- Title
- The investigation of alternative processes for the oxidation of phenol
- Creator
- Pongoma, Basanda
- Subject
- Phenol
- Subject
- Hydroquinone
- Date Issued
- 2010
- Date
- 2010
- Type
- Thesis
- Type
- Masters
- Type
- MTech
- Identifier
- vital:10381
- Identifier
- http://hdl.handle.net/10948/1479
- Identifier
- Phenol
- Identifier
- Hydroquinone
- Description
- The electrochemical oxidation of phenol can be considered as an important process for either producing value added products such as hydroquinone and catechol or for the removal of the phenol from waste water streams to form carbon dioxide. This process had been extensively studied with the main focus on type of anode material used. Even though the anode material could be made from a range of materials, this study focused on using PbO2 as anode material that was made by using Pb-acid battery principles in designing a microporous electrode. In this study, the focus was on using lead dioxide as an anode material that was made by using the formation principles used in the manufacturing of Pb-acid batteries. This allowed for the construction of an electrochemical flow-through micro-porous reactor that contained PbO2 as the anode and Pb as the cathode, allowing for a solution containing phenol to flow through the cell continuously. By applying a suitable potential across the cell, the almost complete oxidation of phenol would occur to form benzoquinone, which was followed by the sequential reduction to other products such as hydroquinone and catechol. The system was shown to be made up of tightly packed micro-porous material that had a very high surface area-to-volume ratio. The study showed that between 80 to 90 percent successful conversion of a 50 mM solution of phenol could be achieved by optimizing the continuous flow process of up to 500 minutes. The main reaction product from this process was hydroquinone, of up to 60 percent with a number of the minor products of which not all could be identified. In order to utilize the characteristics of this reactor system, its design and reaction conditions such as applied potential, phenol concentration, co-solvent concentration and support electrolyte concentration were investigated to optimize the convection of phenol and the yield of hydroquinone.
- Format
- 101 leaves
- Format
- Publisher
- Nelson Mandela Metropolitan University
- Publisher
- Faculty of Science
- Language
- English
- Rights
- Nelson Mandela Metropolitan University
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