- Title
- Spatial and seasonal distribution of selected persistent organic pollutants and phenolic derivatives along the course of the Buffalo River in the Eastern Cape Province of South Africa
- Creator
- Yahaya, Abdulrazaq
- Subject
- Organic water pollutants Water -- Purification -- Organic compounds removal
- Date Issued
- 2017
- Date
- 2017
- Type
- Thesis
- Type
- Doctoral
- Type
- PhD
- Identifier
- http://hdl.handle.net/10353/5939
- Identifier
- vital:29448
- Description
- Persistent organic pollutants (POPs) fall under a group of synthetic chemicals known for their persistence in environmental matrices such as soil and water, and are used in industrial, domestic and agricultural applications. Because of their volatility and lipophilicity, POPs can be transported far away from their point sources and bio-accumulate in food and in fatty tissues of humans and animals. In view of their toxicity and carcinogenicity some organic pollutants such as polychlorinated biphenyl (PCBs), organochlorine pesticides (OCPs) and phenolic derivatives (chlorophenol and nitrophenol) have been classified by United State Environmental Protection Agency (USEPA) and World Health Organization (WHO) as priority pollutants. The present work evaluated the distribution patterns of 19 polychlorinated biphenyls congeners, 17 organochlorine pesticides and selected phenolic derivatives (USEPA 11-priority pollutants) in the Buffalo River, in the Eastern Cape Province, South Africa between December 2015 and May 2016. The Liquid-liquid extraction technique was used for PCBs, OCPs and phenolic derivatives in the river water samples. Silica gel and florisil clean up were carried out for PCBs and OCPs samples respectively and analyzed with gas chromatography electron capture detector (GC/ECD). Phenolic compounds were derivatized and analyzed by gas chromatography mass spectrometer (GC/MS). Limits of detection (LOD), limit of quantitation (LOQ) and relative standard deviation (RSD) for the PCBs were 10 to 330 ng/L, 20 to 1,060 ng/L and 1.18 to 14.1 percent respectively. The LOD, LOQ and RSD for the OCPs were from 20 - 60 ng/L, 110 - 530 ng/L and 0.02 - 0.06 percent, while the corresponding values for the phenolic derivatives were 10 to 70 ng/L, 33 to 222 ng/L and 1.99 - 10.86 percent. In summer, the concentrations of PCBs, OCPs and phenolic derivatives ranged from
- Format
- 165 leaves
- Format
- pdf
- Publisher
- University of Fort Hare
- Publisher
- Faculty of Science and Agriculture
- Language
- English
- Rights
- University of Fort Hare
- Hits: 1470
- Visitors: 1378
- Downloads: 149
Collections
UFH Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Spatial and seasonal distribution of selected persistent organic pollutants and phenolic derivatives along the course of the Buffalo River in the Eastern Cape Province of South Africa | 2 MB | Adobe Acrobat PDF | View Details Download |