Electrooxidation of cresols on carbon electrodes modified with phthalocyaninato and octabutoxyphthalocyaninato cobalt (II) complexes
- Grootboom, Natasha, Nyokong, Tebello
- Authors: Grootboom, Natasha , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293207 , vital:57065 , xlink:href="https://doi.org/10.1016/S0003-2670(00)01351-9"
- Description: Glassy carbon electrodes (GCE) modified with cobalt(II) phthalocyanine (CoPc-GCE) and cobalt(II) octabutoxyphthalocyanine (CoOBuPc-GCE) were employed for the electrochemical analysis of ortho-, meta-, and para-cresols. The oxidation potential of p-cresol was shifted towards less positive values to a larger extent, when compared to m- and o-cresols, on CoOBuPc-GCE. However, the GCE was less stable when modified with CoOBuPc than with CoPc. This is explained using the possible differences in the orientation of the adsorbed phthalocyanine molecules on the electrode. Bulk electrolysis of p-cresol at anodic potentials (1.0 V versus Ag|AgCl) on carbon electrodes modified with CoPc resulted in the formation of radicals which coupled to form trimeric products. On unmodified carbon electrodes, coupling of the radicals resulted in dimeric products following bulk electrolysis. The products formed following bulk electrolysis were characterized by liquid chromatography coupled with mass spectrometry.
- Full Text:
- Date Issued: 2001
- Authors: Grootboom, Natasha , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293207 , vital:57065 , xlink:href="https://doi.org/10.1016/S0003-2670(00)01351-9"
- Description: Glassy carbon electrodes (GCE) modified with cobalt(II) phthalocyanine (CoPc-GCE) and cobalt(II) octabutoxyphthalocyanine (CoOBuPc-GCE) were employed for the electrochemical analysis of ortho-, meta-, and para-cresols. The oxidation potential of p-cresol was shifted towards less positive values to a larger extent, when compared to m- and o-cresols, on CoOBuPc-GCE. However, the GCE was less stable when modified with CoOBuPc than with CoPc. This is explained using the possible differences in the orientation of the adsorbed phthalocyanine molecules on the electrode. Bulk electrolysis of p-cresol at anodic potentials (1.0 V versus Ag|AgCl) on carbon electrodes modified with CoPc resulted in the formation of radicals which coupled to form trimeric products. On unmodified carbon electrodes, coupling of the radicals resulted in dimeric products following bulk electrolysis. The products formed following bulk electrolysis were characterized by liquid chromatography coupled with mass spectrometry.
- Full Text:
- Date Issued: 2001
Experiences in porting a virtual reality system to Java
- Authors: Bangay, Shaun D
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433157 , vital:72947 , https://doi.org/10.1145/513867.513875
- Description: Practical experience in porting a large virtual reality system from C/C++ to Java indicates that porting this type of real-time application is both feasible, and has several merits. The ability to transfer objects in space and time allows useful facilities such as distributed agent support and persistence to be added. Reflection and type comparisons allow flexible manipulations of objects of different types at run-time. Native calls and native code compilation reduce or remove the overhead of interpreting code.Problems encountered include difficulty in achieving cross-platform code portability, limitations of the networking libraries in Java, and clumsy coding practices forced by the language.
- Full Text:
- Date Issued: 2001
- Authors: Bangay, Shaun D
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433157 , vital:72947 , https://doi.org/10.1145/513867.513875
- Description: Practical experience in porting a large virtual reality system from C/C++ to Java indicates that porting this type of real-time application is both feasible, and has several merits. The ability to transfer objects in space and time allows useful facilities such as distributed agent support and persistence to be added. Reflection and type comparisons allow flexible manipulations of objects of different types at run-time. Native calls and native code compilation reduce or remove the overhead of interpreting code.Problems encountered include difficulty in achieving cross-platform code portability, limitations of the networking libraries in Java, and clumsy coding practices forced by the language.
- Full Text:
- Date Issued: 2001
Factors Influencing the Entrepreneurial Orientation of Students
- Amos, Trevor L, Louw, L, Baxter, Jeremy
- Authors: Amos, Trevor L , Louw, L , Baxter, Jeremy
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270879 , vital:54488 , xlink:href="https://scialert.net/abstract/?doi=jas.2001.329.334"
- Description: With entrepreneurship being an important catalyst in wealth creation, it is imperative that entrepreneurs be developed. The aim of this exploratory research is to contribute to our understanding of the development of entrepreneurs and to encourage further research in the area. This paper proposes a model of entrepreneurship and tests the influencing factors on this model. Based on the findings of this research, it appears that entrepreneurial activity of family members influences the development of entrepreneurship more than gender, race, age or education. With education being a logical site for the development of entrepreneurship within society, this finding raises more questions than it provides answers, highlighting the need for educators to critically review the educational process if entrepreneurship is to be a realistic outcome.
- Full Text:
- Date Issued: 2001
- Authors: Amos, Trevor L , Louw, L , Baxter, Jeremy
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270879 , vital:54488 , xlink:href="https://scialert.net/abstract/?doi=jas.2001.329.334"
- Description: With entrepreneurship being an important catalyst in wealth creation, it is imperative that entrepreneurs be developed. The aim of this exploratory research is to contribute to our understanding of the development of entrepreneurs and to encourage further research in the area. This paper proposes a model of entrepreneurship and tests the influencing factors on this model. Based on the findings of this research, it appears that entrepreneurial activity of family members influences the development of entrepreneurship more than gender, race, age or education. With education being a logical site for the development of entrepreneurship within society, this finding raises more questions than it provides answers, highlighting the need for educators to critically review the educational process if entrepreneurship is to be a realistic outcome.
- Full Text:
- Date Issued: 2001
Field Trip A1: Karoo dykes, sills and volcanics in the Eastern Cape
- Authors: Marsh, Julian S
- Date: 2001
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144835 , vital:38383
- Description: The Karoo Province (Fig. I I ) is one of the classic Mesozoic continental flood basalt provinces At present erosion levels it comprises numerous eroded remnants of extensive, thick, and largely volcanic sequence and a well-exposed subvolcanic intrusive complex of dykes and sheets.
- Full Text:
- Date Issued: 2001
- Authors: Marsh, Julian S
- Date: 2001
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144835 , vital:38383
- Description: The Karoo Province (Fig. I I ) is one of the classic Mesozoic continental flood basalt provinces At present erosion levels it comprises numerous eroded remnants of extensive, thick, and largely volcanic sequence and a well-exposed subvolcanic intrusive complex of dykes and sheets.
- Full Text:
- Date Issued: 2001
Implementation and applications of the distortion operator
- Authors: Bangay, Shaun D
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433382 , vital:72966 , https://doi.org/10.1145/513867.513872
- Description: The distortion operator transforms 2D images in a manner similar to image warping or morphing, allowing source pixels to be mapped to any destination pixel. This operator can be implemented on current hardware, allowing at least one distortion per frame at interactive frame rates. Potential applications are numerous, but those described include re-mapping images for correct projection onto curved screens, correcting camera distortion from multiple sources simultaneously, and allowing constant time dynamic texturing and lighting of a static scene which is independent of geometric complexity.
- Full Text:
- Date Issued: 2001
- Authors: Bangay, Shaun D
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433382 , vital:72966 , https://doi.org/10.1145/513867.513872
- Description: The distortion operator transforms 2D images in a manner similar to image warping or morphing, allowing source pixels to be mapped to any destination pixel. This operator can be implemented on current hardware, allowing at least one distortion per frame at interactive frame rates. Potential applications are numerous, but those described include re-mapping images for correct projection onto curved screens, correcting camera distortion from multiple sources simultaneously, and allowing constant time dynamic texturing and lighting of a static scene which is independent of geometric complexity.
- Full Text:
- Date Issued: 2001
Influences of food quality and quantity on the male reproductive organs of a seasonally breeding rodent, the pouched mouse (Saccostomus campestris), from a seasonal but unpredictable environment
- Tinney, Gregory M, Bernard, Ric T F, White, Rehema M
- Authors: Tinney, Gregory M , Bernard, Ric T F , White, Rehema M
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/447258 , vital:74600 , https://doi.org/10.1080/15627020.2001.11657110
- Description: Reproduction in the pouched mouse (Saccostomus campestris) is inhibited in winter in the field and this seasonality is not controlled by photoperiod alone. The present study examines the hypothesis that reproduction in the pouched mouse is opportunistic (sensu Bronson 1989) and that the winter inhibition of reproduction is controlled by a reduction in either food quantity or quality. Food restriction (70 % of normal daily food intake) for six weeks, under short day conditions, was associated with a significant decrease in body fat index and mass of the accessory glands, testes and epididymides, while a high-fibre diet resulted in a significant reduction in fat index and masses of both the accessory glands and epididymides. A low-fibre/low-protein diet had no significant effect on either fat index or masses of the reproductive organs. Although the three experimental diets resulted in assimilation of significantly less energy than the controls, they did not inhibit spermatogenesis. We conclude that reproduction in the pouched mouse in the Eastern Cape Province is probably opportunistic and that the winter inhibition of reproduction may be controlled by a reduction in available energy which results from a combination of the lower ambient temperatures of winter and reduced food quantity and/or quality.
- Full Text:
- Date Issued: 2001
- Authors: Tinney, Gregory M , Bernard, Ric T F , White, Rehema M
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/447258 , vital:74600 , https://doi.org/10.1080/15627020.2001.11657110
- Description: Reproduction in the pouched mouse (Saccostomus campestris) is inhibited in winter in the field and this seasonality is not controlled by photoperiod alone. The present study examines the hypothesis that reproduction in the pouched mouse is opportunistic (sensu Bronson 1989) and that the winter inhibition of reproduction is controlled by a reduction in either food quantity or quality. Food restriction (70 % of normal daily food intake) for six weeks, under short day conditions, was associated with a significant decrease in body fat index and mass of the accessory glands, testes and epididymides, while a high-fibre diet resulted in a significant reduction in fat index and masses of both the accessory glands and epididymides. A low-fibre/low-protein diet had no significant effect on either fat index or masses of the reproductive organs. Although the three experimental diets resulted in assimilation of significantly less energy than the controls, they did not inhibit spermatogenesis. We conclude that reproduction in the pouched mouse in the Eastern Cape Province is probably opportunistic and that the winter inhibition of reproduction may be controlled by a reduction in available energy which results from a combination of the lower ambient temperatures of winter and reduced food quantity and/or quality.
- Full Text:
- Date Issued: 2001
Interaction of serotonin and melatonin with sodium, potassium, calcium, lithium and aluminium
- Lack, Barbara, Daya, Santy, Nyokong, Tebello
- Authors: Lack, Barbara , Daya, Santy , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291553 , vital:56886 , xlink:href="https://doi.org/10.1034/j.1600-079x.2001.310202.x"
- Description: In the present study, we investigated the ability of serotonin and melatonin to bind metals that occur naturally in the brain. An electrochemical technique called adsorptive cathodic stripping voltammetry (AdCSV) was employed to study the metal–serotonin or metal–melatonin interactions. The results show that both serotonin and melatonin form stable complexes with lithium and potassium, with serotonin favouring lithium over potassium, and melatonin favouring potassium over lithium. Coordination between either serotonin or melatonin and calcium was not favoured. The stability of the complexes formed between serotonin and the metals decreased with the metals as follows: Li+>K+>Al3+>Na+>Ca2+. The trend for melatonin–metal complexes was K+>Li+>Na+>Al3+>Ca2+. The binding and stable complex formation between both ligands, serotonin and melatonin with lithium, potassium and sodium is of biological importance. The binding of serotonin to lithium could provide an explanation for the therapeutic effects of lithium in depression treatment, whereas the binding of aluminium by melatonin could provide insight into the role of this element in the aetiology of Alzheimer's disease.
- Full Text:
- Date Issued: 2001
- Authors: Lack, Barbara , Daya, Santy , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291553 , vital:56886 , xlink:href="https://doi.org/10.1034/j.1600-079x.2001.310202.x"
- Description: In the present study, we investigated the ability of serotonin and melatonin to bind metals that occur naturally in the brain. An electrochemical technique called adsorptive cathodic stripping voltammetry (AdCSV) was employed to study the metal–serotonin or metal–melatonin interactions. The results show that both serotonin and melatonin form stable complexes with lithium and potassium, with serotonin favouring lithium over potassium, and melatonin favouring potassium over lithium. Coordination between either serotonin or melatonin and calcium was not favoured. The stability of the complexes formed between serotonin and the metals decreased with the metals as follows: Li+>K+>Al3+>Na+>Ca2+. The trend for melatonin–metal complexes was K+>Li+>Na+>Al3+>Ca2+. The binding and stable complex formation between both ligands, serotonin and melatonin with lithium, potassium and sodium is of biological importance. The binding of serotonin to lithium could provide an explanation for the therapeutic effects of lithium in depression treatment, whereas the binding of aluminium by melatonin could provide insight into the role of this element in the aetiology of Alzheimer's disease.
- Full Text:
- Date Issued: 2001
Khoisan revivalism: the claims of Africa’s first indigenous peoples: racism and the media
- Authors: Garman, Anthea
- Date: 2001
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:40222 , https://hdl.handle.net/10520/EJC144705
- Description: An unexpected development in post-apartheid South Africa is the revivalism of Khoisan identity, the truly indigenous of the country whose blood flows through many who now know themselves by different names.
- Full Text:
- Date Issued: 2001
- Authors: Garman, Anthea
- Date: 2001
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:40222 , https://hdl.handle.net/10520/EJC144705
- Description: An unexpected development in post-apartheid South Africa is the revivalism of Khoisan identity, the truly indigenous of the country whose blood flows through many who now know themselves by different names.
- Full Text:
- Date Issued: 2001
Managing regrowth of an indigenous savanna tree species (Terminalia sericea) for fuelwood: The influence of stump dimensions and post-harvest coppice pruning
- Authors: Shackleton, Charlie M
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181672 , vital:43757 , xlink:href="https://doi.org/10.1016/S0961-9534(00)00086-6"
- Description: Most African savannas are subjected to harvesting of wood, especially for fuelwood, charcoal and construction timber. A key attribute of the resilience and productivity of savannas is the ability of damaged trees to regrow from the remaining stump. Survival of the cut stem and growth rate of the resultant coppice shoots is influenced by several factors, including size of the tree, cutting height and the root/shoot ratio after felling. Some of these can be manipulated to maximise subsequent regrowth, but this is little understood for most African savanna species. This study investigated the influence of original tree size, height of cut and post-harvest pruning on regrowth of Terminalia sericea. Regrowth was monitored as the number of coppice shoots, the mean coppice shoot length and the cumulative coppice shoot length per cut stump over four growing seasons. There was a positive relationship between cutting height and number of coppice shoots, but height of cut did not significantly affect mean or cumulative coppice shoot length. Larger stems produced more coppice and had greater mean and cumulative coppice shoot lengths than smaller stems. Post-harvest pruning increased the mean shoot length, but not the cumulative shoot length. After four growing seasons mean shoot length for the single shoot pruning treatment (one shoot left) was 54% greater than for the no prune treatment, whilst the double shoot pruning (two shoots left) was 40% greater. Extrapolated harvest intervals for fuelwood poles were 3–4 years for large stems, 4–5 years for medium-sized stems, and 4–9 years for small stems.
- Full Text:
- Date Issued: 2001
- Authors: Shackleton, Charlie M
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181672 , vital:43757 , xlink:href="https://doi.org/10.1016/S0961-9534(00)00086-6"
- Description: Most African savannas are subjected to harvesting of wood, especially for fuelwood, charcoal and construction timber. A key attribute of the resilience and productivity of savannas is the ability of damaged trees to regrow from the remaining stump. Survival of the cut stem and growth rate of the resultant coppice shoots is influenced by several factors, including size of the tree, cutting height and the root/shoot ratio after felling. Some of these can be manipulated to maximise subsequent regrowth, but this is little understood for most African savanna species. This study investigated the influence of original tree size, height of cut and post-harvest pruning on regrowth of Terminalia sericea. Regrowth was monitored as the number of coppice shoots, the mean coppice shoot length and the cumulative coppice shoot length per cut stump over four growing seasons. There was a positive relationship between cutting height and number of coppice shoots, but height of cut did not significantly affect mean or cumulative coppice shoot length. Larger stems produced more coppice and had greater mean and cumulative coppice shoot lengths than smaller stems. Post-harvest pruning increased the mean shoot length, but not the cumulative shoot length. After four growing seasons mean shoot length for the single shoot pruning treatment (one shoot left) was 54% greater than for the no prune treatment, whilst the double shoot pruning (two shoots left) was 40% greater. Extrapolated harvest intervals for fuelwood poles were 3–4 years for large stems, 4–5 years for medium-sized stems, and 4–9 years for small stems.
- Full Text:
- Date Issued: 2001
Measuring the value of the arts to society: the importance of the value of externalities for lower income and education groups in South Africa
- Snowball, Jeanette D, Antrobus, Geoffrey G
- Authors: Snowball, Jeanette D , Antrobus, Geoffrey G
- Date: 2001
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143134 , vital:38204 , https://doi.org/10.1111/j.1813-6982.2001.tb00034.x
- Description: Governments in many countries have cut their support of the arts on the grounds that it is the pleasure of the higher income, well educated members of society that they are sponsoring. In the 1980's government support of the arts, even in developed countries, fell by 30 per cent (Throsby 1994). While it is true that many studies have found that arts attenders represent the educated, prosperous minority of society (Morrison and West, 1986; Dobson and West, 1990; Hendon 1990), this paper argues that if the social as well as the more traditional economic measures of the value of the arts are considered, it can be shown that many of the positive externalties provided by the arts accrue to lower income and education groups.
- Full Text:
- Date Issued: 2001
- Authors: Snowball, Jeanette D , Antrobus, Geoffrey G
- Date: 2001
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143134 , vital:38204 , https://doi.org/10.1111/j.1813-6982.2001.tb00034.x
- Description: Governments in many countries have cut their support of the arts on the grounds that it is the pleasure of the higher income, well educated members of society that they are sponsoring. In the 1980's government support of the arts, even in developed countries, fell by 30 per cent (Throsby 1994). While it is true that many studies have found that arts attenders represent the educated, prosperous minority of society (Morrison and West, 1986; Dobson and West, 1990; Hendon 1990), this paper argues that if the social as well as the more traditional economic measures of the value of the arts are considered, it can be shown that many of the positive externalties provided by the arts accrue to lower income and education groups.
- Full Text:
- Date Issued: 2001
Parasitism of Plutella xylostella (Lepidoptera, Plutellidae): field and laboratory observations
- Waladde, S M, Leutle, M F, Villet, Martin H
- Authors: Waladde, S M , Leutle, M F , Villet, Martin H
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/442239 , vital:73969 , https://doi.org/10.1080/02571862.2001.10634397
- Description: Investigations carried out at Alice and its rural environs in the Eastern Cape province of South Africa, showed that parasitoids affecting the diamondback moth Plutella xylostella (L.) (Lepidoptera: Plutellidae) were Cotesia plutellae, Apanteles eriophyes, Diadegma sp., Diadromus collaris, Oomyzus sokolowskii and Hokeria sp. Cotesia plutellae was active all year round and accounted for 30–50% parasitism of P. xylostella. Field experiments using three cabbage cultivars, grown under pesticide-free conditions, indicated that C.plutellae achieved rates of parasitism as high as 90–95% for at least eight months of the year. In winter and early spring parasitism by C. plutellae was less than 30% in the field. This level of parasitism coincided with rising pest density resulting in a pest increase in early spring when C. plutellae appeared unable to control the high pest numbers. Towards the latter part of spring and early summer, C. plutellae parasitism and that of the other parasitoids increased. The possibility of using indigenous parasitoids especially C. plutellae in the management of P. xylostella in this area requires further investigation.
- Full Text:
- Date Issued: 2001
- Authors: Waladde, S M , Leutle, M F , Villet, Martin H
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/442239 , vital:73969 , https://doi.org/10.1080/02571862.2001.10634397
- Description: Investigations carried out at Alice and its rural environs in the Eastern Cape province of South Africa, showed that parasitoids affecting the diamondback moth Plutella xylostella (L.) (Lepidoptera: Plutellidae) were Cotesia plutellae, Apanteles eriophyes, Diadegma sp., Diadromus collaris, Oomyzus sokolowskii and Hokeria sp. Cotesia plutellae was active all year round and accounted for 30–50% parasitism of P. xylostella. Field experiments using three cabbage cultivars, grown under pesticide-free conditions, indicated that C.plutellae achieved rates of parasitism as high as 90–95% for at least eight months of the year. In winter and early spring parasitism by C. plutellae was less than 30% in the field. This level of parasitism coincided with rising pest density resulting in a pest increase in early spring when C. plutellae appeared unable to control the high pest numbers. Towards the latter part of spring and early summer, C. plutellae parasitism and that of the other parasitoids increased. The possibility of using indigenous parasitoids especially C. plutellae in the management of P. xylostella in this area requires further investigation.
- Full Text:
- Date Issued: 2001
Photochemical studies of tetra-2, 3-pyridinoporphyrazines
- Seotsanyana-Mokhosi, Itumeleng, Kuznetsova, Nina, Nyokong, Tebello
- Authors: Seotsanyana-Mokhosi, Itumeleng , Kuznetsova, Nina , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291580 , vital:56889 , xlink:href="https://doi.org/10.1016/S1010-6030(01)00427-0"
- Description: Tetra-2,3-pyridinoporphyrazines and the corresponding water-soluble N,N′,N′′,N′′′-tetramethyl-tetra-2,3-pyridinoporphyrazine complexes, containing central metal atoms; M=Ge, Sn, Si and Zn, were synthesized and their photochemical properties were investigated. The reductive quenching of pyridinoporphyrazines excited states, enhanced relative to phthalocyanines, was considered as the first photochemical step of dyes phototransformation in dimethylformamide (DMF) and dimethylsulfoxide (DMSO) solutions under irradiation with visible light. Efficiency of singlet oxygen photosensitization decreases significantly in the row phthalocyanines, unquaternized, quaternized tetra-2,3-pyridinoporphyrazine metallocomplexes.
- Full Text:
- Date Issued: 2001
- Authors: Seotsanyana-Mokhosi, Itumeleng , Kuznetsova, Nina , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291580 , vital:56889 , xlink:href="https://doi.org/10.1016/S1010-6030(01)00427-0"
- Description: Tetra-2,3-pyridinoporphyrazines and the corresponding water-soluble N,N′,N′′,N′′′-tetramethyl-tetra-2,3-pyridinoporphyrazine complexes, containing central metal atoms; M=Ge, Sn, Si and Zn, were synthesized and their photochemical properties were investigated. The reductive quenching of pyridinoporphyrazines excited states, enhanced relative to phthalocyanines, was considered as the first photochemical step of dyes phototransformation in dimethylformamide (DMF) and dimethylsulfoxide (DMSO) solutions under irradiation with visible light. Efficiency of singlet oxygen photosensitization decreases significantly in the row phthalocyanines, unquaternized, quaternized tetra-2,3-pyridinoporphyrazine metallocomplexes.
- Full Text:
- Date Issued: 2001
Population structure of Apis mellifera scutellata (Hymenoptera: Apidae) filling the Uganda gap
- Radloff, Sarah E, Hepburn, H Randall
- Authors: Radloff, Sarah E , Hepburn, H Randall
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/452017 , vital:75095 , https://hdl.handle.net/10520/EJC32956
- Description: Apis mellifera scutellata Lepeletier (Hymenoptera: Apidae) extends from South Africa to Ethiopia but includes local populations of varying morphology. The honeybees of Uganda previously represented an important biogeographical gap in defining the population structure of A. m. scutellata, but have now been resolved by morphometric analyses of worker honeybees analysed with multivariate techniques. Honeybees of lower altitudes (less than 2000 m) formed one distinct morphocluster typical of A. m. scutellata throughout the continent, while those at higher altitudes (less than 2000 m) formed a separate distinct cluster of large, dark bees. The latter occur as an archipelago of mountain ecotypes of A. m. scutellata..
- Full Text:
- Date Issued: 2001
- Authors: Radloff, Sarah E , Hepburn, H Randall
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/452017 , vital:75095 , https://hdl.handle.net/10520/EJC32956
- Description: Apis mellifera scutellata Lepeletier (Hymenoptera: Apidae) extends from South Africa to Ethiopia but includes local populations of varying morphology. The honeybees of Uganda previously represented an important biogeographical gap in defining the population structure of A. m. scutellata, but have now been resolved by morphometric analyses of worker honeybees analysed with multivariate techniques. Honeybees of lower altitudes (less than 2000 m) formed one distinct morphocluster typical of A. m. scutellata throughout the continent, while those at higher altitudes (less than 2000 m) formed a separate distinct cluster of large, dark bees. The latter occur as an archipelago of mountain ecotypes of A. m. scutellata..
- Full Text:
- Date Issued: 2001
Population structure of Apis mellifera scutellata (Hymenoptera: Apidae) filling the Uganda gap
- Radloff, Sarah E, Hepburn, H Randall
- Authors: Radloff, Sarah E , Hepburn, H Randall
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/452021 , vital:75096 , https://hdl.handle.net/10520/EJC32956
- Description: Apis mellifera scutellata Lepeletier (Hymenoptera: Apidae) extends from South Africa to Ethiopia but includes local populations of varying morphology. The honeybees of Uganda previously represented an important biogeographical gap in defining the population structure of A. m. scutellata, but have now been resolved by morphometric analyses of worker honeybees analysed with multivariate techniques. Honeybees of lower altitudes (less than 2000 m) formed one distinct morphocluster typical of A. m. scutellata throughout the continent, while those at higher altitudes (less than 2000 m) formed a separate distinct cluster of large, dark bees. The latter occur as an archipelago of mountain ecotypes of A. m. scutellata..
- Full Text:
- Date Issued: 2001
- Authors: Radloff, Sarah E , Hepburn, H Randall
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/452021 , vital:75096 , https://hdl.handle.net/10520/EJC32956
- Description: Apis mellifera scutellata Lepeletier (Hymenoptera: Apidae) extends from South Africa to Ethiopia but includes local populations of varying morphology. The honeybees of Uganda previously represented an important biogeographical gap in defining the population structure of A. m. scutellata, but have now been resolved by morphometric analyses of worker honeybees analysed with multivariate techniques. Honeybees of lower altitudes (less than 2000 m) formed one distinct morphocluster typical of A. m. scutellata throughout the continent, while those at higher altitudes (less than 2000 m) formed a separate distinct cluster of large, dark bees. The latter occur as an archipelago of mountain ecotypes of A. m. scutellata..
- Full Text:
- Date Issued: 2001
Pseudocloeon cataractae (Crass)(Ephemeroptera: Baetidae): new combination and lectotype designation
- Lugo-Ortis, C R, de Moor, Ferdy C
- Authors: Lugo-Ortis, C R , de Moor, Ferdy C
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/452189 , vital:75110 , https://hdl.handle.net/10520/EJC32950
- Description: Considerable clarification of taxonomic concepts and phylogenetic relationships within small minnow mayflies (Ephemeroptera: Baetidae) has resulted from recent studies involving Afro-tropical genera and species (Lugo-Ortiz and McCafferty 1996a, b, 1997a, b, 1998a-c; Barber-James and McCafferty 1997; McCafferty et al. 1997; Lugo-Ortiz et al. 1999; Lugo-Ortiz et al. 2001).
- Full Text:
- Date Issued: 2001
- Authors: Lugo-Ortis, C R , de Moor, Ferdy C
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/452189 , vital:75110 , https://hdl.handle.net/10520/EJC32950
- Description: Considerable clarification of taxonomic concepts and phylogenetic relationships within small minnow mayflies (Ephemeroptera: Baetidae) has resulted from recent studies involving Afro-tropical genera and species (Lugo-Ortiz and McCafferty 1996a, b, 1997a, b, 1998a-c; Barber-James and McCafferty 1997; McCafferty et al. 1997; Lugo-Ortiz et al. 1999; Lugo-Ortiz et al. 2001).
- Full Text:
- Date Issued: 2001
Rendering Primitives for a Virtual Holodeck
- Morkel, Chantelle, Bangay, Shaun D
- Authors: Morkel, Chantelle , Bangay, Shaun D
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/432795 , vital:72901 , https://www.cs.ru.ac.za/research/groups/vrsig/pastprojects/039virtualholodeck/paper02.pdf
- Description: The main objective of this research is to implement a “Star Trek”-like holodeck in a computer environment. An experiment to create graphical primitives and images solely out of spheres is being conducted. We investigate several approaches of creating primitives using spheres, and then using these primitives to create images. Initial results of this experiment are presented and we conclude that using spheres to create primitives and images is a viable approach to creating realistic-looking three-dimensional (3D) images.
- Full Text:
- Date Issued: 2001
- Authors: Morkel, Chantelle , Bangay, Shaun D
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/432795 , vital:72901 , https://www.cs.ru.ac.za/research/groups/vrsig/pastprojects/039virtualholodeck/paper02.pdf
- Description: The main objective of this research is to implement a “Star Trek”-like holodeck in a computer environment. An experiment to create graphical primitives and images solely out of spheres is being conducted. We investigate several approaches of creating primitives using spheres, and then using these primitives to create images. Initial results of this experiment are presented and we conclude that using spheres to create primitives and images is a viable approach to creating realistic-looking three-dimensional (3D) images.
- Full Text:
- Date Issued: 2001
Silicon octaphenoxyphthalocyanines
- Maree, M David, Kuznetsova, Nina, Nyokong, Tebello
- Authors: Maree, M David , Kuznetsova, Nina , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291591 , vital:56890 , xlink:href="https://doi.org/10.1016/S1010-6030(01)00409-9"
- Description: Photochemical properties of series of axially substituted silicon octaphenoxyphthalocyanines with aryloxy, siloxy, aminoalkoxy, esters of carboxylic acids and sulphonic acid esters residues as axial ligands were studied in dimethylsulfoxide (DMSO) solution. It was found, that under Q-band excitation axial ligands in compounds studied have the propensity to be changed by hydroxyl groups with quantum yields in the range 10−5 to 10−2 depending on the nature of the axial ligand. Axial substituent phototransformation was followed by slow photobleaching of dihydroxysilicon octaphenoxyphthalocyanine (photoproduct) in self-sensitized singlet oxygen mediated oxidation of the macrocycle. Singlet oxygen quantum yields were found to be in the range 0.15–0.20 for majority of the phthalocyanines (Pc) studied.
- Full Text:
- Date Issued: 2001
- Authors: Maree, M David , Kuznetsova, Nina , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291591 , vital:56890 , xlink:href="https://doi.org/10.1016/S1010-6030(01)00409-9"
- Description: Photochemical properties of series of axially substituted silicon octaphenoxyphthalocyanines with aryloxy, siloxy, aminoalkoxy, esters of carboxylic acids and sulphonic acid esters residues as axial ligands were studied in dimethylsulfoxide (DMSO) solution. It was found, that under Q-band excitation axial ligands in compounds studied have the propensity to be changed by hydroxyl groups with quantum yields in the range 10−5 to 10−2 depending on the nature of the axial ligand. Axial substituent phototransformation was followed by slow photobleaching of dihydroxysilicon octaphenoxyphthalocyanine (photoproduct) in self-sensitized singlet oxygen mediated oxidation of the macrocycle. Singlet oxygen quantum yields were found to be in the range 0.15–0.20 for majority of the phthalocyanines (Pc) studied.
- Full Text:
- Date Issued: 2001
Simultaneous voltammetric determination of dopamine and serotonin on carbon paste electrodes modified with iron (II) phthalocyanine complexes
- Oni, Joshua, Nyokong, Tebello
- Authors: Oni, Joshua , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291603 , vital:56891 , xlink:href="https://doi.org/10.1016/S0003-2670(01)00822-4"
- Description: Carbon paste electrodes (CPE) containing iron(II) phthalocyanine (FePc) and iron(II) tetrasulfophthalocyanine ([FeTSPc]4−) were used for the detection of dopamine (DA) and serotonin (5-HT). Both complexes showed catalytic activity towards the detection of DA and 5-HT. The catalytic activities of [FeTSPc]4− and FePc are compared with those of [CoTSPc]4−, [NiTSPc] 4−, CoPc and NiPc complexes and with those of metal(II) tetraaminophthalocyanines (MTAPc, where M=Ni, Co or Fe) complexes. A significant improvement in the reversibility of the DA oxidation couple was observed on [FeTSPc]4− and FePc modified CPE. [FeTSPc]4− and other [MTSPc]4− modified electrodes inhibited the detection of ascorbic acid (AA), a major interferent in the detection of DA. Simultaneous detection of DA and 5-HT on [FeTSPc]4− modified CPE, in the presence of AA, showed that AA does not interfere with the determination of both species. Also no interference between DA and 5-HT was observed.
- Full Text:
- Date Issued: 2001
- Authors: Oni, Joshua , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291603 , vital:56891 , xlink:href="https://doi.org/10.1016/S0003-2670(01)00822-4"
- Description: Carbon paste electrodes (CPE) containing iron(II) phthalocyanine (FePc) and iron(II) tetrasulfophthalocyanine ([FeTSPc]4−) were used for the detection of dopamine (DA) and serotonin (5-HT). Both complexes showed catalytic activity towards the detection of DA and 5-HT. The catalytic activities of [FeTSPc]4− and FePc are compared with those of [CoTSPc]4−, [NiTSPc] 4−, CoPc and NiPc complexes and with those of metal(II) tetraaminophthalocyanines (MTAPc, where M=Ni, Co or Fe) complexes. A significant improvement in the reversibility of the DA oxidation couple was observed on [FeTSPc]4− and FePc modified CPE. [FeTSPc]4− and other [MTSPc]4− modified electrodes inhibited the detection of ascorbic acid (AA), a major interferent in the detection of DA. Simultaneous detection of DA and 5-HT on [FeTSPc]4− modified CPE, in the presence of AA, showed that AA does not interfere with the determination of both species. Also no interference between DA and 5-HT was observed.
- Full Text:
- Date Issued: 2001
Solvent-free axial ligand substitution in octaphenoxyphthalocyaninato silicon complexes using microwave irradiation
- Maree, M David, Nyokong, Tebello
- Authors: Maree, M David , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/304830 , vital:58494 , xlink:href="https://journals.sagepub.com/doi/epdf/10.3184/030823401103168974"
- Description: Several axially substituted octaphenoxy silicon phthalocyanines were prepared by condensation of the complexes used as axial ligands with octaphenoxyphthalocyaninato (dichloro) silicon under microwave irradiation.
- Full Text:
- Date Issued: 2001
- Authors: Maree, M David , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/304830 , vital:58494 , xlink:href="https://journals.sagepub.com/doi/epdf/10.3184/030823401103168974"
- Description: Several axially substituted octaphenoxy silicon phthalocyanines were prepared by condensation of the complexes used as axial ligands with octaphenoxyphthalocyaninato (dichloro) silicon under microwave irradiation.
- Full Text:
- Date Issued: 2001
Spatial aspects of the reproductive and feeding biology of the striped robber, Brycinus lateralis (Pisces: Characidae), in the Okavango Delta, Botswana
- Booth, Anthony J, McKinlay, Bruce W
- Authors: Booth, Anthony J , McKinlay, Bruce W
- Date: 2001
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/127020 , vital:35944 , https://doi.10.1080/15627020.2001.11657111
- Description: The Okavango Delta is a vast inland wetland system situated in northern Botswana. High rainfall is received in early summer in the southern Angolan highlands and throughout the Delta with the flood waters reaching the upper riverine floodplain between March and May where it percolates through to the lower drainage rivers between July and September. Aspects of the reproductive and feeding biology of two allopatric populations of the striped robber, Brycinus lateralis, a small characin species inhabiting the northern riverine floodplain and southern drainage rivers, were investigated. Both populations were similar in the biological aspects studied, with the flood cycle having little influence on the timing of reproduction, sexual maturity and dietary composition. Female fish from both populations matured sexually at 57mmSL, breeding over a protracted period during the warm, summer months. In both populations, the sex ratio was female-dominated at 4.8:1 (riverine floodplain) and 2.2:1 (drainage rivers). The striped robber is an opportunistic micro-carnivore with immature fish feeding predominantly on Daphnia spp. and adults being largely insectivorous.
- Full Text:
- Date Issued: 2001
- Authors: Booth, Anthony J , McKinlay, Bruce W
- Date: 2001
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/127020 , vital:35944 , https://doi.10.1080/15627020.2001.11657111
- Description: The Okavango Delta is a vast inland wetland system situated in northern Botswana. High rainfall is received in early summer in the southern Angolan highlands and throughout the Delta with the flood waters reaching the upper riverine floodplain between March and May where it percolates through to the lower drainage rivers between July and September. Aspects of the reproductive and feeding biology of two allopatric populations of the striped robber, Brycinus lateralis, a small characin species inhabiting the northern riverine floodplain and southern drainage rivers, were investigated. Both populations were similar in the biological aspects studied, with the flood cycle having little influence on the timing of reproduction, sexual maturity and dietary composition. Female fish from both populations matured sexually at 57mmSL, breeding over a protracted period during the warm, summer months. In both populations, the sex ratio was female-dominated at 4.8:1 (riverine floodplain) and 2.2:1 (drainage rivers). The striped robber is an opportunistic micro-carnivore with immature fish feeding predominantly on Daphnia spp. and adults being largely insectivorous.
- Full Text:
- Date Issued: 2001