- Title
- Spectroscopic studies of the interaction of cobalt (II) N, N', N ″, N‴-tetramethyltetra-3, 4-pyridinoporphyrazine with amino acids and nitrogen oxides
- Creator
- Thamae, Mamothibe A
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 2001
- Date
- 2001
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/291617
- Identifier
- vital:56892
- Identifier
- xlink:href="https://doi.org/10.1002/jpp.551"
- Description
- The interaction of histidine, cysteine, NO and nitrite with cobalt(II) N,N',N″,N‴-tetramethyltetra-3,4-tetrapyridinoporphyrazine ([CoIItmtppa]4+) is reported. Metal-based autoreduction of [CoIItmtppa]4+ occurs with the formation of the [CoItmtppa(-2)]3+ species in the presence of histidine and cysteine. Kinetic data for the auto reduction of [CoIItmtppa]4+ in the presence of these amino acids gave the rate constants kf = 2.1 × 101 and 2.8 dm3 mol-1 s-1, for cysteine and histidine, respectively. One molecule of NO or nitrite was found to coordinate to the [CoIItmtppa]4+ species. The equilibrium and rate constants for the coordination of the nitric oxide were K = 2.3 × 104dm3mol-1 and kf = 7.5 dm3mol-1s-1, respectively. The coordination of nitrite to [CoIItmtppa]4+ occurred with an equilibrium constant of K = 2.0 × 102dm3mol-1 and a rate constant of kf = 4.0 × 10-3dm3mol-1s-1. There was no evidence for the coordination of two molecules of nitrite to the [CoIItmtppa]4+ species.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (8 pages)
- Format
- Publisher
- World Scientific Publishing
- Language
- English
- Relation
- Journal of Porphyrins and Phthalocyanines
- Relation
- Thamae, M.A. and Nyokong, T., 2001. Spectroscopic studies of the interaction of cobalt (II) N, N', N ″, N‴-tetramethyltetra-3, 4-pyridinoporphyrazine with amino acids and nitrogen oxides. Journal of Porphyrins and Phthalocyanines, 5(12), pp.839-845
- Relation
- Journal of Porphyrins and Phthalocyanines volume 5 number 12 p. 839 2001 1099-1409
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the World Scientific Copyright and Permissions Statement (https://0-www.worldscientific.com.wam.seals.ac.za/page/permissions)
- Rights
- Closed Access
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Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
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