Identifying methane emissions with isotopic and hydrochemical clues to their origin across selected areas of the Karoo Basin, South Africa
- Authors: Campbell, Richard Duncombe
- Date: 2019
- Subjects: Methane -- Environmental aspects -- South Africa , Atmospheric methane -- Environmental aspects -- South Africa , Groundwater -- Research
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/42218 , vital:36636
- Description: Currently, only sparse data exists on the methane emissions from the Main Karoo Basin, South Africa, where the potential discovery of vast quantities of unconventional natural gas from the black shales of the Whitehill Formation has sparked great interest in the prospect of hydraulic fracturing. In this study, a new infield methane quantification instrument (Picarro G2201-i) is used to identify freely emitted methane and more importantly collect stable carbon isotope ratios (δ13C-(CH4)g) that is used in obtaining information regarding the genetic origin and thermal maturity of the methane. Hydrochemical information (TOC, δ13C-TOC, 3H, δ18O, δ2H, and anions) were also scrutinised to assist in the determination of the origin of methane across the Karoo Basin. Twenty-one sites were investigated across four provinces in the Main Karoo Basin. Six of these sites are thermal springs, three are shallow boreholes (<100 m in depth), and twelve were Soekor (The Southern Oil Exploration Corporation)/deep boreholes (>1500 m). Of these 21 sites, 17 were suitable for either methane analysis or groundwater sampling, with four of the Soekor boreholes unsuitable. The presence of methane in groundwater and being freely emitted seems to be a common occurrence above the Main Karoo basin and of the 17 sites investigated, 14 had freely emitted methane emission. All but one of these sites had δ13C-(CH4)g signatures greater than -50 ‰, indicating a thermogenic origin. Combining the results obtained from the Picarro instrument with those compiled by Talma & Esterhuyse (2015), a higher resolution distribution map was created. The δ13C-CH4 signatures show patterning with a decreasing trend from the southern Karoo Basin to the north, which corresponds to the general decrease in thermal maturity of the Ecca shales (Whitehill Formation) northward across the Karoo Basin. The δ13C-(CH4)d results from a case study conducted by Eymold et al. (2018) differ significantly with the data collected in this study that included several of the same sampling locations. This is explained by a two phase partitioning (gas + water) that leads to the thermogenic endmember of methane being released in its free state (analysed by Picarro G2201-i) and microbial methane that is formed in situ remains dissolved in the water (analysed by Eymold et al. 2018). Soekor and deep sites; SA 1/66, KA 1/66, and KWV-1 that have direct pathways for methane migration from the Whitehill are deemed the best proxies to resolve the thermogenic endmember of methane, with δ13C-(CH4)g signatures of -26.32‰, 31.66‰, and -34.57‰, respectively. The hydrochemistry results suggests that that free methane emissions do not necessarily have to be associated with saline Cl- waters, as multiple sites have CH4 emissions with low salinities (Cl < 50 mg/L) and that methane in its free state can migrate to the surface due to buoyancy. The results also indicate that dolerite intrusions act as conduits for upward migration of groundwater from depth, but that the deep groundwater signatures proposed by Murray et al., (2015) are related to their different migration pathways and water-rock interactions rather than being representative of the deep formation waters. Using an initial assessment δ13C-CH4, TOC concentration [TOC] and the tritium (3H) values, where water samples that have 3H ≤ 1 TU, detectable TOC and δ13C-CH4 signatures > -50‰ could indicate hydraulic connectivity between the shallow aquifer and an organic/CH4 rich sedimentary layer, which may or may not be from the Whitehill Formation. However, this method for determining aquifer connectivity requires further investigations in the Karoo Basin context. The results obtained in this study add to the limited isotopic data of methane across the Karoo Basin and demonstrates the effectiveness of an infield identification of methane emissions using the Picarro G2201-i.
- Full Text:
- Date Issued: 2019
- Authors: Campbell, Richard Duncombe
- Date: 2019
- Subjects: Methane -- Environmental aspects -- South Africa , Atmospheric methane -- Environmental aspects -- South Africa , Groundwater -- Research
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/42218 , vital:36636
- Description: Currently, only sparse data exists on the methane emissions from the Main Karoo Basin, South Africa, where the potential discovery of vast quantities of unconventional natural gas from the black shales of the Whitehill Formation has sparked great interest in the prospect of hydraulic fracturing. In this study, a new infield methane quantification instrument (Picarro G2201-i) is used to identify freely emitted methane and more importantly collect stable carbon isotope ratios (δ13C-(CH4)g) that is used in obtaining information regarding the genetic origin and thermal maturity of the methane. Hydrochemical information (TOC, δ13C-TOC, 3H, δ18O, δ2H, and anions) were also scrutinised to assist in the determination of the origin of methane across the Karoo Basin. Twenty-one sites were investigated across four provinces in the Main Karoo Basin. Six of these sites are thermal springs, three are shallow boreholes (<100 m in depth), and twelve were Soekor (The Southern Oil Exploration Corporation)/deep boreholes (>1500 m). Of these 21 sites, 17 were suitable for either methane analysis or groundwater sampling, with four of the Soekor boreholes unsuitable. The presence of methane in groundwater and being freely emitted seems to be a common occurrence above the Main Karoo basin and of the 17 sites investigated, 14 had freely emitted methane emission. All but one of these sites had δ13C-(CH4)g signatures greater than -50 ‰, indicating a thermogenic origin. Combining the results obtained from the Picarro instrument with those compiled by Talma & Esterhuyse (2015), a higher resolution distribution map was created. The δ13C-CH4 signatures show patterning with a decreasing trend from the southern Karoo Basin to the north, which corresponds to the general decrease in thermal maturity of the Ecca shales (Whitehill Formation) northward across the Karoo Basin. The δ13C-(CH4)d results from a case study conducted by Eymold et al. (2018) differ significantly with the data collected in this study that included several of the same sampling locations. This is explained by a two phase partitioning (gas + water) that leads to the thermogenic endmember of methane being released in its free state (analysed by Picarro G2201-i) and microbial methane that is formed in situ remains dissolved in the water (analysed by Eymold et al. 2018). Soekor and deep sites; SA 1/66, KA 1/66, and KWV-1 that have direct pathways for methane migration from the Whitehill are deemed the best proxies to resolve the thermogenic endmember of methane, with δ13C-(CH4)g signatures of -26.32‰, 31.66‰, and -34.57‰, respectively. The hydrochemistry results suggests that that free methane emissions do not necessarily have to be associated with saline Cl- waters, as multiple sites have CH4 emissions with low salinities (Cl < 50 mg/L) and that methane in its free state can migrate to the surface due to buoyancy. The results also indicate that dolerite intrusions act as conduits for upward migration of groundwater from depth, but that the deep groundwater signatures proposed by Murray et al., (2015) are related to their different migration pathways and water-rock interactions rather than being representative of the deep formation waters. Using an initial assessment δ13C-CH4, TOC concentration [TOC] and the tritium (3H) values, where water samples that have 3H ≤ 1 TU, detectable TOC and δ13C-CH4 signatures > -50‰ could indicate hydraulic connectivity between the shallow aquifer and an organic/CH4 rich sedimentary layer, which may or may not be from the Whitehill Formation. However, this method for determining aquifer connectivity requires further investigations in the Karoo Basin context. The results obtained in this study add to the limited isotopic data of methane across the Karoo Basin and demonstrates the effectiveness of an infield identification of methane emissions using the Picarro G2201-i.
- Full Text:
- Date Issued: 2019
Fibre optic network supporting high speed transmission in the square kilometre array, South Africa
- Authors: Rotich, Enoch Kirwa
- Date: 2015
- Subjects: Optical communications , Fiber optics , Telecommunication systems
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/6552 , vital:21109
- Description: This thesis provides in-depth information on the high speed optical transport requirements for the Square Kilometre Array. The stringent data rates as well as timing and synchronization requirements are dealt with respect to the optical fibre technology. Regarding the data transport, we draw a clear comparison between a typical telecommunication access network and a telescope network. Invoking simulations and experiments on the field and laboratory test bed, we successfully implement a suitable telescope network using vertical cavity surface emitting laser (VCSEL) technology. Polarization effects on the KAT-7 telescope network, an operational prototype for the SKA is studied so as to estimate the expected effect in the MeerKAT telescope with transmission distances _ 12 km. The study further relates the obtained values to the expected impact on the distribution of the time and frequency reference in the MeerKAT array. Clock stability depends on the differential group delay (DGD) and polarization stability. On a 10:25 km link that includes the riser cable a DGD of 62:1 fs was attained. This corresponds to a polarization mode dispersion (PMD) coefficient of 19:4 fs=km1=2. This is a low PMD value considering telecommunication network. The PMD value is within the allowed budget in the telescope network. However, this may not be the case at longer baselines extending to over 1000 km as expected in SKA 2. The fibre's deployment contribution to the DGD is measured by comparing the deployed fibre to the undeployed of equal lengths. On the 10:25 km deployed single mode fibre, the maximum and mean DGDs measured were 217:7 fs and 84:8 fs respectively. The undeployed fibre of similar type and equal length, gave a maximum and minimum DGDs of 58:6 fs and 36:3 fs respectively. The deployment is seen to increase the maximum and minimum DGDs by factors of 3.7 and 2.3 respectively. This implies that fibre deployment is very critical in ensuring the birefringence is minimized. Polarization fluctuation recorded a maximum of 180o during the 15 hour real time astronomer use of the antenna. To ascertain the contribution of the riser cable, state of polarization (SOP) of the buried section of the single mode fibre in the link was established. A maximum SOP change of 14o over 15 hour monitoring was measured. From the stability realized on the buried section of the fibre, the change in polarization is contributed by the riser cable. The fluctuation in polarization can cause the phase of a clock signal to drift between the birefringent axes by an equal amount corresponding to DGD. We experimentally demonstrate how polarization stabilization can be attained using the polarization maintaining fibre. We also demonstrate the applicability of VCSEL technology in the SKA unidirectional data flow especially for shorter baselines < 100 km. The VCSEL is a low cost light source with attractive advantages such as low power consumption, high speed capabilities and wavelength tuneability. This work entails the use of traditional amplitude modulation commonly known as non-return-to-zero (NRZ) on-off keying (OOK) because of its simplicity and cost. For the MeerKAT typical distances, we show that even in a worst case scenario, the use of VCSEL on different fibres in MeerKAT distance is achievable. Using the impairment reduction approach, we successfully manage to achieve transmission distance beyond MeerKAT. Several in-line dispersion compensation mechanisms in telecommunication have been successfully employed. The work focused on the use of negative dispersion fibre to mitigate the chromatic dispersion effects in the optical fibre. The inverse dispersion fibre (IDF) is proposed for compensation in the conventional zero dispersion wavelength fibres, G.652 that are used at the third window. Similarly, the chromatic dispersion compensation of non-zero dispersion shifted fibre (NZDSF) is experimentally demonstrated using negative dispersion submarine reduced slope (SRS), G. 655 (-). With dispersion management, we demonstrate how transmissions beyond MeerKAT baselines can be achieved error free. A systematic investigation of the use of distributed Raman amplification to overcome the attenuation losses is provided. High on-off gains of up to 15 dB, 8 dB and 5 dB for bidirectional, forward and backward pumping respectively is achieved on a 25 km Raman optimized NZDSF-Reach fibre. Combined dispersion mitigation technique and low noise distributed Raman amplification, up to about 80 km transmission was achieved on a 4:25 Gbps modulated VCSEL using a single pump. Using bidirectional pumping, more than 100 km of transmission was achieved error free. The high gains enhance the VCSEL transmission distance. We further suggest a novel way of using the Raman pump to distribute the clock signal while amplifying the data signal streaming the astronomical data from the remote placed telescope receivers. In summary, the work presented in this thesis has demonstrated the potential use of VCSEL technology for data collection in the telescope array. We have studied the optical effects and mitigation so as to improve the clock and data transmission. This work is relevant and valuable in providing SKA with VCSELs, an option for extremely high network performance at reasonable costs.
- Full Text:
- Date Issued: 2015
- Authors: Rotich, Enoch Kirwa
- Date: 2015
- Subjects: Optical communications , Fiber optics , Telecommunication systems
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/6552 , vital:21109
- Description: This thesis provides in-depth information on the high speed optical transport requirements for the Square Kilometre Array. The stringent data rates as well as timing and synchronization requirements are dealt with respect to the optical fibre technology. Regarding the data transport, we draw a clear comparison between a typical telecommunication access network and a telescope network. Invoking simulations and experiments on the field and laboratory test bed, we successfully implement a suitable telescope network using vertical cavity surface emitting laser (VCSEL) technology. Polarization effects on the KAT-7 telescope network, an operational prototype for the SKA is studied so as to estimate the expected effect in the MeerKAT telescope with transmission distances _ 12 km. The study further relates the obtained values to the expected impact on the distribution of the time and frequency reference in the MeerKAT array. Clock stability depends on the differential group delay (DGD) and polarization stability. On a 10:25 km link that includes the riser cable a DGD of 62:1 fs was attained. This corresponds to a polarization mode dispersion (PMD) coefficient of 19:4 fs=km1=2. This is a low PMD value considering telecommunication network. The PMD value is within the allowed budget in the telescope network. However, this may not be the case at longer baselines extending to over 1000 km as expected in SKA 2. The fibre's deployment contribution to the DGD is measured by comparing the deployed fibre to the undeployed of equal lengths. On the 10:25 km deployed single mode fibre, the maximum and mean DGDs measured were 217:7 fs and 84:8 fs respectively. The undeployed fibre of similar type and equal length, gave a maximum and minimum DGDs of 58:6 fs and 36:3 fs respectively. The deployment is seen to increase the maximum and minimum DGDs by factors of 3.7 and 2.3 respectively. This implies that fibre deployment is very critical in ensuring the birefringence is minimized. Polarization fluctuation recorded a maximum of 180o during the 15 hour real time astronomer use of the antenna. To ascertain the contribution of the riser cable, state of polarization (SOP) of the buried section of the single mode fibre in the link was established. A maximum SOP change of 14o over 15 hour monitoring was measured. From the stability realized on the buried section of the fibre, the change in polarization is contributed by the riser cable. The fluctuation in polarization can cause the phase of a clock signal to drift between the birefringent axes by an equal amount corresponding to DGD. We experimentally demonstrate how polarization stabilization can be attained using the polarization maintaining fibre. We also demonstrate the applicability of VCSEL technology in the SKA unidirectional data flow especially for shorter baselines < 100 km. The VCSEL is a low cost light source with attractive advantages such as low power consumption, high speed capabilities and wavelength tuneability. This work entails the use of traditional amplitude modulation commonly known as non-return-to-zero (NRZ) on-off keying (OOK) because of its simplicity and cost. For the MeerKAT typical distances, we show that even in a worst case scenario, the use of VCSEL on different fibres in MeerKAT distance is achievable. Using the impairment reduction approach, we successfully manage to achieve transmission distance beyond MeerKAT. Several in-line dispersion compensation mechanisms in telecommunication have been successfully employed. The work focused on the use of negative dispersion fibre to mitigate the chromatic dispersion effects in the optical fibre. The inverse dispersion fibre (IDF) is proposed for compensation in the conventional zero dispersion wavelength fibres, G.652 that are used at the third window. Similarly, the chromatic dispersion compensation of non-zero dispersion shifted fibre (NZDSF) is experimentally demonstrated using negative dispersion submarine reduced slope (SRS), G. 655 (-). With dispersion management, we demonstrate how transmissions beyond MeerKAT baselines can be achieved error free. A systematic investigation of the use of distributed Raman amplification to overcome the attenuation losses is provided. High on-off gains of up to 15 dB, 8 dB and 5 dB for bidirectional, forward and backward pumping respectively is achieved on a 25 km Raman optimized NZDSF-Reach fibre. Combined dispersion mitigation technique and low noise distributed Raman amplification, up to about 80 km transmission was achieved on a 4:25 Gbps modulated VCSEL using a single pump. Using bidirectional pumping, more than 100 km of transmission was achieved error free. The high gains enhance the VCSEL transmission distance. We further suggest a novel way of using the Raman pump to distribute the clock signal while amplifying the data signal streaming the astronomical data from the remote placed telescope receivers. In summary, the work presented in this thesis has demonstrated the potential use of VCSEL technology for data collection in the telescope array. We have studied the optical effects and mitigation so as to improve the clock and data transmission. This work is relevant and valuable in providing SKA with VCSELs, an option for extremely high network performance at reasonable costs.
- Full Text:
- Date Issued: 2015
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