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Mesoscale mechanisms of larval transport and settlement in relation to physical factors off the south coast of South Africa: a topographic approach

  • Authors: Mian, Shana Iva
  • Date: 2016
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5947 , http://hdl.handle.net/10962/d1020844
  • Description: The majority of benthic marine invertebrate life cycles include a meroplanktonic phase. Most marine biologists recognise that this stage could play an important role in dispersal, especially for sedentary or sessile organisms. Recent studies on larval dispersal have found that dispersal does not occur to the extent that was previously believed. Some larvae instead remain close to their natal populations through larval nearshore retention mechanisms, both active and passive. This study attempted to a) describe nearshore distribution patterns of several intertidal larvae in relation to nearshore hydrodynamics, b) infer whether larvae are active or passive in the water column and whether this differs among taxa and c) compare pelagic mussel larval abundance with settlement rates, at 2 bay and 2 open coast sites on the south coast of South Africa to note any topographical effects. At each of the four sites, pelagic samples were collected along 2 transects. Larvae and current speed data were collected at various depths (surface, mid-depth and bottom) at distances of 200, 400, 900 and 2400m offshore of the coast. Settlement samples were collected at sites that were onshore of the pelagic transects using plastic souring pads following previous studies. Pelagic larval distribution showed no effect of topography. Instead larval abundance was highly variable among sample periods and among different taxa. Slow swimming D-stage mussel larvae were found to be positively correlated with both upwelling and turbulence indices suggesting that they behave as passive particles in the water column. The abundances of larval taxa with faster swimming speeds than the D-larvae were negatively correlated with upwelling and did not correlate with turbulence. This suggests that these larvae are more active within the water column than the D-larvae which would theoretically allow them to maintain their position in the water column. Further analysis revealed that mean larval depth correlated with mean depth of shoreward moving water masses regardless of the state of upwelling. These results suggest that larvae were actively selecting the depth at which they were found presumably in order to associate themselves with shoreward moving currents. This interpretation was supported by ontogenetic patterns in the behaviour of barnacle larvae, the nauplii of which were found further offshore as they aged, and closer onshore again once they reach the faster swimming cyprid stage. Although there was no detectable effect of topography on the abundances of planktonic larvae, the settlement section of this study revealed an effect of topography, with higher settlement and recruitment rates at bay sites than at the open coast sites. Settlement rates were seen to be negatively correlated with turbulence at bay sites but not open coast sites. Recruitment rates for each sample event were positively correlated with upwelling at each site. This study found pelagic larvae to be generally active within the water column which allowed them to remain close to the shore regardless of topography and upwelling/turbulence regimes. Although meaningful correlation analyses between pelagic larval supply and settlement rates could not be conducted due to loss of settlement collectors, settlement rates were affected by local topography with higher settlement and recruitment in bay sites.
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  • Date Issued: 2016

Photophysicochemical studies of phenylthio phthalocyanines interaction with gold nanoparticles and applications in dye sensitised solar cells and optical limiting

  • Authors: Forteath, Shaun
  • Date: 2012
  • Subjects: Phthalocyanines , Nanoparticles , Photochemistry
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:4334 , http://hdl.handle.net/10962/d1004995 , Phthalocyanines , Nanoparticles , Photochemistry
  • Description: The syntheses, spectroscopic characterisation, photophysical and photochemical studies have been conducted for a variety of phenylthio substituted phthalocyanines (Pcs). Comparisons have been made taking into consideration the influence of the central metal ion, solvent properties and substituent type. The optical limiting properties were also determined for all the Pcs synthesised. A low-symmetry metallophthalocyanine complex was similarly characterised and the photoelectrochemical parameters determined when used as a sensitiser of nanoporous ZnO. The symmetric analogue was conjugated to gold nanoparticles to determine the influence of interactions on its photophysical properties and distinct differences occurred in the absorption and fluorescence spectra suggesting successful formation of conjugates.
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  • Date Issued: 2012

Effects of ant predation on the efficacy of biological control agents Hypena Laceratalis Walker (Lepidoptera : noctuirdae) ; Falconia intermedia Distant (Hemiptera : Miridae and Teleonemia scrupulosa Stål (Hemiptera: Tingidae) on Lantana Camara (Verbenaceae) in South Africa

  • Authors: Tourle, Robyn
  • Date: 2010
  • Subjects: Lantana camara -- Biological control -- South Africa , Weeds -- Biological control -- South Africa , Biological pest control agents -- South Africa , Hemiptera -- South Africa , Miridae -- South Africa , Insect pests -- Biological control -- South Africa , Ants -- Behavior , Lepidoptera , Lace bugs , Noctuidae
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5677 , http://hdl.handle.net/10962/d1005362 , Lantana camara -- Biological control -- South Africa , Weeds -- Biological control -- South Africa , Biological pest control agents -- South Africa , Hemiptera -- South Africa , Miridae -- South Africa , Insect pests -- Biological control -- South Africa , Ants -- Behavior , Lepidoptera , Lace bugs , Noctuidae
  • Description: Lantana camara L. (Verbenaceae) remains a highly invasive and ecologically damaging weed in South Africa, despite some 50 years of biological control efforts. Lack of success has been ascribed to varietal differences, climate and predation of agents but these have not been tested. In this study, the effects of ant predation were tested on populations of three biological control agents for L. camara. Colonies of two species, Crematogaster sp. 1 and 2 were investigated. Crematogaster sp. 1 colonies were offered no choice between immature stages of the agents Hypena laceratalis Walker (Lepidoptera: Noctuidae), Falconia intermedia Distant (Hemiptera: Miridae) or Teleonemia scrupulosa Stål (Hemiptera: Tingidae) on lantana shoots. Density-dependent predation on F. intermedia and T. scrupulosa nymphs on lantana shoots was tested using Crematogaster sp. 2 colonies. In choice experiments Crematogaster sp. 2 colonies were offered F. intermedia or T. scrupulosa nymphs on potted lantana plants. Preliminary food trials confirmed that colonies foraged for protein, thereby validating results of no-choice experiments. Crematogaster sp.1 foragers removed 50% of F. intermedia nymphs, followed by 45% of H. laceratalis larvae and only 9% of T. scrupulosa nymphs. Foragers recruited most actively to H. laceratalis larvae and significantly more H. laceratalis biomass was removed than either F. intermedia or T. scrupulosa. A trade-off existed in prey size selection because larger larvae provided considerably more biomass but required forager cooperation and a longer time to subdue than did smaller prey. This increases both forager energy expense and mortality risk by other predators. This study showed that all Crematogaster sp. 1 colonies removed small (≤10mm) H. laceratalis larvae more frequently than larvae larger than 10mm. Thus, of these biological control agents, predators probably prefer small H. laceratalis larvae. Significantly more F. intermedia than T. scrupulosa nymphs were removed by Crematogaster sp. 1, while Crematogaster sp. 2 colonies removed comparable numbers of both agent species. Falconia intermedia nymphs' fast movement triggered a predatory response by these ant species. In contrast, the relatively immobile behaviour of T. scrupulosa nymphs was identified as a highly effective predator avoidance strategy. Since T. scrupulosa nymphs are unable to escape predators by moving, they appear to depend on the presence of alternative prey attracting predator attention. At high agent and/or forager density, T. scrupulosa nymphs attempted escape, but foragers identified them as prey once they moved and caught them. Predation on F. intermedia was also density dependent in that at high nymph and/or forager densities, escape routes were congested and nymphs were more easily caught. Survival of F. intermedia and T. scrupulosa nymphs in particular was low on ant-accessed shrubs in choice experiments and high on ant-excluded shrubs. It is likely that ants significantly depress F. intermedia populations in the field since besides predation, ant foragers probably interrupt F. intermedia feeding and ovipositioning. The combination of parasitism and predation on early instar larvae may explain why H. laceratalis occurs across lantana's range in South Africa but populations remain low. It is unlikely that T. scrupulosa nymphs are habitually preyed on by ant species unless they attract attention by being mobile. Although biological control of L. camara is influenced by climate and physiological defence mechanisms, this study has shown that predation by two ant species severely impacts leaf-feeding agents for L. camara. Thus, it is recommended that future selection of additional agents to control lantana should exclude leaf-feeding .
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  • Date Issued: 2010

Aspects of the ecology and management of the Soupfin shark (Galeorhinus galeus) in South Africa

  • Authors: McCord, Meaghen Erica
  • Date: 2005
  • Subjects: Soupfin shark -- South Africa , Soupfin shark -- Ecology -- South Africa , Fishery management -- South Africa , Shark fisheries -- Management -- South Africa
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5223 , http://hdl.handle.net/10962/d1005066 , Soupfin shark -- South Africa , Soupfin shark -- Ecology -- South Africa , Fishery management -- South Africa , Shark fisheries -- Management -- South Africa
  • Description: Global trends in teleost fisheries indicate significant population declines. Thus, alternative fisheries are being developed to meet the growing economic and nutritional demands of the expanding human population. Recently, it has been established that elasmobranch fisheries may fulfill these demands. As many elasmobranchs possess life-history characteristics that make them particularly vulnerable to overfishing, it is imperative to develop management strategies prior to the inception of these fisheries to ensure sustainable resource utilisation. In South Africa, elasmobranchs have been commercially exploited since the 1930s. Although generally considered an under-exploited resource, the potential for growth within these fisheries has been recognized. In 2005, the commercial shark fishery will undergo a transition from medium to long-term rights allocations. This represents an ideal opportunity for scientists and managers to develop precautionary species-specific management plans for commercially exploitable elasmobranch species. The soupfin shark (Galeorhinus galeus) is one of the principal target species in South Africa’s shark fisheries. Given its inherent susceptibility to overexploitation, G. galeus was selected as a management priority by South Africa’s regional fisheries organisation. The purpose of this study was to examine and describe the stock status of G. galeus in South Africa, and to develop a precautionary fishery management plan to ensure the sustainability of this resource. Age, growth, and mortality calculations for G. galeus were made from research survey data collected between 1996 and 1999. A small sample size precluded independent analyses of females. The maximum recorded age for G. galeus was 33 years. Estimated von Bertalanffy growth parameters from observed length-at-age for males and combined sexes were: L∞ 1542.8 mm TL, K 0.21 year⁻¹ , t₀ -2.79 year⁻¹ and L∞ 1560.3 mm TL, K 0.19 year¹, t₀ -3.03 year⁻¹, respectively. The age-at-50% maturity was determined to be 6 years, corresponding to 1011 mm TL for males and 1100 mm TL for combined sexes. Natural mortality was calculated as 0.126 yr⁻¹. The rate of instantaneous total mortality was calculated as 0.27 yr⁻¹. Catch trend analysis showed that catches and CPUE of G. galeus are increasing in the demersal longline fishery, and decreasing in the handline fishery. Decreasing catches and CPUE were observed in fishery-independent research survey data. The status of the soupfin shark stock was modelled using per-recruit analysis. The SB/R model indicated the soupfin shark is being optimally exploited and spawner biomass is at 43% of preexploitation levels. Current fishing levels ( F = 0.14 yr⁻¹) approximate the Fsb₄₀ level (F = 0.17 yr¹); thus, an increase in fishing pressure may lead to stock collapse. It was determined that the current age-at-capture (7.9 years) should be increased to 10 years, or 1420 mm TL, to maximize yield and minimize the possibility of recruitment failure. The results of this study indicate a need for immediate scientific and management intervention in South Africa’s soupfin shark fishery. An assessment report and fishery management plan for G. galeus was compiled, and several management options were proposed. These include the implementation of licence and size restrictions, as well as seasonal/area closures. The potential for an experimental gillnet fishery should be investigated.
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  • Date Issued: 2005

An overview of the early-proterozoic, auriferous Black Reef placer in the Transvaal Basin

Epithermal precious metal deposits physicochemical constraints, classification characteristics and exploration guidelines

  • Authors: McIver, Donald A
  • Date: 1997
  • Subjects: Precious metals , Geothermal resources
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:4941 , http://hdl.handle.net/10962/d1005553 , Precious metals , Geothermal resources
  • Description: Epithermal deposits include a broad range of precious metal, base metal, mercury, and stibnite deposits. These deposits exhibit a low temperature of formation (180-280°C) at pressures of less than a few hundred bars (equivalent to depths of 1.5 - 2.0lkm). Epithermal gold deposits are the product of large-scale hydrothermal systems which mostly occur in convergent plate margin settings. Associated volcanism is largely of andesitic arc (calcalkaline to alkaline), or rhyolitic back-arc type. Porphyry Cu-Mo-Au deposits form deeper in the same systems. Genetic processes within individual deposits take place in an extremely complex manner. The resultant mineral associations, alteration styles and metal deposition patterns are even more complicated. Many attempts have been made to classify epithermal deposits based on mineralogy and alteration, host rocks, deposit form, genetic models, and standard deposits. For the explorationist, the most useful classification schemes should be brief, simple, descriptive, observationally based, and informative. Ultimately, two distinct styles of epithermal gold deposits are readily recognised: high-sulphidation, acid sulphate and low-sulphidation, adularia-sericite types. The terms high-sulphidation (HS) and low-sulphidation (IS) are based on the sulphidation state of associated sulphide minerals, which, along with characteristic hydrothermal alteration, reflect fundamental chemical differences in the epithermal environment. Highsulphidation-type deposits form in the root zones of volcanic domes from acid waters that contain residual magmatic volatiles. The low-sulphidation-type deposits form in geothermal systems where surficial waters mix with deeper, heated saline waters in a lateral flow regime, where neutral to weakly acidic, alkali chloride waters are dominant. The HSILS classification, combined with a simple description of the form of the deposit, conveys a large amount of information on mineralogy, alteration, and spatial characteristics of the mineralisation, and allows inferences to be drawn regarding likely regional controls, and the characteristics of the ore-forming fluids. The modern understanding of these environments allows us to quite effectively identify the most probable foci of mineral deposition in any given district. Current knowledge of these deposits has been derived from studies of active geothermal systems. Through comparison with alteration zones within these systems, the exploration geologist may determine the potential distribution and types of ore in a fossil geothermal system. Alteration zoning specifically can be used as a guide towards the most prospective part of the system. Epithermal gold deposits of both HS- and LS-styles are nevertheless profoundly difficult exploration targets. Successful exploration must rely on the integration of a variety of exploration techniques, guided by an understanding of the characteristics of the deposits and the processes that form them. There are no simple formulae for success in epithermal exploration: what works best must be determined for each terrain and each prospect. On a regional scale tectonic, igneous and structural settings can be used, together with assessment of the depth of erosion, to select areas for project area scale exploration. Integrated geological-geophysical interpretation derived from airborne geophysics providesa basis of targeting potential ore environments for follow-up. Geology, geochemistry and surface geophysics localise mineral concentrations within these target areas
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  • Date Issued: 1997

Basin analysis and sequence stratigraphy a review, with a short account of its applicability and utility for the exploration of auriferous placers in the Witwatersrand Basin

  • Authors: Van Eeden, Johan
  • Date: 1996
  • Subjects: Geology, Stratigraphic , Sedimentary basins -- South Africa , Placer deposits -- South Africa
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:4934 , http://hdl.handle.net/10962/d1005546 , Geology, Stratigraphic , Sedimentary basins -- South Africa , Placer deposits -- South Africa
  • Description: The Witwatersrand basin is unique in terms of its mineral wealth. The gold in the Witwatersrand basin is mainly concentrated in the placers and two types of unconformities are associated with the placer formation. This paper attempts to quantitatively describe the origin and depositional process of placers within the context of basin analysis, geohistory and sequences stratigraphic framework. Several tectonic models have been proposed for the evolution of the Witwater~rand basin and it seems as if a cratonic foreland basin accounts for many of the observed features observed the Central Rand Group basin. The tectonic subsidence curve generated for the Witwatersrand Basin clearly implies foreland basin response which was superimposed an older, deep seated extensional basin. These compressive tectonics can be superimposed on extensional basins, where the shift from extensional to compressional tectonics lead to inversion processes. The critical issues about the Witwatersrand basin which were addresed in this review, is the validity of basin wide correlation of placer unconformuties and whether sequence stratigraphy is applicable to fluvial systems of the Witwatersrand sequence. It is believed that the Central Rand Group was deposited as alluvial - fan deltas by fluvially dominated, braidplain systems with minor marine interaction which had a considerable impact on the preservation of economically viable placers. Most important to the exploration geologist is the recognition of stacking patterns of the fluvial strata to determine change in the rate at which accommodation was created. Identifying sequence boundaries and other relevant surfaces important for identifying these stacking patterns of the sequences, depends entirely on the recognition of a hierarchy of stratal units including beds, bedsets, parasequences, parasequence sets and the surfaces bounding sequences. Placers are closely associated with the development of disconformities and therefore become important to recognise in fluvial strata. If these placers are to become economic, the duration of subaerial exposure of the unconformities that allowed the placers to become reworked and concentrated must be determined. In order to preserve the placer, a sudden marine transgression is necessary to allow for minimal shoreline reworking and to cap the placer to prevent it from being dispersed. The placers in the Witwatersrand basin occur in four major gold-bearing placer zones in the Central Rand Group. Accordingly they can be assigned to four supercycles, which are cyclical and therefore predictive. It is the predictive nature of these rocks and the ability of sequence stratigraphy to enhance this aspect, which is a pre-requisite for an effective exploration tool in the search for new ore bodies or their extension in the Witwatersrand basin.
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  • Date Issued: 1996

Synthetic and mechanistic studies of heterocyclic systems

  • Authors: Deane, Philip O'Grady
  • Date: 1996
  • Subjects: Heterocyclic chemistry
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:4379 , http://hdl.handle.net/10962/d1005044 , Heterocyclic chemistry
  • Description: A series of acrylate esters and selected analogues have been reacted with pyridine-2-,pyridine-3-, and pyridine-4-carboxaldehydes in the presence of diazabicyclo[2,2,2]octane (DARCO) to afford a range of Baylis-Hillman products. The pyridine-2-carboxaldehyde-derived products have been acetylated using acetic anhydride and the kinetics of the thermal cyclisation of the acetylated compounds to indolizines was investigated using proton NMR spectroscopy. The first-order kinetics of the cyclisation has been confirmed and the influence of substituents on the first-order rate constant, kₒbs has been examined. The kinetic data has been shown to be consistent with the previously proposed mechanism in which loss of the acetate group is ratedetermining. Each of the cyclisations was also monitored at three different temperatures permitting evaluation of the activation parameters. The Baylis-Hillman products and related acetylated derivatives were treated at room temperature with sodium methylthiolate; the hydroxy precursors were observed to undergo conjugate addition with a degree of diastereocontrol but the acetylated derivatives favoured an apparent SN¹ displacement of the acetate group.
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  • Date Issued: 1996

Synthesis and conformational studies of indolizines

  • Authors: George, Rosemary
  • Date: 1994
  • Subjects: Indole alkaloids -- Research , Organic compounds -- Synthesis , Chemistry, Organic
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:4367 , http://hdl.handle.net/10962/d1005032 , Indole alkaloids -- Research , Organic compounds -- Synthesis , Chemistry, Organic
  • Description: The present investigation has involved a kinetic and mechanistic study of the thermal cyclization of 3-acetoxy-3-(2-pyridyl)-2-methylenepropanoate esters and related compounds to 2-substituted indolizines. Substrates for the kinetic study were prepared via the Baylis-Hillmann reaction of pyridine-2-carboxaldehydes with acrylate esters, acrylonitrile and methyl vinyl ketone. The resulting hydroxy compounds were then acetylated to afford the acetoxy derivatives, thermal cyclization of which gave the corresponding 2-substituted indolizines. The cyclization reactions was followed using 'H NMR spectroscopy and were shown to follow firstorder kinetics. The influence of the various substituents on the observed first-order rate constants has been examined and variable temperature studies have permitted evaluation of activation parameters for the formation of methyl indolizine-2-carboxylate and ethyl indolizine-2-carboxylate. An alternative route to 2-substituted indolizines via halogenated derivatives was explored and several halogenated 2-pyridyl derivatives were synthesised and their thermal cyclization to indolizines was attempted. Novel 5-methylindolizine-2-carboxamides were prepared as part of this investigation and dynamic NMR spectroscopy was used to study internal rotation about the amide N-CO bond in these compounds.
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  • Date Issued: 1994

An assessment of the South African longline fishery with emphasis on stock integrity of kingklip, Genypterus capensis (Pisces : ophidiidae)

  • Authors: Japp, David William
  • Date: 1989
  • Subjects: Genypterus capensis , Ophidiidae , Fisheries -- South Africa , Longlining (Fisheries) -- South Africa
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5209 , http://hdl.handle.net/10962/d1004660 , Genypterus capensis , Ophidiidae , Fisheries -- South Africa , Longlining (Fisheries) -- South Africa
  • Description: The South African demersal longline experiment is assessed with emphasis on the target species, kingklip Genypterus capensis. The hypothesis that kingklip on the South African coast comprise a unit stock is tested. Recommendations for the management of the fishery are made. Longlining was found to be commercially viable. Techniques have been developed to target on either kingklip or the Cape hakes, Herluccius capensis and H. paradoxus. Longline fishermen exploit the kingklip spawner stock from August to No v ember by taking advantage of prespawning aggregations on the South-East Coast . Effort switches to the West Coast in late summer and early winter where kingklip are less abundant and a larger proportion of hake is caught. Catch rates of kingklip on the South Coast have declined sharply and the resource there has been exploited at a rate greater than that required to retain 50% of the unexploited biomass . There is a 17,6% probability that the spawner biomass on the South Coast has already been depleted below its pristine level. On the West Coast the catch rates of kingklip are lower than on the South Coast and have not changed significantly, although within the 95% confidence limits there is a possibility that the resource there has also been depleted below 50% of its pristine level. Genypterus capensis on the South African coast comprise a unit stock. Comparison of kingklip morphology using multivariate and discriminant function analysis and of otolith morphology using univariate statistics shows that there are no significant differences between the fish on the West and South Coasts. They are a slow growing species and were aged up to 25 years. Kingklip on the West Coast are smaller and have a lower L~ than those on the South Coast, but this is not a characteristic of discrete stocks. Kingklip on the South Coast mature earlier than those on the West Coast and aggregate to spawn on the South - East Coast in spring. There is no obvious spawning period on the West Coast. It is hypothesized that kingklip spawning on the South-East Coast is in response to favourable environmental conditions that enhances the survival of their eggs and larvae. It is recommended that demersal longlining be established as a permanent kingklip-directed fishery but that effort should not be allowed to increase. The West and South Coasts should be managed .separately. A TAC of 5 OOOt for kingklip should be introduced for 1989 of which 2 OOOt should be allocated to the West Coast and 3 OOOt to the South Coast . A closed season for kingklip from 1 August to 30 September on the South-East Coast is recommended. Hake-directed longlining should not be allowed as its effect on the hake spawner stocks are unknown and could be a potential threat to the stability of the demersal trawl fishery.
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  • Date Issued: 1989

Instability in the magnetotail

  • Authors: English, Daniel Rowe
  • Date: 1977
  • Subjects: Magnetotails
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5425 , http://hdl.handle.net/10962/d1011764 , Magnetotails
  • Description: The magnetic induction field due to the Earth only would, if undisturbed by any outside agency, resemble macroscopically the field due to a magnetic dipole. Hcwever the field is disturbed by the interplanetary magnetic field, of which the most important component is that of the Sun. If the Sun's magnetic field were effectively steady, it would also be a dipole field, and approximately constant in the region within about twenty earth radii from the earth. Also, if we treat the Sun as a dipole, its dipole axis is roughly normal to the ecliptic plane. The Earth, treated as a dipole, has an axis which is inclined to the normal to the ecliptic plane at an angle which varies daily from a few degrees to nearly a third of a right angle. However, in this paper, it is proposed to treat both dipole axes as contra-parallel and effectively normal to the ecliptic plane, so that a general idea of the combined field can be obtained. Then the effect of a steady field due to the Sun, on the Earth's field would be the formation of a "neutral ring" surrounding the Earth; that is, a closed "neutral line", this being a line of points at each of which the net nagnetic induction is zero. As the point of observation passes through this line, the field changes direction. Intro. p. v.
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  • Date Issued: 1977

An investigation of the equivalent circuit of a conductivity cell

  • Authors: Allison, Francis Sutton
  • Date: 1954
  • Subjects: Electrolytic cells
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:4508 , http://hdl.handle.net/10962/d1013376
  • Description: ( i) A linear circuit is shown not to explain the behaviour of a conductivity cell towards a long rectangular pulse of amplitude less than the decomposition potential of the solution in the cell. (ii) It is shown that the flow of current through the cell is governed by diffusion to the electrode. The diffusion current expression is the familiar one used in the case of diffusion up to a plane micro-electrode, except that in this case the concentration in the layer next to the electrode is not zero, but only somewhat less than the bulk concentration. (iii) Except during a short initial period (less than 10 seconds), the resistance of the electrolytic cell varies directly with the square root of the time for which an e.m.f. (less than the decomposition potential) is applied to the cell, and inversely with the concentration difference between the electrode surface and the bulk of the solution.
  • Full Text:
  • Date Issued: 1954
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