An audience perception of pentecostal churches’ television programmes on star times and dstv in lagos, Nigeria
- Authors: Olaoye, Adewale Titus
- Date: 2020
- Subjects: Religious broadcasting -- Christianity Television in religion Mass media in religion
- Language: English
- Type: Thesis , Doctoral , PhD (Communication)
- Identifier: http://hdl.handle.net/10353/11418 , vital:39070
- Description: Pentecostal churches in Nigeria are leveraging traditional and new media technologies such as cable or digital satellite television, to broadcast services and programmes to their regular and a growing community of virtual worshippers. Critics of this type of religious outreach now known as televangelism have challenged its predominant, if not exclusive focus on miracle and prosperity message. Using the mixed-method research design involving focus group discussions, key informant interviews and a survey of 255 respondents, this study sought to ascertain Lagos audiences‘ perceptions of Pentecostal Television programmes on two satellite stations, Start Times and DSTV. The findings revealed that audience members perceive Pentecostal churches programme as primarily focused on converting the audience members to the Christian faith. The result revealed that miracle sessions are a common feature of televangelism. Respondents see the miracles as manipulations largely intended to woo and often, hoodwink audience members. The findings revealed that although some of the Pentecostal churches‘ programmes dwell more on the word of God compared to the mainline churches, the programmes and teachings, however, often tended to promote the leadership of the church and not the gospel of Christ. Generally, the study indicates the majority of the audience members are aware of and identify with the atrocities the Pentecostal Churches are accused of perpetrating through their TV programmes. The findings revealed poor awareness and knowledge about the role of the Nigeria Broadcasting Corporation (NBC). The results suggest participants do not believe the NBC is living up to its responsibilities. The findings of this study highlight the need for the NBC, the Christian Association of Nigeria (CAN) and Pentecostal Fellowship of Nigeria (PFN) to work together in formulating new regulations for controlling religious broadcast on television, Pentecostal TV broadcasts, in particular. This is the only way to safeguard vulnerable members of the audience from being manipulated and brainwashed.
- Full Text:
- Date Issued: 2020
- Authors: Olaoye, Adewale Titus
- Date: 2020
- Subjects: Religious broadcasting -- Christianity Television in religion Mass media in religion
- Language: English
- Type: Thesis , Doctoral , PhD (Communication)
- Identifier: http://hdl.handle.net/10353/11418 , vital:39070
- Description: Pentecostal churches in Nigeria are leveraging traditional and new media technologies such as cable or digital satellite television, to broadcast services and programmes to their regular and a growing community of virtual worshippers. Critics of this type of religious outreach now known as televangelism have challenged its predominant, if not exclusive focus on miracle and prosperity message. Using the mixed-method research design involving focus group discussions, key informant interviews and a survey of 255 respondents, this study sought to ascertain Lagos audiences‘ perceptions of Pentecostal Television programmes on two satellite stations, Start Times and DSTV. The findings revealed that audience members perceive Pentecostal churches programme as primarily focused on converting the audience members to the Christian faith. The result revealed that miracle sessions are a common feature of televangelism. Respondents see the miracles as manipulations largely intended to woo and often, hoodwink audience members. The findings revealed that although some of the Pentecostal churches‘ programmes dwell more on the word of God compared to the mainline churches, the programmes and teachings, however, often tended to promote the leadership of the church and not the gospel of Christ. Generally, the study indicates the majority of the audience members are aware of and identify with the atrocities the Pentecostal Churches are accused of perpetrating through their TV programmes. The findings revealed poor awareness and knowledge about the role of the Nigeria Broadcasting Corporation (NBC). The results suggest participants do not believe the NBC is living up to its responsibilities. The findings of this study highlight the need for the NBC, the Christian Association of Nigeria (CAN) and Pentecostal Fellowship of Nigeria (PFN) to work together in formulating new regulations for controlling religious broadcast on television, Pentecostal TV broadcasts, in particular. This is the only way to safeguard vulnerable members of the audience from being manipulated and brainwashed.
- Full Text:
- Date Issued: 2020
An evaluation of programme management with reference to inner -city problem buildings: The case of Nelson Mandela Bay Metropolitan Municipality ,South Africa
- Conradie, Hendrik Francois, Shaidi,Walter
- Authors: Conradie, Hendrik Francois , Shaidi,Walter
- Date: 2020
- Subjects: Municipal government -- South Africa -- Port Elizabeth , Finance,Public --South Africa --Port Elizabeth
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/46670 , vital:39607
- Description: This research study is qualitative and cross-sectional in nature. Programme management by South African city governments is investigated and evaluated, as related to inner-city decay and problem (derelict; hijacked; dilapidated; overcrowded) buildings. A case study approach, focusing on the Nelson Mandela Bay Municipality in Port Elizabeth, South Africa, is utilised to understand the phenomenon, and to answer the research question. The significant challenge of inner-city and central business district problem buildings in major South African cities has prompted the study; no scientific research has previously been conducted or published on this topic The study started out with this research question, asked in a case study context: to what extent are programmes dealing with inner-city problem buildings and decay managed effectively by city government in South Africa? In the literature review the researcher focused on programme management theory, emphasising the usefulness of project management principles and practice in public sector programme management contexts. In a subsequent chapter the applicable constitutional and legislative frameworks were presented. The researcher developed, as outcome, strategic remedial legal options available to city governments when dealing with transgressing owners of problematic buildings. Problem building by-laws were dealt with in detail. A qualitative research approach, including semi-structured in-depth interviews with political and managerial leaders at the case study city government, assisted the researcher in effective data generation. Data analysis was performed with vigour, based on thematic content analysis.relevant coding practices were utilised in analysis and interpretation of data.
- Full Text:
- Date Issued: 2020
- Authors: Conradie, Hendrik Francois , Shaidi,Walter
- Date: 2020
- Subjects: Municipal government -- South Africa -- Port Elizabeth , Finance,Public --South Africa --Port Elizabeth
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/46670 , vital:39607
- Description: This research study is qualitative and cross-sectional in nature. Programme management by South African city governments is investigated and evaluated, as related to inner-city decay and problem (derelict; hijacked; dilapidated; overcrowded) buildings. A case study approach, focusing on the Nelson Mandela Bay Municipality in Port Elizabeth, South Africa, is utilised to understand the phenomenon, and to answer the research question. The significant challenge of inner-city and central business district problem buildings in major South African cities has prompted the study; no scientific research has previously been conducted or published on this topic The study started out with this research question, asked in a case study context: to what extent are programmes dealing with inner-city problem buildings and decay managed effectively by city government in South Africa? In the literature review the researcher focused on programme management theory, emphasising the usefulness of project management principles and practice in public sector programme management contexts. In a subsequent chapter the applicable constitutional and legislative frameworks were presented. The researcher developed, as outcome, strategic remedial legal options available to city governments when dealing with transgressing owners of problematic buildings. Problem building by-laws were dealt with in detail. A qualitative research approach, including semi-structured in-depth interviews with political and managerial leaders at the case study city government, assisted the researcher in effective data generation. Data analysis was performed with vigour, based on thematic content analysis.relevant coding practices were utilised in analysis and interpretation of data.
- Full Text:
- Date Issued: 2020
An intervention study for low risk pregnant women and high risk pregnant women with GDM in Buffalo City Metropolitan Municipality, Eastern Cape, South Africa
- Authors: Vellem, Nonceba Mercy
- Date: 2018
- Subjects: Diabetes in pregnancy -- South Africa Nursing services -- South Africa -- Eastern Cape -- Administration Pregnancy -- Complications
- Language: English
- Type: Thesis , Doctoral , Nursing
- Identifier: http://hdl.handle.net/10353/9723 , vital:34891
- Description: Low risk and high risk pregnant women (HRPW) with gestational diabetes mellitus (GDM) who practise sedentary life style are at risk of overweight and obesity that predispose to gestational diabetes mellitus (GDM). The purpose of the study is to describe the effectiveness of an intervention strategy of modified diet and planned physical activity implemented amongst low-risk and high-risk pregnant women with GDM in Buffalo City Metropolitan Municipality in the Eastern Cape, South Africa. Quantitative experimental intervention design and stratified random sampling was used for drawing a sample of low-risk and high risk pregnant women with GDM. A sample size 291 of LRPW and n=34 HRPW were eligible for the study. The sample frame of the study was taken from the registers of the CHCs, Frere Hospital and Cecilia Makiwane Hospital (CMH). Questionnaires were used to collect data from the low and high risk pregnant with GDM. Descriptive statistics (frequency, percentages, mean and standard deviation) were used for categorical variables. A p-value of < 0.05 was considered statistically significant. The total analysed of LRPW were n=135 and HRPW n=34 all in control group due to miscarriages, phone loss and relocation. LRPW had some risk factors of overweight (6.2 percent), obesity (15.5 percent), family history of diabetes (16.5 percent). HRPW also had overweight and obesity of (14.7 percent) and family history of (26.4 percent) as the Pvalue was statistically significant of weight was 001, MUAC Pvalue of 000 and Pvalue of BMI 000. There were alarming abnormalities of urinalysis of protein, glucose, leucocytes and blood in urine. The LRPW and HRPW had consumption of high content of carbohydrates, vegetables, fats and low in fruit, vegetables and fibre diet. Both LRPW and HRPW were also interested on the education about modified diet benefits (95.1 percent) and modified diet programs networks (87.5 percent). The barriers showed that LRPW and HRPW were low motivation (90 percent) minimal knowledge and benefits of modified diet (93 percent) and socio-cultural issues (86 percent). The majority of participants both LRPW and HRPW showed the interest in the planned physical activity benefits especially frequent education (96.9 percent) and encouragement of social support networks (90.2 percent) and convenient location (89.4 percent). But the HRPW had lower engagement than the LRPW in planned physical activity and is associated with risk of GDM. Although pregnant women were faced with fatigue and low energy (98.6 percent), as pregnancy progresses, minimum information regarding benefits of planned physical activity (87.6 percent) and the socio-cultural influence (77.8 percent). The recommendations are education on frequent use of modified diet and planned physical activity that is available, less economical and within their context. Frequent screening of all pregnant women during pregnancy of BMI, MUAC and weight and educate accordingly. The availability of dietician and physical activity speciality is needed.
- Full Text:
- Date Issued: 2018
- Authors: Vellem, Nonceba Mercy
- Date: 2018
- Subjects: Diabetes in pregnancy -- South Africa Nursing services -- South Africa -- Eastern Cape -- Administration Pregnancy -- Complications
- Language: English
- Type: Thesis , Doctoral , Nursing
- Identifier: http://hdl.handle.net/10353/9723 , vital:34891
- Description: Low risk and high risk pregnant women (HRPW) with gestational diabetes mellitus (GDM) who practise sedentary life style are at risk of overweight and obesity that predispose to gestational diabetes mellitus (GDM). The purpose of the study is to describe the effectiveness of an intervention strategy of modified diet and planned physical activity implemented amongst low-risk and high-risk pregnant women with GDM in Buffalo City Metropolitan Municipality in the Eastern Cape, South Africa. Quantitative experimental intervention design and stratified random sampling was used for drawing a sample of low-risk and high risk pregnant women with GDM. A sample size 291 of LRPW and n=34 HRPW were eligible for the study. The sample frame of the study was taken from the registers of the CHCs, Frere Hospital and Cecilia Makiwane Hospital (CMH). Questionnaires were used to collect data from the low and high risk pregnant with GDM. Descriptive statistics (frequency, percentages, mean and standard deviation) were used for categorical variables. A p-value of < 0.05 was considered statistically significant. The total analysed of LRPW were n=135 and HRPW n=34 all in control group due to miscarriages, phone loss and relocation. LRPW had some risk factors of overweight (6.2 percent), obesity (15.5 percent), family history of diabetes (16.5 percent). HRPW also had overweight and obesity of (14.7 percent) and family history of (26.4 percent) as the Pvalue was statistically significant of weight was 001, MUAC Pvalue of 000 and Pvalue of BMI 000. There were alarming abnormalities of urinalysis of protein, glucose, leucocytes and blood in urine. The LRPW and HRPW had consumption of high content of carbohydrates, vegetables, fats and low in fruit, vegetables and fibre diet. Both LRPW and HRPW were also interested on the education about modified diet benefits (95.1 percent) and modified diet programs networks (87.5 percent). The barriers showed that LRPW and HRPW were low motivation (90 percent) minimal knowledge and benefits of modified diet (93 percent) and socio-cultural issues (86 percent). The majority of participants both LRPW and HRPW showed the interest in the planned physical activity benefits especially frequent education (96.9 percent) and encouragement of social support networks (90.2 percent) and convenient location (89.4 percent). But the HRPW had lower engagement than the LRPW in planned physical activity and is associated with risk of GDM. Although pregnant women were faced with fatigue and low energy (98.6 percent), as pregnancy progresses, minimum information regarding benefits of planned physical activity (87.6 percent) and the socio-cultural influence (77.8 percent). The recommendations are education on frequent use of modified diet and planned physical activity that is available, less economical and within their context. Frequent screening of all pregnant women during pregnancy of BMI, MUAC and weight and educate accordingly. The availability of dietician and physical activity speciality is needed.
- Full Text:
- Date Issued: 2018
Livelihood and unemployment transitions : drivers and effects on welfare in Nigeria
- Authors: Fashogbon, Ayodele Emmanuel
- Date: 2018
- Subjects: Social service -- Nigeria Social problems -- Nigeria Nigeria -- Social conditions
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/9176 , vital:34302
- Description: Hunger, unemployment and social crisis are increasing in Nigeria. Statistics supports it that most of the able-bodied youth, both male and female, are not in employment, school or training in Nigeria while poverty rate is as high as a decade ago. A number of research efforts have looked at the micro and macroeconomic paths of the problem with less attention on dynamism of unemployment vis-a-vis the labour market transition, hence this study. This study investigates dynamism of labour market by assessing pattern and transition in labour market and out of labour, as well as determining the effect size of households head’s unemployment on household welfare. To achieve this objective, the General Household Survey (GHS) panel data for 2010/211 and 2012/2013 for Nigeria was used coupled with panel regression analyses to identify determinants of transitions from unemployment to productive sectors, and determinants of transition from productive sectors to unemployment, as well as effect of unemployment on household welfare while controlling for potential endogeneity in unemployment. Across the productive sectors and between 2010 and 2013, the descriptive results of transition show that workforce in the services sector (68 percent) are the most persistent, followed by agriculture (59 percent) and least is mining and manufacturing (44 percent). Transition from nonemployment occurred the most to services sector (22 percent), followed by out-of-labour force (18 percent), agriculture (15 percent) and least to mining and manufacturing (5 percent). Further, the results show that there are both locations and gender differences in the extent of transitions in the labour market. The econometric analyses reveal that job search characteristics, age, educational levels, gender, family ties, locations and time significantly determine transition from unemployment to productive sectors (agriculture or non-agriculture). Likewise, job characteristics, demographic variables, social network, location and time significantly determine switch from one productive sector to another or to unemployment. Moreover, it explicitly reveals as well from the analysis that household head month of unemployment reduces household total consumption and food consumption by 6.4 percent with gender and sectorial differences. The study recommends a combined and swift intervention on three sides: one, there is a need to stimulate education either through scholarship, or adult education from both public and private sectors; two, need to create jobs for youth to reduce potential social and economic crisis; and lastly there is a need to provide social support either in terms of public workfare, skills for jobs and unemployment benefits.
- Full Text:
- Date Issued: 2018
- Authors: Fashogbon, Ayodele Emmanuel
- Date: 2018
- Subjects: Social service -- Nigeria Social problems -- Nigeria Nigeria -- Social conditions
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/9176 , vital:34302
- Description: Hunger, unemployment and social crisis are increasing in Nigeria. Statistics supports it that most of the able-bodied youth, both male and female, are not in employment, school or training in Nigeria while poverty rate is as high as a decade ago. A number of research efforts have looked at the micro and macroeconomic paths of the problem with less attention on dynamism of unemployment vis-a-vis the labour market transition, hence this study. This study investigates dynamism of labour market by assessing pattern and transition in labour market and out of labour, as well as determining the effect size of households head’s unemployment on household welfare. To achieve this objective, the General Household Survey (GHS) panel data for 2010/211 and 2012/2013 for Nigeria was used coupled with panel regression analyses to identify determinants of transitions from unemployment to productive sectors, and determinants of transition from productive sectors to unemployment, as well as effect of unemployment on household welfare while controlling for potential endogeneity in unemployment. Across the productive sectors and between 2010 and 2013, the descriptive results of transition show that workforce in the services sector (68 percent) are the most persistent, followed by agriculture (59 percent) and least is mining and manufacturing (44 percent). Transition from nonemployment occurred the most to services sector (22 percent), followed by out-of-labour force (18 percent), agriculture (15 percent) and least to mining and manufacturing (5 percent). Further, the results show that there are both locations and gender differences in the extent of transitions in the labour market. The econometric analyses reveal that job search characteristics, age, educational levels, gender, family ties, locations and time significantly determine transition from unemployment to productive sectors (agriculture or non-agriculture). Likewise, job characteristics, demographic variables, social network, location and time significantly determine switch from one productive sector to another or to unemployment. Moreover, it explicitly reveals as well from the analysis that household head month of unemployment reduces household total consumption and food consumption by 6.4 percent with gender and sectorial differences. The study recommends a combined and swift intervention on three sides: one, there is a need to stimulate education either through scholarship, or adult education from both public and private sectors; two, need to create jobs for youth to reduce potential social and economic crisis; and lastly there is a need to provide social support either in terms of public workfare, skills for jobs and unemployment benefits.
- Full Text:
- Date Issued: 2018
Third sector intervention and sustainable development : an evaluation of selected non-governmental organization supported projects in the Eastern Cape, South Africa
- Authors: Moyo, Thokozani Patience
- Date: 2017
- Subjects: Non-governmental organizations -- South Africa -- Eastern Cape Economic development projects -- South Africa -- Eastern Cape Sustainable development -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/5774 , vital:29389
- Description: This study evaluates the impact of Third Sector- supported rural development projects in three rural communities of the Eastern Cape, South Africa. It focusses on how interventions driven by this sector – denoted by, among others, local and international non-governmental organisations (NGOs) - impact the lives and livelihoods of the rural poor. This is against the background of an established discourse that views NGOs as effective agents in the alleviation of poverty. The thesis contends that praise for the Third Sector is driven mostly by advocacy than based on systematic scientific evidence of the real impact of NGO-sponsored rural development interventions. Rural agricultural development projects supported by two Eastern Cape-based NGOs (the one a local NGO, and the other international) were selected for the study. A mini survey was conducted in the communities where the projects are located. Survey data were complemented by qualitative data obtained through focus groups, semi-structured and in-depth interviews as well as key informant interviews. The study found that whereas the projects had been established by the state later went moribund, they were resuscitated by the NGOs through a largely ‘bottom-up’ model of rural development intermediation. In other words, the interventions were resuscitated through a relatively robust prior engagement with project beneficiaries. As a result, while originally lacking a meaningful sense of local empowerment, ownership, and commitment, the projects had become revived and now played an important role in the livelihoods of some community members – even though social grants remained the primary and main source of income for those community members. Even so, the narratives of community members revealed what may be termed a ‘transformation paradox’ in the way the projects were implemented. The NGOs seemed to have replaced one kind of lop-sidedness in rural development (the exclusion of women) with another (the exclusion of men), by focussing on community projects that were ‘culturally’ deemed as ’women jobs’. In this way, the interventions appeared like a systematic attempt to do away with the ‘feminisation of rural poverty’ and entrench the ‘feminisation of rural development interventions’. The study concludes from these and other findings, that the key to understanding the significance and impact of Third Sector-supported development interventions in the rural arena – especially in the Eastern Cape context – is to go beyond the proliferation of NGOs and NGO-supported projects – and the broad sweep of advocacy that underpins it – and pay equally robust attention to systematically studying how these projects resonate at the grassroots, especially from a beneficiary perspective.
- Full Text:
- Date Issued: 2017
- Authors: Moyo, Thokozani Patience
- Date: 2017
- Subjects: Non-governmental organizations -- South Africa -- Eastern Cape Economic development projects -- South Africa -- Eastern Cape Sustainable development -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/5774 , vital:29389
- Description: This study evaluates the impact of Third Sector- supported rural development projects in three rural communities of the Eastern Cape, South Africa. It focusses on how interventions driven by this sector – denoted by, among others, local and international non-governmental organisations (NGOs) - impact the lives and livelihoods of the rural poor. This is against the background of an established discourse that views NGOs as effective agents in the alleviation of poverty. The thesis contends that praise for the Third Sector is driven mostly by advocacy than based on systematic scientific evidence of the real impact of NGO-sponsored rural development interventions. Rural agricultural development projects supported by two Eastern Cape-based NGOs (the one a local NGO, and the other international) were selected for the study. A mini survey was conducted in the communities where the projects are located. Survey data were complemented by qualitative data obtained through focus groups, semi-structured and in-depth interviews as well as key informant interviews. The study found that whereas the projects had been established by the state later went moribund, they were resuscitated by the NGOs through a largely ‘bottom-up’ model of rural development intermediation. In other words, the interventions were resuscitated through a relatively robust prior engagement with project beneficiaries. As a result, while originally lacking a meaningful sense of local empowerment, ownership, and commitment, the projects had become revived and now played an important role in the livelihoods of some community members – even though social grants remained the primary and main source of income for those community members. Even so, the narratives of community members revealed what may be termed a ‘transformation paradox’ in the way the projects were implemented. The NGOs seemed to have replaced one kind of lop-sidedness in rural development (the exclusion of women) with another (the exclusion of men), by focussing on community projects that were ‘culturally’ deemed as ’women jobs’. In this way, the interventions appeared like a systematic attempt to do away with the ‘feminisation of rural poverty’ and entrench the ‘feminisation of rural development interventions’. The study concludes from these and other findings, that the key to understanding the significance and impact of Third Sector-supported development interventions in the rural arena – especially in the Eastern Cape context – is to go beyond the proliferation of NGOs and NGO-supported projects – and the broad sweep of advocacy that underpins it – and pay equally robust attention to systematically studying how these projects resonate at the grassroots, especially from a beneficiary perspective.
- Full Text:
- Date Issued: 2017
The chemistry of Algoa Bay ascidians
- Authors: Bromley, Candice Leigh
- Date: 2016
- Subjects: Sea squirts -- South Africa -- Algoa Bay , Marine metabolites , Chemistry, Analytic , Liquid chromatography , Inductively coupled plasma mass spectrometry , Metal ions , Nucleosides , Vanadium
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4560 , http://hdl.handle.net/10962/d1020606
- Description: This thesis investigates the chemistry of 25 ascidian species collected from Algoa Bay, South Africa with a concerted focus on metal accumulation by these ascidians and the possible interaction of these metals with ascidian metabolites. Chapter 2 details the screening techniques employed to establish the presence of nitrogenous metabolites (1H- 15N HMBC), hyper-accumulated metal ions (ICP-MS) and potential metal ion/ ascidian metabolite complexes (LC-ICP-MS/ESI-MS). Unfortunately, exhaustive attempts to detect intact metal ion/ascidian metabolite complexes through the use of liquid chromatography with parallel inductively coupled plasma mass spectrometry/electrospray mass spectrometry (LC-ICPMS/ ESI-MS) were unsuccessful. However, the LC-ICP-MS/ESI-MS data obtained for the crude organic extracts of six of the Algoa Bay ascidian species, Distaplia skoogi, Aplidium monile, Aplidium sp., Didemnum sp., Leptoclindines sp. and Polycitor sp. enabled identification of a number of ten halogenated metabolites, namely the indoles 2.28-2.30, and the tyramine and tyrosine derivatives (2.31-2.33, 2.41, 2.43, 2.44 and 2.46), within the ascidian extracts. This study confirmed that LC-ICP-MS/ESI-MS is a powerful tool for the dereplication of halogenated metabolites in complex mixtures especially where these compounds are present in very small amounts. This study is also the first report of these compounds (eight of which are known) in African ascidians. Compounds 2.32 and 2.46 have not been reported before from a marine source. Compounds 2.28-2.30 and 2.33 were present in sufficient amounts in the respective ascidian extracts to allow their isolation and structure elucidation using standard spectroscopic techniques Chapter 3 explores the ability of ascidians to accumulate a wide range of metal ions at concentrations which are often orders of magnitude higher than those of the surrounding sea water. Inductively coupled plasma mass spectrometry (ICP-MS) was used to determine the total ion concentrations of 24 metals in 25 Algoa Bay ascidian species. To the best of our knowledge this is the largest and most extensive investigation of metal concentrations in a group of different ascidians occurring in the same area. Hypotheisizing that the metal ion concentrations for each ascidian specimen screened may represent a unique fingerprint for each specimen principal component analysis (PCA) was used in an attempt to establish whether there were spatial, temporal or phylogenetic relationships associated with the metal concentration fingerprints of the ascidians that formed part of this study. The PCA results showed that there were no statistically significant relationships between ascidian metal ion concentrations and either the collection year or the collection site of the ascidians. However, species from the family Didemnidae provided the clearest statistical evidence supporting a phylogenetic relationship between these ascidians and their hyperaccumulated metal ion profiles. Furthermore, these results suggested that ascidian species are indeed actively concentrating metal ions from the surrounding sea water and are not simply sinks for passively accumulated metal ions. Interestingly, the concentration of vanadium in the set of ascidians studied did not appear to correlate with any of the other metals accumulated by these ascidians suggesting that there is possibly a unique method employed for the accumulation of vanadium by ascidians. Chapter 4 investigated this possibility further after the nucleosides 4.10, 4.11, 4.13, 4.15, 4.17 and 4.40 were isolated from the vanadium accumulating ascidian Aplidium monile. Studies into the interactions between nucleosides and vanadyl are unfortunately rare and usually qualitative in nature with limited information provided about the stability or structures of the complexes formed. The vanadyl accumulating aplousobranch ascidians e.g. Aplidium monile dominated our study of Algoa Bay ascidians therefore providing us with the rationale to investigate the relatively little studied binding ability and stability of vandyl-nucleoside complexes. Potentiometric studies were conducted to determine the stability constants of complexes formed between the oxovanadium ion vanadyl (VO2+) and the commercially available nucleosides 4.10-4.14. The data afforded by this analysis clearly confirmed the complexity of the vanadyl/nucleoside complexation and suggested that guanosine (4.12) formed the most stable complex with oxovanadium ions. We were also able to establish a third protonation constant for the hydroxyl moiety in 4.12 with a logK 8.87 which has not been previously reported. Finally, Chapter 5 revisited the cytoxicity two Algoa Bay ascidians, Clavelina sp. and Atriolum marinense the extracts from which produced promising bioactivity results in previous studies against oesophageal cancer cells. The HP-20 fractionated extracts of Clavelina sp. and Atriolum marinense proved to be similalrly cytotoxic to breast cancer cells. With the exception for the 100% acetone(aq)fractions the NMR data for both species suggested that most active non polar fractions were dominated by what appeared to be structurally unremarkable fatty acid glycerides and as such were not pursued further. Purification of the 100% acetone(aq)fraction of A. marinense resulted in the isolation of a styrene trimer, 5.1, common to both ascidian extracts. The NMR simulation software WIN-DAISY was employed to confirm the structure of 5.1. Attempts to establish if 5.1 was an isolation artefact or a product of marine pollution were inconclusive
- Full Text:
- Date Issued: 2016
- Authors: Bromley, Candice Leigh
- Date: 2016
- Subjects: Sea squirts -- South Africa -- Algoa Bay , Marine metabolites , Chemistry, Analytic , Liquid chromatography , Inductively coupled plasma mass spectrometry , Metal ions , Nucleosides , Vanadium
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4560 , http://hdl.handle.net/10962/d1020606
- Description: This thesis investigates the chemistry of 25 ascidian species collected from Algoa Bay, South Africa with a concerted focus on metal accumulation by these ascidians and the possible interaction of these metals with ascidian metabolites. Chapter 2 details the screening techniques employed to establish the presence of nitrogenous metabolites (1H- 15N HMBC), hyper-accumulated metal ions (ICP-MS) and potential metal ion/ ascidian metabolite complexes (LC-ICP-MS/ESI-MS). Unfortunately, exhaustive attempts to detect intact metal ion/ascidian metabolite complexes through the use of liquid chromatography with parallel inductively coupled plasma mass spectrometry/electrospray mass spectrometry (LC-ICPMS/ ESI-MS) were unsuccessful. However, the LC-ICP-MS/ESI-MS data obtained for the crude organic extracts of six of the Algoa Bay ascidian species, Distaplia skoogi, Aplidium monile, Aplidium sp., Didemnum sp., Leptoclindines sp. and Polycitor sp. enabled identification of a number of ten halogenated metabolites, namely the indoles 2.28-2.30, and the tyramine and tyrosine derivatives (2.31-2.33, 2.41, 2.43, 2.44 and 2.46), within the ascidian extracts. This study confirmed that LC-ICP-MS/ESI-MS is a powerful tool for the dereplication of halogenated metabolites in complex mixtures especially where these compounds are present in very small amounts. This study is also the first report of these compounds (eight of which are known) in African ascidians. Compounds 2.32 and 2.46 have not been reported before from a marine source. Compounds 2.28-2.30 and 2.33 were present in sufficient amounts in the respective ascidian extracts to allow their isolation and structure elucidation using standard spectroscopic techniques Chapter 3 explores the ability of ascidians to accumulate a wide range of metal ions at concentrations which are often orders of magnitude higher than those of the surrounding sea water. Inductively coupled plasma mass spectrometry (ICP-MS) was used to determine the total ion concentrations of 24 metals in 25 Algoa Bay ascidian species. To the best of our knowledge this is the largest and most extensive investigation of metal concentrations in a group of different ascidians occurring in the same area. Hypotheisizing that the metal ion concentrations for each ascidian specimen screened may represent a unique fingerprint for each specimen principal component analysis (PCA) was used in an attempt to establish whether there were spatial, temporal or phylogenetic relationships associated with the metal concentration fingerprints of the ascidians that formed part of this study. The PCA results showed that there were no statistically significant relationships between ascidian metal ion concentrations and either the collection year or the collection site of the ascidians. However, species from the family Didemnidae provided the clearest statistical evidence supporting a phylogenetic relationship between these ascidians and their hyperaccumulated metal ion profiles. Furthermore, these results suggested that ascidian species are indeed actively concentrating metal ions from the surrounding sea water and are not simply sinks for passively accumulated metal ions. Interestingly, the concentration of vanadium in the set of ascidians studied did not appear to correlate with any of the other metals accumulated by these ascidians suggesting that there is possibly a unique method employed for the accumulation of vanadium by ascidians. Chapter 4 investigated this possibility further after the nucleosides 4.10, 4.11, 4.13, 4.15, 4.17 and 4.40 were isolated from the vanadium accumulating ascidian Aplidium monile. Studies into the interactions between nucleosides and vanadyl are unfortunately rare and usually qualitative in nature with limited information provided about the stability or structures of the complexes formed. The vanadyl accumulating aplousobranch ascidians e.g. Aplidium monile dominated our study of Algoa Bay ascidians therefore providing us with the rationale to investigate the relatively little studied binding ability and stability of vandyl-nucleoside complexes. Potentiometric studies were conducted to determine the stability constants of complexes formed between the oxovanadium ion vanadyl (VO2+) and the commercially available nucleosides 4.10-4.14. The data afforded by this analysis clearly confirmed the complexity of the vanadyl/nucleoside complexation and suggested that guanosine (4.12) formed the most stable complex with oxovanadium ions. We were also able to establish a third protonation constant for the hydroxyl moiety in 4.12 with a logK 8.87 which has not been previously reported. Finally, Chapter 5 revisited the cytoxicity two Algoa Bay ascidians, Clavelina sp. and Atriolum marinense the extracts from which produced promising bioactivity results in previous studies against oesophageal cancer cells. The HP-20 fractionated extracts of Clavelina sp. and Atriolum marinense proved to be similalrly cytotoxic to breast cancer cells. With the exception for the 100% acetone(aq)fractions the NMR data for both species suggested that most active non polar fractions were dominated by what appeared to be structurally unremarkable fatty acid glycerides and as such were not pursued further. Purification of the 100% acetone(aq)fraction of A. marinense resulted in the isolation of a styrene trimer, 5.1, common to both ascidian extracts. The NMR simulation software WIN-DAISY was employed to confirm the structure of 5.1. Attempts to establish if 5.1 was an isolation artefact or a product of marine pollution were inconclusive
- Full Text:
- Date Issued: 2016
The removal of toxic anions from wastewater using electrospun nanofibers
- Authors: Moronkola, Bridget Adekemi
- Date: 2016
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4564 , http://hdl.handle.net/10962/d1020991
- Description: The presence of arsenic and phosphate in waters, especially wastewater, has become a worldwide problem even till the present time. The current regulation of drinking standard water has become more stringent and requires arsenic content to be reduced to a few parts per billion. Nevertheless, phosphorous pollution, known as the eutrophication, is regarded as one of the main causes of water quality deterioration. Hence, the decontamination of phosphorous from aqueous solutions is of importance for eutrophication control and phosphorous recovery. Efforts are being made to remove these contaminants, arsenic (v) and phosphate from wastewater using low cost adsorbents. In the present study, removal of arsenic(v) and phosphate from wastewater using two novel fabricated sorbent materials; polyvinylmethylketone functionalized 2-amino4,6-dihydroxylpyrimidine (APPMKNFs) prepared via a Schiff base condensation reaction and aminated polyvinylbenzylchloride (PVBC) prepared through a substitution reaction and then quaternized using three alkyl groups (R’ = CH₃, C₂H₅ and C₃H₇) were investigated. The experiments were carried out in batch and solid phase extraction mode. Preliminary experiments were done with series of four sorbent materials (APPMKNFs, R’ = CH₃, C₂H₅ and C₃H₇) in order to find out a suitable and low cost adsorbents for the effective removal of arsenic (v) and phosphate. The best sorbent materials were obtained after the optimization and preparation experiments. The APPMKNFs and R’ = CH₃ were effective for arsenic (v) and phosphate removal from wastewater. The effect of pH, initial sorbate concentration, amount of sorbent, effect of co-exisiting anions and the reusability in batch and solid phase extraction mode were also investigated. From the experiment conducted, the pH shows a decisive factor on arsenic and phosphate removal. Analysis of adsorbent dosage, Kinetic studies and co-existing anions were carried out in order to evaluate sorption parameters. The adsorption isotherms were well fitted by Langmuir than Freundlch isotherm for (APPMKNFs). And more...
- Full Text:
- Date Issued: 2016
- Authors: Moronkola, Bridget Adekemi
- Date: 2016
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4564 , http://hdl.handle.net/10962/d1020991
- Description: The presence of arsenic and phosphate in waters, especially wastewater, has become a worldwide problem even till the present time. The current regulation of drinking standard water has become more stringent and requires arsenic content to be reduced to a few parts per billion. Nevertheless, phosphorous pollution, known as the eutrophication, is regarded as one of the main causes of water quality deterioration. Hence, the decontamination of phosphorous from aqueous solutions is of importance for eutrophication control and phosphorous recovery. Efforts are being made to remove these contaminants, arsenic (v) and phosphate from wastewater using low cost adsorbents. In the present study, removal of arsenic(v) and phosphate from wastewater using two novel fabricated sorbent materials; polyvinylmethylketone functionalized 2-amino4,6-dihydroxylpyrimidine (APPMKNFs) prepared via a Schiff base condensation reaction and aminated polyvinylbenzylchloride (PVBC) prepared through a substitution reaction and then quaternized using three alkyl groups (R’ = CH₃, C₂H₅ and C₃H₇) were investigated. The experiments were carried out in batch and solid phase extraction mode. Preliminary experiments were done with series of four sorbent materials (APPMKNFs, R’ = CH₃, C₂H₅ and C₃H₇) in order to find out a suitable and low cost adsorbents for the effective removal of arsenic (v) and phosphate. The best sorbent materials were obtained after the optimization and preparation experiments. The APPMKNFs and R’ = CH₃ were effective for arsenic (v) and phosphate removal from wastewater. The effect of pH, initial sorbate concentration, amount of sorbent, effect of co-exisiting anions and the reusability in batch and solid phase extraction mode were also investigated. From the experiment conducted, the pH shows a decisive factor on arsenic and phosphate removal. Analysis of adsorbent dosage, Kinetic studies and co-existing anions were carried out in order to evaluate sorption parameters. The adsorption isotherms were well fitted by Langmuir than Freundlch isotherm for (APPMKNFs). And more...
- Full Text:
- Date Issued: 2016
An investigation into the development of knowledge and strategies for the teaching of visual literacy in under-resourced Eastern Cape schools
- Authors: Mbelani, Madeyandile
- Date: 2014
- Subjects: Uncatalogued
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/64401 , vital:28540
- Description: This thesis reports on a multiple case study PhD project that aimed to investigate meaningful and critical development of knowledge and strategies to teach visual literacy, a component of English First Additional Language (FAL) in six under-resourced schools of the Eastern Cape of South Africa. The study begins by locating visual literacy within a broad framework of literacy as a social practice, and discusses its importance. Further, it discusses complexities of making sense of and teaching visual literacy, especially for the majority of in-service teachers who experienced visual literacy neither as learners nor as teacher trainees. The gap between the curriculum and teachers’ classroom practices is what triggered this study to adopt a transformative paradigm. The main research question is, “How can teacher professional development in English Language Teaching advance in-service teachers’ knowledge of and strategies for meaningful and critical teaching and learning of visual literacy?” To respond to this question, I drew on cultural historical activity theory (CHAT) and critical realism (CR) to design four phases of this study that incorporated the seven stages of an expansive learning cycle. These phases focussed on exploring and expanding teachers’ sense making and teaching of visual literacy. I collected data through interviews, document analysis, videoed lessons and change laboratory (CL) workshops. I designed a data analysis tool that brought together CHAT, CR, multimodal social semiotics, critical discourse analysis and pedagogical discourse to make sense of the data. Through a process of reflexivity, the study illuminated layers of factors that constrained meaningful and critical teaching of visual literacy in the empirical, the actual and the real domains of reality. These factors include teachers’ unconscious reproduction of discourses of domination, their intolerance of diverse cultural discourses, resistance to curriculum change, and the fact that they are comfortable with the status quo. I brought these factors to CL workshops for expansive learning. The study contributes in-depth insight into English FAL in-service teacher development in the area of visual literacy. By locating the study within meaning making and teaching of visual literacy, it was possible to interrogate access, diversity, domination and design in teachers’ classroom practices. As a result of this study participants were made aware of the extent to which these factors enabled or hindered meaningful and critical teaching. Participants repositioned themselves as subjects of the activity system, thereby mobilising their agency to take control of the structures and cultures that condition their teaching.
- Full Text:
- Date Issued: 2014
- Authors: Mbelani, Madeyandile
- Date: 2014
- Subjects: Uncatalogued
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/64401 , vital:28540
- Description: This thesis reports on a multiple case study PhD project that aimed to investigate meaningful and critical development of knowledge and strategies to teach visual literacy, a component of English First Additional Language (FAL) in six under-resourced schools of the Eastern Cape of South Africa. The study begins by locating visual literacy within a broad framework of literacy as a social practice, and discusses its importance. Further, it discusses complexities of making sense of and teaching visual literacy, especially for the majority of in-service teachers who experienced visual literacy neither as learners nor as teacher trainees. The gap between the curriculum and teachers’ classroom practices is what triggered this study to adopt a transformative paradigm. The main research question is, “How can teacher professional development in English Language Teaching advance in-service teachers’ knowledge of and strategies for meaningful and critical teaching and learning of visual literacy?” To respond to this question, I drew on cultural historical activity theory (CHAT) and critical realism (CR) to design four phases of this study that incorporated the seven stages of an expansive learning cycle. These phases focussed on exploring and expanding teachers’ sense making and teaching of visual literacy. I collected data through interviews, document analysis, videoed lessons and change laboratory (CL) workshops. I designed a data analysis tool that brought together CHAT, CR, multimodal social semiotics, critical discourse analysis and pedagogical discourse to make sense of the data. Through a process of reflexivity, the study illuminated layers of factors that constrained meaningful and critical teaching of visual literacy in the empirical, the actual and the real domains of reality. These factors include teachers’ unconscious reproduction of discourses of domination, their intolerance of diverse cultural discourses, resistance to curriculum change, and the fact that they are comfortable with the status quo. I brought these factors to CL workshops for expansive learning. The study contributes in-depth insight into English FAL in-service teacher development in the area of visual literacy. By locating the study within meaning making and teaching of visual literacy, it was possible to interrogate access, diversity, domination and design in teachers’ classroom practices. As a result of this study participants were made aware of the extent to which these factors enabled or hindered meaningful and critical teaching. Participants repositioned themselves as subjects of the activity system, thereby mobilising their agency to take control of the structures and cultures that condition their teaching.
- Full Text:
- Date Issued: 2014
Textual representations of migrants and the process of migration in selected South African media a combined critical discourse analysis and corpus linguistics study
- Authors: Crymble, Leigh
- Date: 2011
- Subjects: Immigrants in mass media -- South Africa Mass media and foreign workers -- South Africa Refugees -- Press coverage -- South Africa Xenophobia in mass media -- South Africa Critical discourse analysis Corpora (Linguistics) Sunday Times (Johannesburg, South Africa) City Press (Johannesburg, South Africa) Mail & Guardian
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2342 , http://hdl.handle.net/10962/d1002624
- Description: South Africa has long been associated with racial and ethnic issues surrounding prejudice and discrimination and despite a move post-1994 to a democratic ‘rainbow nation’ society, the country has remained plagued by unequal power relations. One such instance of inequality relates to the marginalisation of migrants which has been realised through xenophobic attitudes and actions, most notably the violence that swept across the country in 2008. Several reasons have been suggested in an attempt to explain the cause of the violence, including claims that migrants are taking ‘our jobs and our women’, migrants are ‘illegal and criminal’ and bringing ‘disease and contamination’ with them from their countries of origin. Although widely accepted that many, if not all, of these beliefs are based on ignorance and hearsay, these extensive generalisations shape and reinforce prejudiced ideologies about migrant communities. It is thus only when confronted with evidence that challenges this dominant discourse, that South Africans are able to reconsider their views. Williams (2008) suggests that for many South Africans, Africa continues to be the ‘dark continent’ that is seen as an ominous, threatening force of which they have very little knowledge. For this reason, anti-immigrant sentiment in a South African context has traditionally been directed at African foreigners. In this study I examine the ways in which African migrants and migrant communities, as well as the overall processes of migration, are depicted by selected South African print media: City Press, Mail & Guardian and Sunday Times. Using a combined Corpus Linguistics and Critical Discourse Analysis approach, I investigate the following questions: How are migrants and the process of migration into South Africa represented by these established newspapers between 2006 and 2010? Are there any differences or similarities between these representations? In particular, what ideologies regarding migrants and migrant communities underlie these representations? My analysis focuses on the landscape of public discourse about migration with an exploration of the rise and fall of the terminologies used to categorise migrants and the social implications of these classifications. Additionally, I analyse the expansive occurrences of negative representations of migrants, particularly through the use of ‘othering’ pronouns ‘us’ versus ‘them’ and through the use of metaphorical language which largely depicts these individuals as en masse natural disasters. I conclude that these discursive elements play a crucial role in contributing to an overall xenophobic rhetoric. Despite subtle differences between the three newspapers which can be accounted for based on their political persuasions and agendas, it is surprising to note how aligned these publications are with regard to their portrayal of migrants. With a few exceptions, this representation positions these individuals as powerless and disenfranchised and maintains the status quo view of migrants as burdens on the South African economy and resources. Overall, the newspaper articles contribute to mainstream dominant discourse on migrants and migration with the underlying ideology that migrants are responsible for the hardships suffered by South African citizens. Thus, this study contributes significantly to existing bodies of research detailing discourse on migrants and emphasises the intrinsic links between language, ideology and society.
- Full Text:
- Date Issued: 2011
- Authors: Crymble, Leigh
- Date: 2011
- Subjects: Immigrants in mass media -- South Africa Mass media and foreign workers -- South Africa Refugees -- Press coverage -- South Africa Xenophobia in mass media -- South Africa Critical discourse analysis Corpora (Linguistics) Sunday Times (Johannesburg, South Africa) City Press (Johannesburg, South Africa) Mail & Guardian
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2342 , http://hdl.handle.net/10962/d1002624
- Description: South Africa has long been associated with racial and ethnic issues surrounding prejudice and discrimination and despite a move post-1994 to a democratic ‘rainbow nation’ society, the country has remained plagued by unequal power relations. One such instance of inequality relates to the marginalisation of migrants which has been realised through xenophobic attitudes and actions, most notably the violence that swept across the country in 2008. Several reasons have been suggested in an attempt to explain the cause of the violence, including claims that migrants are taking ‘our jobs and our women’, migrants are ‘illegal and criminal’ and bringing ‘disease and contamination’ with them from their countries of origin. Although widely accepted that many, if not all, of these beliefs are based on ignorance and hearsay, these extensive generalisations shape and reinforce prejudiced ideologies about migrant communities. It is thus only when confronted with evidence that challenges this dominant discourse, that South Africans are able to reconsider their views. Williams (2008) suggests that for many South Africans, Africa continues to be the ‘dark continent’ that is seen as an ominous, threatening force of which they have very little knowledge. For this reason, anti-immigrant sentiment in a South African context has traditionally been directed at African foreigners. In this study I examine the ways in which African migrants and migrant communities, as well as the overall processes of migration, are depicted by selected South African print media: City Press, Mail & Guardian and Sunday Times. Using a combined Corpus Linguistics and Critical Discourse Analysis approach, I investigate the following questions: How are migrants and the process of migration into South Africa represented by these established newspapers between 2006 and 2010? Are there any differences or similarities between these representations? In particular, what ideologies regarding migrants and migrant communities underlie these representations? My analysis focuses on the landscape of public discourse about migration with an exploration of the rise and fall of the terminologies used to categorise migrants and the social implications of these classifications. Additionally, I analyse the expansive occurrences of negative representations of migrants, particularly through the use of ‘othering’ pronouns ‘us’ versus ‘them’ and through the use of metaphorical language which largely depicts these individuals as en masse natural disasters. I conclude that these discursive elements play a crucial role in contributing to an overall xenophobic rhetoric. Despite subtle differences between the three newspapers which can be accounted for based on their political persuasions and agendas, it is surprising to note how aligned these publications are with regard to their portrayal of migrants. With a few exceptions, this representation positions these individuals as powerless and disenfranchised and maintains the status quo view of migrants as burdens on the South African economy and resources. Overall, the newspaper articles contribute to mainstream dominant discourse on migrants and migration with the underlying ideology that migrants are responsible for the hardships suffered by South African citizens. Thus, this study contributes significantly to existing bodies of research detailing discourse on migrants and emphasises the intrinsic links between language, ideology and society.
- Full Text:
- Date Issued: 2011
The role of small antelope in ecosystem functioning in the Matobo Hills, Zimbabwe
- Authors: Lunt, Nicola
- Date: 2011
- Subjects: Antelopes -- Zimbabwe -- Rhodes Matopos National Park Ecosystem health -- Zimbabwe -- Rhodes Matopos National Park Forest ecology -- Zimbabwe -- Rhodes Matopos National Park Savanna ecology -- Zimbabwe -- Rhodes Matopos National Park Woody plants -- Effect of fires on -- Zimbabwe -- Rhodes Matopos National Park Duikers -- Zimbabwe -- Rhodes Matopos National Park Bushbuck -- Zimbabwe -- Rhodes Matopos National Park Greater kudu -- Zimbabwe -- Rhodes Matopos National Park
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5760 , http://hdl.handle.net/10962/d1005448
- Description: The 28-month study assessed the impacts of five syntopic medium-sized mammalian browsers and one fire event in a woodland savanna in the Matobo Hills, Zimbabwe. Aspects of herbivory, mechanical pressures, seed dispersal and nutrient cycling were investigated for three species of small antelope (common duiker [Sylvicapra grimmia]1, klipspringer [Oreotragus oreotragus] and steenbok [Raphicerus campestris]) and two medium-sized species (bushbuck [Tragelaphus scriptus] and greater kudu [T. strepsiceros]). Focusing on Burkea africana2 woodland, in a system that does not include elephant (Loxodonta africana), effects of browsing antelope on woody and herbaceous vegetation development were investigated using exclusion plots. Browsers regulated woody plant cover (measured as basal stem area), with smaller antelope having a greater impact than larger species. This was linked to feeding height, feeding selectivity and mechanical pressures (e.g. twig breakage and trampling). Fire caused an initial reduction in above-ground standing biomass, but in the presence of fauna, pre-fire equilibria were attained within 15 months. In antelope exclosures, herbaceous biomass increased and woody biomass decreased following fire. Responses by woody vegetation to browsing varied among species, with highly palatable species typically exhibiting compensatory regrowth. Woody species richness and abundance (especially of palatable species) increased in the absence of browsers, but species richness of the herbaceous layer was promoted by moderate disturbance (trampling or fire). Faecal deposition behaviour, primarily the use of latrines by small antelope, resulted in localised soil enrichment within defended territories. Decomposition rates (and therefore return of nutrients to the soil) varied among species and seasons, due to defecation site selection, accessibility to decomposers and desiccation rates of faecal pellets. Controlled seed germination experiments indicated that ingestion by small antelope enhances germination rates of large, hard-seeded fruits such as Sclerocarya birrea. However, germination of savanna seeds may require multiple cues. This study demonstrated the critical roles of small antelope in ecosystem functioning, and highlights the importance of the less visible impacts of frequently overlooked smaller mammalian herbivores. Perturbations to the faunal community, especially small antelope, are predicted to have substantial impacts on woody plant cover.
- Full Text:
- Date Issued: 2011
- Authors: Lunt, Nicola
- Date: 2011
- Subjects: Antelopes -- Zimbabwe -- Rhodes Matopos National Park Ecosystem health -- Zimbabwe -- Rhodes Matopos National Park Forest ecology -- Zimbabwe -- Rhodes Matopos National Park Savanna ecology -- Zimbabwe -- Rhodes Matopos National Park Woody plants -- Effect of fires on -- Zimbabwe -- Rhodes Matopos National Park Duikers -- Zimbabwe -- Rhodes Matopos National Park Bushbuck -- Zimbabwe -- Rhodes Matopos National Park Greater kudu -- Zimbabwe -- Rhodes Matopos National Park
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5760 , http://hdl.handle.net/10962/d1005448
- Description: The 28-month study assessed the impacts of five syntopic medium-sized mammalian browsers and one fire event in a woodland savanna in the Matobo Hills, Zimbabwe. Aspects of herbivory, mechanical pressures, seed dispersal and nutrient cycling were investigated for three species of small antelope (common duiker [Sylvicapra grimmia]1, klipspringer [Oreotragus oreotragus] and steenbok [Raphicerus campestris]) and two medium-sized species (bushbuck [Tragelaphus scriptus] and greater kudu [T. strepsiceros]). Focusing on Burkea africana2 woodland, in a system that does not include elephant (Loxodonta africana), effects of browsing antelope on woody and herbaceous vegetation development were investigated using exclusion plots. Browsers regulated woody plant cover (measured as basal stem area), with smaller antelope having a greater impact than larger species. This was linked to feeding height, feeding selectivity and mechanical pressures (e.g. twig breakage and trampling). Fire caused an initial reduction in above-ground standing biomass, but in the presence of fauna, pre-fire equilibria were attained within 15 months. In antelope exclosures, herbaceous biomass increased and woody biomass decreased following fire. Responses by woody vegetation to browsing varied among species, with highly palatable species typically exhibiting compensatory regrowth. Woody species richness and abundance (especially of palatable species) increased in the absence of browsers, but species richness of the herbaceous layer was promoted by moderate disturbance (trampling or fire). Faecal deposition behaviour, primarily the use of latrines by small antelope, resulted in localised soil enrichment within defended territories. Decomposition rates (and therefore return of nutrients to the soil) varied among species and seasons, due to defecation site selection, accessibility to decomposers and desiccation rates of faecal pellets. Controlled seed germination experiments indicated that ingestion by small antelope enhances germination rates of large, hard-seeded fruits such as Sclerocarya birrea. However, germination of savanna seeds may require multiple cues. This study demonstrated the critical roles of small antelope in ecosystem functioning, and highlights the importance of the less visible impacts of frequently overlooked smaller mammalian herbivores. Perturbations to the faunal community, especially small antelope, are predicted to have substantial impacts on woody plant cover.
- Full Text:
- Date Issued: 2011
Myth, Music & Modernism: the Wagnerian dimension in Virginia Woolf's Mrs Dalloway and the waves and James Joyce’s Finnegans Wake
- Authors: McGregor, Jamie Alexander
- Date: 2009
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/77069 , vital:30662
- Description: The study of Wagner's influence on the modernist novel is an established field with clear room for further contributions. Very little of the criticism undertaken to date takes full cognizance of the philosophical content of Wagner's dramas: a revolutionary form of romanticism that calls into question the very nature of the world, its most radical component being Schopenhauer's version of transcendental idealism. The compatibility of this doctrine with Wagner's earlier work, with its already marked privileging of myth over history, enabled his later dramas, consciously influenced by Schopenhauer, to crown a body of work greater than the sum of its parts. In works by Virginia Woolf and James Joyce, the "translation" of Wagnerian ideas into novelistic form demonstrates how they might be applied in "real life". In Mrs Dalloway, the figure of Septimus can be read as partly modelled on Wagner's heroes Siegfried and Tristan, two outstanding examples of the opposing heroic types found throughout his oeuvre, whose contrasting attributes are fused in Septimus's bipolar personality. The Wagnerian pattern also throws light on Septimus's transcendental "relationship" with a woman he does not even know, and on the implied noumenal identity of seemingly isolated individuals. In The Waves, the allusions to both Parsifal and the Ring need to be reconsidered in light of the fact that these works' heroes are all but identical (a fact overlooked in previous criticism); as Wagner's solar hero par excellence, Siegfried is central to the novel's cyclical symbolism. The Waves also revisits the question of identity but in a more cosmic context – the metaphysical unity of everything. In Finnegans Wake, the symbolism of the cosmic cycle is again related to the Ring, as are Wagner's two heroic types to the Shem / Shaun opposition (the Joyce / Woolf parallels here have also been overlooked in criticism to date). All three texts reveal a fascination with the two contrasting faces of a Wagnerian hero who embodies the dual nature of reality, mirroring in himself the eternal rise and fall of world history and, beyond them, the timeless stasis of myth.
- Full Text:
- Date Issued: 2009
- Authors: McGregor, Jamie Alexander
- Date: 2009
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/77069 , vital:30662
- Description: The study of Wagner's influence on the modernist novel is an established field with clear room for further contributions. Very little of the criticism undertaken to date takes full cognizance of the philosophical content of Wagner's dramas: a revolutionary form of romanticism that calls into question the very nature of the world, its most radical component being Schopenhauer's version of transcendental idealism. The compatibility of this doctrine with Wagner's earlier work, with its already marked privileging of myth over history, enabled his later dramas, consciously influenced by Schopenhauer, to crown a body of work greater than the sum of its parts. In works by Virginia Woolf and James Joyce, the "translation" of Wagnerian ideas into novelistic form demonstrates how they might be applied in "real life". In Mrs Dalloway, the figure of Septimus can be read as partly modelled on Wagner's heroes Siegfried and Tristan, two outstanding examples of the opposing heroic types found throughout his oeuvre, whose contrasting attributes are fused in Septimus's bipolar personality. The Wagnerian pattern also throws light on Septimus's transcendental "relationship" with a woman he does not even know, and on the implied noumenal identity of seemingly isolated individuals. In The Waves, the allusions to both Parsifal and the Ring need to be reconsidered in light of the fact that these works' heroes are all but identical (a fact overlooked in previous criticism); as Wagner's solar hero par excellence, Siegfried is central to the novel's cyclical symbolism. The Waves also revisits the question of identity but in a more cosmic context – the metaphysical unity of everything. In Finnegans Wake, the symbolism of the cosmic cycle is again related to the Ring, as are Wagner's two heroic types to the Shem / Shaun opposition (the Joyce / Woolf parallels here have also been overlooked in criticism to date). All three texts reveal a fascination with the two contrasting faces of a Wagnerian hero who embodies the dual nature of reality, mirroring in himself the eternal rise and fall of world history and, beyond them, the timeless stasis of myth.
- Full Text:
- Date Issued: 2009
A critical analysis of oppositional discourses of the ideal female body in women's conversations
- Authors: Pienaar, Kiran Merle
- Date: 2007
- Subjects: Conversation analysis Women in mass media Self-perception in women Self-perception in adolescence Body image
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2358 , http://hdl.handle.net/10962/d1002641
- Description: Socialisation agents such as the popular media and same age female peers construct and reproduce notions of what is physically ideal, feminine and beautiful in a woman (Hesse-Biber 1996). My interest lies in how a group of young women reproduce, contest and possibly transform such notions in conversations with their same age female friends. The study aims to answer the following question: What ideologies are reflected and perpetuated in the discourses associated with the ideal female body? Since notions of what is ideal and beautiful are indeterminate and in perpetual flux, I focus in particular on areas of contradiction and contestation in the body talk conversations. As such, the analysis examines three extracts in which the young women draw on oppositional discourses to construct notions of female beauty. I believe that these extracts represent discursive struggles in relation to the dominant Western ideal of the slim, toned female body, an ideal which more closely resembles a newly pubescent girl's body than the curvaceous, shapely body of an adult woman (Bartky 2003; Grogan 1998). My analysis is based on conversational data collected from sixteen, white adolescent English-speaking women between the ages of fourteen and eighteen who attend a boarding school in Grahamstown. I elicited the body talk data using three stimulus exercises designed to encourage discussion on topics such as the overweight female body, dieting and the ideal body. I selected three extracts from the recorded conversations and used the methodological framework of Critical Discourse Analysis to analyse the data. This framework proposes three interdependent stages of analysis: 1) the Description of the formal features of the text, 2) the Interpretation of the text in terms of the participants' background assumptions, the situational context and the intertextual context and 3) an Explanation of the text in light of the sociocultural context and the text's contribution to the reproduction or transformation of the status quo. Since I was present during the conversational recordings and contributed to the discussions, part of the interpretation stage of analysis critically evaluates how the asymmetrical power relations between myself and the participants influenced the conversations. In this regard, my findings attest to my coercive role in promoting conservative, reactionary discourses which sustain the dominance of traditional ideologies of female beauty and which stifle oppositional ideologies. My interpretation of the extracts also reveals that, in their discussions of topics such as excess weight, female ageing and cosmetic surgery, the young women negotiate alternative conceptions of what constitutes the ideal female body. However, the articulation of an alternative beauty ideal, one which values women of different body sizes and ages is not sustained in the extracts. By discussing the relationship between these alternative constructions and dominant norms of beauty, I show how the prevailing ideal of the youthful, slim, toned female body wins out in the conversations. The interpretation of the extracts also reveals the participants' preoccupation with the pursuit of health and well¬being. In this respect, the young women construct the ideal body as not only slim and youthful, but also healthy. In my explanation of the extracts, I explore the sociocultural factors which have contributed to the rise of the health ethic. In concluding, I argue that the valorisation of the healthy body in the conversations, far from challenging the imperative to be thin, actually reinforces it by constructing dieting as a necessary adjunct to the pursuit of health. From this perspective, the preoccupation with attaining the ideal thin, toned body can be justified in terms of a desire to be healthy.
- Full Text: false
- Date Issued: 2007
- Authors: Pienaar, Kiran Merle
- Date: 2007
- Subjects: Conversation analysis Women in mass media Self-perception in women Self-perception in adolescence Body image
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2358 , http://hdl.handle.net/10962/d1002641
- Description: Socialisation agents such as the popular media and same age female peers construct and reproduce notions of what is physically ideal, feminine and beautiful in a woman (Hesse-Biber 1996). My interest lies in how a group of young women reproduce, contest and possibly transform such notions in conversations with their same age female friends. The study aims to answer the following question: What ideologies are reflected and perpetuated in the discourses associated with the ideal female body? Since notions of what is ideal and beautiful are indeterminate and in perpetual flux, I focus in particular on areas of contradiction and contestation in the body talk conversations. As such, the analysis examines three extracts in which the young women draw on oppositional discourses to construct notions of female beauty. I believe that these extracts represent discursive struggles in relation to the dominant Western ideal of the slim, toned female body, an ideal which more closely resembles a newly pubescent girl's body than the curvaceous, shapely body of an adult woman (Bartky 2003; Grogan 1998). My analysis is based on conversational data collected from sixteen, white adolescent English-speaking women between the ages of fourteen and eighteen who attend a boarding school in Grahamstown. I elicited the body talk data using three stimulus exercises designed to encourage discussion on topics such as the overweight female body, dieting and the ideal body. I selected three extracts from the recorded conversations and used the methodological framework of Critical Discourse Analysis to analyse the data. This framework proposes three interdependent stages of analysis: 1) the Description of the formal features of the text, 2) the Interpretation of the text in terms of the participants' background assumptions, the situational context and the intertextual context and 3) an Explanation of the text in light of the sociocultural context and the text's contribution to the reproduction or transformation of the status quo. Since I was present during the conversational recordings and contributed to the discussions, part of the interpretation stage of analysis critically evaluates how the asymmetrical power relations between myself and the participants influenced the conversations. In this regard, my findings attest to my coercive role in promoting conservative, reactionary discourses which sustain the dominance of traditional ideologies of female beauty and which stifle oppositional ideologies. My interpretation of the extracts also reveals that, in their discussions of topics such as excess weight, female ageing and cosmetic surgery, the young women negotiate alternative conceptions of what constitutes the ideal female body. However, the articulation of an alternative beauty ideal, one which values women of different body sizes and ages is not sustained in the extracts. By discussing the relationship between these alternative constructions and dominant norms of beauty, I show how the prevailing ideal of the youthful, slim, toned female body wins out in the conversations. The interpretation of the extracts also reveals the participants' preoccupation with the pursuit of health and well¬being. In this respect, the young women construct the ideal body as not only slim and youthful, but also healthy. In my explanation of the extracts, I explore the sociocultural factors which have contributed to the rise of the health ethic. In concluding, I argue that the valorisation of the healthy body in the conversations, far from challenging the imperative to be thin, actually reinforces it by constructing dieting as a necessary adjunct to the pursuit of health. From this perspective, the preoccupation with attaining the ideal thin, toned body can be justified in terms of a desire to be healthy.
- Full Text: false
- Date Issued: 2007
An investigation into the pharmacological properties of propolis
- Authors: Hu, Fuliang
- Date: 2005
- Subjects: Propolis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5831 , http://hdl.handle.net/10962/d1007955
- Description: Propolis is a traditional value-added product from beekeeping, and has been widely used in medicine and the chemical industry because of its extensive biological activities. In this dissertation some pharmacological properties of propolis extracted by ethanol (EEP) and water (WSP) were studied by means of modem pharmacological methods. The results of the experiments show the following: 1. Both EEP and WSD led to decreased levels of fasting blood glucose (FBG), glycosylated haemoglobin (HBA1c), Fructosamine (FRU), blood urea nitrogen (BUN), uric acid (UA), malonaldehyde (MDA), nitric oxide (NO), nitric oxide synthetase (NOS), total cholesterol (TC), triglyceride (TG), low-density lipoprotein cholesterol (LDL-C) and very-low density lipoprotein cholesterol (VLDL-C) in the serum of fasting rats; and, to increased serum levels of high-density lipoprotein cholesterol (HDL-C) and superoxide dismutase (SOD) in rats with diabetes mellitus. This suggests that propolis can control blood glucose and modulate the metabolism of glucose, blood lipid and protein, leading to decreased outputs of lipid peroxidation and scavenging free radicals in rats with diabetes mellitus. 2. Both EEP and WSD showed inhibitory effects on swelling induced by Freund's complete adjuvant and decreased the degree of local inflammatory responses; significantly inhibited the increase of interleukin-6 (lL-6) in inflamed tissues, but had no significant effect on levels of interleukin-2 (IL-2) and interferon-y (IFN-y). The results are consistent with the interpretation that EEP and WSD may exert these effects by inhibiting the activation and differentiation of mononuclear macrophages. 3. Both EEP and WSD exhibited significant anti-inflammatory effects in animal models with respect to thoracic capillary vessel leakage in mice, Carrageenan-induced oedema, Carrageen-aninduced pleurisy and acute lung damage in rats. The mechanisms for the anti-inflammatory effects probably involve decreasing prostaglandin and NO levels. 4. Both EEP and WSD had an inhibitory effect on the level of TG, TC, LDL-C, glutamic-pyruvic transaminase (GPT) and glutamic-oxalacetic transaminase (GOT) in serum, and TC, TG and MDA in liver of hyperlipidemic SD rats; but were without effects on HDL-C, MDA, SOD and NO in serum. EEP also reduced body weight, liver weight and liver index, but WSD did not reduce those indexes. The results showed that the two extracts contribute to the improvement of lipid metabolism in hyperlipidemic rats and provide them with the required anti-oxidative activity. 5. The 80% ethanol extracts of propolis had the highest flavonoid content. The flavone content of water extracts of propolis were obtained with a natural surface-active agent, under ultrasonic perturbation at 80°C, for 12 h and was 6.7 times greater than that of propolis extracted with water at room temperature. Compared to EEP, WSD has the same or a greater anti-tumor or anti-inflammation effect at the same dosage, and shows considerable pharmacological potential especially because of its low side effects and ease of preparation.
- Full Text:
- Date Issued: 2005
- Authors: Hu, Fuliang
- Date: 2005
- Subjects: Propolis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5831 , http://hdl.handle.net/10962/d1007955
- Description: Propolis is a traditional value-added product from beekeeping, and has been widely used in medicine and the chemical industry because of its extensive biological activities. In this dissertation some pharmacological properties of propolis extracted by ethanol (EEP) and water (WSP) were studied by means of modem pharmacological methods. The results of the experiments show the following: 1. Both EEP and WSD led to decreased levels of fasting blood glucose (FBG), glycosylated haemoglobin (HBA1c), Fructosamine (FRU), blood urea nitrogen (BUN), uric acid (UA), malonaldehyde (MDA), nitric oxide (NO), nitric oxide synthetase (NOS), total cholesterol (TC), triglyceride (TG), low-density lipoprotein cholesterol (LDL-C) and very-low density lipoprotein cholesterol (VLDL-C) in the serum of fasting rats; and, to increased serum levels of high-density lipoprotein cholesterol (HDL-C) and superoxide dismutase (SOD) in rats with diabetes mellitus. This suggests that propolis can control blood glucose and modulate the metabolism of glucose, blood lipid and protein, leading to decreased outputs of lipid peroxidation and scavenging free radicals in rats with diabetes mellitus. 2. Both EEP and WSD showed inhibitory effects on swelling induced by Freund's complete adjuvant and decreased the degree of local inflammatory responses; significantly inhibited the increase of interleukin-6 (lL-6) in inflamed tissues, but had no significant effect on levels of interleukin-2 (IL-2) and interferon-y (IFN-y). The results are consistent with the interpretation that EEP and WSD may exert these effects by inhibiting the activation and differentiation of mononuclear macrophages. 3. Both EEP and WSD exhibited significant anti-inflammatory effects in animal models with respect to thoracic capillary vessel leakage in mice, Carrageenan-induced oedema, Carrageen-aninduced pleurisy and acute lung damage in rats. The mechanisms for the anti-inflammatory effects probably involve decreasing prostaglandin and NO levels. 4. Both EEP and WSD had an inhibitory effect on the level of TG, TC, LDL-C, glutamic-pyruvic transaminase (GPT) and glutamic-oxalacetic transaminase (GOT) in serum, and TC, TG and MDA in liver of hyperlipidemic SD rats; but were without effects on HDL-C, MDA, SOD and NO in serum. EEP also reduced body weight, liver weight and liver index, but WSD did not reduce those indexes. The results showed that the two extracts contribute to the improvement of lipid metabolism in hyperlipidemic rats and provide them with the required anti-oxidative activity. 5. The 80% ethanol extracts of propolis had the highest flavonoid content. The flavone content of water extracts of propolis were obtained with a natural surface-active agent, under ultrasonic perturbation at 80°C, for 12 h and was 6.7 times greater than that of propolis extracted with water at room temperature. Compared to EEP, WSD has the same or a greater anti-tumor or anti-inflammation effect at the same dosage, and shows considerable pharmacological potential especially because of its low side effects and ease of preparation.
- Full Text:
- Date Issued: 2005
The assessment of first-line management competencies at a selected automotive manufacturer using a recognition of prior learning approach
- Authors: Poisat, Paul
- Date: 2001
- Subjects: Executives -- Rating of , Automobile industry and trade -- Management -- Case studies
- Language: English
- Type: Thesis , Masters , MTech (Human Resources Management)
- Identifier: vital:10871 , http://hdl.handle.net/10948/41 , Executives -- Rating of , Automobile industry and trade -- Management -- Case studies
- Description: This research addresses the problem of determining which managerial competencies first-line managers operating in a world class organisation should have. To achieve this objective a three-step method was followed. Firstly, an approach had to be found for the assessment of managerial competencies at the selected organisation involved in the research project. A comprehensive literature survey was conducted in an attempt to establish an approach and identify management competencies for first-line managers. Secondly, the recognition of prior learning (RPL) approaches appropriate to first-line managers were investigated and synthesized with the managerial competence approach of step one. Finally, the managerial competencies were assessed utilising the matrix of managerial competence instrument developed in accordance with the findings of the research. The information obtained from the literature study and from the candidates who were assessed resulted in various findings and recommendations. Using the matrix of managerial competence instrument, it was found that the majority of first-line managers at the organisation were competent. Notwithstanding this finding, a major recommendation is that the organisation should become more future and development orientated in its training strategy. Finally, the research project has created the foundation for the development of a managerial competency model at the selected organisation. Findings of the literature survey and development of the RPL instrument provide guidelines for future RPL initiatives, both at the selected organisation and at the Port Elizabeth Technikon.
- Full Text:
- Date Issued: 2001
- Authors: Poisat, Paul
- Date: 2001
- Subjects: Executives -- Rating of , Automobile industry and trade -- Management -- Case studies
- Language: English
- Type: Thesis , Masters , MTech (Human Resources Management)
- Identifier: vital:10871 , http://hdl.handle.net/10948/41 , Executives -- Rating of , Automobile industry and trade -- Management -- Case studies
- Description: This research addresses the problem of determining which managerial competencies first-line managers operating in a world class organisation should have. To achieve this objective a three-step method was followed. Firstly, an approach had to be found for the assessment of managerial competencies at the selected organisation involved in the research project. A comprehensive literature survey was conducted in an attempt to establish an approach and identify management competencies for first-line managers. Secondly, the recognition of prior learning (RPL) approaches appropriate to first-line managers were investigated and synthesized with the managerial competence approach of step one. Finally, the managerial competencies were assessed utilising the matrix of managerial competence instrument developed in accordance with the findings of the research. The information obtained from the literature study and from the candidates who were assessed resulted in various findings and recommendations. Using the matrix of managerial competence instrument, it was found that the majority of first-line managers at the organisation were competent. Notwithstanding this finding, a major recommendation is that the organisation should become more future and development orientated in its training strategy. Finally, the research project has created the foundation for the development of a managerial competency model at the selected organisation. Findings of the literature survey and development of the RPL instrument provide guidelines for future RPL initiatives, both at the selected organisation and at the Port Elizabeth Technikon.
- Full Text:
- Date Issued: 2001
Towards a collaborative approach to teacher professional development : a journey of negotiation
- Authors: Southwood, Sue
- Date: 2001
- Subjects: Teachers -- Training of -- South Africa Teachers -- In-service training -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1866 , http://hdl.handle.net/10962/d1004649
- Description: The research presented in this thesis is a case study, based on ethnographic principles, located in the interpretive paradigm of qualitative research. The focus is specifically on the development of a collaborative approach ro teacher professional development: an approach that recognises and celebrates teachers themselves as resources for their own and other teachers' professional development. The study was carried out over a period of four years with a group of twelve teachers who had recognised the need and expressed the desire to develop their teaching. The research evolved in two main phases. The initial phase was based on the implementation and evaluation of a project designed to encourage a collaborative approach to teacher development based on mutual peer support. This led to a second phase, the main focus of the research, aimed at gaining a greater understanding of the teachers' situation and situating their practice in the wider context generated by this understanding. Conversations with the teachers led to the identification of dimensions and tensions characterising their experience. The research presented here, represents an attempt to understand, interpret and make recommendations relating to the professional development of teachers. The understanding is linked to the teachers' educational biographies and experience of the culture in which they are situated. The interpretation is based on what may be viewed as a dynamic ongoing construction of meaning - a journey of negotiation. The text, described as a narrative collage, a tapestry of voices interwoven by threads of negotiation, represents a collaborative accomplishment. The teachers' words have been interpretively framed and these constructions validated in an interpersonal construction of social reality. The reader is invited to engage in an act of complicity, to collude with the text in the construction and negotiation of shared meaning, possibly finding resonance with their own situations. Reflections on the teachers' experience reveal journeys which resonate with that of the society in which the school is located - 'a case in transition' - situated between an environment characterised by constrained cooperation and an environment characterised by freer collaboration. The overall tension may be viewed metaphorically as a 'Tug o' War'. On one end of the rope is a cultural legacy of authority, isolation, social division and conservatism, while on the other end there is a pull towards greater autonomy and interaction, to adapt rather than conserve and to work together in mutual collegial support: a struggle between cooperating with what is and collaborating towards what could be. The main contention of this thesis is that we ought strongly to support and encourage collaborative approaches to professional development based on mutual peer support. We need to look towards a future of open professionalism where the teachers are regarded as key persons in the process. The attainment of such an ideal needs to be seen as part of systemic changes in management, policies and structure geared towards greater inclusivity and democratic practice; it necessitates a coherent approach that is based on relationships of mutual respect and appreciation.
- Full Text:
- Date Issued: 2001
- Authors: Southwood, Sue
- Date: 2001
- Subjects: Teachers -- Training of -- South Africa Teachers -- In-service training -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1866 , http://hdl.handle.net/10962/d1004649
- Description: The research presented in this thesis is a case study, based on ethnographic principles, located in the interpretive paradigm of qualitative research. The focus is specifically on the development of a collaborative approach ro teacher professional development: an approach that recognises and celebrates teachers themselves as resources for their own and other teachers' professional development. The study was carried out over a period of four years with a group of twelve teachers who had recognised the need and expressed the desire to develop their teaching. The research evolved in two main phases. The initial phase was based on the implementation and evaluation of a project designed to encourage a collaborative approach to teacher development based on mutual peer support. This led to a second phase, the main focus of the research, aimed at gaining a greater understanding of the teachers' situation and situating their practice in the wider context generated by this understanding. Conversations with the teachers led to the identification of dimensions and tensions characterising their experience. The research presented here, represents an attempt to understand, interpret and make recommendations relating to the professional development of teachers. The understanding is linked to the teachers' educational biographies and experience of the culture in which they are situated. The interpretation is based on what may be viewed as a dynamic ongoing construction of meaning - a journey of negotiation. The text, described as a narrative collage, a tapestry of voices interwoven by threads of negotiation, represents a collaborative accomplishment. The teachers' words have been interpretively framed and these constructions validated in an interpersonal construction of social reality. The reader is invited to engage in an act of complicity, to collude with the text in the construction and negotiation of shared meaning, possibly finding resonance with their own situations. Reflections on the teachers' experience reveal journeys which resonate with that of the society in which the school is located - 'a case in transition' - situated between an environment characterised by constrained cooperation and an environment characterised by freer collaboration. The overall tension may be viewed metaphorically as a 'Tug o' War'. On one end of the rope is a cultural legacy of authority, isolation, social division and conservatism, while on the other end there is a pull towards greater autonomy and interaction, to adapt rather than conserve and to work together in mutual collegial support: a struggle between cooperating with what is and collaborating towards what could be. The main contention of this thesis is that we ought strongly to support and encourage collaborative approaches to professional development based on mutual peer support. We need to look towards a future of open professionalism where the teachers are regarded as key persons in the process. The attainment of such an ideal needs to be seen as part of systemic changes in management, policies and structure geared towards greater inclusivity and democratic practice; it necessitates a coherent approach that is based on relationships of mutual respect and appreciation.
- Full Text:
- Date Issued: 2001
Baylis-Hillman derived benzopyrans and related systems : a synthetic and mechanistic study
- Authors: Robinson, Ross Stuart
- Date: 1998
- Subjects: Benzopyrans Coumarins Heterocyclic compounds -- Derivatives
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4429 , http://hdl.handle.net/10962/d1007193
- Description: The Baylis-Hillman reaction between substituted salicylaldehydes and various acrylate species has been shown to afford complex reaction mixtures, careful chromatography of which has led to the isolation of an extensive range of novel compounds. One- and two-dimensional NMR spectroscopic, mass spectrometric and X-ray crystallographic analysis of these compounds have permitted identification of no less than eight general classes of chromene and coumarin derivatives. The formation of the various product types is attributed to cascades of successive reactions stemming, in each case, from a Baylis-Hillman product as the common intermediate. The mechanistic sequence involved in the formation of the various chromene and coumarin derivatives have been elucidated by examining isolated or specifically prepared compounds as putative reaction intermediates. Conjugate addition and acyl or allylic substitution by various nucleophiles appear to be common processes in the formation of the chromene and coumarin derivatives, and studies focussing on these processes have been undertaken. Reactions of Baylis-Hillman adducts have been carried out, using oxygen, sulfur and nitrogen nucleophiles, in order to explore stereoselectivity and regioselectivity trends. The results show that the reactions proceed with a very high degree of regioselectivity, affording conjugate addition rather than acyl substitution products. The diastereoselectivity observed for the addition products, however was typically low. A kinetic study to explore the regioselectivity of the reaction between various Baylis-Hillman derived halogeno esters and the nucleophile, methyl 3-oxobutanolate enloate, in two different base-solvent systems at high dilution was also undertaken. The reactions were monitored by ¹H NMR spectroscopy, and the results revealed that the reaction kinetics are more complex than originally anticipated. A mechanistic rationalisation is offered which is consistent with both the kinetic data and the observed regioselectivity trends.
- Full Text:
- Date Issued: 1998
- Authors: Robinson, Ross Stuart
- Date: 1998
- Subjects: Benzopyrans Coumarins Heterocyclic compounds -- Derivatives
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4429 , http://hdl.handle.net/10962/d1007193
- Description: The Baylis-Hillman reaction between substituted salicylaldehydes and various acrylate species has been shown to afford complex reaction mixtures, careful chromatography of which has led to the isolation of an extensive range of novel compounds. One- and two-dimensional NMR spectroscopic, mass spectrometric and X-ray crystallographic analysis of these compounds have permitted identification of no less than eight general classes of chromene and coumarin derivatives. The formation of the various product types is attributed to cascades of successive reactions stemming, in each case, from a Baylis-Hillman product as the common intermediate. The mechanistic sequence involved in the formation of the various chromene and coumarin derivatives have been elucidated by examining isolated or specifically prepared compounds as putative reaction intermediates. Conjugate addition and acyl or allylic substitution by various nucleophiles appear to be common processes in the formation of the chromene and coumarin derivatives, and studies focussing on these processes have been undertaken. Reactions of Baylis-Hillman adducts have been carried out, using oxygen, sulfur and nitrogen nucleophiles, in order to explore stereoselectivity and regioselectivity trends. The results show that the reactions proceed with a very high degree of regioselectivity, affording conjugate addition rather than acyl substitution products. The diastereoselectivity observed for the addition products, however was typically low. A kinetic study to explore the regioselectivity of the reaction between various Baylis-Hillman derived halogeno esters and the nucleophile, methyl 3-oxobutanolate enloate, in two different base-solvent systems at high dilution was also undertaken. The reactions were monitored by ¹H NMR spectroscopy, and the results revealed that the reaction kinetics are more complex than originally anticipated. A mechanistic rationalisation is offered which is consistent with both the kinetic data and the observed regioselectivity trends.
- Full Text:
- Date Issued: 1998
An investigation into the pre-service training of secondary school mathematics teachers at colleges of education administered by the House of Representatives
- Authors: Hendricks, Mogamat Armien
- Date: 1989
- Subjects: Mathematics teachers -- Training of -- South Africa Mathematics -- Study and teaching (Higher) -- South Africa Colored people (South Africa) -- Education Colored people (South Africa) -- Education (Secondary)
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1864 , http://hdl.handle.net/10962/d1004591
- Description: This study involves an investigatioh into the nature and effectiveness of the pre-service training, where provided, of secondary school Mathematics teachers at the 11 colleges of education administered by the House of Representatives in the Republic of South Africa. The purpose of this study is to determine whether the HDE (Secondary) course offered at some of the aforementioned colleges of education is justified, In spite of the fact that it contravenes the requirements of the Education Act, No. 73 of 1969. Three different questionnaires were designed and during 1986 were sent to heads of Mathematics departments at the aforementioned colleges of education , to Mathematics teacher educators at these colleges and to beginning secondary school Mathematics teachers, teaching at schools administered by the House of Representatives in the Eastern Cape and Natal. The findings of this study show that the secondary course for Mathematics teachers is only offered at 5 of the 11 colleges of education and only a small percentage of students take this course. During 1986 most of the Mathematics teacher educators at the colleges of education were not suitably qualified. The study also shows that the Mathematics curriculum for the training of secondary school teachers is inadequate and a revision thereof is thus recommended. An obvious conclusion drawn from the findings is that the training of secondary school Mathematics teachers at these colleges of education is still in an early stage of development. One of the main recommendations of this study is that the training of secondary school Mathematics teachers at colleges of education administered by the House of Representatives should be terminated , in view of its ineffectiveness and In accordance with Education Act , No . 73 of 1969. On the other hand, in case this is not possible, suggestions are also made for the improvement of the pre-service training of secondary school mathematics teachers at these colleges of education.
- Full Text:
- Date Issued: 1989
- Authors: Hendricks, Mogamat Armien
- Date: 1989
- Subjects: Mathematics teachers -- Training of -- South Africa Mathematics -- Study and teaching (Higher) -- South Africa Colored people (South Africa) -- Education Colored people (South Africa) -- Education (Secondary)
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1864 , http://hdl.handle.net/10962/d1004591
- Description: This study involves an investigatioh into the nature and effectiveness of the pre-service training, where provided, of secondary school Mathematics teachers at the 11 colleges of education administered by the House of Representatives in the Republic of South Africa. The purpose of this study is to determine whether the HDE (Secondary) course offered at some of the aforementioned colleges of education is justified, In spite of the fact that it contravenes the requirements of the Education Act, No. 73 of 1969. Three different questionnaires were designed and during 1986 were sent to heads of Mathematics departments at the aforementioned colleges of education , to Mathematics teacher educators at these colleges and to beginning secondary school Mathematics teachers, teaching at schools administered by the House of Representatives in the Eastern Cape and Natal. The findings of this study show that the secondary course for Mathematics teachers is only offered at 5 of the 11 colleges of education and only a small percentage of students take this course. During 1986 most of the Mathematics teacher educators at the colleges of education were not suitably qualified. The study also shows that the Mathematics curriculum for the training of secondary school teachers is inadequate and a revision thereof is thus recommended. An obvious conclusion drawn from the findings is that the training of secondary school Mathematics teachers at these colleges of education is still in an early stage of development. One of the main recommendations of this study is that the training of secondary school Mathematics teachers at colleges of education administered by the House of Representatives should be terminated , in view of its ineffectiveness and In accordance with Education Act , No . 73 of 1969. On the other hand, in case this is not possible, suggestions are also made for the improvement of the pre-service training of secondary school mathematics teachers at these colleges of education.
- Full Text:
- Date Issued: 1989
The sedimentology and palaeoenvironmental significance of vlei sediments on the Winterberg range, South Africa
- Authors: Dewey, Felicity Joy
- Date: 1989
- Subjects: Geology, Stratigraphic -- Holocene Sedimentology Sediments (Geology) -- South Africa -- Eastern Cape -- Winterberg range Geology, Stratigraphic -- Pleistocene Paleoecology -- South Africa -- Eastern Cape -- Winterberg range
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4797 , http://hdl.handle.net/10962/d1001897
- Description: Palaeoenvironmental reconstruction of the late Pleistocene and Holocene geological periods for central and southern Africa has been hampered by the erratic distribution of suitable sites, incomplete and inaccurately dated sequences and the limited nature of published data. One geomorphological feature which has supplied valuable evidence for fluctuations in past environmental conditions, is the vlei or dambo. The type-site of these waterlogged features is in south central Africa, but similar features have been described on other continents. The clastic and organic sediments contained within these features are affected by, and therefore reflect to some degree, the environment under which they were formed. The characteristics of the sediments supply information as to their transport and mechanisms of deposition. From these processes, the environmental conditions at the time of vlei formation can be inferred. The environmental history of the Eastern Cape region has been considerably neglected, and is far less well understood than other countries such as Malawi, Zambia and Zimbabwe. A study site in the Winterberg Range (Eastern Cape) was selected which permitted the comparison of two vleis, the objective being to establish an accurate late Pleistocene sediment chronology for the entire plateau area. Radiocarbon dates from organic layers indicate that these sediments span the last 12 000 years BP, suggesting that organic accumulation at this site began at roughly the same time as at sites further afield. The vlei sediments are analysed in terms of their morphology, particle slze distribution, and other physical and chemical characteristics. These data facilitate the construction of detailed stratigraphic diagrams and a chronological summary of sediment accumulation, from which the period and governing processes of vlei development under changing environments may be described. It is found that the Winterberg vleis contain sediments which respond to changes in the prevailing environment. This makes these sediments useful indices from which to trace such changes during the late Pleistocene and Holocene times. These features are found to be similar in many respects to those described elsewhere in Southern Africa. The study attempts to provide greater understanding of contemporary vlei processes and emphasises the necessity of their preservation, as finite and valuable resources, by future generations
- Full Text:
- Date Issued: 1989
- Authors: Dewey, Felicity Joy
- Date: 1989
- Subjects: Geology, Stratigraphic -- Holocene Sedimentology Sediments (Geology) -- South Africa -- Eastern Cape -- Winterberg range Geology, Stratigraphic -- Pleistocene Paleoecology -- South Africa -- Eastern Cape -- Winterberg range
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4797 , http://hdl.handle.net/10962/d1001897
- Description: Palaeoenvironmental reconstruction of the late Pleistocene and Holocene geological periods for central and southern Africa has been hampered by the erratic distribution of suitable sites, incomplete and inaccurately dated sequences and the limited nature of published data. One geomorphological feature which has supplied valuable evidence for fluctuations in past environmental conditions, is the vlei or dambo. The type-site of these waterlogged features is in south central Africa, but similar features have been described on other continents. The clastic and organic sediments contained within these features are affected by, and therefore reflect to some degree, the environment under which they were formed. The characteristics of the sediments supply information as to their transport and mechanisms of deposition. From these processes, the environmental conditions at the time of vlei formation can be inferred. The environmental history of the Eastern Cape region has been considerably neglected, and is far less well understood than other countries such as Malawi, Zambia and Zimbabwe. A study site in the Winterberg Range (Eastern Cape) was selected which permitted the comparison of two vleis, the objective being to establish an accurate late Pleistocene sediment chronology for the entire plateau area. Radiocarbon dates from organic layers indicate that these sediments span the last 12 000 years BP, suggesting that organic accumulation at this site began at roughly the same time as at sites further afield. The vlei sediments are analysed in terms of their morphology, particle slze distribution, and other physical and chemical characteristics. These data facilitate the construction of detailed stratigraphic diagrams and a chronological summary of sediment accumulation, from which the period and governing processes of vlei development under changing environments may be described. It is found that the Winterberg vleis contain sediments which respond to changes in the prevailing environment. This makes these sediments useful indices from which to trace such changes during the late Pleistocene and Holocene times. These features are found to be similar in many respects to those described elsewhere in Southern Africa. The study attempts to provide greater understanding of contemporary vlei processes and emphasises the necessity of their preservation, as finite and valuable resources, by future generations
- Full Text:
- Date Issued: 1989
Extractives from six species of Lamiaceae
- Davies-Coleman, Michael Trevor
- Authors: Davies-Coleman, Michael Trevor
- Date: 1988
- Subjects: Lamiaceae
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4532 , http://hdl.handle.net/10962/d1016235
- Description: In continuation of the phytochemical studies of plants belonging to the Lamiaceae (formerly Labiatae) the acetone extractives of six Southern African species from this family have been examined. The genus Syncolostemon has not been investigated before and a new 6- substituted-5 ,6-dihydro-a-pyrone , synrotolide was isolated from S. rotundifolius. The structure of synrotolide was fully elucidated as 6fixii [3'R, 61S-(diacetyloxy)-4 1R, 5 1 8-(dihydroxy)-1~-hepteny~ -5,6-dihydro-2H-pyran- 2-one. Oleanolic acid is the major component of both~ rotundifolius and S. densifloris. The flavonol quercetin was isolated from S. densifloris as its 3, 3', 4' , 7 tetramethyl ether. A further 6-substituted-5,6-dihydro-a-pyrone, boronolide, was obtained from Tetradenia barberae. The structure of boronolide was known but the absolute stereochemistry was unassigned. Chemical degradation established the total structure of this compound as 6R- [1 'R, 2'R, 3's -(trisacetyloxy)heptyl] -5,6-dihydro-2H-pyran-2-one. The chemistry of naturally occuring 6-substituted-5,6-dihydro-apyrones has not as such been previously reviewed and a comprehensive review covering the literature up to June 1987 is presented here. Three known labdane diterpenoids nepetaefuran, hispanalone and dubiin were iso lated from Leonotis nepetaefolia, Ballota africana and L. ocymifolia var. ocymifolia (formerly~ dubia). Both~ nepetaefolia and L. dubia have been examined before. An X-ray analysis of saponified dubiin and a circular dichroism study of 6-deacetyldehydrodubiin and related compounds corroborated the structure of dubiin as 48, 5R, 6R, 8R, 9R, 10R-[6-acetoxy-15,16-epoxy-9-hydroxylabda-13 (16), 14-dien-19, 20- olactoneJ. The chemotaxonomic relationships of the genera Ballota and Leonotis are discussed.
- Full Text:
- Date Issued: 1988
- Authors: Davies-Coleman, Michael Trevor
- Date: 1988
- Subjects: Lamiaceae
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4532 , http://hdl.handle.net/10962/d1016235
- Description: In continuation of the phytochemical studies of plants belonging to the Lamiaceae (formerly Labiatae) the acetone extractives of six Southern African species from this family have been examined. The genus Syncolostemon has not been investigated before and a new 6- substituted-5 ,6-dihydro-a-pyrone , synrotolide was isolated from S. rotundifolius. The structure of synrotolide was fully elucidated as 6fixii [3'R, 61S-(diacetyloxy)-4 1R, 5 1 8-(dihydroxy)-1~-hepteny~ -5,6-dihydro-2H-pyran- 2-one. Oleanolic acid is the major component of both~ rotundifolius and S. densifloris. The flavonol quercetin was isolated from S. densifloris as its 3, 3', 4' , 7 tetramethyl ether. A further 6-substituted-5,6-dihydro-a-pyrone, boronolide, was obtained from Tetradenia barberae. The structure of boronolide was known but the absolute stereochemistry was unassigned. Chemical degradation established the total structure of this compound as 6R- [1 'R, 2'R, 3's -(trisacetyloxy)heptyl] -5,6-dihydro-2H-pyran-2-one. The chemistry of naturally occuring 6-substituted-5,6-dihydro-apyrones has not as such been previously reviewed and a comprehensive review covering the literature up to June 1987 is presented here. Three known labdane diterpenoids nepetaefuran, hispanalone and dubiin were iso lated from Leonotis nepetaefolia, Ballota africana and L. ocymifolia var. ocymifolia (formerly~ dubia). Both~ nepetaefolia and L. dubia have been examined before. An X-ray analysis of saponified dubiin and a circular dichroism study of 6-deacetyldehydrodubiin and related compounds corroborated the structure of dubiin as 48, 5R, 6R, 8R, 9R, 10R-[6-acetoxy-15,16-epoxy-9-hydroxylabda-13 (16), 14-dien-19, 20- olactoneJ. The chemotaxonomic relationships of the genera Ballota and Leonotis are discussed.
- Full Text:
- Date Issued: 1988
A study of the population dynamics, production and potential yield of the sardine Limnothrissa Miodon (Boulenger) in Lake Kariba
- Authors: Marshall, Brian Eric
- Date: 1987
- Subjects: Fishes Lake Tanganyika sardine
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5191 , http://hdl.handle.net/10962/d1001967
- Description: The limnology of Lake Kariba, especially those aspects that affect sardine biology, are described. The hydrological regime of the lake is seen as a major influence and may be one of the reasons why the fish are very much smaller in Kariba than they are in Lakes Tanganyika or Kivu. Growth was reassessed and there appeared to be a correlation between rates of growth and limnological parameters. In particular, the fish appeared to grow faster, but smaller, in the man-made lakes and this may be a consequence of food shortages brought about by their hydrological characteristics. Mortality rates were also much higher in Kariba and this tended to support the view that the lake is a relatively unsuitable habitat for the sardines. However, estimates of biomass, expressed in terms of lake volume, contradicted this as they were very similar in both Kariba and Tanganyika. The life history strategy of Limnothrissa in Kariba was therefore to reduce its size and increase its productivity in order to maintain the maximum possible biomass and its very high P/B̄ ratio was probably the means by which this was achieved. In terms of lake volume the predicted yields from the pelagic communities of Kariba and Tanganyika were very similar, equivalent to about 20 000 t annually for Kariba. This is close to the yield predicted by several empirical models and the fishery now appears to be entering a phase where increases in effort will not be matched by increased yields. The mechanisms for controlling effort in the fishery appear to be inadequate and particular concern was expressed about the lack of co-ordination between the Zimbabwean and Zambian fishery authorities in planning the development of this shared resource.
- Full Text:
- Date Issued: 1987
- Authors: Marshall, Brian Eric
- Date: 1987
- Subjects: Fishes Lake Tanganyika sardine
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5191 , http://hdl.handle.net/10962/d1001967
- Description: The limnology of Lake Kariba, especially those aspects that affect sardine biology, are described. The hydrological regime of the lake is seen as a major influence and may be one of the reasons why the fish are very much smaller in Kariba than they are in Lakes Tanganyika or Kivu. Growth was reassessed and there appeared to be a correlation between rates of growth and limnological parameters. In particular, the fish appeared to grow faster, but smaller, in the man-made lakes and this may be a consequence of food shortages brought about by their hydrological characteristics. Mortality rates were also much higher in Kariba and this tended to support the view that the lake is a relatively unsuitable habitat for the sardines. However, estimates of biomass, expressed in terms of lake volume, contradicted this as they were very similar in both Kariba and Tanganyika. The life history strategy of Limnothrissa in Kariba was therefore to reduce its size and increase its productivity in order to maintain the maximum possible biomass and its very high P/B̄ ratio was probably the means by which this was achieved. In terms of lake volume the predicted yields from the pelagic communities of Kariba and Tanganyika were very similar, equivalent to about 20 000 t annually for Kariba. This is close to the yield predicted by several empirical models and the fishery now appears to be entering a phase where increases in effort will not be matched by increased yields. The mechanisms for controlling effort in the fishery appear to be inadequate and particular concern was expressed about the lack of co-ordination between the Zimbabwean and Zambian fishery authorities in planning the development of this shared resource.
- Full Text:
- Date Issued: 1987
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