Soil erosion and sediment source dynamics of a catchment in the Eastern Cape province, South Africa: an approach using remote sensing and sediment source fingerprinting techniques
- Authors: Manjoro, Munyaradzi
- Date: 2012
- Subjects: Soil erosion -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10663 , http://hdl.handle.net/10948/d1015038
- Description: This study originated from an evaluation of the performance of a commercially available high concentration point focus concentrator PV system. The effect of module design flaws was studied by using current-voltage (I-V) curves obtained from each module in the array. The position of reverse bias steps revealed the severity of mismatch in a string of series-connected cells. By understanding the effects of the various types of mismatch, power losses and damage to the solar cells resulting from hot spot formation can be minimized and several recommendations for improving the basic performance of similar systems were made. Concern over the extent and type of defect failure of the concentrator photovoltaic (CPV) cells prompted an investigation into the use of a light beam induced current (LBIC) technique to investigate the spatial distribution of defects. An overview of current and developing LBIC techniques revealed that the original standard LBIC techniques have found widespread application, and that far-reaching and important developments of the technique have taken place over the years. These developments are driven by natural progression as well as the availability of newly developed advanced measurement equipment. Several techniques such as Lock-in Thermography and the use of infrared cameras have developed as complementary techniques to advanced LBIC techniques. As an accurate contactless evaluation tool that is able to image spatially distributed defects in cell material, the basis of this method seemed promising for the evaluation of concentrator cells.
- Full Text:
- Date Issued: 2012
- Authors: Manjoro, Munyaradzi
- Date: 2012
- Subjects: Soil erosion -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10663 , http://hdl.handle.net/10948/d1015038
- Description: This study originated from an evaluation of the performance of a commercially available high concentration point focus concentrator PV system. The effect of module design flaws was studied by using current-voltage (I-V) curves obtained from each module in the array. The position of reverse bias steps revealed the severity of mismatch in a string of series-connected cells. By understanding the effects of the various types of mismatch, power losses and damage to the solar cells resulting from hot spot formation can be minimized and several recommendations for improving the basic performance of similar systems were made. Concern over the extent and type of defect failure of the concentrator photovoltaic (CPV) cells prompted an investigation into the use of a light beam induced current (LBIC) technique to investigate the spatial distribution of defects. An overview of current and developing LBIC techniques revealed that the original standard LBIC techniques have found widespread application, and that far-reaching and important developments of the technique have taken place over the years. These developments are driven by natural progression as well as the availability of newly developed advanced measurement equipment. Several techniques such as Lock-in Thermography and the use of infrared cameras have developed as complementary techniques to advanced LBIC techniques. As an accurate contactless evaluation tool that is able to image spatially distributed defects in cell material, the basis of this method seemed promising for the evaluation of concentrator cells.
- Full Text:
- Date Issued: 2012
Surface modifications of InAs: effect of chemical processing on electronic structure and photoluminescent properties
- Eassa, Nahswa Abo Alhassan Eassa
- Authors: Eassa, Nahswa Abo Alhassan Eassa
- Date: 2012
- Subjects: Indium arsenide , Chemical processes , Photoluminescence
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/8714 , vital:26423
- Description: In this thesis, the effects of various chemical treatments on the surface modification of bulk InAs are investigated. The study focuses on the chemical processes that occur upon the exposure of the surface to sulphur-, chlorine- and bromine-containing solutions and oxygen, and the resulting changes to the electronic structure of the surface, as deduced from photoluminescence (PL) measurements, X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES), Raman scattering and scanning electron microscopy (SEM). Three processing treatments were evaluated: i) treatment with sulphur-based solutions (Na2S:9H2O, (NH4)2S + S, [(NH4)2S / (NH4)2SO4] + S); ii) etching in halogen-based solutions (bromine-methanol and HCl: H2O); and iii) thermal oxidation. A significant overall enhancement in PL response was observed after chemical treatment or thermal oxidation, which is associated with a reduction in surface band bending. These changes correlate with the removal of the native oxide, in addition to the formation of well-ordered layers of In-S (or In-As)O as a passivating layer, indicating that electronic passivation occurs at the surface. The passivating effect on sulphide treated surfaces is unstable, however, with an increase in band bending, due to reoxidation, observed over periods of a few days. The lowest re-oxidation rate was observed for ([(NH4)2S / (NH4)2SO4] + S). Etching in HCl:H2O and Br-methanol solutions of appropriate concentrations and for moderate times (1 min) resulted in smooth and defect-free InAs surfaces. Etching completely removed the native oxides from the surface and enhanced the PL response. The adsorption of bromine and chlorine onto the InAs surface led to the formation of As-Brx , In-Brx, As-Clx and In-Clxcompounds (x = 1, 2, 3), as inferred from changes in the In 3d3/2; 5/2 and As 3d core level binding energies. The etch rate was found to decrease because of strong anisotropic effects. The improvements in surface properties were reversed, however, if the concentrations of the etchants increased or the etch time was too long. In the worst cases, pit formation and inverted pyramids with {111} side facets were observed. Surface treatments or thermal oxidisation significantly enhanced the PL intensity relative to that of the as-received samples. This was due to a reduction in the surface state density upon de-oxidation, or in some cases, to the formation of a well ordered oxide layer on the surface. The overall increase in PL intensity after treatment is ascribed to a reduction in band bending near the surface. This allows several welldefined peaks not observed or reported previously for bulk InAs (with a carrier concentration n~2x1016 cm-3), to be studied. A combination of PL and XPS measurements before and after the various treatments was used to identify the chemical nature of the impurities giving rise to bound exciton recombination in InAs (111).
- Full Text:
- Date Issued: 2012
- Authors: Eassa, Nahswa Abo Alhassan Eassa
- Date: 2012
- Subjects: Indium arsenide , Chemical processes , Photoluminescence
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/8714 , vital:26423
- Description: In this thesis, the effects of various chemical treatments on the surface modification of bulk InAs are investigated. The study focuses on the chemical processes that occur upon the exposure of the surface to sulphur-, chlorine- and bromine-containing solutions and oxygen, and the resulting changes to the electronic structure of the surface, as deduced from photoluminescence (PL) measurements, X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES), Raman scattering and scanning electron microscopy (SEM). Three processing treatments were evaluated: i) treatment with sulphur-based solutions (Na2S:9H2O, (NH4)2S + S, [(NH4)2S / (NH4)2SO4] + S); ii) etching in halogen-based solutions (bromine-methanol and HCl: H2O); and iii) thermal oxidation. A significant overall enhancement in PL response was observed after chemical treatment or thermal oxidation, which is associated with a reduction in surface band bending. These changes correlate with the removal of the native oxide, in addition to the formation of well-ordered layers of In-S (or In-As)O as a passivating layer, indicating that electronic passivation occurs at the surface. The passivating effect on sulphide treated surfaces is unstable, however, with an increase in band bending, due to reoxidation, observed over periods of a few days. The lowest re-oxidation rate was observed for ([(NH4)2S / (NH4)2SO4] + S). Etching in HCl:H2O and Br-methanol solutions of appropriate concentrations and for moderate times (1 min) resulted in smooth and defect-free InAs surfaces. Etching completely removed the native oxides from the surface and enhanced the PL response. The adsorption of bromine and chlorine onto the InAs surface led to the formation of As-Brx , In-Brx, As-Clx and In-Clxcompounds (x = 1, 2, 3), as inferred from changes in the In 3d3/2; 5/2 and As 3d core level binding energies. The etch rate was found to decrease because of strong anisotropic effects. The improvements in surface properties were reversed, however, if the concentrations of the etchants increased or the etch time was too long. In the worst cases, pit formation and inverted pyramids with {111} side facets were observed. Surface treatments or thermal oxidisation significantly enhanced the PL intensity relative to that of the as-received samples. This was due to a reduction in the surface state density upon de-oxidation, or in some cases, to the formation of a well ordered oxide layer on the surface. The overall increase in PL intensity after treatment is ascribed to a reduction in band bending near the surface. This allows several welldefined peaks not observed or reported previously for bulk InAs (with a carrier concentration n~2x1016 cm-3), to be studied. A combination of PL and XPS measurements before and after the various treatments was used to identify the chemical nature of the impurities giving rise to bound exciton recombination in InAs (111).
- Full Text:
- Date Issued: 2012
The effects of salinity and inundation on salt marsh plants in the context of climate change
- Authors: Tabot, Pascal Tabi
- Date: 2012
- Subjects: Salt marsh plants -- Climatic factors , Plant ecophysiology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10637 , http://hdl.handle.net/10948/d1019919
- Description: Ecophysiology studies are needed to predict plant responses in relation to climate change. Variations in salinity and inundation are expected to influence the survival and distribution of salt marsh. The following species were chosen to study as they occur in most South African salt marshes and are representative of different tidal ranges; namely Triglochin buchenaui (lower intertidal), Bassia diffusa (upper intertidal succulent) and Limonium linifolium (upper intertidal non-succulent). To simulate climate change conditions as predicted for South Africa, a 3 x 5 controlled experiment of three inundation levels (tidal, submerged and drought) and five salinity levels (0, 8, 18, 35, 45 ppt) was conducted for each species. This resulted in 15 treatments per species. Plant responses were measured over a three month period. Triglochin buchenaui showed significant variation in height (7.57 ± 0.5 to 29 ± 1.55 cm, p < 0.005, DF = 55) with optimum growth at 0 ppt under tidal conditions; leaf area increments and relative growth rates which decreased with increasing salinity under all inundation states. There was almost a cessation of growth under submergence which reduces the plant’s regeneration potential under these conditions. Proline accumulation (1.84 ± 0.23 to 3.36 ± 0.38 mg l-1), response of photosynthetic pigments and electrolyte leakage (8.17 ± 0.80 to 38.36 ± 7.42 percent) were fundamental to osmotic and membrane response regulation. Plants survived in all inundation states at salinity up to 45 ppt, but the optimum range was 0 to 18 ppt, and best water state was the tidal condition. Viable rhizomes were produced under drought conditions. Bassia diffusa (Thunb.) Kuntze plants under submergence died within one month, irrespective of the salinity. Optimum growth occurred in plants of the tidal treatment at 18 ppt, and reduced with increased salinity and drought conditions. Plants in the tidal treatments were more succulent than the drought-treated plants. There was reduced leaf mass and high anthocyanin concentrations in drought-treated plants and these effects increased with salinity. Soil and leaf water potential were positively correlated with anthocyanin concentration in leaves and stems, suggesting anthocyanin accumulated in response to drought and could be an adaptation to lower the plant’s water potential under drought conditions. A shift of anthocyanin from leaves to stems was found in drought-treated plants, and this possibly enables the maximization of photosynthesis in leaves, to complement its role in osmotic balance and photo-protection. Growth of Limonium linifolium showed that the plant was tolerant to a wide range of salinity under both tidal and drought conditions, but was susceptible to complete submergence, with high membrane damage even in tidal-treated plants. Plants died within 2 weeks of complete submergence. Results further indicated that L. linifolium tolerates extreme drought by accumulating large quantities of proline and oxalic acid, which consequently lowers its water potential for uptake of soil water of high salinity. Excess salts were excreted through salt glands. This is an important adaptation for a plant that thrives in a highly variable saline habitat Further investigation of submergence effects on upper intertidal species using B. diffusa showed three key stages in the response. A drop in chlorophyll a+b within 6 hours (4.2 ± 0.2 to 2.4 ± 0.3 mg l-1) with a corresponding increase in carotenoid concentration (0.6 ± 0.1 mg l-1) indicated an immediate response to submergence. Oxalic acid concentration was highest on Day 4 (13.6 mM) as opposed to control levels, indicative of its role in submergence tolerance, thus Day 4 may be the peak of positive acclimation. The third phase was marked by a sharp increase in electrolyte leakage to 47.5 ± 2.6 percent on Day 10, from 9.4 ± 1.4 percent on Day 7, with a corresponding decrease in total dissolved solutes between Days 7 and 10. Results suggest that oxalic acid accumulates under submergence possibly as a stabilizing osmolyte. The threshold for tolerance of the species under submergence is 7 days with membrane damage thereafter. Bassia diffusa would not survive prolonged submergence (> 7 days) but could survive submergence of short duration (< 7 days) through continuous underwater photosynthesis, accumulation of osmolytes such as oxalic acid and carotenoid, and maintenance of relative water content and succulence within control levels. When considered together, results showed that the two upper intertidal species were sensitive to waterlogging and would not survive complete submergence, whereas the lower intertidal species could in addition to its natural range, thrive in conditions typical of the upper intertidal range, namely prolonged dry conditions and high sediment salinity. These results have important implications for the future management of salt marshes under predicted climate change conditions. In permanently open South African estuaries, a landward migration of salt marsh will be possible if coastal squeeze is limited and the rate of landward recruitment is on par with sea level rise. In this case salt marsh species would retain their current zonation while shifting inland. Increased sea storms and saltwater intrusion could lead to high salinity concentration in the sediment and significantly reduce growth of salt-sensitive plants. In estuaries that are temporarily open to the sea, reduced freshwater inflow will result in an increase in mouth closure, high water levels, prolonged submergence, and consequently die back of salt marsh vegetation. On the other hand increased abstraction and drought would result in low water levels and high sediment salinity which would decrease growth and survival of salt marsh. This research has provided new knowledge on the ecophysiology of salt marsh plants which can be used to predict the responses of plants to climate change.
- Full Text:
- Date Issued: 2012
- Authors: Tabot, Pascal Tabi
- Date: 2012
- Subjects: Salt marsh plants -- Climatic factors , Plant ecophysiology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10637 , http://hdl.handle.net/10948/d1019919
- Description: Ecophysiology studies are needed to predict plant responses in relation to climate change. Variations in salinity and inundation are expected to influence the survival and distribution of salt marsh. The following species were chosen to study as they occur in most South African salt marshes and are representative of different tidal ranges; namely Triglochin buchenaui (lower intertidal), Bassia diffusa (upper intertidal succulent) and Limonium linifolium (upper intertidal non-succulent). To simulate climate change conditions as predicted for South Africa, a 3 x 5 controlled experiment of three inundation levels (tidal, submerged and drought) and five salinity levels (0, 8, 18, 35, 45 ppt) was conducted for each species. This resulted in 15 treatments per species. Plant responses were measured over a three month period. Triglochin buchenaui showed significant variation in height (7.57 ± 0.5 to 29 ± 1.55 cm, p < 0.005, DF = 55) with optimum growth at 0 ppt under tidal conditions; leaf area increments and relative growth rates which decreased with increasing salinity under all inundation states. There was almost a cessation of growth under submergence which reduces the plant’s regeneration potential under these conditions. Proline accumulation (1.84 ± 0.23 to 3.36 ± 0.38 mg l-1), response of photosynthetic pigments and electrolyte leakage (8.17 ± 0.80 to 38.36 ± 7.42 percent) were fundamental to osmotic and membrane response regulation. Plants survived in all inundation states at salinity up to 45 ppt, but the optimum range was 0 to 18 ppt, and best water state was the tidal condition. Viable rhizomes were produced under drought conditions. Bassia diffusa (Thunb.) Kuntze plants under submergence died within one month, irrespective of the salinity. Optimum growth occurred in plants of the tidal treatment at 18 ppt, and reduced with increased salinity and drought conditions. Plants in the tidal treatments were more succulent than the drought-treated plants. There was reduced leaf mass and high anthocyanin concentrations in drought-treated plants and these effects increased with salinity. Soil and leaf water potential were positively correlated with anthocyanin concentration in leaves and stems, suggesting anthocyanin accumulated in response to drought and could be an adaptation to lower the plant’s water potential under drought conditions. A shift of anthocyanin from leaves to stems was found in drought-treated plants, and this possibly enables the maximization of photosynthesis in leaves, to complement its role in osmotic balance and photo-protection. Growth of Limonium linifolium showed that the plant was tolerant to a wide range of salinity under both tidal and drought conditions, but was susceptible to complete submergence, with high membrane damage even in tidal-treated plants. Plants died within 2 weeks of complete submergence. Results further indicated that L. linifolium tolerates extreme drought by accumulating large quantities of proline and oxalic acid, which consequently lowers its water potential for uptake of soil water of high salinity. Excess salts were excreted through salt glands. This is an important adaptation for a plant that thrives in a highly variable saline habitat Further investigation of submergence effects on upper intertidal species using B. diffusa showed three key stages in the response. A drop in chlorophyll a+b within 6 hours (4.2 ± 0.2 to 2.4 ± 0.3 mg l-1) with a corresponding increase in carotenoid concentration (0.6 ± 0.1 mg l-1) indicated an immediate response to submergence. Oxalic acid concentration was highest on Day 4 (13.6 mM) as opposed to control levels, indicative of its role in submergence tolerance, thus Day 4 may be the peak of positive acclimation. The third phase was marked by a sharp increase in electrolyte leakage to 47.5 ± 2.6 percent on Day 10, from 9.4 ± 1.4 percent on Day 7, with a corresponding decrease in total dissolved solutes between Days 7 and 10. Results suggest that oxalic acid accumulates under submergence possibly as a stabilizing osmolyte. The threshold for tolerance of the species under submergence is 7 days with membrane damage thereafter. Bassia diffusa would not survive prolonged submergence (> 7 days) but could survive submergence of short duration (< 7 days) through continuous underwater photosynthesis, accumulation of osmolytes such as oxalic acid and carotenoid, and maintenance of relative water content and succulence within control levels. When considered together, results showed that the two upper intertidal species were sensitive to waterlogging and would not survive complete submergence, whereas the lower intertidal species could in addition to its natural range, thrive in conditions typical of the upper intertidal range, namely prolonged dry conditions and high sediment salinity. These results have important implications for the future management of salt marshes under predicted climate change conditions. In permanently open South African estuaries, a landward migration of salt marsh will be possible if coastal squeeze is limited and the rate of landward recruitment is on par with sea level rise. In this case salt marsh species would retain their current zonation while shifting inland. Increased sea storms and saltwater intrusion could lead to high salinity concentration in the sediment and significantly reduce growth of salt-sensitive plants. In estuaries that are temporarily open to the sea, reduced freshwater inflow will result in an increase in mouth closure, high water levels, prolonged submergence, and consequently die back of salt marsh vegetation. On the other hand increased abstraction and drought would result in low water levels and high sediment salinity which would decrease growth and survival of salt marsh. This research has provided new knowledge on the ecophysiology of salt marsh plants which can be used to predict the responses of plants to climate change.
- Full Text:
- Date Issued: 2012
The further development, optimisation and application of a Yarn Dismantler
- Authors: Fassihi, Ali Akbar
- Date: 2012
- Subjects: Textile industry , Cotton yarn industry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10452 , http://hdl.handle.net/10948/d1016066
- Description: The fibre properties of cotton, which vary widely according to genetic and environmental conditions, determine its price and textile processing performance and product quality. It is therefore hardly surprising that cotton fibre properties are routinely measured for trading and quality control purposes, with a great deal of research having been, and still being, devoted towards developing instruments which enable the various fibre properties to be measured rapidly and accurately. In many cases, it is also necessary to be able to measure properties of cotton fibres when they have already been converted into yarn and fabric form. To do so, the yarn has to be dismantled into its component fibres, preferably without significantly changing the fibre properties. This could only be done by manually untwisting the yarn and carefully extracting the fibres from the untwisted yarn, care being taken not to break or lose any fibres in the process. This is a time consuming, laborious and labour intensive process. In view of this, a „yarn dismantler‟ which could automatically, cost effectively and within acceptable time frames, dismantle a cotton yarn into its constituent fibres, without undue damage or changes to the fibres, was developed and patented. This thesis reports the results of research undertaken to further develop, evaluate and optimize the yarn dismantler into the final prototype, as well as those relating to its practical applications, including tracking changes in fibre properties during miniature and pilot scale processing, up to, and including the yarn stage. Initial research undertaken on the original bench and first prototype models indicated that, although they produced very promising results, certain improvements and modifications were necessary, if the dismantler was to perform in an efficient and operator friendly manner at the required speeds. These included changes in the axial position of the untwisting spindle and the perforated screen of the suction drum, increasing the air suction at the perforated drum, installing a new motor for the untwisting spindle drive, separating the drives to the different parts of the unit in order to control them independently, integrating a more effective steaming unit into the unit etc. It was found that the dismantling rate had to be set to equal about 95 percent of the original twist in the yarn, and that steaming of the dismantled (untwisted) yarn on the perforated drum was necessary in order to eliminate any twist liveliness (residual torque) in the dismantled yarn, and enable it to be handled and tested on the AFIS instrument. When the final prototype Yarn Dismantler was produced, incorporating all the above mentioned improvements, it functioned very well at dismantling speeds of at least 2m/min, enabling the length of yarn required for subsequent AFIS testing to be dismantled within an acceptable time of less than 10 minutes, with excellent reproducibility and repeatability of results, also under commercial conditions. It was found that the AFIS measured length characteristics of fibres from the instrument dismantled yarns compared very well with those of fibres from manually dismantled yarns, differences in fibre length generally being less than 1mm, and it was concluded from these and other evaluation tests, that the yarn dismantler produced fibres without any significant fibre breakage. Some limited tests, carried out on commercially produced carded and combed yarns, indicated that short fibre content and dust and trash levels, as measured by the AFIS on fibres from dismantled yarn, together with the corresponding Uster Statistics, could enable a carded cotton yarn to be distinguished from a combed cotton yarn. Statistical analysis of fibre test results obtained at the different stages during miniature and pilot plant scale processing of various cottons, clearly showed that very significant changes in fibre properties could be caused by certain of the processes. For example, significant fibre breakage occurred during the drafting on the spinning frame, prior to twist insertion. The thesis provides detailed results of changes in various fibre properties, including length, short fibre content, maturity, immature fibre content, seed coat neps and fibrous neps, which occurred from the lint to the final yarn, as well as on the relationship between the properties of the fibres from the dismantled yarn and those from the lint. The results obtained have clearly demonstrated the practical value of the yarn dismantler in enabling yarns to be automatically dismantled into their constituent fibres, which can then be tested by an instrument, such as the AFIS, and the test results related to those of the original lint fibres, thereby opening up many fields of research and practical applications, some of which are captured under „Recommended Further Work‟.
- Full Text:
- Date Issued: 2012
- Authors: Fassihi, Ali Akbar
- Date: 2012
- Subjects: Textile industry , Cotton yarn industry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10452 , http://hdl.handle.net/10948/d1016066
- Description: The fibre properties of cotton, which vary widely according to genetic and environmental conditions, determine its price and textile processing performance and product quality. It is therefore hardly surprising that cotton fibre properties are routinely measured for trading and quality control purposes, with a great deal of research having been, and still being, devoted towards developing instruments which enable the various fibre properties to be measured rapidly and accurately. In many cases, it is also necessary to be able to measure properties of cotton fibres when they have already been converted into yarn and fabric form. To do so, the yarn has to be dismantled into its component fibres, preferably without significantly changing the fibre properties. This could only be done by manually untwisting the yarn and carefully extracting the fibres from the untwisted yarn, care being taken not to break or lose any fibres in the process. This is a time consuming, laborious and labour intensive process. In view of this, a „yarn dismantler‟ which could automatically, cost effectively and within acceptable time frames, dismantle a cotton yarn into its constituent fibres, without undue damage or changes to the fibres, was developed and patented. This thesis reports the results of research undertaken to further develop, evaluate and optimize the yarn dismantler into the final prototype, as well as those relating to its practical applications, including tracking changes in fibre properties during miniature and pilot scale processing, up to, and including the yarn stage. Initial research undertaken on the original bench and first prototype models indicated that, although they produced very promising results, certain improvements and modifications were necessary, if the dismantler was to perform in an efficient and operator friendly manner at the required speeds. These included changes in the axial position of the untwisting spindle and the perforated screen of the suction drum, increasing the air suction at the perforated drum, installing a new motor for the untwisting spindle drive, separating the drives to the different parts of the unit in order to control them independently, integrating a more effective steaming unit into the unit etc. It was found that the dismantling rate had to be set to equal about 95 percent of the original twist in the yarn, and that steaming of the dismantled (untwisted) yarn on the perforated drum was necessary in order to eliminate any twist liveliness (residual torque) in the dismantled yarn, and enable it to be handled and tested on the AFIS instrument. When the final prototype Yarn Dismantler was produced, incorporating all the above mentioned improvements, it functioned very well at dismantling speeds of at least 2m/min, enabling the length of yarn required for subsequent AFIS testing to be dismantled within an acceptable time of less than 10 minutes, with excellent reproducibility and repeatability of results, also under commercial conditions. It was found that the AFIS measured length characteristics of fibres from the instrument dismantled yarns compared very well with those of fibres from manually dismantled yarns, differences in fibre length generally being less than 1mm, and it was concluded from these and other evaluation tests, that the yarn dismantler produced fibres without any significant fibre breakage. Some limited tests, carried out on commercially produced carded and combed yarns, indicated that short fibre content and dust and trash levels, as measured by the AFIS on fibres from dismantled yarn, together with the corresponding Uster Statistics, could enable a carded cotton yarn to be distinguished from a combed cotton yarn. Statistical analysis of fibre test results obtained at the different stages during miniature and pilot plant scale processing of various cottons, clearly showed that very significant changes in fibre properties could be caused by certain of the processes. For example, significant fibre breakage occurred during the drafting on the spinning frame, prior to twist insertion. The thesis provides detailed results of changes in various fibre properties, including length, short fibre content, maturity, immature fibre content, seed coat neps and fibrous neps, which occurred from the lint to the final yarn, as well as on the relationship between the properties of the fibres from the dismantled yarn and those from the lint. The results obtained have clearly demonstrated the practical value of the yarn dismantler in enabling yarns to be automatically dismantled into their constituent fibres, which can then be tested by an instrument, such as the AFIS, and the test results related to those of the original lint fibres, thereby opening up many fields of research and practical applications, some of which are captured under „Recommended Further Work‟.
- Full Text:
- Date Issued: 2012
The past and present limnology of the Soetendalsvlei wetlands, Agulhas coast, South Africa
- Authors: Gordon, Nuette
- Date: 2012
- Subjects: Limnology -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10619 , http://hdl.handle.net/10948/d1009430 , Limnology -- South Africa
- Description: As climatic conditions continue to change globally, there is a need to assess past environmental change in relation to changing water balance, temperature and sea-level. By understanding the extent of past environmental change, and how anthropogenic impacts have affected ecosystems, better and more accurate future predictions of change can be made. Through the use of the sedimentary record within coastal wetlands, geochemical, (organic content and stable isotopes) and biological (diatoms) proxies were utilised to determine; (i) the baseline water quality record for Soetendalsvlei, one of only a few coastal lakes in South Africa, (ii) the effect of agriculture and mouth manipulation of the Heuningnes Estuary on the microalgae ecology and (iii) the link between palaeo-salinity and trophic status on a regional basis between Soetendalsvlei and Groenvlei, situated 320 km apart. Present water quality and phytoplankton biomass and community structure were assessed for Soetendalsvlei and its associated wetlands, Voëlvlei and Waskraalsvlei to determine the current health of these systems and to obtain modern diatom analogues to be used in the palaeolimnological reconstruction of the coastal lake. Diatoms were not dominant during this study period. Chlorophytes and flagellates were the dominant phytoplankton groups throughout the different wetlands. With the exception of Voëlvlei, the wetlands were all in good health, although SRP concentrations were within the eutrophic to hypertrophic range and are cause for concern. In Voëlvlei, phytoplankton biomass was within the eutrophic range with chlorophyll a concentrations ranging between 20 – 400 ug.l-1 Cyanobacteria, a further indicator of eutrophic conditions, were dominant during the warmer summer periods. Rainfall and freshwater inflow had a significant effect on the biomass and composition of the phytoplankton and acted as a resetting mechanism for all the wetlands as water quality conditions improved thereafter. Comparisons of the water quality and phytoplankton community between the upper reaches of the Heuningnes Estuary and Soetendalsvlei, indicated that artificial breaching of the estuary mouth significantly impacted the connectivity between these two systems, with marine intrusion extending into the upper reaches, while freshwater conditions dominate in the coastal lake. Unfortunately for the palaeolimnological study diatom preservation was poor, however, geochemistry and stable isotope analyses did provide adequate evidence of marine transgression (~8000 yr BP and 4000-2000 yr BP) and regression events comparable to other South African sea-level models developed for the east and west coast. High organic matter content (i.e. higher trophic state) and estuarine POC (C4 vegetation) were associated with periods of marine regression, i.e. increased freshwater, whereas marine transgression events were associated with low organic content and marine POC and DOC. This is comparable to studies conducted in Uruguay (South America) where palaeo-salinity was related to trophic status, i.e. increased freshwater input was associated with high nutrients. Comparisons of the palaeo-record with recorded historical occurrences of droughts and floods, also provided a means of assessing the sedimentary record and to infer anthropogenic impacts after 1850 AD. Overall it can be concluded that coastal lakes of both continents in the Southern Hemisphere displayed similar trophic responses to sea-level fluctuations during the Holocene. This adds valuable information to global sea-level change models.
- Full Text:
- Date Issued: 2012
- Authors: Gordon, Nuette
- Date: 2012
- Subjects: Limnology -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10619 , http://hdl.handle.net/10948/d1009430 , Limnology -- South Africa
- Description: As climatic conditions continue to change globally, there is a need to assess past environmental change in relation to changing water balance, temperature and sea-level. By understanding the extent of past environmental change, and how anthropogenic impacts have affected ecosystems, better and more accurate future predictions of change can be made. Through the use of the sedimentary record within coastal wetlands, geochemical, (organic content and stable isotopes) and biological (diatoms) proxies were utilised to determine; (i) the baseline water quality record for Soetendalsvlei, one of only a few coastal lakes in South Africa, (ii) the effect of agriculture and mouth manipulation of the Heuningnes Estuary on the microalgae ecology and (iii) the link between palaeo-salinity and trophic status on a regional basis between Soetendalsvlei and Groenvlei, situated 320 km apart. Present water quality and phytoplankton biomass and community structure were assessed for Soetendalsvlei and its associated wetlands, Voëlvlei and Waskraalsvlei to determine the current health of these systems and to obtain modern diatom analogues to be used in the palaeolimnological reconstruction of the coastal lake. Diatoms were not dominant during this study period. Chlorophytes and flagellates were the dominant phytoplankton groups throughout the different wetlands. With the exception of Voëlvlei, the wetlands were all in good health, although SRP concentrations were within the eutrophic to hypertrophic range and are cause for concern. In Voëlvlei, phytoplankton biomass was within the eutrophic range with chlorophyll a concentrations ranging between 20 – 400 ug.l-1 Cyanobacteria, a further indicator of eutrophic conditions, were dominant during the warmer summer periods. Rainfall and freshwater inflow had a significant effect on the biomass and composition of the phytoplankton and acted as a resetting mechanism for all the wetlands as water quality conditions improved thereafter. Comparisons of the water quality and phytoplankton community between the upper reaches of the Heuningnes Estuary and Soetendalsvlei, indicated that artificial breaching of the estuary mouth significantly impacted the connectivity between these two systems, with marine intrusion extending into the upper reaches, while freshwater conditions dominate in the coastal lake. Unfortunately for the palaeolimnological study diatom preservation was poor, however, geochemistry and stable isotope analyses did provide adequate evidence of marine transgression (~8000 yr BP and 4000-2000 yr BP) and regression events comparable to other South African sea-level models developed for the east and west coast. High organic matter content (i.e. higher trophic state) and estuarine POC (C4 vegetation) were associated with periods of marine regression, i.e. increased freshwater, whereas marine transgression events were associated with low organic content and marine POC and DOC. This is comparable to studies conducted in Uruguay (South America) where palaeo-salinity was related to trophic status, i.e. increased freshwater input was associated with high nutrients. Comparisons of the palaeo-record with recorded historical occurrences of droughts and floods, also provided a means of assessing the sedimentary record and to infer anthropogenic impacts after 1850 AD. Overall it can be concluded that coastal lakes of both continents in the Southern Hemisphere displayed similar trophic responses to sea-level fluctuations during the Holocene. This adds valuable information to global sea-level change models.
- Full Text:
- Date Issued: 2012
Vapour phase dehydrogenation of cyclohexane on microstructured reactors
- Authors: Mpuhlu, Batsho
- Date: 2012
- Subjects: Dehydrogenation , Cyclohexane
- Language: English
- Type: Thesis , Doctoral , DTech (Chemistry)
- Identifier: http://hdl.handle.net/10948/8661 , vital:26418
- Description: The work that is described in this thesis forms part of the research and development projects at InnoVenton: NMMU Institute of Chemical Technology in collaboration with Sasol Technologies. The broader view of the project was testing on the so-called “Small Production Platforms” (SPP’s). In particular the main aim of this study was to investigate the effect of micro-structuring on the heterogeneous catalysed, vapour-phase oxidative dehydrogenation of cyclohexane in the presence of air. Ground work studies were done to provide a proper comparison of the micro-structured reactor with a traditional fixed-bed reactor. These included evaluation of a proper vanadium pyrophosphate catalyst for the reaction, testing of reaction parameters for the oxidative dehydrogenation reaction on a fixed-bed reactor and lastly comparing the performance of the micro-structured reactor to that of the fixed-bed reactor Various vanadium pyrophosphate catalysts that were tested for activity included: bulk (VO)2P2O7, bulk (VO)2P2O7 promoted with Fe, (VO)2P2O7 supported on -Al2O3 and Fe promoted (VO)2P2O7 supported on -Al2O3. These catalysts showed significant differences in TOF, however it was not conclusive from the results whether these differences may be traced to increased activity for dehydrogenation for different catalysts since all reactions were run under conditions of oxygen deficiency. It is, however, clear that Fe promotion significantly increase activity, irrespective of the relative degrees of oxidative dehydrogenation and normal dehydrogenation. The Fe promoted catalyst was further tested for long term stability in-view of using it as the catalyst in the micro-structured reactor. These studies showed the catalyst to have a high degree of stability with minimal structural changes under the reaction conditions used. Various response surface models describing the variation in each of the cyclohexane conversion, cyclohexene selectivity, and benzene selectivity, respectively when changing reaction condition, were derived by means of multiple regression. To obtain some idea of the degree and nature of the normal dehydrogenation reaction, the amount of deficit oxygen was estimated from the measured results for cyclohexane conversion and cyclohexene and benzene selectivities. These estimated values were also modelled as described above. The regression models were used to interpret specific trends in the responses for the oxidative dehydrogenation of cyclohexane and account for the oxygen deficit in the system. The performance of a fixed bed tubular reactor (FBR) and micro-structured sandwich reactor (MSSR) were compared over an Fe promoted vanadium pyrophosphate. Reactor performance was evaluated by varying specific reaction conditions (temperature and space velocity). Subsequently the turn-over frequencies, conversion and selectivities from the two reactors were compared. The conversion achieved in the micro-structured reactor was observed to be significantly higher than that achieved in the fixed-bed reactor at all reaction parameters. This is despite the fact that the total amount of catalyst in the micro-structured reactor is approximately 5 times less than that used in the fixed bed reactor. In addition, the contact time (1/MHSV) in the micro-structured reactor is also significantly shorter than in the fixed-bed reactor.
- Full Text:
- Date Issued: 2012
- Authors: Mpuhlu, Batsho
- Date: 2012
- Subjects: Dehydrogenation , Cyclohexane
- Language: English
- Type: Thesis , Doctoral , DTech (Chemistry)
- Identifier: http://hdl.handle.net/10948/8661 , vital:26418
- Description: The work that is described in this thesis forms part of the research and development projects at InnoVenton: NMMU Institute of Chemical Technology in collaboration with Sasol Technologies. The broader view of the project was testing on the so-called “Small Production Platforms” (SPP’s). In particular the main aim of this study was to investigate the effect of micro-structuring on the heterogeneous catalysed, vapour-phase oxidative dehydrogenation of cyclohexane in the presence of air. Ground work studies were done to provide a proper comparison of the micro-structured reactor with a traditional fixed-bed reactor. These included evaluation of a proper vanadium pyrophosphate catalyst for the reaction, testing of reaction parameters for the oxidative dehydrogenation reaction on a fixed-bed reactor and lastly comparing the performance of the micro-structured reactor to that of the fixed-bed reactor Various vanadium pyrophosphate catalysts that were tested for activity included: bulk (VO)2P2O7, bulk (VO)2P2O7 promoted with Fe, (VO)2P2O7 supported on -Al2O3 and Fe promoted (VO)2P2O7 supported on -Al2O3. These catalysts showed significant differences in TOF, however it was not conclusive from the results whether these differences may be traced to increased activity for dehydrogenation for different catalysts since all reactions were run under conditions of oxygen deficiency. It is, however, clear that Fe promotion significantly increase activity, irrespective of the relative degrees of oxidative dehydrogenation and normal dehydrogenation. The Fe promoted catalyst was further tested for long term stability in-view of using it as the catalyst in the micro-structured reactor. These studies showed the catalyst to have a high degree of stability with minimal structural changes under the reaction conditions used. Various response surface models describing the variation in each of the cyclohexane conversion, cyclohexene selectivity, and benzene selectivity, respectively when changing reaction condition, were derived by means of multiple regression. To obtain some idea of the degree and nature of the normal dehydrogenation reaction, the amount of deficit oxygen was estimated from the measured results for cyclohexane conversion and cyclohexene and benzene selectivities. These estimated values were also modelled as described above. The regression models were used to interpret specific trends in the responses for the oxidative dehydrogenation of cyclohexane and account for the oxygen deficit in the system. The performance of a fixed bed tubular reactor (FBR) and micro-structured sandwich reactor (MSSR) were compared over an Fe promoted vanadium pyrophosphate. Reactor performance was evaluated by varying specific reaction conditions (temperature and space velocity). Subsequently the turn-over frequencies, conversion and selectivities from the two reactors were compared. The conversion achieved in the micro-structured reactor was observed to be significantly higher than that achieved in the fixed-bed reactor at all reaction parameters. This is despite the fact that the total amount of catalyst in the micro-structured reactor is approximately 5 times less than that used in the fixed bed reactor. In addition, the contact time (1/MHSV) in the micro-structured reactor is also significantly shorter than in the fixed-bed reactor.
- Full Text:
- Date Issued: 2012