Structural and optical properties of sol-gel derived α-Fe2O3 nanoparticles
- Mathevula, Langutani E, Noto, L L, Mothudi, Bakang M, Chithambo, Makaiko L, Dhlamini, M S
- Authors: Mathevula, Langutani E , Noto, L L , Mothudi, Bakang M , Chithambo, Makaiko L , Dhlamini, M S
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115467 , vital:34145 , DOI: 10.1016/j.jlumin.2017.07.055
- Description: α-Fe2O3 nanoparticles of crystallite size between 3.9 and 9.5 nm were synthesized by a simple sol-gel method using iron (III) nitrate nonahydrate (Fe(NO3)3·9H2O) as a precursor. Polyvinyl alcohol (PVA) was added as a capping agent to avoid agglomeration of the nanoparticles. A single pure phase was obtained when the sample was annealed at 300 °C and 600 °C. The purity was further confirmed with the Fourier Transform Infrared Spectroscopy. The energy band gap of the materials was extrapolated from the Kubelka-Munk relation and it ranges between 1.8 and 2.3 eV. The Photoluminescence of the 3 samples shows a broad emission spectrum centered at about 422 nm when excited by a 336 nm lamp. The emission peaks intensities increased with an increase in the annealing temperature, accept for the 576 nm peak, which was quenched as the temperature increased from 300 °C to 600 °C. The thermoluminescence glow curves were carried out at different heating rates and the samples were exposed to different beta particle doses (82–1315 Gy). The activation energy of the trapped electrons was determined.
- Full Text: false
- Date Issued: 2017
- Authors: Mathevula, Langutani E , Noto, L L , Mothudi, Bakang M , Chithambo, Makaiko L , Dhlamini, M S
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115467 , vital:34145 , DOI: 10.1016/j.jlumin.2017.07.055
- Description: α-Fe2O3 nanoparticles of crystallite size between 3.9 and 9.5 nm were synthesized by a simple sol-gel method using iron (III) nitrate nonahydrate (Fe(NO3)3·9H2O) as a precursor. Polyvinyl alcohol (PVA) was added as a capping agent to avoid agglomeration of the nanoparticles. A single pure phase was obtained when the sample was annealed at 300 °C and 600 °C. The purity was further confirmed with the Fourier Transform Infrared Spectroscopy. The energy band gap of the materials was extrapolated from the Kubelka-Munk relation and it ranges between 1.8 and 2.3 eV. The Photoluminescence of the 3 samples shows a broad emission spectrum centered at about 422 nm when excited by a 336 nm lamp. The emission peaks intensities increased with an increase in the annealing temperature, accept for the 576 nm peak, which was quenched as the temperature increased from 300 °C to 600 °C. The thermoluminescence glow curves were carried out at different heating rates and the samples were exposed to different beta particle doses (82–1315 Gy). The activation energy of the trapped electrons was determined.
- Full Text: false
- Date Issued: 2017
Student-generated content: an approach to harnessing the power of diversity in higher education
- Snowball, Jeanette D, McKenna, Sioux
- Authors: Snowball, Jeanette D , McKenna, Sioux
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/66763 , vital:28991 , ISSN 1470-1294 , https://doi.org/10.1080/13562517.2016.1273205
- Description: Publisher version , Internationally, classes in higher education institutions are becoming larger and more diverse. Support for ‘non-traditional’ students has often taken the form of additional remedial classes offered outside the main curriculum, which has met with limited success. Sociocultural theories of learning argue that the potential clash between the sociocultural context of disciplinary knowledge and the very different home contexts of many non-traditional students needs to be acknowledged. One way to achieve this is to use student-generated content, which allows teachers to bring student experiences and voices into the community of practice and acknowledges the importance of their prior experiences in knowledge production. Building on such sociocultural approaches to teaching and learning, this paper focuses on the use of student-generated podcasts as a means to harness the diversity of student experiences in a large (nearly 600 students) first-year Economics class at a South African University.
- Full Text: false
- Date Issued: 2017
- Authors: Snowball, Jeanette D , McKenna, Sioux
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/66763 , vital:28991 , ISSN 1470-1294 , https://doi.org/10.1080/13562517.2016.1273205
- Description: Publisher version , Internationally, classes in higher education institutions are becoming larger and more diverse. Support for ‘non-traditional’ students has often taken the form of additional remedial classes offered outside the main curriculum, which has met with limited success. Sociocultural theories of learning argue that the potential clash between the sociocultural context of disciplinary knowledge and the very different home contexts of many non-traditional students needs to be acknowledged. One way to achieve this is to use student-generated content, which allows teachers to bring student experiences and voices into the community of practice and acknowledges the importance of their prior experiences in knowledge production. Building on such sociocultural approaches to teaching and learning, this paper focuses on the use of student-generated podcasts as a means to harness the diversity of student experiences in a large (nearly 600 students) first-year Economics class at a South African University.
- Full Text: false
- Date Issued: 2017
Technauriture as a platform to create an inclusive environment for the sharing of research
- Authors: Kaschula, Russell H
- Date: 2017
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/67005 , vital:29016 , http://books.openedition.org/obp/4209
- Description: publisher version , From Introduction: This chapter examines the importance of orality in rural communities using the paradigm of technauriture, which describes how technology, auriture2and literature intersect to transmit educational and other messages within communities. It uses oral literary research that has been conducted in the Eastern Cape region to show how technology can aid the data collection process, and how this technology can return such information to the communities from which it comes. This chapter also explores the process of orality fostered by community meetings, oral histories, oral poetry, beadwork, music and story-telling, and how this culture interacts with the recording process facilitated by modern technology. It will also consider the return of recorded oral material to educational and archival circles. These objectives are pursued using empirical data collected at Tshani near Port St. Johns, an area falling within the Mankosi tribal authority in the Eastern Cape Province of South Africa. They are also considered in relation to the work of oral poet, Bongani Sitole who lived in Mqhekezweni village near Qunu and Mthatha, as well as against the backdrop of research conducted in Keiskammahoek, and at the Broster Beadwork Collection, now housed at Walter Sisulu University in Mthatha.
- Full Text: false
- Date Issued: 2017
- Authors: Kaschula, Russell H
- Date: 2017
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/67005 , vital:29016 , http://books.openedition.org/obp/4209
- Description: publisher version , From Introduction: This chapter examines the importance of orality in rural communities using the paradigm of technauriture, which describes how technology, auriture2and literature intersect to transmit educational and other messages within communities. It uses oral literary research that has been conducted in the Eastern Cape region to show how technology can aid the data collection process, and how this technology can return such information to the communities from which it comes. This chapter also explores the process of orality fostered by community meetings, oral histories, oral poetry, beadwork, music and story-telling, and how this culture interacts with the recording process facilitated by modern technology. It will also consider the return of recorded oral material to educational and archival circles. These objectives are pursued using empirical data collected at Tshani near Port St. Johns, an area falling within the Mankosi tribal authority in the Eastern Cape Province of South Africa. They are also considered in relation to the work of oral poet, Bongani Sitole who lived in Mqhekezweni village near Qunu and Mthatha, as well as against the backdrop of research conducted in Keiskammahoek, and at the Broster Beadwork Collection, now housed at Walter Sisulu University in Mthatha.
- Full Text: false
- Date Issued: 2017
Temperature dependence of optically stimulated luminescence of α-Al2O3: C, Mg
- Kalita, Jitumani M, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115708 , vital:34217 , https://doi.org/10.1016/j.radmeas.2017.08.009
- Description: Thermal assistance and thermal quenching are two independently acting thermodynamic phenomena that simultaneously affect the stimulation of luminescence. We have studied thermal assistance to luminescence optically stimulated from α-Al2O3:C,Mg. Since thermal assistance causes only a minor change in the luminescence intensity, measurements were made after the sample had been pre-exposed to stimulating light to reduce its intensity significantly, that is, in the slow component of its decay curve. The luminescence intensity was monitored as a function of measurement temperature between 30 and 130 °C. The intensity goes through a peak at 60 °C due to competing effects of thermal assistance and thermal quenching. The initial increase of intensity is attributed to dominant thermal assistance whereas the subsequent decrease of intensity is ascribed to dominant thermal quenching. The activation energy for thermal assistance was calculated for the main electron trap of an un-annealed sample as 0.324 ± 0.020 eV and in a sample annealed at 900 °C as 0.416 ± 0.028 eV. Implications of such differences in the value of the activation energy for thermal assistance are considered.
- Full Text: false
- Date Issued: 2017
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115708 , vital:34217 , https://doi.org/10.1016/j.radmeas.2017.08.009
- Description: Thermal assistance and thermal quenching are two independently acting thermodynamic phenomena that simultaneously affect the stimulation of luminescence. We have studied thermal assistance to luminescence optically stimulated from α-Al2O3:C,Mg. Since thermal assistance causes only a minor change in the luminescence intensity, measurements were made after the sample had been pre-exposed to stimulating light to reduce its intensity significantly, that is, in the slow component of its decay curve. The luminescence intensity was monitored as a function of measurement temperature between 30 and 130 °C. The intensity goes through a peak at 60 °C due to competing effects of thermal assistance and thermal quenching. The initial increase of intensity is attributed to dominant thermal assistance whereas the subsequent decrease of intensity is ascribed to dominant thermal quenching. The activation energy for thermal assistance was calculated for the main electron trap of an un-annealed sample as 0.324 ± 0.020 eV and in a sample annealed at 900 °C as 0.416 ± 0.028 eV. Implications of such differences in the value of the activation energy for thermal assistance are considered.
- Full Text: false
- Date Issued: 2017
Temperature-dependence of time-resolved optically stimulated luminescence and composition heterogeneity of synthetic α-Al2O3: C
- Chithambo, Makaiko L, Costin, G
- Authors: Chithambo, Makaiko L , Costin, G
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124172 , vital:35573 , https://doi.org/10.1016/j.jlumin.2016.10.038
- Description: The relationship of pulse-width, lifetime and measurement temperature in describing intensity of time-resolved luminescence optically stimulated at 470 nm from α-Al2O3:C is reported. The change of luminescence intensity with stimulation temperature is discussed in terms of the signal integrated over a complete time-resolved luminescence spectrum or in terms of ratios of the signal emitted either during or after pulsed stimulation to the total signal obtained per spectrum. The temperature-induced change in these parameters depends on whether the pulse-width is less or more than the luminescence lifetime. This is because the lifetime in α-Al2O3:C varies with measurement temperature. We have developed and applied new models to distinguish thermal assistance from different traps and to use this information as an additional means to analyse thermal quenching by using the luminescence intensity integrated from time-resolved spectra. Using a model based on use of the throughput, the activation energy for thermal assistance was determined for the shallow trap as 0.054±0.001 eV and as 0.53±0.03 eV for the main trap. The activation energy for thermal quenching was then evaluated using luminescence yield during the pulse as 1.09±0.01 eV and as 1.12±0.01 eV using the throughput after the pulse. Using the new analytical method based on integrated intensity, the activation energy for thermal quenching was found as 1.00±0.07 eV. These values are self-consistent and show that the methods for analyzing temperature-induced changes in intensity and the attendant thermal effects, such as thermal assistance can be successfully applied. We have also reported a general mathematical model that accounts for the temperature-dependence of time-resolved luminescence from α-Al2O3:C. The luminescence study was complemented by investigation of the phase and composition heterogeneity of the samples.
- Full Text: false
- Date Issued: 2017
- Authors: Chithambo, Makaiko L , Costin, G
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124172 , vital:35573 , https://doi.org/10.1016/j.jlumin.2016.10.038
- Description: The relationship of pulse-width, lifetime and measurement temperature in describing intensity of time-resolved luminescence optically stimulated at 470 nm from α-Al2O3:C is reported. The change of luminescence intensity with stimulation temperature is discussed in terms of the signal integrated over a complete time-resolved luminescence spectrum or in terms of ratios of the signal emitted either during or after pulsed stimulation to the total signal obtained per spectrum. The temperature-induced change in these parameters depends on whether the pulse-width is less or more than the luminescence lifetime. This is because the lifetime in α-Al2O3:C varies with measurement temperature. We have developed and applied new models to distinguish thermal assistance from different traps and to use this information as an additional means to analyse thermal quenching by using the luminescence intensity integrated from time-resolved spectra. Using a model based on use of the throughput, the activation energy for thermal assistance was determined for the shallow trap as 0.054±0.001 eV and as 0.53±0.03 eV for the main trap. The activation energy for thermal quenching was then evaluated using luminescence yield during the pulse as 1.09±0.01 eV and as 1.12±0.01 eV using the throughput after the pulse. Using the new analytical method based on integrated intensity, the activation energy for thermal quenching was found as 1.00±0.07 eV. These values are self-consistent and show that the methods for analyzing temperature-induced changes in intensity and the attendant thermal effects, such as thermal assistance can be successfully applied. We have also reported a general mathematical model that accounts for the temperature-dependence of time-resolved luminescence from α-Al2O3:C. The luminescence study was complemented by investigation of the phase and composition heterogeneity of the samples.
- Full Text: false
- Date Issued: 2017
The Etendeka Igneous Province: magma types and their stratigraphic distribution with implications for the evolution of the Paraná-Etendeka flood basalt province
- Marsh, Julian S, Ewart, A, Milner, Simon C, Duncan, Andrew R, Miller, R McG
- Authors: Marsh, Julian S , Ewart, A , Milner, Simon C , Duncan, Andrew R , Miller, R McG
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/149762 , vital:38882 , https://doi.org/10.1007/s004450000115
- Description: Detailed geochemical and field data for the volcanic sequence and intrusions of the Etendeka Igneous Province are used to construct a stratigraphic framework for petrogenetic interpretation of the evolution of the Etendeka-Paraná continental flood volcanic event. Geochemical and petrographic characterization of over 1,000 analyzed samples allows 8 mafic and 17 silicic magma types to be recognized.
- Full Text: false
- Date Issued: 2017
- Authors: Marsh, Julian S , Ewart, A , Milner, Simon C , Duncan, Andrew R , Miller, R McG
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/149762 , vital:38882 , https://doi.org/10.1007/s004450000115
- Description: Detailed geochemical and field data for the volcanic sequence and intrusions of the Etendeka Igneous Province are used to construct a stratigraphic framework for petrogenetic interpretation of the evolution of the Etendeka-Paraná continental flood volcanic event. Geochemical and petrographic characterization of over 1,000 analyzed samples allows 8 mafic and 17 silicic magma types to be recognized.
- Full Text: false
- Date Issued: 2017
The influence of dose on the kinetic parameters and dosimetric features of the main thermoluminescence glow peak in α-Al2O3: C, Mg
- Kalita, Jitumani M, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119834 , vital:34787 , https://doi.org/10.1016/j.nimb.2016.12.027
- Description: The influence of dose (0.1–100 Gy) on the kinetic parameters and the dosimetric features of the main glow peak of α-Al2O3:C,Mg have been investigated. Thermoluminescence (TL) measured at 1 °C/s shows a very high intensity glow peak at 161 °C and six secondary peaks at 42, 72, 193, 279, 330, 370 °C respectively. Analysis shows that the main peak follows first order kinetics irrespective of the irradiation dose. The activation energy is found to be consistent at 1.37 eV and the frequency factor is of the order of 1014 s−1 for any dose between 0.1 and 100 Gy. Further, the analysis for thermal quenching of the main peak of 0.1 Gy irradiated sample shows that the activation energy for thermal quenching is (0.94 ± 0.04) eV.
- Full Text: false
- Date Issued: 2017
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119834 , vital:34787 , https://doi.org/10.1016/j.nimb.2016.12.027
- Description: The influence of dose (0.1–100 Gy) on the kinetic parameters and the dosimetric features of the main glow peak of α-Al2O3:C,Mg have been investigated. Thermoluminescence (TL) measured at 1 °C/s shows a very high intensity glow peak at 161 °C and six secondary peaks at 42, 72, 193, 279, 330, 370 °C respectively. Analysis shows that the main peak follows first order kinetics irrespective of the irradiation dose. The activation energy is found to be consistent at 1.37 eV and the frequency factor is of the order of 1014 s−1 for any dose between 0.1 and 100 Gy. Further, the analysis for thermal quenching of the main peak of 0.1 Gy irradiated sample shows that the activation energy for thermal quenching is (0.94 ± 0.04) eV.
- Full Text: false
- Date Issued: 2017
The influence of radiation-induced defects on thermoluminescence and optically stimulated luminescence of α-Al2O3: C
- Nyirenda, Angel N, Chithambo, Makaiko L
- Authors: Nyirenda, Angel N , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119818 , vital:34786 , https://doi.org/10.1016/j.nimb.2017.02.077
- Description: It is known that when α-Al2O3:C is exposed to excessive amounts of ionising radiation, defects are induced within its matrix. We report the influence of radiation-induced defects on the thermoluminescence (TL) and optically stimulated luminescence (OSL) measured from α-Al2O3:C after irradiation to 1000 Gy. These radiation-induced defects are thermally unstable in the region 450–650 °C and result in TL peaks in this range when the TL is measured at 1 °C/s. Heating a sample to 700 °C obliterates the radiation-induced defects, that is, the TL peaks corresponding to the radiation induced defects are no longer observed in the subsequent TL measurements when moderate irradiation doses below 10 Gy are used. The charge traps associated with these radiation-induced defects are more stable than the dosimetric trap when the sample is exposed to either sunlight or 470-nm blue light from LEDs. TL glow curves measured following the defect-inducing irradiation produce a dosimetric peak that is broader and positioned at a higher temperature than observed in glow curves obtained before the heavy irradiation. In addition, sample sensitization/desensitization occurs due to the presence of these radiation-induced defects. Furthermore, both the activation energy and the kinetic order of the dosimetric peak evaluated when the radiation-induced defects are present in the sample are significantly lower in value than those obtained when these defects are absent. The radiation-induced defects also affect the shape and total light sum of the OSL signal as well as the position and width of the resultant residual phototransferred thermoluminescence main peak.
- Full Text: false
- Date Issued: 2017
- Authors: Nyirenda, Angel N , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119818 , vital:34786 , https://doi.org/10.1016/j.nimb.2017.02.077
- Description: It is known that when α-Al2O3:C is exposed to excessive amounts of ionising radiation, defects are induced within its matrix. We report the influence of radiation-induced defects on the thermoluminescence (TL) and optically stimulated luminescence (OSL) measured from α-Al2O3:C after irradiation to 1000 Gy. These radiation-induced defects are thermally unstable in the region 450–650 °C and result in TL peaks in this range when the TL is measured at 1 °C/s. Heating a sample to 700 °C obliterates the radiation-induced defects, that is, the TL peaks corresponding to the radiation induced defects are no longer observed in the subsequent TL measurements when moderate irradiation doses below 10 Gy are used. The charge traps associated with these radiation-induced defects are more stable than the dosimetric trap when the sample is exposed to either sunlight or 470-nm blue light from LEDs. TL glow curves measured following the defect-inducing irradiation produce a dosimetric peak that is broader and positioned at a higher temperature than observed in glow curves obtained before the heavy irradiation. In addition, sample sensitization/desensitization occurs due to the presence of these radiation-induced defects. Furthermore, both the activation energy and the kinetic order of the dosimetric peak evaluated when the radiation-induced defects are present in the sample are significantly lower in value than those obtained when these defects are absent. The radiation-induced defects also affect the shape and total light sum of the OSL signal as well as the position and width of the resultant residual phototransferred thermoluminescence main peak.
- Full Text: false
- Date Issued: 2017
The Kenyan banking industry: Challenges and sustainability
- Muriithi, Samuel M, Louw, Lynette
- Authors: Muriithi, Samuel M , Louw, Lynette
- Date: 2017
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/69151 , vital:29433 , https://doi.org/10.1007/978-3-319-41090-6_1
- Description: This first chapter of the book aims to provide an overview of the key factors in knowledge and innovation management processes that are influencing and are influenced by the business environment in Africa. The chapter highlights the problematic of achieving a successful and sustainable business in Africa. It therefore outlines the various study programmes of cutting-edge research within different thematic areas such as innovation; entrepreneurship; education; capacity building; human capital; investment; and banking and finance. Finally, the chapter provides an executive summary of all the chapters included in the book.
- Full Text: false
- Date Issued: 2017
- Authors: Muriithi, Samuel M , Louw, Lynette
- Date: 2017
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/69151 , vital:29433 , https://doi.org/10.1007/978-3-319-41090-6_1
- Description: This first chapter of the book aims to provide an overview of the key factors in knowledge and innovation management processes that are influencing and are influenced by the business environment in Africa. The chapter highlights the problematic of achieving a successful and sustainable business in Africa. It therefore outlines the various study programmes of cutting-edge research within different thematic areas such as innovation; entrepreneurship; education; capacity building; human capital; investment; and banking and finance. Finally, the chapter provides an executive summary of all the chapters included in the book.
- Full Text: false
- Date Issued: 2017
The role of doctoral education in early career academic development
- Frick, Liezel, Albertyn, Ruth, Brodin, Eva, McKenna, Sioux, Claessson, Silwa
- Authors: Frick, Liezel , Albertyn, Ruth , Brodin, Eva , McKenna, Sioux , Claessson, Silwa
- Date: 2017
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/66658 , vital:28978 , ISBN 9781928357216 , https://www.researchgate.net/publication/311427468/download
- Description: The social and economic significance of the doctorate is recognised across the world, as doctoral candidates are considered to be key contributors to the knowledge society by contributing to socio-economic development through innovation (Barnacle 2005; Taylor 2012). Doctoral students – regardless of their discipline – are expected to take part actively in the knowledge creation process at universities, and this is especially important for those who will remain in academia and continue to contribute in this way.1 But knowledge creation is a complex process. Knowledge creation at the doctoral level and beyond requires a comprehensive understanding of relevant knowledge, sound judgment, and the ability to advise with insight. Doctoral learning also includes aspects such as abstract reasoning, the ability to conceptualise, and problem solving. Thus, through the original contribution candidates are expected to create during the doctorate, they are supposed to become experts in their chosen field of study. This process has been described by Evans (2014) as disciplinary acculturation. Various authors (for example Danby & Lee 2012; Lin & Cranton 2005; Manathunga & Goozée 2007) point out that this process of becoming an expert is by no means easy or straightforward. Rather, developing as a scholar is a lifelong process in which moving from a novice to an expert is an essential rite of passage into academic practice (Dreyfus & Dreyfus 1986). Benmore (2014) states that for those pursuing academic careers, it involves coming to know, but also coming to be an academic. Such a process of becoming doctorate implies movement over time, progression, and transformation (Barnacle, 2005).
- Full Text: false
- Date Issued: 2017
- Authors: Frick, Liezel , Albertyn, Ruth , Brodin, Eva , McKenna, Sioux , Claessson, Silwa
- Date: 2017
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/66658 , vital:28978 , ISBN 9781928357216 , https://www.researchgate.net/publication/311427468/download
- Description: The social and economic significance of the doctorate is recognised across the world, as doctoral candidates are considered to be key contributors to the knowledge society by contributing to socio-economic development through innovation (Barnacle 2005; Taylor 2012). Doctoral students – regardless of their discipline – are expected to take part actively in the knowledge creation process at universities, and this is especially important for those who will remain in academia and continue to contribute in this way.1 But knowledge creation is a complex process. Knowledge creation at the doctoral level and beyond requires a comprehensive understanding of relevant knowledge, sound judgment, and the ability to advise with insight. Doctoral learning also includes aspects such as abstract reasoning, the ability to conceptualise, and problem solving. Thus, through the original contribution candidates are expected to create during the doctorate, they are supposed to become experts in their chosen field of study. This process has been described by Evans (2014) as disciplinary acculturation. Various authors (for example Danby & Lee 2012; Lin & Cranton 2005; Manathunga & Goozée 2007) point out that this process of becoming an expert is by no means easy or straightforward. Rather, developing as a scholar is a lifelong process in which moving from a novice to an expert is an essential rite of passage into academic practice (Dreyfus & Dreyfus 1986). Benmore (2014) states that for those pursuing academic careers, it involves coming to know, but also coming to be an academic. Such a process of becoming doctorate implies movement over time, progression, and transformation (Barnacle, 2005).
- Full Text: false
- Date Issued: 2017
Thermally-assisted optically stimulated luminescence from deep electron traps in α-Al2O3: C, Mg
- Kalita, Jitumani M, Chithambo, Makaiko L, Polymeris, G S
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L , Polymeris, G S
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116133 , vital:34322 , https://doi.org/10.1016/j.nimb.2017.04.075
- Description: We report thermally-assisted optically stimulated luminescence (TA-OSL) in α-Al2O3:C,Mg. The OSL was measured at elevated temperatures between 50 and 240 °C from a sample preheated to 500 °C after irradiation to 100 Gy. That OSL could be measured even after the preheating is direct evidence of the existence of deep electron traps in α-Al2O3:C,Mg. The TA-OSL intensity goes through a peak with measurement temperature. The initial increase is ascribed to thermal assistance to optical stimulation whereas the subsequent decrease in intensity is deduced to reflect increasing incidences of non-radiative recombination, that is, thermal quenching. The activation energy for thermal assistance corresponding to a deep electron trap was estimated as 0.667 ± 0.006 eV whereas the activation energy for thermal quenching was calculated as 0.90 ± 0.04 eV. The intensity of the TA-OSL was also found to increase with irradiation dose. The dose response is sublinear from 25 to 150 Gy but saturates with further increase of dose. The TA-OSL dose response has been discussed by considering the competition for charges at the deep traps. This study incidentally shows that TA-OSL can be effectively used in dosimetry involving large doses.
- Full Text: false
- Date Issued: 2017
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L , Polymeris, G S
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116133 , vital:34322 , https://doi.org/10.1016/j.nimb.2017.04.075
- Description: We report thermally-assisted optically stimulated luminescence (TA-OSL) in α-Al2O3:C,Mg. The OSL was measured at elevated temperatures between 50 and 240 °C from a sample preheated to 500 °C after irradiation to 100 Gy. That OSL could be measured even after the preheating is direct evidence of the existence of deep electron traps in α-Al2O3:C,Mg. The TA-OSL intensity goes through a peak with measurement temperature. The initial increase is ascribed to thermal assistance to optical stimulation whereas the subsequent decrease in intensity is deduced to reflect increasing incidences of non-radiative recombination, that is, thermal quenching. The activation energy for thermal assistance corresponding to a deep electron trap was estimated as 0.667 ± 0.006 eV whereas the activation energy for thermal quenching was calculated as 0.90 ± 0.04 eV. The intensity of the TA-OSL was also found to increase with irradiation dose. The dose response is sublinear from 25 to 150 Gy but saturates with further increase of dose. The TA-OSL dose response has been discussed by considering the competition for charges at the deep traps. This study incidentally shows that TA-OSL can be effectively used in dosimetry involving large doses.
- Full Text: false
- Date Issued: 2017
Thermoluminescence of K-Mg-Al-Zn fluorophosphate glass
- Thomas, Sunil, Chithambo, Makaiko L
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124188 , vital:35574 , https://doi.org/10.1016/j.optmat.2016.12.035
- Description: The thermoluminescence of beta irradiated K-Mg-Al-Zn fluorophosphate glass is reported. A glow-curve corresponding to 10 Gy measured at 1 °C/s shows two peaks, a weaker-intensity one at 70 °C and a more prominent one at 235 °C, the subject of this report. The main peak was observed to fade with delay between irradiation and measurement and specifically, by 11% in 15 h. Its dose response is superlinear in the dose range 1–190 Gy although the change was linear for the initial 10 Gy. Regarding kinetic analysis, the activation energy of the higher temperature peak was evaluated as 1.31 eV and that of the lower temperature peak was found as 0.47 eV. It was also noted that the main peak is affected by thermal quenching with an activation energy for thermal quenching equal to 1.37 eV. It is proposed that the mechanism associated with the thermoluminescence in K-Mg-Al-Zn fluorophosphate glass is that electrons trapped by the metal cations are released during heating and then recombine with holes at oxygen sites.
- Full Text: false
- Date Issued: 2017
- Authors: Thomas, Sunil , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124188 , vital:35574 , https://doi.org/10.1016/j.optmat.2016.12.035
- Description: The thermoluminescence of beta irradiated K-Mg-Al-Zn fluorophosphate glass is reported. A glow-curve corresponding to 10 Gy measured at 1 °C/s shows two peaks, a weaker-intensity one at 70 °C and a more prominent one at 235 °C, the subject of this report. The main peak was observed to fade with delay between irradiation and measurement and specifically, by 11% in 15 h. Its dose response is superlinear in the dose range 1–190 Gy although the change was linear for the initial 10 Gy. Regarding kinetic analysis, the activation energy of the higher temperature peak was evaluated as 1.31 eV and that of the lower temperature peak was found as 0.47 eV. It was also noted that the main peak is affected by thermal quenching with an activation energy for thermal quenching equal to 1.37 eV. It is proposed that the mechanism associated with the thermoluminescence in K-Mg-Al-Zn fluorophosphate glass is that electrons trapped by the metal cations are released during heating and then recombine with holes at oxygen sites.
- Full Text: false
- Date Issued: 2017
Thermoluminescence of SrAl2O4: Eu2+, Dy3+: kinetic analysis of a composite-peak
- Chithambo, Makaiko L, Wako, A H, Finch, A A
- Authors: Chithambo, Makaiko L , Wako, A H , Finch, A A
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124157 , vital:35571 , https://doi.org/10.1016/j.radmeas.2016.12.009
- Description: The kinetic analysis of thermoluminescence of beta-irradiated SrAl2O4:Eu2+,Dy3+ is reported. The glow-curve is dominated by an apparently-single peak. It has been demonstrated using a number of tests including partial dynamic-heating, isothermal heating, phosphorescence and, the effect of fading, that the peak and the glow-curve consists of a set of closely-spaced peaks. In view of the peak being complex, its first few components were abstracted and analysed and for comparison, the peak was also analysed assuming it is genuinely single.
- Full Text: false
- Date Issued: 2017
- Authors: Chithambo, Makaiko L , Wako, A H , Finch, A A
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124157 , vital:35571 , https://doi.org/10.1016/j.radmeas.2016.12.009
- Description: The kinetic analysis of thermoluminescence of beta-irradiated SrAl2O4:Eu2+,Dy3+ is reported. The glow-curve is dominated by an apparently-single peak. It has been demonstrated using a number of tests including partial dynamic-heating, isothermal heating, phosphorescence and, the effect of fading, that the peak and the glow-curve consists of a set of closely-spaced peaks. In view of the peak being complex, its first few components were abstracted and analysed and for comparison, the peak was also analysed assuming it is genuinely single.
- Full Text: false
- Date Issued: 2017
Thermoluminescence of the main peak in SrAl2O4: Eu2+, Dy3+: spectral and kinetics features of secondary emission detected in the ultra-violet region
- Authors: Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124197 , vital:35575 , https://doi.org/10.1016/j.radmeas.2016.12.001
- Description: We report the thermoluminescence of SrAl2O4:Eu2+,Dy3+ measured in the ultra-violet region of the spectrum between 300 and 400 nm. Complementary measurements of X-ray excited optical luminescence confirm emission bands of stimulated luminescence in this region. As a further test, optically stimulated luminescence was also measured in this region. The glow curve measured at 1 °C s−1 following irradiation to various doses appears simple and single but is in reality a collection of several components. This was shown by results from the Tm-Tstop method on both ends of the peak, application of thermal cleaning beyond the peak maximum as well as the dependence of the peak on fading. The latter shows that new peaks appear as preceding ones fade. Kinetic analysis of some of the main peaks was carried out giving an activation energy of 0.6 eV. The implication of the results on measurement of phosphorescence, interpretation of dose response and fading is discussed.
- Full Text: false
- Date Issued: 2017
- Authors: Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124197 , vital:35575 , https://doi.org/10.1016/j.radmeas.2016.12.001
- Description: We report the thermoluminescence of SrAl2O4:Eu2+,Dy3+ measured in the ultra-violet region of the spectrum between 300 and 400 nm. Complementary measurements of X-ray excited optical luminescence confirm emission bands of stimulated luminescence in this region. As a further test, optically stimulated luminescence was also measured in this region. The glow curve measured at 1 °C s−1 following irradiation to various doses appears simple and single but is in reality a collection of several components. This was shown by results from the Tm-Tstop method on both ends of the peak, application of thermal cleaning beyond the peak maximum as well as the dependence of the peak on fading. The latter shows that new peaks appear as preceding ones fade. Kinetic analysis of some of the main peaks was carried out giving an activation energy of 0.6 eV. The implication of the results on measurement of phosphorescence, interpretation of dose response and fading is discussed.
- Full Text: false
- Date Issued: 2017
Thermoluminescence of α-Al2O3: C, Mg: kinetic analysis of the main glow peak
- Kalita, Jitumani M, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119844 , vital:34788 , https://doi.org/10.1016/j.jlumin.2016.10.031
- Description: The kinetic analysis of the thermoluminescence of aluminium oxide doped with carbon and co-doped with magnesium (α-Al2O3:C,Mg) is reported. Measurements were made at 1 °C/s following beta irradiation to 1 Gy. The glow curve consists of a dominant peak at a peak-maximum Tm of 161 °C and six secondary peaks of weaker intensity at 42, 72, 193, 279, 330 and 370 °C. Kinetic analysis of the main peak, the subject of this report, was carried out using initial rise, whole glow peak, peak shape, curve fitting and variable heating rate methods. The order of kinetics of the main peak was determined as first order using various methods including the Tm–Tstop technique and the dependence of Tm on irradiation dose. The activation energy of the peak is about ~1.36 eV and the frequency factor of the order of 1014 s−1. The peak area changes with heating rate in a manner that shows that the peak is affected by thermal quenching. The activation energy of thermal quenching was evaluated as 0.99±0.08 eV. A comparison of analytical results from the main peak before and after correction for thermal quenching show that the kinetic parameters of the main peak are not that affected by thermal quenching.
- Full Text: false
- Date Issued: 2017
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119844 , vital:34788 , https://doi.org/10.1016/j.jlumin.2016.10.031
- Description: The kinetic analysis of the thermoluminescence of aluminium oxide doped with carbon and co-doped with magnesium (α-Al2O3:C,Mg) is reported. Measurements were made at 1 °C/s following beta irradiation to 1 Gy. The glow curve consists of a dominant peak at a peak-maximum Tm of 161 °C and six secondary peaks of weaker intensity at 42, 72, 193, 279, 330 and 370 °C. Kinetic analysis of the main peak, the subject of this report, was carried out using initial rise, whole glow peak, peak shape, curve fitting and variable heating rate methods. The order of kinetics of the main peak was determined as first order using various methods including the Tm–Tstop technique and the dependence of Tm on irradiation dose. The activation energy of the peak is about ~1.36 eV and the frequency factor of the order of 1014 s−1. The peak area changes with heating rate in a manner that shows that the peak is affected by thermal quenching. The activation energy of thermal quenching was evaluated as 0.99±0.08 eV. A comparison of analytical results from the main peak before and after correction for thermal quenching show that the kinetic parameters of the main peak are not that affected by thermal quenching.
- Full Text: false
- Date Issued: 2017
Towards a framework for assessing the sustainability of local economic development based on natural resources: honeybush tea in the Eastern Cape Province of South Africa
- Polak, James, Snowball, Jeanette D
- Authors: Polak, James , Snowball, Jeanette D
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/69201 , vital:29445 , https://doi.org/10.1080/13549839.2016.1196348
- Description: Despite the popularity of local economic development (LED) as a job creation and economic growth strategy in South Africa, many LED projects have not proved to be sustainable in the long-run, especially where human systems interact with biological ones. This article examines the relationship between sustainability and LED within the context of the emerging honeybush tea industry in the Eastern Cape. Data were gathered from provincial as well as local government policy documents and reports, and via key informant interviews. The data were analysed using Connelly’s [(2007). Mapping sustainable development as a contested concept. Local Environment, 12 (3), 259–278] three pronged approach to sustainable development as a lens through which to view the local industry. Findings showed that the industry offers many opportunities for development, including job creation in poorer, rural households; sustainable wild harvesting using a permit system; commercial cultivation; potential to develop social capital; potential for community-based LED; and product diversification. However, there are also corresponding challenges: There is currently no reliable data on the maximum sustainable yield, which is needed to guide quota allocations for entrepreneurial harvesters harvesting from wild stocks; possible biodiversity loss; and enforcing the permit scheme is proving difficult in remote rural areas.
- Full Text: false
- Date Issued: 2017
- Authors: Polak, James , Snowball, Jeanette D
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/69201 , vital:29445 , https://doi.org/10.1080/13549839.2016.1196348
- Description: Despite the popularity of local economic development (LED) as a job creation and economic growth strategy in South Africa, many LED projects have not proved to be sustainable in the long-run, especially where human systems interact with biological ones. This article examines the relationship between sustainability and LED within the context of the emerging honeybush tea industry in the Eastern Cape. Data were gathered from provincial as well as local government policy documents and reports, and via key informant interviews. The data were analysed using Connelly’s [(2007). Mapping sustainable development as a contested concept. Local Environment, 12 (3), 259–278] three pronged approach to sustainable development as a lens through which to view the local industry. Findings showed that the industry offers many opportunities for development, including job creation in poorer, rural households; sustainable wild harvesting using a permit system; commercial cultivation; potential to develop social capital; potential for community-based LED; and product diversification. However, there are also corresponding challenges: There is currently no reliable data on the maximum sustainable yield, which is needed to guide quota allocations for entrepreneurial harvesters harvesting from wild stocks; possible biodiversity loss; and enforcing the permit scheme is proving difficult in remote rural areas.
- Full Text: false
- Date Issued: 2017
Unexpected transformations of 3-(bromoacetyl)coumarin provides new evidence for the mechanism of thiol mediated dehalogenation of α-halocarbonyls
- Magwenzi, Faith N, Khanye, Setshaba D, Veale, Clinton G L
- Authors: Magwenzi, Faith N , Khanye, Setshaba D , Veale, Clinton G L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/66200 , vital:28916 , https://doi.org/10.1016/j.tetlet.2017.01.082
- Description: publisher version , The mechanism for the thiol mediated dehalogenation of α-halogenated carbonyls has remained an unresolved problem, despite its ongoing application in synthetic organic chemistry. Nakamura and co-workers first proposed that net dehalogenation occurs via sequential nucleophilic substitutions, while Israel and co-workers concluded that the rate at which dehalogenation occurred suggested that dehalogenation proceeds in a single concerted step. In this study, we investigated the debromination and nucleophilic substitution of 3-(bromoacetyl)coumarin with a variety of thiophenols, whose electron donating or withdrawing natures resulted in large variations in the degree of nucleophilic substitution and dehalogenation products, respectively. Results from these experiments, in addition to an unexpected formation of thioether containing dibenzo[b,d]pyran-6-ones from a Robinson annulation, has provided new evidence for this disputed mechanism.
- Full Text: false
- Date Issued: 2017
- Authors: Magwenzi, Faith N , Khanye, Setshaba D , Veale, Clinton G L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/66200 , vital:28916 , https://doi.org/10.1016/j.tetlet.2017.01.082
- Description: publisher version , The mechanism for the thiol mediated dehalogenation of α-halogenated carbonyls has remained an unresolved problem, despite its ongoing application in synthetic organic chemistry. Nakamura and co-workers first proposed that net dehalogenation occurs via sequential nucleophilic substitutions, while Israel and co-workers concluded that the rate at which dehalogenation occurred suggested that dehalogenation proceeds in a single concerted step. In this study, we investigated the debromination and nucleophilic substitution of 3-(bromoacetyl)coumarin with a variety of thiophenols, whose electron donating or withdrawing natures resulted in large variations in the degree of nucleophilic substitution and dehalogenation products, respectively. Results from these experiments, in addition to an unexpected formation of thioether containing dibenzo[b,d]pyran-6-ones from a Robinson annulation, has provided new evidence for this disputed mechanism.
- Full Text: false
- Date Issued: 2017
Waiting for happiness in Africa
- Moller, Valerie, Roberts, Benjamin J, Tiliouine, Habib, Loschky, Jay
- Authors: Moller, Valerie , Roberts, Benjamin J , Tiliouine, Habib , Loschky, Jay
- Date: 2017
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/67225 , vital:29061 , https://s3.amazonaws.com/sdsn-whr2017/HR17-Ch4_lr.pdf
- Description: publisher version , From Introduction: Are the people in Africa really among the least happy in the world? And if African countries do have a ‘happiness deficit’, what are the prospects of Africa achieving happiness in the near future? These are questions we shall try to address in this chapter. The World Happiness Report (WHR), published since 2012, has found that happiness is less evident in Africa than in other regions of the world. It reports Gallup World Poll (GWP) ratings of happiness, measured on the ‘ladder of life’, a scale of 0 to 10, with 10 indicating greatest happiness. On the map of the Geography of Happiness, published in an earlier World Happiness Report Update 2015, the happiest countries in the world are shaded green, the unhappiest red. Africa stands out as the unhappiest continent, being coloured almost entirely in shades of glaring red (See Fig. 4.1). In 2017, the WHR reports that average ladder scores for over four in five African countries are below the mid-point of the scale (see Fig. 4.2). And only two African countries have made significant gains in happiness over the past decade . There are also considerable inequalities in life evaluations in African countries, and this inequality in happiness has increased over the past years . In this chapter, we shall tentatively seek a number of explanations for the unhappiness on the African continent, which is home to about 16% of the world’s population. It will be no easy task to identify factors that may have shaped perceptions of well-being among the 1.2 billion African people who live in 54 nation states with different historical, cultural, and socio-economic backgrounds. Nonetheless, we shall attempt to describe some of the positive and negative experiences in the lives of people in African countries that likely impact on personal well-being. We shall also try to identify the prospects for change and development that could spell hope for increasing the happiness of African people in future.
- Full Text: false
- Date Issued: 2017
- Authors: Moller, Valerie , Roberts, Benjamin J , Tiliouine, Habib , Loschky, Jay
- Date: 2017
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/67225 , vital:29061 , https://s3.amazonaws.com/sdsn-whr2017/HR17-Ch4_lr.pdf
- Description: publisher version , From Introduction: Are the people in Africa really among the least happy in the world? And if African countries do have a ‘happiness deficit’, what are the prospects of Africa achieving happiness in the near future? These are questions we shall try to address in this chapter. The World Happiness Report (WHR), published since 2012, has found that happiness is less evident in Africa than in other regions of the world. It reports Gallup World Poll (GWP) ratings of happiness, measured on the ‘ladder of life’, a scale of 0 to 10, with 10 indicating greatest happiness. On the map of the Geography of Happiness, published in an earlier World Happiness Report Update 2015, the happiest countries in the world are shaded green, the unhappiest red. Africa stands out as the unhappiest continent, being coloured almost entirely in shades of glaring red (See Fig. 4.1). In 2017, the WHR reports that average ladder scores for over four in five African countries are below the mid-point of the scale (see Fig. 4.2). And only two African countries have made significant gains in happiness over the past decade . There are also considerable inequalities in life evaluations in African countries, and this inequality in happiness has increased over the past years . In this chapter, we shall tentatively seek a number of explanations for the unhappiness on the African continent, which is home to about 16% of the world’s population. It will be no easy task to identify factors that may have shaped perceptions of well-being among the 1.2 billion African people who live in 54 nation states with different historical, cultural, and socio-economic backgrounds. Nonetheless, we shall attempt to describe some of the positive and negative experiences in the lives of people in African countries that likely impact on personal well-being. We shall also try to identify the prospects for change and development that could spell hope for increasing the happiness of African people in future.
- Full Text: false
- Date Issued: 2017
A case study of the opportunities and trade-offs associated with deproclamation of a protected area following a land claim in South Africa
- Krüger, Ruth, Cundill, Georgina, Thondhlana, Gladman
- Authors: Krüger, Ruth , Cundill, Georgina , Thondhlana, Gladman
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67791 , vital:29145 , https://doi.org/10.1080/13549839.2015.1065804
- Description: Publisher version , Reconciling conservation and social justice imperatives is a major challenge facing many postcolonial states worldwide. Where historically disenfranchised communities have laid legal claim to protected areas, the typical resolution has been collaborative management agreements between the state and claimant communities. The real outcomes of such strategies for people and ecosystems have been seriously questioned, although alternative approaches are seldom explored. Here, we reflect on one such alternative that was pursued in a case in South Africa, where the land was handed back to the community and a replacement protected area created. Our objective was to explore the opportunities and trade-offs associated with this approach for communities and conservation agencies alike, and to compare these to typical collaborative management outcomes. Methods included key informant interviews, focus group discussions and household surveys. We find that, surprisingly, this approach created more benefits for the conservation agency than for claimant communities. Indeed, the community experiences bore a striking resemblance to those experienced in collaborative management settings: intra-community conflict, confusion over leadership and serious questions about the boundaries of the “community”. Processes aimed at redressing past injustice in disputes over conservation land, regardless of the approach adopted, must bring with them a strong commitment to building institutional and leadership capacities within communities, and pay serious attention to the ways in which equity and social justice can be fostered after the settlement of a land claim. Settlement agreements are frequently treated as the final step towards social justice, but are in fact just the beginning.
- Full Text: false
- Date Issued: 2016
- Authors: Krüger, Ruth , Cundill, Georgina , Thondhlana, Gladman
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67791 , vital:29145 , https://doi.org/10.1080/13549839.2015.1065804
- Description: Publisher version , Reconciling conservation and social justice imperatives is a major challenge facing many postcolonial states worldwide. Where historically disenfranchised communities have laid legal claim to protected areas, the typical resolution has been collaborative management agreements between the state and claimant communities. The real outcomes of such strategies for people and ecosystems have been seriously questioned, although alternative approaches are seldom explored. Here, we reflect on one such alternative that was pursued in a case in South Africa, where the land was handed back to the community and a replacement protected area created. Our objective was to explore the opportunities and trade-offs associated with this approach for communities and conservation agencies alike, and to compare these to typical collaborative management outcomes. Methods included key informant interviews, focus group discussions and household surveys. We find that, surprisingly, this approach created more benefits for the conservation agency than for claimant communities. Indeed, the community experiences bore a striking resemblance to those experienced in collaborative management settings: intra-community conflict, confusion over leadership and serious questions about the boundaries of the “community”. Processes aimed at redressing past injustice in disputes over conservation land, regardless of the approach adopted, must bring with them a strong commitment to building institutional and leadership capacities within communities, and pay serious attention to the ways in which equity and social justice can be fostered after the settlement of a land claim. Settlement agreements are frequently treated as the final step towards social justice, but are in fact just the beginning.
- Full Text: false
- Date Issued: 2016
A case study on the health risks related to flood disasters in South Africa
- Tandlich, Roman, Ncube, Mbonisi, Khamanga, Sandile M, Zuma, Bongumusa M
- Authors: Tandlich, Roman , Ncube, Mbonisi , Khamanga, Sandile M , Zuma, Bongumusa M
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/75917 , vital:30482 , DOI: 10.20965/jdr.2016.p0732
- Description: Floods occurred in the Ndlambe Local Municipality in South Africa in October 2012. During various stages of the post-disaster recovery, bacterial concentrations were measured in water and soil samples from the flood zone. All drinking water concentrations of E. coli were below 1–3 colony forming units per 100 millilitres (CFUs/100 mL). The flood waters contained between 46500 to more than 100000 CFUs/100 mL of E. coli. {The concentrations of Salmonella spp. in the flood waters varied from 5000 to 250000 CFUs/100 mL. The presumptive Vibrio spp. concentrations in flood waters ranged from 1000 to over 150000 CFUs/100 mL. {The soil concentrations for E. coli ranged from 1 to above 330 colony-forming units per 1 g of soil dry weight (CFUs/g). The soil concentrations of Salmonella spp. varied from below 1 to 22 CFUs/g. The estimated airborne fungal concentrations ranged from 16820 to 28540 colony-forming units per 1 cubic meter. An outbreak of an infectious disease was recorded among the volunteers who assisted with the post-disaster recovery. The likely bacterial causative agents included strains of Aeromonas spp. and Vibrio cholerae. Any human contact with either the contaminated flood waters or of flooded dwellings should only occur, if the individuals in questions are equipped with the full-body personal protective gear. Non-governmental stakeholders performed majority of the post-disaster recovery operations, as the local government could only cover 11% of the required costs. Applying sanitation funds to disaster recovery and increased use of the low-cost flood defence products in high risk areas could provide a solution for the future.
- Full Text: false
- Date Issued: 2016
- Authors: Tandlich, Roman , Ncube, Mbonisi , Khamanga, Sandile M , Zuma, Bongumusa M
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/75917 , vital:30482 , DOI: 10.20965/jdr.2016.p0732
- Description: Floods occurred in the Ndlambe Local Municipality in South Africa in October 2012. During various stages of the post-disaster recovery, bacterial concentrations were measured in water and soil samples from the flood zone. All drinking water concentrations of E. coli were below 1–3 colony forming units per 100 millilitres (CFUs/100 mL). The flood waters contained between 46500 to more than 100000 CFUs/100 mL of E. coli. {The concentrations of Salmonella spp. in the flood waters varied from 5000 to 250000 CFUs/100 mL. The presumptive Vibrio spp. concentrations in flood waters ranged from 1000 to over 150000 CFUs/100 mL. {The soil concentrations for E. coli ranged from 1 to above 330 colony-forming units per 1 g of soil dry weight (CFUs/g). The soil concentrations of Salmonella spp. varied from below 1 to 22 CFUs/g. The estimated airborne fungal concentrations ranged from 16820 to 28540 colony-forming units per 1 cubic meter. An outbreak of an infectious disease was recorded among the volunteers who assisted with the post-disaster recovery. The likely bacterial causative agents included strains of Aeromonas spp. and Vibrio cholerae. Any human contact with either the contaminated flood waters or of flooded dwellings should only occur, if the individuals in questions are equipped with the full-body personal protective gear. Non-governmental stakeholders performed majority of the post-disaster recovery operations, as the local government could only cover 11% of the required costs. Applying sanitation funds to disaster recovery and increased use of the low-cost flood defence products in high risk areas could provide a solution for the future.
- Full Text: false
- Date Issued: 2016