Photophysical properties of newly synthesized fluorinated zinc phthalocyanines in the presence of CdTe quantum dots and the accompanying energy transfer processes
- Erdoğmuş, Ali, Moeno, Sharon, Litwinski, Christian, Nyokong, Tebello
- Authors: Erdoğmuş, Ali , Moeno, Sharon , Litwinski, Christian , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262671 , vital:53543 , xlink:href="https://doi.org/10.1016/j.jphotochem.2009.12.014"
- Description: The photophysical properties of two newly synthesized phthalocyanines (Pcs) were studied in the presence and the absence of 3-mercaptopropionic acid (MPA) capped quantum dots (QDs). Energy transfer processes resulting from the combination of QDs and the Pcs: 4-(tetrakis-5-(trifluoromethyl)-2-mercaptopyridinephthalocyaninato)zinc(II) (TtfmMPyZnPc, 3) and 4-(tetrakis-5-(trifluoromethyl)-2-pyridyloxyphthalocyaninato) zinc(II) (TtfmPyZnPc, 4) were also studied. The photophysical properties of the Pcs in the presence of QDs were enhanced and Förster resonance energy transfer (FRET) was observed with the phthalocyanines used. The efficiency of FRET between the QDs and TtfmMPyZnPc and TtfmPyZnPc was found to be 0.31% and 0.45% in DMSO and 0.24% and 0.32% in pyridine, respectively. The triplet state quantum yields for TtfmMPyZnPc and TtfmPyZnPc were found to be 0.86 and 0.74 in DMSO and 0.83 and 0.76 in pyridine.
- Full Text:
- Date Issued: 2010
- Authors: Erdoğmuş, Ali , Moeno, Sharon , Litwinski, Christian , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262671 , vital:53543 , xlink:href="https://doi.org/10.1016/j.jphotochem.2009.12.014"
- Description: The photophysical properties of two newly synthesized phthalocyanines (Pcs) were studied in the presence and the absence of 3-mercaptopropionic acid (MPA) capped quantum dots (QDs). Energy transfer processes resulting from the combination of QDs and the Pcs: 4-(tetrakis-5-(trifluoromethyl)-2-mercaptopyridinephthalocyaninato)zinc(II) (TtfmMPyZnPc, 3) and 4-(tetrakis-5-(trifluoromethyl)-2-pyridyloxyphthalocyaninato) zinc(II) (TtfmPyZnPc, 4) were also studied. The photophysical properties of the Pcs in the presence of QDs were enhanced and Förster resonance energy transfer (FRET) was observed with the phthalocyanines used. The efficiency of FRET between the QDs and TtfmMPyZnPc and TtfmPyZnPc was found to be 0.31% and 0.45% in DMSO and 0.24% and 0.32% in pyridine, respectively. The triplet state quantum yields for TtfmMPyZnPc and TtfmPyZnPc were found to be 0.86 and 0.74 in DMSO and 0.83 and 0.76 in pyridine.
- Full Text:
- Date Issued: 2010
Applications of polymerized metal tetra-amino phthalocyanines towards hydrogen peroxide detection
- Mashazi, Philani N, Togo, Chumunorwa, Limson, Janice, Nyokong, Tebello
- Authors: Mashazi, Philani N , Togo, Chumunorwa , Limson, Janice , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261840 , vital:53451 , xlink:href="https://doi.org/10.1142/S1088424610001994"
- Description: This work reports the use of metallo tetra-amino phthalocyanines (MTAPc, M = Co and Mn) polymer thin films on gold and glassy carbon electrode surfaces for the detection and monitoring of hydrogen peroxide (H2O2). The polymer-modified electrodes were characterized using electrochemical and microscopic-based methods. Atomic force microscopy (AFM) was used to study the bare and polymer-modified ITO surfaces. The electrocatalytic reduction of H2O2 with glassy carbon polymer-modified electrodes gave higher current densities compared to their gold counterparts. The electroanalytical properties of H2O2 were obtained using a real-time calibration curve of the amperometric determination in pH 7.4 aqueous solution. The limits of detection (LoD) of the polymer-modified electrodes towards electroreduction of H2O2 were of the order of 10–7 M, with high sensitivity ranging from 6.0–15.4 mA.mM-1.cm-2.
- Full Text:
- Date Issued: 2010
- Authors: Mashazi, Philani N , Togo, Chumunorwa , Limson, Janice , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261840 , vital:53451 , xlink:href="https://doi.org/10.1142/S1088424610001994"
- Description: This work reports the use of metallo tetra-amino phthalocyanines (MTAPc, M = Co and Mn) polymer thin films on gold and glassy carbon electrode surfaces for the detection and monitoring of hydrogen peroxide (H2O2). The polymer-modified electrodes were characterized using electrochemical and microscopic-based methods. Atomic force microscopy (AFM) was used to study the bare and polymer-modified ITO surfaces. The electrocatalytic reduction of H2O2 with glassy carbon polymer-modified electrodes gave higher current densities compared to their gold counterparts. The electroanalytical properties of H2O2 were obtained using a real-time calibration curve of the amperometric determination in pH 7.4 aqueous solution. The limits of detection (LoD) of the polymer-modified electrodes towards electroreduction of H2O2 were of the order of 10–7 M, with high sensitivity ranging from 6.0–15.4 mA.mM-1.cm-2.
- Full Text:
- Date Issued: 2010
The effects of point of substitution on the formation of manganese phthalocyanine-based molecular materials
- Akinbulu, Isaac Adebayo, Khene, Samson, Nyokong, Tebello
- Authors: Akinbulu, Isaac Adebayo , Khene, Samson , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249103 , vital:51778 , xlink:href="https://doi.org/10.1016/j.tsf.2010.08.145"
- Description: Molecular films of manganese phthalocyanine (MnPc) complexes, tetra-substituted with 2-diethylaminoethanethio at the peripheral (Mn(OAc)-β-TDEAETPc, 1) and non-peripheral (Mn(OAc)-α-TDEAETPc, 2) positions were formed on glassy carbon electrode by electropolymerization and electrodeposition respectively. Atomic force microscopy images confirmed the presence of the films and revealed significant morphological differences. The films exhibited an electrocatalytic activity towards the oxidation of the insecticide, bendiocarb. Hydrodynamic technique, using rotating disc electrode voltammetry, was used to investigate the kinetics of electro-oxidation of the insecticide. Morphological differences of the films significantly influenced kinetic parameters. Values of Tafel slopes, obtained from Tafel plots, suggested that catalysis of bendiocarb occurred via outer sphere mechanism.
- Full Text:
- Date Issued: 2010
- Authors: Akinbulu, Isaac Adebayo , Khene, Samson , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249103 , vital:51778 , xlink:href="https://doi.org/10.1016/j.tsf.2010.08.145"
- Description: Molecular films of manganese phthalocyanine (MnPc) complexes, tetra-substituted with 2-diethylaminoethanethio at the peripheral (Mn(OAc)-β-TDEAETPc, 1) and non-peripheral (Mn(OAc)-α-TDEAETPc, 2) positions were formed on glassy carbon electrode by electropolymerization and electrodeposition respectively. Atomic force microscopy images confirmed the presence of the films and revealed significant morphological differences. The films exhibited an electrocatalytic activity towards the oxidation of the insecticide, bendiocarb. Hydrodynamic technique, using rotating disc electrode voltammetry, was used to investigate the kinetics of electro-oxidation of the insecticide. Morphological differences of the films significantly influenced kinetic parameters. Values of Tafel slopes, obtained from Tafel plots, suggested that catalysis of bendiocarb occurred via outer sphere mechanism.
- Full Text:
- Date Issued: 2010
Optical limiting properties of zinc phthalocyanines in solution and solid PMMA composite films
- Tekin, Sezen, Kürüm, Ulaş, Durmus, Mahmut, Yaglioglu, H Gul, Nyokong, Tebello, Elmali, Ayhan
- Authors: Tekin, Sezen , Kürüm, Ulaş , Durmus, Mahmut , Yaglioglu, H Gul , Nyokong, Tebello , Elmali, Ayhan
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249071 , vital:51775 , xlink:href="https://doi.org/10.1016/j.optcom.2010.07.003"
- Description: The nonlinear absorption and optical limiting (OL) performance of tetra- and octasubstituted zinc phthalocyanine complexes were described in solution and in the solid state using the open-aperture Z-scan technique. The measurements were performed using collimated 4 ns pulses generated from a frequency-doubled Nd:YAG laser at 532 nm wavelength. The polymeric films exhibit a much larger effective nonlinear absorption coefficient in comparison with solution. However, the parameters of the ratio of the excited to ground state absorption cross section and energy-dependent saturation in solution are much better compared to properties in the polymeric film. In terms of the ratio of the excited to ground state absorption cross section, the peripherally substituted complexes show better OL performance than the non-peripherally substituted derivative.
- Full Text:
- Date Issued: 2010
- Authors: Tekin, Sezen , Kürüm, Ulaş , Durmus, Mahmut , Yaglioglu, H Gul , Nyokong, Tebello , Elmali, Ayhan
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249071 , vital:51775 , xlink:href="https://doi.org/10.1016/j.optcom.2010.07.003"
- Description: The nonlinear absorption and optical limiting (OL) performance of tetra- and octasubstituted zinc phthalocyanine complexes were described in solution and in the solid state using the open-aperture Z-scan technique. The measurements were performed using collimated 4 ns pulses generated from a frequency-doubled Nd:YAG laser at 532 nm wavelength. The polymeric films exhibit a much larger effective nonlinear absorption coefficient in comparison with solution. However, the parameters of the ratio of the excited to ground state absorption cross section and energy-dependent saturation in solution are much better compared to properties in the polymeric film. In terms of the ratio of the excited to ground state absorption cross section, the peripherally substituted complexes show better OL performance than the non-peripherally substituted derivative.
- Full Text:
- Date Issued: 2010
The Scope of Teaching and Learning in Environmental Education
- Authors: Lotz-Sisitka, Heila
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183037 , vital:43906 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/172809"
- Description: Environmental Education involves a variety of teaching and learning processes which are diversely situated in a range of social and educational contexts. The diversity of scope is an interesting 'contour' of a field like environmental education. Contemporary environmental sciences and complexity studies draw our attention to an ever-changing world and to increasingly complex social-ecological issues, patterns and risks that require our attention. These too influence the scope of environmental education teaching and learning processes. This edition of the Southern African Journal of Environmental Education provides a window through which we may see some of the scope of environmental education activities, research questions, learning and teaching settings, and educational activity. It provides insight into the range of research methodologies that are being deployed to investigate the educational processes that are needed for re-orientation towards sustainability, equity, adaptability and transformation at the people-environment interface.
- Full Text: false
- Date Issued: 2010
- Authors: Lotz-Sisitka, Heila
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183037 , vital:43906 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/172809"
- Description: Environmental Education involves a variety of teaching and learning processes which are diversely situated in a range of social and educational contexts. The diversity of scope is an interesting 'contour' of a field like environmental education. Contemporary environmental sciences and complexity studies draw our attention to an ever-changing world and to increasingly complex social-ecological issues, patterns and risks that require our attention. These too influence the scope of environmental education teaching and learning processes. This edition of the Southern African Journal of Environmental Education provides a window through which we may see some of the scope of environmental education activities, research questions, learning and teaching settings, and educational activity. It provides insight into the range of research methodologies that are being deployed to investigate the educational processes that are needed for re-orientation towards sustainability, equity, adaptability and transformation at the people-environment interface.
- Full Text: false
- Date Issued: 2010
Fluorescence quenching and energy transfer in conjugates of quantum dots with zinc and indium tetraamino phthalocyanines
- Britton, Jonathan, Antunes, Edith M, Nyokong, Tebello
- Authors: Britton, Jonathan , Antunes, Edith M , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262638 , vital:53539 , xlink:href="https://doi.org/10.1016/j.jphotochem.2009.12.013"
- Description: CdTe QDs capped with mercapto propionic acid (MPA) and thioglycolic acid (TGA) were covalently linked to zinc and indium tetraaminophthalocyanines (TAPcs) using N-ethyl-N(3-dimethylaminopropyl) carbodiimide (EDC) and N-hydroxy succinimide (NHS) as the coupling agents. The results presented give evidence in favour of formation of an amide bond between the MTAPc and CdTe QDs. Both the linked ZnTAPc–QD complexes and the mixture of QDs and ZnTAPc (without chemical linking) showed Förster resonance energy transfer (FRET), whereas the QD interactions with InTAPc yielded no evidence of FRET. Both MTAPcs quenched the QDs emission, with quenching constants of the order of 103–104 M−1. High energy transfer efficiencies were obtained in some cases (as high as 93%), due to the low donor to acceptor distances.
- Full Text:
- Date Issued: 2010
- Authors: Britton, Jonathan , Antunes, Edith M , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262638 , vital:53539 , xlink:href="https://doi.org/10.1016/j.jphotochem.2009.12.013"
- Description: CdTe QDs capped with mercapto propionic acid (MPA) and thioglycolic acid (TGA) were covalently linked to zinc and indium tetraaminophthalocyanines (TAPcs) using N-ethyl-N(3-dimethylaminopropyl) carbodiimide (EDC) and N-hydroxy succinimide (NHS) as the coupling agents. The results presented give evidence in favour of formation of an amide bond between the MTAPc and CdTe QDs. Both the linked ZnTAPc–QD complexes and the mixture of QDs and ZnTAPc (without chemical linking) showed Förster resonance energy transfer (FRET), whereas the QD interactions with InTAPc yielded no evidence of FRET. Both MTAPcs quenched the QDs emission, with quenching constants of the order of 103–104 M−1. High energy transfer efficiencies were obtained in some cases (as high as 93%), due to the low donor to acceptor distances.
- Full Text:
- Date Issued: 2010
Fabrication and characterization of single walled carbon nanotubes-iron phthalocyanine nano-composite
- Akinbulu, Isaac A, Nyokong, Tebello
- Authors: Akinbulu, Isaac A , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262622 , vital:53537 , xlink:href="https://doi.org/10.1039/C0NJ00395F"
- Description: Nano-composite of single walled carbon nanotubes (SWCNTs) and iron phthalocyanine, peripherally tetra-substituted with diethylaminoethanethiol (complex 2), was fabricated and characterized by infra red (IR) spectroscopy, X-ray diffraction (XRD) and transmission electron microscopy (TEM). TEM technique gave a convincing image of the nano-composite. Self-assembled monolayer (SAM) film of the composite (SWCNT-2-SAM) was formed on gold electrode. Its surface properties were investigated, relative to that of 2-SAM film, by cyclic voltammetry and scanning electron microscopy (SEM). Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry, using [Fe(CN)6]3− as redox probe, were used to investigate the dynamics of electron transport in the SWCNT-2-SAM film. Lower charge transfer resistance, RCT, of the SWCNT-2-SAM modified Au electrode, relative to that of the 2-SAM modified Au electrode, was an indication of enhanced electron transport in the presence of SWCNT. The SAM film of the nano-composite showed better electrocatalytic behaviour, relative to that of 2-SAM film, towards the oxidation of the insecticide, carbofuran. The electrode (SWCNT-2-SAM) showed good selectivity for carbofuran, in the presence of diazinon (a non-electroactive interferent) and at lower concentration of the electroactive interferents (chlorpyrifos and dichlorfos).
- Full Text:
- Date Issued: 2010
- Authors: Akinbulu, Isaac A , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262622 , vital:53537 , xlink:href="https://doi.org/10.1039/C0NJ00395F"
- Description: Nano-composite of single walled carbon nanotubes (SWCNTs) and iron phthalocyanine, peripherally tetra-substituted with diethylaminoethanethiol (complex 2), was fabricated and characterized by infra red (IR) spectroscopy, X-ray diffraction (XRD) and transmission electron microscopy (TEM). TEM technique gave a convincing image of the nano-composite. Self-assembled monolayer (SAM) film of the composite (SWCNT-2-SAM) was formed on gold electrode. Its surface properties were investigated, relative to that of 2-SAM film, by cyclic voltammetry and scanning electron microscopy (SEM). Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry, using [Fe(CN)6]3− as redox probe, were used to investigate the dynamics of electron transport in the SWCNT-2-SAM film. Lower charge transfer resistance, RCT, of the SWCNT-2-SAM modified Au electrode, relative to that of the 2-SAM modified Au electrode, was an indication of enhanced electron transport in the presence of SWCNT. The SAM film of the nano-composite showed better electrocatalytic behaviour, relative to that of 2-SAM film, towards the oxidation of the insecticide, carbofuran. The electrode (SWCNT-2-SAM) showed good selectivity for carbofuran, in the presence of diazinon (a non-electroactive interferent) and at lower concentration of the electroactive interferents (chlorpyrifos and dichlorfos).
- Full Text:
- Date Issued: 2010
Handspring Puppet Company, Jane Taylor (Ed.)
- Authors: Krueger, Anton
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229658 , vital:49697 , xlink:href="https://0hdl.handle.net.wam.seals.ac.za/10520/EJC31088"
- Description: Handspring Puppet Company recently won three prestigious London awards (including the Olivier) for their design of the production War Horse, which is still running to great acclaim in the West End. This beautiful book has been released at exactly the right time, at a highpoint of an extraordinary company which has been producing astonishing work for 28 years already. It is an appropriate celebration of their many marvellous designs for 11 plays and two operas.
- Full Text:
- Date Issued: 2010
- Authors: Krueger, Anton
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229658 , vital:49697 , xlink:href="https://0hdl.handle.net.wam.seals.ac.za/10520/EJC31088"
- Description: Handspring Puppet Company recently won three prestigious London awards (including the Olivier) for their design of the production War Horse, which is still running to great acclaim in the West End. This beautiful book has been released at exactly the right time, at a highpoint of an extraordinary company which has been producing astonishing work for 28 years already. It is an appropriate celebration of their many marvellous designs for 11 plays and two operas.
- Full Text:
- Date Issued: 2010
Probing electrochemical and electrocatalytic properties of cobalt (II) and manganese (III) octakis (hexylthio) phthalocyanine as self-assembled monolayers
- Mashazi, Philani N, Antunes, Edith M, Nyokong, Tebello
- Authors: Mashazi, Philani N , Antunes, Edith M , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249115 , vital:51779 , xlink:href="https://doi.org/10.1142/S108842461000277X"
- Description: New peripherally (β) and non-peripherally (α) substituted metal octakis(hexylthio)phthalocyanines (β- and α-MOcHexTPc) containing cobalt and manganese as metal centers were synthesized. Their characterization using electrochemical methods showed that these complexes exhibit several redox processes at E1/2 (mV vs. Ag∣AgCl) = 380 (212) (I), 1140 (864) (II), -450 (-460) (III) and -1170 (-1304) (IV) for β- (α-) CoOcHexTPc. These redox processes were assigned to CoIIIPc-2/CoIIPc-2 (I), CoIIIPc-1/CoIIIPc-2 (II), CoIIPc-2/CoIPc-2 (III) and CoIPc-2/CoIPc-3 (IV) using spectroelectrochemistry. For the β- (α-) MnOcHexTPc complex the redox processes were observed at E1/2 (mV vs. Ag∣AgCl) = -20 (5) (I), -530 (-640) (II) and -1270 (-1380) (III) and were assigned to MnIIIPc-2/MnIIPc-2 (I), MnIIPc-2/MnIIPc-3 (II) and MnIIPc-3/MnIIPc-4 (III). Electrochemical and microscopic characterization using AFM showed that the self-assembled monolayers (SAMs) are formed on the gold surface using these complexes. The electrochemical characterization showed the blocking of the Faradaic processes at SAMs modified electrodes and these reactions are well-known to easily occur at unmodified gold electrodes. The AFM characterization showed an increase in surface roughness upon modifying the gold surface with MOcHexTPc SAMs, further confirming the presence of the monolayers on the gold surface. The MOcHexTPc SAMs were investigated for their electrocatalytic application towards H2O2 detection. The MOcHexTPc SAMs modified gold electrodes gave excellent currents for H2O2 detection. The observed H2O2 electrocatalytic reduction peaks were close to where the metal redox processes from the MOcHexTPc occurred, showing the involvement of the metal redox processes in the electrocatalytic mediation reactions.
- Full Text:
- Date Issued: 2010
- Authors: Mashazi, Philani N , Antunes, Edith M , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249115 , vital:51779 , xlink:href="https://doi.org/10.1142/S108842461000277X"
- Description: New peripherally (β) and non-peripherally (α) substituted metal octakis(hexylthio)phthalocyanines (β- and α-MOcHexTPc) containing cobalt and manganese as metal centers were synthesized. Their characterization using electrochemical methods showed that these complexes exhibit several redox processes at E1/2 (mV vs. Ag∣AgCl) = 380 (212) (I), 1140 (864) (II), -450 (-460) (III) and -1170 (-1304) (IV) for β- (α-) CoOcHexTPc. These redox processes were assigned to CoIIIPc-2/CoIIPc-2 (I), CoIIIPc-1/CoIIIPc-2 (II), CoIIPc-2/CoIPc-2 (III) and CoIPc-2/CoIPc-3 (IV) using spectroelectrochemistry. For the β- (α-) MnOcHexTPc complex the redox processes were observed at E1/2 (mV vs. Ag∣AgCl) = -20 (5) (I), -530 (-640) (II) and -1270 (-1380) (III) and were assigned to MnIIIPc-2/MnIIPc-2 (I), MnIIPc-2/MnIIPc-3 (II) and MnIIPc-3/MnIIPc-4 (III). Electrochemical and microscopic characterization using AFM showed that the self-assembled monolayers (SAMs) are formed on the gold surface using these complexes. The electrochemical characterization showed the blocking of the Faradaic processes at SAMs modified electrodes and these reactions are well-known to easily occur at unmodified gold electrodes. The AFM characterization showed an increase in surface roughness upon modifying the gold surface with MOcHexTPc SAMs, further confirming the presence of the monolayers on the gold surface. The MOcHexTPc SAMs were investigated for their electrocatalytic application towards H2O2 detection. The MOcHexTPc SAMs modified gold electrodes gave excellent currents for H2O2 detection. The observed H2O2 electrocatalytic reduction peaks were close to where the metal redox processes from the MOcHexTPc occurred, showing the involvement of the metal redox processes in the electrocatalytic mediation reactions.
- Full Text:
- Date Issued: 2010
Synthesis and photophysical properties of 1, 1′-binaphthol substituted phthalocyanines
- Canlica, Meylude, Nyokong, Tebello
- Authors: Canlica, Meylude , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249148 , vital:51782 , xlink:href="https://doi.org/10.1016/j.ica.2010.06.034"
- Description: We report on the synthesis, characterization and photophysical properties of a new symmetrically tetra substituted {at non-peripheral positions with tetra(1,1′-bi-binaphtoxy)} phthalocyanines containing H2, Mg(II), Al(III)Cl, Si(IV)Cl2 in the central cavity. The synthesized compounds were characterized by the elemental analyses, UV–Vis, FT-IR and 1H NMR spectroscopies. The fluorescence quantum yields, triplet quantum yields and lifetimes of the newly synthesized H2, Mg, Al, and Si phthalocyanines were explored. Triplet quantum yields ranged from 0.24 to 0.54. The triplet lifetime for the silicon phthalocyanine derivative was the highest ever reported for a phthalocyanine (∼3.5 ms).
- Full Text:
- Date Issued: 2010
- Authors: Canlica, Meylude , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249148 , vital:51782 , xlink:href="https://doi.org/10.1016/j.ica.2010.06.034"
- Description: We report on the synthesis, characterization and photophysical properties of a new symmetrically tetra substituted {at non-peripheral positions with tetra(1,1′-bi-binaphtoxy)} phthalocyanines containing H2, Mg(II), Al(III)Cl, Si(IV)Cl2 in the central cavity. The synthesized compounds were characterized by the elemental analyses, UV–Vis, FT-IR and 1H NMR spectroscopies. The fluorescence quantum yields, triplet quantum yields and lifetimes of the newly synthesized H2, Mg, Al, and Si phthalocyanines were explored. Triplet quantum yields ranged from 0.24 to 0.54. The triplet lifetime for the silicon phthalocyanine derivative was the highest ever reported for a phthalocyanine (∼3.5 ms).
- Full Text:
- Date Issued: 2010
Photoelectrochemical characterization of electrodeposited ZnO thin films sensitized by octacarboxymetallophthalocyanine derivatives
- Idowu, Mopelola, Loewenstein, Thomas, Hastall, Andreas, Nyokong, Tebello, Schlettwein, Derck
- Authors: Idowu, Mopelola , Loewenstein, Thomas , Hastall, Andreas , Nyokong, Tebello , Schlettwein, Derck
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262655 , vital:53541 , xlink:href="https://doi.org/10.1142/S1088424610001854"
- Description: Hybrid thin films of crystalline zinc oxide (ZnO) modified by different octacarboxymetallophthalocyanines (MOCPc) were prepared by the readsorption method. Homogeneously blue or green thin films were formed. The photoelectrochemical characteristics of the electrodes were studied by time-resolved photocurrent measurements. Zinc(II) 2,3,9,10,16,17,23,24-octacarboxyphthalocyanine (ZnOCPc) showed considerably large quantum efficiency in sensitization of ZnO, one of the highest quantum efficiencies obtained so far with phthalocyanine-type sensitizers on nanocrystalline ZnO films.
- Full Text:
- Date Issued: 2010
- Authors: Idowu, Mopelola , Loewenstein, Thomas , Hastall, Andreas , Nyokong, Tebello , Schlettwein, Derck
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262655 , vital:53541 , xlink:href="https://doi.org/10.1142/S1088424610001854"
- Description: Hybrid thin films of crystalline zinc oxide (ZnO) modified by different octacarboxymetallophthalocyanines (MOCPc) were prepared by the readsorption method. Homogeneously blue or green thin films were formed. The photoelectrochemical characteristics of the electrodes were studied by time-resolved photocurrent measurements. Zinc(II) 2,3,9,10,16,17,23,24-octacarboxyphthalocyanine (ZnOCPc) showed considerably large quantum efficiency in sensitization of ZnO, one of the highest quantum efficiencies obtained so far with phthalocyanine-type sensitizers on nanocrystalline ZnO films.
- Full Text:
- Date Issued: 2010
Synthetic pathways to water-soluble phthalocyanines and close analogs
- Dumoulin, Fabienne, Durmus, Mahmut, Ahsen, Vefa, Nyokong, Tebello
- Authors: Dumoulin, Fabienne , Durmus, Mahmut , Ahsen, Vefa , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249082 , vital:51776 , xlink:href="https://doi.org/10.1016/j.ccr.2010.05.002"
- Description: The different types of water-soluble phthalocyanines are presented and their synthesis is reviewed.
- Full Text:
- Date Issued: 2010
- Authors: Dumoulin, Fabienne , Durmus, Mahmut , Ahsen, Vefa , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249082 , vital:51776 , xlink:href="https://doi.org/10.1016/j.ccr.2010.05.002"
- Description: The different types of water-soluble phthalocyanines are presented and their synthesis is reviewed.
- Full Text:
- Date Issued: 2010
Electrochemical, spectroscopic and microscopic studies of new manganese phthalocyanine complexes in solution and as self-assembled monolayers on gold
- Coates, Megan, Antunes, Edith M, Nyokong, Tebello
- Authors: Coates, Megan , Antunes, Edith M , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261144 , vital:53363 , xlink:href="https://doi.org/10.1142/S1088424610002471"
- Description: Four new manganese(III) phthalocyanines (3a–d), octasubstituted at the peripheral position with pentylthio, decylthio, benzylthio, and phenylthio groups, respectively, were synthesized. Their specific electrochemical, spectroscopic and microscopic properties in solution and as self-assembled monolayers on gold were characterized. The UV-vis spectra confirmed red-shifted Q bands for all the complexes, due to the effect of the central metal and the electron-donating substituents. Three redox couples were visible during cyclic voltammetry studies for the four complexes, and spectroelectrochemistry confirmed the couples as corresponding to MnIIIPc-2/MnIIPc-2 (II) (metal reduction), MnIIPc-2/MnIIPc-3 (III) (ring reduction) and MnIIIPc-1/MnIIIPc-2 (I) (ring oxidation). Electrochemistry was also used to determine the blocking characteristics of the MnPc self-assembled monolayers on gold, which proved to be highly dependent on the type of substituent. Other methods of characterization included Raman spectroscopy, atomic force and scanning electrochemical microscopy analyses of the SAMs.
- Full Text:
- Date Issued: 2010
- Authors: Coates, Megan , Antunes, Edith M , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261144 , vital:53363 , xlink:href="https://doi.org/10.1142/S1088424610002471"
- Description: Four new manganese(III) phthalocyanines (3a–d), octasubstituted at the peripheral position with pentylthio, decylthio, benzylthio, and phenylthio groups, respectively, were synthesized. Their specific electrochemical, spectroscopic and microscopic properties in solution and as self-assembled monolayers on gold were characterized. The UV-vis spectra confirmed red-shifted Q bands for all the complexes, due to the effect of the central metal and the electron-donating substituents. Three redox couples were visible during cyclic voltammetry studies for the four complexes, and spectroelectrochemistry confirmed the couples as corresponding to MnIIIPc-2/MnIIPc-2 (II) (metal reduction), MnIIPc-2/MnIIPc-3 (III) (ring reduction) and MnIIIPc-1/MnIIIPc-2 (I) (ring oxidation). Electrochemistry was also used to determine the blocking characteristics of the MnPc self-assembled monolayers on gold, which proved to be highly dependent on the type of substituent. Other methods of characterization included Raman spectroscopy, atomic force and scanning electrochemical microscopy analyses of the SAMs.
- Full Text:
- Date Issued: 2010
Remarkable sensitivity for detection of bisphenol A on a gold electrode modified with nickel tetraamino phthalocyanine containing Ni–O–Ni bridges
- Chauke, Vongani, Matemadombo, Fungisai, Nyokong, Tebello
- Authors: Chauke, Vongani , Matemadombo, Fungisai , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261280 , vital:53380 , xlink:href="https://doi.org/10.1016/j.jhazmat.2010.01.061"
- Description: This work reports the electrocatalysis of bisphenol A on Ni(II) tetraamino metallophthalocyanine (NiTAPc) polymer modified gold electrode containing Ni–O–Ni bridges (represented as Ni(OH)TAPc). The Ni(II)TAPc films were electro-transformed in 0.1 mol L−1 NaOH aqueous solution to form ‘O–Ni–O oxo bridges’, forming poly-n-Ni(OH)TAPc (where n is the number of polymerising scans). poly-30-Ni(OH)TAPc, poly-50-Ni(OH)TAPc, poly-70-Ni(OH)TAPc and poly-90-Ni(OH)TAPc films were investigated. The polymeric films were characterised by electrochemical impedance spectroscopy and the charge transfer resistance (RCT) values increased with film thickness. The best catalytic activity for the detection of bisphenol A was on poly-70-Ni(OH)TAPc. Electrode resistance to passivation improved with polymer thickness. The electrocatalytic behaviour of bisphenol A was compared to that of p-nitrophenol in terms of electrode passivation and regeneration. The latter was found to passivate the electrode less than the former. The poly-70-Ni(OH)TAPc modified electrode could reliably detect bisphenol A in a concentration range of 7 × 10−4 to 3 × 10−2 mol L−1 with a limit of detection of 3.68 × 10−9 mol L−1. The sensitivity was 3.26 × 10−4 A mol−1 L cm−2.
- Full Text:
- Date Issued: 2010
- Authors: Chauke, Vongani , Matemadombo, Fungisai , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261280 , vital:53380 , xlink:href="https://doi.org/10.1016/j.jhazmat.2010.01.061"
- Description: This work reports the electrocatalysis of bisphenol A on Ni(II) tetraamino metallophthalocyanine (NiTAPc) polymer modified gold electrode containing Ni–O–Ni bridges (represented as Ni(OH)TAPc). The Ni(II)TAPc films were electro-transformed in 0.1 mol L−1 NaOH aqueous solution to form ‘O–Ni–O oxo bridges’, forming poly-n-Ni(OH)TAPc (where n is the number of polymerising scans). poly-30-Ni(OH)TAPc, poly-50-Ni(OH)TAPc, poly-70-Ni(OH)TAPc and poly-90-Ni(OH)TAPc films were investigated. The polymeric films were characterised by electrochemical impedance spectroscopy and the charge transfer resistance (RCT) values increased with film thickness. The best catalytic activity for the detection of bisphenol A was on poly-70-Ni(OH)TAPc. Electrode resistance to passivation improved with polymer thickness. The electrocatalytic behaviour of bisphenol A was compared to that of p-nitrophenol in terms of electrode passivation and regeneration. The latter was found to passivate the electrode less than the former. The poly-70-Ni(OH)TAPc modified electrode could reliably detect bisphenol A in a concentration range of 7 × 10−4 to 3 × 10−2 mol L−1 with a limit of detection of 3.68 × 10−9 mol L−1. The sensitivity was 3.26 × 10−4 A mol−1 L cm−2.
- Full Text:
- Date Issued: 2010
Photophysical and photochemical properties of Ni (II), Pd (II) and Pt (II) aryloxo and alkylthio derivatised phthalocyanine
- Ogunbayo, Taofeek B, Nyokong, Tebello
- Authors: Ogunbayo, Taofeek B , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261511 , vital:53416 , xlink:href="https://doi.org/10.1016/j.molstruc.2010.03.047"
- Description: Several aryloxo (3a–6a and 3b–6b) and alkylthio (3d and 3e) derivatised phthalocyanines were synthesized, characterized and the photochemical and photophysical properties investigated along with those of the previously reported (3c–5c, 4d, 5d, 4e and 5e) complexes. The effects of open-shell metals (Ni(II), Pd(II) and Pt(II)) on the photophysical and photochemical properties of the phthalocyanine ligands were investigated. Palladium and platinum improved the triplet quantum yield and singlet oxygen generation capacities of the unmetalated phthalocyanines (3a–3e) making their complexes candidates for further investigation in photocatalysis. Ni(II)Pc analogues gave poor results compared with their Pd(II)Pc and Pt(II)Pc counterparts.
- Full Text:
- Date Issued: 2010
- Authors: Ogunbayo, Taofeek B , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261511 , vital:53416 , xlink:href="https://doi.org/10.1016/j.molstruc.2010.03.047"
- Description: Several aryloxo (3a–6a and 3b–6b) and alkylthio (3d and 3e) derivatised phthalocyanines were synthesized, characterized and the photochemical and photophysical properties investigated along with those of the previously reported (3c–5c, 4d, 5d, 4e and 5e) complexes. The effects of open-shell metals (Ni(II), Pd(II) and Pt(II)) on the photophysical and photochemical properties of the phthalocyanine ligands were investigated. Palladium and platinum improved the triplet quantum yield and singlet oxygen generation capacities of the unmetalated phthalocyanines (3a–3e) making their complexes candidates for further investigation in photocatalysis. Ni(II)Pc analogues gave poor results compared with their Pd(II)Pc and Pt(II)Pc counterparts.
- Full Text:
- Date Issued: 2010
Production of and trade in African indigenous vegetables in the urban and peri-urban areas of Durban, South Africa
- Shackleton, Charlie M, Paumgartner, Fiona, Mthembu, Thami, Ernst, Lisa, Pasquini, Margaret W, Pichop, Germain
- Authors: Shackleton, Charlie M , Paumgartner, Fiona , Mthembu, Thami , Ernst, Lisa , Pasquini, Margaret W , Pichop, Germain
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181134 , vital:43701 , xlink:href="https://doi.org/10.1080/0376835X.2010.498937"
- Description: This paper reports on the farming and trade of lesser known crops, here termed African indigenous vegetables (AIVs), in the Durban metropole. Most households grow AIVs, and collect them from the wild, primarily for home consumption. Modal income from sale was approximately R30 per month per farmer, most of whom were middle-aged to elderly females, with limited education, who had been cultivating AIVs here for many years. The main constraints to greater sales were deemed to be low market demand and adverse climate. The commonest AIVs grown were pumpkin leaves, taro and amaranth. Although most farmers sold very little, there is a thriving retail trade in AIVs. Generally, retailers were females, but younger and more educated than the farmers. The majority viewed retailing as a full-time occupation. Modal income for retailers was R450 per month, but included non-AIV produce. Most of the traders thought there was insufficient market demand for AIVs.
- Full Text:
- Date Issued: 2010
- Authors: Shackleton, Charlie M , Paumgartner, Fiona , Mthembu, Thami , Ernst, Lisa , Pasquini, Margaret W , Pichop, Germain
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181134 , vital:43701 , xlink:href="https://doi.org/10.1080/0376835X.2010.498937"
- Description: This paper reports on the farming and trade of lesser known crops, here termed African indigenous vegetables (AIVs), in the Durban metropole. Most households grow AIVs, and collect them from the wild, primarily for home consumption. Modal income from sale was approximately R30 per month per farmer, most of whom were middle-aged to elderly females, with limited education, who had been cultivating AIVs here for many years. The main constraints to greater sales were deemed to be low market demand and adverse climate. The commonest AIVs grown were pumpkin leaves, taro and amaranth. Although most farmers sold very little, there is a thriving retail trade in AIVs. Generally, retailers were females, but younger and more educated than the farmers. The majority viewed retailing as a full-time occupation. Modal income for retailers was R450 per month, but included non-AIV produce. Most of the traders thought there was insufficient market demand for AIVs.
- Full Text:
- Date Issued: 2010
The synthesis and fluorescence behaviour of phthalocyanines unsymmetrically substituted with naphthol and carboxy groups
- Nombona, Nolwazi, Antunes, Edith M, Nyokong, Tebello
- Authors: Nombona, Nolwazi , Antunes, Edith M , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261534 , vital:53418 , xlink:href="https://doi.org/10.1016/j.dyepig.2009.11.010"
- Description: Unsymmetrically substituted phthalocyanines 8,15,22-tris-(naphtho)-2-(carboxy)phthalocyanine, [8,15,22-tris-(naphtho)-2-(carboxy)phthalocyanato]zinc(II), 8,15,22-tris-(naphtho)-4,5-(3-carboxy-1,2-dioxyphenyl)phthalocyanine and [8,15,22-tris-(naphtho)-4,5-(3-carboxy-1,2-dioxyphenoxy)phthalocyanato]zinc(II) were prepared using the mixed phthalonitrile cyclotetramerization of 3-(1-naphthoxy) phthalonitrile with a carboxylic acid phthalonitrile. The phthalocyanines were separated using column chromatography employing a mixture of THF, ammonia and water. The novel compounds were characterized using UV–Vis, IR, 1H NMR and mass spectrometry as well as elemental analysis. Fluorescence quantum yields were found to range from 0.05 to 0.16.
- Full Text:
- Date Issued: 2010
- Authors: Nombona, Nolwazi , Antunes, Edith M , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261534 , vital:53418 , xlink:href="https://doi.org/10.1016/j.dyepig.2009.11.010"
- Description: Unsymmetrically substituted phthalocyanines 8,15,22-tris-(naphtho)-2-(carboxy)phthalocyanine, [8,15,22-tris-(naphtho)-2-(carboxy)phthalocyanato]zinc(II), 8,15,22-tris-(naphtho)-4,5-(3-carboxy-1,2-dioxyphenyl)phthalocyanine and [8,15,22-tris-(naphtho)-4,5-(3-carboxy-1,2-dioxyphenoxy)phthalocyanato]zinc(II) were prepared using the mixed phthalonitrile cyclotetramerization of 3-(1-naphthoxy) phthalonitrile with a carboxylic acid phthalonitrile. The phthalocyanines were separated using column chromatography employing a mixture of THF, ammonia and water. The novel compounds were characterized using UV–Vis, IR, 1H NMR and mass spectrometry as well as elemental analysis. Fluorescence quantum yields were found to range from 0.05 to 0.16.
- Full Text:
- Date Issued: 2010
Fashionably ethnic
- Authors: Krueger, Anton
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229567 , vital:49688 , xlink:href="https://doi.org/10.1080/1013929X.2010.9678333"
- Description: This essay highlights a shift in South African literature towards ideals of individualism and explores some of the paradoxes inherent in the competing claims of individuality and heritage. The characters created by Greig Coetzee in Happy Natives are examined as examples of identities constructed in terms of tradition, function and indoctrination. The comic potential of these incongruent identity constructions is then elaborated by means of Henri Bergson’s description of the humour arising from an inability to adapt to changing fashions. Ultimately, appeals towards tradition and individuality begin to look like similar proposals.
- Full Text:
- Date Issued: 2010
- Authors: Krueger, Anton
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229567 , vital:49688 , xlink:href="https://doi.org/10.1080/1013929X.2010.9678333"
- Description: This essay highlights a shift in South African literature towards ideals of individualism and explores some of the paradoxes inherent in the competing claims of individuality and heritage. The characters created by Greig Coetzee in Happy Natives are examined as examples of identities constructed in terms of tradition, function and indoctrination. The comic potential of these incongruent identity constructions is then elaborated by means of Henri Bergson’s description of the humour arising from an inability to adapt to changing fashions. Ultimately, appeals towards tradition and individuality begin to look like similar proposals.
- Full Text:
- Date Issued: 2010
The use and appreciation of botanical gardens as urban green spaces in South Africa
- Ward, Catherine D, Parker, Caitlin M, Shackleton, Charlie M
- Authors: Ward, Catherine D , Parker, Caitlin M , Shackleton, Charlie M
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181146 , vital:43702 , xlink:href="https://doi.org/10.1016/j.ufug.2009.11.001"
- Description: There are few formal studies on the contribution of botanical gardens as urban green spaces, particularly within developing countries. Therefore, this paper reports on an assessment of the use and appreciation of botanical gardens as urban green spaces in South Africa. Users and staff were surveyed in six national botanical gardens. The gardens provided numerous benefits in terms of conservation, education and recreation. However, the people using the gardens were not demographically representative of the general population of the surrounding city or town. Generally, most of the visitors were middle- to old-aged, well-educated professionals with medium to high incomes. Most were white and English was their home language. There was an even gender representation. Most visited only a few times per year. The majority of users visited the gardens for recreation and psychological reasons rather than educational ones. However, the staff of each garden placed emphasis on education in the gardens and amongst surrounding schools. Most visitors appreciated the conservation dimensions of botanical gardens, and felt that there was insufficient public green space in their town or city. Understanding how people perceive and use the botanical gardens of South Africa is important to inform future research and strategies regarding the conservation of urban green space within a developing country.
- Full Text:
- Date Issued: 2010
- Authors: Ward, Catherine D , Parker, Caitlin M , Shackleton, Charlie M
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181146 , vital:43702 , xlink:href="https://doi.org/10.1016/j.ufug.2009.11.001"
- Description: There are few formal studies on the contribution of botanical gardens as urban green spaces, particularly within developing countries. Therefore, this paper reports on an assessment of the use and appreciation of botanical gardens as urban green spaces in South Africa. Users and staff were surveyed in six national botanical gardens. The gardens provided numerous benefits in terms of conservation, education and recreation. However, the people using the gardens were not demographically representative of the general population of the surrounding city or town. Generally, most of the visitors were middle- to old-aged, well-educated professionals with medium to high incomes. Most were white and English was their home language. There was an even gender representation. Most visited only a few times per year. The majority of users visited the gardens for recreation and psychological reasons rather than educational ones. However, the staff of each garden placed emphasis on education in the gardens and amongst surrounding schools. Most visitors appreciated the conservation dimensions of botanical gardens, and felt that there was insufficient public green space in their town or city. Understanding how people perceive and use the botanical gardens of South Africa is important to inform future research and strategies regarding the conservation of urban green space within a developing country.
- Full Text:
- Date Issued: 2010
'I won't be squeezed into someone else's frame': Stories of supervisor selection
- Harrison, Liz, McKenna, Sioux, Searle, Ruth
- Authors: Harrison, Liz , McKenna, Sioux , Searle, Ruth
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187395 , vital:44629 , xlink:href="https://hdl.handle.net/10520/EJC15100"
- Description: Using a collection of stories from a group of women who belong to a PhD support group, this article tracks the issue of choosing a supervisor. These women are all academics and therefore had some claim to an "insider" status but as novice researchers they were also "outsiders". Their discussions around how and why they chose their supervisors highlight issues often underplayed or ignored in textbooks on postgraduate supervision. In particular, this article examines issues of knowledge, embodied subjectivity and power by following three questions that arise from the data : whose knowing is important; who should I be, and whose PhD is it?
- Full Text:
- Date Issued: 2010
- Authors: Harrison, Liz , McKenna, Sioux , Searle, Ruth
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187395 , vital:44629 , xlink:href="https://hdl.handle.net/10520/EJC15100"
- Description: Using a collection of stories from a group of women who belong to a PhD support group, this article tracks the issue of choosing a supervisor. These women are all academics and therefore had some claim to an "insider" status but as novice researchers they were also "outsiders". Their discussions around how and why they chose their supervisors highlight issues often underplayed or ignored in textbooks on postgraduate supervision. In particular, this article examines issues of knowledge, embodied subjectivity and power by following three questions that arise from the data : whose knowing is important; who should I be, and whose PhD is it?
- Full Text:
- Date Issued: 2010