Perceptions and experiences of G2E e-Government workplace restructuring: The cases of Buffalo City and City of Cape Town metropolitan municipalities, South Africa
- Authors: Makwembere, Sandra
- Date: 2016
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/617 , vital:19975
- Description: Taking the cases of Buffalo City Metropolitan municipality (BCMM) and City of Cape Town Metropolitan municipality (CoCT), this thesis explores the implications of government to employee (G2E) electronic government workplace restructuring on skills transformation and workplace control as perceived by back office employees and managers from different Corporate Services departments. It aims to describe the arrangements, rationale and degree of G2E e-government at BCMM and CoCT, investigate how managers, employees and union representatives identify the workplace changes relating to skill as well as document and analyse workplace struggles linked to G2E e-government. Using labour process analysis, the impacts of G2E e-government technological change are conceptualised. The labour process concepts alert us to ways in which G2E e-government technology is applied in the context of specific public sector production relations. They explain how employees and managers experience the dynamics of skill transformation and the mechanisms of control related to G2E e-government. The consideration of the labour process contrasts predominant e-government scholarly works that focus on government websites. Further, by using case study methods, namely interviews, surveys and observations, the thesis documents the particular back office employees’ and managers’ realities of G2E e-government which are marginalised in scholarly literature. The sample of respondents were selected using purposive sampling based on the subjects’ knowledge and experience, snowball sampling following referrals and random sampling during site visits. The respondents included four managers, four employees, two shop stewards and one service provider at BCMM and 16 managers, 20 employees and four shop stewards at CoCT. The findings from BCMM and CoCT illustrate how G2E e-government workplace restructuring individualises the labour process through the kind of technologies it introduces. Moreover, they show how the restructuring facilitates electronic information, communication and operations which broaden demands on technical as well as social skills. The findings also show that the restructuring extends avenues for managerial control thereby marginalising union representivity as the workplace control systems create opportunities for systemic control by management. As the South African government adopts electronic government and makes optimistic declarations of “cost saving”, “efficiency”, “productivity” and “innovation” through egovernment, the study uncovers marginalised local government employee and manager experiences. It contributes to building new knowledge on the impacts of contemporary technological change on the local government labour process and contributes to debates around the effects of G2E e-government reforms on local government.
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- Date Issued: 2016
Perceptions of the rules of business behaviour in the competitive banking environment in Uganda
- Authors: Mukasa, Herbert , Smith, Elroy Eugene
- Date: 2016
- Subjects: Business etiquette -- Uganda Banks and banking -- Uganda Financial services industry -- Uganda
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/12297 , vital:27052
- Description: Business rules shape the behaviour of a business and guide the behaviour of employees when conducting business. Therefore, business rules explain what is allowed and not allowed. It is argued that all organisations have business rules and engage in some form of relationship whether through competition or cooperation with other companies. In today’s business environment, organisations are embedded in relationships with other actors in order to gain access to resources that are needed. Therefore, each organisation’s business rules define their strategies and actions. The type of business rule behaviour which is applied by organisations encourages them to grow by taking market share from rivals or creating new markets. The aim of this study was to determine the influence of the rules of business behaviour on perceptions of the competitive banking environment in Uganda and its potential impact on certain outcomes. In this study, a quantitative research approach was adopted, as the study sought to investigate the relationships between variables. This study collected data through the use of a structured self-administered survey questionnaire which was distributed to 233 branches of banks in Uganda, totaling 700 bank employees. The survey yielded 529 usable questionnaires which were analyzed, using several statistical analysis techniques. A hypothetical model and measuring instrument of perceptions of the rules of business behaviour in the competitive banking environment within Uganda was developed. Six null-hypotheses were subjected to statistical analysis. The influence of three independent variables, namely, confrontational business behaviour, co-operational business behaviour and typologies of competition on the intermediate variable, perceptions of the competitive banking environment in Uganda were tested. The impact of these variables on three independent outcome variables, namely, organisational performance and customer loyalty and retention were also tested The empirical findings revealed that the rules of business behaviour have a significant relationship with perceptions of the competitive banking environment in Uganda. These results showed that confrontational behaviour as a rule of business behaviour can be classified as being direct or indirect. The study further revealed that banks should consider competitors as co-partners and not only as aggressors, indicating that co-operational business behaviour is statistically significantly related to perceptions of the competitive business environment in Uganda. The three typologies of competition, namely, defy attack, defense and debase attack are also positively related to perceptions of the competitive business environment in Uganda. The empirical results of the study also indicated that perceptions of the competitive banking environment have a positive relationship with outcomes such as organisational performance, customer retention and customer loyalty. This study contributed to the literature and body of knowledge regarding the impact of rules of business behaviour in the competitive banking environment in Uganda. This study could also assist banks, employees and customers alike to understand the different rules of business behaviour that exist and what strategies banks can employ to improve their position in the market. This study could also be replicated by other banks in other developing countries so as to ensure successful competition and the cooperation of banks as they engage in their activities in the banking industry.
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- Date Issued: 2016
Perceptions regarding organisational citizenship behaviour in South African retail firms
- Authors: Ngxukumeshe, Tandiswa
- Date: 2016
- Subjects: Organizational behavior -- South Africa Retail trade -- South Africa Consumers -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/11898 , vital:27002
- Description: The wholesale and retail industry is a more volatile nudstry, with respect to cyclical changes and global economic conditions, than many other industries. The growth of technology in this industry has led to informed customers, bringing with them many challenges to retailers, as these retailers have to win customer loyalty by focusing not only on prices and quality, but also on global competition. The heterogeneity as well as the illusive preferences, expectations, personality characteristics, attitudes, and desires of customers have created diverse and fast-evolving customer demand. As a result, retailers need to source highly customer-focused employees who are willing to go beyond their expected call of duties to satisfy customer needs and wants, thereby keeping firms competitive. This behaviour is called organisational citizenship behaviour (OCB). OCB involves extra-role performance, which represents behaviours not formally required by any particular job, but which help to develop the social context of all jobs, thus facilitating effectiveness. Thus, retailers who encourage OCB among their employees are more likely to improve the performance of both the organisation and the employees, and increase the organisation’s competitiveness in the global economy. The primary objective of this study is to assess the perceptions of employees regarding OCB within retail firms in South Africa. A positivistic research paradigm was used, in this study, by means of quantitative research. Secondary data in the form of textbooks, journal articles and Internet sources provided the theoretical framework for this study. Primary data was obtained using the survey method, by means of self-administered structured questionnaires. The aim was to target 1000 employees in the retail industry (250 employees from each of the most economically active provinces, namely, the Eastern Cape; the Western Cape, Gauteng and Kwa-Zulu Natal). However, 690 questionnaires were returned and only 554 were usable, which amounts to an effective response rate of 80%. Seven null-hypotheses and a hypothetical model of employee perceptions regarding OCB behaviour in retail firms were tested. The influence of four independent variables were tested, these are: job perceptions, role considerations, organisational climate and employment considerations on OCB. In addition, three dependent variables, namely, employee commitment, propensity to leave and employee engagement were tested. The Statistica (version 12) computer programme was used to analyse the results by means of advanced statistical techniques (such as exploratory factor analysis, regression and correlation analysis) as well as descriptive analysis and frequency distributions. After various statistical procedures, the model was re-specified, some of the variables were renamed and the hypotheses were adjusted accordingly. The empirical results revealed that job considerations and employment considerations have a positive influence on both OCB related to compassion and OCB related to civic non-obligatory acts, while role considerations and job security were found to have no significant influence on both OCB related to compassion and OCB related to civic non-obligatory acts. Furthermore, the empirical results showed that OCB related to compassion have a positive influence on both organisational commitment and propensity to resign, while OCB related to civic non-obligatory acts has a positive influence on organisational commitment and its influence on propensity to resign was not significant. It is envisaged that the results of this study could assist retail firms to understand the variables that influence the organisational citizenship behaviour of employees. In addition, it is further envisaged that the results and recommendations of this study could be used to implement effective strategies in retail firms in order to ensure effective engagement in OCB related behaviour and to create awareness of the importance of employee engagement in organisational citizenship behaviour.
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- Date Issued: 2016
Perspectives of the historical–biographical criticism In the creative works of J. J. R. Jolobe
- Authors: Khumalo, Hlonpha Pamela Vivienne , Kwatsha, Linda Loretta
- Date: 2016
- Subjects: South African literature -- History and criticism -- Biography Xhosa literature -- History and criticism
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/21983 , vital:29809
- Description: Olu phando lohlalutyo lukwaluncomo-gxeko lwemisebenzi kaJolobe, injongo yalo kukubonisa ukuba lukho uqhagamshelwano phakathi kobomi bakhe jikelele kunye noncwadi lwakhe. Ulwazi olunjalo lungathi lube luncedo kwiphulo elibalulekileyo ekuncediseni kulwazi lokubhala ibhayografi yakhe. Kubonakele kufanelekile ukuba iphulo elinjalo lenziwe ukukhumbula imisebenzi emikhulu eyenziwe ngamaqhawe abantu abaNtsundu abathe banegalelo elikhulu ekuphakanyiswni koncwadi lwemvelo kwakunye nenkuqubela phambili kwimfundo yabantu abangama-Afrika beli lizwe. Umzekelo uJolobe ulusebenzele ukuba uncwadi lwakhe ukuxwayisa abantu bakowabo abaNtsundu ngemfundo nolwazi olwakhaya. Ukwalusebenzise uncwadi lwakhe ukuvusa abantu ama-Afrika balumke kwingozi zemimoya yocinezelo lwabo ngurhulumente ocalule abantu abaNtsundu kuba bebantsundu ngebala. Nangona uncwadi lwakhe ulenze lwabasisonwabiso kodwa ikhakhulu ulusebenzise kwanokunika intuthuzelo, ithemba kwanokomelela kubantu abathe bacinezelwe zimeko zobomi ukuba bangalahli ithemba loluzuza impumelelo, kuba izinto zingatshintsha ebomini babo ngokuhamba kwamaxesha. Kwakhona ukongeza uncwadi lwakhe ulusebenzise ukuphakamisa nokuhambisela phambili ulwimi lwemveli, inkcubeko, imbali ngokusebenzisa isixhobo esiluncwadi lwakhe ukuze ezi ngongoma zikhankanyisweyo zihlale ezincwadini zakhe ezithe zazisele zolwazi, zingabi nakuze zife kuba zililifa lesizwe esiNtsundu, Uninzi loncwadi olubhalwe nguJolobe luthe lwaxoxwa kwesi sifundo, kodwa kuye kwaphonongwa ikakhulu uncwadi lwemibongo, inoveli idrama kuba kubonakele ukuba lo msebenzi ubanzi kakhulu kwaye esi sifundo kubonakele ukuba kungabanzima ukuba singagqibeka lula, kodwa ke uJolobe ubengumntu okhutheleyo. Ubhale incwadi eziliqela ngenxa yothando lwakhe lobhalo loncwadi oluqhutywe ngumbono wakhe wobuthandazwe, wokubona kubalulekile ukuba inani loncwadi olubhaliweyo esiXhoseni linyuke kwaye libe kwizinga eliphezulu, ukuze umzi wasemaXhoseni nowamanye ama-Afrika ngokubanzi ungalambathi ngoncwadi lokufunda ujongelwe phantsi ngokuba semva kwinkqubela phambili zezinye izizwe Ingokuphandle uncwadi lukaJolobe lubonakela luyinxenye yobomi bakhe. Kulunye uncwadi kwakhe kufumaniseka ukuba ukubhale endululwe zizinto ezithe azamphatha kakuhle ebomini bakhe zazaza ezo zinto zawuphazamisa umoya wakhe, nentlalo yakhe wada waqanda ukuba makabhale aphokoze okukuphuphuma kwengcinga zakhe ukuzithuthuzela kwanokuphilisa kwanabanye abantu abathe badibana neenzima ezinjalo zobomi. Umzekelo: iimeko zopolitiko zeli lizwe zithe zabuchaphazela ubomi bakhe, oko kubesisiphumo sokuba abhale incwadi yakhe yedrama apho adiza ngeemeko zokuphatheka kwabantu baseBhayi kwilokishi eyathi yabelwa bona ngurhulumnte wobandlululo, apho ebexelenga khona njengetitshala kwanoMfundisi weliZwi. Kanti noncwadi apho athe wabonisa ukuvuya khona olo luvuyo olusukela kwinto ethe yamvuyisa emalunga nobomi bakhe, izimvo zakhe kwanenkolo yakhe njengomntu, kwanendlela akhule ngayo. Umzekelo, uJolobe uye wazisa abafundi bakhe ukuba iimbalo zakhe zisukele kwizinto ezithe zamchukumisa ebomini bakhe. Ngoko ke kwabonakala ukuba olu phando luluncedo ekusungulweni kweprojekti yokubhalwa kwebhayografi kaJolobe neya kuba luncedo kwimisebenzi yophando olubalulekileyo kuncwadi kuba iincwadi ezinje zityebile ngolwazi olubalulekileyo ekungena kucingelwa ukuba lunokufunyanwa kulo.
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- Date Issued: 2016
Pharmacological studies of Foeniculum Vulgare (Mill.) and Lippia Javanica (Burm.F.) spreng. used as spices in Nkonkobe Municipality of the Eastern Cape Province, South Africa
- Authors: Asowata-Ayodele, Abiola Mojisola
- Date: 2016
- Subjects: Medicinal plants -- South Africa -- Eastern Cape Fennel -- Utilization -- South Africa -- Eastern Cape Ethnopharmacology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/2777 , vital:28085
- Description: Spices are of great importance in the indigenous culinary and traditional medicine systems of the people of Nkonkobe Municipality of the Eastern Cape, South Africa. The present investigation evaluated the ethnopharmacological potentials of two indigenous South African spices- Foeniculum vulgare and Lippia javanica. The pharmacological investigations on these two plant species include ultra-morphology, nutrient and mineral analysis, evaluation of the essential oil, phytochemical and antioxidant assays, antimicrobial, anti-inflammatory as well as anti-urolithiatic assay of the acetone and aqueous extracts of the two plants. The species were selected for study as the most cited plants after an ethnobotanical survey conducted on the indigenous knowledge of plants used as spices and medicine in Nkonkobe Municipality, Eastern Cape of South Africa. Among the plants cited Foeniculum vulgare(Apiaceae) and Lippia javanica (Verbenaceae) stood out as the most commonly used spices. Others were members of the families; Solanaceae, Apiaceae, Amaryllidaceae, Amaranthaceae and Lamiaceae. Ultra-morphological studies conducted on the leaves of the two selected plants using scanning electron microscope revealed the presence of non-glandular and glandular trichomes, stomata and crystals. The leaf surfaces of these herbs may serve as secretory sites where aromatic secondary metabolites are produced. Analyses of the proximate, mineral, vitamin and anti-nutrients contents of these two spices showed that both species are good sources of these phytochemicals and may be used to enrich the human diet. Lippia javanica possesses lower lipid (0.50 percent), fibre (5 percent) and carbohydrate (64.96 percent) contents than Foeniculum vulgare. On the other hand, protein (20.54 percent), ash (11.60 percent) and moisture content (11.69 percent) were higher in Foeniculum vulgare than in Lippia javanica. Foeniculum vulgare showed higher N (3286 mg/100g), Mg (386.7 mg/100g), K (3187 mg/100g) and Na (1383 mg/100g) content while Lippia javanica was higher in Ca (1833 mg/100g), Zn (4.7 mg/100g), Cu (0.9 mg/100g) and Fe (78.4 mg/100g). Vitamins Aand E were also higher in Lippia javanica (1.31 mg/100g; 2.52 mg/100g) while Foeniculum vulgare (0.45 mg/100g) had higher vitamin C content. No significant differences were observed in the phytate, oxalate and tannin contents of the two spices, but saponin and cyanide were significantly lower in Lippia javanica (268.5 mg/100g; 8.45 mg/100g) than in Foeniculum vulgare (1855 mg/100g; 10.5 mg/100g) Evaluation of the essential oil component, cytotoxicity and antimicrobial activities of both fresh and dried leaves of Lippia javanica and Foeniculum vulgare revealed that the dried samples yielded more oil and also contain more chemical than the fresh samples of both plants. The overall antimicrobial activity evaluated using susceptibility and microdilution assays revealed that the oils of F. vulgare and L. javanica exhibited high antifungal and antibacterial activity, compared to the reference drugs. In addition, essential oil from fresh leaves of both spices was less toxic compared to the oil from the dried leaves. Polyphenolic evaluation of the aqueous and acetone extracts of the plants revealed that the acetone extract had higher phenol, flavanol, flavonoid and proanthocyanidin contents than the aqueous extracts. The total phenolic content of acetone and aqueous extracts were 4.49 ± 0.411 mg/g and 3.73 ± 0.498 mg/g tannic acid equivalent (TAE) respectively for Lippia javanica. The same trend was also observed in Foeniculum vulgare with total phenolic content of acetone and aqueous extracts were 4.22 ± 0.325 mg/g and 4.17 ± 0.651 mg/g tannic acid equivalent (TAE) respectively. Further assessment of the antioxidant activity of the solvent extracts revealed that both plants exhibited promising free radical scavenging potentials against 1,1 diphenyl-2-picrylhydrazyl (DPPH), 2, 2’-azino-bis(3- ethylbenzthiazoline-6-sulfonic acid (ABTS), reducing power, lipid peroxidation, nitric oxide, phosphomolybdate and hydrogen peroxide. Antimicrobial activities of the acetone and aqueous extracts of the two plants revealed moderate antibacterial and antifungal activities. They inhibited the growth of Microsporium canis and Trichophyton rubrum that were not susceptible to the standard antifungal drug used as control.
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- Date Issued: 2016
Phylogenetics and historical biogeography of the Teloganodidae (Ephemeroptera)
- Authors: Pereira da Conceicoa, Lyndall Louise
- Date: 2016
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/64900 , vital:28629
- Description: The Teloganodidae are a mayfly family endemic to the southwestern Cape (South Africa), with relatives in Madagascar and Asia. Like many other aquatic invertebrates in Africa, they have been considerably understudied. Research into biodiversity and biogeography allows an understanding of the earth’s biota, producing knowledge which can be used to develop strategies to preserve and monitor this biota. Mismanagement of water systems places biodiversity of river fauna under an ever-increasing extinction threat. This investigation explores rivers in under-collected areas to determine how well teloganodids have been represented in the literature, with four genera and five species described at the onset of this study. A lectotype for Lestagella penicillata Barnard (1940) has been elected and described in detail, setting “benchmark” characters for future descriptions. Standard DNA sequencing methods provide portions of three mitochondrial genes; cytochrome oxidase subunit I (COI), small subunit ribosomal 16S RNA (16S), 12S ribosomal DNA (12S) and two nuclear genes, Histone 3 (H3) and 28S ribosomal DNA (28S) for up to 255 specimens. Fore and hind wings of 79 teloganodid adults were used to examine phylogenetic signal and evolutionary divergence using geometric morphometrics. A multi-faceted approach is used to investigate relationships between clades and the effects of deep-time climatic and landform changes which have influenced the diversity and distribution seen today. Tree (Bayesian Inference and Maximum Likelihood) and network (parsimony) phylogenies, ancestral reconstruction, historical biogeography and wingevolution of the Teloganodidae are investigated. Species tree analyses discovered 27 species and six genera. Distinct lineages are restricted to catchments, and strong phylogeographic structure was found within most genera. Southern African Teloganodidae are shown to have originated in the Cretaceous, with divergence and dispersal of lineages depended on their established locality at the time of tectonic events (uplift) and climatic changes (sea level regressions and transgressions). Geographic clines in wing-shape of Lestagella across its range imply evolutionary adaptations to specific catchment landscape and environment. A detailed analysis of biodiversity has many valuable contributions, from directing future research, understanding adaptive processes, fine-tuning phylogeographical and evolutionary hypotheses, to improving management and conservation decisions in order to preserve endemic biodiversity hotspots.
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- Date Issued: 2016
Phylogenetics of the keratin-feeding beetle family Trogidae (Coleoptera: Scarabaeoidea)
- Authors: Strümpher, Werner Petrus
- Date: 2016
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/1232 , vital:20037
- Description: Trogidae constitute a monophyletic and biologically unique family within the Scarabaeoidea, being the only keratinophagous group in its superfamily. Traditionally, the family has been divided into three distinctive genera, Omorgus Erichson, Polynoncus Burmeister, and Trox Fabricius. Although the taxonomy of the group is relatively well studied, recently changes to the existing classification have been proposed without the family as currently constituted being subjected to phylogenetic analyses. In this study I present the first molecular phylogeny for this cosmopolitan family, based on three partially sequenced gene regions: 16SrRNA, 18S rRNA and 28S rRNA domain 2. Analyses resolved relationships between and within genera and subgenera that are largely congruent with existing taxonomic hypotheses based on morphology. I recovered four well-supported radiations: Polynoncus, Omorgus, Holarctic Trox and Afrotropical Phoberus. One of the more surprising results was the monophyly of Phoberus. Based on the evidence, I propose reinstating the genus Phoberus to accommodate all Afrotropical (including Madagascan endemic) species. The results re-emphasise the validity of Scholtz’s (1986a) classification system for the genus Omorgusand its subgeneraand provide evidence of an African origin for Madagascan trogids. Divergence analysis was able to date the major events for the origin of extant lineages of Trogidae. The subsequent diversification of the major lineages is largely attributed to Pangaean and Gondwanan vicariance events in the Mid-Jurassic and early Late Cretaceous, respectively. The separation of the landmasses resulted in the evolution of four distinct groups: Omorgus, Polynoncus, Trox and Phoberus. The monophyletic subgenus Phoberus MacLeay is of particular interest; about one-third (14 of 40) of the species in the Afrotropical region have lost the ability to fly. To gain insights into the evolution of flightlessness in this clade, phylogenetic relationships among species were inferred using molecular sequence data. Four partial sequences of four genes (COI, 16S, 18S and 28S domain 2) were obtained for 27 species, covering all of the recognised species-groups. Estimated times of divergence were based on published mutation rates for COI. The results recovered eight monophyletic lineages, supporting the morphology-based subdivisions of the genus. Flightlessness evolved at least five times within the subgenus. There is no strong support for the re-acquisition of functional wings once they are lost. Diversification, and the present relictual distributions, in African Phoberus can be linked to climatic and geological events associated with the Miocene and Pliocene Climate Optimum in southern Africa. The evolution of flightlessness in Phoberus is consistent with the habitat stability hypothesis. All flightless species occupy refugial areas with relatively long-term environmental stability. Phoberus is a promising model group for studying evolutionary trends relating to flightlessness, speciation and biogeography. Flightlessness is a counterintuitive evolutionary development, given the many advantages of flight. To interpret the diversification in the flightless Phoberus capensis Scholtz, the phylogenetic relationships among several populations of P. capensis are investigated. Phylogenetic relationships among populations were inferred using molecular sequence data that suggested three distinct evolutionary lineages, which was also supported by morphological characters. Divergence time estimates suggest a Pliocene-Pleistocene diversification. Based on these results, it is suggested that P. capensis experienced climatically-driven allopatric speciation with sheltered Afrotemperate forests and high mountain peaks serving as important refugia in response to climatic exacerbations. The P. capensis complex thus represents a speciation process in which flight-restricted populations evolved in close allopatry, possibly as recently as the Pleistocene. Two of the three divergent and geographically distinct lineages are described as novel species. This study represents the most recent comprehensive work on the Trogidae. On the basis of this study, it is proposed that taxonomic changes to the generic classification of the family be made. Trogidae are formally divided into two subfamilies, Omorginae and Troginae. The subgenus Phoberus is restored to genus rank to include all the Afrotropical species, and Afromorgus is confirmed at subgeneric rank. The genus Madagatrox is synonymised with Phoberus.
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- Date Issued: 2016
Predators of aerial insects and riparian cross-boundary trophic dynamics: web-building spiders, dragonflies and damselflies
- Authors: Chari, Lenin Dzibakwe
- Date: 2016
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/55791 , vital:26734
- Description: This thesis characterises the cross-boundary trophic interactions of a relatively small model ecosystem, the Kowie River (Eastern Cape of South Africa), to explore their epistemic implications for systems ecology. Using web-building spiders and odonates (dragonflies and damselflies) as model organisms, I sought to investigate whether the diets of predators of aerial insects could be used to assess the strength of the trophic connectivity between freshwater and terrestrial systems in relation to variables such as stream width, distance from the river and aquatic insect emergence rates and abundances. Predator diet composition was determined by using a combination of diet analysis tools: direct observations of cross-subsidies, naturally-abundant stable (carbon and nitrogen) isotope analysis and fatty acid analysis. I also sought to reveal feeding niches and guilds among riparian aerial predators and investigate how the environment influenced predators’ access to aquatic prey subsidies. As emergent aquatic insect abundances decreased with an increase in distance from the river, and increased with stream width and seasonal changes from winter to summer, stable isotope and fatty acid analyses revealed distinct changes in web-building spider diet composition. Examination of the fatty acid eicosapentaenoic acid, a component commonly used as an indicator of consumer reliance on aquatic nutritional subsidies, showed that aquatic subsidies extended further inland at the wider sections of the river. Spiders and odonates at the wider sections of the Kowie River generally received more subsidies (56 – 70%) than those at the narrower sections (25 – 60%). When terrestrial insect biomass was distinctly low in winter, the benefit of aquatic subsidisation to spiders was relatively lower at the narrower sections of the Kowie River relative to the wide sections. As such, riparian areas adjacent to wide parts of the river were more likely to support larger populations of aerial predators than those at the narrow sections. Apart from the diet changes across time and space, there was evidence of inter-specific niche partitioning in both spiders and odonates, but no differences were observed between males and females of the same species. Results showed odonates of different sizes and hunting strategies had separate dietary niches, hence varied access to aquatic nutritional subsidies. The larger odonate taxa that frequently foraged mid-air had more varied diets and relied less on aquatic emergent insects than the smaller odonates that foraged from perches near the river. There was also evidence of niche partitioning amongst the spiders, as those that built horizontal webs captured more aquatic insects (40 – 78%) than the vertical orb-web builders (20 – 66%). This study showed that the nature and extent of trophic cross-boundary linkages in riparian areas largely depended on the availability of subsidies that varied seasonally and spatially. The width of the stream and seasonal variability emerged as important predictors of emergent insect abundances/biomasses that influenced predator feeding niches. The high mobility of odonates made their reliance on aquatic nutritional subsidies different from the less mobile spiders. The link between the width of the river and the extent of trophic connectivity has implications for riparian area management and definition of riparian buffer zones. However, the variation in diet niches amongst terrestrial consumers makes the results area-specific, and more studies are required that incorporate additional terrestrial predators in other fluvial systems so that we can make some generalizations on the dynamics of riparian trophic cross-boundary links.
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- Date Issued: 2016
Preparation and application of plasmon metal enhanced titanium dioxide photocatalyst for the removal of organics in water
- Authors: Nyamukamba, Pardon
- Date: 2016
- Subjects: Water -- Purification -- Photocatalysis Titanium dioxide Water chemistry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/2765 , vital:28074
- Description: Advanced oxidation processes are capable of removing organic compounds that cannot be removed by conventional water treatment methods. Among the oxidation processes, photo-catalysis using titanium dioxide (TiO2) is a promising method but suffers from rapid electron-hole recombination rates and only absorbs UV light which is a small percentage (5 percent) of the total solar radiation. Therefore there is a need to reduce the recombination rates and also extend the absorption of the photo-catalyst into the visible region which constitutes 55 percent of the total solar radiation. The major aims of this study were to prepare plasmon metal decorated and doped TiO2 photo-catalysts immobilized on quartz substrates and test their photo-catalytic and antimicrobial activities. The effect of film thickness (loading) and use of different shapes of plasmon metal nanostructures was investigated. TiO2 thin films were prepared by a sputter coating technique while plasmon metal (Au & Ag)/carbon co-doped TiO2 by a simple sol gel process and plasmon metal films were prepared by the thermal evaporation technique. Different plasmon metal nanostructures (nanorods, dendrites, nanowires and spherical nanoparticles) were prepared using a wet chemical technique using sodium borohydride as the reducing agent. Nanocomposites of co-doped TiO2 photo-catalyst and plasmon elements of different proportions were also prepared. The prepared photo-catalysts were coated onto etched and MPTMS (3-Mercaptopropyl trimethoxysliane) treated quartz glass substrate which is a stable support favouring easy recovery. The prepared materials were characterized by XRD, HRTEM, TEM, HRSEM, FT-IR, SEM, PIXE and TGA while the doped TiO2 was characterized by XPS, BET, CHNS and Raman Spectroscopy. The effect of pH of solution, presence of other contaminants and salts in solution, initial concentration of the model pollutant and type of the plasmonic elements on the photocatalytic activity of TiO2 towards 4-(4-sulfophenylazo)-N,N-dimethyl aniline (methyl orange) were also investigated. The selected TiO2 photo-catalyst films were tested for antimicrobial properties. The effect of different types of plasmon elements on the antimicrobial activity of TiO2 against E. coli ATCC 3695 was evaluated under both sunlight and weak UV light. Under UV light, Ag showed the highest enhancement in photo-catalytic activity of TiO2 than Au and Cu. The photo-catalytic activity of TiO2 increased with an increase in Ag content to an optimum loading and then started to decrease with a further increase in loading. For Cu and Au, photo-activity activity increased with an increase in plasmon metal content. Under sunlight, Cu showed the highest enhancement of TiO2 photocatalytic compared to Ag and Au. The change in order of deposition showed that Au films enhanced the photo-activity better when they were deposited underneath rather than on top of TiO2 on quartz supports but Ag films performed better in enhancing photo-activity when they were deposited on top of TiO2. The use of bimetallic layers and three layer systems of different plasmon elements enhanced photo-catalytic activity better than the use of a monometallic layer. The presence of other organic contaminants and salts in solutions was found to reduce the photo-degradation of methyl orange due to preferential adsorption of other contaminants. When the pH was increased, the photocatalytic activity of TiO2 towards methyl orange was reduced. In antimicrobial studies, it was found that the plasmon elements greatly improved the antibacterial action of TiO2 against Escherichia coli ATCC 3695 in water and the best antibacterial action was observed with silver/carbon co-doped TiO2 photo-catalyst under sunlight The doped samples consisted of polydisperse nanoparticles which were found to be beneficial for photo-catalytic activity enhancement under sunlight.
- Full Text:
- Date Issued: 2016
Relationships between cash management and growth of informal businesses in Uganda
- Authors: Nuwagaba, Geoffrey , Struwig, Miemie
- Date: 2016
- Subjects: Cash management -- Uganda , Informal sector (Economics) -- Uganda , Small business -- Uganda
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/12319 , vital:27054
- Description: This study investigates the relationships between cash management and growth of informal businesses in Uganda. Whereas anecdotal evidence has for some time revealed that informal businesses in Uganda are faced with the challenge of cash management, no specific studies have been conducted to investigate how this relates to the growth of businesses where evidence has also indicated that most of these businesses do not exist for very long. In particular, the study assesses and explores the growth levels of informal businesses in terms of sales volume, growth in employment and length of existence. The study investigates the various ways in which informal businesses manage their cash and investigates the various internal and external factors that moderate cash management and the growth of the informal businesses. Furthermore, the study proposes a possible framework to manage cash in informal businesses and makes recommendations to informal business owners and managers on how to effectively manage cash in order to stimulate business growth. In order to investigate the relationships between the variables, an empirical investigation was undertaken. Based on the literature review, the primary objective of the study was formulated to investigate the relationships between cash management and growth of informal businesses amidst the external and internal environment in Uganda in order to suggest a framework for effective management of cash by informal businesses that would enhance their growth. A positivistic research paradigm was adopted in this study. A sample of 383 informal businesses was drawn from the five divisions of Kampala district namely; Central, Kawempe, Makindye, Nakawa and Rubaga. To ensure validity and reliability, EFA and Cronbach’s alpha coefficient were computed. Six hypotheses were developed to test the relationships between cash management and growth of informal businesses. The empirical results revealed that there is a significant relationship between cash management and the external environment in which informal businesses operate, a significant relationship between the external environment and the growth of informal businesses and a significant relationship between cash management and growth of informal businesses where the external environment will have a moderating influence on the relationship. The empirical results did not establish a significant relationship between cash management and the internal environment in which informal businesses operate, the internal environment and growth of informal businesses and cash management and growth of informal businesses where internal environment will have a moderating influence on the relationship. The results of this study show that the growth of informal businesses is largely hampered by poor cash management practices and challenges such as the lack of cash planning, lack of cash forecasting and budgeting, lack of financial controls and reporting, the tendency to invest largely in short-term assets which limits their profitability, the employment of less competent and skilled staff and lack of formal accounting information systems. The magnitude of the impact of these is accelerated by the external environment such as competition and the legal and regulatory environment which put pressure on the little cash resources owned by these businesses. Based on the study results, several strategies based on individual cash components of cash planning, cash forecasting and budgeting, financial controls and reporting, short-term investment of cash surplus, competence and skills of staff and accounting information systems were recommended for implementation. It was further recommended that these strategies should be implemented while giving due attention to the external environment if informal businesses are to effectively manage cash and enhance their growth.
- Full Text:
- Date Issued: 2016
Rhenium complexes with multidentate imine-, amine-, thione-, thiol-, hydroxy- and carboxamide chelates
- Authors: Habarurema, Gratien
- Date: 2016
- Subjects: Rhenium Metal complexes
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/12679 , vital:27106
- Description: This study entails the synthesis, spectroscopic and structural characterization of new rhenium complexes with multidentate imine-, amine-, thione-, thiol-, hydroxy- and carboxamide chelates in various oxidation states. Rhenium(I) and (V) complexes with imidazolidine, pyrimidine and bridging pyridyl derivatives are reported in Chapter 3. The reactions of the potential tridentate N,N,Odonor ligand 2,2'-dipyridylketone (dpk) with trans-[ReOCl3(PPh3)2], (n-Bu4N)[ReOCl4] and trans-[ReOI2(OEt)(PPh3)2] led to the isolation of cis-[ReOCl2(edpm)], cis-[ReOCl2(dpk.OH)] and [ReO3(dpk.OH)] respectively (see Scheme 1). The reaction of (E)-N-((pyridine-2-yl)methylene)benzo[d]thiazol-2-amine (pbt) with trans- [ReOCl3(PPh3)2] produced a mononuclear oxorhenium(V) complex cis- [ReOCl2(epm)(PPh3)]. Both dpk and pbt exhibited a nucleophilic attack by acetonitrile (for Hedpm), water (for dpk) and ethanol (for pbt) leading to chelates that act as uninegative tridentate N,N,O- and bidentate N,O-donor chelates respectively. The reaction of [Re(CO)5Cl] with 2,3-dihydro-2,2-di(pyridin-2-yl)-1H-benzo[d]imidazole (H2dpb), (2,6-diaza-cyclohex-1-enylolonium)2-aza-benzoate (H2den) and 2-(2-(pyridine-2-yl)imidazolidin-2-yl)pyridine (H2pip) (see Scheme 1) gave rise to novel rhenium(I) complexes fac-[Re(CO)3(H2dmb)Cl], fac-[Re(CO)3(Hhdm)] and fac-[Re(CO)3(H2pip)]Cl respectively. The monomeric cationic salt fac-[Re(CO)3(H2salbam)]Br and ligand-bridged dimer fac- (μ-H2salet)[Re(CO)3]2 complexes were formed by the reactions of [Re(CO)5X] (X = Br or Cl) with the potentially heptadentate Schiff base 2,2,2-tris (salicylideneimino)- triethylamine (H3salet; Scheme 2) respectively. The reactions of the potentially hexadentate ligands acting as tridentate monoanionic N,N,O- or N,O,O-donor chelates N1-(3-(2-hydroxy enzylideneamino) propylamino) ethyl)benzylidenepropane-1,3-diamine (H2salpd) and N,N -bis(salicylidene) -3,6-dioxa-1,8-diaminooctane (H2saldane) (Scheme 2) with [Re(CO)5Cl] led to the isolation of the mononuclear and dinuclear complexes fac-[Re(CO)3(Hsaldane)] and fac-(μ-salpd)[Re(CO)3]2 respectively. The reactions of [Re(CO)5Cl] with the tetradentate ligands 2-{[2-hydroxy-3-{[(E)-(2- hydroxyphenyl)-methylidene]amino}propyl)imino]methyl}phenol (H2hmp), 6-((6E)- ((3E)-3-((oxocyclohexa-2,4-dienyl)methyleneamino)-2-hydroxypropylimino)methyl)- cyclohexa-2,4-dienone (H2hcd.H2O) zwitterion and 2-((1E)-1-((E)-3-(2-hydoxyphenylmethylideneamino)propylimino)methyl)phenol (H2hdp) (see Scheme 2) resulted in the formation of the neutral fac-[Re(CO)3(Hamp)], fac-[Re(CO)3(Hhetp)] and fac- [Re(CO)3(Happ)] respectively. The treatment of 2-((3-(2-hydroxybenzylamino)-propylamino)methyl)phenol (H2hbp) with [Re(CO)3Cl] and trans-[ReOCl3(PPh3)2] gave the fac-[Re(CO)3(Hhbp)] and (μ-O)[ReO(hbp)]2 complexes. The reactions of the ligands H2hmp, H2hdp and H2hap (see Scheme 2) with trans-[ReOBr3(PPh3)2] and trans-[ReOI2(OEt)(PPh3)2] produced dinuclear oxo-bridged rhenium(V) complexes (μ-O)[ReO(hmp)]2, [(μ-O)[ReO(hdp)]2 and (μ-O)[ReO(hap)]2 respectively. The neutral and anionic binding modes of thiosemicarbazones to the fac-[Re(CO)3]+, cis- [ReO2]+ and trans-[ReO2]+ cores have been investigated in Chapter 6. The reactions of the potentially tridentate ligand 1-{1-(2- hydroxyphenyl)ethylidene}-4- phenylthiosemicarbazide (H2hpt) (see Scheme 3) with [Re(CO)5Cl], cis-[ReO2I(PPh3)2]cand trans-[ReO2(py)4]Cl led to the isolation of the complexes fac-[Re(CO)3(H2hpt)2]Cl, [Re(hipt)(Hipht)(PPh3)] and trans-[ReO(hpt)(Hhpt)] respectively. The X-ray crystal analysis of the complexes show that the ligand H2hpt exhibits decomposition, thiol-enol tautomerism and a thiolate-iminium zwitterionic process, and coordinates in the neutral form via its thione sulfur and nitrogen and anionic through the azo nitrogen, thiolate sulfur and acetophenolic oxygen. A series of nitrogen-heterocyclic amide-, acid-, thiol- and diol-based ligands as well as their related monomeric rhenium(III) and (V) complexes have also been studied (see Chapter 7). The reaction of N-(2-(pyrazine-2-carboxamido)phenyl)pyrazine-2- carboxamide (H2ppc) (Scheme 3) with trans-[ReOBr3(PPh3)2] yielded the complex trans- [ReBr2(Hppca)(PPh3)2]. The reactions of trans-[ReOX3(PPh3)2] (X = Cl, Br) with pyridine-2,6-dicarboxylic acid (H2pda) produced the neutral oxorhenium(V) complexes [ReOX2(epca)(PPh3)]. The treatment of trans-[ReOBr3(PPh3)2] with 2-mercaptopyridine- 3-carboxylic acid (H2mpc) gave rise to the rhenium(III) complex [Re(empc)3(PPh3)]. The reaction of 2,6-bis(hydroxymethyl)pyridine (H2bhp) with trans-[ReOI2(EOt)(PPh3)2], trans-[ReOBr3(PPh3)2] and [Re(CO)5Cl] gave the complexes [ReO(Hbhp)2(PPh3)]I.PPh3, cis-[ReOBr2(Hbhp)(PPh3)] and fac-(μ- O)2[Re(CO)3(Hbhp)]2 respectively. Their X-ray crystal structures indicate that the ligand acts as a bidentate monoanionic N,O-donor chelate leaving a free aliphatic hydroxyl group.
- Full Text:
- Date Issued: 2016
Rhenium complexes with pontentially multidentate ligands containing the amino, imino, hydroxy and thiol groups
- Authors: Mukiza, Janvier
- Date: 2016
- Subjects: Rhenium Thiols Ligands
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/12308 , vital:27053
- Description: The chemistry of rhenium has received considerable interest due to its versatility in various catalytic applications, fixation and especially the potential use of 186Re and 188Re radionuclides in nuclear medicine. This study investigates the synthesis and characterisation of rhenium complexes with potentially multidentate ligands containing the amino, imino, hydroxyl and thiol groups. It reports new rhenium complexes in the +1, +3, +4 and +5 oxidation states, which display structural diversity, from monomers to ligand-bridged dimers as well as metal-metal multiply bonded dimers. The reaction of orotic acid (H2oa) and 2-mercapto-orotic acid (H2moa) with trans- [ReOX3(PPh3)2] (X = Cl, Br) were studied and led to the formation of ligand-bridged dimers with metal-metal multiple bonds i.e. (μ-Br)(μ-O)(μ-oa)[Re2 IVBr(OEt)2(PPh3)2], (μ-X)(μ-O)(μ-oa)[Re2 IVX2(OiPr)(PPh3)2] and (μ-Cl)(μ-O)(μ-moa)2[Re(PPh3)]2. The reaction of H2oa with [ReO2(py)4]Cl, [Re(dab)Br3(PPh3)2] (H2dab = 1,2- diaminobenzene) and [Re(CO)5Cl] were also studied and monomeric complexes [ReO(py)2(OEt)(oa)], [Re(dab)Br(oa)(PPh3)2] and (Ph4P)[Re(CO)3(H2O)(oa)] were isolated. The treatment of 5-amino-orotic acid (H2aoa) with [ReOBr3(PPh3)2] led to dimers with metal-metal triple bonds ReIV≡ReIV i.e. (μ-Br)(μ-O)(μ-oa)[Re2 IVBr(OEt)2(PPh3)2], (μ-Br)(μ-O)(μ-oa)[Re2 IVBr2(OiPr)(PPh3)2], as well as the monomer [ReV(apd)Br(aoa)(PPh3)2] (apd2− = 5-imidopyrimidine-2,4-dione). The chelating ligand 5-aminopyrimidine-2,4-dione (H2apd) was formed by oxorhenium(V)-catalysed decarboxylation of 5-amino-orotic acid (H2aoa) (see Scheme 1). The reaction of the Schiff base derivative of 5-amino-ortic acid, salicylimine-orotic acid (H2soa), with trans-[ReOI2(OEt)(PPh3)2] in ethanol was also investigated and led to the formation of the rhenium(III) complex salt [Re(coa)I(PPh3)2]I [Hcoa = 5-(2- hydroxybenzylideneamino)pyrimidine-2,4(1H,3H)-dione]. The chelating Hcoa is also formed from the oxorhenium(V)-catalysed decarboxylation of H2soa and coordinates to the rhenium(III) ion as a monoanionic tridentate N,O,O-donor chelate via the phenolate and ketonic oxygens, and the imino nitrogen atom. However, decarboxylation of H2soa was not observed in its reaction with [ReOCl3(PPh3)2], which led to the isolation of [ReOCl(soa)(PPh3)]. The reaction of the carboxamide derivative of 5-aminoorotic acid, 5-(5-aminopyrimidine-2,4(1H,3H)- dioxamido)-1,2,3,6-tetrahedro-2,6-dioxopyrimidine-4-carboxylic acid (H2ampa) with [Re(CO)5Cl] in ethanol led to the formation of a zwitterionic rhenium(I) complex [Re(CO)3(H2O)(amef)] [amef = {5-(5-ammoniumpyrimidine-2,4(1H,3H)-dioxamido)- 1,2,3,6-tetrahedro-2,6-dioxopyrimidine-4-ethylformate}]. The chelating ion amef was formed from the combined tricarbonylrhenium(I)-catalysed esterification and aminoprotonation of H2ampa (see Scheme 1) and coordinates to the fac-[Re(CO)3]+ core as a dianionic bidentate N,N-donor chelate via the amido nitrgens.
- Full Text:
- Date Issued: 2016
Rural livelihood strategies of female headed households in former Bantustans of post-apartheid South Africa: The case of Cala, Eastern Cape Province.
- Authors: Chirau, Takunda John
- Date: 2016
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3410 , http://hdl.handle.net/10962/d1021301
- Description: Communal areas in contemporary South Africa (that is, the former Bantustans of apartheid South Africa) continue to bear and endure, albeit in new forms, socio-economic and political vulnerabilities which are negatively affecting household livelihoods. Current studies on rural livelihoods have failed to keep pace in exploring and analysing the lived experiences and ever-changing challenges faced by these rural households. This thesis provides an understanding and explanation of the livelihood activities of specifically de facto and de jure female-headed households in the former Transkei Bantustan, with a specific focus on villages in Cala. This is framed analytically by feminist theories with their emphasis on systems of patriarchy and by a rural livelihoods framework. It uses a multiplicity of research methods, including focus group discussions, in-depth interviews, life histories and survey questionnaires. The major findings of the thesis show that the female-headed households in Cala depend upon agricultural-based activities and non-agriculturally-based activities and income (including social grants) but that they exist under conditions of extreme vulnerability which are subject to fluctuation. In the end, the livelihoods of female-headed households are precarious and unstable as they live under circumstances of poverty. However, the female heads are not mere passive victims of the rural crisis in post-apartheid South Africa, as they demonstrate qualities of ingenuity and resourcefulness including through a range of coping mechanisms. At the same time, rural communities continue to be marked by patriarchal norms and practices, including systems of chieftainship, which disempower women (including female heads), though this affects de jure heads and de facto heads differently. The thesis contributes to an understanding of rural livelihoods in communal areas (or former Bantustans) of present-day South Africa by way of ‘thick descriptions’ of the everyday lives of female heads in Cala. Further, in examining rural livelihoods, it highlights the importance of bringing to bear on the livelihoods framework a feminist perspective in pinpointing the additional livelihood burdens carried by rural women.
- Full Text:
- Date Issued: 2016
Scalable chemistry involving diazonium salts
- Authors: Akwi, Faith Mary
- Date: 2016
- Subjects: Azo compounds -- Synthesis , Chemical processes
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/6909 , vital:21162
- Description: Herein an alternative approach aimed at reducing the cost of numbering up technique as a scale up strategy for chemical processes from the laboratory bench top to the industry is explored. The effect of increasing channel size on the reaction conversion of the synthesis of azo compounds is investigated. This was achieved via a systematic investigative understanding of the synthesis in microreactors where a proof of concept study was performed to determine the optimum reaction parameters in azo coupling reactions involving couplers with aminated or hydroxylated groups in Little Things Factory-MS microreactors (Channel diameter: 1.0 mm) It was found that at slightly alkaline conditions (pH 8.55) and at a temperature of 25 °C, excellent conversions were attained in the azo coupling reaction of the diazonium salt solution of 2,4-dimethylaniline to 2-naphthol. On the other hand, the azo coupling reaction of the diazonium salt solution of p-nitroaniline to diphenylamine was found to thrive at a pH of 5.71 and at a temperature of 25 °C. Using, these optimized reaction parameters, the in-situ and reactive quench of diazonium salts in LTF-MS microreactors was investigated where it was found that at a flow rate of 0.2 ml/min, 0.03 ml/min and 0.07 ml/min of diazotizable amine & HCl, sodium nitrite and coupler solutions respectively, a conversion of 98% is achieved in approximately 2.4 minutes. A library of azo compounds was thus generated under these reaction conditions from couplers with aminated or hydroxylated aromatic aromatic systems. The scaled up synthesis of these compounds in a homemade PTFE tubing (ID 1.5 mm) reactor system was thereafter investigated and comparable conversions were observed. Capitalizing on the benefits of a large surface area and the short molecular diffusion distances observed in microreactors, in-situ phase transfer catalyzed azo coupling reaction of diphenylamine to p-nitroaniline was also explored. In this investigation a rapid and easy optimization protocol that yielded a 99%, 22% and 33% conversion of diphenylamine, carbazole and triphenylamine respectively in approximately 2.4 minutes using Chemtrix microreactors was established. On increasing the microreactor channel internal diameter in the scaled up synthesis approach, it was found that a 0.5 mm increase in channel internal diameter does result in lower reaction conversions.
- Full Text:
- Date Issued: 2016
Selecting and augmenting a FOSS development and deployment environment for personalized video-oriented services in a Telco context
- Authors: Shibeshi, Zelalem Sintayehu
- Date: 2016
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/943 , vital:20005
- Description: The great demand for video services on the Internet is one contributing factor that led telecom companies to search for solutions to deliver innovative video services, using the different access technologies managed by them and leveraging the capacity of enforcing Quality of Service (QoS). One part of the solution was an infrastructure that guarantees QoS for these services, in the form of the IP Multimedia Subsystem (IMS) framework. The IMS framework was developed for delivering innovative multimedia services, but IMS alone does not provide the required services. This has led to further work in the area of multimedia service architectures. One noteworthy architecture is IPTV. IPTV is more than what its name implies, as it allows the development of various innovative video-oriented services and not just tv. When IPTV was introduced, many thought that it would bring back the revenue loss that telecom companies experienced to over-the-top (OTT) service providers. However, despite all its promises, the IPTV implementation has not shown as wide an uptake as one would expect. Although there could be various reasons for the slow penetration of IPTV, one reason could be the technical challenge that IPTV poses to service developers. One of the main reasons for the embarking of the research reported in this thesis was to identify and select free and open source software (FOSS) based platforms and augment them for easy development and deployment of video-oriented services. The thesis motivated how the IPTV architecture, with some modification, can be a good architecture to develop innovative video-oriented services. For a better understanding and investigate the issues of video-oriented service development on different platforms, we followed an incremental and iterative prototyping method. As a result, various video-oriented services were first developed and implementation-related issues were analyzed. This has helped us to identify problems that service developers face, including the requirement to utilize a number of protocols to develop an IPTV-based video-oriented service and the lack of a platform that provides a consistent programming interface to implement them all. The process also helped us to identify new uses cases through the process. As part of our selection process, we found that the Mobicents service development platform can be used as the basis for a good service development and deployment environment for video-oriented services. Mobicents is a Java-based service delivery platform for quick development, deployment and management of next generation network applications. Mobicents is a good choice because it provides a consistent programming interface and supports the various protocols needed in a consistent manner or an easy way to include the support for them. We used Mobicents to compose the environment that developers can use to build video-oriented services. Specifically we developed components and service building blocks that service developer can use to develop various innovative video-oriented services. During our research, we also identified various issues with regard to support from streaming servers in general and open source streaming servers in particular and also with the protocol they use. Specifically, we identified issues with Real Time Streaming Protocol (RTSP), a protocol specified as the media control protocol in the IPTV specification, and made proposals for solving them. We developed an RSTP proxy to augment the features lacking in the current streaming servers and implemented some of the features we proposed in it.
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- Date Issued: 2016
Self-reflection practices of school-management teams in the Capricorn District : towards a reflective management strategy for South African schools
- Authors: Malatji, Khashane Stephen
- Date: 2016
- Subjects: School management teams -- South Africa Educational leadership -- South Africa School management and organization -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/3021 , vital:28238
- Description: The study investigated the self-reflection practices of School Management Teams (SMTs) in the Capricorn District. The purpose of the study was to establish self-reflective practices employed by SMT in performing their management functions, and to suggest a reflective model for the enhancement of SMT performance. The study followed the qualitative approach with a case-study research design. The population consisted of SMTs from primary, secondary and special schools. Purposive sampling was utilised to select 8 Head of Departments from less experienced to more experienced in management positions, while 9 principal and 9 deputy principals were randomly selected. Literature reviewed focused on the aims of self-reflection; the functions of SMT; the strengths and weaknesses of self-reflection; self-reflective practices and enhanced performance; models of school management; challenges in school management; and previous studies on SMT and school management. Henderson’s Ethical Model of Enquiry on reflective practice was used. The theory discusses what characterises reflective practitioners. Data was collected from quest views, individual interviews and focus group interviews. The interpretation and understanding were organised in the form of descriptive accounts. Tape-recorded interviews and data from quest views were transcribed verbatim. After transcribing data a sense of the whole was obtained by reading carefully with understanding, and then summarizing the salient aspects. Themes were identified from the responses and discussed. The study found that SMT members were not fully aware of all of their daily functions and poor reflective practices made it difficult for them to effectively fulfil their management functions. Furthermore, the study revealed that SMT members experienced challenges, such as dealing with unprofessional teachers, poor parental involvement, poor communication, poor infrastructure and lack of resources amd these impacted negatively on their performance. The study provided insights into the practice of self-reflection and how SMT members could become reflective practitioners. A new framework was suggested that SMTs should continuously and critically reflect on their management practices and decisions. The study recommends that SMT be trained and oriented about management functions prior to their appointment in the positions. The study further recommends that SMTs consider self-reflection as part of their daily activities.
- Full Text:
- Date Issued: 2016
Shifting identities: An exploration of the possibilities for a syncretic Afrikaans theatre by means of three case studies – Hex (2003), Lady Anne (2007), Ekspedisies (2008)
- Authors: Gehring, Heike
- Date: 2016
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2165 , http://hdl.handle.net/10962/d1021269
- Description: This thesis investigates the possibilities for syncretic Afrikaans language theatre within a post-1994 South African society. The research sets out to explore in what manner theatre can be language-specific, while at the same time being able to cross language contexts. This exploration is driven by the wish to develop strategies for creating Afrikaans theatre that is able to reflect on a society “united in diversity”. In this regard it is argued that for theatre to be able to both retain and cross language barriers, processes of bonding and bridging are necessary. The thesis sets out first to explain why these processes are required and then to suggest ways in which such processes can be implemented in practice. A triangular approach is used, in which conceptual and theoretical frameworks are developed to reflect on actual theatre practices. Three of my own productions are used as case studies, namely Hex (2000; 2003), Lady Anne (2007) and Ekspedisies (2008). These productions can be understood to be “boundary objects” in Henk Borgdorff’s (2012: 177) sense of the word, in that they fulfil a dual function: they are artistic productions that can also be reconstituted to serve a research purpose beyond the productions themselves. All three works were first created for public consumption before becoming cases for this thesis. Many of the strategies that were developed and tested in creating these productions are examples of ways in which bonding and bridging in Afrikaans language theatre can be understood. Chapter One of the thesis contextualises the political currents and events that necessitated the impulse towards “bonding and bridging”. In this case the political and ethical impetus behind the practical explorations has been related predominantly to the democratisation of South African society, in which a paradigm shift happened from viewing the Afrikaans language as one over many to one amongst many. Within a multilingual South Africa, concerns are raised about ways in which to create theatre in South African languages other than English (often understood to be the only possible bridging language) that are able to cross language divides. Following this introduction to language-related concerns, Chapter Two explains how the shift from apartheid to democracy made space for shifts in identity – on personal as well as institutional levels: a progression from essentialised notions of culture to the celebration of plurality. This progression is then related to theatre, with an explanation of how the post-1994 theatre landscape demanded a reimagining of the form and function of theatre. In this re-imagination the notion of a “third space” is important; something that is introduced in this chapter as an alternative to polarised identity constructions. The function of the “third space” as an in-between space and a meeting point for diverse people and entities is a strong underlying theme of this thesis and it serves as a reoccurring touchstone to the ideas put forward. Chapter Three discusses the South African arts festival culture and its contribution to the South African theatre landscape. Particular focus is placed on the Klein Karoo National Arts festival (KKNK) as a platform for the development of the Afrikaans language within a post-1994 context. What is emphasized in particular is the attempt by the KKNK festival to be linguistically and culturally exploratory and inclusive in the face of language protectionism. After the contextual background of the first three chapters, the thesis shifts to an analysis of theories related to “hybridity” and “syncretism”. In Chapter Four the argument is put forward that of the various inclusive performance and theatre models that represent a multicultural society, the most responsive forms are those that are syncretic and hybrid. Principles that can contribute to the unification and merging of diverse and polarized societal groups are described, and suggestions are made for possible ways to bring about bonding and bridging within cultural practices. Having introduced these principles, examples are offered of how these theories might be understood in other disciplines, namely, religious studies, anthropology, history and a range of cultural practices. Following this broad discussion, Chapter Five describes syncretism and hybridity more specifically in theatre by means of relevant examples. Taking the discussion further into the realm of application, Chapter Six offers an overview of “workshop theatre”, “translation” and “collage making” as strategies for putting theories of hybridity and syncretism into practice. This is followed (in Chapters Seven, Eight and Nine) by a discussion of the three productions (Hex, Lady Anne and Ekspedisies) as case studies that demonstrate how these theories can be understood in practice. Practical strategies for bridging language divides are foregrounded, such as code switching as an approach for enabling a “co-habitation” of languages; physical theatre as a means for crossing language divides; and the creation of more than one language version of a production as a tactic to accommodate shifting contexts. Following on from the discoveries made in the foregoing chapters, I conclude that theories and practices related to notions of “third space”, “hybridity” and “syncretism” are ideal for creating theatre forms (in the Afrikaans language in particular) that can truly reflect a South African society which is “united in diversity”. The thesis ends by offering suggestions for ways in which new, future identities, can be developed.
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- Date Issued: 2016
Smallholder farmer's adoption decision-making processes in the utilisation of soil conservation practices in South Africa: the case of Qamata Irrigation Scheme, in the Eastern Cape
- Authors: David, Ighodaro Ikponmwosa
- Date: 2016
- Subjects: Qamata Irrigation Scheme (South Africa) Irrigation -- South Africa -- Eastern Cape Farm management -- South Africa -- Decision making , Farms, Small -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/1740 , vital:27554
- Description: The goal of this study was to determine the nature and factors influencing smallholder farmers in their adoption decision-making regarding the use of soil conservation practices introduced by extension practitioners in South Africa, using the case of farming at Qamata Irrigation Scheme, Eastern Cape. Using a central argument (thesis statement), the study argued that an adequate understanding and definition of smallholder farmers’ adoption decision-making process is very crucial to solving the problem of soil erosion/ degradation problem amongst smallholder farmers. Adopting the case study research design, information from 70 crop farmers (in a farmer focus group interviews) form the basis of the study. Basic models of analysis were the multiple, probit and logit, as well as the binary logistic regression analyses. According to the empirical results, perception was found very relevant in adoption decision-making, interacting positively and significantly with eight of the seventeen adoption variables chosen for the study. The indication therefore is that age (p<0.050), education (p<0.0030), and marriage (p<0.036), have more potentials to improve farmers’ perception. Similarly, higher farmer incomes (from crops [p<0.017], off-farm [p<0.038] and overall [p<0.011] income) also have a likelihood to improve farmers’ perception regarding soil conservation, for improved adoption. Further indication is that farmers who are aware (p<0.015) of the soil practices introduced by extension are also those who participate in their use (p<0.041). Employing the binary logistic, probit and logit regression models, results suggest that the nature of adoption decision-making processes of smallholder farmers is complex (not straight), being influenced by multiple factors. While age (p<0.099), gender (p<0.031), total income (p<0.081) impacted positively significant on smallholder farmers’ adoption decision-making, marital status (p<0.025), sources of land (p<0.063), length of continuously farming on same piece of land (p<0.013), and level of crop production (p<0.002) impacted negatively. The indication therefore was that older farmers preferred their own practices to the recommended practices by extension, which is in line with literature. Also as expected, more females preferred their own practices to extension recommended, while more males preferred the recommended practices. Similarly, marriage, land ownership, farming continuously on a spot for a long period, as well as increase in the level of crop production, all had a propensity to influence farmers toward the adoption of extension recommended practices as against farmers’ practices. Further results indicate, that farmers’ education (p<0.032), household size (p<0.37), and income (off-farm [p<0.036] and total [p<0.004]), measures used to measure farmers’ livelihood standards in the study, were positively significant in association with adoption. The indication was that, adoption decision-making is potentially capable of improving education level of farmers; increase the size of household, thus providing easy family labour; and as well improve level of income for the farmer. Based on the foregoing, the suggestion therefore is that any technology intervention programme that will succeed must begin with a clear understanding and analysis of farmers’ adoption process. This is better achieved when the adoption process is seen as a four-stage process, where the farmer first forms a view about the innovation (perception stage), and then decides whether or not to use it (adoption stage), as well as how much of the innovation to adopt (level of adoption stage), and finally how much is this innovation going to affect my livelihood (impact of adoption stage). Also, due to the particular relevance of perception in the adoption decision-making process, technology disseminators (extension), researchers and policy makers alike must never conclude on the rejection of any technology, not until factors determining perception of individuals have been well studied. The notion here is that, even at the confirmation stage of the adoption process of an individual adopter, when a rejection is confirmed, for an example, analysing factors of the adopter’s perception at play at the particular time of the innovation in question, could go a long way to redirecting the course of the adoption process of the said individual.
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- Date Issued: 2016
Strategies for the implementation of a total quality management approach for the South African Police Service
- Authors: Wolvaard, Irene Wilhelmina
- Date: 2016
- Subjects: Total quality management in government -- South Africa Organizational effectiveness -- South Africa Police administration -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/13171 , vital:27158
- Description: This study focussed on drafting a framework for Total Quality Management (TQM) for the South African Police Service (SAPS) in the Eastern Cape as a public non-profit organisation where quality of services is fast becoming a key organisational imperative. The early pioneers of Quality laid the foundation for Total Quality Management (TQM). The literature review highlighted that TQM has its origins in the manufacturing industry where it has a proven track record, and that the theory could be purposely adapted use by a specific industry, i.e. SAPS. This study extends the applicability of the TQM theory to the SAPS by using a mixed method approach to gather information by means of interviews and questionnaires. A combination of primary and secondary data was used in determining the Critical Success Factors (CSF). The Primary CSF’s were originally identified as Leadership, Strategic Management, Empowerment of employees, Teamwork, Continuous improvement, Customer satisfaction and Culture. The Secondary factors were identified as Communication, Training, Partnership development, Support structures, Systems and Resources, Systems thinking, Selfassessment, Processes; Elimination of barriers, Adoption of a Prevention approach and Change management. Data was analysed using frequency and other means, as well as correlation analysis. After the data was analysed two CSF’s were discarded, i.e. Training and Elimination of Barriers. The results show support for the applicability of the theory to the SAPS. Critical Success Factors were determined and a framework for implementation specifically for this industry, was presented. The study identified Leadership as the most important primary factor with the ultimate goal of meeting the quality expectations as defined by the customer.
- Full Text:
- Date Issued: 2016
Structural bioinformatics studies and tool development related to drug discovery
- Authors: Hatherley, Rowan
- Date: 2016
- Subjects: Structural bioinformatics , Drug development , Natural products -- Databases , Natural products -- Biotechnology , Sequence alignment (Bioinformatics) , Malaria -- Chemotherapy , Heat shock proteins , Plasmodium falciparum
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4164 , http://hdl.handle.net/10962/d1020021
- Description: This thesis is divided into two distinct sections which can be combined under the broad umbrella of structural bioinformatics studies related to drug discovery. The first section involves the establishment of an online South African natural products database. Natural products (NPs) are chemical entities synthesised in nature and are unrivalled in their structural complexity, chemical diversity, and biological specificity, which has long made them crucial to the drug discovery process. South Africa is rich in both plant and marine biodiversity and a great deal of research has gone into isolating compounds from organisms found in this country. However, there is no official database containing this information, making it difficult to access for research purposes. This information was extracted manually from literature to create a database of South African natural products. In order to make the information accessible to the general research community, a website, named “SANCDB”, was built to enable compounds to be quickly and easily searched for and downloaded in a number of different chemical formats. The content of the database was assessed and compared to other established natural product databases. Currently, SANCDB is the only database of natural products in Africa with an online interface. The second section of the thesis was aimed at performing structural characterisation of proteins with the potential to be targeted for antimalarial drug therapy. This looked specifically at 1) The interactions between an exported heat shock protein (Hsp) from Plasmodium falciparum (P. falciparum), PfHsp70-x and various host and exported parasite J proteins, as well as 2) The interface between PfHsp90 and the heat shock organising protein (PfHop). The PfHsp70-x:J protein study provided additional insight into how these two proteins potentially interact. Analysis of the PfHsp90:PfHop also provided a structural insight into the interaction interface between these two proteins and identified residues that could be targeted due to their contribution to the stability of the Hsp90:Hop binding complex and differences between parasite and human proteins. These studies inspired the development of a homology modelling tool, which can be used to assist researchers with homology modelling, while providing them with step-by-step control over the entire process. This thesis presents the establishment of a South African NP database and the development of a homology modelling tool, inspired by protein structural studies. When combined, these two applications have the potential to contribute greatly towards in silico drug discovery research.
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- Date Issued: 2016