The contribution and direct-use value of livestock to rural livelihoods in the Sand River catchment, South Africa
- Shackleton, Charlie M, Shackleton, Sheona E, Netshiluvhi, T R, Mathabela, F R
- Authors: Shackleton, Charlie M , Shackleton, Sheona E , Netshiluvhi, T R , Mathabela, F R
- Date: 2005
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181335 , vital:43720 , xlink:href="https://doi.org/10.2989/10220110509485870"
- Description: The productive functions of livestock ownership in communal areas are multipurpose in character, comprising a mix of stock types and a range of goods and services used. When all these multiple uses are accounted for, the cash and direct-use returns of livestock in communal areas can be comparable to commercial systems, although temporally and spatially variable. Yet previous work has generally excluded small stock from such analyses, as well as benefits and costs to non-owning households. This paper presents empirical results of a study in the Sand River catchment, assessing the benefits and costs accruing to owners and non-owners for both cattle and goats within a livelihoods analysis framework. Results indicate that cattle are used for a greater variety of goods and services than are goats. The savings value represented the most important function, followed by milk and then manure. Even if savings value was excluded, cattle ownership made a significant contribution to local livelihoods. Goats also provided a net positive benefit, represented largely by the savings value, followed by meat and cash sales. Non-owners also benefited through donations of manure, milk, draught and meat for free, or at a cheaper rate than alternatives. The majority of non-owners aspired to livestock ownership, although the risk of theft of animals was of growing concern. Averaged across the whole catchment, the net value of goods and services from livestock was just over R400 per hectare, with an annual return to capital of 36%. Cattle contributed the bulk of the value by virtue of their greater numbers and larger size, but on a per kilogramme basis goats provided higher value. Many of the goods and services obtained from livestock were not enumerated in regional or national economic statistics.
- Full Text:
- Date Issued: 2005
- Authors: Shackleton, Charlie M , Shackleton, Sheona E , Netshiluvhi, T R , Mathabela, F R
- Date: 2005
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181335 , vital:43720 , xlink:href="https://doi.org/10.2989/10220110509485870"
- Description: The productive functions of livestock ownership in communal areas are multipurpose in character, comprising a mix of stock types and a range of goods and services used. When all these multiple uses are accounted for, the cash and direct-use returns of livestock in communal areas can be comparable to commercial systems, although temporally and spatially variable. Yet previous work has generally excluded small stock from such analyses, as well as benefits and costs to non-owning households. This paper presents empirical results of a study in the Sand River catchment, assessing the benefits and costs accruing to owners and non-owners for both cattle and goats within a livelihoods analysis framework. Results indicate that cattle are used for a greater variety of goods and services than are goats. The savings value represented the most important function, followed by milk and then manure. Even if savings value was excluded, cattle ownership made a significant contribution to local livelihoods. Goats also provided a net positive benefit, represented largely by the savings value, followed by meat and cash sales. Non-owners also benefited through donations of manure, milk, draught and meat for free, or at a cheaper rate than alternatives. The majority of non-owners aspired to livestock ownership, although the risk of theft of animals was of growing concern. Averaged across the whole catchment, the net value of goods and services from livestock was just over R400 per hectare, with an annual return to capital of 36%. Cattle contributed the bulk of the value by virtue of their greater numbers and larger size, but on a per kilogramme basis goats provided higher value. Many of the goods and services obtained from livestock were not enumerated in regional or national economic statistics.
- Full Text:
- Date Issued: 2005
The effect of structure on the electrochemical properties of 14 marine pyrroloquinoline metabolites
- Antunes, Edith M, Maree, Suzanne E, Nyokong, Tebello, Davies-Coleman, Mike T, Maree, M David
- Authors: Antunes, Edith M , Maree, Suzanne E , Nyokong, Tebello , Davies-Coleman, Mike T , Maree, M David
- Date: 2005
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/286126 , vital:56242 , xlink:href="https://doi.org/10.3184/030823405775146915"
- Description: The electrochemical properties of 14 structurally related pyrroloquinoline metabolites (compounds 1–14) isolated from marine sponges were studied in pH-varied experiments using cyclic and square wave voltammetry. In general both substitution patterns and pH were observed to influence the reduction potentials of these molecules.
- Full Text:
- Date Issued: 2005
- Authors: Antunes, Edith M , Maree, Suzanne E , Nyokong, Tebello , Davies-Coleman, Mike T , Maree, M David
- Date: 2005
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/286126 , vital:56242 , xlink:href="https://doi.org/10.3184/030823405775146915"
- Description: The electrochemical properties of 14 structurally related pyrroloquinoline metabolites (compounds 1–14) isolated from marine sponges were studied in pH-varied experiments using cyclic and square wave voltammetry. In general both substitution patterns and pH were observed to influence the reduction potentials of these molecules.
- Full Text:
- Date Issued: 2005
Towards a better grasp of what matters in view of ‘the posts’
- O'Donoghue, Rob, Lotz-Sisitka, Heila
- Authors: O'Donoghue, Rob , Lotz-Sisitka, Heila
- Date: 2005
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182693 , vital:43854 , xlink:href="https://doi.org/10.1080/13504620500169593"
- Description: This response to McKenzie suggests that the issues of representivity, legitimacy and politics, inscribed within an institutional continuism characteristic of modernity within the McKenzie discourse, could well be recast within a reflexive view informed by insights derived with developing social theory. It briefly overviews the struggle for human agency that played out within the deconstructive engagements of the posts and probes how perspectives in social theory are opening the way for a break with features of environmental education as an institutional field. The review points to a reconstituting of the idea of environmental education research from scholastic field of/for environmental awareness and sustainable development, to a reflexive engagement within processes of social reproduction and reorientation in a changing world. A shift such as this would constitute a subtle change in a developing field of research, to situated design decisions of reflexive engagement (research) in social fields constituted within developing cultural contexts of risk.
- Full Text:
- Date Issued: 2005
- Authors: O'Donoghue, Rob , Lotz-Sisitka, Heila
- Date: 2005
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182693 , vital:43854 , xlink:href="https://doi.org/10.1080/13504620500169593"
- Description: This response to McKenzie suggests that the issues of representivity, legitimacy and politics, inscribed within an institutional continuism characteristic of modernity within the McKenzie discourse, could well be recast within a reflexive view informed by insights derived with developing social theory. It briefly overviews the struggle for human agency that played out within the deconstructive engagements of the posts and probes how perspectives in social theory are opening the way for a break with features of environmental education as an institutional field. The review points to a reconstituting of the idea of environmental education research from scholastic field of/for environmental awareness and sustainable development, to a reflexive engagement within processes of social reproduction and reorientation in a changing world. A shift such as this would constitute a subtle change in a developing field of research, to situated design decisions of reflexive engagement (research) in social fields constituted within developing cultural contexts of risk.
- Full Text:
- Date Issued: 2005
Reactor development and process optimisation for the bioremediation of phenolic wastewaters by trametes species
- Authors: Ryan, Daniel Reginald
- Date: 2004-04
- Subjects: Uncatalogued
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/191487 , vital:45103
- Description: In many service industries, the source of a company’s value has shifted from capital to knowledge and ideas, the quality of which is dependent on its employees (Wooldridge, 2006). In fact, human resources can be considered part of factor conditions which can positively impact on a firm’s competitive context. This impact can ultimately translate into improved financial results (Porter and Kramer, 2002). There is therefore a growing interest in ways to attract and retain talent. According to the managers of many big companies, well communicated corporate responsibility practices can improve staff attraction as well as retention rates by improving morale (CSRwire, 2002). To explore this, a small, creative company in Johannesburg which engages in charity work was selected as a case study, with the goal being to understand whether their culture of good deeds has a positive impact on staff wellbeing. While the owner of the company actively attempts to make the company an enjoyable place to work at, he appears to have initiated the philanthropic activities in a true spirit of giving, rather than with the motive of engaging staff in order to make more money. Nevertheless, the researcher’s investigative stance is that of an enlightened egoist, and the study focuses on the business case of giving being beneficial to the giver (ultimately the company) in the long term, as well as to the recipient. While the danger of suggesting that philanthropy could be instrumentalised is acknowledged (Morton, 2004), the investigation explores the possibility because such evidence could persuade other companies to become more socially concerned. Through a qualitative approach involving interviews, observation and analysis of video footage, it becomes apparent that there is clearly value for the staff in the charity work they do. Unfortunately the multiple initiatives undertaken to keep staff morale high at the company make it impossible to establish a clear link between the philanthropy and overall wellbeing, but as the study was conducted in the phenomenological paradigm the main concern was with understanding the experience of participants. However, an unexpected finding was that the employees derive great satisfaction from using their professional skills for charity work rather than just donating money to the charity. They feel that their skills uniquely position them to make significant changes to the lives of others, which gives them a sense of pride and achievement that they don’t necessarily experience in their ordinary activities at work. On the basis of this, it is recommended that companies look to involve staff with projects that require their specific expertise when evaluating philanthropic initiatives. , Thesis (PhD) -- Faculty of Science, Biochemistry, Microbiology and Biotechnology, 2004
- Full Text:
- Date Issued: 2004-04
- Authors: Ryan, Daniel Reginald
- Date: 2004-04
- Subjects: Uncatalogued
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/191487 , vital:45103
- Description: In many service industries, the source of a company’s value has shifted from capital to knowledge and ideas, the quality of which is dependent on its employees (Wooldridge, 2006). In fact, human resources can be considered part of factor conditions which can positively impact on a firm’s competitive context. This impact can ultimately translate into improved financial results (Porter and Kramer, 2002). There is therefore a growing interest in ways to attract and retain talent. According to the managers of many big companies, well communicated corporate responsibility practices can improve staff attraction as well as retention rates by improving morale (CSRwire, 2002). To explore this, a small, creative company in Johannesburg which engages in charity work was selected as a case study, with the goal being to understand whether their culture of good deeds has a positive impact on staff wellbeing. While the owner of the company actively attempts to make the company an enjoyable place to work at, he appears to have initiated the philanthropic activities in a true spirit of giving, rather than with the motive of engaging staff in order to make more money. Nevertheless, the researcher’s investigative stance is that of an enlightened egoist, and the study focuses on the business case of giving being beneficial to the giver (ultimately the company) in the long term, as well as to the recipient. While the danger of suggesting that philanthropy could be instrumentalised is acknowledged (Morton, 2004), the investigation explores the possibility because such evidence could persuade other companies to become more socially concerned. Through a qualitative approach involving interviews, observation and analysis of video footage, it becomes apparent that there is clearly value for the staff in the charity work they do. Unfortunately the multiple initiatives undertaken to keep staff morale high at the company make it impossible to establish a clear link between the philanthropy and overall wellbeing, but as the study was conducted in the phenomenological paradigm the main concern was with understanding the experience of participants. However, an unexpected finding was that the employees derive great satisfaction from using their professional skills for charity work rather than just donating money to the charity. They feel that their skills uniquely position them to make significant changes to the lives of others, which gives them a sense of pride and achievement that they don’t necessarily experience in their ordinary activities at work. On the basis of this, it is recommended that companies look to involve staff with projects that require their specific expertise when evaluating philanthropic initiatives. , Thesis (PhD) -- Faculty of Science, Biochemistry, Microbiology and Biotechnology, 2004
- Full Text:
- Date Issued: 2004-04
The depositional history and evaluation of two late quaternary, diamondiferous pocket beaches, south-western Namibia
- Authors: Milad, Micael George
- Date: 2004-03
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/420934 , vital:71795
- Description: The two Late Quaternary, diamondiferous pocket beach deposits studied here are situated along a 10 km stretch of the storm-dominated, Atlantic coastline of the Sperrgebiet, south-western Namibia. The pocket beaches are approximately 130 km north of the Orange River mouth, which is widely accepted as a long-lived point source for diamonds sourced from the interior of southern Africa. A total of fourteen pocket beach deposits were recently evaluated in this area, but only two of these, namely Site 2 (to the south) and Site 3 (to the north), are considered here. The main diamondbearing horizons are beach gravels, which occur within, and form part of, the pocket beach sequences. The beach gravels are mostly blanketed by sand overburden, meaning that exposures available for study were limited, and much reliance was placed on borehole logging and observations of evaluation sample tailings. The main aims are to unravel the depositional history of the pocket beach sequences, identify the controls on diamond mineralisation in the beach gravels, and critically examine two different methods of estimating average diamond size for the deposits. In pursuit of these aims, sedimentological characteristics of the unconsolidated pocket beach deposits were recorded using small diameter drill holes, hydraulic grab bulk samples, trench exposures and surface outcrops. The surface geology, geomorphology and modern wave patterns were mapped using high-resolution, Airborne Laser Survey imagery coupled with extensive field checking. Three-dimensional geological modeling software was used to gain insight into the subsurface morphology of the deposits. Fossil shell samples were used to aid interpretation of ancient depositional environments and to date parts of the pocket beach sequences. Variations in diamond concentration and the size of diamonds were recorded using bulk samples, some of which were taken from a trench, but most of which were excavated using a hydraulic grab tool called the GB50. Finally, by using diamond size data from Site 3, sample data from diamondiferous beach gravels to the south of the study area and sample campaign simulations, two alternative methods of evaluating average diamond size in marine gravel deposits were appraised.The pocket beach sequences occur within north-south trending valleys of a major deflation basin and are separated from one another by rocky headlands. The ridge-and-valley topography of the deflation basin has resulted from differential erosion of Late Proterozoic basement rock units, alternating layers of which differ greatly in their resistance to the long-lived, local denudationalprocesses. On the basis of the stratigraphic information collected from the unconsolidated pocket beach valley fills, interpreted within the context of global, Late Pleistocene sea level records, the following depositional history is deduced : a) Deposition of sheetflood gravels by ephemeral streams, activated during a regressive phase. b) Transgression, culminating in the deposition of a gravel beach, representing a sea level highstand of +4 metres above mean sea level (mamsl) at between 120 000 and 130 000 BP. c)A regressive phase, resulting in deflation of former valley fills to the bedrock valley floor and accompanied by re-activation of ephemeral stream activity to form sheetflood deposits; this represents a protracted period of subaerial exposure of the +4 m gravel beach deposit. d) Deposition of a great volume of sediment in the valleys during the latter stages of the transgression from the Last Glacial Maximum (LGM). The sequence generated during this phase, which started at ca. 9 000 BP, contains : i) pan/coastal sabkha sediments, ii) shallow, sheltered bay sediments, iii) back-barrier lagoonal sediments, iv) a gravel beach deposit representing a sea level stillstand at -5 mamsl, laid down between 7 600 and 5 600 BP, v) another gravel beach deposit representing the well-known Middle Holocene sea level highstand at +2 to +3 mamsl, laid down at ca. 5 000 BP, and which terminated the transgression from the LGM. e) A minor regression to the current sea level, accompanied by progradation of the shoreline to its current position. This progradational marine unit consists almost entirely of sand and grit, reflecting the lack of gravel supply to this part of the coastline in the most recent past. f) Deposition of modern coastal dunes, which cap the pocket beach sequence and are the youngest sediments in the study area. Using trench and hydraulic grab evaluation sample results, in combination with analysis of wave patterns and field observations, the following local controls on the density distribution (ie. concentration) and size distribution of diamonds in the gravel beach deposits (+4, -5 and +2 to +3 mamsl stands) are recognised: a) Gravel beach depositional processes, which are responsible for clast sorting on the beach, have influenced the density and size distribution of diamonds. The infill zone, or beach toe, favours maximum diamond concentration while diamond size decreases from the imbricate zone (intertidal) to the infill zone (subtidal). b) Wave energy is identified as the dominant local control on diamond size distribution, but has also influenced diamond concentration to a limited degree. Larger diamonds are intimately associated with coarser beach gravels, both of which are a reflection of increased wave energy. Higher concentrations of diamonds are sometimes associated with zones of coarser gravel and therefore greater wave energy. c) The time of deposition of the host gravel beach is seen to be the dominant controlling factor with respect to diamond concentration. This is seen as evidence of significant temporal variation in the availability of diamonds in the littoral evironment. A significant reduction (20%) in average diamond size from Site 2 to Site 3, over a distance of only 6 km, is evident. The following were identified as reasons for this reduction in diamond size : a) Longshore sorting processes, of which the long-lived northerly littoral drift is a key part, are known to have played a role in the diminution of diamond size northwards from the Orange River mouth point source. However, it is believed that this can only partly account for the observed 20% reduction in diamond size. b) Input of sediment and smaller diamonds at Site 3, reworked out of an older, Eocene-aged marine succession in the hinterland, is recognised as a possible additional reason for the large reduction in diamond size from Site 2 to Site 3. It is also speculated that the large size of the pocket beach at Site 3, relative to Site 2, may have resulted in lower average wave energy at Site 3, with consequent reduced average diamond size. Diamond size in the beach gravels of Site 3, as well as in beach gravels elsewhere in the Sperrgebiet, is seen to be lognormally-distributed within geologically homogeneous zones. In theory, lognormal mean estimators represent the best method of estimating average diamond size in such cases, whereas the arithmetic mean estimator has the tendency to overestimate when large outlier values occur. Lognormal mean estimators have the added benefit of providing for the calculation of confidence limits, which are becoming increasingly more important as financial lending institutions insist on better quantification of the risk involved in resource estimates. Sample campaign simulations demonstrate, for the kinds of diamond size-frequency distributions typical of beach gravel deposits at Site 3, that there is no significant improvement in the accuracy of average diamond size estimates when lognormal mean estimators are used instead of the arithmetic mean estimator. This is because the variance (a ) of the diamond populations is low, and large outlier values are extremely unlikely to occur. However, simulation of a diamond population with high variance, drawn from a sample of beach gravels near the Orange River mouth, shows that lognormal estimators produce significantly more accurate results when a is large. Since individual diamond weights were not recorded during evaluation sampling of Site 3, numerical solution of lognormal estimators is not possible, and these would need to be solved using a less accurate graphical method. It is therefore recommended that individual diamond weights are recorded in future sampling campaigns, allowing for the use of lognormal mean estimators, and the calculation of confidence limits for average diamond size estimates. , Thesis (MSc) -- Science, Geology, 2004
- Full Text:
- Date Issued: 2004-03
- Authors: Milad, Micael George
- Date: 2004-03
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/420934 , vital:71795
- Description: The two Late Quaternary, diamondiferous pocket beach deposits studied here are situated along a 10 km stretch of the storm-dominated, Atlantic coastline of the Sperrgebiet, south-western Namibia. The pocket beaches are approximately 130 km north of the Orange River mouth, which is widely accepted as a long-lived point source for diamonds sourced from the interior of southern Africa. A total of fourteen pocket beach deposits were recently evaluated in this area, but only two of these, namely Site 2 (to the south) and Site 3 (to the north), are considered here. The main diamondbearing horizons are beach gravels, which occur within, and form part of, the pocket beach sequences. The beach gravels are mostly blanketed by sand overburden, meaning that exposures available for study were limited, and much reliance was placed on borehole logging and observations of evaluation sample tailings. The main aims are to unravel the depositional history of the pocket beach sequences, identify the controls on diamond mineralisation in the beach gravels, and critically examine two different methods of estimating average diamond size for the deposits. In pursuit of these aims, sedimentological characteristics of the unconsolidated pocket beach deposits were recorded using small diameter drill holes, hydraulic grab bulk samples, trench exposures and surface outcrops. The surface geology, geomorphology and modern wave patterns were mapped using high-resolution, Airborne Laser Survey imagery coupled with extensive field checking. Three-dimensional geological modeling software was used to gain insight into the subsurface morphology of the deposits. Fossil shell samples were used to aid interpretation of ancient depositional environments and to date parts of the pocket beach sequences. Variations in diamond concentration and the size of diamonds were recorded using bulk samples, some of which were taken from a trench, but most of which were excavated using a hydraulic grab tool called the GB50. Finally, by using diamond size data from Site 3, sample data from diamondiferous beach gravels to the south of the study area and sample campaign simulations, two alternative methods of evaluating average diamond size in marine gravel deposits were appraised.The pocket beach sequences occur within north-south trending valleys of a major deflation basin and are separated from one another by rocky headlands. The ridge-and-valley topography of the deflation basin has resulted from differential erosion of Late Proterozoic basement rock units, alternating layers of which differ greatly in their resistance to the long-lived, local denudationalprocesses. On the basis of the stratigraphic information collected from the unconsolidated pocket beach valley fills, interpreted within the context of global, Late Pleistocene sea level records, the following depositional history is deduced : a) Deposition of sheetflood gravels by ephemeral streams, activated during a regressive phase. b) Transgression, culminating in the deposition of a gravel beach, representing a sea level highstand of +4 metres above mean sea level (mamsl) at between 120 000 and 130 000 BP. c)A regressive phase, resulting in deflation of former valley fills to the bedrock valley floor and accompanied by re-activation of ephemeral stream activity to form sheetflood deposits; this represents a protracted period of subaerial exposure of the +4 m gravel beach deposit. d) Deposition of a great volume of sediment in the valleys during the latter stages of the transgression from the Last Glacial Maximum (LGM). The sequence generated during this phase, which started at ca. 9 000 BP, contains : i) pan/coastal sabkha sediments, ii) shallow, sheltered bay sediments, iii) back-barrier lagoonal sediments, iv) a gravel beach deposit representing a sea level stillstand at -5 mamsl, laid down between 7 600 and 5 600 BP, v) another gravel beach deposit representing the well-known Middle Holocene sea level highstand at +2 to +3 mamsl, laid down at ca. 5 000 BP, and which terminated the transgression from the LGM. e) A minor regression to the current sea level, accompanied by progradation of the shoreline to its current position. This progradational marine unit consists almost entirely of sand and grit, reflecting the lack of gravel supply to this part of the coastline in the most recent past. f) Deposition of modern coastal dunes, which cap the pocket beach sequence and are the youngest sediments in the study area. Using trench and hydraulic grab evaluation sample results, in combination with analysis of wave patterns and field observations, the following local controls on the density distribution (ie. concentration) and size distribution of diamonds in the gravel beach deposits (+4, -5 and +2 to +3 mamsl stands) are recognised: a) Gravel beach depositional processes, which are responsible for clast sorting on the beach, have influenced the density and size distribution of diamonds. The infill zone, or beach toe, favours maximum diamond concentration while diamond size decreases from the imbricate zone (intertidal) to the infill zone (subtidal). b) Wave energy is identified as the dominant local control on diamond size distribution, but has also influenced diamond concentration to a limited degree. Larger diamonds are intimately associated with coarser beach gravels, both of which are a reflection of increased wave energy. Higher concentrations of diamonds are sometimes associated with zones of coarser gravel and therefore greater wave energy. c) The time of deposition of the host gravel beach is seen to be the dominant controlling factor with respect to diamond concentration. This is seen as evidence of significant temporal variation in the availability of diamonds in the littoral evironment. A significant reduction (20%) in average diamond size from Site 2 to Site 3, over a distance of only 6 km, is evident. The following were identified as reasons for this reduction in diamond size : a) Longshore sorting processes, of which the long-lived northerly littoral drift is a key part, are known to have played a role in the diminution of diamond size northwards from the Orange River mouth point source. However, it is believed that this can only partly account for the observed 20% reduction in diamond size. b) Input of sediment and smaller diamonds at Site 3, reworked out of an older, Eocene-aged marine succession in the hinterland, is recognised as a possible additional reason for the large reduction in diamond size from Site 2 to Site 3. It is also speculated that the large size of the pocket beach at Site 3, relative to Site 2, may have resulted in lower average wave energy at Site 3, with consequent reduced average diamond size. Diamond size in the beach gravels of Site 3, as well as in beach gravels elsewhere in the Sperrgebiet, is seen to be lognormally-distributed within geologically homogeneous zones. In theory, lognormal mean estimators represent the best method of estimating average diamond size in such cases, whereas the arithmetic mean estimator has the tendency to overestimate when large outlier values occur. Lognormal mean estimators have the added benefit of providing for the calculation of confidence limits, which are becoming increasingly more important as financial lending institutions insist on better quantification of the risk involved in resource estimates. Sample campaign simulations demonstrate, for the kinds of diamond size-frequency distributions typical of beach gravel deposits at Site 3, that there is no significant improvement in the accuracy of average diamond size estimates when lognormal mean estimators are used instead of the arithmetic mean estimator. This is because the variance (a ) of the diamond populations is low, and large outlier values are extremely unlikely to occur. However, simulation of a diamond population with high variance, drawn from a sample of beach gravels near the Orange River mouth, shows that lognormal estimators produce significantly more accurate results when a is large. Since individual diamond weights were not recorded during evaluation sampling of Site 3, numerical solution of lognormal estimators is not possible, and these would need to be solved using a less accurate graphical method. It is therefore recommended that individual diamond weights are recorded in future sampling campaigns, allowing for the use of lognormal mean estimators, and the calculation of confidence limits for average diamond size estimates. , Thesis (MSc) -- Science, Geology, 2004
- Full Text:
- Date Issued: 2004-03
Catalytic activity of iron and cobalt phthalocyanine complexes towards the oxidation of cyclohexene using tert-butylhydroperoxide and chloroperoxybenzoic acid
- Sehlotho, Nthapo, Nyokong, Tebello
- Authors: Sehlotho, Nthapo , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/290257 , vital:56729 , xlink:href="https://doi.org/10.1016/j.molcata.2003.08.014"
- Description: Cyclohexene oxidation using tert-butylhydroperoxide (TBHP) or chloroperoxybenzoic acid (CPBA) in the presence of iron(II) polychlorophthalocyanine (Cl16PcFe), iron(II) phthalocyanine (PcFe) and cobalt(II) phthalocyanine (PcCo), results in the formation of the following products: cyclohexene oxide, 2-cyclohexene-1-ol and 2-cyclohexene-1-one. Adipic acid was also formed after long reaction times. The selectivity for 2-cyclohexene-1-one is favoured when Cl16PcFe or PcCo catalysts are employed, while PcFe is selective towards the formation of 2-cyclohexene-1-ol. The Cl16PcFe catalyst is transformed into a μ-oxo dimer (Cl16PcFeIIIOIIIFePcCl16) during the oxidation process. The catalytic process using the unsubstituted PcCoII and PcFeII catalysts involved PcMIII species as an intermediate. The active form of the Cl16PcFe catalyst was stable to degradation in that it was still active even after 4 weeks of continued catalysis.
- Full Text:
- Date Issued: 2004
- Authors: Sehlotho, Nthapo , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/290257 , vital:56729 , xlink:href="https://doi.org/10.1016/j.molcata.2003.08.014"
- Description: Cyclohexene oxidation using tert-butylhydroperoxide (TBHP) or chloroperoxybenzoic acid (CPBA) in the presence of iron(II) polychlorophthalocyanine (Cl16PcFe), iron(II) phthalocyanine (PcFe) and cobalt(II) phthalocyanine (PcCo), results in the formation of the following products: cyclohexene oxide, 2-cyclohexene-1-ol and 2-cyclohexene-1-one. Adipic acid was also formed after long reaction times. The selectivity for 2-cyclohexene-1-one is favoured when Cl16PcFe or PcCo catalysts are employed, while PcFe is selective towards the formation of 2-cyclohexene-1-ol. The Cl16PcFe catalyst is transformed into a μ-oxo dimer (Cl16PcFeIIIOIIIFePcCl16) during the oxidation process. The catalytic process using the unsubstituted PcCoII and PcFeII catalysts involved PcMIII species as an intermediate. The active form of the Cl16PcFe catalyst was stable to degradation in that it was still active even after 4 weeks of continued catalysis.
- Full Text:
- Date Issued: 2004
Determination of 2′, 3′-Dideoxyinosine Using Iron (II) Phthalocyanine Modified Carbon Paste Electrode
- Ozoemena, Kenneth I, Stefan, Raluca-Ioana, Nyokong, Tebello
- Authors: Ozoemena, Kenneth I , Stefan, Raluca-Ioana , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300298 , vital:57914 , xlink:href="https://doi.org/10.1081/AL-200031940"
- Description: An amperometric sensor, based on carbon paste impregnated with iron (II) phthalocyanine complex (FePc), has been constructed for the assay of anti‐HIV agent dideoxyinosine (didanosine, DDI). Using chronoamperometry (E = +1.04 V versus Ag/AgCl) technique, the amperometric sensor can be used reliably for dideoxyinosine assay at pH 7.4 phosphate buffer in the 1.5–9.5 nmol/L concentration range with a detection limit of 5.7 × 10−10 mol/L. The surface of the electrode can easily be regenerated by simple polishing, obtaining a fresh surface ready for use in a new assay. The new amperometric sensor proved to be highly reliable for the assay of dideoxyinosine purity in raw material as well as for the uniformity content test of Videx® tablets.
- Full Text:
- Date Issued: 2004
- Authors: Ozoemena, Kenneth I , Stefan, Raluca-Ioana , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300298 , vital:57914 , xlink:href="https://doi.org/10.1081/AL-200031940"
- Description: An amperometric sensor, based on carbon paste impregnated with iron (II) phthalocyanine complex (FePc), has been constructed for the assay of anti‐HIV agent dideoxyinosine (didanosine, DDI). Using chronoamperometry (E = +1.04 V versus Ag/AgCl) technique, the amperometric sensor can be used reliably for dideoxyinosine assay at pH 7.4 phosphate buffer in the 1.5–9.5 nmol/L concentration range with a detection limit of 5.7 × 10−10 mol/L. The surface of the electrode can easily be regenerated by simple polishing, obtaining a fresh surface ready for use in a new assay. The new amperometric sensor proved to be highly reliable for the assay of dideoxyinosine purity in raw material as well as for the uniformity content test of Videx® tablets.
- Full Text:
- Date Issued: 2004
Electrochemical and catalytic properties of chromium tetraaminophthalocyanine
- Obirai, Joe, Nyokong, Tebello
- Authors: Obirai, Joe , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300310 , vital:57915 , xlink:href="https://doi.org/10.1016/j.jelechem.2004.06.026"
- Description: Chromium tetraaminophthalocyanine (CrIIITAPc) has been synthesized and its electrochemical and spectroelectrochemical properties reported. The first reduction and oxidation in this complex occur at the central metal, giving CrIITAPc and CrIVTAPc complexes, respectively, the latter having been observed for the first time. The CrIIITAPc species was polymerized onto glassy carbon (GCE) or indium tin oxide (ITO) electrodes and the polymer evolution confirmed by UV/Visible spectroscopy and by scanning electron microscopy. The polymers were employed for the catalytic oxidation of nitrite or nitric oxide, and the catalysis involved the CrIVTAPc−1 species.
- Full Text:
- Date Issued: 2004
- Authors: Obirai, Joe , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300310 , vital:57915 , xlink:href="https://doi.org/10.1016/j.jelechem.2004.06.026"
- Description: Chromium tetraaminophthalocyanine (CrIIITAPc) has been synthesized and its electrochemical and spectroelectrochemical properties reported. The first reduction and oxidation in this complex occur at the central metal, giving CrIITAPc and CrIVTAPc complexes, respectively, the latter having been observed for the first time. The CrIIITAPc species was polymerized onto glassy carbon (GCE) or indium tin oxide (ITO) electrodes and the polymer evolution confirmed by UV/Visible spectroscopy and by scanning electron microscopy. The polymers were employed for the catalytic oxidation of nitrite or nitric oxide, and the catalysis involved the CrIVTAPc−1 species.
- Full Text:
- Date Issued: 2004
Electrochemical studies of manganese tetraamminophthalocyanine monomer and polymer
- Obirai, Joseph, Nyokong, Tebello
- Authors: Obirai, Joseph , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/290330 , vital:56738 , xlink:href="https://doi.org/10.1016/j.electacta.2003.11.006"
- Description: Manganese tetraaminophthalocyanine (MnTAPc) has been synthesised. The cyclic voltammetry and spectroelectrochemistry of the complex have been examined. Spectroelectrochemistry has been used to confirm that the species synthesised in this work contains MnIII, giving (OH)MnIIITAPc. The oxidation and reduction couples obtained from cyclic voltammetry have been assigned to MnIVPc−/MnIVPc2− (couple I), MnIVPc2−/MnIIIPc2− (couple I′), MnIIIPc2−/MnIIPc2− (couple II) and MnIIPc2−/MnIIPc3− (couple III). Electropolymerization of the MnTAPc onto either the indium tin oxide or glassy carbon electrode results in the in the formation of a poly-MnTAPc. The poly-MnTAPc shows improved reversibility at low pH. The poly-MnTAPc electrode was employed to analyse glycine.
- Full Text:
- Date Issued: 2004
- Authors: Obirai, Joseph , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/290330 , vital:56738 , xlink:href="https://doi.org/10.1016/j.electacta.2003.11.006"
- Description: Manganese tetraaminophthalocyanine (MnTAPc) has been synthesised. The cyclic voltammetry and spectroelectrochemistry of the complex have been examined. Spectroelectrochemistry has been used to confirm that the species synthesised in this work contains MnIII, giving (OH)MnIIITAPc. The oxidation and reduction couples obtained from cyclic voltammetry have been assigned to MnIVPc−/MnIVPc2− (couple I), MnIVPc2−/MnIIIPc2− (couple I′), MnIIIPc2−/MnIIPc2− (couple II) and MnIIPc2−/MnIIPc3− (couple III). Electropolymerization of the MnTAPc onto either the indium tin oxide or glassy carbon electrode results in the in the formation of a poly-MnTAPc. The poly-MnTAPc shows improved reversibility at low pH. The poly-MnTAPc electrode was employed to analyse glycine.
- Full Text:
- Date Issued: 2004
Emerging patterns of abstraction in environmental education: A review of materials, methods and professional development perspectives
- O'Donoghue, Rob B, Russo, Vladimir
- Authors: O'Donoghue, Rob B , Russo, Vladimir
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/373610 , vital:66707 , xlink:href="https://doi.org/10.1080/1350462042000258170"
- Description: The epistemic unconscious is the history of the field. And it is clear that, to secure some chance of really knowing what one is doing, one has to unfold what is inscribed in the various relations of implication in which the thinker and his thoughts are caught up, that is, the presuppositions he engages and the inclusions and exclusions he unwittingly performs. (Bourdieu, 2000, p. 99).
- Full Text:
- Date Issued: 2004
- Authors: O'Donoghue, Rob B , Russo, Vladimir
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/373610 , vital:66707 , xlink:href="https://doi.org/10.1080/1350462042000258170"
- Description: The epistemic unconscious is the history of the field. And it is clear that, to secure some chance of really knowing what one is doing, one has to unfold what is inscribed in the various relations of implication in which the thinker and his thoughts are caught up, that is, the presuppositions he engages and the inclusions and exclusions he unwittingly performs. (Bourdieu, 2000, p. 99).
- Full Text:
- Date Issued: 2004
Environmental education research and social change: Southern African perspectives
- Authors: Lotz-Sisitka, Heila
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182709 , vital:43855 , xlink:href="https://doi.org/10.1080/1350462042000258143"
- Description: Environmental issues and risks in southern Africa have, like elsewhere in the world, their roots in the structures and orientations of modern societies. In modernist fashion, we draw on education and research to address socio-ecological concerns. In 1995 Eureta Janse van Rensburg, then Murray and Roberts Chair of Environmental Education at Rhodes University,1 undertook a study to identify environmental education research priorities, and through her study she provided a description of research in environmental education as a ‘landscape of shifting priorites’ (Janse van Rensburg, 1995). The papers in this journal offer a contemporary ‘snapshot’ of the landscape of environmental education research in southern Africa, illustrating a fresh range of ‘shifting priorities’.
- Full Text:
- Date Issued: 2004
- Authors: Lotz-Sisitka, Heila
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182709 , vital:43855 , xlink:href="https://doi.org/10.1080/1350462042000258143"
- Description: Environmental issues and risks in southern Africa have, like elsewhere in the world, their roots in the structures and orientations of modern societies. In modernist fashion, we draw on education and research to address socio-ecological concerns. In 1995 Eureta Janse van Rensburg, then Murray and Roberts Chair of Environmental Education at Rhodes University,1 undertook a study to identify environmental education research priorities, and through her study she provided a description of research in environmental education as a ‘landscape of shifting priorites’ (Janse van Rensburg, 1995). The papers in this journal offer a contemporary ‘snapshot’ of the landscape of environmental education research in southern Africa, illustrating a fresh range of ‘shifting priorities’.
- Full Text:
- Date Issued: 2004
Harvesting impacts on commonly used medicinal tree species (Catha edulis and Rapanea melanophloeos) under different land management regimes in the Mpumalanga Lowveld, South Africa
- Botha, Jenny, Witkowski, Ed T F, Shackleton, Charlie M
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181379 , vital:43728 , xlink:href="https://doi.org/10.4102/koedoe.v47i2.77"
- Description: Harvesting of products from plants in the wild is widespread throughout southern Africa. Particularly important products are plant parts used in traditional medicine. However, the impacts of harvesting practices are rarely quantified, with as yet insufficient generic rules across species and life forms. This limits the predictive ability to monitor and manage the affected populations. This paper examines the harvesting impact on two popular woody medicinal species used throughout sub-Saharan Africa, namely Catha edulis (Vahl) Forssk. ex Endl. (bushman’s tea) and Rapanea melanophloeos (L.) Mez. (Cape beech). In both species, basal diameters, heights, and the number of size classes in the harvested populations were lower than in unharvested. Densities of harvested populations were higher in both species, including densities of young plants, but the frequency of individuals in larger size classes was lower. The populations of both species being harvested for medicinal products appeared to be withstanding the current levels of harvesting, but the population structure of C. edulis populations being harvested for poles on the roadside and near human settlements had been substantially altered. Despite the resilience of the two species to harvesting for medicinal products, loss of habitat or changes in land use pose a threat to a number of the assessed populations.
- Full Text:
- Date Issued: 2004
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181379 , vital:43728 , xlink:href="https://doi.org/10.4102/koedoe.v47i2.77"
- Description: Harvesting of products from plants in the wild is widespread throughout southern Africa. Particularly important products are plant parts used in traditional medicine. However, the impacts of harvesting practices are rarely quantified, with as yet insufficient generic rules across species and life forms. This limits the predictive ability to monitor and manage the affected populations. This paper examines the harvesting impact on two popular woody medicinal species used throughout sub-Saharan Africa, namely Catha edulis (Vahl) Forssk. ex Endl. (bushman’s tea) and Rapanea melanophloeos (L.) Mez. (Cape beech). In both species, basal diameters, heights, and the number of size classes in the harvested populations were lower than in unharvested. Densities of harvested populations were higher in both species, including densities of young plants, but the frequency of individuals in larger size classes was lower. The populations of both species being harvested for medicinal products appeared to be withstanding the current levels of harvesting, but the population structure of C. edulis populations being harvested for poles on the roadside and near human settlements had been substantially altered. Despite the resilience of the two species to harvesting for medicinal products, loss of habitat or changes in land use pose a threat to a number of the assessed populations.
- Full Text:
- Date Issued: 2004
Socio-economic differentiation in the trade of wildlife species for traditional medicines in the Lowveld, South Africa: Implications for resource management initiatives
- Botha, Jenny, Witkowski, Ed T F, Shackleton, Charlie M, Fairbanks, Dean H K
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M , Fairbanks, Dean H K
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183071 , vital:43909 , xlink:href="https://doi.org/10.1080/13504500409469832"
- Description: Surveys of trade in wildlife products utilised in traditional medicine were conducted between 1997 and 1999 on the western boundary of the Kruger National Park, South Africa. Although the extent of trade and numbers of people operating in this sector were lower than other regions of South Africa, this study again highlighted the value of indigenous wildlife products to subsistence economies. Apart from cultural diversity, socioeconomic differentiation occurred at a number of levels. (i) There were socio-economic differences between the traders and vendors. (ii) Gender differences were apparent, with women earning significantly less than men and having to undergo more social challenges in their operation in the market place. (iii) Operational differences were noted between the vendors and traders, as well as between the street and pension day vendors. (iv) Multidimensional Scaling (MDS) highlighted the socio-economic differentiation at the household level, emphasizing in particular one of the most vulnerable groups, the elderly. The potential influence of this socio-economic differentiation needs to be considered during the development of Community-Based Conservation programmes, if the dual aims of conserving biodiversity and improving the lives and livelihoods of those who traditionally rely on medicinal plants are to be met.
- Full Text:
- Date Issued: 2004
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M , Fairbanks, Dean H K
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183071 , vital:43909 , xlink:href="https://doi.org/10.1080/13504500409469832"
- Description: Surveys of trade in wildlife products utilised in traditional medicine were conducted between 1997 and 1999 on the western boundary of the Kruger National Park, South Africa. Although the extent of trade and numbers of people operating in this sector were lower than other regions of South Africa, this study again highlighted the value of indigenous wildlife products to subsistence economies. Apart from cultural diversity, socioeconomic differentiation occurred at a number of levels. (i) There were socio-economic differences between the traders and vendors. (ii) Gender differences were apparent, with women earning significantly less than men and having to undergo more social challenges in their operation in the market place. (iii) Operational differences were noted between the vendors and traders, as well as between the street and pension day vendors. (iv) Multidimensional Scaling (MDS) highlighted the socio-economic differentiation at the household level, emphasizing in particular one of the most vulnerable groups, the elderly. The potential influence of this socio-economic differentiation needs to be considered during the development of Community-Based Conservation programmes, if the dual aims of conserving biodiversity and improving the lives and livelihoods of those who traditionally rely on medicinal plants are to be met.
- Full Text:
- Date Issued: 2004
Study South Africa
- International Education Association of South Africa (IEASA), Van Essche, Alexandra
- Authors: International Education Association of South Africa (IEASA) , Van Essche, Alexandra
- Date: 2004
- Subjects: Education, Higher -- South Africa , Education and globalization -- South Africa Student mobility -- Africa International education -- South Africa Education, Higher -- International cooperation , Universities and colleges -- South Africa , Technical Institutes -- South Africa , Vocational guidance -- South Africa
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/65333 , vital:28746 , ISBN 0620247290
- Description: [Message from the President of IEASA, Dr Roshen Kishun]: The fourth edition of Study South Africa; Guide to South African Tertiary Education coincides with a momentous event in the history of South Africa. It is the 10th anniversary of the democracy after the 1994 elections that ended apartheid. It is time to celebrate the achievements, the development strides, and the reintegration of South Africa into the world community. The International Education Association of South Africa (IEASA) welcomes the new Minister of Education, Ms Naledi Pandor, elected to the Cabinet after the April 2004 elections. We wish her well in her new and demanding portfolio. We are confident that the Minister will support the tertiary education sector to develop linkages between international education, skilled migration and the transition to knowledge economies. While we believe that a free and democratic country may be the most powerful attraction for international students wishing to study in South Africa there are other reasons. South Africa is rated as a technological powerhouse on the African continent. Comparatively South Africa’s educational infrastructure can be compared with the best in the world. Its research sector is by far the strongest in Africa. The country has adopted English as one of its official languages and it is the main medium of instruction in the tertiary education sector. A significant factor which makes South African qualifications attractive is the relatively lower cost of study. Study in South Africa offers the best of both worlds to international students, combining the experience of living in Africa with the opportunity to obtain quality education at a fraction of the cost. In the ten years since 1994, the opening-up of the tertiary education sector in South Africa is evidenced by the dramatic increase of international students studying in the South African public education sector from about 13 000 to more than 47 000 in 2002. While the headcount numbers include distance education students, it is possible that South Africa is currently the leading host country for international students in Africa. An IDP report predicts that by 2025 almost eight million students will be educated trans-nationally. The growth in international student numbers presents South Africa with some exciting challenges in the global context. South Africa is expected to become one of the top nations in the world hosting international students in the next ten yean. Study South Africa is published in the middle of one of the most intense periods of change when the South African education system is being restructured to eliminate duplications created under the apartheid system. The number of public institutions is being reduced from 36 to 23 through mergers and incorporations. The binary divide that existed in the public higher education system pre- 2002, where there were 21 universities and 15 technikons is blurred by the creation of the universities of technology. In spite of the massive transformation, the South African higher education sector has much to offer in the form of quality education, advanced research facilities and internationally recognized qualifications. The information provided in this Guide introduces the individual institutions, their academic offerings, support services provided and other relevant details needed to make a choice of study destination Study South Africa is also a useful tool in the development of a strategy to market South African higher education into the competitive world of international education. The decision by IEASA to develop a marketing strategy is not only a reaction to global higher education pressures, but is also an acknowledgement of South Africa’s return to the global higher education community and in identified geographical areas. IEASA realised that past isolation can only be overturned by conscious new strategies. This 'marketing initiative’ meant that the presence of South Africa was highly visible at some of the leading forums dealing with international education in the world. Study South Africa is undertaken by IEASA in association with the South African Vice-Chancellors Association (SAUVCA) and the Committee of Technikon Principals (CTP). These organizations themselves are set to merge in the near future. We appreciate the support of the Council on Higher Education (CHE), the South African Qualifications Authority (SAQA), Unitech (Higher Education professional body for marketing, communication and development), and Professor T Mthembu. We are most grarefril to Karen MacGregor, our specialist writer, who compiled the excellent articles in this publication on achievements during the ten years of transformation. I wish to take this opportunity of thanking all those who made contributions for their support and all the tertiary education institutions in the public education sector for their participation. We are grateful to the Department of Foreign Affairs for the distribution of the Guide abroad and to members of the IEASA publications committee for their input. We appreciate the support of Artworks Publishing for working under pressure to meet publications deadline. Special thanks are due to Zandile Wanda for the work in coordinating the response from the tertiary education sector and to Alexandra van Essche for compiling and producing the Guide. Without their efforts it would not have been possible to publish the Guide. , 4th Edition
- Full Text:
- Date Issued: 2004
- Authors: International Education Association of South Africa (IEASA) , Van Essche, Alexandra
- Date: 2004
- Subjects: Education, Higher -- South Africa , Education and globalization -- South Africa Student mobility -- Africa International education -- South Africa Education, Higher -- International cooperation , Universities and colleges -- South Africa , Technical Institutes -- South Africa , Vocational guidance -- South Africa
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/65333 , vital:28746 , ISBN 0620247290
- Description: [Message from the President of IEASA, Dr Roshen Kishun]: The fourth edition of Study South Africa; Guide to South African Tertiary Education coincides with a momentous event in the history of South Africa. It is the 10th anniversary of the democracy after the 1994 elections that ended apartheid. It is time to celebrate the achievements, the development strides, and the reintegration of South Africa into the world community. The International Education Association of South Africa (IEASA) welcomes the new Minister of Education, Ms Naledi Pandor, elected to the Cabinet after the April 2004 elections. We wish her well in her new and demanding portfolio. We are confident that the Minister will support the tertiary education sector to develop linkages between international education, skilled migration and the transition to knowledge economies. While we believe that a free and democratic country may be the most powerful attraction for international students wishing to study in South Africa there are other reasons. South Africa is rated as a technological powerhouse on the African continent. Comparatively South Africa’s educational infrastructure can be compared with the best in the world. Its research sector is by far the strongest in Africa. The country has adopted English as one of its official languages and it is the main medium of instruction in the tertiary education sector. A significant factor which makes South African qualifications attractive is the relatively lower cost of study. Study in South Africa offers the best of both worlds to international students, combining the experience of living in Africa with the opportunity to obtain quality education at a fraction of the cost. In the ten years since 1994, the opening-up of the tertiary education sector in South Africa is evidenced by the dramatic increase of international students studying in the South African public education sector from about 13 000 to more than 47 000 in 2002. While the headcount numbers include distance education students, it is possible that South Africa is currently the leading host country for international students in Africa. An IDP report predicts that by 2025 almost eight million students will be educated trans-nationally. The growth in international student numbers presents South Africa with some exciting challenges in the global context. South Africa is expected to become one of the top nations in the world hosting international students in the next ten yean. Study South Africa is published in the middle of one of the most intense periods of change when the South African education system is being restructured to eliminate duplications created under the apartheid system. The number of public institutions is being reduced from 36 to 23 through mergers and incorporations. The binary divide that existed in the public higher education system pre- 2002, where there were 21 universities and 15 technikons is blurred by the creation of the universities of technology. In spite of the massive transformation, the South African higher education sector has much to offer in the form of quality education, advanced research facilities and internationally recognized qualifications. The information provided in this Guide introduces the individual institutions, their academic offerings, support services provided and other relevant details needed to make a choice of study destination Study South Africa is also a useful tool in the development of a strategy to market South African higher education into the competitive world of international education. The decision by IEASA to develop a marketing strategy is not only a reaction to global higher education pressures, but is also an acknowledgement of South Africa’s return to the global higher education community and in identified geographical areas. IEASA realised that past isolation can only be overturned by conscious new strategies. This 'marketing initiative’ meant that the presence of South Africa was highly visible at some of the leading forums dealing with international education in the world. Study South Africa is undertaken by IEASA in association with the South African Vice-Chancellors Association (SAUVCA) and the Committee of Technikon Principals (CTP). These organizations themselves are set to merge in the near future. We appreciate the support of the Council on Higher Education (CHE), the South African Qualifications Authority (SAQA), Unitech (Higher Education professional body for marketing, communication and development), and Professor T Mthembu. We are most grarefril to Karen MacGregor, our specialist writer, who compiled the excellent articles in this publication on achievements during the ten years of transformation. I wish to take this opportunity of thanking all those who made contributions for their support and all the tertiary education institutions in the public education sector for their participation. We are grateful to the Department of Foreign Affairs for the distribution of the Guide abroad and to members of the IEASA publications committee for their input. We appreciate the support of Artworks Publishing for working under pressure to meet publications deadline. Special thanks are due to Zandile Wanda for the work in coordinating the response from the tertiary education sector and to Alexandra van Essche for compiling and producing the Guide. Without their efforts it would not have been possible to publish the Guide. , 4th Edition
- Full Text:
- Date Issued: 2004
Synthesis and photochemical studies of substituted adjacent binaphthalophthalocyanines
- Seotsanyana-Mokhosi, Itumeleng, Nyokong, Tebello
- Authors: Seotsanyana-Mokhosi, Itumeleng , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289883 , vital:56689 , xlink:href="https://doi.org/10.1142/S1088424604000568"
- Description: Adjacent phthalocyanines with a binaphthalo backbone and phenoxy substituents were synthesized and their photochemical properties were investigated. The adjacent phthalocyanines are the binaphthalophthalocyanines, with the phenoxy, 4-tert-butylphenoxy and the sulfophenoxy substituents, respectively and bis-binaphthalophthalocyanine which has an extended π conjugation system and larger singlet oxygen quantum yield compared to the other compounds. The presence of the phenoxy substituents as well as the binaphthalo bridge does not cause a marked difference on the fluorescing properties of these complexes when compared to zinc phthalocyanine. The binaphthalo backbone allowed the molecules to photoswitch during photolysis affording them very high photostability.
- Full Text:
- Date Issued: 2004
- Authors: Seotsanyana-Mokhosi, Itumeleng , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289883 , vital:56689 , xlink:href="https://doi.org/10.1142/S1088424604000568"
- Description: Adjacent phthalocyanines with a binaphthalo backbone and phenoxy substituents were synthesized and their photochemical properties were investigated. The adjacent phthalocyanines are the binaphthalophthalocyanines, with the phenoxy, 4-tert-butylphenoxy and the sulfophenoxy substituents, respectively and bis-binaphthalophthalocyanine which has an extended π conjugation system and larger singlet oxygen quantum yield compared to the other compounds. The presence of the phenoxy substituents as well as the binaphthalo bridge does not cause a marked difference on the fluorescing properties of these complexes when compared to zinc phthalocyanine. The binaphthalo backbone allowed the molecules to photoswitch during photolysis affording them very high photostability.
- Full Text:
- Date Issued: 2004
The fuelwood crisis in southern Africa: Relating fuelwood use to livelihoods in a rural village
- Dovie, Delali B K, Witkowski, Ed T F, Shackleton, Charlie M
- Authors: Dovie, Delali B K , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181402 , vital:43730 , xlink:href="https://doi.org/10.1023/B:GEJO.0000033597.34013.9f"
- Description: The aim of the paper is to examine wood as a source of fuel energy in rural South Africa and factors influencing its usage. The analysis is based on household profiles and characteristics (e.g., gender, caste, population and income) in a livelihood framework. Fuelwood consumption was estimated to be 692 kg/capita, and 4343 kg/user household per annum, valued at $311 per household. Consumption was modelled in relation to informal and formal cash incomes, and population of children, female and male adults. However, only the population of female adults could significantly influence consumption of fuelwood. This implied that where there were more women in a household, consumption was likely to be high. This might be due to the majority of women doing the cooking and heating in the household. Any change in the value of cash income of households had no significant impacts on fuelwood consumed. Cash incomes might therefore not be strong determinants of the types of energy used by rural households. The average quantity of wood consumed for fuel energy in summer was not significantly different from consumption in winter. Some households perpetually used more wood than others. The study further showed that harvesting of wood for fuel energy is not opportunistic, but requires reallocation of time for other livelihood activities in times of shortage. The fuelwood crisis is not simple and not only about shortage of fuelwood and/or population growth but linked to household profiles and other livelihood strategies and subsequently vulnerability of households. These would require thorough investigation and understanding in relation to precise demand and supply data for fuelwood before the fuelwood problem can be sufficiently managed.
- Full Text:
- Date Issued: 2004
- Authors: Dovie, Delali B K , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181402 , vital:43730 , xlink:href="https://doi.org/10.1023/B:GEJO.0000033597.34013.9f"
- Description: The aim of the paper is to examine wood as a source of fuel energy in rural South Africa and factors influencing its usage. The analysis is based on household profiles and characteristics (e.g., gender, caste, population and income) in a livelihood framework. Fuelwood consumption was estimated to be 692 kg/capita, and 4343 kg/user household per annum, valued at $311 per household. Consumption was modelled in relation to informal and formal cash incomes, and population of children, female and male adults. However, only the population of female adults could significantly influence consumption of fuelwood. This implied that where there were more women in a household, consumption was likely to be high. This might be due to the majority of women doing the cooking and heating in the household. Any change in the value of cash income of households had no significant impacts on fuelwood consumed. Cash incomes might therefore not be strong determinants of the types of energy used by rural households. The average quantity of wood consumed for fuel energy in summer was not significantly different from consumption in winter. Some households perpetually used more wood than others. The study further showed that harvesting of wood for fuel energy is not opportunistic, but requires reallocation of time for other livelihood activities in times of shortage. The fuelwood crisis is not simple and not only about shortage of fuelwood and/or population growth but linked to household profiles and other livelihood strategies and subsequently vulnerability of households. These would require thorough investigation and understanding in relation to precise demand and supply data for fuelwood before the fuelwood problem can be sufficiently managed.
- Full Text:
- Date Issued: 2004
The impact of commercial harvesting on Warburgia salutaris (‘pepper-bark tree’) in Mpumalanga, South Africa
- Botha, Jenny, Witkowski, Ed T F, Shackleton, Charlie M
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181391 , vital:43729 , xlink:href="https://doi.org/10.1023/B:BIOC.0000029333.72945.b0"
- Description: Commercialisation often increases the difficulty in managing harvested plant populations sustainably. The bark of the popular medicinal species, Warburgia salutaris (Bertol.f.) Chiov. (Canellaceae) (‘pepper-bark tree’), is widely traded throughout southern Africa. The impact of commercial harvesting on this Red Data species was assessed by comparing commercially harvested populations with populations growing on private land or in protected areas (termed ‘protected populations’) in Mpumalanga and Limpopo Province, South Africa. The basal diameters and heights of stems in commercially harvested populations were significantly lower than those of the protected populations. The density of young/small plants was low in all populations. W. salutaris is usually resilient to high levels of bark harvesting. In this study, 75% of heavily harvested stems (>10% of the stem below 2 m) coppiced (resprouted). However, individuals that had been affected by regular fires, or repeatedly harvested, appeared prone to a fungal disease and had high percentage mortality. The populations occurring on private land appeared the most vigorous. Habitat in one protected area had been reduced through the construction of a dam. In another, small W. salutaris populations exhibited a shrubby growth form, probably due to frequent fires. Our current knowledge for this species supports a global IUCN status of EN A4acd. Plant conservation needs to become a higher priority both within and outside protected areas. Commercially harvested populations should be better managed through improved harvesting techniques and monitoring. Cultivation levels urgently need to be increased. Further research should be conducted on factors limiting regeneration, including the most appropriate fire regime.
- Full Text:
- Date Issued: 2004
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181391 , vital:43729 , xlink:href="https://doi.org/10.1023/B:BIOC.0000029333.72945.b0"
- Description: Commercialisation often increases the difficulty in managing harvested plant populations sustainably. The bark of the popular medicinal species, Warburgia salutaris (Bertol.f.) Chiov. (Canellaceae) (‘pepper-bark tree’), is widely traded throughout southern Africa. The impact of commercial harvesting on this Red Data species was assessed by comparing commercially harvested populations with populations growing on private land or in protected areas (termed ‘protected populations’) in Mpumalanga and Limpopo Province, South Africa. The basal diameters and heights of stems in commercially harvested populations were significantly lower than those of the protected populations. The density of young/small plants was low in all populations. W. salutaris is usually resilient to high levels of bark harvesting. In this study, 75% of heavily harvested stems (>10% of the stem below 2 m) coppiced (resprouted). However, individuals that had been affected by regular fires, or repeatedly harvested, appeared prone to a fungal disease and had high percentage mortality. The populations occurring on private land appeared the most vigorous. Habitat in one protected area had been reduced through the construction of a dam. In another, small W. salutaris populations exhibited a shrubby growth form, probably due to frequent fires. Our current knowledge for this species supports a global IUCN status of EN A4acd. Plant conservation needs to become a higher priority both within and outside protected areas. Commercially harvested populations should be better managed through improved harvesting techniques and monitoring. Cultivation levels urgently need to be increased. Further research should be conducted on factors limiting regeneration, including the most appropriate fire regime.
- Full Text:
- Date Issued: 2004
The renaissance in optical spectroscopy of phthalocyanines and other tetraazaporphyrins
- Nyokong, Tebello, Isago, Hiroaki
- Authors: Nyokong, Tebello , Isago, Hiroaki
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289388 , vital:56628 , xlink:href="https://doi.org/10.1142/S1088424604000453"
- Description: Spectral properties of metallophthalocyanines and other tetraazaporphyrins are governed mainly by the Q band which originates from the π-π* transitions within the ring. The position and intensity of the Q band is important in tailoring new phthalocyanine derivatives for particular applications. Aggregation, the nature of the central metal, π conjugation, symmetry of the molecules, and axial, peripheral or non-peripheral substitutions affect the spectra and hence the properties of the phthalocyanine molecule. This review gives a brief outline on how optical spectroscopy provides useful informations on molecular and electronic structures, chemistry and physics of phthalocyanines and other tetraazaporphyrins.
- Full Text:
- Date Issued: 2004
- Authors: Nyokong, Tebello , Isago, Hiroaki
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289388 , vital:56628 , xlink:href="https://doi.org/10.1142/S1088424604000453"
- Description: Spectral properties of metallophthalocyanines and other tetraazaporphyrins are governed mainly by the Q band which originates from the π-π* transitions within the ring. The position and intensity of the Q band is important in tailoring new phthalocyanine derivatives for particular applications. Aggregation, the nature of the central metal, π conjugation, symmetry of the molecules, and axial, peripheral or non-peripheral substitutions affect the spectra and hence the properties of the phthalocyanine molecule. This review gives a brief outline on how optical spectroscopy provides useful informations on molecular and electronic structures, chemistry and physics of phthalocyanines and other tetraazaporphyrins.
- Full Text:
- Date Issued: 2004
Zinc phthalocyanine photocatalyzed oxidation of cyclohexene
- Sehlotho, Nthapo, Nyokong, Tebello
- Authors: Sehlotho, Nthapo , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289399 , vital:56629 , xlink:href="https://doi.org/10.1016/j.molcata.2004.05.010"
- Description: Cyclohexene photooxidation catalyzed by zinc phthalocyanine (ZnPc) using either red or white light results in the formation of cyclohexenone, cyclohexenol, trans-cyclohexanediol, cyclohexene oxide and cyclohexene hydroperoxide. The product yield increased as follows: cyclohexenone > cyclohexenol > trans-cyclohexanediol > cyclohexene oxide > cyclohexene hydroperoxide. The mechanism for the formation of these products involves both singlet oxygen and radicals (Type II and Type I mechanisms, respectively). The catalyst degraded slowly when low light intensities were employed. The product yields were found to depend on the light intensity, the nature of solvent, irradiation time and the rate of photodegradation of the catalyst.
- Full Text:
- Date Issued: 2004
- Authors: Sehlotho, Nthapo , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289399 , vital:56629 , xlink:href="https://doi.org/10.1016/j.molcata.2004.05.010"
- Description: Cyclohexene photooxidation catalyzed by zinc phthalocyanine (ZnPc) using either red or white light results in the formation of cyclohexenone, cyclohexenol, trans-cyclohexanediol, cyclohexene oxide and cyclohexene hydroperoxide. The product yield increased as follows: cyclohexenone > cyclohexenol > trans-cyclohexanediol > cyclohexene oxide > cyclohexene hydroperoxide. The mechanism for the formation of these products involves both singlet oxygen and radicals (Type II and Type I mechanisms, respectively). The catalyst degraded slowly when low light intensities were employed. The product yields were found to depend on the light intensity, the nature of solvent, irradiation time and the rate of photodegradation of the catalyst.
- Full Text:
- Date Issued: 2004
Investment management: an analysis of the risk-return profiles of the South African and Kenyan stock markets
- Authors: Ndungu, Stanley Ngaruiya
- Date: 2003-03
- Subjects: Uncatalogued
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/191305 , vital:45082
- Description: This study analyses the risk-return profiles of securities and constructed portfolio of the South African and Kenya’s stock markets. The analysis is done with cognisance of the dynamism that characterizes contemporary financial markets especially in the face of globalisation. To this end the study inter alia, considers the impact of the technological, information and telecommunications revolution particularly with regard to trading, delivery and settlement period. It also considers the factors that influence the business environment in each of the two markets and how these affect their risk return profiles. Key among the findings of the study are that, only a few sectors and securities in both the South African and Kenyan markets (S % and less than 1 % respectively) exhibited very high risk-return profiles while most of the rest (32 % and 40 % respectively) recorded low risk-return profiles. Overall, the business environment in South Africa is evidently better when compared to that of Kenya. Consequently, each country’s business environment may be used to explain the high/low risk return profiles. , Thesis (MA) -- Faculty of Commerce, Economics and Economic History, 2003
- Full Text:
- Date Issued: 2003-03
- Authors: Ndungu, Stanley Ngaruiya
- Date: 2003-03
- Subjects: Uncatalogued
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/191305 , vital:45082
- Description: This study analyses the risk-return profiles of securities and constructed portfolio of the South African and Kenya’s stock markets. The analysis is done with cognisance of the dynamism that characterizes contemporary financial markets especially in the face of globalisation. To this end the study inter alia, considers the impact of the technological, information and telecommunications revolution particularly with regard to trading, delivery and settlement period. It also considers the factors that influence the business environment in each of the two markets and how these affect their risk return profiles. Key among the findings of the study are that, only a few sectors and securities in both the South African and Kenyan markets (S % and less than 1 % respectively) exhibited very high risk-return profiles while most of the rest (32 % and 40 % respectively) recorded low risk-return profiles. Overall, the business environment in South Africa is evidently better when compared to that of Kenya. Consequently, each country’s business environment may be used to explain the high/low risk return profiles. , Thesis (MA) -- Faculty of Commerce, Economics and Economic History, 2003
- Full Text:
- Date Issued: 2003-03