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Mineralogy, geochemistry and pebble morphology of the Katberg Formation around Graaff Reinet and East London, Eastern Cape province of South Africa

  • Authors: Ndlazi, Nondumiso Zandile
  • Date: 2020
  • Subjects: Mineralogy|
  • Language: English
  • Type: Thesis , Masters , MSc (Geology)
  • Identifier: http://hdl.handle.net/10353/18631 , vital:42615
  • Description: The Katberg Formation forms the upper part of the Tarkastad Subgroup in the Beaufort Group of the main Karoo Supergroup. The Katberg Formation consists of siliciclastic sedimentary rocks mostly dominated by greyish sandstone, red mudstone with minor siltstone occurrences. The Katberg Formation also consists of calcareous and ferruginous concretions that formed during diagenesis. Braided streams deposited the Katberg Formation with a predominantly sand bed load. The Katberg Formation sandstones contain pebbles with no true conglomerates identified in the study area. This study was conducted in the Katberg Formation to understand the mineralogy, geochemistry, and pebble morphology around Graaff Reinet and East London areas. The major and trace elements were analyzed through X-Ray Fluorescence (XRF) to deduce the source rock provenance, tectonic setting, paleo-weathering conditions, climatic conditions, and sediment maturity. The X-Ray Diffraction (XRD) was used to highlight a detailed distribution and variation of mineralogical polymorphs of the minerals present in sandstones and mudstones. The pebble morphology was used to confirm the depositional environment of the Katberg Formation. The use of The bivariate plots of the Maximum Projection Sphericity Index (MPSI) and the Oblate-Prolate Index (OPI) showed that 79 % of pebbles fall in the fluvial environment, whereas 21 % of pebbles fall in the beach environment. A small proportion of beach pebbles within the Katberg Formation suggests that the river reached the marginal marine environment during its flow. The majority of the pebbles yielded a bladed shape with a dominating Sphericity Index symptomatic of fluvial sediments. All the bivariate plots illustrate the fluvial depositional environment for the sediments of the Katberg Formation. Petrographic studies based on the prepared 15 thin sections indicated that the Katberg Formation rocks are dominated by quartz, feldspar, and clay minerals. However, they show more plagioclase feldspar than k-feldspars. The grains are poorly sorted and immature, with irregular grain sizes and shapes. The angularity of clasts indicates that the grains have travelled shorter distances. The abundance of feldspar minerals suggests that the arkose sandstone was derived either from situ or from a short distance. The albitization of plagioclase to illite and the replacement of plagioclase feldspars by calcite and laumontite is very common in the Katberg Formation, which points out deep burial diagenesis. The XRD analysis revealed the occurrence of 14 minerals in the siliciclastic rocks of the Katberg Formation, namely: quartz, albite, clinochlore, muscovite, phlogopite, annite, illite, orthoclase, anorthoclase, laumontite, calcite, and ankerite. Amongst these minerals, albite, clinochlore, muscovite, and phlogopite show variation in crystal forms known as polymorphs. Geochemical analysis of the Katberg Formation sandstones and mudrocks revealed that all samples show a high concentration of SiO2, Al2O3, Fe2O3, K2O, Na2O, CaO, and MgO. The trace elements: TiO2, MnO, P2O5, BaO, SrO, ZrO2, and V2O5 are depleted with values ranging below 1 wt %. The geochemical classification of the Katberg Formation sandstones revealed the origin from wacke and arkose sources. The geochemical diagrams and indices of paleoweathering conditions suggested that the Katberg Formation underwent a moderate degree of chemical weathering. The geochemistry revealed that the sediments were 4 Final Submission of Thesis, Dissertation or Research Report/Project, Conference or Exam Paper deposited during the arid climate conditions. The studied sandstone and mudstone samples pointed an active continental margin and passive margin tectonic setting of the Katberg Formation.
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  • Date Issued: 2020

Social Media as Human Rights Watchdog: A critical Analysis of Facebook and WhatsApp use by Citizens and Civil Society Groups in the Run-up to the 2018 Elections in Zimbabwe

  • Authors: Mututwa, Wishes.T
  • Date: 2019
  • Subjects: Social media Online social networks
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: http://hdl.handle.net/10353/15837 , vital:40531
  • Description: This study analysed the use of social media platforms, WhatsApp and Facebook in monitoring human rights ahead of Zimbabwe’s 2018 Harmonised elections. Zimbabwe has witnessed gross human rights violations since the attainment of independence in 1980 but most of these violations have been misrepresented, partially captured or ignored particularly by the partisan state media. While issues of human rights have been researched on, there has been a gap in research on the role of social media in safeguarding human rights in Zimbabwe, particularly during election times. There has also been a gap in research about the influences of social media, not just to inspire revolutions but to strengthen democratic practices in Zimbabwe through vibrant discussions of human rights issues on social media platforms. This study was informed by Habermas Theory of public sphere and Social network theory in order to analyse texts shared and discussed on WhatsApp and Facebook about human rights committed ahead of 2018 Harmonised elections. The aim was to establish use of social media as watchdog of human rights. A qualitative content analysis was applied to study texts shared on WhatsApp and Facebook about human rights violations across the country. Three WhatsApp groups and seven Facebook pages were selected for the study from which posts and responses from participants were extracted for analysis. The findings of the study revealed that social media can effectively strengthen democratic practices by exposing government’s unconstitutional practices. Further, social media can be useful in offering ordinary citizens a platform for engagement with civic society as they discuss issues that affect them. The findings of the study also hold the state accountable for the majority of human rights abuses committed throughout the election campaign period. The study then recommended that the government of Zimbabwe should go back to constitutionalism and abide by international human rights treaties to which they are signatory. Further, the study recommended that Zimbabwe Human Rights Commission and other independent commissions be empowered so that human rights are fully enjoyed in Zimbabwe, not just during election campaign periods but all the time
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  • Date Issued: 2019

The use of textbooks by teachers in teaching mathematics at selected primary schools in East London education district

  • Authors: Adu, K.O.
  • Date: 2018
  • Subjects: Mathematics -- Textbooks Mathematics -- Study and teaching (Primary)
  • Language: English
  • Type: Thesis , Masters , MEd.
  • Identifier: http://hdl.handle.net/10353/8989 , vital:34180
  • Description: Mathematics is the foundation for the economic and technological development of any nation. It has been asserted that Mathematics is expected to help in accelerating social, economic and technological progress of any society. The Primary school level is very important in any educational system and any lack at this level would permeate to other levels of the educational system. Hence, this dissertation examines the use of textbooks by teachers in teaching Mathematics at selected primary schools in East London Education district. The study adopted the interpretivist paradigm and employed the qualitative approach in investigating the phenomenon. The dissertation made use of phenomenology research design as it attempted to understand people’s (learners’ and teachers’) perceptions, perspectives and understandings of the use of textbooks in teaching Mathematics. Semi-structured interviews and observation were used to elicit information from the six mathematics teachers and three heads of department who were purposively selected. The data collected were analysed using thematic approach where themes were developed from the research questions after transcribing, sorting and categorizing them. The findings of the study demonstrated that the participants selected textbooks from the ones prescribed by the department that were written in the CAPS documents. They had no influence or decision on textbook selection. All the teachers believed that lesson plan is very important and it is a must to have a very detailed and comprehensive lesson plan that is well-aligned to the contents of CAPS document and the textbook. The study further revealed that, for effective delivery of lesson and planning, there is need for a practical use of textbooks by the teacher. The study concluded that one of the most fundamental issues to consider is the fact that, as good as the use of textbook for planning and delivery of lesson activities is, it can also be a problem if not carefully and professionally planned and used accordingly. The over-dependence on textbooks at the expense of other resources may cause ineffective learning and teaching of mathematics.
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  • Date Issued: 2018

Ruthenium sulphide nanoparticles derived from tri-dithiocarbamato ruthenium (III) complexes : synthesis, optical and structural studies

  • Authors: Mbese, Johannes Zanoxolo
  • Date: 2017
  • Subjects: Nanoparticles Ruthenium compounds
  • Language: English
  • Type: Thesis , Doctoral , DPhil
  • Identifier: http://hdl.handle.net/10353/15420 , vital:40406
  • Description: The present Thesis pioneer the application of single-source molecular precursor method for the synthesis of ruthenium sulfide nanoparticles using a series of novel self-prepared single-source molecular precursors. The preparation of precursors involved the design and synthesis of compounds containing all the desired elements required within the coordination compound. Good precursors are tailored to give reproducible, clean decomposition at moderate temperatures, leading to high quality, defect free, mono-dispersed nanoparticles. Nine (9) homonuclear tris-dithiocarbamato ruthenium(III) complexes, [Ru(S2CNR2)3] were prepared from a stoichiometric reaction of RuCl3·H2O with self-prepared dithiocarbamate ligands at room temperature in a molar ratio of Ru3+: Ligand of 1:3. Dithiocarbamate ligands were derived from a stoichiometric reaction of carbon disulfide with (aniline, N-allylmethylamine, p-toluidine, p-anisidine, N-ethyl-m-toluidine, piperidine, morpholine, di-isopropylamine, and diallylamine) in the presence of concentrated ammonia or potassium hydroxide in ice cold bath. The dithiocarbamate ligands and complexes were characterized by elemental analyses, UV-Vis, Fourier transform infrared spectroscopy (FTIR), 1H- and 13C-NMR spectroscopy. Thermogravimetric analyses (TGA) was used to study the decomposition profiles of the precursor complexes. The results obtained from the TGA of precursors showed that the complexes decompose to ruthenium sulfide nanoparticles. The FTIR spectra of the ligands revealed prominent strong absorption bands ascribed to v(N-H) stretching vibrations and also confirm the bidentate coordination of the dithiocarbamate ligands. Ruthenium(III) complexes show absorption spectra in the visible region that exhibit bands attributed to n → π* electronic transitions located on the sulfur atoms located in the S–C–S and N–C–S chromophores of the bidentate dithiocarbamate ligands respectively. The absorption spectra also confirmed the geometry of ruthenium(III) complexes to be octahedral. The proposed structures of dithiocarbamate ligands and ruthenium(III) complexes were confirmed by the 1H- and 13C-NMR. The complexes were used as single-source molecular precursors for the synthesis of ruthenium sulfide nanoparticles. The structural and optical properties were studied using transmission electron microscope (TEM), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS), UV-Vis absorption and photoluminescence (PL) spectra. FTIR revealed that Ru2S3 nanoparticles are capped through the interaction of the –NH2 group of hexadecylamine HDA adsorbed on the surfaces of nanoparticles and it also showed that oleic acid (OA) is acting as both coordinating stabilizing surfactant and capping agent. The XRD confirmed the successful formation of Ru2S3 nanoparticles induced by the thermal decomposition of series of [Ru(S2CNR2)3] complexes. The diffraction peaks: 2θ = 29.43, 40.54, 49.33, 51.86, 61.92, and 75.94 were assign the Miler indices (hkl) to be (111), (211), (220), (300), (222) and (330) reflections, respectively, and were found to be in agreement with a cubic crystal structure reported in database file of (JCPDS 19-1107). The particle sizes estimated from Scherer's equation were found in a range between 2.5 and 4.9 nm. EDS spectra reveal that the prepared nanoparticles are mainly composed of Ru and S, confirming the presence of Ru2S3 nanoparticles in cubic phase. The inner morphology of nanoparticles was obtained by transmission electron microscopy (TEM) and most nanoparticles had narrow particle size distribution characterized by an average diameter of 8.45 nm with a standard deviation of 1.6 nm. The optical band gap (Eg) determined from Tauc plot was found in the range (3.44 to 4.18 eV) values.
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  • Date Issued: 2017

Fathers' involvement in the social development of children under six years: a social capital perspective and implications for early childhood development in the East London Education District

  • Authors: Adams, Clyde Glenith Graham
  • Date: 2016
  • Subjects: Child development-- South Africa -- Eastern Cape Father and child -- South Africa -- Eastern Cape Fatherhood -- South Africa -- Eastern Cape
  • Language: English
  • Type: Thesis , Doctoral , Degree
  • Identifier: http://hdl.handle.net/10353/5116 , vital:29077
  • Description: The experiences of twenty fathers were explored to understand the involvement in the social development of children under six years. The main research question that guided the study was: what are fathers’ experiences with involvement in the social development of their children under the age of six years and what implications do these have for early childhood development? A social capital perspective was followed. The qualitative data was collected through the use of semi-structured interviews. The data was then analysed qualitatively. Results show that although most of the respondents could not give a definition of the concept of social development, they, however, understood the importance of parents playing a role in the development of a child. Fathers understood their role as supportive, nurturing and being there for their children. Fathers also understood their basic role as being the provider and protector. They also perceived their role as being authoritative and see themselves as the main disciplinarians. Results reveal that most schools do not offer programs specifically designed to encourage fathers to participate. Most importantly, results indicate that fathers’ interest in a variety of sporting activities, information sharing and talking about challenges both the schools as well as fathers face, are some of the ways fathers would like to be involved. Findings also indicate that although fathers acknowledged the role of the Department of Basic Education (DoBE) as mainly that of financial contributor in order to facilitate the skills development as well as that of information dissemination. However, fathers who took part in the study did not understand how the DoBE skills development agenda is envisaged for fathers. Notwithstanding, the respondents were quite clear that a father has an influential role to play in their children’s development. It also emerged that the greater the involvement, the more positive the influence on the child’s development. This study concludes that the presence of fathers in children’s lives is known to contribute significantly to their chances of experiencing positive developmental outcomes. Although the father-child relationship’s influences on children’s social competence have received increased attention in general, research on fathers’ understanding of their roles, involvement with their children as well as challenges confronting them with their involvement is scant. Based this the above, a number of recommendations have been made.
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  • Date Issued: 2016

An exploration of the structural, cultural and agential conditions that shape life skills teachers' responses and experiences in teaching sexuality and HIV and AIDS

  • Authors: Hakaala, Beatha Ndinelao
  • Date: 2015
  • Subjects: Life skills -- Study and teaching (Secondary) -- Namibia , Sex instruction -- Study and teaching (Secondary) -- Namibia , HIV infections -- Study and teaching (Secondary) -- Namibia , AIDS (Disease) -- Study and teaching (Secondary) -- Namibia
  • Language: English
  • Type: Thesis , Masters , MEd
  • Identifier: vital:2029 , http://hdl.handle.net/10962/d1017340
  • Description: This paper reports findings on how Namibian secondary school Life Skills teachers are exercising their agency to teach or not to teach Sexuality and HIV and AIDS, a subject which is regarded as sensitive and has been surrounded by secrecy and has issues which are cloaked by silence and taboos. The aim of the study was to explore the structural and cultural factors that shape the responses and experiences of Life Skills teachers in teaching sexuality and HIV and AIDS. The study was conducted through observations and interviews with four full-time Life Skills teachers. Document analysis was carried out throughout the study in which lesson plans, portfolios, assessment forms, Life Skills syllabuses, schemes of works, national curriculum documents and subject policy on HIV and AIDS were analysed. The data were analysed by identifying categories, codes and themes using the analytic dualism framework, and the literature review was used to summarise the findings. The study revealed that all teachers operate in an environment that consists of the National structures such as high teacher: learner ratio in their classrooms that they have to teach Life Skills and do day to day counselling, a lack of teaching and learning support material that they should use to scaffold the learning of sexuality and HIV and AIDS, and little time allocated to Life Skills teaching. The same study also revealed that the teaching of Life Skills is hampered by the cultural structures which emerged from teachers’ discourses as evidenced from the data which shows that cultural properties have powers that condition teachers in teaching sexuality and HIV and AIDS. This included learners’ silence in sex-related discussion versus teachers’ position; discourses on the importance of full-time Life Skills teachers in school; comfort in teaching selected topics in Life Skills; Life Skills teachers’ perceptions on parents’ feelings on teaching sexuality and HIV and AIDS in schools, and perceptions on the Life Skills teachers’ position and teaching sexuality and sex education. While the findings revealed that teachers are conditioned by the structural and cultural conditions that acted as constraints to teaching sexuality and HIV and AIDS, the observations revealed agency on their part. The study finding depicts instances where teachers acted in agreement or in contravention of the structural and cultural pressures or conditions in their environments.
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  • Date Issued: 2015

Implementation of the business studies national curriculum statement: a case study of four high schools in the Fort Beaufort education district

  • Authors: Tyilo, Nomakula
  • Date: 2014
  • Subjects: Curriculum planning Curriculum planning Curriculum planning Education -- Curricula -- South Africa -- Eastern Cape Educational change -- South Africa -- Eastern Cape
  • Language: English
  • Type: Thesis , Masters , Degree
  • Identifier: http://hdl.handle.net/10353/5829 , vital:29400
  • Description: This study investigated the implementation of the Business Studies National Curriculum Statement in Schools in Fort Beaufort District. The interpretive paradigm was utilized in this study because it focuses on individual perceptions and experiences. In addition a qualitative approach was used for the collection of data so as to gain in-depth information on the implementation of the Business Studies National Curriculum. Semi- structured interviews, focus group interviews and document analysis were used as a form of collecting data. The participants were purposively selected for the sample of this study and comprised of 4 Principals, 3 Subject Advisors, 1 Provincial Subject Planner, 6 Teachers and 36 learners and interviews lasted for about 1 ½ hours. Data analysis was done in line with the research questions, aims and objectives of the study. Through the participants’ answers from schools under study, a transcript was formulated, coded and categorized in view of the implementation of Business Studies National Curriculum Statement in schools. Therefore, it was discovered from the data of the research study that the participants encounter a number of challenges with regard to teaching and implementing Business Studies in their schools. Namely: (1) lack of qualified personnel to teach Business Studies (2) lack of adequate teaching materials (3) lack of Subject Advisors executing their roles in helping teachers to teach Business Studies effectively (4) lack of training programmes and workshops on how to teach Business Studies in the classroom. Thus, there were variances in schools under study especially with relations to funding, availability of teaching material, support offered by School Heads and the Department of Education. As a result, emphasis was that the Department of Education had to come up with ways of continuously training the teachers and offering support in terms of teaching materials. Most of the participants from the school under study did not bother to plan their lessons when they were going to teach this subject. In sum, this study attempted to highlight the challenges that the participants encounter as they try to implement the Business Studies in their schools taking into the considering the educational history of their country. Hence some of the participants expressed why there is a need to create, cultivate and have a conducive and supportive working environment. The study recommends that the Department of Education provide teachers with special training on how to select relevant learning and teaching support material. Moreover, there is a greater need for Business Studies teachers to strike a balance between theory and practice in the deliverance of their lessons in Business Studies. Additionally, the District Officials must organise on-going training in Business Studies as this would help to rectify the problems that are currently being encountered in implementing Business Studies in schools.
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  • Date Issued: 2014

Perceptions of organisational commitment within a selected Chinese organisation in South Africa: a case study approach

  • Authors: Paterson, Steven James
  • Date: 2014
  • Subjects: Organizational commitment -- South Africa , Personnel management -- South Africa , Employee motivation -- South Africa , International business enterprises -- South Africa , China -- Foreign economic relations -- South Africa
  • Language: English
  • Type: Thesis , Masters , MCom
  • Identifier: vital:1201 , http://hdl.handle.net/10962/d1013094
  • Description: Chinese organisations are benefiting from increasing support from the Chinese government to enter into Africa. It is believed that over 2 000 Chinese organisations are operational in Africa, contributing greatly to employment within the continent. Despite the importance of Chinese organisations and their operations in Africa, very little research has been done on individual and organisational issues in Chinese organisations operating in Africa, and more specifically the local employees' organisational commitment to such organisations. The organisational commitment of South African employees within Chinese organisations in South Africa is important as it promotes the success of Chinese business, which may promote further investment into the country, as well as the use of local human resources. The primary aim of this research was therefore to conduct a literature and empirical study into the levels of and factors influencing the organisational commitment of South African employees in a selected Chinese organisation in South Africa. For the purposes of this study, a single case study approach, located within the phenomenological research paradigm, was used. A large multinational Chinese organisation with operations in South Africa agreed to participate in this study. The research made use of a descriptive case study design. To give effect to the primary aim of the study, three research objectives were identified. Firstly, to identify and describe key factors influencing local employee commitment. Secondly, to identify and describe current commitment levels amongst local employees, and lastly, to propose recommendations to improve local employee commitment and its implications for the appropriate management of human resources within the Chinese organisation. Data were collected by means of in-depth, semi-structured interviews with 20 participating employees at four organisational branches across South Africa. Moreover, although the interview transcripts were the primary source of data, the collection process was enriched with the use of organisational and participant observations. The findings of this research revealed ten factors which are perceived to influence the commitment of South African employees within the organisation, namely: Open communication, Leadership, Supervisory support, Opportunities for training and development, Compensation, Job security, Promotional opportunities, Shared values, Recognition and Trust. Certain issues were raised by the participants during the in-depth interviews, most notably the limited opportunities for training, development and promotion, as well as issues regarding the perceived limited compensation received from the organisation. Despite these issues, the general findings relating to the levels of commitment in the organisation were positive for the organisation under study, with the majority of the participants being perceived to demonstrate high levels of affective, normative and continuance commitment.
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  • Date Issued: 2014

Voltammetric investigation of microbiological growth media and carbon nanotube modified electrodes : a case study of oxytetracycline

  • Authors: Kruid, Jan
  • Date: 2013
  • Subjects: Voltammetry , Electrodes , Oxytetracycline , Carbon nanotubes
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:4156 , http://hdl.handle.net/10962/d1018238
  • Description: Oxytetracycline (OTC) is a broad spectrum antibiotic used extensively in the agricultural and human-health sector, and is effective against various gram positive and –negative bacteria as well as large viruses and certain pathogenic Rickettsiae. This study addresses the lack of voltammetric knowledge regarding the electroanalytical characterisation of OTC and its analysis in complex matrices. Cyclic voltammetry (CV) revealed several irreversible anodic peaks for OTC at a bare glassy carbon electrode (GCE). These current responses were improved through the selection of a diluent for OTC stock preparation, electrolyte solution and electrolyte pH, stir time and applied preconditioning potential. Under enhanced adsorptive conditions and using square wave voltammetry (SWV), a detection limit of 24.3 nM was achieved. The electrode surface could be renewed in vitro for 10 successive scans. OTC oxidation was characterised as a one electron:one proton ECiE mechanisms. Next, investigating the viability of voltammetry in various complex microbiological growth media revealed that selected growth media contained interfering redox active components, which, while simultaneously coating the electrode surface, effectively reduced GCE performance and lowered the active electrode surface area, as ascertained through CV and electrochemical impedance spectroscopy (EIS) studies. This interference lowered OTC current response in the presence of growth media which was partially recovered by appropriate growth media selection and sample dilution. In testing the use of acid functionalised multi-walled carbon nanotubes (MWCNTs) to improve anodic OTC response, charge-based attraction was observed between the MWCNT dispersal agent Nafion® and OTC, while increased surface area associated with prolonged acid functionalisation time aided in improving OTC current response.
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  • Date Issued: 2013

The mediating role of mobile technology in the linkage between customer satisfaction and customer loyalty

  • Authors: Chihombori, Rumbidzai Anna
  • Date: 2012
  • Subjects: Mobile commerce , Mobile communication systems , Customer services -- Management , Customer relations , Customer loyalty , Customer services -- Evaluation
  • Language: English
  • Type: Thesis , Masters , M Com (Business Management)
  • Identifier: vital:11324 , http://hdl.handle.net/10353/d1013388 , Mobile commerce , Mobile communication systems , Customer services -- Management , Customer relations , Customer loyalty , Customer services -- Evaluation
  • Description: The main objective of this study was to critically investigate the mediating role that the use of mobile technology plays in the linkage between customer satisfaction and customer loyalty in a semi-urban environment. The research problem focused on the application of mobile technology in the linkage between customer satisfaction and customer loyalty in the clothing industry in King Williams Town. In accomplishing this objective, this research study hypothesised that mobile technology plays a mediating role in the linkage between customer satisfaction and customer loyalty of customers of clothing retailers in South Africa. Multiple regression was conducted to test for the first hypothesis. The first secondary objective aimed at establishing if there is disconfirmation between customer expectations and the performance of clothing retail outlets in King Williams Town. In exploring this objective, it was hypothesised that there is negative disconfirmation between customer expectations and performance. A paired sample test was conducted to test for this hypothesis. In addition, the influence of service quality and customer satisfaction on customer loyalty was explored. To accomplish these, it was hypothesised that both service quality and customer satisfaction have an influence on customer loyalty. Pearson’s Correlation and the Chi-Square Test were applied to test the influence of service quality and Customer satisfaction on Customer loyalty. Data was analysed using the Statistical Package for Social Sciences (SPSS) statistical software. Regression analysis, chi-square tests, Paired sample tests and correlation reports were used to analyse data inferentially. Reliability and validity of the research was also tested using Cronchbach’s alpha test. The results show that mobile phones have become a basic necessity for customers and that mobile technology plays a mediating role in the linkage between customer satisfaction and customer loyalty; however, the mediation is partial. The results also show that there is positive disconfirmation between customer expectations and retailer performance; that both service quality and customer satisfaction have a positive correlation with customer loyalty and that mobile technology enhances customer loyalty. Finally, the results show that the total service experience of customers is favourable vii because the five components of service quality were rendered at a high level of service quality. The study offers several managerial recommendations. Firstly, retail managers should make strategic investments in mobile technology and use this technology to the full to reap the benefits of technologically advanced mobile communication. Secondly, managers should be creative in their use of this mobile technology to enhance customer satisfaction and, hence, customer loyalty. Thirdly, managers should prioritise the improvement of all five components of service quality in order to enhance customer loyalty. Finally, managers should provide a customer-centred service experience that exceeds customer expectations for service quality and mobile communication, one that maximises customer satisfaction and loyalty. The implementation of these recommendations could result in clothing retailers providing a customer-focused service experience in all five aspects of service quality. To successfully implement these recommendations, clothing retailers should: ensure that expectations created, could be accomplished or exceeded to build and enhance customer satisfaction; create expectations that are realistic to avoid negative disconfirmation and hence customer dissatisfaction; implement innovative and creative mobile communication strategies to build and enhance customer loyalty; and finally, improve loyalty programmes to enlarge the customer base.
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  • Date Issued: 2012

A bioinorganic investigation of some metal complexes of the Schiff base, N,N'-bis(3-methoxysalicylaldimine)propan-2-ol

  • Authors: Mopp, Estelle
  • Date: 2010 , 2012-04-13
  • Subjects: Schiff bases , Bioinorganic chemistry , Metal complexes , Transition metal complexes , Transition metals , Cancer -- Chemotherapy , Ligands -- Toxicity , Antineoplastic agents
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:4413 , http://hdl.handle.net/10962/d1006768 , Schiff bases , Bioinorganic chemistry , Metal complexes , Transition metal complexes , Transition metals , Cancer -- Chemotherapy , Ligands -- Toxicity , Antineoplastic agents
  • Description: This thesis includes the synthesis, characterisation, antioxidant and antimicrobial activities of Cu(II)-, Co(II)- and Co(III) complexes with N,N'-bis(3- methoxysalicylaldimine)propan-2-ol, 2-OH-oVANPN. The Schiff base ligand, 2-OHoVANPN, is derived from o-vanillin and 1,3-diaminopropan-2-ol. The o-vanillin condensed with 1,3-diaminopropan-2-ol in a 2:1 molar ratio yields this potential tetraor pentadentate ligand. The complexes synthesized are tetra (or penta or hexa) coordinated. Formation of the complexes is symbolized as follows:- MX₂ + 2-OH-oVANPN (2:1) -> [M(2-OH-oVANPN)Xn] + HnX MX₂ + 2-OH-oVANPN (2:1) -> [Mn(2-OH-oVANPN)OH] + H₂X₂ MX₂ + (o-vanillin : diaminopropanol) (1:1) -> [M(1:1)X₂] MX₂ + (o-vanillin : diaminopropanol) (1:1) -> [M₃(1:1)X₄] M = Cu(II), Co(II) or Co(III); X = Cl; n = 1, 2. Their structural features have been deduced from their elemental analytical data, IR spectral data, and electronic spectral data. With the exception of {Cu₃(C₁₁H₁₄N₂O₃)(Cl)₄(H₂O)₆}(A4), the Cu(II) complexes were monomeric with 2-OH-oVANPN acting as a tetradentate ligand. A binuclear Co(II) complex, [Co₂(C₁₉H₁₉N₂O₅)(OH)] (B1), was synthesised and the rest of the Co(II) and Co(III) complexes were monomeric with chloride ions coordinating to the metal centre in some cases. Electronic data suggest that the cobalt(II) complexes have octahedral geometries and the copper(II) complexes have square planar structures – Co(III) is likely to be octahedral. Thermal analyses, which included the copper-block-method for determining sublimation temperatures, revealed that some copper(II) and cobalt(II) complexes are hygroscopic and sublime at 200 °C and below. DSC analyses of the Cu(II) complexes gave exotherms around 300 °C for complexes K[Cu(C₁₉H₂₀N₂O₅)(OH)]·2H₂O (A1) and [Cu(C₁₁H15N₂O₃)(Cl)₂]·2H₂O (A2) and above 400 °C for [Cu(C₁₁H₁₆N₂O₃)(Cl)₂] (A3) and {Cu₃(C₁₁H₁₄N₂O₃)(Cl)₄(H₂O)₆} (A4). Antioxidant studies were carried out against the 2,2-diphenyl-1-picrylhydrazyl radical (DPPH·). The cobalt(II) complex, [Co₂(C₁₉H₁₉N₂O₅)(OH)] (B1), which was synthesized in the presence of KOH, had no antioxidant activity, whilst the other cobalt(II) complexes, [Co(C₁₇H₁₇N₂O₅(Cl))]·1½H₂O (B2), [Co(C₁₉H₂₂N₂O₅) (Cl)₂]·5½H₂O (B3) and [Co(C₁₉H₂₂N₂O₅)(Cl)₂]·5½H₂O (B4), which were synthesised in the absence of KOH, demonstrated antioxidant activity. The latter complexes are candidates for cancer cell line testing, while [Cu(C₁₁H₁₆N₂O₃)(Cl)₂] (A3), {Cu₃(C₁₁H₁₄N₂O₃)(Cl)₄(H₂O)₆} (A4), [Co(C₁₉H₂₁N₂O₅)(Cl)₂ ]·5H₂O (C2) and [Co(C₁₉H₂₀N₂O₅)(Cl)]·3H₂O (C3) may show anticancer activity through possible hydrolysis products. Most of the complexes synthesized displayed antimicrobial activity against Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger and Candida albicans. The results indicated that complexes [Cu(C₁₁H₁₆N₂O₃)(Cl)₂](A3), [Co(C₁₉H₂₂N₂O₅)(Cl)₂]·5½H₂O (B3) and [Co(C₁₉H₂₁N₂O₅)(Cl)₂ ]·5H₂O (C2) are active against the Gram-negative Ps. aeruginosa and that the ligand, 2-OH-oVANPN, did not have any activity. The same trend was observed with 2-OH-oVANPN, {Cu₃(C₁₁H₁₄N₂O₃)(Cl)4(H₂O)₆} (A4) and [Co(C₁₉H₂₀N₂O₅)(Cl)]·3H₂O (C3) against the Gram-positive S. aureus. As for activity against E. coli and C. albicans, some complexes showed more activity than the ligand. There is an observed trend here that the metal complexes are more active (toxic) than the corresponding ligand, which is in agreement with Tweedy’s chelation theory.
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  • Date Issued: 2010

Integrated anaerobic/aerobic bioprocess environments and the biodegradation of complex hydrocarbon wastes

  • Authors: Ehlers, George A C
  • Date: 2004
  • Subjects: Hydrocarbons -- Biodegradation Sewage -- Purification -- Anaerobic treatment Water -- Purification -- Biological treatment Anaerobic bacteria Aerobic bacteria
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:4011 , http://hdl.handle.net/10962/d1004071
  • Description: An investigation of the biodegradation of complex hydrocarbon wastes, with emphasis on chlorinated aromatic compounds, in an anaerobic/aerobic bioprocess environment was made. A reactor configuration was developed consisting of linked anaerobic and aerobic reactors which served as the model for a proposed bioremediation strategy targeting subterranean soil/sediment/aquifer chlorinated phenol-contaminated environments. Here oxygen is frequently limited and sulphate is readily available, as occurs especially in marine sediment and intertidal habitats. In the anaerobic system the successful transformation and mobilization of the model contaminant, 2,4,6-trichlorophenol, was shown to rely on reductive dechlorination by a sulphate-reducing dependent dechlororespiring co-culture. This was followed in the aerobic system by degradation of the pollutant and its metabolites, 2,4-dichlorophenol, 4-chlorophenol and phenol, by immobilized white-rot fungi.The strategy was initially investigated separately in laboratory bench- and intermediate scale reactors whereafter reactors were linked to simulate the integrated biodegradation strategy. The application of the fungal reactor to treat an actual waste stream by degrading complex mixtures of hydrocarbons in a waste oil recycling effluent was also investigated. The mineralization of phenol and 2,4,6-TCP by immobilized fungal cultures was studied in pinewood chip and foam glass bead-packed trickling reactors. The reactors were operated in sequencing batch format. Removal efficiency increased over time and elevated influent phenol and TCP (800 and 85 mg.L⁻¹) concentrations were degraded by > 98 % in 24 – 30 h batch cycles. Comparable performance between the packing materials was shown. Uptake by the packing was negligible and stripping of compounds induced by aeration had a minimal effect on biodegradation efficiency. Reactor performances are discussed in relation to sequencing batch operation and nutrient requirements necessary to sustain fungal activity in inert vs. organic material packed systems. It was shown that a co-culture consisting of sulphate-reducing and dechlororespiring bacteria established in fed-batch and soil flasks, as well as pine chip-packed fluidized bed reactors. Results showed reductive dechlorination of 2,4,6-TCP to be in strict dependence on the activity of the sulphate-reducing population, sulphate and lactate concentrations. Transformation to 2,4-DCP, 4-CP and phenol was enhanced in sulphate deficient conditions. Dechlororespiring activity was found to be dependent on the fermentative activity of sulphate-reducing bacteria, and the culture was also shown to mobilize and dechlorinate TCP in soils contaminated with the pollutant. Linking the systems achieved degradation of the compound by > 99 % through fungal mineralization of metabolites produced in the dechlororespiring stage of the system. pH correction to the anaerobic reactor was found to be necessary since acidic effluent from the fungal reactor inhibited sulphate reduction and dechlorination. The fungal reactor system was evaluated at intermediate-scale using a complex waste oil recycling effluent. Substantial COD reduction (> 96 % in 48 h batch cycles) and removal of specific effluent hydrocarbon components was shown in diluted, undiluted (COD > 37 g.L⁻¹) and 2,4,6-TCP-spiked effluents. Industrial application of the fungal reactor was evaluated in a 14 m³ pilot plant operated on-site at a waste oil processing plant.
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  • Date Issued: 2004

Using the topic "Water management in Umtata" to promote the use of an environmental approach in the teaching of geography

  • Authors: Nduna, Joyce Nothemba
  • Date: 1995
  • Subjects: Geography -- Study and teaching -- Environmental aspects Water -- Management -- Study and teaching -- Environmental aspects Environmental education -- South Africa
  • Language: English
  • Type: Thesis , Masters , MEd
  • Identifier: vital:1819 , http://hdl.handle.net/10962/d1003705
  • Description: This study first offers a critique of some conventional approaches to environmental education and geography. The critique is followed by an analysis of current learning theories which underpin environmental and geographical thinking. On the basis of this analysis an environmental approach to the teaching of geography is identified. Within the broad theoretical context provided by debates on the importance of environmental education for the solution of environmental problems, the study promotes student teachers' understanding of an environmental approach in the teaching of geography at Transkei College of Education. Water management, a section of the geography syllabus, is selected to illustrate the process and implementation of such an approach in geography. The educational effectiveness of an environmental approach with regard to the students' conceptual understanding of water management is evaluated. The study as a whole is set within the general literature of environmental education, and particularly that of education for the environment.
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  • Date Issued: 1995

Lifestyle orientation of high versus low achievers in traditional school sports: an holistic analysis

  • Authors: Davies, Simeon
  • Date: 1994
  • Subjects: School sports Achievement motivation
  • Language: English
  • Type: Thesis , Masters , MA
  • Identifier: vital:5147 , http://hdl.handle.net/10962/d1009501
  • Description: One hundred and four subjects aged 16-18 years volunteered to participate in this study which sought to identify via an holistic model those factors that characterise the lifestyle orientations of high and low achievers (male and female) in traditional school sport. Subjects were evaluated with respect to their anthropometric, physiological, psychological and perceptual responses. The data were statistically analyzed by one way ANOVAS for significant differences in the following pairs; males and females, high and low achievers, Mhi (male high achievers) and Mlo (male low achievers), and Fhi (female high achievers) and Flo (female low achievers). Anthropometric results indicate that Fhi and Flo were significantly different in their stature, mass and body fat, while Mhi and Mlo show no significant differences. A greater disparity existed between VO, max of Fhi and Flo compared with Mhi and Mlo, along with trends in heart rate and RPE responses that were also more divergent. Psychological responses indicate that Fhi and Flo were significantly different in five of the seven sub-domains of CATPA, while Mhi and Mlo were only identifiable in one. In the PSPP Fhi and Flo were significantly different in all five subscales, while Mhi and Mlo in only two. This contrast in variability between the paired group analysis of Fhi and Flo as compared to Mhi and Mlo appears throughout the data.
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  • Date Issued: 1994
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