Controls on the distribution of manganese in banded iron-formations (BIF) of the palaeoproterozoic transvaal supergroup, South Africa
- Authors: Fryer, Lindi
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/2926 , vital:20343
- Description: The 2.65 to 2.05 Ga Transvaal Supergroup comprises one of the best-preserved and largely continuous successions in the world of Banded Iron-Formation (BIF), a chemical sedimentary rock composed of fine (mm to cm scale) interbanded iron-rich and iron-poor bands, developed atop the Archaean Kaapvaal Craton of southern Africa. The Transvaal BIF sequence contains at its upper stratigraphic part, an intriguing interlayered BIF-Mn association, namely the Hotazel Formation in the Kalahari Manganese Field, which constitutes the largest land-based manganese deposit on record. The genesis of the Hotazel deposits, and their exact significance in terms of atmosphere-hydrosphere-biosphere evolution, remain as elusive as they are challenging. In this thesis, an attempt is made to illuminate the origin and diagenesis of the Hotazel Formation and its post-depositional hydrothermal modification, through a highresolution geochemical study of the narrowest of the three BIF-Mn sedimentary cycles present in the Hotazel stratigraphy. This approach is coupled with a preliminary geochemical study of the distribution of Mn in older BIF of the Transvaal Supergroup as well (Kuruman and Griquatown Formations), so as to test recent models that causally link all BIFs in the Transvaal Supergroup under a common and evolving palaeo-environment of deposition. The results indicate that the cyclic deposition of the Hotazel BIF and enveloped Mn-rich sediments would have taken place in a stratified basin with a well-developed chemocline in terms of the vertical distributions of Mn and Fe, much like recent anoxic stratified basins such as the Orca Basin in the Gulf of Mexico. The increased Mn abundances as Mn-bearing ferrous carbonates in the upper part of the Griquatown BIF predating the Hotazel strata, also seems to lend support to the notion that the two BIFs are temporally interlinked as part of a broader sedimentary continuum. Finally, the largely conservative behaviour of Mn and associated elements during hydrothermal alteration of the Hotazel rocks is re-assessed, and renewed emphasis is placed on the possibility that brine metasomatism may have been a key factor in Mn redistribution and residual enrichment.
- Full Text:
- Date Issued: 2016
- Authors: Fryer, Lindi
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/2926 , vital:20343
- Description: The 2.65 to 2.05 Ga Transvaal Supergroup comprises one of the best-preserved and largely continuous successions in the world of Banded Iron-Formation (BIF), a chemical sedimentary rock composed of fine (mm to cm scale) interbanded iron-rich and iron-poor bands, developed atop the Archaean Kaapvaal Craton of southern Africa. The Transvaal BIF sequence contains at its upper stratigraphic part, an intriguing interlayered BIF-Mn association, namely the Hotazel Formation in the Kalahari Manganese Field, which constitutes the largest land-based manganese deposit on record. The genesis of the Hotazel deposits, and their exact significance in terms of atmosphere-hydrosphere-biosphere evolution, remain as elusive as they are challenging. In this thesis, an attempt is made to illuminate the origin and diagenesis of the Hotazel Formation and its post-depositional hydrothermal modification, through a highresolution geochemical study of the narrowest of the three BIF-Mn sedimentary cycles present in the Hotazel stratigraphy. This approach is coupled with a preliminary geochemical study of the distribution of Mn in older BIF of the Transvaal Supergroup as well (Kuruman and Griquatown Formations), so as to test recent models that causally link all BIFs in the Transvaal Supergroup under a common and evolving palaeo-environment of deposition. The results indicate that the cyclic deposition of the Hotazel BIF and enveloped Mn-rich sediments would have taken place in a stratified basin with a well-developed chemocline in terms of the vertical distributions of Mn and Fe, much like recent anoxic stratified basins such as the Orca Basin in the Gulf of Mexico. The increased Mn abundances as Mn-bearing ferrous carbonates in the upper part of the Griquatown BIF predating the Hotazel strata, also seems to lend support to the notion that the two BIFs are temporally interlinked as part of a broader sedimentary continuum. Finally, the largely conservative behaviour of Mn and associated elements during hydrothermal alteration of the Hotazel rocks is re-assessed, and renewed emphasis is placed on the possibility that brine metasomatism may have been a key factor in Mn redistribution and residual enrichment.
- Full Text:
- Date Issued: 2016
The application of GIS and remote sensing to assess the effect of periodic flooding on communities along the Juskeiriver: A case study of Alexandria Township, Johannesburg, South Africa
- Authors: Mawasha, Tshepo Sylvester
- Date: 2016
- Subjects: Remote sensing Geographic information systems -- South Africa , Remote sensing
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/45613 , vital:38918
- Description: Floods are water induced disasters that led to temporary induction of dry and cause serious damages in the affected location such as loss of valuable assets, lives and destruction of infrastructure. Flooding had become common in Alexandra Township during rainfall season and the recorded impact of periodic flooding on communities is increasing at an alarming rate. This study seeks to identify populations vulnerable to flooding and to map-out areas at high risk of flood disasters, using GIS and RS as a tool. For GIS application different types of maps were produced, namely, flood vulnerability, hazards, risk and risk index map highlighting areas at risk of being affected by flooding. Flood risk index maps identify three categories of risk zones; low and high risk zone. The household units within each of the risk zones was calculated and the total was estimated to be 762 for low-risk and 32 486 for high risk zone. The SRTM Digital Elevation Model (DEM) and multi-temporal Satellite Probatoire d’Observation de la Terra (SPOT) satellite images for 1997, 2006 and 2013 of the area was used for land-use and land-cover (LULC) change analyses using maximum-likelihood post-classification comparison. Results reveal that tremendous urban development had taken place in the study area along the Jukskei River area for the past sixteen years. It was observed that there was a sharp decrease in vegetation from 237ha (1997) to 134ha (2006) to 68ha (2013). This may had a negative impact on the environment around this area by decreasing surface runoff. The trend however, shows that bare surface and vegetation land-cover class has no potential to recover. Questionnaires aimed at all the residents in the study area were used to assess the effect of periodic flooding on communities. Community leader and City of Johannesburg Disaster Management Unit (CoJDMU) interviews were also conducted to get more insight about floods management in the study area. Finally, strategies for alleviating flood risk in the study area were discussed and some recommendations were made to help the government and municipal authorities to improve and development sustainable flood mitigation measures.
- Full Text:
- Date Issued: 2016
- Authors: Mawasha, Tshepo Sylvester
- Date: 2016
- Subjects: Remote sensing Geographic information systems -- South Africa , Remote sensing
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/45613 , vital:38918
- Description: Floods are water induced disasters that led to temporary induction of dry and cause serious damages in the affected location such as loss of valuable assets, lives and destruction of infrastructure. Flooding had become common in Alexandra Township during rainfall season and the recorded impact of periodic flooding on communities is increasing at an alarming rate. This study seeks to identify populations vulnerable to flooding and to map-out areas at high risk of flood disasters, using GIS and RS as a tool. For GIS application different types of maps were produced, namely, flood vulnerability, hazards, risk and risk index map highlighting areas at risk of being affected by flooding. Flood risk index maps identify three categories of risk zones; low and high risk zone. The household units within each of the risk zones was calculated and the total was estimated to be 762 for low-risk and 32 486 for high risk zone. The SRTM Digital Elevation Model (DEM) and multi-temporal Satellite Probatoire d’Observation de la Terra (SPOT) satellite images for 1997, 2006 and 2013 of the area was used for land-use and land-cover (LULC) change analyses using maximum-likelihood post-classification comparison. Results reveal that tremendous urban development had taken place in the study area along the Jukskei River area for the past sixteen years. It was observed that there was a sharp decrease in vegetation from 237ha (1997) to 134ha (2006) to 68ha (2013). This may had a negative impact on the environment around this area by decreasing surface runoff. The trend however, shows that bare surface and vegetation land-cover class has no potential to recover. Questionnaires aimed at all the residents in the study area were used to assess the effect of periodic flooding on communities. Community leader and City of Johannesburg Disaster Management Unit (CoJDMU) interviews were also conducted to get more insight about floods management in the study area. Finally, strategies for alleviating flood risk in the study area were discussed and some recommendations were made to help the government and municipal authorities to improve and development sustainable flood mitigation measures.
- Full Text:
- Date Issued: 2016
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