Educated mother-tongue South African English: A corpus approach
- Adendorff, Ralph, de Klerk, Vivian A, de Vos, Mark, Hunt, Sally, Simango, Ronald, Todd, Louise, Niesler, Thomas
- Authors: Adendorff, Ralph , de Klerk, Vivian A , de Vos, Mark , Hunt, Sally , Simango, Ronald , Todd, Louise , Niesler, Thomas
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124352 , vital:35597 , https://doi.org/10.1080/10228190608566261
- Description: South Africa is anecdotally known for its complex system of speech varieties correlating with variables such as ethnicity, first language, class and education. These intuitions (e.g. Lass 1990) require further investigation, especially in the context of a changing South Africa where language variety plays a key role in identifying social, economic and ethnic group membership. Thus, in this research, the extent to which these variables play a role in variety is explored using a corpus approach (the nature of class and race in the corpus is discussed more fully later in the article). The corpus project, focusing primarily on accent, has been undertaken by members of the Department of English Language and Linguistics at Rhodes University in South Africa, collaborating with staff from the Department of Electrical and Electronic Engineering from Stellenbosch University, South Africa. A corpus (the first of its kind) is being compiled, comprising the speech of educated, white, mother-tongue speakers of South African English (as distinct from Afrikaans English, Indian English, and the second language (L2) varieties of English used by speakers of indigenous African languages), and data collection is well under way. This short article aims to describe the aims of the project, and the methodological approach which underpins it, as well as to highlight some of the more problematic aspects of the research.
- Full Text:
- Date Issued: 2008
- Authors: Adendorff, Ralph , de Klerk, Vivian A , de Vos, Mark , Hunt, Sally , Simango, Ronald , Todd, Louise , Niesler, Thomas
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124352 , vital:35597 , https://doi.org/10.1080/10228190608566261
- Description: South Africa is anecdotally known for its complex system of speech varieties correlating with variables such as ethnicity, first language, class and education. These intuitions (e.g. Lass 1990) require further investigation, especially in the context of a changing South Africa where language variety plays a key role in identifying social, economic and ethnic group membership. Thus, in this research, the extent to which these variables play a role in variety is explored using a corpus approach (the nature of class and race in the corpus is discussed more fully later in the article). The corpus project, focusing primarily on accent, has been undertaken by members of the Department of English Language and Linguistics at Rhodes University in South Africa, collaborating with staff from the Department of Electrical and Electronic Engineering from Stellenbosch University, South Africa. A corpus (the first of its kind) is being compiled, comprising the speech of educated, white, mother-tongue speakers of South African English (as distinct from Afrikaans English, Indian English, and the second language (L2) varieties of English used by speakers of indigenous African languages), and data collection is well under way. This short article aims to describe the aims of the project, and the methodological approach which underpins it, as well as to highlight some of the more problematic aspects of the research.
- Full Text:
- Date Issued: 2008
Education in the wetlands and wetlands in the education: a case of contextualizing primary/basic education in Tanzania
- Authors: Hogan, Alice Rosemary
- Date: 2008
- Subjects: Education -- Tanzania Environmental education -- Tanzania Education, Rural -- Tanzania Education -- Curricula -- Tanzania Community and school -- Tanzania
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1504 , http://hdl.handle.net/10962/d1003386
- Description: This dissertation describes an action research case study carried out at a sub-village school at Nyamakurukuru, Utete, Rufiji District, Tanzania. The study was a fully independent research activity funded and led by a female Irish environmental and community specialist who has fifteen years experience of working in rural Tanzania, five of which were in Rufiji District. The aim of the action research was to engage a community of villagers, teachers, students and district officers in a participatory process to adapt a module of a school curriculum to the local context, and teach it in order to describe one way in which contextualization, using local and indigenous knowledge and active discovery teaching-learning processes, can be done. The major research question, which I wished to answer for one specific case, was: Does integrating local environmental cultural knowledge into formal schooling contribute to curriculum relevance? If so, in what way? This document describes the background and context of the research, the motivation and the theoretical basis for the work, the methodology and methods, and the action research process itself. The results are interpreted and discussed in the light of current theoretical perspectives on education and environmental education. The main findings within the case are that: Contextualization improved relevance of education and thus its quality by: • breaking through traditional frames/barriers between teachers and students, students and elders and community and teachers, • allowing formal education to take place outside of the school, • necessitating a change in pedagogy1 to more learner-centered, discovery methods, • allowing indigenous knowledge to come into the classroom, • stimulating creativity and increased confidence, and • bringing local socio-political environmental issues into the classroom. This study provides a case example of how education processes, when engaging local cultural knowledge, can improve the relevance, and thus an aspect of the quality of teaching and learning in school-community contexts, while providing a conduit for integrating environmental education into the formal school curriculum. It provides insights into the key issue of relevance which currently faces educators of children in wetlands in Tanzania. Recommendations were made for the case studied and may be useful beyond the boundaries of the case: • Give more explicit government policy and strategic support for community involvement in educational content–epistemologies and pedagogies. • Weaken framing (hierarchical power positions) to encourage greater partnership between school, home and community to improve relevance. • Investigate the provision of education beyond schools. • Provide practical teacher and community training on use of learner-centered, discovery and active pedagogies. • Provide teacher and community education on biodiversity and the environment. • Provide relevant reference texts and research data on the ecology, biodiversity, vegetation, hydrology, agriculture, sociology, history and other relevant subjects. • Officially nurture a culture that learning should be enjoyable. • Allow the curriculum freedom, in these times of increasing risk for rural tropical wetland communities, to make the curriculum fit the local issues rather than vice versa. • Nurture critical analysis of the curriculum in local pedagogic discourse i.e., at the local contextualization level of the home, community and school.
- Full Text:
- Date Issued: 2008
- Authors: Hogan, Alice Rosemary
- Date: 2008
- Subjects: Education -- Tanzania Environmental education -- Tanzania Education, Rural -- Tanzania Education -- Curricula -- Tanzania Community and school -- Tanzania
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1504 , http://hdl.handle.net/10962/d1003386
- Description: This dissertation describes an action research case study carried out at a sub-village school at Nyamakurukuru, Utete, Rufiji District, Tanzania. The study was a fully independent research activity funded and led by a female Irish environmental and community specialist who has fifteen years experience of working in rural Tanzania, five of which were in Rufiji District. The aim of the action research was to engage a community of villagers, teachers, students and district officers in a participatory process to adapt a module of a school curriculum to the local context, and teach it in order to describe one way in which contextualization, using local and indigenous knowledge and active discovery teaching-learning processes, can be done. The major research question, which I wished to answer for one specific case, was: Does integrating local environmental cultural knowledge into formal schooling contribute to curriculum relevance? If so, in what way? This document describes the background and context of the research, the motivation and the theoretical basis for the work, the methodology and methods, and the action research process itself. The results are interpreted and discussed in the light of current theoretical perspectives on education and environmental education. The main findings within the case are that: Contextualization improved relevance of education and thus its quality by: • breaking through traditional frames/barriers between teachers and students, students and elders and community and teachers, • allowing formal education to take place outside of the school, • necessitating a change in pedagogy1 to more learner-centered, discovery methods, • allowing indigenous knowledge to come into the classroom, • stimulating creativity and increased confidence, and • bringing local socio-political environmental issues into the classroom. This study provides a case example of how education processes, when engaging local cultural knowledge, can improve the relevance, and thus an aspect of the quality of teaching and learning in school-community contexts, while providing a conduit for integrating environmental education into the formal school curriculum. It provides insights into the key issue of relevance which currently faces educators of children in wetlands in Tanzania. Recommendations were made for the case studied and may be useful beyond the boundaries of the case: • Give more explicit government policy and strategic support for community involvement in educational content–epistemologies and pedagogies. • Weaken framing (hierarchical power positions) to encourage greater partnership between school, home and community to improve relevance. • Investigate the provision of education beyond schools. • Provide practical teacher and community training on use of learner-centered, discovery and active pedagogies. • Provide teacher and community education on biodiversity and the environment. • Provide relevant reference texts and research data on the ecology, biodiversity, vegetation, hydrology, agriculture, sociology, history and other relevant subjects. • Officially nurture a culture that learning should be enjoyable. • Allow the curriculum freedom, in these times of increasing risk for rural tropical wetland communities, to make the curriculum fit the local issues rather than vice versa. • Nurture critical analysis of the curriculum in local pedagogic discourse i.e., at the local contextualization level of the home, community and school.
- Full Text:
- Date Issued: 2008
Educators perceived challenges in dealing with HIV and AIDS orphans and vulnerable children
- Authors: Goba, Linda
- Date: 2008
- Subjects: Children of AIDS patients -- Education -- South Africa , Orphans -- Education -- South Africa , Teachers -- South Africa -- Attitudes
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:9526 , http://hdl.handle.net/10948/963 , Children of AIDS patients -- Education -- South Africa , Orphans -- Education -- South Africa , Teachers -- South Africa -- Attitudes
- Description: The HIV and AIDS pandemic in South Africa has increased the number of orphans and vulnerable children in the school system. Given the prominent role that teachers can play in ensuring that these children receive a quality education so as to maximise their life opportunities, it is important for teachers to be empowered and equipped to enable them to deal with issues surrounding orphans and vulnerable children (OVC) at schools. This study focuses on how teachers are experiencing the impact of HIV and AIDS in schools as a result of having OVC in their classes. The Department of Education has developed training courses to help teachers cope with the impact of HIV and AIDS, but the effectiveness of these programmes has not yet been evaluated. This study aims to establish how teachers who have attended these programmes feel about the assistance rendered to them to deal with OVC related issues. In order to meet this aim, a qualitative enquiry was conducted among a sample of selected teachers from the Eastern Cape. The findings suggest that, while the training has helped to improve the knowledge and attitudes of the teachers, it has not equipped them with the necessary skills to overcome barriers to implement the training programmes at school level. The findings also suggest that there is a need for ongoing support from the Department of Education and the trainers it contracts to ensure that learning from the training is implemented in the schools. Based on the research findings, the study concludes with recommendations that will help teachers to better cope with OVC related issues at school.
- Full Text:
- Date Issued: 2008
- Authors: Goba, Linda
- Date: 2008
- Subjects: Children of AIDS patients -- Education -- South Africa , Orphans -- Education -- South Africa , Teachers -- South Africa -- Attitudes
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:9526 , http://hdl.handle.net/10948/963 , Children of AIDS patients -- Education -- South Africa , Orphans -- Education -- South Africa , Teachers -- South Africa -- Attitudes
- Description: The HIV and AIDS pandemic in South Africa has increased the number of orphans and vulnerable children in the school system. Given the prominent role that teachers can play in ensuring that these children receive a quality education so as to maximise their life opportunities, it is important for teachers to be empowered and equipped to enable them to deal with issues surrounding orphans and vulnerable children (OVC) at schools. This study focuses on how teachers are experiencing the impact of HIV and AIDS in schools as a result of having OVC in their classes. The Department of Education has developed training courses to help teachers cope with the impact of HIV and AIDS, but the effectiveness of these programmes has not yet been evaluated. This study aims to establish how teachers who have attended these programmes feel about the assistance rendered to them to deal with OVC related issues. In order to meet this aim, a qualitative enquiry was conducted among a sample of selected teachers from the Eastern Cape. The findings suggest that, while the training has helped to improve the knowledge and attitudes of the teachers, it has not equipped them with the necessary skills to overcome barriers to implement the training programmes at school level. The findings also suggest that there is a need for ongoing support from the Department of Education and the trainers it contracts to ensure that learning from the training is implemented in the schools. Based on the research findings, the study concludes with recommendations that will help teachers to better cope with OVC related issues at school.
- Full Text:
- Date Issued: 2008
Effect of a South African medicinal plant on antiretroviral drug induced abnormalities in rats
- Authors: Van Gend, Tania Anli
- Date: 2008
- Subjects: Medicinal plants -- South Africa , Antiretroviral agents -- South Africa , Materia medica, Vegetable -- South Africa , HIV infections -- Alternative treatment -- South Africa , Rats as laboratory animals , Rats -- Metabolism
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10121 , http://hdl.handle.net/10948/1080 , Medicinal plants -- South Africa , Antiretroviral agents -- South Africa , Materia medica, Vegetable -- South Africa , HIV infections -- Alternative treatment -- South Africa , Rats as laboratory animals , Rats -- Metabolism
- Description: The worldwide AIDS epidemic is known to have had a profoundly negative social, economic and personal impact and has taken a heavy toll on existing health care systems, particularly in developing countries. South Africa is experiencing an HIV epidemic with enormous social and economic consequences. Lopinavir/ritonavir antiretroviral treatment has been accredited with having a significantly positive effect and is a key advance in controlling HIV morbidity and mortality. An indigenous South African medicinal plant, Sutherlandia frutescens, known for its anti-diabetic properties and immune-boosting effects, is used for treating HIV positive patients suffering from opportunistic infections. Despite the use of the medicinal plant extract as homeotherapeutic medication, there is little evidence of toxicity testing that identifies its potential for interaction with antiretroviral drugs. However, scientific data relating to the mechanism through which Sutherlandia frutescens acts on the immune system has not been comprehensively documented. The aim of this study was to investigate lopinavir/ritonavir induced metabolic abnormalities in rats and whether the introduction of a plant extract of Sutherlandia frutescens would counteract the side effects of ARV medication. The results indicated that the rodents did not become insulin resistant, however, biochemical analysis indicated that extended ARV drug treatment would have caused insulin resistance. Significant morphological changes were found in the livers, kidneys and pancreases of rats exposed to the lopinavir/ritonavir. Rats exposed to the Sutherlandia frutescens plant extract showed improved histopathology with minimal abnormalities.
- Full Text:
- Date Issued: 2008
- Authors: Van Gend, Tania Anli
- Date: 2008
- Subjects: Medicinal plants -- South Africa , Antiretroviral agents -- South Africa , Materia medica, Vegetable -- South Africa , HIV infections -- Alternative treatment -- South Africa , Rats as laboratory animals , Rats -- Metabolism
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10121 , http://hdl.handle.net/10948/1080 , Medicinal plants -- South Africa , Antiretroviral agents -- South Africa , Materia medica, Vegetable -- South Africa , HIV infections -- Alternative treatment -- South Africa , Rats as laboratory animals , Rats -- Metabolism
- Description: The worldwide AIDS epidemic is known to have had a profoundly negative social, economic and personal impact and has taken a heavy toll on existing health care systems, particularly in developing countries. South Africa is experiencing an HIV epidemic with enormous social and economic consequences. Lopinavir/ritonavir antiretroviral treatment has been accredited with having a significantly positive effect and is a key advance in controlling HIV morbidity and mortality. An indigenous South African medicinal plant, Sutherlandia frutescens, known for its anti-diabetic properties and immune-boosting effects, is used for treating HIV positive patients suffering from opportunistic infections. Despite the use of the medicinal plant extract as homeotherapeutic medication, there is little evidence of toxicity testing that identifies its potential for interaction with antiretroviral drugs. However, scientific data relating to the mechanism through which Sutherlandia frutescens acts on the immune system has not been comprehensively documented. The aim of this study was to investigate lopinavir/ritonavir induced metabolic abnormalities in rats and whether the introduction of a plant extract of Sutherlandia frutescens would counteract the side effects of ARV medication. The results indicated that the rodents did not become insulin resistant, however, biochemical analysis indicated that extended ARV drug treatment would have caused insulin resistance. Significant morphological changes were found in the livers, kidneys and pancreases of rats exposed to the lopinavir/ritonavir. Rats exposed to the Sutherlandia frutescens plant extract showed improved histopathology with minimal abnormalities.
- Full Text:
- Date Issued: 2008
Effect of salinity on oxygen consumption and growth of juvenile white steenbras, litohognathus lithognathus
- Authors: Kandjou, Kaunahama
- Date: 2008
- Subjects: Lithognathus -- Growth , Salinity
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5275 , http://hdl.handle.net/10962/d1005119 , Lithognathus -- Growth , Salinity
- Description: A stress-induced increase in metabolic rate of fish consumes energy within the metabolic scope of a fish that could otherwise be used for such functions as growth and reproduction. By estimating the degree of the metabolic response under given salinity levels and sudden changes thereof, it could be tested whether growth under given culture conditions could be predicted. Using intermittent respirometers, this study investigated the metabolic response of juvenile Lithognathus lithognathus following gradual acclimation to 5, 25 and 35‰ and, as a result of abrupt change from 35‰ to 5‰ or from 35‰ to 25‰ at 20˚C. The main aim of the study was to establish whether the magnitude of such responses could be used to predict growth of juvenile L. lithognathus under culture conditions. Hence, in addition to the respirometry study, two growth studies were conducted at 5, 10, 25 and 35‰ salinities. The baseline metabolic rates of juvenile L. lithognathus were also determined. Oxygen consumption measurements over 24-hours showed that most fish exhibited a diurnal peak in metabolic rates. The standard and active metabolic rates calculated from juvenile L. lithognathus with a diurnal peak in oxygen consumption were 0.06±0.001mgO₂g⁻¹h⁻¹ (mean±SEM, n = 5), and 0.11±0.01mg O₂g⁻¹h⁻¹, respectively. The standard and active metabolic rates of juvenile L lithognathus showing a nocturnal peak in metabolic activities were 0.04±0.001mgO₂g-1h-1 (n = 1), and 0.12±0.003 mg O₂g⁻¹ h⁻¹, respectively. Routine metabolic rate of these fish calculated over a 3-h measurement period was 0.09±0.005mgO₂g⁻¹h⁻¹ (n = 6). Juvenile L. lithognathus showed a relationship between metabolic rate (mo₂) and body weight (W) following the equation: mo₂ = 0.62 W⁻°·⁵³.
- Full Text:
- Date Issued: 2008
- Authors: Kandjou, Kaunahama
- Date: 2008
- Subjects: Lithognathus -- Growth , Salinity
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5275 , http://hdl.handle.net/10962/d1005119 , Lithognathus -- Growth , Salinity
- Description: A stress-induced increase in metabolic rate of fish consumes energy within the metabolic scope of a fish that could otherwise be used for such functions as growth and reproduction. By estimating the degree of the metabolic response under given salinity levels and sudden changes thereof, it could be tested whether growth under given culture conditions could be predicted. Using intermittent respirometers, this study investigated the metabolic response of juvenile Lithognathus lithognathus following gradual acclimation to 5, 25 and 35‰ and, as a result of abrupt change from 35‰ to 5‰ or from 35‰ to 25‰ at 20˚C. The main aim of the study was to establish whether the magnitude of such responses could be used to predict growth of juvenile L. lithognathus under culture conditions. Hence, in addition to the respirometry study, two growth studies were conducted at 5, 10, 25 and 35‰ salinities. The baseline metabolic rates of juvenile L. lithognathus were also determined. Oxygen consumption measurements over 24-hours showed that most fish exhibited a diurnal peak in metabolic rates. The standard and active metabolic rates calculated from juvenile L. lithognathus with a diurnal peak in oxygen consumption were 0.06±0.001mgO₂g⁻¹h⁻¹ (mean±SEM, n = 5), and 0.11±0.01mg O₂g⁻¹h⁻¹, respectively. The standard and active metabolic rates of juvenile L lithognathus showing a nocturnal peak in metabolic activities were 0.04±0.001mgO₂g-1h-1 (n = 1), and 0.12±0.003 mg O₂g⁻¹ h⁻¹, respectively. Routine metabolic rate of these fish calculated over a 3-h measurement period was 0.09±0.005mgO₂g⁻¹h⁻¹ (n = 6). Juvenile L. lithognathus showed a relationship between metabolic rate (mo₂) and body weight (W) following the equation: mo₂ = 0.62 W⁻°·⁵³.
- Full Text:
- Date Issued: 2008
Effects of coastal topography on physiology, behaviour and genetics of indigenous (Perna perna) and invasive (Mytilus galloprovincialis) mussels
- Authors: Nicastro, Katy R
- Date: 2008
- Subjects: Mussels -- Ecology -- South Africa , Perna -- Physiology -- South Africa , Perna -- Behavior -- South Africa , Mussels -- Behavior -- Environmental factors -- South Africa , Mussels -- Habitat -- South Africa , Mytilus galloprovincialis , Mytilus galloprovincialis -- Physiology -- South Africa , Mytilus galloprovincialis -- Behavior -- South Africa , Mytilus galloprovincialis -- Genetics -- South Africa , Coastal ecology -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5833 , http://hdl.handle.net/10962/d1008262
- Description: Organisms inhabit environments that have many dimensions, each of which can vary temporally and spatially. The spatial-temporal variations of environmental stressors and disturbances may have major but different effects on indigenous and invasive species, favouring either of them at different times and places. The invasive mussel Mytilus galloprovincialis invaded the South African coast 30 years ago and, on the south coast of South Africa, it now competes and co-exists with the indigenous Perna perna in the lower eulittoral zone (referred to here as the mussel zone) The invasive and indigenous species dominate the upper and the lower mussel zones respectively, while the two co-exist in the mid-zone. My results show that intertidal mussels experience, and respond to, spatial and temporal fluctuations of several biotic and abiotic stressors. The invasive and the indigenous species adopt different strategies when reacting to environmental factors and their physiological and behavioural responses vary in time and in different habitats as different pressures become of overriding importance. Attachment strength of both species decreased in summer and increased in winter, and was higher on the open coast than in bays for both species, showing a strong positive correlation with wave force in time and space. P. perna had significantly higher attachment strength than M. galloprovincialis but, contrary to previous studies, the difference in gonad index between the two species varied according to the habitat. In bay habitats, M. galloprovincialis had a higher maximum reproductive effort than P. perna, however, on the open coast, there was no significant difference between the two species, suggesting that for the invasive species wave action is a limiting factor not only in terms of the attachment strength but also of energy availability for reproductive tissue development. Major spawning events occurred during periods of low wave action while minor spawning coincided with periods of intense hydrodynamic stress. On the open coast, gonad index was negatively correlated with attachment strength for both species while, in bays, there was no correlation between these two factors for either. The two species also showed different behaviour. In the field, M. galloprovincialis moved significantly more than P. perna over a period of six months. The higher mobility of the invasive species was also confirmed in the laboratory where, in general, M. galloprovincialis formed clumps more readily than P. perna. Taken collectively, these results suggest that channelling more energy into attachment strength limits reproductive tissue development and that, while the indigenous species invests more in byssal production, the invasive species adopts a more dynamic strategy looking for aggregation or a safer arrangement. Higher endolithic infestation and a greater expression of heat shock proteins (Hsps) in mussel populations on the open coast than in bays indicate that this habitat is a more stressful environment not only in terms of wave action. Endolith damaged mussels had significantly lower attachment strengths and condition indices than clean mussels, probably due to the need to channel energy into shell repair. The constant shell repair and expression of Hsps typical of open coast populations are energetically demanding processes. These observations suggest that on the open coast, mussels are subjected to more severe energetic constraints than in bay habitats. Wave and sand stress fluctuated seasonally with the former having a greater effect on mussel mortality on the open coast and the latter a higher impact on bay populations. Overall, mussel mortality rates were higher on the open coast than in bays. My results show that populations on the open coast had fewer private haplotypes and less genetic endemism than those inside bays. Gene flow analysis showed the relatively stable bay habitats act as source populations with greater genetic migration rates out of bays than into them. These differences in genetic structure on scales of las of kilometers show that coastal configuration strongly affects selection, larval dispersal and haplotype diversity. Environmental gradients that are key factors in species distribution over large geographical scales can also be responsible for micro-scale distributions. My results show that M. galloprovincialis colonizes the upper mussel zone where temperature is high, but is less tolerant to this stressor and has to maintain a high expression of Hsps. This suggests that temperature is probably a limiting factor in its invasion towards the sub-tropical east coast. There are inter- and intra-specific differences in responses to the environment which highlight the efforts of M. galloprovincialis and P. perna to optimize resource utilization for survival and reproduction. Determining these differences is crucial to understanding patterns of co-existence between competing indigenous and invasive species.
- Full Text:
- Date Issued: 2008
- Authors: Nicastro, Katy R
- Date: 2008
- Subjects: Mussels -- Ecology -- South Africa , Perna -- Physiology -- South Africa , Perna -- Behavior -- South Africa , Mussels -- Behavior -- Environmental factors -- South Africa , Mussels -- Habitat -- South Africa , Mytilus galloprovincialis , Mytilus galloprovincialis -- Physiology -- South Africa , Mytilus galloprovincialis -- Behavior -- South Africa , Mytilus galloprovincialis -- Genetics -- South Africa , Coastal ecology -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5833 , http://hdl.handle.net/10962/d1008262
- Description: Organisms inhabit environments that have many dimensions, each of which can vary temporally and spatially. The spatial-temporal variations of environmental stressors and disturbances may have major but different effects on indigenous and invasive species, favouring either of them at different times and places. The invasive mussel Mytilus galloprovincialis invaded the South African coast 30 years ago and, on the south coast of South Africa, it now competes and co-exists with the indigenous Perna perna in the lower eulittoral zone (referred to here as the mussel zone) The invasive and indigenous species dominate the upper and the lower mussel zones respectively, while the two co-exist in the mid-zone. My results show that intertidal mussels experience, and respond to, spatial and temporal fluctuations of several biotic and abiotic stressors. The invasive and the indigenous species adopt different strategies when reacting to environmental factors and their physiological and behavioural responses vary in time and in different habitats as different pressures become of overriding importance. Attachment strength of both species decreased in summer and increased in winter, and was higher on the open coast than in bays for both species, showing a strong positive correlation with wave force in time and space. P. perna had significantly higher attachment strength than M. galloprovincialis but, contrary to previous studies, the difference in gonad index between the two species varied according to the habitat. In bay habitats, M. galloprovincialis had a higher maximum reproductive effort than P. perna, however, on the open coast, there was no significant difference between the two species, suggesting that for the invasive species wave action is a limiting factor not only in terms of the attachment strength but also of energy availability for reproductive tissue development. Major spawning events occurred during periods of low wave action while minor spawning coincided with periods of intense hydrodynamic stress. On the open coast, gonad index was negatively correlated with attachment strength for both species while, in bays, there was no correlation between these two factors for either. The two species also showed different behaviour. In the field, M. galloprovincialis moved significantly more than P. perna over a period of six months. The higher mobility of the invasive species was also confirmed in the laboratory where, in general, M. galloprovincialis formed clumps more readily than P. perna. Taken collectively, these results suggest that channelling more energy into attachment strength limits reproductive tissue development and that, while the indigenous species invests more in byssal production, the invasive species adopts a more dynamic strategy looking for aggregation or a safer arrangement. Higher endolithic infestation and a greater expression of heat shock proteins (Hsps) in mussel populations on the open coast than in bays indicate that this habitat is a more stressful environment not only in terms of wave action. Endolith damaged mussels had significantly lower attachment strengths and condition indices than clean mussels, probably due to the need to channel energy into shell repair. The constant shell repair and expression of Hsps typical of open coast populations are energetically demanding processes. These observations suggest that on the open coast, mussels are subjected to more severe energetic constraints than in bay habitats. Wave and sand stress fluctuated seasonally with the former having a greater effect on mussel mortality on the open coast and the latter a higher impact on bay populations. Overall, mussel mortality rates were higher on the open coast than in bays. My results show that populations on the open coast had fewer private haplotypes and less genetic endemism than those inside bays. Gene flow analysis showed the relatively stable bay habitats act as source populations with greater genetic migration rates out of bays than into them. These differences in genetic structure on scales of las of kilometers show that coastal configuration strongly affects selection, larval dispersal and haplotype diversity. Environmental gradients that are key factors in species distribution over large geographical scales can also be responsible for micro-scale distributions. My results show that M. galloprovincialis colonizes the upper mussel zone where temperature is high, but is less tolerant to this stressor and has to maintain a high expression of Hsps. This suggests that temperature is probably a limiting factor in its invasion towards the sub-tropical east coast. There are inter- and intra-specific differences in responses to the environment which highlight the efforts of M. galloprovincialis and P. perna to optimize resource utilization for survival and reproduction. Determining these differences is crucial to understanding patterns of co-existence between competing indigenous and invasive species.
- Full Text:
- Date Issued: 2008
Effects of sheep kraal manure and intercropping with maize on growth, nutrient uptake and yield of a vegetable Amaranthus accession in the central region of the Eastern Cape, South Africa
- Authors: Mhlontlo, Simphiwe
- Date: 2008
- Subjects: Intercropping , Amaranths , Traditional farming , Manures
- Language: English
- Type: Thesis , Masters , MSc Agric (Crop Science)
- Identifier: vital:11864 , http://hdl.handle.net/10353/76 , Intercropping , Amaranths , Traditional farming , Manures
- Description: Amaranthus is among the nutritious indigenous plant species that are gathered from the wild in the Eastern Cape to prepare a traditional meal known as ‘imifino’ or ‘isigwampa’ to supplement the necessary proteins, vitamins and minerals which are poor in maizebased meals. Amaranthus species are adapted to wild conditions unsuitable for exotic vegetables and could be cultivated but information on its fertility requirements, as sole or intercrop, is the key for its domestication and production as a leafy vegetable, particularly where manure is used. Two dry-land and one glasshouse experiments were conducted to study the effects of sheep kraal manure application rate, intercropping with maize and soil type on growth, fresh and dry matter yields, nutrient uptake and grain yield of a local Amaranthus accession that grows wild in the Eastern Cape. Sheep kraal manure rates ranging from 0 to 10 t ha-1 and an NPK {2:3:4(30) + 0.5% Zn} fertilizer as a positive control, applied at rates recommended for spinach, were tested. In the Gqumahashe experiment, where Amaranthus was grown as a sole crop, low manure rates (≤ 2.5 t ha-1) resulted in plant heights and fresh matter yields which were comparable to those in the unfertilized control, whereas higher rates (5 and 10 t ha-1) and recommended NPK fertilizer had higher levels both at 30 and 60 days after transplanting (DAT) at p < 0.05. At 30 DAT, manure application rates of ≥ 2.5 t ha-1 and the NPK fertilizer treatment, produced greater shoot dry-matter yields (29.35, 30.75 and 37.68 g plant-1) than the unfertilized control (17.11 g plant-1) at p < 0.05. Uptake of N and P in the leaves increased with increase in manure application rate with N uptake reaching a maximum (308 mg plant-1) at a manure rate of 2.5 t ha-1 which corresponded with the maximum dry matter yield. There was no effect of manure rate or fertilizer on residual soil N and Ca, whereas P, K, Mg and Zn increased. In a pot experiment with soils from Ntselamanzi and Gqumahashe Villages, manure rates ≥ 2.5 t ha-1 resulted in plant heights and fresh matter yield that compared well with the NPK fertilizer treatment in the Gqumahashe soil whereas only the 10 t ha-1 manure treatment was comparable to the NPK fertilizer treatment in the Ntselamanzi soil. Only treatments with ≥ 5 t ha-1 manure had stem girth (1.00 and 1.07 cm) that compared well to NPK fertilizer (1.03 cm) in the Ntselamanzi soil whereas in the Gqumahashe soil, all manure levels compared well to NPK fertilizer (1.02 cm). However, no significant difference was observed in plant height and stem girth and fresh matter due to soil type. In both soils, the 1.3-10 t ha-1 manure treatments had dry leaf weight comparable to plants fertilized with NPK fertilizer (3.72 g plant-1 for the Ntselamanzi soil and 3.65 g plant-1 for the Gqumahashe soil) and were bigger than the unfertilized control (2.2 g plant-1 for the Ntselamanzi soil and 1.38 g plant-1 for the Gqumahashe soil) at p < 0.05. Uptake of N, P and K increased as result of manure application but nonetheless, it was less when compared to plants fertilized with NPK fertilizer in both soils. In a field intercropping experiment carried out at Ntselamanzi, growth and yield of sole and intercropped Amaranthus plants grown with manure improved when compared to the unfertilized control and compared well to NPK fertilizer. At 30 days after transplanting (DAT), both sole and intercropped plants grown with ≥ 2.5 t ha-1 manure had fresh and dry matter yield comparable to plants fertilized with NPK fertilizer. At 60 DAT, intercropped plants grown with all manure levels had bigger fresh matter yield when compared to unfertilized control (836.0 g plant-1) whereas for sole cropped plants only those grown with ≥ 2.5 t ha-1 compared to NPK fertilizer (1467.7 g plant-1) at p < 0.05. Uptake of N, P, K, Ca and Mg increased with increase in manure application in both sole and intercropped Amaranthus. Whereas Amaranthus did not suffer from the competition in the intercrop, maize biomass and grain yield were severely reduced with the effects being evident after 60 DAT. Based on results of this study, it is therefore suggested that, if Amaranthus is to be intercropped with maize under dry land conditions of the Central Region of the Eastern Cape, sheep manure should at least be applied at rate of ≥ 2.5 t ha-1 and Amaranthus be harvested at 30 DAT.
- Full Text:
- Date Issued: 2008
- Authors: Mhlontlo, Simphiwe
- Date: 2008
- Subjects: Intercropping , Amaranths , Traditional farming , Manures
- Language: English
- Type: Thesis , Masters , MSc Agric (Crop Science)
- Identifier: vital:11864 , http://hdl.handle.net/10353/76 , Intercropping , Amaranths , Traditional farming , Manures
- Description: Amaranthus is among the nutritious indigenous plant species that are gathered from the wild in the Eastern Cape to prepare a traditional meal known as ‘imifino’ or ‘isigwampa’ to supplement the necessary proteins, vitamins and minerals which are poor in maizebased meals. Amaranthus species are adapted to wild conditions unsuitable for exotic vegetables and could be cultivated but information on its fertility requirements, as sole or intercrop, is the key for its domestication and production as a leafy vegetable, particularly where manure is used. Two dry-land and one glasshouse experiments were conducted to study the effects of sheep kraal manure application rate, intercropping with maize and soil type on growth, fresh and dry matter yields, nutrient uptake and grain yield of a local Amaranthus accession that grows wild in the Eastern Cape. Sheep kraal manure rates ranging from 0 to 10 t ha-1 and an NPK {2:3:4(30) + 0.5% Zn} fertilizer as a positive control, applied at rates recommended for spinach, were tested. In the Gqumahashe experiment, where Amaranthus was grown as a sole crop, low manure rates (≤ 2.5 t ha-1) resulted in plant heights and fresh matter yields which were comparable to those in the unfertilized control, whereas higher rates (5 and 10 t ha-1) and recommended NPK fertilizer had higher levels both at 30 and 60 days after transplanting (DAT) at p < 0.05. At 30 DAT, manure application rates of ≥ 2.5 t ha-1 and the NPK fertilizer treatment, produced greater shoot dry-matter yields (29.35, 30.75 and 37.68 g plant-1) than the unfertilized control (17.11 g plant-1) at p < 0.05. Uptake of N and P in the leaves increased with increase in manure application rate with N uptake reaching a maximum (308 mg plant-1) at a manure rate of 2.5 t ha-1 which corresponded with the maximum dry matter yield. There was no effect of manure rate or fertilizer on residual soil N and Ca, whereas P, K, Mg and Zn increased. In a pot experiment with soils from Ntselamanzi and Gqumahashe Villages, manure rates ≥ 2.5 t ha-1 resulted in plant heights and fresh matter yield that compared well with the NPK fertilizer treatment in the Gqumahashe soil whereas only the 10 t ha-1 manure treatment was comparable to the NPK fertilizer treatment in the Ntselamanzi soil. Only treatments with ≥ 5 t ha-1 manure had stem girth (1.00 and 1.07 cm) that compared well to NPK fertilizer (1.03 cm) in the Ntselamanzi soil whereas in the Gqumahashe soil, all manure levels compared well to NPK fertilizer (1.02 cm). However, no significant difference was observed in plant height and stem girth and fresh matter due to soil type. In both soils, the 1.3-10 t ha-1 manure treatments had dry leaf weight comparable to plants fertilized with NPK fertilizer (3.72 g plant-1 for the Ntselamanzi soil and 3.65 g plant-1 for the Gqumahashe soil) and were bigger than the unfertilized control (2.2 g plant-1 for the Ntselamanzi soil and 1.38 g plant-1 for the Gqumahashe soil) at p < 0.05. Uptake of N, P and K increased as result of manure application but nonetheless, it was less when compared to plants fertilized with NPK fertilizer in both soils. In a field intercropping experiment carried out at Ntselamanzi, growth and yield of sole and intercropped Amaranthus plants grown with manure improved when compared to the unfertilized control and compared well to NPK fertilizer. At 30 days after transplanting (DAT), both sole and intercropped plants grown with ≥ 2.5 t ha-1 manure had fresh and dry matter yield comparable to plants fertilized with NPK fertilizer. At 60 DAT, intercropped plants grown with all manure levels had bigger fresh matter yield when compared to unfertilized control (836.0 g plant-1) whereas for sole cropped plants only those grown with ≥ 2.5 t ha-1 compared to NPK fertilizer (1467.7 g plant-1) at p < 0.05. Uptake of N, P, K, Ca and Mg increased with increase in manure application in both sole and intercropped Amaranthus. Whereas Amaranthus did not suffer from the competition in the intercrop, maize biomass and grain yield were severely reduced with the effects being evident after 60 DAT. Based on results of this study, it is therefore suggested that, if Amaranthus is to be intercropped with maize under dry land conditions of the Central Region of the Eastern Cape, sheep manure should at least be applied at rate of ≥ 2.5 t ha-1 and Amaranthus be harvested at 30 DAT.
- Full Text:
- Date Issued: 2008
Effects of temperature on the development, behaviour and geography of blowflies in a forensic context
- Authors: Richards, Cameron Spencer
- Date: 2008
- Subjects: Blowflies Blowflies -- South Africa Diptera -- South Africa Insects -- Development Insects -- Behavior Forensic entomology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5683 , http://hdl.handle.net/10962/d1005369
- Description: The development of immature insects is commonly employed in forensic investigations to estimate time of death, or postmortem interval (PMI), of a corpse on which they are feeding. The bulk of this thesis focuses on factors influencing the accuracy of developmental data, and exploring how and why developmental data differ between studies involving the same species, and between different species. Because carrion feeding insects are ectotherms, temperature may be expected to significantly influence their behaviour, development and distribution, and the remainder of the thesis therefore focuses on the thermal biology and geographical distribution of seven forensically important blowflies. The species include Chrysomya albiceps, C. putoria, C. chloropyga, C. megacephala, C. marginalis, C. inclinata and Calliphora croceipalpis. A robust experimental design for estimating developmental models is outlined and tested. It is recommended that forensic entomologists should involve at least six constant temperatures, starting at about 7°C above the relevant developmental zero (D0) and going to about 10°C above the upper critical temperature, and a temporal sampling interval with a relative precision of about 10%. Using this design, focused experiments consistently provided the most reliable developmental data, while data pooled from different studies yielded inconsistent results. Similarly, developmental data from closely related species differed significantly, and surprisingly so did developmental data from different populations of the same species. Possible explanations for the latter lay in the different methods of data collection but only temporal sampling resolution had a direct influence on the accuracy of developmental data. Consequently, disparities in such data were primarily ascribed to genetic differences and phenotypic plasticity. Comparisons between numerous thermal thresholds of larvae, pupae and adults support this conclusion and suggest a phylogenetic component to the thermal biology of blowflies. Further comparisons were made between these temperature thresholds and the distributions of blowfly species present on two rhinoceros carcasses. These comparisons suggest that blowfly larvae with high upper lethal temperature thresholds dominate in interspecific competition in favorable thermal environments by raising maggot mass temperature above the thresholds of other carrion-feeding blowflies, through maggot-generated heat. Bioclimatic modeling using maximum entropy analysis provided a successful means of predicting whether a species is likely to occur in an area, and whether it would therefore be expected in a local carcass community. It also showed that temperature was less important than moisture in shaping the geographical distribution of African carrion blowflies. Based on these results, several recommendations are made for the practice of forensic entomology.
- Full Text:
- Date Issued: 2008
- Authors: Richards, Cameron Spencer
- Date: 2008
- Subjects: Blowflies Blowflies -- South Africa Diptera -- South Africa Insects -- Development Insects -- Behavior Forensic entomology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5683 , http://hdl.handle.net/10962/d1005369
- Description: The development of immature insects is commonly employed in forensic investigations to estimate time of death, or postmortem interval (PMI), of a corpse on which they are feeding. The bulk of this thesis focuses on factors influencing the accuracy of developmental data, and exploring how and why developmental data differ between studies involving the same species, and between different species. Because carrion feeding insects are ectotherms, temperature may be expected to significantly influence their behaviour, development and distribution, and the remainder of the thesis therefore focuses on the thermal biology and geographical distribution of seven forensically important blowflies. The species include Chrysomya albiceps, C. putoria, C. chloropyga, C. megacephala, C. marginalis, C. inclinata and Calliphora croceipalpis. A robust experimental design for estimating developmental models is outlined and tested. It is recommended that forensic entomologists should involve at least six constant temperatures, starting at about 7°C above the relevant developmental zero (D0) and going to about 10°C above the upper critical temperature, and a temporal sampling interval with a relative precision of about 10%. Using this design, focused experiments consistently provided the most reliable developmental data, while data pooled from different studies yielded inconsistent results. Similarly, developmental data from closely related species differed significantly, and surprisingly so did developmental data from different populations of the same species. Possible explanations for the latter lay in the different methods of data collection but only temporal sampling resolution had a direct influence on the accuracy of developmental data. Consequently, disparities in such data were primarily ascribed to genetic differences and phenotypic plasticity. Comparisons between numerous thermal thresholds of larvae, pupae and adults support this conclusion and suggest a phylogenetic component to the thermal biology of blowflies. Further comparisons were made between these temperature thresholds and the distributions of blowfly species present on two rhinoceros carcasses. These comparisons suggest that blowfly larvae with high upper lethal temperature thresholds dominate in interspecific competition in favorable thermal environments by raising maggot mass temperature above the thresholds of other carrion-feeding blowflies, through maggot-generated heat. Bioclimatic modeling using maximum entropy analysis provided a successful means of predicting whether a species is likely to occur in an area, and whether it would therefore be expected in a local carcass community. It also showed that temperature was less important than moisture in shaping the geographical distribution of African carrion blowflies. Based on these results, several recommendations are made for the practice of forensic entomology.
- Full Text:
- Date Issued: 2008
Electro-catalyzed oxidation of reduced glutathione and 2-mercaptoethanol by cobalt phthalocyanine-containing screen printed graphite electrodes
- Sehlotho, Nthapo, Griveau, Sophie, Ruillé, Nadine, Boujtita, Mohammed, Nyokong, Tebello, Bedioui, Fethi
- Authors: Sehlotho, Nthapo , Griveau, Sophie , Ruillé, Nadine , Boujtita, Mohammed , Nyokong, Tebello , Bedioui, Fethi
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265935 , vital:53902 , xlink:href="https://doi.org/10.1016/j.msec.2007.10.054"
- Description: Electro-catalytic behavior of screen printed graphite electrodes modified with cobalt phthalocyanine (CoPc) towards the oxidation of reduced glutathione (GSH) and 2-mercaptoethanol (2-ME) is reported. We find, by using cyclic voltammetry, that the oxidation of 2-ME occurs at 0.2 V vs Ag/AgCl and − 0.3 vs Ag/AgCl V at pH = 7 and pH = 13, respectively and that of GSH occurs at 0.4 V vs Ag/AgCl and 0.0 V vs Ag/AgCl at pH = 7 and 13, respectively. The electro-catalytic activity depends on the method of electrode modification and the amount of catalyst incorporated in the ink used to fabricate the SPCEs. The highest activity was obtained with electrodes prepared with 2.5% (w:w) of CoPc.
- Full Text:
- Date Issued: 2008
- Authors: Sehlotho, Nthapo , Griveau, Sophie , Ruillé, Nadine , Boujtita, Mohammed , Nyokong, Tebello , Bedioui, Fethi
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265935 , vital:53902 , xlink:href="https://doi.org/10.1016/j.msec.2007.10.054"
- Description: Electro-catalytic behavior of screen printed graphite electrodes modified with cobalt phthalocyanine (CoPc) towards the oxidation of reduced glutathione (GSH) and 2-mercaptoethanol (2-ME) is reported. We find, by using cyclic voltammetry, that the oxidation of 2-ME occurs at 0.2 V vs Ag/AgCl and − 0.3 vs Ag/AgCl V at pH = 7 and pH = 13, respectively and that of GSH occurs at 0.4 V vs Ag/AgCl and 0.0 V vs Ag/AgCl at pH = 7 and 13, respectively. The electro-catalytic activity depends on the method of electrode modification and the amount of catalyst incorporated in the ink used to fabricate the SPCEs. The highest activity was obtained with electrodes prepared with 2.5% (w:w) of CoPc.
- Full Text:
- Date Issued: 2008
Electrocatalytic and photosensitizing behavior of metallophthalocyanine complexes
- Authors: Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265908 , vital:53899 , xlink:href="https://doi.org/10.1142/S1088424608000388"
- Description: Electrocatalytic or photosensitizing (photocatalytic) properties of metallophthalocyanine (MPc) complexes are dependent on the central metal. Electrocatalytic behavior is observed for electroactive central metals such as Co, Mn and Fe, whereas photosensitizing behavior is observed for diamagnetic metals such as Al, Zn and Si. In the presence of nanoparticles such as quantum dots, the photosensitizing behavior of MPc complexes is improved. Carbon nanotubes enhance the electrocatalytic behavior of MPc complexes.
- Full Text:
- Date Issued: 2008
- Authors: Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265908 , vital:53899 , xlink:href="https://doi.org/10.1142/S1088424608000388"
- Description: Electrocatalytic or photosensitizing (photocatalytic) properties of metallophthalocyanine (MPc) complexes are dependent on the central metal. Electrocatalytic behavior is observed for electroactive central metals such as Co, Mn and Fe, whereas photosensitizing behavior is observed for diamagnetic metals such as Al, Zn and Si. In the presence of nanoparticles such as quantum dots, the photosensitizing behavior of MPc complexes is improved. Carbon nanotubes enhance the electrocatalytic behavior of MPc complexes.
- Full Text:
- Date Issued: 2008
Electrocatalytic detection of amitrole on the multi-walled carbon nanotube–iron (II) tetra-aminophthalocyanine platform
- Siswana, Msimelelo P, Ozoemena, Kenneth I, Nyokong, Tebello
- Authors: Siswana, Msimelelo P , Ozoemena, Kenneth I , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265924 , vital:53901 , xlink:href="https://doi.org/10.3390/s8085096"
- Description: It is shown that iron(II) tetra-aminophthalocyanine complex electropolymerized onto a multi-walled carbon nanotube-modified basal plane pyrolytic graphite electrode greatly enhanced the electrocatalytic detetion of amitrole (a toxic herbicide), resulting in a very low detection limit (0.5 nM) and excellent sensitivity of 8.80±0.44 μA/nM, compared to any known work reported so far. The electrocatalytic detection of amitrole at this electrode occurred at less positive potential (~0.3 V vs Ag|ACl) and also revealed a typical coupled chemical reaction. The mechanism for this response is proposed. The electrode gave satisfactory selectivity to amitrole in the presence of other potential interfering pesticides in aqueous solutions.
- Full Text:
- Date Issued: 2008
- Authors: Siswana, Msimelelo P , Ozoemena, Kenneth I , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265924 , vital:53901 , xlink:href="https://doi.org/10.3390/s8085096"
- Description: It is shown that iron(II) tetra-aminophthalocyanine complex electropolymerized onto a multi-walled carbon nanotube-modified basal plane pyrolytic graphite electrode greatly enhanced the electrocatalytic detetion of amitrole (a toxic herbicide), resulting in a very low detection limit (0.5 nM) and excellent sensitivity of 8.80±0.44 μA/nM, compared to any known work reported so far. The electrocatalytic detection of amitrole at this electrode occurred at less positive potential (~0.3 V vs Ag|ACl) and also revealed a typical coupled chemical reaction. The mechanism for this response is proposed. The electrode gave satisfactory selectivity to amitrole in the presence of other potential interfering pesticides in aqueous solutions.
- Full Text:
- Date Issued: 2008
Electrochemical and electrocatalytic properties of α-substituted manganese and titanium phthalocyanines
- Nombona, Nolwazi, Tau, Prudence, Sehlotho, Nthapo, Nyokong, Tebello
- Authors: Nombona, Nolwazi , Tau, Prudence , Sehlotho, Nthapo , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268587 , vital:54212 , xlink:href="https://doi.org/10.1016/j.electacta.2007.11.046"
- Description: This work reports on the synthesis of manganese and titanium phthalocyanine complexes that are tetra-substituted at four non-peripheral positions with amino ligands. The complexes are investigated for the first time for their electrochemical properties using cyclic voltammetry, rotating disc electrode voltammetry and spectroelectrochemistry. Electropolymerisation on a glassy carbon electrode was performed with ease and the modified electrodes were investigated for electrocatalysis of nitrite oxidation. Nitrite oxidation to nitrate is confirmed from the transfer of a total of two electrons.
- Full Text:
- Date Issued: 2008
- Authors: Nombona, Nolwazi , Tau, Prudence , Sehlotho, Nthapo , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268587 , vital:54212 , xlink:href="https://doi.org/10.1016/j.electacta.2007.11.046"
- Description: This work reports on the synthesis of manganese and titanium phthalocyanine complexes that are tetra-substituted at four non-peripheral positions with amino ligands. The complexes are investigated for the first time for their electrochemical properties using cyclic voltammetry, rotating disc electrode voltammetry and spectroelectrochemistry. Electropolymerisation on a glassy carbon electrode was performed with ease and the modified electrodes were investigated for electrocatalysis of nitrite oxidation. Nitrite oxidation to nitrate is confirmed from the transfer of a total of two electrons.
- Full Text:
- Date Issued: 2008
Electrochemical Characterization of Self-Assembled Monolayer of a Novel Manganese Tetrabenzylthio-Substituted Phthalocyanine and Its Use in Nitrite Oxidation
- Matemadombo, Fungisai, Griveau, Sophie, Bedioui, Fethi, Nyokong, Tebello
- Authors: Matemadombo, Fungisai , Griveau, Sophie , Bedioui, Fethi , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265950 , vital:53903 , xlink:href="https://doi.org/10.1002/elan.200804269"
- Description: Manganese phthalocyanine MnPc(SPh)4 has been synthesized and used to form self assembled monolayers on gold electrodes. The well packed SAM monolayer was characterized by analyzing the blocking of a number of Faradic processes by cyclic voltammetry, evaluating the electrical characteristics of the modified electrode by electrochemical impedance and imaging the modified surface by electrochemical scanning microscopy. Finally, MnPc(SPh)4-SAM modified electrode displayed an electrocatalytic behavior toward the oxidation of nitrite.
- Full Text:
- Date Issued: 2008
- Authors: Matemadombo, Fungisai , Griveau, Sophie , Bedioui, Fethi , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265950 , vital:53903 , xlink:href="https://doi.org/10.1002/elan.200804269"
- Description: Manganese phthalocyanine MnPc(SPh)4 has been synthesized and used to form self assembled monolayers on gold electrodes. The well packed SAM monolayer was characterized by analyzing the blocking of a number of Faradic processes by cyclic voltammetry, evaluating the electrical characteristics of the modified electrode by electrochemical impedance and imaging the modified surface by electrochemical scanning microscopy. Finally, MnPc(SPh)4-SAM modified electrode displayed an electrocatalytic behavior toward the oxidation of nitrite.
- Full Text:
- Date Issued: 2008
Electrooxidation of hydrazine catalyzed by noncovalently functionalized single-walled carbon nanotubes with CoPc
- Geraldo, Daniela A, Togo, Chamunorwa A, Limson, Janice L, Nyokong, Tebello
- Authors: Geraldo, Daniela A , Togo, Chamunorwa A , Limson, Janice L , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265963 , vital:53904 , xlink:href="https://doi.org/10.1016/j.electacta.2008.05.083"
- Description: We report on the electrooxidation of hydrazine catalyzed by single-walled carbon nanotube (SWCNT) functionalized with cobalt phthalocyanine (CoPc) which shows that the presence of the single-walled carbon nanotubes enhances the catalytic activity of the CoPc itself without any change in the reaction mechanism. A synergistic effect, in terms of reactivity when the new nanocomposite material was adsorbed on the GC electrode, was observed. The obtained hybrid electrodes were tested under hydrodynamic conditions, showing two different oxidation processes, which suggest the presence of two different types of active sites on the electrode surface catalyzing the reaction. Electrochemical impedance spectroscopy (EIS) analyses in the presence of [Fe(CN)6]3−/4− as a redox probe revealed that the GC/SWCNT + CoPc showed much lower electron-resistance (Ret) confirming the synergistic effect of the composite mentioned above. Atomic force microscopy (AFM) images showed the clear differences in surface roughness for each film, confirming the different compositions of the hybrid electrodes used in this study.
- Full Text:
- Date Issued: 2008
- Authors: Geraldo, Daniela A , Togo, Chamunorwa A , Limson, Janice L , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265963 , vital:53904 , xlink:href="https://doi.org/10.1016/j.electacta.2008.05.083"
- Description: We report on the electrooxidation of hydrazine catalyzed by single-walled carbon nanotube (SWCNT) functionalized with cobalt phthalocyanine (CoPc) which shows that the presence of the single-walled carbon nanotubes enhances the catalytic activity of the CoPc itself without any change in the reaction mechanism. A synergistic effect, in terms of reactivity when the new nanocomposite material was adsorbed on the GC electrode, was observed. The obtained hybrid electrodes were tested under hydrodynamic conditions, showing two different oxidation processes, which suggest the presence of two different types of active sites on the electrode surface catalyzing the reaction. Electrochemical impedance spectroscopy (EIS) analyses in the presence of [Fe(CN)6]3−/4− as a redox probe revealed that the GC/SWCNT + CoPc showed much lower electron-resistance (Ret) confirming the synergistic effect of the composite mentioned above. Atomic force microscopy (AFM) images showed the clear differences in surface roughness for each film, confirming the different compositions of the hybrid electrodes used in this study.
- Full Text:
- Date Issued: 2008
Employee performance, leadership style and emotional intelligence
- Hayward, Brett A, Amos, Trevor L, Baxter, Jeremy
- Authors: Hayward, Brett A , Amos, Trevor L , Baxter, Jeremy
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270077 , vital:54393 , xlink:href="https://hdl.handle.net/10520/EJC17031"
- Description: Purpose: The purpose of this research is to explore the relationship between employee performance, leadership style and emotional intelligence in the context of a South African parastatal. Problem Investigated: There is a lack of literature and empirical research on the type of leadership required to achieve high levels of employee performance within South African parastatals. Methodology: The Multifactor Leadership Questionnaire (MLQ) was used to determine leadership style, while the Emotional Competency Profiler (ECP) was used to determine the emotional intelligence of the sample of leaders. Employee performance data was provided by the parastatal, based on their performance management system. Data was analysed using correlation analysis, multiple regression analysis, the standard regression ANOVA/F-test, t-tests and Cronbach alpha reliability coefficient. Findings: The findings of the research show that the ECP is a reliable measure of emotional intelligence and that while the MLQ is a reliable measure of transformational leadership, it is not a reliable measure of transactional leadership. The results of the correlation analysis show a positive significant relationship between emotional intelligence and transformational leadership and a negative significant relationship between employee performance and emotional intelligence. The results of regressing employee performance on emotional intelligence and transformational leadership show that emotional intelligence and transformational leadership have no significant effect on employee performance. The results of the regression models of the research could be biased by the lack of variance in employee performance data. Value of the Research: The value of the research lies in it confirming the MLQ as a reliable measure of transformational leadership and the ECP as a reliable measure of emotional intelligence. The finding of a positive significant relationship between emotional intelligence and transformational leadership is a valuable contribution to the literature. Conclusion: Although a positive significant relationship between emotional intelligence and transformational leadership was found, there is a need for further research to determine the type of leadership best suited to achieve high levels of employee performance within the parastatal.
- Full Text:
- Date Issued: 2008
- Authors: Hayward, Brett A , Amos, Trevor L , Baxter, Jeremy
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270077 , vital:54393 , xlink:href="https://hdl.handle.net/10520/EJC17031"
- Description: Purpose: The purpose of this research is to explore the relationship between employee performance, leadership style and emotional intelligence in the context of a South African parastatal. Problem Investigated: There is a lack of literature and empirical research on the type of leadership required to achieve high levels of employee performance within South African parastatals. Methodology: The Multifactor Leadership Questionnaire (MLQ) was used to determine leadership style, while the Emotional Competency Profiler (ECP) was used to determine the emotional intelligence of the sample of leaders. Employee performance data was provided by the parastatal, based on their performance management system. Data was analysed using correlation analysis, multiple regression analysis, the standard regression ANOVA/F-test, t-tests and Cronbach alpha reliability coefficient. Findings: The findings of the research show that the ECP is a reliable measure of emotional intelligence and that while the MLQ is a reliable measure of transformational leadership, it is not a reliable measure of transactional leadership. The results of the correlation analysis show a positive significant relationship between emotional intelligence and transformational leadership and a negative significant relationship between employee performance and emotional intelligence. The results of regressing employee performance on emotional intelligence and transformational leadership show that emotional intelligence and transformational leadership have no significant effect on employee performance. The results of the regression models of the research could be biased by the lack of variance in employee performance data. Value of the Research: The value of the research lies in it confirming the MLQ as a reliable measure of transformational leadership and the ECP as a reliable measure of emotional intelligence. The finding of a positive significant relationship between emotional intelligence and transformational leadership is a valuable contribution to the literature. Conclusion: Although a positive significant relationship between emotional intelligence and transformational leadership was found, there is a need for further research to determine the type of leadership best suited to achieve high levels of employee performance within the parastatal.
- Full Text:
- Date Issued: 2008
Energy transfer in zinc porphyrin–phthalocyanine heterotrimer and heterononamer studied by fluorescence resonance energy transfer (FRET)
- Durmus, Mahmut, Chen, Jiyao Y, Zhao, Zhixin X, Nyokong, Tebello
- Authors: Durmus, Mahmut , Chen, Jiyao Y , Zhao, Zhixin X , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268599 , vital:54213 , xlink:href="https://doi.org/10.1016/j.saa.2007.07.010"
- Description: Two or eight zinc triphenyl porphyrins were conjugated with Zn-phthalocyanine or H2-phthalocyanine to form ZnPc–(ZnTPP)2, ZnPc–(ZnTPP)8, H2Pc–(ZnTPP)2 and H2Pc–(ZnTPP)8. Energy transfers from the porphyrin moiety to phthalocyanine part were quantitatively studied with the modality of fluorescence resonance energy transfer (FRET). By measuring the fluorescence increment from the phthalocyanine moiety and the decrease from porphyrin part under selective excitation at the B band of the porphyrin part in those conjugated compounds and their equimolar mixture of compositions, energy transfer efficiencies were estimated to be 90% for H2Pc–(ZnTPP)8 and ZnPc–(ZnTPP)8, and 60%, 30% for ZnPc–(ZnTPP)2 and H2Pc–(ZnTPP)2, respectively.
- Full Text:
- Date Issued: 2008
- Authors: Durmus, Mahmut , Chen, Jiyao Y , Zhao, Zhixin X , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268599 , vital:54213 , xlink:href="https://doi.org/10.1016/j.saa.2007.07.010"
- Description: Two or eight zinc triphenyl porphyrins were conjugated with Zn-phthalocyanine or H2-phthalocyanine to form ZnPc–(ZnTPP)2, ZnPc–(ZnTPP)8, H2Pc–(ZnTPP)2 and H2Pc–(ZnTPP)8. Energy transfers from the porphyrin moiety to phthalocyanine part were quantitatively studied with the modality of fluorescence resonance energy transfer (FRET). By measuring the fluorescence increment from the phthalocyanine moiety and the decrease from porphyrin part under selective excitation at the B band of the porphyrin part in those conjugated compounds and their equimolar mixture of compositions, energy transfer efficiencies were estimated to be 90% for H2Pc–(ZnTPP)8 and ZnPc–(ZnTPP)8, and 60%, 30% for ZnPc–(ZnTPP)2 and H2Pc–(ZnTPP)2, respectively.
- Full Text:
- Date Issued: 2008
Engendering childhood: concerning the content of South African Television content
- Boshoff, Priscilla A, Prinsloo, Jeanne
- Authors: Boshoff, Priscilla A , Prinsloo, Jeanne
- Date: 2008
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/143560 , vital:38257 , ISBN , https://ischp.files.wordpress.com/2015/08/ischp_2015_abstract_booklet.pdf
- Description: The essays in this volume reflect a wide-range of issues and concerns related to children’s media culture in Africa. For example, several address the role of entertainment television in Addis Abba, Ghana, South Africa, Kenya, and Zambia and in the lives of Muslim children. Other essays introduce us to children-centered media from Ghana, South Africa, and Zimbabwe, and the innovative programs of PLAN-International. In addition to entertainment media and children-centered media, media education and digital media literacy are also discussed.
- Full Text:
- Date Issued: 2008
- Authors: Boshoff, Priscilla A , Prinsloo, Jeanne
- Date: 2008
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/143560 , vital:38257 , ISBN , https://ischp.files.wordpress.com/2015/08/ischp_2015_abstract_booklet.pdf
- Description: The essays in this volume reflect a wide-range of issues and concerns related to children’s media culture in Africa. For example, several address the role of entertainment television in Addis Abba, Ghana, South Africa, Kenya, and Zambia and in the lives of Muslim children. Other essays introduce us to children-centered media from Ghana, South Africa, and Zimbabwe, and the innovative programs of PLAN-International. In addition to entertainment media and children-centered media, media education and digital media literacy are also discussed.
- Full Text:
- Date Issued: 2008
Enhancing end-user capabilities in high speed audio networks
- Chigwamba, Nyasha, Foss, Richard
- Authors: Chigwamba, Nyasha , Foss, Richard
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427279 , vital:72427 , https://www.aes.org/e-lib/browse.cfm?elib=14266
- Description: Firewire is a digital network technology that can be used to interconnect professional audio equipment, PCs and electronic devices. The Plural Node Architecture splits connection management of firewire audio devices between two nodes, namely an Enabler and a Transporter. The Audio Engineering Society’s SC-02-12-G Task Group has produced an Open Generic Transporter guideline document which describes a generic interface between the Enabler and Transporter. A client-server implementation above the Plural Node Architecture allows connection management of firewire audio devices via TCP/IP. This paper describes enhancements made to connection management applications as a result of additional capabilities revealed by the Open Generic Transporter document.
- Full Text:
- Date Issued: 2008
- Authors: Chigwamba, Nyasha , Foss, Richard
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427279 , vital:72427 , https://www.aes.org/e-lib/browse.cfm?elib=14266
- Description: Firewire is a digital network technology that can be used to interconnect professional audio equipment, PCs and electronic devices. The Plural Node Architecture splits connection management of firewire audio devices between two nodes, namely an Enabler and a Transporter. The Audio Engineering Society’s SC-02-12-G Task Group has produced an Open Generic Transporter guideline document which describes a generic interface between the Enabler and Transporter. A client-server implementation above the Plural Node Architecture allows connection management of firewire audio devices via TCP/IP. This paper describes enhancements made to connection management applications as a result of additional capabilities revealed by the Open Generic Transporter document.
- Full Text:
- Date Issued: 2008
Enigmatic trace fossils from the Aeolian lower Jurassic Clarens formation, Southern Africa
- Authors: Bordy, Emese M
- Date: 2008
- Language: English
- Type: Article
- Identifier: vital:6730 , http://hdl.handle.net/10962/d1007538
- Description: The Lower Jurassic aeolienites of the Clarens Formation in southern Africa contain unique sedimentary structures that are unlikely to be non-biogenic. They are also unlike any known modern or ancient trace fossils. Here, some nigmatic, horizontal,regularly-oriented sedimentary structures are described, which occur in association with other trace fossils as well as features that were previously nterpreted as nests of termites or termite-like ancient social nsects. These spectacular structures are exposed in enormous profusion as straight, ~5 mm cylinders with strong compass orientation, in parallel alignment with one another and to ancient horizontal bedding planes. Their fill is identical to that of the host rock: clean, well-sorted, very fine- to finegrained quartz-arenite. In cross-section, each structure is defined by a subtle, ~0.1 mm thin, concentric gap. Without comparable modern biogenic structures, the biological origin of the structures is uncertain. Their strong compass orientations are, however, also inconsistent with an inorganic origin, even though they may resemble pipey concretions generated by flowing groundwater. Nonetheless, this paper, based on spatiotemporal distribution patterns of the oriented structures, their locally high abundance and association with obvious trace fossils, as well as other sedimentological and palaeontological lines of evidence, argues that the compass structures may be products of ancient social invertebrates living in a resource-limited, semi-arid to arid environment. Furthermore, the compass structures as well as the accompanying structures of the predominantly aeolian Clarens Formation collectively imply the recurrence of favourable ecological parameters (e.g., moist ubstrates) related to episodic climate fluctuations in the Early Jurassic of southern Pangaea (i.e., southern Gondwana).
- Full Text:
- Date Issued: 2008
- Authors: Bordy, Emese M
- Date: 2008
- Language: English
- Type: Article
- Identifier: vital:6730 , http://hdl.handle.net/10962/d1007538
- Description: The Lower Jurassic aeolienites of the Clarens Formation in southern Africa contain unique sedimentary structures that are unlikely to be non-biogenic. They are also unlike any known modern or ancient trace fossils. Here, some nigmatic, horizontal,regularly-oriented sedimentary structures are described, which occur in association with other trace fossils as well as features that were previously nterpreted as nests of termites or termite-like ancient social nsects. These spectacular structures are exposed in enormous profusion as straight, ~5 mm cylinders with strong compass orientation, in parallel alignment with one another and to ancient horizontal bedding planes. Their fill is identical to that of the host rock: clean, well-sorted, very fine- to finegrained quartz-arenite. In cross-section, each structure is defined by a subtle, ~0.1 mm thin, concentric gap. Without comparable modern biogenic structures, the biological origin of the structures is uncertain. Their strong compass orientations are, however, also inconsistent with an inorganic origin, even though they may resemble pipey concretions generated by flowing groundwater. Nonetheless, this paper, based on spatiotemporal distribution patterns of the oriented structures, their locally high abundance and association with obvious trace fossils, as well as other sedimentological and palaeontological lines of evidence, argues that the compass structures may be products of ancient social invertebrates living in a resource-limited, semi-arid to arid environment. Furthermore, the compass structures as well as the accompanying structures of the predominantly aeolian Clarens Formation collectively imply the recurrence of favourable ecological parameters (e.g., moist ubstrates) related to episodic climate fluctuations in the Early Jurassic of southern Pangaea (i.e., southern Gondwana).
- Full Text:
- Date Issued: 2008
Environmental Education and Educational Quality and Relevance-Opening the debate
- Authors: Lotz-Sisitka, Heila
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182668 , vital:43852 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122756"
- Description: This edition of the Southern African Journal of Environmental Education (SAJEE) tackles a critical issue being debated across the world today, namely the question of educational quality and relevance. In 2005 the UNESCO Education for All Global Monitoring Report entitled Education for All: The Quality Imperative (UNESCO, 2004) was published. This global monitoring report drew attention to issues of educational quality, and raised the problem that physical access to education does not necessarily lead to epistemological access to knowledge or to relevant education being offered to learners. In the foreword to the 430-page assessment of educational quality issues, Koïchiro Matsuura, Director General of UNESCO, stated that ‘although much debate surrounds attempts to define educational quality, solid common ground exists … Quality must be seen in light of how societies define the purpose of education’ (UNESCO, 2004: Foreword). He went on to explain that there seem to be two mutually agreed upon purposes for education in the world today: cognitive development of learners, and creative and emotional growth of learners to help them acquire values and attitudes for responsible citizenship. He also pointed out that ‘quality must pass the test of equity’ (UNESCO, 2004: Foreword), emphasising the importance of equity of opportunity to access and participate in education and learning. Relevant to the field of environmental education, is the inclusion of educational quality as a major thrust of the United Nations Decade of Education for Sustainable Development (UNDESD) (UNESCO, 2004).
- Full Text:
- Date Issued: 2008
- Authors: Lotz-Sisitka, Heila
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182668 , vital:43852 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122756"
- Description: This edition of the Southern African Journal of Environmental Education (SAJEE) tackles a critical issue being debated across the world today, namely the question of educational quality and relevance. In 2005 the UNESCO Education for All Global Monitoring Report entitled Education for All: The Quality Imperative (UNESCO, 2004) was published. This global monitoring report drew attention to issues of educational quality, and raised the problem that physical access to education does not necessarily lead to epistemological access to knowledge or to relevant education being offered to learners. In the foreword to the 430-page assessment of educational quality issues, Koïchiro Matsuura, Director General of UNESCO, stated that ‘although much debate surrounds attempts to define educational quality, solid common ground exists … Quality must be seen in light of how societies define the purpose of education’ (UNESCO, 2004: Foreword). He went on to explain that there seem to be two mutually agreed upon purposes for education in the world today: cognitive development of learners, and creative and emotional growth of learners to help them acquire values and attitudes for responsible citizenship. He also pointed out that ‘quality must pass the test of equity’ (UNESCO, 2004: Foreword), emphasising the importance of equity of opportunity to access and participate in education and learning. Relevant to the field of environmental education, is the inclusion of educational quality as a major thrust of the United Nations Decade of Education for Sustainable Development (UNDESD) (UNESCO, 2004).
- Full Text:
- Date Issued: 2008