder phosphors were characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), high resolution scanning electron microscopy (HRSEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS) and photoluminescence spectroscopy (PL). XRD data confirmed crystallization of pure hexagonal phase of Ba5(PO4)3OH and HRSEM images showed formation of ellipsoidal particles. XPS data combined with EDS analysis confirmed the materials composition that corresponds with identification of all the chemical elements constituting the materials. The in vitro dark cytotoxicity of the particles confirmed lack of cytocidal behaviour in the absence of light, but considerable photodynamic therapy (PDT) activity was observed upon illumination. Upon excitation using a 980 nm laser, multiple emission peaks in the green and red regions corresponding to the optical transitions of Er3+ ion were observed. Upon co-doping with Yb3+, upconverted red emission was detected and this was attributable to non-radiative energy transfer from Yb3+ to Er3+. The proposed mechanism of upconversion photoluminescence is discussed.
- Full Text:
- Date Issued: 2021
The influence of dopants on thermoluminescence of Sr2MgSi2O7
- Thomas, Sunil, Kalita, Jitumani M, Chithambo, Makaiko L, Ntwaeaborwa, Odireleng M
- Authors: Thomas, Sunil , Kalita, Jitumani M , Chithambo, Makaiko L , Ntwaeaborwa, Odireleng M
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/105148 , vital:32469 , https://doi.org/10.1016/j.jlumin.2018.12.035
- Description: We report the influence of dopants on the thermoluminescence of Sr2MgSi2O7. Samples studied comprise undoped Sr2MgSi2O7 and doped versions, namely, Sr2MgSi2O7:Dy3+, Sr2MgSi2O7:Eu3+, Sr2MgSi2O7:Tb3+ and Sr2MgSi2O7:Tb3+,Eu3+ phosphors. All samples show a broad glow peak near 60 °C when measured at 1 °C/s after irradiation to 10 Gy. The peak changes with partial heating, irradiation and fades between irradiation and measurement in a manner expected of a composite one. The behaviour is used to exemplify the analysis of a composite peak on the basis that particular features reflect those of the dominant component.
- Full Text: false
- Date Issued: 2019
- Authors: Thomas, Sunil , Kalita, Jitumani M , Chithambo, Makaiko L , Ntwaeaborwa, Odireleng M
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/105148 , vital:32469 , https://doi.org/10.1016/j.jlumin.2018.12.035
- Description: We report the influence of dopants on the thermoluminescence of Sr2MgSi2O7. Samples studied comprise undoped Sr2MgSi2O7 and doped versions, namely, Sr2MgSi2O7:Dy3+, Sr2MgSi2O7:Eu3+, Sr2MgSi2O7:Tb3+ and Sr2MgSi2O7:Tb3+,Eu3+ phosphors. All samples show a broad glow peak near 60 °C when measured at 1 °C/s after irradiation to 10 Gy. The peak changes with partial heating, irradiation and fades between irradiation and measurement in a manner expected of a composite one. The behaviour is used to exemplify the analysis of a composite peak on the basis that particular features reflect those of the dominant component.
- Full Text: false
- Date Issued: 2019
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