- Title
- Spectral properties and photophysical behaviour of water soluble cationic Mg (II) and Al (III) phthalocyanines
- Creator
- Idowu, Mopelola A
- Creator
- Arslanoğlu, Yasin
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 2014
- Date
- 2014
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/241549
- Identifier
- vital:50949
- Identifier
- xlink:href="https://doi.org/10.2478/s11532-013-0388-z"
- Description
- Peripherally and non-peripherally tetrasubstituted-[(N-methyl-2-pyridylthio)]phthalocyaninato magnesium (II) (5 and 6) and chloro aluminium (III) (7 and 8) tetraiodide have been synthesized and characterized. The photophysical properties of the complexes in dimethyl sulfoxide (DMSO) and aqueous medium in the presence and absence of cremophore EL have been studied. These complexes show high solubility in aqueous medium though they were aggregated. The triplet state quantum yields (FT) and the triplet lifetimes (tT) were found to be higher in DMSO with ΦT ranging from 0.32 to 0.51, while tT ranged from 282 to 622 ms in DMSO, compared to aqueous medium (pH 7.4 buffer) where ΦT ranged from 0.15 to 0.19 and tT from 26 to 35 ms. Addition of cremophore EL in aqueous solution resulted in partial disaggregation and increased photoactivity. The fluorescence lifetimes of the complexes showed strong dependence on their immediate environment. The ionic magnesium(II) and aluminium(III) phthalocyanines strongly bind to bovine serum albumin (BSA).
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (13 pages)
- Format
- Publisher
- SpringerLink
- Language
- English
- Relation
- Central European Journal of Chemistry
- Relation
- Idowu, M.A., Arslanoğlu, Y. and Nyokong, T., 2014. Spectral properties and photophysical behaviour of water soluble cationic Mg (II) and Al (III) phthalocyanines. Central European Journal of Chemistry, 12(3), pp.403-415
- Relation
- Central European Journal of Chemistry volume 12 number 3 p. 403 2014 1644-3624
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the SpringerLink Terms of Use Statement ( https://link.springer.com/termsandconditions)
- Rights
- Open Access
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Nyokong, Tebello (Distinguished Professor)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Spectral properties and photophysical behaviour.pdf | 1 MB | Adobe Acrobat PDF | View Details Download |