The influence of dopants on thermoluminescence of Sr2MgSi2O7
- Thomas, Sunil, Kalita, Jitumani M, Chithambo, Makaiko L, Ntwaeaborwa, Odireleng M
- Authors: Thomas, Sunil , Kalita, Jitumani M , Chithambo, Makaiko L , Ntwaeaborwa, Odireleng M
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/105148 , vital:32469 , https://doi.org/10.1016/j.jlumin.2018.12.035
- Description: We report the influence of dopants on the thermoluminescence of Sr2MgSi2O7. Samples studied comprise undoped Sr2MgSi2O7 and doped versions, namely, Sr2MgSi2O7:Dy3+, Sr2MgSi2O7:Eu3+, Sr2MgSi2O7:Tb3+ and Sr2MgSi2O7:Tb3+,Eu3+ phosphors. All samples show a broad glow peak near 60 °C when measured at 1 °C/s after irradiation to 10 Gy. The peak changes with partial heating, irradiation and fades between irradiation and measurement in a manner expected of a composite one. The behaviour is used to exemplify the analysis of a composite peak on the basis that particular features reflect those of the dominant component.
- Full Text: false
- Date Issued: 2019
- Authors: Thomas, Sunil , Kalita, Jitumani M , Chithambo, Makaiko L , Ntwaeaborwa, Odireleng M
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/105148 , vital:32469 , https://doi.org/10.1016/j.jlumin.2018.12.035
- Description: We report the influence of dopants on the thermoluminescence of Sr2MgSi2O7. Samples studied comprise undoped Sr2MgSi2O7 and doped versions, namely, Sr2MgSi2O7:Dy3+, Sr2MgSi2O7:Eu3+, Sr2MgSi2O7:Tb3+ and Sr2MgSi2O7:Tb3+,Eu3+ phosphors. All samples show a broad glow peak near 60 °C when measured at 1 °C/s after irradiation to 10 Gy. The peak changes with partial heating, irradiation and fades between irradiation and measurement in a manner expected of a composite one. The behaviour is used to exemplify the analysis of a composite peak on the basis that particular features reflect those of the dominant component.
- Full Text: false
- Date Issued: 2019
Thermally and optically stimulated luminescence of natural red and blue corundum (Al2O3)
- Kalita, Jitumani M, Thomas, Sunil, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Thomas, Sunil , Chithambo, Makaiko L
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/105177 , vital:32472 , https://doi.org/10.1016/j.jlumin.2018.09.058
- Description: We report the thermoluminescence (TL) and optically stimulated luminescence (OSL) of natural corundum (Al2O3) of two varieties; one red and the other blue. X-ray fluorescence spectroscopy of the samples show that the concentration of Al2O3 in the red corundum is 43.05% and 46.87% in the blue corundum. TL measurements carried out on un-annealed samples and samples annealed at 700 °C, 900 °C and 1200 °C show that the TL sensitivity increases with annealing. The sensitivity of the red corundum reaches a maximum after annealing at 900 °C whereas that of the blue corundum increases with annealing up to the maximum annealing temperature of 1200 °C used in this study. Both samples have a complex glow curve between 30 °C and 500 °C. The composite nature of the glow curves is deduced to be due to a continuum in the trap distribution in the crystal. The activation energy of the traps vary between 0.70 eV and 1.15 eV. The dose response of the red corundum under TL is linear within 100‒1000 Gy whereas that of the blue corundum is superlinear for the same dose range. The TL of both samples is reproducible but the signal fades with time between irradiation and measurement. Both samples produce OSL under 470 nm blue light stimulation. The dose response of the OSL is superlinear within 100‒1000 Gy. It is found that the samples also produce thermally-assisted OSL (TA-OSL) at elevated temperature. The TA-OSL intensity of the red corundum increases with dose up to 400 Gy and saturates thereafter. On the other hand, the intensity of the blue corundum increases consistently with dose from 100 Gy to 1000 Gy.
- Full Text: false
- Date Issued: 2019
- Authors: Kalita, Jitumani M , Thomas, Sunil , Chithambo, Makaiko L
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/105177 , vital:32472 , https://doi.org/10.1016/j.jlumin.2018.09.058
- Description: We report the thermoluminescence (TL) and optically stimulated luminescence (OSL) of natural corundum (Al2O3) of two varieties; one red and the other blue. X-ray fluorescence spectroscopy of the samples show that the concentration of Al2O3 in the red corundum is 43.05% and 46.87% in the blue corundum. TL measurements carried out on un-annealed samples and samples annealed at 700 °C, 900 °C and 1200 °C show that the TL sensitivity increases with annealing. The sensitivity of the red corundum reaches a maximum after annealing at 900 °C whereas that of the blue corundum increases with annealing up to the maximum annealing temperature of 1200 °C used in this study. Both samples have a complex glow curve between 30 °C and 500 °C. The composite nature of the glow curves is deduced to be due to a continuum in the trap distribution in the crystal. The activation energy of the traps vary between 0.70 eV and 1.15 eV. The dose response of the red corundum under TL is linear within 100‒1000 Gy whereas that of the blue corundum is superlinear for the same dose range. The TL of both samples is reproducible but the signal fades with time between irradiation and measurement. Both samples produce OSL under 470 nm blue light stimulation. The dose response of the OSL is superlinear within 100‒1000 Gy. It is found that the samples also produce thermally-assisted OSL (TA-OSL) at elevated temperature. The TA-OSL intensity of the red corundum increases with dose up to 400 Gy and saturates thereafter. On the other hand, the intensity of the blue corundum increases consistently with dose from 100 Gy to 1000 Gy.
- Full Text: false
- Date Issued: 2019
A study of the kinetics of a high temperature thermoluminescence peak in annealed natural quartz
- Thomas, Sunil, Chithambo, Makaiko L
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/110007 , vital:33213 , DOI: 10.1016/j.jlumin.2018.08.077
- Description: Thermoluminescence of a high temperature secondary glow-peak in natural quartz annealed at 900 °C is reported. The glow-curve of a sample irradiated to 10 Gy and measured at 1 °C/s shows three peaks; the main peak at 71 °C and two other weaker-intensity peaks at 125 °C and 177 °C. For reference, the peaks are labelled as I, II and III. This study is concerned with the secondary peak at 177 °C (peak III). The electron trap responsible for peak III is stable at ambient temperature as determined by monitoring the peak intensity after various delays between irradiation and measurement. The activation energy and frequency factor of the peak were estimated as ~1.24 eV and ~10¹² s⁻¹ respectively. The dose response of the peak in the range 1–300 Gy is sublinear. The influence of either partial heating or irradiation dose on the peak position suggest that the peak follows non-first-order kinetics.
- Full Text: false
- Date Issued: 2018
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/110007 , vital:33213 , DOI: 10.1016/j.jlumin.2018.08.077
- Description: Thermoluminescence of a high temperature secondary glow-peak in natural quartz annealed at 900 °C is reported. The glow-curve of a sample irradiated to 10 Gy and measured at 1 °C/s shows three peaks; the main peak at 71 °C and two other weaker-intensity peaks at 125 °C and 177 °C. For reference, the peaks are labelled as I, II and III. This study is concerned with the secondary peak at 177 °C (peak III). The electron trap responsible for peak III is stable at ambient temperature as determined by monitoring the peak intensity after various delays between irradiation and measurement. The activation energy and frequency factor of the peak were estimated as ~1.24 eV and ~10¹² s⁻¹ respectively. The dose response of the peak in the range 1–300 Gy is sublinear. The influence of either partial heating or irradiation dose on the peak position suggest that the peak follows non-first-order kinetics.
- Full Text: false
- Date Issued: 2018
Characteristics of the thermoluminescence of Sm3+-doped P2O5-K2O-MgO-Al2O3-ZnF2 glass
- Thomas, Sunil, Chithambo, Makaiko L
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/109979 , vital:33211 , https://doi.org/10.1016/j.radmeas.2018.06.005
- Description: We report the thermoluminescence of Sm3+-doped P2O5-K2O-MgO-Al2O3-ZnF2 glass. A glow-curve measured at 1 °C/s after beta irradiation to 10 Gy shows two peaks; a broad high intensity one at 214.0 ± 0.4 °C and a weaker intensity peak at 75.2 ± 0.8 °C. The dependence of peak position on partial heating as well as on irradiation suggest that the main peak at 214 °C is a combination of several overlapping peaks. The activation energy of the different components of the main peak, calculated using the initial-rise method, differ showing that the components are distinct. The reproducibility, fading and dose response were examined by considering the dominant component of the main peak. The intensity of the peak changes with heating rate in a manner consistent with thermal quenching.
- Full Text: false
- Date Issued: 2018
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/109979 , vital:33211 , https://doi.org/10.1016/j.radmeas.2018.06.005
- Description: We report the thermoluminescence of Sm3+-doped P2O5-K2O-MgO-Al2O3-ZnF2 glass. A glow-curve measured at 1 °C/s after beta irradiation to 10 Gy shows two peaks; a broad high intensity one at 214.0 ± 0.4 °C and a weaker intensity peak at 75.2 ± 0.8 °C. The dependence of peak position on partial heating as well as on irradiation suggest that the main peak at 214 °C is a combination of several overlapping peaks. The activation energy of the different components of the main peak, calculated using the initial-rise method, differ showing that the components are distinct. The reproducibility, fading and dose response were examined by considering the dominant component of the main peak. The intensity of the peak changes with heating rate in a manner consistent with thermal quenching.
- Full Text: false
- Date Issued: 2018
General features and kinetic analysis of thermoluminescence from annealed natural quartz
- Thomas, Sunil, Chithambo, Makaiko L
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/112885 , vital:33670 , https://doi.org/10.1016/j.jlumin.2018.02.003
- Description: The aim of this study is to explore the thermoluminescence properties of beta irradiated natural quartz annealed at 900 °C, that is, beyond its second phase inversion temperature of 867 °C. The sample was annealed to improve its sensitivity and to deplete any residual charge from electron traps. The glow-curve corresponding to 10 Gy shows three peaks when measured at 1 °C/s; a dominant one at 71 °C, the subject of this report, and two other ones at 125 and 177 °C. The dose response of the main peak was studied in the range 1–300 Gy. The activation energy of the main glow-peak was evaluated as ~1 eV. Kinetic analyses using various methods show that the main glow-peak follows first order kinetics.
- Full Text: false
- Date Issued: 2018
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/112885 , vital:33670 , https://doi.org/10.1016/j.jlumin.2018.02.003
- Description: The aim of this study is to explore the thermoluminescence properties of beta irradiated natural quartz annealed at 900 °C, that is, beyond its second phase inversion temperature of 867 °C. The sample was annealed to improve its sensitivity and to deplete any residual charge from electron traps. The glow-curve corresponding to 10 Gy shows three peaks when measured at 1 °C/s; a dominant one at 71 °C, the subject of this report, and two other ones at 125 and 177 °C. The dose response of the main peak was studied in the range 1–300 Gy. The activation energy of the main glow-peak was evaluated as ~1 eV. Kinetic analyses using various methods show that the main glow-peak follows first order kinetics.
- Full Text: false
- Date Issued: 2018
Dose response and kinetic analysis of thermoluminescence of Li–Zn fluoroborate glass
- Thomas, Sunil, Chithambo, Makaiko L
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116164 , vital:34326 , https://doi.org/10.1080/10420150.2017.1313844
- Description: The intention of this study is to explore the thermoluminescence properties of beta-irradiated Li–Zn fluoroborate glass. The glow-curve corresponding to 10 Gy shows two peaks when measured at 1°C/s. The dose response of the glass to beta irradiation was investigated. The trapping level parameters such as activation energy, frequency factor and order of kinetics associated with the observed glow-peak were determined using different methods. The thermoluminescence is affected by thermal quenching. A possible mechanism for the thermoluminescence is described.
- Full Text:
- Date Issued: 2017
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116164 , vital:34326 , https://doi.org/10.1080/10420150.2017.1313844
- Description: The intention of this study is to explore the thermoluminescence properties of beta-irradiated Li–Zn fluoroborate glass. The glow-curve corresponding to 10 Gy shows two peaks when measured at 1°C/s. The dose response of the glass to beta irradiation was investigated. The trapping level parameters such as activation energy, frequency factor and order of kinetics associated with the observed glow-peak were determined using different methods. The thermoluminescence is affected by thermal quenching. A possible mechanism for the thermoluminescence is described.
- Full Text:
- Date Issued: 2017
Kinetic analysis and general features of thermoluminescence of B2O3-Li2O-ZnF2 glass
- Thomas, Sunil, Chithambo, Makaiko L
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116154 , vital:34324 , https://doi.org/10.1016/j.radmeas.2017.03.038
- Description: The intention of this study is to explore the thermoluminescence of beta irradiated B2O3-Li2O-ZnF2 glass. The glow-curve corresponding to 200 Gy shows three peaks; two weak-intensity peaks at 60 and 243 °C and a more prominent one at 118 °C, when measured at 1 °C/s. The dose response of the main peak at 118 °C was found to be sublinear in the range 200–1000 Gy. Regarding the kinetic analysis of the main peak, the activation energy of the corresponding electron trap was evaluated as 0.96 eV and the frequency factor as ∼1011 s−1. It is proposed that the thermoluminescence in B2O3-Li2O-ZnF2 glass is due to recombination of electrons, thermally released from Zn+ ionic defect sites, with the holes at boron-oxygen hole centres.
- Full Text: false
- Date Issued: 2017
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116154 , vital:34324 , https://doi.org/10.1016/j.radmeas.2017.03.038
- Description: The intention of this study is to explore the thermoluminescence of beta irradiated B2O3-Li2O-ZnF2 glass. The glow-curve corresponding to 200 Gy shows three peaks; two weak-intensity peaks at 60 and 243 °C and a more prominent one at 118 °C, when measured at 1 °C/s. The dose response of the main peak at 118 °C was found to be sublinear in the range 200–1000 Gy. Regarding the kinetic analysis of the main peak, the activation energy of the corresponding electron trap was evaluated as 0.96 eV and the frequency factor as ∼1011 s−1. It is proposed that the thermoluminescence in B2O3-Li2O-ZnF2 glass is due to recombination of electrons, thermally released from Zn+ ionic defect sites, with the holes at boron-oxygen hole centres.
- Full Text: false
- Date Issued: 2017
Thermoluminescence of K-Mg-Al-Zn fluorophosphate glass
- Thomas, Sunil, Chithambo, Makaiko L
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124188 , vital:35574 , https://doi.org/10.1016/j.optmat.2016.12.035
- Description: The thermoluminescence of beta irradiated K-Mg-Al-Zn fluorophosphate glass is reported. A glow-curve corresponding to 10 Gy measured at 1 °C/s shows two peaks, a weaker-intensity one at 70 °C and a more prominent one at 235 °C, the subject of this report. The main peak was observed to fade with delay between irradiation and measurement and specifically, by 11% in 15 h. Its dose response is superlinear in the dose range 1–190 Gy although the change was linear for the initial 10 Gy. Regarding kinetic analysis, the activation energy of the higher temperature peak was evaluated as 1.31 eV and that of the lower temperature peak was found as 0.47 eV. It was also noted that the main peak is affected by thermal quenching with an activation energy for thermal quenching equal to 1.37 eV. It is proposed that the mechanism associated with the thermoluminescence in K-Mg-Al-Zn fluorophosphate glass is that electrons trapped by the metal cations are released during heating and then recombine with holes at oxygen sites.
- Full Text: false
- Date Issued: 2017
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124188 , vital:35574 , https://doi.org/10.1016/j.optmat.2016.12.035
- Description: The thermoluminescence of beta irradiated K-Mg-Al-Zn fluorophosphate glass is reported. A glow-curve corresponding to 10 Gy measured at 1 °C/s shows two peaks, a weaker-intensity one at 70 °C and a more prominent one at 235 °C, the subject of this report. The main peak was observed to fade with delay between irradiation and measurement and specifically, by 11% in 15 h. Its dose response is superlinear in the dose range 1–190 Gy although the change was linear for the initial 10 Gy. Regarding kinetic analysis, the activation energy of the higher temperature peak was evaluated as 1.31 eV and that of the lower temperature peak was found as 0.47 eV. It was also noted that the main peak is affected by thermal quenching with an activation energy for thermal quenching equal to 1.37 eV. It is proposed that the mechanism associated with the thermoluminescence in K-Mg-Al-Zn fluorophosphate glass is that electrons trapped by the metal cations are released during heating and then recombine with holes at oxygen sites.
- Full Text: false
- Date Issued: 2017
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