The role and impact of trade unions on service delivery in Lukhanji Municipality (Eastern Cape)
- Authors: Brown, Gregory Simon
- Date: 2013
- Subjects: Municipal services , Labor unions , Service industries workers -- Labor unions
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/26537 , vital:65578
- Description: The role and impact of trade unions on service delivery is such a pertinent question to research given the times our young democracy goes through. This was an inevitable piece of study to undertake especially from the point of view to examine which form and philosophy of unionism suits the public sector best. The wildcat strikes and unprotected industrial action that grip municipalities at 10 o’clock early in the day needs deeper thinking and new ground-breaking solutions. Very fundamental questions have to be examined to determine the extent of control SAMWU as a union have over the strategic management environment of the local sphere of state. Lukhanji municipality, given its strategic location happened to host many regional offices of all COSATU affiliated unions happens to be an inconvenient choice of the nucleus of radical trade unionism in Queenstown fall victim and the study examines that. Subsequently to that the municipality fell victim to rigid and radical forms of trade union operations that has strangled it to the point of it losing its character and role of a developmentalist institution in the communities it served. The study also highlights the severe service delivery backlogs in both former Transkei Ezibeleni and Ciskei Whittlesea and how transformation and integration of these two areas have been neglected as shown by the socio-economic profile. The study in the last Chapter makes particular recommendations on how the Strategic Management environment and corporate principles should be prioritised for Performance Management to be introduced and routinely implemented. , Thesis (MPA) -- Faculty of Management and Commerce, 2013
- Full Text:
- Date Issued: 2013
- Authors: Brown, Gregory Simon
- Date: 2013
- Subjects: Municipal services , Labor unions , Service industries workers -- Labor unions
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/26537 , vital:65578
- Description: The role and impact of trade unions on service delivery is such a pertinent question to research given the times our young democracy goes through. This was an inevitable piece of study to undertake especially from the point of view to examine which form and philosophy of unionism suits the public sector best. The wildcat strikes and unprotected industrial action that grip municipalities at 10 o’clock early in the day needs deeper thinking and new ground-breaking solutions. Very fundamental questions have to be examined to determine the extent of control SAMWU as a union have over the strategic management environment of the local sphere of state. Lukhanji municipality, given its strategic location happened to host many regional offices of all COSATU affiliated unions happens to be an inconvenient choice of the nucleus of radical trade unionism in Queenstown fall victim and the study examines that. Subsequently to that the municipality fell victim to rigid and radical forms of trade union operations that has strangled it to the point of it losing its character and role of a developmentalist institution in the communities it served. The study also highlights the severe service delivery backlogs in both former Transkei Ezibeleni and Ciskei Whittlesea and how transformation and integration of these two areas have been neglected as shown by the socio-economic profile. The study in the last Chapter makes particular recommendations on how the Strategic Management environment and corporate principles should be prioritised for Performance Management to be introduced and routinely implemented. , Thesis (MPA) -- Faculty of Management and Commerce, 2013
- Full Text:
- Date Issued: 2013
The synthesis and characterisation of magnetic nanoparticles and their interaction with a zinc phthalocyanine
- Antunes, Edith M, Rapulenyane, Nomasonto, Ledwaba, Mpho, Litwinski, Christian, Chidawanyika, Wadzanai J U, Nyokong, Tebello
- Authors: Antunes, Edith M , Rapulenyane, Nomasonto , Ledwaba, Mpho , Litwinski, Christian , Chidawanyika, Wadzanai J U , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/242111 , vital:51002 , xlink:href="https://doi.org/10.1016/j.inoche.2012.12.010"
- Description: A variety of nanoparticles (NPs), including FePt nanoparticles with Fe as the shell (2) or Pt as the shell (3), Pt NPs (4), and FePd (5) were synthesised, characterised and their effect on a zinc phthalocyanine (1) tetra-substituted with a pyridyl-oxy substituent studied using UV/Vis and fluorescence spectroscopy (including time correlated single photon counting, TCSPC). The nanoparticles were characterised using a number of techniques including UV/Vis and inductively coupled plasma-optical emission (ICP-OES) spectroscopies, transmission electron microscopy (TEM), differential scanning calorimetry (DSC), X-ray powder diffraction (XRD) and electron paramagnetic resonance (EPR) spectroscopy. Nanocomposites (NCs, 6,7) where the ZnPc (1) was used as the stabiliser, instead of oleic acid and or oleylamine, were also synthesised and characterised.
- Full Text:
- Date Issued: 2013
- Authors: Antunes, Edith M , Rapulenyane, Nomasonto , Ledwaba, Mpho , Litwinski, Christian , Chidawanyika, Wadzanai J U , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/242111 , vital:51002 , xlink:href="https://doi.org/10.1016/j.inoche.2012.12.010"
- Description: A variety of nanoparticles (NPs), including FePt nanoparticles with Fe as the shell (2) or Pt as the shell (3), Pt NPs (4), and FePd (5) were synthesised, characterised and their effect on a zinc phthalocyanine (1) tetra-substituted with a pyridyl-oxy substituent studied using UV/Vis and fluorescence spectroscopy (including time correlated single photon counting, TCSPC). The nanoparticles were characterised using a number of techniques including UV/Vis and inductively coupled plasma-optical emission (ICP-OES) spectroscopies, transmission electron microscopy (TEM), differential scanning calorimetry (DSC), X-ray powder diffraction (XRD) and electron paramagnetic resonance (EPR) spectroscopy. Nanocomposites (NCs, 6,7) where the ZnPc (1) was used as the stabiliser, instead of oleic acid and or oleylamine, were also synthesised and characterised.
- Full Text:
- Date Issued: 2013
Think Piece, Naked Science-Avoiding Methodolatry in an Environmental Education Context
- Authors: Price, Leigh
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/387264 , vital:68220 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122255"
- Description: Research methodology is significantly political and in this think piece I try to better understand the effect of this politicisation in the production of science. The main focus of the think piece is to identify the dominant methodological discourses and analyse them using techniques borrowed from post-structuralism. From this analysis, I suggest that methodological discourses are reproduced and normalised in much the same way as discourses of, for example, sexuality, and I give examples of this from my experience as a PhD student of environmental education. I also suggest that some transgressive methodologies, such as those associated with postmodernism or participatory research, despite purporting to empower, at times also disempower. Furthermore, all of the methodologies that I analyse are, in one way or another, ‘loaded’; they cloak their agendas. From this analysis, I move towards suggesting an alternative critical realist methodology for environmental education which is naked; its agendas are clearly stated, not least because this epistemology does not lend itself to deception. An important part of this critical realist conception of methodology is the idea of ‘meta-reflexivity’ in which truth is not vulgarly pragmatic or fideistic.
- Full Text:
- Date Issued: 2013
- Authors: Price, Leigh
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/387264 , vital:68220 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122255"
- Description: Research methodology is significantly political and in this think piece I try to better understand the effect of this politicisation in the production of science. The main focus of the think piece is to identify the dominant methodological discourses and analyse them using techniques borrowed from post-structuralism. From this analysis, I suggest that methodological discourses are reproduced and normalised in much the same way as discourses of, for example, sexuality, and I give examples of this from my experience as a PhD student of environmental education. I also suggest that some transgressive methodologies, such as those associated with postmodernism or participatory research, despite purporting to empower, at times also disempower. Furthermore, all of the methodologies that I analyse are, in one way or another, ‘loaded’; they cloak their agendas. From this analysis, I move towards suggesting an alternative critical realist methodology for environmental education which is naked; its agendas are clearly stated, not least because this epistemology does not lend itself to deception. An important part of this critical realist conception of methodology is the idea of ‘meta-reflexivity’ in which truth is not vulgarly pragmatic or fideistic.
- Full Text:
- Date Issued: 2013
Third order nonlinear optical properties of phthalocyanines in the presence nanomaterials and in polymer thin films
- Britton, Jonathan, Durmus, Mahmut, Khene, Samson M, Chauke, Vongani, Nyokong, Tebello
- Authors: Britton, Jonathan , Durmus, Mahmut , Khene, Samson M , Chauke, Vongani , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241772 , vital:50968 , xlink:href="https://doi.org/10.1142/S108842461350003X"
- Description: Third order nonlinear optical properties were determined for phthalocyanine complexes 1–10 containing In, Ga and Zn central metals and tetra- or octa-substituted with benzyloxyphenoxy, phenoxy, tert-butylphenoxy and amino groups at peripheral or non-peripheral positions. The phthalocyanines were embedded in poly (methyl methacrylate) polymer in the presence of CdTe quantum dots. All complexes 1–10 were studied in the presence of CdTe quantum dots and embedded in poly (methyl methacrylate) to form thin films. Complex 3 tetrasubstituted with tert-butylphenoxy groups at non-peripheral positions was also studied in the presence of CdS, CdSe quantum dots, fullerenes, single walled carbon nanotubes. Third order nonlinear optical parameters generally increase for Pcs in the presence of CdTe quantum dots.
- Full Text:
- Date Issued: 2013
- Authors: Britton, Jonathan , Durmus, Mahmut , Khene, Samson M , Chauke, Vongani , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241772 , vital:50968 , xlink:href="https://doi.org/10.1142/S108842461350003X"
- Description: Third order nonlinear optical properties were determined for phthalocyanine complexes 1–10 containing In, Ga and Zn central metals and tetra- or octa-substituted with benzyloxyphenoxy, phenoxy, tert-butylphenoxy and amino groups at peripheral or non-peripheral positions. The phthalocyanines were embedded in poly (methyl methacrylate) polymer in the presence of CdTe quantum dots. All complexes 1–10 were studied in the presence of CdTe quantum dots and embedded in poly (methyl methacrylate) to form thin films. Complex 3 tetrasubstituted with tert-butylphenoxy groups at non-peripheral positions was also studied in the presence of CdS, CdSe quantum dots, fullerenes, single walled carbon nanotubes. Third order nonlinear optical parameters generally increase for Pcs in the presence of CdTe quantum dots.
- Full Text:
- Date Issued: 2013
Ultrafast Photodynamics of the Indoline Dye D149 Adsorbed to Porous ZnO in Dye‐Sensitized Solar Cells
- Rohwer, Egmont, Richter, Christoph, Heming, Nadine, Strauch, Kerstin, Litwinski, Christian, Nyokong, Tebello, Schlettwein, Derck, Schwoerer, Heinrich
- Authors: Rohwer, Egmont , Richter, Christoph , Heming, Nadine , Strauch, Kerstin , Litwinski, Christian , Nyokong, Tebello , Schlettwein, Derck , Schwoerer, Heinrich
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/242153 , vital:51006 , xlink:href="https://doi.org/10.1002/cphc.201200715"
- Description: We investigate the ultrafast dynamics of the photoinduced electron transfer between surface-adsorbed indoline D149 dye and porous ZnO as used in the working electrodes of dye-sensitized solar cells. Transient absorption spectroscopy was conducted on the dye in solution, on solid state samples and for the latter in contact to a I−/I3− redox electrolyte typical for dye-sensitized solar cells to elucidate the effect of each component in the observed dynamics. D149 in a solution of 1:1 acetonitrile and tert-butyl alcohol shows excited-state lifetimes of 300±50 ps. This signature is severely quenched when D149 is adsorbed to ZnO, with the fastest component of the decay trace measured at 150±20 fs due to the charge-transfer mechanism. Absorption bands of the oxidized dye molecule were investigated to determine regeneration times which are in excess of 1 ns. The addition of the redox electrolyte to the system results in faster regeneration times, of the order of 1 ns.
- Full Text:
- Date Issued: 2013
- Authors: Rohwer, Egmont , Richter, Christoph , Heming, Nadine , Strauch, Kerstin , Litwinski, Christian , Nyokong, Tebello , Schlettwein, Derck , Schwoerer, Heinrich
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/242153 , vital:51006 , xlink:href="https://doi.org/10.1002/cphc.201200715"
- Description: We investigate the ultrafast dynamics of the photoinduced electron transfer between surface-adsorbed indoline D149 dye and porous ZnO as used in the working electrodes of dye-sensitized solar cells. Transient absorption spectroscopy was conducted on the dye in solution, on solid state samples and for the latter in contact to a I−/I3− redox electrolyte typical for dye-sensitized solar cells to elucidate the effect of each component in the observed dynamics. D149 in a solution of 1:1 acetonitrile and tert-butyl alcohol shows excited-state lifetimes of 300±50 ps. This signature is severely quenched when D149 is adsorbed to ZnO, with the fastest component of the decay trace measured at 150±20 fs due to the charge-transfer mechanism. Absorption bands of the oxidized dye molecule were investigated to determine regeneration times which are in excess of 1 ns. The addition of the redox electrolyte to the system results in faster regeneration times, of the order of 1 ns.
- Full Text:
- Date Issued: 2013
Understanding the sexual risk behaviours of people living with different mental illnesses and their vulnerability to HIV infection
- Authors: Ndlovu, Deogracious
- Date: 2013
- Subjects: Health -- Social aspects , HIV infections
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/25037 , vital:63899
- Description: This study was primarily carried out in order to assess the sexual risk behaviours of people living with mental illnesses as well as their vulnerability to HIV infection. It sets out the basic realities of the interaction between mental illness and HIV/AIDS and its impact on individuals and communities. This study explores the implications for health policy and practice, and suggests how to provide better support and assistance in the empowerment of people living with mental illness as far as HIV and AIDS is concerned, including community support. It was also the aim of this study to look into the factors that expose this group of people to HIV infection as well as to understand the link between HIV/AIDS and mental illness. It also tested the inclusion of people with mental disabilities in HIV and AIDS prevention and education programmes. The research was conducted on the basis of a qualitative research design. A semi-structured interview schedule was used in broad based interviews to gather information from caregivers or guardians of people with mental disabilities as well as the professionals in the mental health sector. The results of the research revealed that people who are living with mental illnesses are a vulnerable group as regards HIV infection. It also conveys that this group of people presents with sexual risk behaviours, which increase their vulnerability to HIV and AIDS. In addition, there are many barriers against the inclusion of this group of people in HIV and AIDS prevention and education programmes and, as a result, they are often excluded from participating in such programmes. Importantly, the findings of this study acknowledge that there is a two-fold relationship between mental illness and HIV/AIDS. It indicates that mental illnesses are still regarded as mysterious in the community and there is much stigma and discrimination towards the mentally ill, increasing their vulnerability to HIV infection. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2013
- Full Text:
- Date Issued: 2013
- Authors: Ndlovu, Deogracious
- Date: 2013
- Subjects: Health -- Social aspects , HIV infections
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/25037 , vital:63899
- Description: This study was primarily carried out in order to assess the sexual risk behaviours of people living with mental illnesses as well as their vulnerability to HIV infection. It sets out the basic realities of the interaction between mental illness and HIV/AIDS and its impact on individuals and communities. This study explores the implications for health policy and practice, and suggests how to provide better support and assistance in the empowerment of people living with mental illness as far as HIV and AIDS is concerned, including community support. It was also the aim of this study to look into the factors that expose this group of people to HIV infection as well as to understand the link between HIV/AIDS and mental illness. It also tested the inclusion of people with mental disabilities in HIV and AIDS prevention and education programmes. The research was conducted on the basis of a qualitative research design. A semi-structured interview schedule was used in broad based interviews to gather information from caregivers or guardians of people with mental disabilities as well as the professionals in the mental health sector. The results of the research revealed that people who are living with mental illnesses are a vulnerable group as regards HIV infection. It also conveys that this group of people presents with sexual risk behaviours, which increase their vulnerability to HIV and AIDS. In addition, there are many barriers against the inclusion of this group of people in HIV and AIDS prevention and education programmes and, as a result, they are often excluded from participating in such programmes. Importantly, the findings of this study acknowledge that there is a two-fold relationship between mental illness and HIV/AIDS. It indicates that mental illnesses are still regarded as mysterious in the community and there is much stigma and discrimination towards the mentally ill, increasing their vulnerability to HIV infection. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2013
- Full Text:
- Date Issued: 2013
Using a unified invasion framework to characterize Africa’s first loricariid catfish invasion
- Jones, Roy W, Weyl, Olaf L F, Hill, Martin P, Swartz, Ernst R
- Authors: Jones, Roy W , Weyl, Olaf L F , Hill, Martin P , Swartz, Ernst R
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/418081 , vital:71507 , xlink:href="https://doi.org/10.1007/s10530-013-0438-7"
- Description: This paper presents evidence of establishment of a loricariid population in the Nseleni River in South Africa and uses a unified framework to determine its invasion stage. Specimens were identified morphologically as Pterygioplichthys disjunctivus (Weber 1991), but genetic barcoding results indicated close association with specimens that may have a hybrid history. The species was introduced into South Africa via the pet trade and the first record of introduction into the wild was in 2004. Samples collected in 2011 and 2012 demonstrated that there were multiple length cohorts in the population including juveniles (12–130 mm total length TL) and large (>300 mm TL) adult fish. Gonadal assessment of adults demonstrated the presence of reproduction capable specimens. The concurrent occurrence of mature adults and juvenile fish demonstrated establishment. Locality records indicate that P. disjunctivus has already spread between two rivers through an inter basin water transfer. Using a unified framework for invasions this invasion was categorized as a self-sustaining population in the wild with individuals surviving and reproducing a significant distance from their original point of introduction. Containment is suggested as potential management strategy.
- Full Text:
- Date Issued: 2013
- Authors: Jones, Roy W , Weyl, Olaf L F , Hill, Martin P , Swartz, Ernst R
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/418081 , vital:71507 , xlink:href="https://doi.org/10.1007/s10530-013-0438-7"
- Description: This paper presents evidence of establishment of a loricariid population in the Nseleni River in South Africa and uses a unified framework to determine its invasion stage. Specimens were identified morphologically as Pterygioplichthys disjunctivus (Weber 1991), but genetic barcoding results indicated close association with specimens that may have a hybrid history. The species was introduced into South Africa via the pet trade and the first record of introduction into the wild was in 2004. Samples collected in 2011 and 2012 demonstrated that there were multiple length cohorts in the population including juveniles (12–130 mm total length TL) and large (>300 mm TL) adult fish. Gonadal assessment of adults demonstrated the presence of reproduction capable specimens. The concurrent occurrence of mature adults and juvenile fish demonstrated establishment. Locality records indicate that P. disjunctivus has already spread between two rivers through an inter basin water transfer. Using a unified framework for invasions this invasion was categorized as a self-sustaining population in the wild with individuals surviving and reproducing a significant distance from their original point of introduction. Containment is suggested as potential management strategy.
- Full Text:
- Date Issued: 2013
Using assessment strategically to gestate a student thesis
- Authors: Grant, Carolyn
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281164 , vital:55698 , xlink:href="https://hdl.handle.net/10520/EJC153523"
- Description: In the context of higher education in South Africa and drawing on the author's experience as a lecturer in two higher education institutions (HEIs), this article presents her attempts to bring together - and into balance - teaching, supervision and research in an endeavour to offer a transformative learning experience for her post graduate students. It does this by foregrounding student assessment in the Master of Education (MEd) degree in the field of Educational Leadership and Management (ELM) where the development of a half thesis, underpinned by research, stands as the evidence of success. The author suggests that the MEd (ELM) degree be conceptualised differently in order that the half thesis be permitted to gestate over a two-year period. Within this conceptualisation, she argues that inspired teaching and meaningful research is best attained through a community of learning approach which seeks to foreground participatory learning, the advancement of scholarly discourse and the development of student agency. Through the use of a case study, the author provides evidence to suggest that a range of authentic assessment strategies which are purposeful and in alignment with the teaching strategies, the content and the intended outcomes of the qualification being taught are essential. She further argues that well-crafted, formative, recursive and sustainable feedback is an essential part of the gestation process.
- Full Text:
- Date Issued: 2013
- Authors: Grant, Carolyn
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281164 , vital:55698 , xlink:href="https://hdl.handle.net/10520/EJC153523"
- Description: In the context of higher education in South Africa and drawing on the author's experience as a lecturer in two higher education institutions (HEIs), this article presents her attempts to bring together - and into balance - teaching, supervision and research in an endeavour to offer a transformative learning experience for her post graduate students. It does this by foregrounding student assessment in the Master of Education (MEd) degree in the field of Educational Leadership and Management (ELM) where the development of a half thesis, underpinned by research, stands as the evidence of success. The author suggests that the MEd (ELM) degree be conceptualised differently in order that the half thesis be permitted to gestate over a two-year period. Within this conceptualisation, she argues that inspired teaching and meaningful research is best attained through a community of learning approach which seeks to foreground participatory learning, the advancement of scholarly discourse and the development of student agency. Through the use of a case study, the author provides evidence to suggest that a range of authentic assessment strategies which are purposeful and in alignment with the teaching strategies, the content and the intended outcomes of the qualification being taught are essential. She further argues that well-crafted, formative, recursive and sustainable feedback is an essential part of the gestation process.
- Full Text:
- Date Issued: 2013
Weevil borne microbes contribute as much to the reduction of photosynthesis in water hyacinth as does herbivory
- Venter, Nic, Hill, Martin P, Hutchinson, Sarah-Leigh, Ripley, Bradford S
- Authors: Venter, Nic , Hill, Martin P , Hutchinson, Sarah-Leigh , Ripley, Bradford S
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/423573 , vital:72073 , xlink:href="https://doi.org/10.1016/j.biocontrol.2012.10.011"
- Description: Arthropods released for weed biocontrol can have effects other than simply removing biomass and frequently decrease photosynthetic rate more than can be attributed to the mere loss of photosynthetic surface area. Some of this effect may result because biological control agents facilitate the transfer and ingress of deleterious microbes into plant tissues on which they feed. We evaluated this facilitation effect using water hyacinth (Eichhornia crassipes) and a weevil (Neochetina eichhorniae) and compared the reductions in photosynthetic rates between leaves subject to herbivory by adult weevils sterilized with 3.5% chlorine bleach, to those that were unsterilized. The results showed that weevils carried both fungi and bacteria, transferred these to leaves on which they fed, and that microbes and biomass removal contributed almost equally to the 37% decrease in photosynthetic productivity. Hence, maximising the effectiveness of using arthropods that damage leaf surfaces for biocontrol requires the presence of microorganisms that are deleterious to plants.
- Full Text:
- Date Issued: 2013
- Authors: Venter, Nic , Hill, Martin P , Hutchinson, Sarah-Leigh , Ripley, Bradford S
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/423573 , vital:72073 , xlink:href="https://doi.org/10.1016/j.biocontrol.2012.10.011"
- Description: Arthropods released for weed biocontrol can have effects other than simply removing biomass and frequently decrease photosynthetic rate more than can be attributed to the mere loss of photosynthetic surface area. Some of this effect may result because biological control agents facilitate the transfer and ingress of deleterious microbes into plant tissues on which they feed. We evaluated this facilitation effect using water hyacinth (Eichhornia crassipes) and a weevil (Neochetina eichhorniae) and compared the reductions in photosynthetic rates between leaves subject to herbivory by adult weevils sterilized with 3.5% chlorine bleach, to those that were unsterilized. The results showed that weevils carried both fungi and bacteria, transferred these to leaves on which they fed, and that microbes and biomass removal contributed almost equally to the 37% decrease in photosynthetic productivity. Hence, maximising the effectiveness of using arthropods that damage leaf surfaces for biocontrol requires the presence of microorganisms that are deleterious to plants.
- Full Text:
- Date Issued: 2013
X-ray photoelectron spectroscopy analysis of the effect of alkyl-and arylthio substituents on manganese phthalocyanines for self-assembled monolayer formation on gold
- Coates, Megan, Nyokong, Tebello
- Authors: Coates, Megan , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190490 , vital:44999 , xlink:href="https://doi.org/10.1016/j.elecom.2013.03.019"
- Description: Self-assembled monolayers of an octa-substituted alkylthio and arylthio manganese phthalocyanines were formed on gold. X-ray photoelectron spectroscopy was used to analyse both of the phthalocyanine layers on gold. Approximately 60% of the sulphur groups in the aryl substituted-SAM surface were bound to gold through the cleavage of the C S bond, as opposed to only 37% for the alkyl substituted-SAM.
- Full Text:
- Date Issued: 2013
- Authors: Coates, Megan , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190490 , vital:44999 , xlink:href="https://doi.org/10.1016/j.elecom.2013.03.019"
- Description: Self-assembled monolayers of an octa-substituted alkylthio and arylthio manganese phthalocyanines were formed on gold. X-ray photoelectron spectroscopy was used to analyse both of the phthalocyanine layers on gold. Approximately 60% of the sulphur groups in the aryl substituted-SAM surface were bound to gold through the cleavage of the C S bond, as opposed to only 37% for the alkyl substituted-SAM.
- Full Text:
- Date Issued: 2013
Zinc (II) 2, 9, 16, 23-tetrakis [4-(N-methylpyridyloxy)]-phthalocyanine anchored on an electrospun polysulfone polymer fiber: Application for photosensitized conversion of methyl orange
- Zugle, Ruphino, Nyokong, Tebello
- Authors: Zugle, Ruphino , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/232741 , vital:50020 , xlink:href="https://doi.org/10.1016/j.molcata.2012.10.001"
- Description: In this work, a comparative study of photodegradation of methyl orange, an azo dye, in homogeneous aqueous solution of a quarternized cationic zinc phthalocyanine and a heterogeneous catalytic system based on the same phthalocyanine anchored on polysulfone polymer fiber is presented. In both cases, conversion involved the azo bond of the dye with no detectable opening up of the aromatic benzene rings. The reaction kinetics in both cases were consistent with first order with the conversion occurring in the homogeneous system being faster than when the functionalized polymer fiber was used. The reaction products consisted of a coupling product as well as a series of oligopolymeric products.
- Full Text:
- Date Issued: 2013
- Authors: Zugle, Ruphino , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/232741 , vital:50020 , xlink:href="https://doi.org/10.1016/j.molcata.2012.10.001"
- Description: In this work, a comparative study of photodegradation of methyl orange, an azo dye, in homogeneous aqueous solution of a quarternized cationic zinc phthalocyanine and a heterogeneous catalytic system based on the same phthalocyanine anchored on polysulfone polymer fiber is presented. In both cases, conversion involved the azo bond of the dye with no detectable opening up of the aromatic benzene rings. The reaction kinetics in both cases were consistent with first order with the conversion occurring in the homogeneous system being faster than when the functionalized polymer fiber was used. The reaction products consisted of a coupling product as well as a series of oligopolymeric products.
- Full Text:
- Date Issued: 2013
A Feminist Analysis of Lyman Frank Baum’s The Wonderful Wizard of Oz, Lucy Maud Montgomery’s Anne of Green Gables and Frances Hodgson Burnett’s The Secret Garden
- Authors: Becker, Bonnie
- Date: 2013-01
- Subjects: Fiction , Children , Orphans
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23214 , vital:55905
- Description: The primary aim of this project is to provide a close contextual and textual analysis of the selected children’s classics: The Wonderful Wizard of Oz, Anne of Green Gables and The Secret Garden using the feminist literary theory. From this perspective I have shown how the selected works of Lyman Frank Baum, Lucy Maud Montgomery and Frances Hodgson Burnett’s writing have contributed to women’s stereotypical roles within society and perpetuated their subjugated position. I have also conducted an examination of the extent to which the female protagonists attempt to emancipate themselves from gender oppression. A comparative study of the selected children’s texts has not yet been conducted and therefore this project serves as a significant contribution to this field of study. An exploration of the historical background of the authors and children’s literature is conducted to provide an overview into the inner workings of the writers’ lives and the historical significance of children’s literature as a genre. The theoretical framework of feminist literary theory is used in the analysis of the selected texts. The connection between feminist literary theory and children’s literature is highlighted and provides further understanding of the purpose of this study. The history of feminism as both a movement and a contemporary literary criticism is explored. Simone de Beauvoir’s The Second Sex is used when analysing the texts’ characters and how they are based on society’s stereotypical gender roles. Luce Irigaray’s Speculum of the Other Woman and This Sex Which is Not One is examined to aid in an exploration of psychological female oppression through feminine and masculine discourse evident in the creation of the novels’ female and male characters. Hélène Cixous’ “The Laugh of the Medusa” and The Newly Born Woman is interrogated according to the stereotypical ideology surrounding the terms masculinity and femininity and how these terms are interpreted in the selected works. Judith Butler’s Gender Trouble and Undoing Gender are additionally explored to assist in the understanding of the concept of gender performativity and through the lens of Butler’s interpolation of gender the move towards the emancipation of women is seen in the selected children’s texts. The close textual feminist analysis focuses on the female protagonists: Dorothy, Anne and Mary as well as the secondary female characters: the wicked witches, Aunt Em, the Queen of the Field-Mice, the princess made from china, Glinda’s female soldiers from The Wonderful Wizard of Oz; Marilla Cuthbert, Rachel Lynde and Diana Barry from Anne of Green Gables and Martha, Mrs Sowerby and Mrs Craven from The Secret Garden. The portrayal of the secondary male characters are additionally explored according to feminist literary theory: The Scarecrow, the Tin Woodman, the Lion and the wizard Oz from The Wonderful Wizard of Oz; Matthew Cuthbert and Gilbert Blythe from Anne of the Green Gables’ and Mr Craven, Colin Craven and Dickon Sowerby from The Secret Garden. The comparison of these children’s classics by Baum, Montgomery and Burnett provides insight into the selected works of all three writers, through the lens offered by feminist literary theory. Through the interrogation of these representative female protagonists found in early children’s literature, an understanding of not only the subordination of women, as evident in literature during this era, is illustrated but also the comprehension that women’s liberation was foreshadowed in these early children’s novels. , Thesis (MA) -- Faculty of Social Sciences and Humanities, 2013
- Full Text:
- Date Issued: 2013-01
- Authors: Becker, Bonnie
- Date: 2013-01
- Subjects: Fiction , Children , Orphans
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23214 , vital:55905
- Description: The primary aim of this project is to provide a close contextual and textual analysis of the selected children’s classics: The Wonderful Wizard of Oz, Anne of Green Gables and The Secret Garden using the feminist literary theory. From this perspective I have shown how the selected works of Lyman Frank Baum, Lucy Maud Montgomery and Frances Hodgson Burnett’s writing have contributed to women’s stereotypical roles within society and perpetuated their subjugated position. I have also conducted an examination of the extent to which the female protagonists attempt to emancipate themselves from gender oppression. A comparative study of the selected children’s texts has not yet been conducted and therefore this project serves as a significant contribution to this field of study. An exploration of the historical background of the authors and children’s literature is conducted to provide an overview into the inner workings of the writers’ lives and the historical significance of children’s literature as a genre. The theoretical framework of feminist literary theory is used in the analysis of the selected texts. The connection between feminist literary theory and children’s literature is highlighted and provides further understanding of the purpose of this study. The history of feminism as both a movement and a contemporary literary criticism is explored. Simone de Beauvoir’s The Second Sex is used when analysing the texts’ characters and how they are based on society’s stereotypical gender roles. Luce Irigaray’s Speculum of the Other Woman and This Sex Which is Not One is examined to aid in an exploration of psychological female oppression through feminine and masculine discourse evident in the creation of the novels’ female and male characters. Hélène Cixous’ “The Laugh of the Medusa” and The Newly Born Woman is interrogated according to the stereotypical ideology surrounding the terms masculinity and femininity and how these terms are interpreted in the selected works. Judith Butler’s Gender Trouble and Undoing Gender are additionally explored to assist in the understanding of the concept of gender performativity and through the lens of Butler’s interpolation of gender the move towards the emancipation of women is seen in the selected children’s texts. The close textual feminist analysis focuses on the female protagonists: Dorothy, Anne and Mary as well as the secondary female characters: the wicked witches, Aunt Em, the Queen of the Field-Mice, the princess made from china, Glinda’s female soldiers from The Wonderful Wizard of Oz; Marilla Cuthbert, Rachel Lynde and Diana Barry from Anne of Green Gables and Martha, Mrs Sowerby and Mrs Craven from The Secret Garden. The portrayal of the secondary male characters are additionally explored according to feminist literary theory: The Scarecrow, the Tin Woodman, the Lion and the wizard Oz from The Wonderful Wizard of Oz; Matthew Cuthbert and Gilbert Blythe from Anne of the Green Gables’ and Mr Craven, Colin Craven and Dickon Sowerby from The Secret Garden. The comparison of these children’s classics by Baum, Montgomery and Burnett provides insight into the selected works of all three writers, through the lens offered by feminist literary theory. Through the interrogation of these representative female protagonists found in early children’s literature, an understanding of not only the subordination of women, as evident in literature during this era, is illustrated but also the comprehension that women’s liberation was foreshadowed in these early children’s novels. , Thesis (MA) -- Faculty of Social Sciences and Humanities, 2013
- Full Text:
- Date Issued: 2013-01
Children’s Grants and Social Security Communities in the Eastern Cape : The Case of Nqabarha Administrative Area
- Authors: Mwangolela, Tafadzwa Fungay
- Date: 2013-01
- Subjects: Children -- Services for -- South Africa -- Eastern Cape , Grants in aid , Social Security -- South Africa -- Eastern Cape
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23159 , vital:55664
- Description: This study examines the impact of children’s grants on household access to food, education and health care. In the face of increased poverty and socio-economic inequalities, social grants are a critical poverty alleviation intervention implemented by the government of South Africa. The children’s grants are offered as part of the social security system which is provided for in the Republic of South Africa Constitution of 1996 and the Social Assistance Act of 2004. The basic needs conceptual framework is the lens informing the focus of the study. Among other major findings, the study reveals that (a) childrens grants play a critical role in improvement of access to food, health care and education, (b) childrens grants are used as collateral, to access short term loans, and (c) social networks and home gardens play a significant role in aiding children’s grants to ensure household access to food, education and health care. , Thesis (MA) -- Faculty Social Sciences and Humanities, 2013
- Full Text:
- Date Issued: 2013-01
- Authors: Mwangolela, Tafadzwa Fungay
- Date: 2013-01
- Subjects: Children -- Services for -- South Africa -- Eastern Cape , Grants in aid , Social Security -- South Africa -- Eastern Cape
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23159 , vital:55664
- Description: This study examines the impact of children’s grants on household access to food, education and health care. In the face of increased poverty and socio-economic inequalities, social grants are a critical poverty alleviation intervention implemented by the government of South Africa. The children’s grants are offered as part of the social security system which is provided for in the Republic of South Africa Constitution of 1996 and the Social Assistance Act of 2004. The basic needs conceptual framework is the lens informing the focus of the study. Among other major findings, the study reveals that (a) childrens grants play a critical role in improvement of access to food, health care and education, (b) childrens grants are used as collateral, to access short term loans, and (c) social networks and home gardens play a significant role in aiding children’s grants to ensure household access to food, education and health care. , Thesis (MA) -- Faculty Social Sciences and Humanities, 2013
- Full Text:
- Date Issued: 2013-01
Group 12 metal chalcogenides as single source molecular precursors for the preparation of metal sulfide nanoparticles
- Osuntokun, Jejenija https://orcid.org/0000-0003-0886-2732
- Authors: Osuntokun, Jejenija https://orcid.org/0000-0003-0886-2732
- Date: 2013-01
- Subjects: Ligands , Chalcogenides , Chemistry, Inorganic
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/27428 , vital:67295
- Description: Twelve Zn(II), Cd(II) and Hg(II) complexes of mixed ligands: alkyl thiourea, 1-ethoxylcarbonyl-1-cyanoethylene-2,2-dithiolate and tetramethylthiuram disulfide were synthesized by the reaction between the ligands and the respective metal salts. The compounds were characterized by elemental analysis, infrared (IR), 1H- and 13C-NMR spectroscopy. Four coordinate geometries were proposed for the compounds based on elemental and spectroscopic analyses. The metal complexes were at best sparingly soluble in polar coordinating solvents such as DMSO and DMF and insoluble in most organic solvents. This makes it practically impossible to grow single crystals suitable for X-ray crystallographic analysis and also resulted in extremely poor 13C-NMR spectra for some of the complexes. Thermogravimetric analysis on some of the complexes showed that they decomposed to their respective metal sulfides and thus suitable as single molecular precursors for the preparation of metal sulfide nanoparticles. Nine of the complexes with good yield were thermolysed and used as single source precursors to synthesized hexadexylamine capped metal sulfide nanoparticles. The optical and structural properties of the nanoparticles were studied using UV-Visible, photoluminescence (PL), scanning electron microscopy (SEM), transmission electron microscopy (TEM), powder X-ray diffraction (XRD) and energy dispersive spectroscopy (EDX). The absorption and emission spectra of the nanoparticles show quantum confinement. The SEM showed the morphology of the particles as nearly spherical, the EDX spectra revealed peaks corresponding to respective metal and sulfur with traces of contaminants being phosphorus from tri-n-octylphosphine (TOP). , Thesis (MSc) -- Faculty of Science and Agriculture, 2013
- Full Text:
- Date Issued: 2013-01
- Authors: Osuntokun, Jejenija https://orcid.org/0000-0003-0886-2732
- Date: 2013-01
- Subjects: Ligands , Chalcogenides , Chemistry, Inorganic
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/27428 , vital:67295
- Description: Twelve Zn(II), Cd(II) and Hg(II) complexes of mixed ligands: alkyl thiourea, 1-ethoxylcarbonyl-1-cyanoethylene-2,2-dithiolate and tetramethylthiuram disulfide were synthesized by the reaction between the ligands and the respective metal salts. The compounds were characterized by elemental analysis, infrared (IR), 1H- and 13C-NMR spectroscopy. Four coordinate geometries were proposed for the compounds based on elemental and spectroscopic analyses. The metal complexes were at best sparingly soluble in polar coordinating solvents such as DMSO and DMF and insoluble in most organic solvents. This makes it practically impossible to grow single crystals suitable for X-ray crystallographic analysis and also resulted in extremely poor 13C-NMR spectra for some of the complexes. Thermogravimetric analysis on some of the complexes showed that they decomposed to their respective metal sulfides and thus suitable as single molecular precursors for the preparation of metal sulfide nanoparticles. Nine of the complexes with good yield were thermolysed and used as single source precursors to synthesized hexadexylamine capped metal sulfide nanoparticles. The optical and structural properties of the nanoparticles were studied using UV-Visible, photoluminescence (PL), scanning electron microscopy (SEM), transmission electron microscopy (TEM), powder X-ray diffraction (XRD) and energy dispersive spectroscopy (EDX). The absorption and emission spectra of the nanoparticles show quantum confinement. The SEM showed the morphology of the particles as nearly spherical, the EDX spectra revealed peaks corresponding to respective metal and sulfur with traces of contaminants being phosphorus from tri-n-octylphosphine (TOP). , Thesis (MSc) -- Faculty of Science and Agriculture, 2013
- Full Text:
- Date Issued: 2013-01
Leaners' perceptions of factors contributing to poor academic performance in rural high schools of the Fort Beaufort Education District
- Authors: Tom, Lusu Lennox
- Date: 2013-01
- Subjects: Education, Higher , School management and organization , Teacher effectiveness
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10353/25272 , vital:64137
- Description: This research investigates learners’ perceptions of factors which they believe contribute to their poor academic performance in high schools. The study focuses on four schools in Fort Beaufort district of the Eastern Cape. Twenty-four learners (6 from each school) participated in this study. Using a theoretical framework drawn from Bandura (1977) the study explored the views of learners in both under and high performing schools. One main research question was posed, answered and discussed for the purpose of the study. Data was collected through individual interviews, focus group discussions and document analyses. The findings of the study revealed a number of factors contributing to poor academic performance. These were learner factors, teacher factors, home factors and teaching resources. Regarding learner factors, the study revealed that while learners were committed and motivated to do their work in order to avoid low income jobs, this did not always happen as they found themselves getting distracted during class time and this affected their performance. The study revealed that some of the teachers lacked commitment, and were very unprofessional and incompetent. This, according to the learners, contributed to poor learner performance in the various subjects. Home factors also played a role in learner performance. The study revealed that home factors were seen to be enabling when parents were supportive and helpful to their children. At the same time, home factors tended to impede learning when learners were given household chores to do and this impinged on their study time. Some parents were also illiterate and as a result were not able to help their children with homework or supervise them while they were busy with their homework. The lack of teaching and learning resources such as textbooks, computers and laboratories as well as overcrowded classrooms also contributed to poor learner performance. This study makes the following recommendations: Teachers should be closely monitored by principals to ensure that they come to class regularly and are punctual so that learners do not lose time necessary to cover the content on their syllabus. Teachers should plan and prepare for lessons thoroughly. Lessons must cover a wide range of activities during their teaching to actively engage learners and prepare them adequately for their assessment tasks, including examinations. Teachers should be work-shopped regularly in order to capacitate them on the latest trends and pedagogies in education as well as rejuvenate their professionalism. It is important that teachers be active researchers in class in order to appraise themselves their learners’ needs and how they can, from the learners’ point of view, improve service delivery. From time to time teachers should work closely with parents to develop strategies they can jointly use to monitor and support children’s learning effectively. , Thesis (MEd) -- Faculty of Education, 2013
- Full Text:
- Date Issued: 2013-01
- Authors: Tom, Lusu Lennox
- Date: 2013-01
- Subjects: Education, Higher , School management and organization , Teacher effectiveness
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10353/25272 , vital:64137
- Description: This research investigates learners’ perceptions of factors which they believe contribute to their poor academic performance in high schools. The study focuses on four schools in Fort Beaufort district of the Eastern Cape. Twenty-four learners (6 from each school) participated in this study. Using a theoretical framework drawn from Bandura (1977) the study explored the views of learners in both under and high performing schools. One main research question was posed, answered and discussed for the purpose of the study. Data was collected through individual interviews, focus group discussions and document analyses. The findings of the study revealed a number of factors contributing to poor academic performance. These were learner factors, teacher factors, home factors and teaching resources. Regarding learner factors, the study revealed that while learners were committed and motivated to do their work in order to avoid low income jobs, this did not always happen as they found themselves getting distracted during class time and this affected their performance. The study revealed that some of the teachers lacked commitment, and were very unprofessional and incompetent. This, according to the learners, contributed to poor learner performance in the various subjects. Home factors also played a role in learner performance. The study revealed that home factors were seen to be enabling when parents were supportive and helpful to their children. At the same time, home factors tended to impede learning when learners were given household chores to do and this impinged on their study time. Some parents were also illiterate and as a result were not able to help their children with homework or supervise them while they were busy with their homework. The lack of teaching and learning resources such as textbooks, computers and laboratories as well as overcrowded classrooms also contributed to poor learner performance. This study makes the following recommendations: Teachers should be closely monitored by principals to ensure that they come to class regularly and are punctual so that learners do not lose time necessary to cover the content on their syllabus. Teachers should plan and prepare for lessons thoroughly. Lessons must cover a wide range of activities during their teaching to actively engage learners and prepare them adequately for their assessment tasks, including examinations. Teachers should be work-shopped regularly in order to capacitate them on the latest trends and pedagogies in education as well as rejuvenate their professionalism. It is important that teachers be active researchers in class in order to appraise themselves their learners’ needs and how they can, from the learners’ point of view, improve service delivery. From time to time teachers should work closely with parents to develop strategies they can jointly use to monitor and support children’s learning effectively. , Thesis (MEd) -- Faculty of Education, 2013
- Full Text:
- Date Issued: 2013-01
Perspectives of communities on use of alcohol among children in rural areas
- Authors: Noganta, Nandi
- Date: 2013-01
- Subjects: Children -- Alcohol use , Youth -- Alcohol use -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/25382 , vital:64234
- Description: Globalisation raises hopes that communities will become self reliant through development success and thus become an integrated whole (Offiong 2001). But the creation of global village leads to fragmentation of communities, a loss of norms and local values. This study focuses on communities of the Eastern Cape Province, exploring the nature of and extent to which children use alcohol as a consequence of cultural rituals. The researcher aims to develop a culturally sensitive psycho-social approach to address alcohol use among children. The purpose of the research was to investigate the extent to which certain cultural practices contribute towards alcohol use among children in the rural areas of the Eastern Cape Province. Thus exploring the nature and extent to which children use alcohol as a consequence of cultural rituals and to explore whether families and communities are aware of the impact of alcohol use by children in the community. The research was qualitative in nature and through semi-structured interview schedules the researcher was able to gain insight in the area of substance use amongst children in the rural areas of the Eastern Cape Province. Community members, learners from schools, educators and probation officers formed part of the research sample. The research findings suggest that community members are aware that the traditional rituals that are carried out in the rural areas have been contributing to the issue of children using alcohol. However, the community members feel challenged as they become conflicted by their traditional rituals and this impacts upon children using alcohol. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2013
- Full Text:
- Date Issued: 2013-01
- Authors: Noganta, Nandi
- Date: 2013-01
- Subjects: Children -- Alcohol use , Youth -- Alcohol use -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/25382 , vital:64234
- Description: Globalisation raises hopes that communities will become self reliant through development success and thus become an integrated whole (Offiong 2001). But the creation of global village leads to fragmentation of communities, a loss of norms and local values. This study focuses on communities of the Eastern Cape Province, exploring the nature of and extent to which children use alcohol as a consequence of cultural rituals. The researcher aims to develop a culturally sensitive psycho-social approach to address alcohol use among children. The purpose of the research was to investigate the extent to which certain cultural practices contribute towards alcohol use among children in the rural areas of the Eastern Cape Province. Thus exploring the nature and extent to which children use alcohol as a consequence of cultural rituals and to explore whether families and communities are aware of the impact of alcohol use by children in the community. The research was qualitative in nature and through semi-structured interview schedules the researcher was able to gain insight in the area of substance use amongst children in the rural areas of the Eastern Cape Province. Community members, learners from schools, educators and probation officers formed part of the research sample. The research findings suggest that community members are aware that the traditional rituals that are carried out in the rural areas have been contributing to the issue of children using alcohol. However, the community members feel challenged as they become conflicted by their traditional rituals and this impacts upon children using alcohol. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2013
- Full Text:
- Date Issued: 2013-01
Perspectives of communities on use of alcohol among children in rural areas
- Noganta, Nandi https://orcid.org/0000-0002-7115-3261
- Authors: Noganta, Nandi https://orcid.org/0000-0002-7115-3261
- Date: 2013-01
- Subjects: Alcohol use , Substance abuse , Children
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23192 , vital:55893
- Description: Globalisation raises hopes that communities will become self reliant through development success and thus become an integrated whole (Offiong 2001). But the creation of global village leads to fragmentation of communities, a loss of norms and local values. This study focuses on communities of the Eastern Cape Province, exploring the nature of and extent to which children use alcohol as a consequence of cultural rituals. The researcher aims to develop a culturally sensitive psycho-social approach to address alcohol use among children. The purpose of the research was to investigate the extent to which certain cultural practices contribute towards alcohol use among children in the rural areas of the Eastern Cape Province. Thus exploring the nature and extent to which children use alcohol as a consequence of cultural rituals and to explore whether families and communities are aware of the impact of alcohol use by children in the community. The research was qualitative in nature and through semi-structured interview schedules the researcher was able to gain insight in the area of substance use amongst children in the rural areas of the Eastern Cape Province. Community members, learners from schools, educators and probation officers formed part of the research sample. The research findings suggest that community members are aware that the traditional rituals that are carried out in the rural areas have been contributing to the issue of children using alcohol. However, the community members feel challenged as they become conflicted by their traditional rituals and this impacts upon children using alcohol. , Thesis (MA) -- Faculty of Social Sciences and Humanities, 2013
- Full Text:
- Date Issued: 2013-01
- Authors: Noganta, Nandi https://orcid.org/0000-0002-7115-3261
- Date: 2013-01
- Subjects: Alcohol use , Substance abuse , Children
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23192 , vital:55893
- Description: Globalisation raises hopes that communities will become self reliant through development success and thus become an integrated whole (Offiong 2001). But the creation of global village leads to fragmentation of communities, a loss of norms and local values. This study focuses on communities of the Eastern Cape Province, exploring the nature of and extent to which children use alcohol as a consequence of cultural rituals. The researcher aims to develop a culturally sensitive psycho-social approach to address alcohol use among children. The purpose of the research was to investigate the extent to which certain cultural practices contribute towards alcohol use among children in the rural areas of the Eastern Cape Province. Thus exploring the nature and extent to which children use alcohol as a consequence of cultural rituals and to explore whether families and communities are aware of the impact of alcohol use by children in the community. The research was qualitative in nature and through semi-structured interview schedules the researcher was able to gain insight in the area of substance use amongst children in the rural areas of the Eastern Cape Province. Community members, learners from schools, educators and probation officers formed part of the research sample. The research findings suggest that community members are aware that the traditional rituals that are carried out in the rural areas have been contributing to the issue of children using alcohol. However, the community members feel challenged as they become conflicted by their traditional rituals and this impacts upon children using alcohol. , Thesis (MA) -- Faculty of Social Sciences and Humanities, 2013
- Full Text:
- Date Issued: 2013-01
Pregnant teenagers' readiness for motherhood: a quantitative investigation in Nkonkobe Municipality, Eastern Cape
- Authors: Pitso, Tsolo Joseph
- Date: 2013-01
- Subjects: Teenage mothers -- South Africa , Teenage pregnancy -- South Africa , Motherhood -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/27440 , vital:67298
- Description: The issue of teenage motherhood has been a concern, globally, continentally and locally. The quantitative study assessed whether the pregnant teenagers were ready for motherhood. This report analysed the current positions of women whose first child was to be born when they were teenagers in the rural Eastern Cape setting. The structured questionnaires were given to 106 pregnant teenagers who visited the War Memorial clinic for pregnancy check-up and convenient sampling was used to select these respondents. The items of the questionnaire were divided into the following sub-topics: prenatal and postnatal challenges and roles and responsibilities of motherhood. The study found that most of the pregnant teenagers were aware of the prenatal and postnatal challenges but they were not ready to perform the roles and responsibilities associated with motherhood. The analysis of data was divided in terms of descriptive and inferential statistics. The binary regression model was used to assess the factors affecting the pregnant teenagers’ readiness for motherhood. The finding of this study indicated that most (about 79%) of the pregnant teenagers were not aware of the roles and responsibilities of motherhood In addition to being not ready to face the psycho-social challenges of motherhood. Hence they indicated low level of readiness to motherhood. The psycho-social theory of Erikson posited that children who had strong and intact psycho-social relationships with the caregivers might have a high possibility of acquiring their identity during adolescent stage and this will help them to interact both effectively and efficiently with their peers and the society at large. While those do had negative psycho-social development have a high chance of facing identity crisis/confusion. As a result, they might lead them to being victims of psycho-social interaction such as early pregnancy. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2013
- Full Text:
- Date Issued: 2013-01
- Authors: Pitso, Tsolo Joseph
- Date: 2013-01
- Subjects: Teenage mothers -- South Africa , Teenage pregnancy -- South Africa , Motherhood -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/27440 , vital:67298
- Description: The issue of teenage motherhood has been a concern, globally, continentally and locally. The quantitative study assessed whether the pregnant teenagers were ready for motherhood. This report analysed the current positions of women whose first child was to be born when they were teenagers in the rural Eastern Cape setting. The structured questionnaires were given to 106 pregnant teenagers who visited the War Memorial clinic for pregnancy check-up and convenient sampling was used to select these respondents. The items of the questionnaire were divided into the following sub-topics: prenatal and postnatal challenges and roles and responsibilities of motherhood. The study found that most of the pregnant teenagers were aware of the prenatal and postnatal challenges but they were not ready to perform the roles and responsibilities associated with motherhood. The analysis of data was divided in terms of descriptive and inferential statistics. The binary regression model was used to assess the factors affecting the pregnant teenagers’ readiness for motherhood. The finding of this study indicated that most (about 79%) of the pregnant teenagers were not aware of the roles and responsibilities of motherhood In addition to being not ready to face the psycho-social challenges of motherhood. Hence they indicated low level of readiness to motherhood. The psycho-social theory of Erikson posited that children who had strong and intact psycho-social relationships with the caregivers might have a high possibility of acquiring their identity during adolescent stage and this will help them to interact both effectively and efficiently with their peers and the society at large. While those do had negative psycho-social development have a high chance of facing identity crisis/confusion. As a result, they might lead them to being victims of psycho-social interaction such as early pregnancy. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2013
- Full Text:
- Date Issued: 2013-01
Pregnant teenagers’ readiness for motherhood:A quantitative investigation in Nkonkobe Municipality, Eastern Cape
- Authors: Pitso, Tsolo Joseph
- Date: 2013-01
- Subjects: Teenage Mothers , Teenage Pregnancy
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23142 , vital:55652
- Description: The issue of teenage motherhood has been a concern, globally, continentally and locally. The quantitative study assessed whether the pregnant teenagers were ready for motherhood. This report analysed the current positions of women whose first child was to be born when they were teenagers in the rural Eastern Cape setting. The structured questionnaires were given to 106 pregnant teenagers who visited the War Memorial clinic for pregnancy check-up and convenient sampling was used to select these respondents. The items of the questionnaire were divided into the following sub-topics: prenatal and postnatal challenges and roles and responsibilities of motherhood. The study found that most of the pregnant teenagers were aware of the prenatal and postnatal challenges but they were not ready to perform the roles and responsibilities associated with motherhood. The analysis of data was divided in terms of descriptive and inferential statistics. The binary regression model was used to assess the factors affecting the pregnant teenagers’ readiness for motherhood. The finding of this study indicated that most (about 79 percent) of the pregnant teenagers were not aware of the roles and responsibilities of motherhood In addition to being not ready to face the psycho-social challenges of motherhood. Hence they indicated low level of readiness to motherhood. The psycho-social theory of Erikson posited that children who had strong and intact psycho-social relationships with the caregivers might have a high possibility of acquiring their identity during adolescent stage and this will help them to interact both effectively and efficiently with their peers and the society at large. While those do had negative psycho-social development have a high chance of facing identity crisis/confusion. As a result, they might lead them to being victims of psycho-social interaction such as early pregnancy. , Thesis (MA) -- Faculty of Social Sciences and Humanities, 2021
- Full Text:
- Date Issued: 2013-01
- Authors: Pitso, Tsolo Joseph
- Date: 2013-01
- Subjects: Teenage Mothers , Teenage Pregnancy
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23142 , vital:55652
- Description: The issue of teenage motherhood has been a concern, globally, continentally and locally. The quantitative study assessed whether the pregnant teenagers were ready for motherhood. This report analysed the current positions of women whose first child was to be born when they were teenagers in the rural Eastern Cape setting. The structured questionnaires were given to 106 pregnant teenagers who visited the War Memorial clinic for pregnancy check-up and convenient sampling was used to select these respondents. The items of the questionnaire were divided into the following sub-topics: prenatal and postnatal challenges and roles and responsibilities of motherhood. The study found that most of the pregnant teenagers were aware of the prenatal and postnatal challenges but they were not ready to perform the roles and responsibilities associated with motherhood. The analysis of data was divided in terms of descriptive and inferential statistics. The binary regression model was used to assess the factors affecting the pregnant teenagers’ readiness for motherhood. The finding of this study indicated that most (about 79 percent) of the pregnant teenagers were not aware of the roles and responsibilities of motherhood In addition to being not ready to face the psycho-social challenges of motherhood. Hence they indicated low level of readiness to motherhood. The psycho-social theory of Erikson posited that children who had strong and intact psycho-social relationships with the caregivers might have a high possibility of acquiring their identity during adolescent stage and this will help them to interact both effectively and efficiently with their peers and the society at large. While those do had negative psycho-social development have a high chance of facing identity crisis/confusion. As a result, they might lead them to being victims of psycho-social interaction such as early pregnancy. , Thesis (MA) -- Faculty of Social Sciences and Humanities, 2021
- Full Text:
- Date Issued: 2013-01
Production and biochemical characterization of new bioflocculants from bacteria isolated from freshwater and marine environments of the Eastern Cape in South Africa
- Mabinya, Leonard Vuyani https://orcid.org/0000-0002-0682-7282
- Authors: Mabinya, Leonard Vuyani https://orcid.org/0000-0002-0682-7282
- Date: 2013-01
- Subjects: Flocculation , Bacteria
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24228 , vital:62445
- Description: The production and characterization of bioflocculants produced by three bacteria belonging to Arthrobacter, Halomonas and Micrococcus genera and isolated from freshwater and marine environments were evaluated both as axenic cultures and as consortia. The influences of cultutre conditions such as carbon, nitrogen and metal ions sources, as well as initial pH on bioflocculant production by individual isolates were investigated. Both Arthrobacter sp. Raats and Halomonas sp. Okoh utilized urea as a nitrogen source of choice for optimal production of the bioflocculants with Micrococcus sp. Leo having a preference for peptone. All three strains differed in as far as the carbon source of choice was concerned with lactose, glucose and sucrose the preferred carbon sources respectively. Also, all three bacterial strains produced an extracellular bioflocculant aerobically but an intial pH 7.0 of the culture media was suitable for both Arthrobacter sp. Raats and Halomonas sp. Okoh with a slightly alkaline pH of 9.0 preferred by Micrococcus sp. Leo. The presence of Mg2+ cations stimulated bioflocculant production by both Arthrobacter sp. Raats and Micrococcus sp. Leo while Ca2+ resulted in more efficient bioflocculant production by Halomonas sp. Okoh. Chemical analyses revealed the bioflocculants produced by both Halomonas sp. Okoh and Micrococcus sp. Leo to be predominantly polysaccharides whereas Arthrobacter sp. Raats produced principally a glycoprotein composed of about 56percent protein and 25percent total carbohydrate. Response surface methodology (RSM) was used to optimize production medium for bioflocculant production by a consortium of Halomonas sp. Okoh and Micrococcus sp. Leo. Plackett-Burman experimental design showed that fructose, ammonium sulphate and MgCl2 were significant in the high yield of the bioflocculant. Furthermore, central composite design showed that optimal concentration of these critical nutritional sources were 16.14 g/L, 1.55 g/L and 1.88 g/L for fructose, ammonium sulphate and MgCl2 respectively. Quantification of the bioflocculant showed a yield of 6.43 g/L which was in close accord with the predicted value of 6.51 g/L. FTIR spectrometry of the bioflocculant indicated the presence of carboxyl, hydroxyl and amino groups, typical for heteropolysaccharide, while SEM imaging revealed a lattice-like structure. The efficiency of the nutrient optimization suggests suitability for industrial applicability. , Thesis (PhD) -- Faculty of Science and Agriculture, 2013
- Full Text:
- Date Issued: 2013-01
- Authors: Mabinya, Leonard Vuyani https://orcid.org/0000-0002-0682-7282
- Date: 2013-01
- Subjects: Flocculation , Bacteria
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24228 , vital:62445
- Description: The production and characterization of bioflocculants produced by three bacteria belonging to Arthrobacter, Halomonas and Micrococcus genera and isolated from freshwater and marine environments were evaluated both as axenic cultures and as consortia. The influences of cultutre conditions such as carbon, nitrogen and metal ions sources, as well as initial pH on bioflocculant production by individual isolates were investigated. Both Arthrobacter sp. Raats and Halomonas sp. Okoh utilized urea as a nitrogen source of choice for optimal production of the bioflocculants with Micrococcus sp. Leo having a preference for peptone. All three strains differed in as far as the carbon source of choice was concerned with lactose, glucose and sucrose the preferred carbon sources respectively. Also, all three bacterial strains produced an extracellular bioflocculant aerobically but an intial pH 7.0 of the culture media was suitable for both Arthrobacter sp. Raats and Halomonas sp. Okoh with a slightly alkaline pH of 9.0 preferred by Micrococcus sp. Leo. The presence of Mg2+ cations stimulated bioflocculant production by both Arthrobacter sp. Raats and Micrococcus sp. Leo while Ca2+ resulted in more efficient bioflocculant production by Halomonas sp. Okoh. Chemical analyses revealed the bioflocculants produced by both Halomonas sp. Okoh and Micrococcus sp. Leo to be predominantly polysaccharides whereas Arthrobacter sp. Raats produced principally a glycoprotein composed of about 56percent protein and 25percent total carbohydrate. Response surface methodology (RSM) was used to optimize production medium for bioflocculant production by a consortium of Halomonas sp. Okoh and Micrococcus sp. Leo. Plackett-Burman experimental design showed that fructose, ammonium sulphate and MgCl2 were significant in the high yield of the bioflocculant. Furthermore, central composite design showed that optimal concentration of these critical nutritional sources were 16.14 g/L, 1.55 g/L and 1.88 g/L for fructose, ammonium sulphate and MgCl2 respectively. Quantification of the bioflocculant showed a yield of 6.43 g/L which was in close accord with the predicted value of 6.51 g/L. FTIR spectrometry of the bioflocculant indicated the presence of carboxyl, hydroxyl and amino groups, typical for heteropolysaccharide, while SEM imaging revealed a lattice-like structure. The efficiency of the nutrient optimization suggests suitability for industrial applicability. , Thesis (PhD) -- Faculty of Science and Agriculture, 2013
- Full Text:
- Date Issued: 2013-01