A comparison of conventional and ultrasonic seams in swimwear
- Authors: Tyalana, Nommiselo
- Date: 2018
- Subjects: Textile finishing , Textile finishing agents Seams (Sewing) Textile fabrics Textile fibers Textile design
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/36727 , vital:34048
- Description: Ultrasonic welding technology is a relatively new technology in apparel construction, this research forms part of a study to assess its effectiveness as a joining technology that can be used in ladies swimwear. The ultimate aim was to determine whether the ultrasonic welding joining technique could be successfully used in assembling ladies swimwear garments, comprising only synthetic fibres, namely polyester/Lycra, polyamide/Lycra, polyamide/Lycra power-net and polyamide/Lycra mesh warp knitted fabrics. These specific swimwear fabrics were selected since they comprise 100% thermoplastic synthetic fibres, considered ideal for ultrasonic welding. This study essentially compares and contrasts the performance of two seam joining techniques: namely conventional sewing and ultrasonic welding, in terms of seam strength, when used in the above mentioned four fabrics. Conventionally sewn and ultrasonically welded seams were produced, straight and curved, in both the wale and course directions of the fabrics. The conventionally sewn seams were produced using two sewing machines; namely an overlocker, also known as a mock safety sewing machine, and a cover seam machines. All conventionally sewn seams were stitched and tested under similar conditions. The ultrasonic welded seams were produced using three different wheels, a Medium Male Knurled pattern wheel, a Staggered Triple Stitch pattern wheel and a Single Stitch pattern wheel. The amplitude and speed of the welding machine, during the ultrasonic seaming, were kept constant, except when welding the polyamide/Lycra power-net and the polyamide/Lycra mesh fabrics when the pressure had to be drastically reduced in order to avoid excessively softened seams. The results of the study are presented in the form of line charts, scatter charts and tables. The ultrasonic welded seams, joined with the Medium Male Knurled wheel, exhibited surface waviness, as opposed to those joined with the Staggered Triple Stitch wheel which were smooth. It was found that, in terms of seam strength, the ultrasonic seams produced with the Single Stitch and Medium Male Knurled pattern wheels out performed those produced with the Staggered Triple Stitch wheels. The polyester/Lycra fabric was found easier to handle during the ultrasonic seaming process than the polyamide/Lycra fabric, although the strength of the ultrasonic seams in the polyester/Lycra fabric did not differ consistently from those of the polyamide/Lycra fabric. It was found that the conventional sewn seams were consistently stronger, and had a better appearance, than the ultrasonic welded seams. Although some promising results were obtained, in terms of the strength of the ultrasonic welded seams, the results overall were far too variable, inconsistent and unsatisfactory for this technique of seaming to be recommended at this stage for any of the swimwear fabrics covered. Further, more in depth, studies are required in order to gain a better understating of the effect of the various ultrasonic seaming parameters, as well as fabric parameters on ultrasonic seam strength and consistency.
- Full Text:
- Date Issued: 2018
- Authors: Tyalana, Nommiselo
- Date: 2018
- Subjects: Textile finishing , Textile finishing agents Seams (Sewing) Textile fabrics Textile fibers Textile design
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/36727 , vital:34048
- Description: Ultrasonic welding technology is a relatively new technology in apparel construction, this research forms part of a study to assess its effectiveness as a joining technology that can be used in ladies swimwear. The ultimate aim was to determine whether the ultrasonic welding joining technique could be successfully used in assembling ladies swimwear garments, comprising only synthetic fibres, namely polyester/Lycra, polyamide/Lycra, polyamide/Lycra power-net and polyamide/Lycra mesh warp knitted fabrics. These specific swimwear fabrics were selected since they comprise 100% thermoplastic synthetic fibres, considered ideal for ultrasonic welding. This study essentially compares and contrasts the performance of two seam joining techniques: namely conventional sewing and ultrasonic welding, in terms of seam strength, when used in the above mentioned four fabrics. Conventionally sewn and ultrasonically welded seams were produced, straight and curved, in both the wale and course directions of the fabrics. The conventionally sewn seams were produced using two sewing machines; namely an overlocker, also known as a mock safety sewing machine, and a cover seam machines. All conventionally sewn seams were stitched and tested under similar conditions. The ultrasonic welded seams were produced using three different wheels, a Medium Male Knurled pattern wheel, a Staggered Triple Stitch pattern wheel and a Single Stitch pattern wheel. The amplitude and speed of the welding machine, during the ultrasonic seaming, were kept constant, except when welding the polyamide/Lycra power-net and the polyamide/Lycra mesh fabrics when the pressure had to be drastically reduced in order to avoid excessively softened seams. The results of the study are presented in the form of line charts, scatter charts and tables. The ultrasonic welded seams, joined with the Medium Male Knurled wheel, exhibited surface waviness, as opposed to those joined with the Staggered Triple Stitch wheel which were smooth. It was found that, in terms of seam strength, the ultrasonic seams produced with the Single Stitch and Medium Male Knurled pattern wheels out performed those produced with the Staggered Triple Stitch wheels. The polyester/Lycra fabric was found easier to handle during the ultrasonic seaming process than the polyamide/Lycra fabric, although the strength of the ultrasonic seams in the polyester/Lycra fabric did not differ consistently from those of the polyamide/Lycra fabric. It was found that the conventional sewn seams were consistently stronger, and had a better appearance, than the ultrasonic welded seams. Although some promising results were obtained, in terms of the strength of the ultrasonic welded seams, the results overall were far too variable, inconsistent and unsatisfactory for this technique of seaming to be recommended at this stage for any of the swimwear fabrics covered. Further, more in depth, studies are required in order to gain a better understating of the effect of the various ultrasonic seaming parameters, as well as fabric parameters on ultrasonic seam strength and consistency.
- Full Text:
- Date Issued: 2018
A congestion aware ant colony optimisation-based routing and wavelength assignment algorithm for transparent flexi-grid optical burst switched networks
- Authors: Oladipo, Joshua Femi
- Date: 2018
- Subjects: Ants -- Behavior -- Mathematical models , Distributed algorithms
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/34733 , vital:33432
- Description: Optical Burst Switching (OBS) over transparent exi-grid optical networks, is considered a potential solution to the increasing pressure on backbone networks due to the increase in internet use and widespread adoption of various high bandwidth applications. Both technologies allow for more e cient usage of a networks resources. However, transmissions over exi-grid networks are more susceptible to optical impairments than transmissions made over xed-grid networks, and OBS suers from high burst loss due to contention. These issues need to be solved in order to reap the full benets of both technologies. An open issue for OBS whose solution would mitigate both issues is the Routing and Wavelength Assignment (RWA) algorithm. Ant Colony Optimisation (ACO) is a method of interest for solving the RWA problem on OBS networks. This study aims to improve on current dynamic ACO-based solutions to the Routing and Wavelength Assignment problem on transparent exi-grid Optical Burst Switched networks.
- Full Text:
- Date Issued: 2018
- Authors: Oladipo, Joshua Femi
- Date: 2018
- Subjects: Ants -- Behavior -- Mathematical models , Distributed algorithms
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/34733 , vital:33432
- Description: Optical Burst Switching (OBS) over transparent exi-grid optical networks, is considered a potential solution to the increasing pressure on backbone networks due to the increase in internet use and widespread adoption of various high bandwidth applications. Both technologies allow for more e cient usage of a networks resources. However, transmissions over exi-grid networks are more susceptible to optical impairments than transmissions made over xed-grid networks, and OBS suers from high burst loss due to contention. These issues need to be solved in order to reap the full benets of both technologies. An open issue for OBS whose solution would mitigate both issues is the Routing and Wavelength Assignment (RWA) algorithm. Ant Colony Optimisation (ACO) is a method of interest for solving the RWA problem on OBS networks. This study aims to improve on current dynamic ACO-based solutions to the Routing and Wavelength Assignment problem on transparent exi-grid Optical Burst Switched networks.
- Full Text:
- Date Issued: 2018
A seismic characterization of the crustal structure underlying the offshore Natal valley within the south-west Indian Ocean
- Authors: Moorcroft, David
- Date: 2018
- Subjects: Seismology , Seismology -- Kwa Zulu Natal -- Research Coasts -- Kwa Zulu Natal
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/22387 , vital:29965
- Description: The Natal Valley is a ~1000 km long, elongated depression in the seafloor, located within the south-west Indian Ocean, between the coastline of south-east Africa and the offshore aseismic Mozambique Ridge. Knowledge of its present-day crustal structure is important to reconstruct the Gondwana supercontinent break-up history and the concurrent opening of the Indian Ocean, which started during the Jurassic, some ~180 – 150 million years ago. Major geological events relating to this supercontinent break-up including continental rifting, magmatism, the emplacement of extensive oceanic flood basalt as submarine plateaus, vertical processes associated with tectonic uplift, flexural subsidence of the margin and relative global sea-level change are recorded within the crust underlying the south-west Indian Ocean. Although these events have been well modelled, fundamental questions remain regarding the nature and tectonic structure of the crust. Today, the Natal Valley region represents a frontier for geophysical exploration. Early attempts at imaging the crust beneath the seafloor within the south-west Indian Ocean made use of now primitive seismic reflection data acquisition and processing techniques available to them at the time (1960’s - 1970’s). Considering the advancements made in marine seismic reflection imaging, these vintage datasets lacked the horizontal and vertical resolution necessary to most accurately account for and describe features of the upper crust underlying the northern Natal Valley. This study is based on the acquisition, processing and preliminary interpretation of a newly acquired, regional seismic reflection profile, Profile Mz5-007, acquired across the northernmost region of the Natal Valley during the PAMELA-Moz5 cruise in 2016. The methods of marine seismic reflection data acquisition, processing and interpretation are described. The seismic reflection data presented in this dissertation provides a regional-scaled appraisal of the upper crust underlying the northern Natal Valley for the first time. The imagery allows a comprehensive description of crustal structures and features from the very northern Natal Valley, close to the Mozambique coastline, southwards into the southern Natal Valley offshore of Durban. The findings presented here support the notion that the crust underlying the northern Natal Valley experienced roughly N-S orientated trans-tensional stresses in relation to the breakup of West Gondwana. At least two major phases of volcanism are imaged within the seismic stratigraphy. The lower-most event underlies the Limpopo Fan in the northernmost regions of the Natal Valley at a depth of 2 seconds TWT and is interpreted as a seismic expression of the upper surface of the Lower – Middle Jurassic Karoo LIP. The progressive disappearance of this horizon towards the south coincides with the emergence of a second, overlying, as yet unreported volcanic horizon, which extends southwards throughout the Natal Valley. On the basis of its regional distribution, spatial relationship with the underlying event boundary and its deformation history, this volcanic horizon is interpreted to represent a series of basaltic lava outpourings during the Lower Cretaceous, initiated in response to trans-tensional crustal deformation associated with the breakup of West Gondwana. In addition to these two major phases of flood basalt outpouring, a number of localized volcanic flows are imaged throughout the stratigraphy, most notably over the Central Terrace. In addition, at least four major unconformities are identified, all of which are well developed within the Limpopo Fan. One of these is interpreted to represent the well-developed Mid-Cretaceous hiatus in sedimentation, providing a relative seismo-stratigraphic constraint to overlying and underlying seismic units. A review of the structural elements of the crust reveals how the northern Natal Valley is partitioned into two sub-basins separated by a prominent basement high, the Central Terrace, imaged across the central portions of Profile Mz5-007. To the north of the Central Terrace, structural deformation appears largely extensional, characterized by a large (~37 km wide) asymmetrical depression directly to the north of the Central Terrace and only minor structural faulting. To the south of the Central Terrace, trans-tensional stresses associated with withdrawal of the Falkland Malvinas Plateau have deformed the upper crust into a series of apparently southwards tilted crustal blocks, producing a series of deep (3.5 s TWT) half graben-like structures, within which syn-rift fill has an apparent dip towards the south. There is evidence to suggest ongoing reactivation of these fault structures. This zone of deformation is shown to bear resemblances to the faulting mapped onshore of the Kwa-Zulu Natal coastline, providing reason to consider the two regions as a continuous zone of deformation associated with the withdrawal of the Falkland-Malvinas Plateau during the breakup of West Gondwana. Furthermore, a number of post-sedimentary intrusive features are imaged, the largest of which is the Naude Ridge; a large pinnacle-like feature which has penetrated the upper crust towards the southern limit of the profile. This feature corresponds to an abrupt change in seafloor depth and upper crustal structure, suggesting that this feature may mark the transition between subsided continental crust interpreted to underlie the northern Natal Valley to the north and oceanic crust known to underlie the southern Natal Valley to the south.
- Full Text:
- Date Issued: 2018
- Authors: Moorcroft, David
- Date: 2018
- Subjects: Seismology , Seismology -- Kwa Zulu Natal -- Research Coasts -- Kwa Zulu Natal
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/22387 , vital:29965
- Description: The Natal Valley is a ~1000 km long, elongated depression in the seafloor, located within the south-west Indian Ocean, between the coastline of south-east Africa and the offshore aseismic Mozambique Ridge. Knowledge of its present-day crustal structure is important to reconstruct the Gondwana supercontinent break-up history and the concurrent opening of the Indian Ocean, which started during the Jurassic, some ~180 – 150 million years ago. Major geological events relating to this supercontinent break-up including continental rifting, magmatism, the emplacement of extensive oceanic flood basalt as submarine plateaus, vertical processes associated with tectonic uplift, flexural subsidence of the margin and relative global sea-level change are recorded within the crust underlying the south-west Indian Ocean. Although these events have been well modelled, fundamental questions remain regarding the nature and tectonic structure of the crust. Today, the Natal Valley region represents a frontier for geophysical exploration. Early attempts at imaging the crust beneath the seafloor within the south-west Indian Ocean made use of now primitive seismic reflection data acquisition and processing techniques available to them at the time (1960’s - 1970’s). Considering the advancements made in marine seismic reflection imaging, these vintage datasets lacked the horizontal and vertical resolution necessary to most accurately account for and describe features of the upper crust underlying the northern Natal Valley. This study is based on the acquisition, processing and preliminary interpretation of a newly acquired, regional seismic reflection profile, Profile Mz5-007, acquired across the northernmost region of the Natal Valley during the PAMELA-Moz5 cruise in 2016. The methods of marine seismic reflection data acquisition, processing and interpretation are described. The seismic reflection data presented in this dissertation provides a regional-scaled appraisal of the upper crust underlying the northern Natal Valley for the first time. The imagery allows a comprehensive description of crustal structures and features from the very northern Natal Valley, close to the Mozambique coastline, southwards into the southern Natal Valley offshore of Durban. The findings presented here support the notion that the crust underlying the northern Natal Valley experienced roughly N-S orientated trans-tensional stresses in relation to the breakup of West Gondwana. At least two major phases of volcanism are imaged within the seismic stratigraphy. The lower-most event underlies the Limpopo Fan in the northernmost regions of the Natal Valley at a depth of 2 seconds TWT and is interpreted as a seismic expression of the upper surface of the Lower – Middle Jurassic Karoo LIP. The progressive disappearance of this horizon towards the south coincides with the emergence of a second, overlying, as yet unreported volcanic horizon, which extends southwards throughout the Natal Valley. On the basis of its regional distribution, spatial relationship with the underlying event boundary and its deformation history, this volcanic horizon is interpreted to represent a series of basaltic lava outpourings during the Lower Cretaceous, initiated in response to trans-tensional crustal deformation associated with the breakup of West Gondwana. In addition to these two major phases of flood basalt outpouring, a number of localized volcanic flows are imaged throughout the stratigraphy, most notably over the Central Terrace. In addition, at least four major unconformities are identified, all of which are well developed within the Limpopo Fan. One of these is interpreted to represent the well-developed Mid-Cretaceous hiatus in sedimentation, providing a relative seismo-stratigraphic constraint to overlying and underlying seismic units. A review of the structural elements of the crust reveals how the northern Natal Valley is partitioned into two sub-basins separated by a prominent basement high, the Central Terrace, imaged across the central portions of Profile Mz5-007. To the north of the Central Terrace, structural deformation appears largely extensional, characterized by a large (~37 km wide) asymmetrical depression directly to the north of the Central Terrace and only minor structural faulting. To the south of the Central Terrace, trans-tensional stresses associated with withdrawal of the Falkland Malvinas Plateau have deformed the upper crust into a series of apparently southwards tilted crustal blocks, producing a series of deep (3.5 s TWT) half graben-like structures, within which syn-rift fill has an apparent dip towards the south. There is evidence to suggest ongoing reactivation of these fault structures. This zone of deformation is shown to bear resemblances to the faulting mapped onshore of the Kwa-Zulu Natal coastline, providing reason to consider the two regions as a continuous zone of deformation associated with the withdrawal of the Falkland-Malvinas Plateau during the breakup of West Gondwana. Furthermore, a number of post-sedimentary intrusive features are imaged, the largest of which is the Naude Ridge; a large pinnacle-like feature which has penetrated the upper crust towards the southern limit of the profile. This feature corresponds to an abrupt change in seafloor depth and upper crustal structure, suggesting that this feature may mark the transition between subsided continental crust interpreted to underlie the northern Natal Valley to the north and oceanic crust known to underlie the southern Natal Valley to the south.
- Full Text:
- Date Issued: 2018
An appraisal of warm temperate mangrove estuaries as food patches using zooplankton and RNA: DNA ratios of Gilchristella aestuaria larvae as indicators
- Authors: Bornman, Eugin
- Date: 2018
- Subjects: Mangrove swamps Fishes -- Larvae , Mangrove ecology , Zooplankton
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/17908 , vital:28481
- Description: Mangrove habitats are considered as the ideal fish nursery as they are known to increase the growth and survival of juvenile fishes by providing enhanced food availability and protection. However, most studies have focused on tropical mangroves with a few recent warm temperate studies finding conflicting results. Furthermore, the nursery value of South African mangroves to fishes remain understudied in subtropical areas, while warm temperate mangroves are yet to be evaluated. This study aimed to assess whether mangrove presence leads to any advantage to the larvae of an important estuarine resident fish species, Gilchristella aestuaria, by comparing the food patch quality of South African warm temperate mangrove and non-mangrove estuaries. Results indicate that larvae fed primarily on the dominant prey species, Pseudodiaptomus hessei, Paracrtia longipatella, and Acartiella natalensis. However, postflexion larvae consumed more of the larger species, P. hessei, within the two mangrove estuaries (16.09 %V in Nahoon and 13.79 %V in Xhora) than the two nonmangrove estuaries (12.20 %V in Gonubie and 7.05 %V in Qora), despite other prey species occurring at similar densities. Results indicate that mangrove habitats acted as sediment sinks, slightly reducing the turbidity of these estuaries which resulted in postflexion larvae actively selecting larger, more nutritious prey, which in turn, significantly increased their individual instantaneous growth rates (0.11 ± 0.21 Gi) when compared to postflexion larvae in non-mangrove estuaries (0.09 ± 0.12 Gi). This study found that mangrove presence was significantly related to postflexion larval densities when coupled with abiotic (such as temperature and turbidity) and biotic factors (such as predator-prey interactions). Understanding the spatial and temporal dynamics, predator-prey interactions as well as the growth and survival of G. aestuaria is particularly important as they are key zooplanktivores that are prey to other species in estuarine food webs.
- Full Text:
- Date Issued: 2018
- Authors: Bornman, Eugin
- Date: 2018
- Subjects: Mangrove swamps Fishes -- Larvae , Mangrove ecology , Zooplankton
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/17908 , vital:28481
- Description: Mangrove habitats are considered as the ideal fish nursery as they are known to increase the growth and survival of juvenile fishes by providing enhanced food availability and protection. However, most studies have focused on tropical mangroves with a few recent warm temperate studies finding conflicting results. Furthermore, the nursery value of South African mangroves to fishes remain understudied in subtropical areas, while warm temperate mangroves are yet to be evaluated. This study aimed to assess whether mangrove presence leads to any advantage to the larvae of an important estuarine resident fish species, Gilchristella aestuaria, by comparing the food patch quality of South African warm temperate mangrove and non-mangrove estuaries. Results indicate that larvae fed primarily on the dominant prey species, Pseudodiaptomus hessei, Paracrtia longipatella, and Acartiella natalensis. However, postflexion larvae consumed more of the larger species, P. hessei, within the two mangrove estuaries (16.09 %V in Nahoon and 13.79 %V in Xhora) than the two nonmangrove estuaries (12.20 %V in Gonubie and 7.05 %V in Qora), despite other prey species occurring at similar densities. Results indicate that mangrove habitats acted as sediment sinks, slightly reducing the turbidity of these estuaries which resulted in postflexion larvae actively selecting larger, more nutritious prey, which in turn, significantly increased their individual instantaneous growth rates (0.11 ± 0.21 Gi) when compared to postflexion larvae in non-mangrove estuaries (0.09 ± 0.12 Gi). This study found that mangrove presence was significantly related to postflexion larval densities when coupled with abiotic (such as temperature and turbidity) and biotic factors (such as predator-prey interactions). Understanding the spatial and temporal dynamics, predator-prey interactions as well as the growth and survival of G. aestuaria is particularly important as they are key zooplanktivores that are prey to other species in estuarine food webs.
- Full Text:
- Date Issued: 2018
An investigation of the movement of sediment through the Noordhoek headland bypass dunefield system at Cape Recife, South Africa
- Authors: Goosen, Gerrit Pieter
- Date: 2018
- Subjects: Sedimentation and deposition , Fluvial geomorphology Geomorphology Sand dunes -- Environmental aspects
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/22101 , vital:29840
- Description: A detailed study of the movement of sediment across the Cape Recife headland via the Noordhoek headland bypass dunefield was conducted. The Noordhoek HBD is important because of the environmental impacts anticipated on the sewerage works, settling ponds, and road to the Cape Recife lighthouse situated in the migration path of the dunefield to the ENE of its active boundary. The primary objective of the study was to investigate the movement of sediment in and through the Noordhoek HBD system. This study has provided sand transportation and dune migration rates by making use of various dune monitoring techniques. In doing so, useful predictions have been made as to when the settling ponds and the road to the lighthouse will be inundated. An indication has also been given as to how much sand moves through the system. Some key findings from this research included: the net migration direction of the Noordhoek HBD was found to be towards the east-north-east; the wind environment at the study area was classified as a high energy wind environment; this study has highlighted that various climatic factors such as rainfall and temperature influence the movement of sediment through dune systems; sediment transport was found to be directly related to the source area and topography; the central zone of the dunefield proved to be a groundwater recharge zone for the western and eastern zones; and the leading lobes of the migrating Noordhoek dunefield are gradually covering stabilising vegetation by pulses of dunes moving through. In this study, it was calculated that presently a total volume of about 26 000 m3 of sand is migrating into the vegetation at the leading lobes annually. If the Noordhoek HBD is left to run its natural course and migrate across the Cape Recife headland to the downwind beach, an approximate volume of 26 000 m3 of sand could be supplied to the downwind beach by this system. In doing so, it has the potential to play a role in replenishing some of the sand to Port Elizabeth’s eroded southern beaches via a natural process.
- Full Text:
- Date Issued: 2018
- Authors: Goosen, Gerrit Pieter
- Date: 2018
- Subjects: Sedimentation and deposition , Fluvial geomorphology Geomorphology Sand dunes -- Environmental aspects
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/22101 , vital:29840
- Description: A detailed study of the movement of sediment across the Cape Recife headland via the Noordhoek headland bypass dunefield was conducted. The Noordhoek HBD is important because of the environmental impacts anticipated on the sewerage works, settling ponds, and road to the Cape Recife lighthouse situated in the migration path of the dunefield to the ENE of its active boundary. The primary objective of the study was to investigate the movement of sediment in and through the Noordhoek HBD system. This study has provided sand transportation and dune migration rates by making use of various dune monitoring techniques. In doing so, useful predictions have been made as to when the settling ponds and the road to the lighthouse will be inundated. An indication has also been given as to how much sand moves through the system. Some key findings from this research included: the net migration direction of the Noordhoek HBD was found to be towards the east-north-east; the wind environment at the study area was classified as a high energy wind environment; this study has highlighted that various climatic factors such as rainfall and temperature influence the movement of sediment through dune systems; sediment transport was found to be directly related to the source area and topography; the central zone of the dunefield proved to be a groundwater recharge zone for the western and eastern zones; and the leading lobes of the migrating Noordhoek dunefield are gradually covering stabilising vegetation by pulses of dunes moving through. In this study, it was calculated that presently a total volume of about 26 000 m3 of sand is migrating into the vegetation at the leading lobes annually. If the Noordhoek HBD is left to run its natural course and migrate across the Cape Recife headland to the downwind beach, an approximate volume of 26 000 m3 of sand could be supplied to the downwind beach by this system. In doing so, it has the potential to play a role in replenishing some of the sand to Port Elizabeth’s eroded southern beaches via a natural process.
- Full Text:
- Date Issued: 2018
Application of hidden Markov models and their extensions to animal movement data
- Authors: Van Niekerk, Bracken
- Date: 2018
- Subjects: Markov processes Animal locomotion Time-series analysis
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/23835 , vital:30624
- Description: Hidden Markov Models (HMMs) have become increasingly popular in animal movement studies as they provide a flexible modelling approach and take the correlation between successive observations into account. They can segment the movement paths into latent states, which can be considered as rough proxies for the behaviours of the animals. This study comprises of two sections, both involving the application of HMMs to large terrestrial mammal movement data. Usually step lengths representing the displacement distances between successive observations, turning angles measuring the tortuosity, or a bivariate input of both variables are used as inputs in the models. It has been found in the literature that the turning angle is either included in the modelling process or it is excluded without much justification for doing so. The first part of this study investigates the nfluence of the turning angle on the model output and resultant interpretations of the HMMs when modelling the trajectories of large terrestrial mammals in southern Africa. Results revealed at different time scales, and for both predator and herbivore species in this study, that the turning angle does not influence the state allocation of the HMMs, which is the main output in terms of interpreting the behaviours of the animals. It is thought in most cases that the inclusion of the turning angle overcomplicates the models unnecessarily without contributing any additional information in terms of the behavioural interpretations or improving the overall fit of the models. This was found for the variety of movements of the species under observation in this study. The second part of this study attempts to validate the state allocation of the HMMs fitted to eland trajectories in the Greater Addo Elephant National Park in the Eastern Cape, with the use of camera trap data. This presented a unique opportunity as this type of data is mainly used for abundance or capture-recapture studies, and the HMMs are rarely validated as the true behaviours of the animals are seldom known. Results revealed that the same diel patterns were detected by the HMMs that were shown by the classified camera trap data. Direct comparisons of the observations where the dates and times matched for the telemetry and camera trap data could be done in several rare instances, which revealed many similarities. Although it was not an ideal comparison, the camera trap data provided a rough validation of the state allocation of the HMMs used in the study.
- Full Text:
- Date Issued: 2018
- Authors: Van Niekerk, Bracken
- Date: 2018
- Subjects: Markov processes Animal locomotion Time-series analysis
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/23835 , vital:30624
- Description: Hidden Markov Models (HMMs) have become increasingly popular in animal movement studies as they provide a flexible modelling approach and take the correlation between successive observations into account. They can segment the movement paths into latent states, which can be considered as rough proxies for the behaviours of the animals. This study comprises of two sections, both involving the application of HMMs to large terrestrial mammal movement data. Usually step lengths representing the displacement distances between successive observations, turning angles measuring the tortuosity, or a bivariate input of both variables are used as inputs in the models. It has been found in the literature that the turning angle is either included in the modelling process or it is excluded without much justification for doing so. The first part of this study investigates the nfluence of the turning angle on the model output and resultant interpretations of the HMMs when modelling the trajectories of large terrestrial mammals in southern Africa. Results revealed at different time scales, and for both predator and herbivore species in this study, that the turning angle does not influence the state allocation of the HMMs, which is the main output in terms of interpreting the behaviours of the animals. It is thought in most cases that the inclusion of the turning angle overcomplicates the models unnecessarily without contributing any additional information in terms of the behavioural interpretations or improving the overall fit of the models. This was found for the variety of movements of the species under observation in this study. The second part of this study attempts to validate the state allocation of the HMMs fitted to eland trajectories in the Greater Addo Elephant National Park in the Eastern Cape, with the use of camera trap data. This presented a unique opportunity as this type of data is mainly used for abundance or capture-recapture studies, and the HMMs are rarely validated as the true behaviours of the animals are seldom known. Results revealed that the same diel patterns were detected by the HMMs that were shown by the classified camera trap data. Direct comparisons of the observations where the dates and times matched for the telemetry and camera trap data could be done in several rare instances, which revealed many similarities. Although it was not an ideal comparison, the camera trap data provided a rough validation of the state allocation of the HMMs used in the study.
- Full Text:
- Date Issued: 2018
Assessing growth response patterns of microalgae to varying environmental conditions using sediments from ephemeral wetlands
- Authors: Mazwane, Sixolile
- Date: 2018
- Subjects: Microalgae -- South Africa , Wetland conservation -- South Africa Landscape ecology -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/22398 , vital:29966
- Description: Ephemeral wetlands serve as habitats for different fauna and flora. Microalgae make up a bulk of primary production in newly inundated wetlands and have a big influence on the aquatic community structure. As ephemeral wetlands have cyclical drying and wetting phases, algal species found in these habitats have evolved adaptations (i.e. dormancy and cysts) to survive during dry periods and become productive upon inundation. Algae have been used as ecological indicators in many aquatic ecosystems including wetlands, particularly associated with water quality and with varying inundation states. Whilst temperature and water level have been shown to affect microalgal biomass independently, this study aims to assess the effects of these two factors simultaneously on microalgal biomass, species diversity and community changes. The aim of the study was to investigate microalgal dynamics using two ephemeral wetlands in the Nelson Mandela Bay Municipality. The growth response patterns of microalgal communities to varying temperatures and inundation levels through experiments using dry temporary wetland sediments was also assessed. Dry sediments were collected from two depression wetlands with different sediment characteristics (1592 and Elephant Wallow (EW)). The study consisted of replicated treatments with three different surface area: volume ratios (SA:V) (Low surface area: volume (LSAV), Medium (MSAV) and High (HSAV)), inundated with distilled water. The microcosms were placed inside a Conviron environmental growth chamber and illuminated at between 106 to 138 μmol.m-2s-1, with a 12:12 light-dark cycle at constant temperatures of 12 °C (mean winter) and 22 °C (mean summer). Physicochemical data were recorded, and biological samples were collected every 4 days over a 28-day inundation period. In the field, Electrical conductivity (EC) and pH showed a gradual increase over the inundation period. The systems were well oxygenated (6-10 mg L-1). Overall, phytoplankton biomass in the field was ~10 μg L-1 whereas benthic biomass (MPB) was significantly higher 10 – 300 mg L-1. Within the experiments, the phytoplankton biomass showed a pattern while MPB biomass increased gradually for both experiments. There were no significant (p>0.05) differences between the 1592 and EW phytoplankton biomass. However, the MPB biomass showed significant (p<0.05) differences between the two sediments (EW high, 1592 low) and the experiments, respectively. In the winter experiment, the 1592 sediment had high phytoplankton biomass compared to EW, the reverse was observed for the MPB biomass. In summer experiment, similar results were observed in terms of phytoplankton biomass. For the MPBs, 1592 had greater biomass for all treatments compared to EW. The phytoplankton community for both field samples and experiments was dominated by chlorophytes (>50 %), followed by cyanophytes and euglenophytes (with cryptophytes in summer experiment) for both field and experiments. The MPB community was dominated by bacillariophytes (55 %) and chlorophytes (25 %) in the 1592 sediments and this was also the case with EW sediments bacillariophytes (70 %), although cyanophytes (15 %) made up the remainder of the MPB community. The 1592 sediments supported higher diatom abundances under the HSAV compared to the same treatment from the EW wetland suggesting that possibly grain size or texture might be responsible. In contrast, sediments from EW under LSAV conditions showed higher diatom cell numbers possibly indicating that increased water depth has the propensity to support greater diatom assemblages compared with the same water level for sediments from 1592. The results indicate that microalgae community is influenced by sediment type more than it is by water level. From this study it was also established that microalgae were able to reemerge from their dormancy state upon inundation and that tank experiments were successful in simulating natural ephemeral wetland conditions. The findings from this study will add to the available baseline data on microalgal dynamics in the ephemeral wetlands in South Africa, especially in semi-arid areas. This information can be valuable in enhancing our understanding regarding the role of microalgae in ephemeral wetlands in order to conserve them.
- Full Text:
- Date Issued: 2018
- Authors: Mazwane, Sixolile
- Date: 2018
- Subjects: Microalgae -- South Africa , Wetland conservation -- South Africa Landscape ecology -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/22398 , vital:29966
- Description: Ephemeral wetlands serve as habitats for different fauna and flora. Microalgae make up a bulk of primary production in newly inundated wetlands and have a big influence on the aquatic community structure. As ephemeral wetlands have cyclical drying and wetting phases, algal species found in these habitats have evolved adaptations (i.e. dormancy and cysts) to survive during dry periods and become productive upon inundation. Algae have been used as ecological indicators in many aquatic ecosystems including wetlands, particularly associated with water quality and with varying inundation states. Whilst temperature and water level have been shown to affect microalgal biomass independently, this study aims to assess the effects of these two factors simultaneously on microalgal biomass, species diversity and community changes. The aim of the study was to investigate microalgal dynamics using two ephemeral wetlands in the Nelson Mandela Bay Municipality. The growth response patterns of microalgal communities to varying temperatures and inundation levels through experiments using dry temporary wetland sediments was also assessed. Dry sediments were collected from two depression wetlands with different sediment characteristics (1592 and Elephant Wallow (EW)). The study consisted of replicated treatments with three different surface area: volume ratios (SA:V) (Low surface area: volume (LSAV), Medium (MSAV) and High (HSAV)), inundated with distilled water. The microcosms were placed inside a Conviron environmental growth chamber and illuminated at between 106 to 138 μmol.m-2s-1, with a 12:12 light-dark cycle at constant temperatures of 12 °C (mean winter) and 22 °C (mean summer). Physicochemical data were recorded, and biological samples were collected every 4 days over a 28-day inundation period. In the field, Electrical conductivity (EC) and pH showed a gradual increase over the inundation period. The systems were well oxygenated (6-10 mg L-1). Overall, phytoplankton biomass in the field was ~10 μg L-1 whereas benthic biomass (MPB) was significantly higher 10 – 300 mg L-1. Within the experiments, the phytoplankton biomass showed a pattern while MPB biomass increased gradually for both experiments. There were no significant (p>0.05) differences between the 1592 and EW phytoplankton biomass. However, the MPB biomass showed significant (p<0.05) differences between the two sediments (EW high, 1592 low) and the experiments, respectively. In the winter experiment, the 1592 sediment had high phytoplankton biomass compared to EW, the reverse was observed for the MPB biomass. In summer experiment, similar results were observed in terms of phytoplankton biomass. For the MPBs, 1592 had greater biomass for all treatments compared to EW. The phytoplankton community for both field samples and experiments was dominated by chlorophytes (>50 %), followed by cyanophytes and euglenophytes (with cryptophytes in summer experiment) for both field and experiments. The MPB community was dominated by bacillariophytes (55 %) and chlorophytes (25 %) in the 1592 sediments and this was also the case with EW sediments bacillariophytes (70 %), although cyanophytes (15 %) made up the remainder of the MPB community. The 1592 sediments supported higher diatom abundances under the HSAV compared to the same treatment from the EW wetland suggesting that possibly grain size or texture might be responsible. In contrast, sediments from EW under LSAV conditions showed higher diatom cell numbers possibly indicating that increased water depth has the propensity to support greater diatom assemblages compared with the same water level for sediments from 1592. The results indicate that microalgae community is influenced by sediment type more than it is by water level. From this study it was also established that microalgae were able to reemerge from their dormancy state upon inundation and that tank experiments were successful in simulating natural ephemeral wetland conditions. The findings from this study will add to the available baseline data on microalgal dynamics in the ephemeral wetlands in South Africa, especially in semi-arid areas. This information can be valuable in enhancing our understanding regarding the role of microalgae in ephemeral wetlands in order to conserve them.
- Full Text:
- Date Issued: 2018
Assessment of indigenous forest degradation and deforestation along the wild coast, near Port St John’s, Eastern Cape Province, South Africa
- Katende, Lukyamuzi Lucky Fulgentius
- Authors: Katende, Lukyamuzi Lucky Fulgentius
- Date: 2018
- Subjects: Deforestation -- South Africa -- Eastern Cape , Forest degradation -- South Africa -- Eastern Cape Forest management -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/30649 , vital:31006
- Description: Indigenous forests along the Wild Coast of the Eastern Cape Province have experienced both degradation and deforestation over the past decades. In early 2000, steps were taken to rehabilitate some of the degraded areas. Nevertheless, there is no monitoring mechanism in place, so little is known about the extent of degradation and impact of the rehabilitation efforts. The present study assesses the extent to which deforestation and degradation of the indigenous forests have occurred, and evaluates rehabilitation efforts in the study area around Port Saint John’s. Forest degradation was defined as the decrease in forest cover density while deforestation was defined as an increase in the trend of light forests and/ or a decrease in dense forests. The details for this study were obtained from multi – temporal remotely sensed data for a period between 1982 and 2013 (31 years). Multi-temporal Landsat satellite imagery for 1982, 1986, 1989, 2002, 2009 and 2013 was acquired and analysed. On the basis of prior knowledge of the area, the supervised classification approach was used. The Maximum likelihood supervised classification technique was used to extract information from satellite data. The classified images were filtered using a majority filtering procedure to reduce noise. Google Earth (Astrium) ancillary images were used to refine the classification based on expert rules. The derived changes in the degraded and rehabilitated areas were further validated through field visits. The overall image classification accuracy generated from Landsat image data ranged from 80% to 90%. It was noted that the area of dense forest almost doubled between 1986 and 1989, coinciding with a 59% decrease in the light forest. Subsequently, dense forests increased by 14,820 ha while light forests decreased by 16,690 ha between 1989 and 2002. The subsequent reduction in light forest coverage is explained by the establishment of the Participatory Forest Management (PFMA) approach by Department of Water Affairs and Forestry (DWAF) which reversed the degradation trend. However, specific degradation hotspots were identified, particularly where new settlements have been established. The emergence of the non-vegetated area increased gradually from 7% in 1986 to 23.4% in 2013. Notably, dense forest was observed to have experienced higher rates of forest degradation and deforestation than the light forest. The highest number patches were 4 recorded between 2002 and 1998, followed by between 2010 and 2013 and lastly 1986. Based on spatial connectedness of patches, the year 1986 had the highest landscape connectedness of forest vegetation (CONAT = 35.3) followed by 2002 and 1996 while the year 2010 and 2013 had the lowest landscape contiguity. Over the study period, the distribution of patches clearly shows that forest degradation and deforestation rates were lower in the years 1986, 1998 and tremendously increased in the later period of between 2010 and 2013. However, as a result of rehabilitation efforts, dense forest was seen to steadily gain more land than light forest. Finer details of degradation trends could not be easily picked from the images used in the study, given their spatial resolution limitations. That notwithstanding, the trends identified are good for overview decisions. The study has also established that de-agraianisation, forest restoration and rehabilitation greatly contributed to increased forest cover. Therefore, with more use of GIS by forest managers, and imagery of the high resolution being readily available, forests will in future be easily monitored using remote sensing.
- Full Text:
- Date Issued: 2018
- Authors: Katende, Lukyamuzi Lucky Fulgentius
- Date: 2018
- Subjects: Deforestation -- South Africa -- Eastern Cape , Forest degradation -- South Africa -- Eastern Cape Forest management -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/30649 , vital:31006
- Description: Indigenous forests along the Wild Coast of the Eastern Cape Province have experienced both degradation and deforestation over the past decades. In early 2000, steps were taken to rehabilitate some of the degraded areas. Nevertheless, there is no monitoring mechanism in place, so little is known about the extent of degradation and impact of the rehabilitation efforts. The present study assesses the extent to which deforestation and degradation of the indigenous forests have occurred, and evaluates rehabilitation efforts in the study area around Port Saint John’s. Forest degradation was defined as the decrease in forest cover density while deforestation was defined as an increase in the trend of light forests and/ or a decrease in dense forests. The details for this study were obtained from multi – temporal remotely sensed data for a period between 1982 and 2013 (31 years). Multi-temporal Landsat satellite imagery for 1982, 1986, 1989, 2002, 2009 and 2013 was acquired and analysed. On the basis of prior knowledge of the area, the supervised classification approach was used. The Maximum likelihood supervised classification technique was used to extract information from satellite data. The classified images were filtered using a majority filtering procedure to reduce noise. Google Earth (Astrium) ancillary images were used to refine the classification based on expert rules. The derived changes in the degraded and rehabilitated areas were further validated through field visits. The overall image classification accuracy generated from Landsat image data ranged from 80% to 90%. It was noted that the area of dense forest almost doubled between 1986 and 1989, coinciding with a 59% decrease in the light forest. Subsequently, dense forests increased by 14,820 ha while light forests decreased by 16,690 ha between 1989 and 2002. The subsequent reduction in light forest coverage is explained by the establishment of the Participatory Forest Management (PFMA) approach by Department of Water Affairs and Forestry (DWAF) which reversed the degradation trend. However, specific degradation hotspots were identified, particularly where new settlements have been established. The emergence of the non-vegetated area increased gradually from 7% in 1986 to 23.4% in 2013. Notably, dense forest was observed to have experienced higher rates of forest degradation and deforestation than the light forest. The highest number patches were 4 recorded between 2002 and 1998, followed by between 2010 and 2013 and lastly 1986. Based on spatial connectedness of patches, the year 1986 had the highest landscape connectedness of forest vegetation (CONAT = 35.3) followed by 2002 and 1996 while the year 2010 and 2013 had the lowest landscape contiguity. Over the study period, the distribution of patches clearly shows that forest degradation and deforestation rates were lower in the years 1986, 1998 and tremendously increased in the later period of between 2010 and 2013. However, as a result of rehabilitation efforts, dense forest was seen to steadily gain more land than light forest. Finer details of degradation trends could not be easily picked from the images used in the study, given their spatial resolution limitations. That notwithstanding, the trends identified are good for overview decisions. The study has also established that de-agraianisation, forest restoration and rehabilitation greatly contributed to increased forest cover. Therefore, with more use of GIS by forest managers, and imagery of the high resolution being readily available, forests will in future be easily monitored using remote sensing.
- Full Text:
- Date Issued: 2018
Assessment of the microalgal community structure and biomass in surface waterbodies of the Eastern Cape Karoo region earmarked for shale gas exploration
- Authors: Roussouw, Natasha Kimberlee
- Date: 2018
- Subjects: Fresh water -- Eastern Cape , Water-supply -- South Africa -- Eastern Cape Water-supply, Rural -- South Africa -- Eastern Cape Constructed wetlands Watershed management
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/35234 , vital:33655
- Description: The Eastern Cape Karoo region of South Africa typically displays low rainfall and high temperatures, which is particularly concerning considering the shale gas exploration/extraction project proposed recently. Almost 90% of the fracking fluid consists of water and with the Karoo region already classified as a water-stressed region, the increased demand for freshwater for fracking could put further pressure on water resources of the region. By understanding the ecological functioning of the lower trophic levels, likely implications for higher trophic levels can be determined, and ultimately, recommendations for mitigation actions can be made. Here, observations aimed at understanding the dynamics of lower trophic levels are presented, that is, the microalgal biomass and assemblage composition within three characteristic surface waterbodies of the region. In addition, the work focuses on the smaller, more dynamic temporary wetland systems typical of this water-scarce region, with the aim of understanding the significance of single species macrophyte cover in relation to the lower trophic levels. Thirty-three waterbodies were sampled (natural depressions = 13, dams = 9, rivers = 11) during November 2014 (austral spring) and April 2015 (austral autumn). Waterbody physico-chemistry, hydro-morphometry, habitat cover and surrounding land-use, as well as microalgal biomass and assemblage composition within each waterbody type were measured. Thirteen natural depression wetlands were sampled during October 2015, December 2015 and March 2016. Once again, waterbody physico-chemistry, microalgal biomass and assemblage composition were measured. However, in addition, Schoenoplectus decipiens macrophyte cover and microalgal (diatom) species composition were also determined. In general, no significant differences in microalgal biomass between the three main waterbody types of the Eastern Cape Karoo region were found; however, the different waterbody types each displayed distinct microalgal assemblage compositions. Also, Schoenoplectus decipiens cover had negligible effects on microalgal biomass and assemblages in the temporary wetlands investigated here. These results suggest that the generalist nature of species occupying these systems allows them to adapt to the ever-changing conditions typical of this region. Ongoing monitoring initiatives considering impending hydraulic fracturing activities should include a comprehensive species-level diversity census, which could further inform management of any impacts associated with this potential disturbance.
- Full Text:
- Date Issued: 2018
- Authors: Roussouw, Natasha Kimberlee
- Date: 2018
- Subjects: Fresh water -- Eastern Cape , Water-supply -- South Africa -- Eastern Cape Water-supply, Rural -- South Africa -- Eastern Cape Constructed wetlands Watershed management
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/35234 , vital:33655
- Description: The Eastern Cape Karoo region of South Africa typically displays low rainfall and high temperatures, which is particularly concerning considering the shale gas exploration/extraction project proposed recently. Almost 90% of the fracking fluid consists of water and with the Karoo region already classified as a water-stressed region, the increased demand for freshwater for fracking could put further pressure on water resources of the region. By understanding the ecological functioning of the lower trophic levels, likely implications for higher trophic levels can be determined, and ultimately, recommendations for mitigation actions can be made. Here, observations aimed at understanding the dynamics of lower trophic levels are presented, that is, the microalgal biomass and assemblage composition within three characteristic surface waterbodies of the region. In addition, the work focuses on the smaller, more dynamic temporary wetland systems typical of this water-scarce region, with the aim of understanding the significance of single species macrophyte cover in relation to the lower trophic levels. Thirty-three waterbodies were sampled (natural depressions = 13, dams = 9, rivers = 11) during November 2014 (austral spring) and April 2015 (austral autumn). Waterbody physico-chemistry, hydro-morphometry, habitat cover and surrounding land-use, as well as microalgal biomass and assemblage composition within each waterbody type were measured. Thirteen natural depression wetlands were sampled during October 2015, December 2015 and March 2016. Once again, waterbody physico-chemistry, microalgal biomass and assemblage composition were measured. However, in addition, Schoenoplectus decipiens macrophyte cover and microalgal (diatom) species composition were also determined. In general, no significant differences in microalgal biomass between the three main waterbody types of the Eastern Cape Karoo region were found; however, the different waterbody types each displayed distinct microalgal assemblage compositions. Also, Schoenoplectus decipiens cover had negligible effects on microalgal biomass and assemblages in the temporary wetlands investigated here. These results suggest that the generalist nature of species occupying these systems allows them to adapt to the ever-changing conditions typical of this region. Ongoing monitoring initiatives considering impending hydraulic fracturing activities should include a comprehensive species-level diversity census, which could further inform management of any impacts associated with this potential disturbance.
- Full Text:
- Date Issued: 2018
Biological activity of macrofungi in South Africa against respiratory and lung disease
- Authors: Didloff, Jenske
- Date: 2018
- Subjects: Macrofungi , Microbiology Medical microbiology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/30138 , vital:30835
- Description: Macrofungi represent an untapped source of natural bioactive compounds for various diseases, which have been targeted as potential therapeutic agents. The medicinal uses of macrofungi discovered to date include anticancer, antidiabetic, antioxidant, antimicrobial, and immunomodulatory properties. The knowledge regarding the medicinal uses of macrofungi in Africa is limited; however, it is believed that Africa may contain a large number of unidentified species of macrofungi. The objectives of this study were to: (i) screen the macrofungal extracts for antimicrobial activity against microorganisms responsible for respiratory diseases (e.g. Pseudomonas aeruginosa, Klebsiella pneumoniae, Streptococcus pneumoniae, Streptococcus pyogenes, Staphylococcus aureus, Mycobacterium tuberculosis, HIV-1), (ii) determine the effect of macrofungal extracts on bacterial morphology, (iii) investigate the cytotoxicity of macrofungal extracts against human lung carcinoma cells, and to elucidate the mechanism/s of action of cytotoxicity/anticancer activity. In vitro bioassays for antimicrobial activity included: ρ-iodonitrotetrazolium chloride assays and microplate alamar blue assay (MABA), while the HIV-1 reverse transcriptase colorimetric ELISA and HIV-1 protease fluorometric assay kits were used for anti-HIV activity. Cytotoxicity of the macrofungal species against A549 lung cancer cell line was measured using the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide (MTT) assay, and the IC50 values determined for the most cytotoxic macrofungal spp. The mechanism of cytotoxicity was investigated by cell cycle analysis and fluorescent staining to observe morphological and biochemical changes (i.e. acridine orange, caspase activation). Ethanol extracts of Amanita foetidissima, Gymnopilus junonius, Pisolithus tinctorius, Fomitopsis lilacinogilva, Stereum hirsutum and Pycnoporus sanguineus showed higher antimicrobial activity against the Gram-positive bacteria than aqueous extracts, with S. pneumoniae being the most susceptible. The ethanol extracts of Agaricus campestris, Chlorophyllum molybdites, Gymnopilus penetrans, Pseudophaeolus baudonii and Laetiporus sulphureus exhibited anti-TB (tuberculosis) activity with minimum inhibitory concentrations (MICs) ranging between 500-1,000 μg/mL. C. molybdites ethanol extract inhibited HIV-1 protease activity (IC50: 49.7 μg/mL). The macrofungal extracts did not inhibit HIV-1 reverse transcriptase activity. Ethanol extracts of F. lilacinogilva, G. junonius, P. sanguineus and the aqueous extract iv of P. baudonii were cytotoxic against A549 lung cancer cells at IC50 values of 69.2±3.6, 57±5, 7.4±1.1 and 53.6±1.1 μg/mL, respectively. Cell cycle arrest was observed in the G2 phase for both P. sanguineus and P. baudonii, and G2/M and early M phases for G. junonius and F. lilacinogilva, respectively. Apoptosis induced by macrofungal extracts was confirmed by fluorescent staining. Morphological and biochemical changes included chromatin condensation, membrane blebbing, loss of cytoskeletal structure, caspase activation and phosphatidylserine translocation. This study demonstrates the biological activities of selected macrofungal extracts and their potential mechanisms of action. Isolation and identification of active compounds require further analysis.
- Full Text:
- Date Issued: 2018
- Authors: Didloff, Jenske
- Date: 2018
- Subjects: Macrofungi , Microbiology Medical microbiology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/30138 , vital:30835
- Description: Macrofungi represent an untapped source of natural bioactive compounds for various diseases, which have been targeted as potential therapeutic agents. The medicinal uses of macrofungi discovered to date include anticancer, antidiabetic, antioxidant, antimicrobial, and immunomodulatory properties. The knowledge regarding the medicinal uses of macrofungi in Africa is limited; however, it is believed that Africa may contain a large number of unidentified species of macrofungi. The objectives of this study were to: (i) screen the macrofungal extracts for antimicrobial activity against microorganisms responsible for respiratory diseases (e.g. Pseudomonas aeruginosa, Klebsiella pneumoniae, Streptococcus pneumoniae, Streptococcus pyogenes, Staphylococcus aureus, Mycobacterium tuberculosis, HIV-1), (ii) determine the effect of macrofungal extracts on bacterial morphology, (iii) investigate the cytotoxicity of macrofungal extracts against human lung carcinoma cells, and to elucidate the mechanism/s of action of cytotoxicity/anticancer activity. In vitro bioassays for antimicrobial activity included: ρ-iodonitrotetrazolium chloride assays and microplate alamar blue assay (MABA), while the HIV-1 reverse transcriptase colorimetric ELISA and HIV-1 protease fluorometric assay kits were used for anti-HIV activity. Cytotoxicity of the macrofungal species against A549 lung cancer cell line was measured using the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide (MTT) assay, and the IC50 values determined for the most cytotoxic macrofungal spp. The mechanism of cytotoxicity was investigated by cell cycle analysis and fluorescent staining to observe morphological and biochemical changes (i.e. acridine orange, caspase activation). Ethanol extracts of Amanita foetidissima, Gymnopilus junonius, Pisolithus tinctorius, Fomitopsis lilacinogilva, Stereum hirsutum and Pycnoporus sanguineus showed higher antimicrobial activity against the Gram-positive bacteria than aqueous extracts, with S. pneumoniae being the most susceptible. The ethanol extracts of Agaricus campestris, Chlorophyllum molybdites, Gymnopilus penetrans, Pseudophaeolus baudonii and Laetiporus sulphureus exhibited anti-TB (tuberculosis) activity with minimum inhibitory concentrations (MICs) ranging between 500-1,000 μg/mL. C. molybdites ethanol extract inhibited HIV-1 protease activity (IC50: 49.7 μg/mL). The macrofungal extracts did not inhibit HIV-1 reverse transcriptase activity. Ethanol extracts of F. lilacinogilva, G. junonius, P. sanguineus and the aqueous extract iv of P. baudonii were cytotoxic against A549 lung cancer cells at IC50 values of 69.2±3.6, 57±5, 7.4±1.1 and 53.6±1.1 μg/mL, respectively. Cell cycle arrest was observed in the G2 phase for both P. sanguineus and P. baudonii, and G2/M and early M phases for G. junonius and F. lilacinogilva, respectively. Apoptosis induced by macrofungal extracts was confirmed by fluorescent staining. Morphological and biochemical changes included chromatin condensation, membrane blebbing, loss of cytoskeletal structure, caspase activation and phosphatidylserine translocation. This study demonstrates the biological activities of selected macrofungal extracts and their potential mechanisms of action. Isolation and identification of active compounds require further analysis.
- Full Text:
- Date Issued: 2018
Capacitance spectroscopy of GaAs p-i-n solar cells embedded with GaNAs quantum wells
- Authors: Venter, Danielle Ahlers
- Date: 2018
- Subjects: Solar cells , Photocatalysis Nanotechnology Fuel cells
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/21593 , vital:29713
- Description: The search for higher efficiencies in solar cell technology has brought forth competitive ideas, among them tandem solar cells (TSC) and intermediate-band solar cells (IBSC). These cells deliver higher efficiencies by absorbing a wider range of the electro-magnetic spectrum compared to conventional cells, but do come with unique challenges. This includes, amongst others, the need to find suitable material systems, which can fully realise the requirements behind the concept. In this study, the notion of using dilute nitrides in III-V systems as a candidate for the IBSC is considered. Incorporation of GaNAs QW structures into GaAs p-i-n solar cells are structurally, optically and electrically characterised. At a first estimate the photovoltaic properties of the material is obtained through current-voltage (I-V) measurements under illumination. It is observed that the open circuit voltage (𝑉𝑂𝐶), short circuit current (𝐼𝑆𝐶) and conversion efficiency decrease upon the incorporation of the QWs. Electrically active defect levels are notorious for reducing the life time of electron-hole pairs, directly impacting cell efficiency. In an effort to gain a clearer understanding of this behavior, the study of electrically active deep level center present in such devices were investigated. A comprehensive understanding of defects in semiconductors remains of fundamental importance and thus reinforces this approach. This was done using two of the most commonly used semiconductor defect spectroscopy techniques viz. admittance spectroscopy (AS) and deep level transient spectroscopy (DLTS). Since in principle, these two techniques are similar, deep level related results were compared in order to verify the validity of the results. The devices under study, GaNAs/GaAs embedded QW p-i-n solar cells, were grown by molecular beam epitaxy (MBE). In particular, the doping of the quantum wells was varied and this effect on the electrical properties investigated. Four samples were studied and their electrical, optical and structural properties compared. The sample series consisted of a reference GaAs p-i-n diode that contained no embedded QWs and three GaAs p-i-n diodes each containing ten equally spaced and equally thick GaNAs QW layers. These layers were either Beryllium (Be) doped (p-type), un-doped or Silicon (Si) doped (n-type) respectively. Both AS and DLTS revealed deep level centers present in the devices. Each technique presented its own list of advantages and disadvantages and the collaborative use of both of them was found to be complementary in their determination of deep level defect centers. The correlation of these defects with the QWs is not clear as the structures were not optimized for capacitance spectroscopic measurements. NextNano++ simulation software was also used to theoretically model the electronic structure of the sample. The addition of the applied bias and its effect on the cross-over point of the Fermi level and the deep level energy, as well as the depletion width was investigated. This was a useful and essential tool for the interpretation of the results obtained and for the design of optimal structures for future studies.
- Full Text:
- Date Issued: 2018
- Authors: Venter, Danielle Ahlers
- Date: 2018
- Subjects: Solar cells , Photocatalysis Nanotechnology Fuel cells
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/21593 , vital:29713
- Description: The search for higher efficiencies in solar cell technology has brought forth competitive ideas, among them tandem solar cells (TSC) and intermediate-band solar cells (IBSC). These cells deliver higher efficiencies by absorbing a wider range of the electro-magnetic spectrum compared to conventional cells, but do come with unique challenges. This includes, amongst others, the need to find suitable material systems, which can fully realise the requirements behind the concept. In this study, the notion of using dilute nitrides in III-V systems as a candidate for the IBSC is considered. Incorporation of GaNAs QW structures into GaAs p-i-n solar cells are structurally, optically and electrically characterised. At a first estimate the photovoltaic properties of the material is obtained through current-voltage (I-V) measurements under illumination. It is observed that the open circuit voltage (𝑉𝑂𝐶), short circuit current (𝐼𝑆𝐶) and conversion efficiency decrease upon the incorporation of the QWs. Electrically active defect levels are notorious for reducing the life time of electron-hole pairs, directly impacting cell efficiency. In an effort to gain a clearer understanding of this behavior, the study of electrically active deep level center present in such devices were investigated. A comprehensive understanding of defects in semiconductors remains of fundamental importance and thus reinforces this approach. This was done using two of the most commonly used semiconductor defect spectroscopy techniques viz. admittance spectroscopy (AS) and deep level transient spectroscopy (DLTS). Since in principle, these two techniques are similar, deep level related results were compared in order to verify the validity of the results. The devices under study, GaNAs/GaAs embedded QW p-i-n solar cells, were grown by molecular beam epitaxy (MBE). In particular, the doping of the quantum wells was varied and this effect on the electrical properties investigated. Four samples were studied and their electrical, optical and structural properties compared. The sample series consisted of a reference GaAs p-i-n diode that contained no embedded QWs and three GaAs p-i-n diodes each containing ten equally spaced and equally thick GaNAs QW layers. These layers were either Beryllium (Be) doped (p-type), un-doped or Silicon (Si) doped (n-type) respectively. Both AS and DLTS revealed deep level centers present in the devices. Each technique presented its own list of advantages and disadvantages and the collaborative use of both of them was found to be complementary in their determination of deep level defect centers. The correlation of these defects with the QWs is not clear as the structures were not optimized for capacitance spectroscopic measurements. NextNano++ simulation software was also used to theoretically model the electronic structure of the sample. The addition of the applied bias and its effect on the cross-over point of the Fermi level and the deep level energy, as well as the depletion width was investigated. This was a useful and essential tool for the interpretation of the results obtained and for the design of optimal structures for future studies.
- Full Text:
- Date Issued: 2018
Correlation of photovoltaics plant performance metrics
- Authors: Vumbugwa, Monphias
- Date: 2018
- Subjects: Photovoltaic cells , Perfomance -- Evaluation , Thin films
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/45657 , vital:38924
- Description: The generation of electrical energy using Photovoltaic (PV) technology has increased globally with the decrease in the cost of PV systems and the rise in electrical power demand. In South Africa, the support by the government in implementing the Renewable Energy Independent Power Producer Procurement Programme (REIPPPP) has seen a growth in PV system deployment and investment in roof and ground mounted, stand alone and grid connected PV plants. This rapid growth shows that the PV industry is becoming highly competitive as there is a shift to low carbon emissions and it is anticipated to be the most affordable source of electricity. Hence, there is need to develop maintenance and fault diagnosis expertise and capabilities in the PV industry, which can in turn improve the dependability, productiveness and lifespan of PV systems. Solar PV modules directly receive and convert solar irradiance into electricity and may not generate the expected optimum energy due to abnormalities which arise when they are exposed to harsh unfavorable environmental conditions in the field. Thermal Infrared (TIR) imaging is widely used as a fault diagnosis tool in operating PV modules and mostly in large PV power plants. Therefore, there is need to research the interpretation of the observed thermal signatures and the impact that the anomalies have on electrical output of the system so as to improve the PV maintenance systems. This research focuses on identifying performance limiting defects using an Infra-Red (I-R) camera, mounted on an Unmanned Aerial Vehicle (UAV), to understand the effect of thermal signatures on current-voltage (I-V) characteristics of PV module strings. Aerial TIR imaging using a UAV can rapidly identify abnormalities in operational PV modules strings as hotspots. Any deviation of the string I-V curve, from the expected, indicates a problem with one or more PV modules in the string. However, locating the faulty module involves measuring I-V parameters of the individual modules in a string, which is not feasible in large PV power plants. Therefore, there is a need to estimate the power loss associated with the thermal signatures in PV module strings. Visual inspection may help in identifying the exact cause of some hotspots, while other hotspots need special characterization techniques, such as Electroluminescence (EL) and UV Fluorescence (UV-F), which can indicate if a solar cell is cracked or has weak busbars or contact finger connections.
- Full Text:
- Date Issued: 2018
- Authors: Vumbugwa, Monphias
- Date: 2018
- Subjects: Photovoltaic cells , Perfomance -- Evaluation , Thin films
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/45657 , vital:38924
- Description: The generation of electrical energy using Photovoltaic (PV) technology has increased globally with the decrease in the cost of PV systems and the rise in electrical power demand. In South Africa, the support by the government in implementing the Renewable Energy Independent Power Producer Procurement Programme (REIPPPP) has seen a growth in PV system deployment and investment in roof and ground mounted, stand alone and grid connected PV plants. This rapid growth shows that the PV industry is becoming highly competitive as there is a shift to low carbon emissions and it is anticipated to be the most affordable source of electricity. Hence, there is need to develop maintenance and fault diagnosis expertise and capabilities in the PV industry, which can in turn improve the dependability, productiveness and lifespan of PV systems. Solar PV modules directly receive and convert solar irradiance into electricity and may not generate the expected optimum energy due to abnormalities which arise when they are exposed to harsh unfavorable environmental conditions in the field. Thermal Infrared (TIR) imaging is widely used as a fault diagnosis tool in operating PV modules and mostly in large PV power plants. Therefore, there is need to research the interpretation of the observed thermal signatures and the impact that the anomalies have on electrical output of the system so as to improve the PV maintenance systems. This research focuses on identifying performance limiting defects using an Infra-Red (I-R) camera, mounted on an Unmanned Aerial Vehicle (UAV), to understand the effect of thermal signatures on current-voltage (I-V) characteristics of PV module strings. Aerial TIR imaging using a UAV can rapidly identify abnormalities in operational PV modules strings as hotspots. Any deviation of the string I-V curve, from the expected, indicates a problem with one or more PV modules in the string. However, locating the faulty module involves measuring I-V parameters of the individual modules in a string, which is not feasible in large PV power plants. Therefore, there is a need to estimate the power loss associated with the thermal signatures in PV module strings. Visual inspection may help in identifying the exact cause of some hotspots, while other hotspots need special characterization techniques, such as Electroluminescence (EL) and UV Fluorescence (UV-F), which can indicate if a solar cell is cracked or has weak busbars or contact finger connections.
- Full Text:
- Date Issued: 2018
Corrosion resistance of nanocrystalline titanium zirconium nitride layers deposited on ZIRLO
- Nyembe, Hlanganani Siphelele
- Authors: Nyembe, Hlanganani Siphelele
- Date: 2018
- Subjects: Zirconium alloys , Titanium alloys Nanocrystals Nanotechnology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/34744 , vital:33435
- Description: Zirconium (Zr) alloys are used as nuclear fuel cladding in water-cooled nuclear reactors. Being in contact with steam, the Zr-alloy is oxidised and it absorbs hydrogen. The hydrogen pickup in Zr-alloys induces embrittlement of the tubes due to hydride formation. In this study, effectiveness of corrosion resistant nanocrystalline titanium zirconium nitride (nc-TiZrN) coatings on the surface of a Zr-alloy for the reduction of corrosion and hydrogen pickup is investigated. The nc-TiZrN layers were deposited onto the surface of ZIRLO® using the cathodic arc vapour deposition (CAVD) technique. The influence of nc-TiZrN coatings on the corrosion performance of ZIRLO® was investigated under the following conditions: (a) In an oxygen atmosphere at various temperatures from 400 to 900 ℃ for 30 minutes, (b) for various exposure times from 6 – 24 hours with the temperature kept constant at 500 ℃ in a tube furnace, and (c) in pure steam for 30 days at 360 ℃ and 18.7 MPa in an autoclave. The corrosion properties of the nc-TiZrN coated ZIRLO were compared to uncoated ZIRLO for all experiments. Following corrosion testing, the TiZrN coatings and oxide layers were investigated by scanning and transmission electron microscopy and energy dispersive X-ray spectroscopy. The TiZrN coating had a thickness of ~3.8 μm with a small number of Ti-rich and Nb-rich inclusions. The coating exhibited a single phase solid solution of Ti0.42Zr0.58N with a NaCl-type crystal structure and columnar nanocrystals. These columnar nanocrystals showed a strong {111} preferred orientation and the {111} planes of the TiZrN crystals are oriented parallel to the (001) planes of α-ZIRLO grains with <001> direction perpendicular to the coating/ZIRLO interface. The corrosion testing at various temperatures from 400 to 900 ℃ for 30 minutes showed that the TiZrN coating oxidises slowly and retained its microstructure, composition and crystallinity up to 600 ℃. At higher temperatures above 600 ℃, the TiZrN layer completely oxidised to a non-protective TiZr-oxide layer and resulted in rapid corrosion of the underlying ZIRLO substrate. The rapid corrosion was not observed in the uncoated ZIRLO sample for all temperatures. The results of samples subjected to annealing treatment at 500 ℃ in an oxygen atmosphere at various times up to 24 hours revealed that the TiZrN layer oxidises faster than ZIRLO. This was confirmed by sub-cubic and sub-parabolic oxide growth kinetics observed in the uncoated ZIRLO which are slower than the parabolic kinetics of TiZrN coated samples. In all coated samples, the spallation was observed near the edges of the samples. The spallation was caused by rapid corrosion of the underlying ZIRLO substrate which resulted from the penetration of oxygen ions between the TiZrN coating and ZIRLO substrate along the edges of the samples. In pure steam for 30 days at 360 ℃, a complete loss of the TiZrN layer occurred but the results show that the coating might have delayed the corrosion of ZIRLO. In summary, corrosion resistance of nc-TiZrN coated ZIRLO was lower than that of uncoated ZIRLO. The study shows that the failure of TiZrN coatings leads to rapid corrosion of the underlying ZIRLO substrate which was not observed on the uncoated ZIRLO. It is not yet understood why the presence TiZrN coatings reduced the oxidation resistance of ZIRLO.
- Full Text:
- Date Issued: 2018
- Authors: Nyembe, Hlanganani Siphelele
- Date: 2018
- Subjects: Zirconium alloys , Titanium alloys Nanocrystals Nanotechnology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/34744 , vital:33435
- Description: Zirconium (Zr) alloys are used as nuclear fuel cladding in water-cooled nuclear reactors. Being in contact with steam, the Zr-alloy is oxidised and it absorbs hydrogen. The hydrogen pickup in Zr-alloys induces embrittlement of the tubes due to hydride formation. In this study, effectiveness of corrosion resistant nanocrystalline titanium zirconium nitride (nc-TiZrN) coatings on the surface of a Zr-alloy for the reduction of corrosion and hydrogen pickup is investigated. The nc-TiZrN layers were deposited onto the surface of ZIRLO® using the cathodic arc vapour deposition (CAVD) technique. The influence of nc-TiZrN coatings on the corrosion performance of ZIRLO® was investigated under the following conditions: (a) In an oxygen atmosphere at various temperatures from 400 to 900 ℃ for 30 minutes, (b) for various exposure times from 6 – 24 hours with the temperature kept constant at 500 ℃ in a tube furnace, and (c) in pure steam for 30 days at 360 ℃ and 18.7 MPa in an autoclave. The corrosion properties of the nc-TiZrN coated ZIRLO were compared to uncoated ZIRLO for all experiments. Following corrosion testing, the TiZrN coatings and oxide layers were investigated by scanning and transmission electron microscopy and energy dispersive X-ray spectroscopy. The TiZrN coating had a thickness of ~3.8 μm with a small number of Ti-rich and Nb-rich inclusions. The coating exhibited a single phase solid solution of Ti0.42Zr0.58N with a NaCl-type crystal structure and columnar nanocrystals. These columnar nanocrystals showed a strong {111} preferred orientation and the {111} planes of the TiZrN crystals are oriented parallel to the (001) planes of α-ZIRLO grains with <001> direction perpendicular to the coating/ZIRLO interface. The corrosion testing at various temperatures from 400 to 900 ℃ for 30 minutes showed that the TiZrN coating oxidises slowly and retained its microstructure, composition and crystallinity up to 600 ℃. At higher temperatures above 600 ℃, the TiZrN layer completely oxidised to a non-protective TiZr-oxide layer and resulted in rapid corrosion of the underlying ZIRLO substrate. The rapid corrosion was not observed in the uncoated ZIRLO sample for all temperatures. The results of samples subjected to annealing treatment at 500 ℃ in an oxygen atmosphere at various times up to 24 hours revealed that the TiZrN layer oxidises faster than ZIRLO. This was confirmed by sub-cubic and sub-parabolic oxide growth kinetics observed in the uncoated ZIRLO which are slower than the parabolic kinetics of TiZrN coated samples. In all coated samples, the spallation was observed near the edges of the samples. The spallation was caused by rapid corrosion of the underlying ZIRLO substrate which resulted from the penetration of oxygen ions between the TiZrN coating and ZIRLO substrate along the edges of the samples. In pure steam for 30 days at 360 ℃, a complete loss of the TiZrN layer occurred but the results show that the coating might have delayed the corrosion of ZIRLO. In summary, corrosion resistance of nc-TiZrN coated ZIRLO was lower than that of uncoated ZIRLO. The study shows that the failure of TiZrN coatings leads to rapid corrosion of the underlying ZIRLO substrate which was not observed on the uncoated ZIRLO. It is not yet understood why the presence TiZrN coatings reduced the oxidation resistance of ZIRLO.
- Full Text:
- Date Issued: 2018
Deep learning applied to the semantic segmentation of tyre stockpiles
- Barfknecht, Nicholas Christopher
- Authors: Barfknecht, Nicholas Christopher
- Date: 2018
- Subjects: Neural networks (Computer science)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/23947 , vital:30647
- Description: The global push for manufacturing which is environmentally sustainable has disrupted standard methods of waste tyre disposal. This push is further intensified by the health and safety risks discarded tyres pose to the surrounding population. Waste tyre recycling initiatives in South Africa are on the increase; however, there is still a growing number of undocumented tyre stockpiles developing throughout the country. The plans put in place to eradicate these tyre stockpiles have been met with collection, transport and storage logistical issues caused by the remoteness and distant locales. Eastwood (2016) aimed at optimising the logistics associated with collection, by estimating the number of visible tyres from images of tyre stockpiles. This research was limited by the need for manual segmentation of each tyre stockpile located within each image. This research proposes the use of semantic segmentation to automatically segment images of tyre stockpiles. An initial review of neural network, convolutional network and semantic segmentation literature resulted in the selection of Dilated Net as the semantic segmentation architecture for this research. Dilated Net builds upon the VGG-16 classification architecture to perform semantic segmentation. This resulted in classification experiments which were evaluated using precision, recall and f1-score. The results indicated that regardless of tyre stockpile image dimension, fairly accurate levels of classification accuracy can be attained. This was followed by semantic segmentation experiments which made use of intersection over union (IoU) and pixel accuracy to evaluate the effectiveness of Dilated Net on images of tyre stockpiles. The results indicated that accurate tyre stockpile segmentation regions can be obtained and that the trained model generalises well to unseen images.
- Full Text:
- Date Issued: 2018
- Authors: Barfknecht, Nicholas Christopher
- Date: 2018
- Subjects: Neural networks (Computer science)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/23947 , vital:30647
- Description: The global push for manufacturing which is environmentally sustainable has disrupted standard methods of waste tyre disposal. This push is further intensified by the health and safety risks discarded tyres pose to the surrounding population. Waste tyre recycling initiatives in South Africa are on the increase; however, there is still a growing number of undocumented tyre stockpiles developing throughout the country. The plans put in place to eradicate these tyre stockpiles have been met with collection, transport and storage logistical issues caused by the remoteness and distant locales. Eastwood (2016) aimed at optimising the logistics associated with collection, by estimating the number of visible tyres from images of tyre stockpiles. This research was limited by the need for manual segmentation of each tyre stockpile located within each image. This research proposes the use of semantic segmentation to automatically segment images of tyre stockpiles. An initial review of neural network, convolutional network and semantic segmentation literature resulted in the selection of Dilated Net as the semantic segmentation architecture for this research. Dilated Net builds upon the VGG-16 classification architecture to perform semantic segmentation. This resulted in classification experiments which were evaluated using precision, recall and f1-score. The results indicated that regardless of tyre stockpile image dimension, fairly accurate levels of classification accuracy can be attained. This was followed by semantic segmentation experiments which made use of intersection over union (IoU) and pixel accuracy to evaluate the effectiveness of Dilated Net on images of tyre stockpiles. The results indicated that accurate tyre stockpile segmentation regions can be obtained and that the trained model generalises well to unseen images.
- Full Text:
- Date Issued: 2018
Determining productivity, residual damage and cost of two alternative harvesting systems in pinus elliottii thinning
- Dembure, Tigere Pasca, Spinelli, Raffaele, Ramantswana, Muedanyi
- Authors: Dembure, Tigere Pasca , Spinelli, Raffaele , Ramantswana, Muedanyi
- Date: 2018
- Subjects: Pinus caribaea , Forests and forestry Logging Harvesting -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/22016 , vital:29813
- Description: Pinus elliottii is the second most dominant softwood grown in the South African plantation forestry industry. It possesses desirable timber characteristics and is useful for production of solid wood products. In the silviculture of softwoods (grown for solid wood products), thinning is an important tending operation. It is necessary for stand hygiene and volume increment of residual trees through the creation of growing space. The selection of a suitable harvesting system for thinning is vital. The system of choice has to attain higher productivity, cause the least damage to residual trees and must be cost effective. From as early as 2000 the South African forestry industry witnessed a general shift towards the use of fully mechanised cut-to-length harvesting systems. This has been a result of high labour turnover, increased labour costs, increased timber demand and the effects of HIV and AIDS on forestry workers. With this recent introduction of mechanised systems, they have not been benchmarked against conventional harvesting systems. In this regard, two harvesting systems were studied side-by-side for productivity, residual damage and cost in a seventh row second thinning operation in P. elliottii stands. First thinnings generate poor financial returns since small trees are harvested and they have a relatively low financial value but have a relatively high operational cost per unit harvested. The second thinning operation is usually the thinning operation that is most likely to result in an intermediate financial return for the organisation, hence the need to benchmark these harvesting systems during the second thinning. These systems were a fully mechanised cut-to-length (CTL) and a semi-mechanised tree length (TL) system. The fully mechanised system comprised of a harvester (felling) and a forwarder (extracting) and the semi-system consisted of felling by chainsaw, tractor extraction, roadside processing by chainsaw and stacking by three-wheeled logger. Two uniform compartments planted with P. elliottii were selected for the study. A total number of 32 plots (16 plots per compartment) were marked and randomly assigned between the two treatments, each plot comprised of seven rows, with the middle row clear-cut and three rows on either side, where marked trees were selectively removed. Within each plot, the number of removal trees ranged from 80 to 105. The diameter, height and form of each removal tree were measured to determine tree volume and ultimately determine productivity. Before analysis, plot characteristics were compared to determine if conditions were equal for both treatments using the Mann-Whitney test at alpha level ˂ 0.05. There was a statistically significant difference in total operator efficiency between the two systems (p ˂ 0.0001). The fully mechanised system attained higher levels of productivity than the semi-mechanised system (15.58 m3/SMH versus 5.26 m3/SMH, for felling and 15.56 m3/SMH versus 5.29 m3/SMH, for the extraction operation). Operator productivity comparisons were restricted to the two harvester operators, and one operator achieved 16.9 m3/SMH while the other operator achieved 14.3 m3/SMH. Different operator working technique contributed to the productivity differences with one operator spending (on average) four seconds less per tree on the fell-process work element. Residual tree damage was assessed immediately after all felling and extraction had taken place. Damage size was measured as ellipse surface area. For each record of residual damage, the damage type was noted, damage position along the stem, and tree position from extraction trail. The most predominant damage type was bark peel. The motor-manual system caused five per cent damage and the fully mechanised system inflicted only three per cent damage to the residual trees. Residual tree damage from the semi-mechanised system mainly occurred at the root zone, and occurred more frequently on edge trees. The mechanised CTL system was characterised by high investment and operational costs. The mechanised system incurred 3037.75 R/SMH while the semi-mechanised system incurred 1667.10 R/SMH. The difference in total costs per year between both systems was 56.29 per cent, with the fully mechanised system being more expensive. The high capacity and the superior technology of mechanised harvesting systems may not be fully exploited in thinnings, therefore harvesting systems with lower capital costs and reasonable productivity can be competitive.
- Full Text:
- Date Issued: 2018
- Authors: Dembure, Tigere Pasca , Spinelli, Raffaele , Ramantswana, Muedanyi
- Date: 2018
- Subjects: Pinus caribaea , Forests and forestry Logging Harvesting -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/22016 , vital:29813
- Description: Pinus elliottii is the second most dominant softwood grown in the South African plantation forestry industry. It possesses desirable timber characteristics and is useful for production of solid wood products. In the silviculture of softwoods (grown for solid wood products), thinning is an important tending operation. It is necessary for stand hygiene and volume increment of residual trees through the creation of growing space. The selection of a suitable harvesting system for thinning is vital. The system of choice has to attain higher productivity, cause the least damage to residual trees and must be cost effective. From as early as 2000 the South African forestry industry witnessed a general shift towards the use of fully mechanised cut-to-length harvesting systems. This has been a result of high labour turnover, increased labour costs, increased timber demand and the effects of HIV and AIDS on forestry workers. With this recent introduction of mechanised systems, they have not been benchmarked against conventional harvesting systems. In this regard, two harvesting systems were studied side-by-side for productivity, residual damage and cost in a seventh row second thinning operation in P. elliottii stands. First thinnings generate poor financial returns since small trees are harvested and they have a relatively low financial value but have a relatively high operational cost per unit harvested. The second thinning operation is usually the thinning operation that is most likely to result in an intermediate financial return for the organisation, hence the need to benchmark these harvesting systems during the second thinning. These systems were a fully mechanised cut-to-length (CTL) and a semi-mechanised tree length (TL) system. The fully mechanised system comprised of a harvester (felling) and a forwarder (extracting) and the semi-system consisted of felling by chainsaw, tractor extraction, roadside processing by chainsaw and stacking by three-wheeled logger. Two uniform compartments planted with P. elliottii were selected for the study. A total number of 32 plots (16 plots per compartment) were marked and randomly assigned between the two treatments, each plot comprised of seven rows, with the middle row clear-cut and three rows on either side, where marked trees were selectively removed. Within each plot, the number of removal trees ranged from 80 to 105. The diameter, height and form of each removal tree were measured to determine tree volume and ultimately determine productivity. Before analysis, plot characteristics were compared to determine if conditions were equal for both treatments using the Mann-Whitney test at alpha level ˂ 0.05. There was a statistically significant difference in total operator efficiency between the two systems (p ˂ 0.0001). The fully mechanised system attained higher levels of productivity than the semi-mechanised system (15.58 m3/SMH versus 5.26 m3/SMH, for felling and 15.56 m3/SMH versus 5.29 m3/SMH, for the extraction operation). Operator productivity comparisons were restricted to the two harvester operators, and one operator achieved 16.9 m3/SMH while the other operator achieved 14.3 m3/SMH. Different operator working technique contributed to the productivity differences with one operator spending (on average) four seconds less per tree on the fell-process work element. Residual tree damage was assessed immediately after all felling and extraction had taken place. Damage size was measured as ellipse surface area. For each record of residual damage, the damage type was noted, damage position along the stem, and tree position from extraction trail. The most predominant damage type was bark peel. The motor-manual system caused five per cent damage and the fully mechanised system inflicted only three per cent damage to the residual trees. Residual tree damage from the semi-mechanised system mainly occurred at the root zone, and occurred more frequently on edge trees. The mechanised CTL system was characterised by high investment and operational costs. The mechanised system incurred 3037.75 R/SMH while the semi-mechanised system incurred 1667.10 R/SMH. The difference in total costs per year between both systems was 56.29 per cent, with the fully mechanised system being more expensive. The high capacity and the superior technology of mechanised harvesting systems may not be fully exploited in thinnings, therefore harvesting systems with lower capital costs and reasonable productivity can be competitive.
- Full Text:
- Date Issued: 2018
Effects of polymerisation conditions on the mechanism and properties of furfuryl alcohol resin
- Authors: Iroegbu, Austine Ofondu
- Date: 2018
- Subjects: Polymerization , Polyethylene
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/30386 , vital:30937
- Description: The purpose of this study was to do a comparative investigation on the acid- and heat catalysed polymerisation and resinification of furfuryl alcohol and the effects of these polymerisation conditions on the mechanism, morphology, molecular weight and thermal properties of the polyfurfuryl alcohol resins. The formation of furfuryl alcohol polymers was confirmed using size exclusion chromatography (SEC); the synthesised polymer resins were investigated using Fourier transform infrared spectroscopy (FTIR,), scanning electron microscopy (SEM) and Thermogravimetric analysis (TGA). The effects of polymerisation conditions on the mechanism of polyfurfuryl alcohol polymerisation was a major focus of this study. The obtained results confirm that the surface topology, mechanism of polymerisation, thermal behaviour and molecular weights of polyfurfuryl alcohol polymer resins are dependent on the polymerisation condition. The acid and heat catalysed polyfurfuryl alcohol resin polymers presented interesting and promising results.
- Full Text:
- Date Issued: 2018
- Authors: Iroegbu, Austine Ofondu
- Date: 2018
- Subjects: Polymerization , Polyethylene
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/30386 , vital:30937
- Description: The purpose of this study was to do a comparative investigation on the acid- and heat catalysed polymerisation and resinification of furfuryl alcohol and the effects of these polymerisation conditions on the mechanism, morphology, molecular weight and thermal properties of the polyfurfuryl alcohol resins. The formation of furfuryl alcohol polymers was confirmed using size exclusion chromatography (SEC); the synthesised polymer resins were investigated using Fourier transform infrared spectroscopy (FTIR,), scanning electron microscopy (SEM) and Thermogravimetric analysis (TGA). The effects of polymerisation conditions on the mechanism of polyfurfuryl alcohol polymerisation was a major focus of this study. The obtained results confirm that the surface topology, mechanism of polymerisation, thermal behaviour and molecular weights of polyfurfuryl alcohol polymer resins are dependent on the polymerisation condition. The acid and heat catalysed polyfurfuryl alcohol resin polymers presented interesting and promising results.
- Full Text:
- Date Issued: 2018
Electrospinning of carbon nanofibers for investigating the behaviour of lead electrodeposits on the carbon surface
- Authors: Madikane, Zipporah Kayakazi
- Date: 2018
- Subjects: Materials science , Nanotechnology Nanostructured materials
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/31622 , vital:31629
- Description: Over the years, the lead acid battery’s performance in modern vehicles has improved considerably to adapt to the new demands of vehicle electronics and start-stop applications. Although vehicles are valuable for commuting, their high volume of usage has resulted in an increase of fuel prices and emitted carbon dioxide (CO2). Due to the drastic global warming concerns, vehicle manufactures have been pressured into developing a variety of hybrid electric vehicles (HEV) that would reduce their fuel consumption and thereby reduced CO2 emission. The HEVs construction requires the implementation of advanced battery systems that operate under high rate partial state of charge (HRPSoC) conditions. During battery’s discharge, the Pb contained on the negative plate is oxidised to insulating PbSO4 crystals. When the battery is charged, the PbSO4 is reduced back to Pb. With prolonged use at HRPSoC, the battery undergoes an irreversible process wherein small PbSO4 crystallites dissolve and precipitate into large passivating PbSO4 crystals that accumulate as a dense layer on the surface of the negative plate. This layer restricts the diffusion of the H2SO4 electrolyte into the reaction sites for further reactions, resulting in the battery to fail prematurely. Research has shown that the inclusion of appropriate carbon materials on the negative active material (NAM) improves the performance of the batteries in HRPSoC cycling. This study looked at the making of some of the carbon-based additives by using relatively cheap materials such as polyvinyl alcohol (PVA) polymer with a sucrose blend in ratios of 75:25, 50:50 and 25:75, respectively. The blended materials were electrospun into PVA/Sucrose nanofibers. These were further stabilised by iodine and carbonised at 500 °C in a tube furnace. The properties of the carbon fibres were investigated by a number of analytical techniques such as TGA, DSC, XRD, BET, FTIR and SEM. The obtained carbon fibre surfaces were further electroplated with Pb in order to investigate the chemical bonding, the relationship between the carbon-based material interface and the Pb was investigated by SEM and CV techniques. The results of the study demonstrated that the varied ratios of the PVA/Sucrose nanofibers influenced the differences in their respective chemical and physical properties. Thermal analysis demonstrated that at approximately 500 °C, the final residue of the PVA/Sucrose nanofibers decreased as the sucrose content decreased. iii Carbonisation of the nanofibers was confirmed by the structural changes corresponding to the disappearance of the major bonds of PVA and sucrose materials, as well as by the appearance of C=C stretches. Carbonisation was also confirmed by the XRD diffractogram that demonstrated two broad amorphous peaks that corresponded to the planes of the graphite structure. The broadness of the peaks confirmed the amorphous nature of the carbon fibres. The morphological studies demonstrated that upon blending PVA with increasing quantities of sucrose, the uniformity of the fibres was altered into beaded fibrous structures with large diameters due to the increased viscosity of the electrospinning solution. The behaviour of the Pb deposits on the carbon surfaces was influenced by the high quantity of PVA present on the blend and the fibrous structure of the carbonised material. The Pb had high affinity towards the fibrous carbon derived from 75:25 as it deposited widely across the surface. Whereas, the absence of Pb deposits on the surface of the carbon derived from the 25:75 ratio was an indication that the high sucrose content and the bulky non-fibrous structure hindered the electrodeposition. The electrochemical study findings demonstrated that the bare Pb electrode had two distinct current peaks corresponding to the anodic (discharge) and cathodic (charge) reactions of Pb/PbSO4. Upon the inclusion of the electrospun carbon materials on the Pb electrode, the intensities of the anodic and cathodic peaks were reduced. Implying that none of the carbon materials enhanced the electrochemical redox reactions of the Pb/PbSO4 couple in the H2SO4 electrolyte.
- Full Text:
- Date Issued: 2018
- Authors: Madikane, Zipporah Kayakazi
- Date: 2018
- Subjects: Materials science , Nanotechnology Nanostructured materials
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/31622 , vital:31629
- Description: Over the years, the lead acid battery’s performance in modern vehicles has improved considerably to adapt to the new demands of vehicle electronics and start-stop applications. Although vehicles are valuable for commuting, their high volume of usage has resulted in an increase of fuel prices and emitted carbon dioxide (CO2). Due to the drastic global warming concerns, vehicle manufactures have been pressured into developing a variety of hybrid electric vehicles (HEV) that would reduce their fuel consumption and thereby reduced CO2 emission. The HEVs construction requires the implementation of advanced battery systems that operate under high rate partial state of charge (HRPSoC) conditions. During battery’s discharge, the Pb contained on the negative plate is oxidised to insulating PbSO4 crystals. When the battery is charged, the PbSO4 is reduced back to Pb. With prolonged use at HRPSoC, the battery undergoes an irreversible process wherein small PbSO4 crystallites dissolve and precipitate into large passivating PbSO4 crystals that accumulate as a dense layer on the surface of the negative plate. This layer restricts the diffusion of the H2SO4 electrolyte into the reaction sites for further reactions, resulting in the battery to fail prematurely. Research has shown that the inclusion of appropriate carbon materials on the negative active material (NAM) improves the performance of the batteries in HRPSoC cycling. This study looked at the making of some of the carbon-based additives by using relatively cheap materials such as polyvinyl alcohol (PVA) polymer with a sucrose blend in ratios of 75:25, 50:50 and 25:75, respectively. The blended materials were electrospun into PVA/Sucrose nanofibers. These were further stabilised by iodine and carbonised at 500 °C in a tube furnace. The properties of the carbon fibres were investigated by a number of analytical techniques such as TGA, DSC, XRD, BET, FTIR and SEM. The obtained carbon fibre surfaces were further electroplated with Pb in order to investigate the chemical bonding, the relationship between the carbon-based material interface and the Pb was investigated by SEM and CV techniques. The results of the study demonstrated that the varied ratios of the PVA/Sucrose nanofibers influenced the differences in their respective chemical and physical properties. Thermal analysis demonstrated that at approximately 500 °C, the final residue of the PVA/Sucrose nanofibers decreased as the sucrose content decreased. iii Carbonisation of the nanofibers was confirmed by the structural changes corresponding to the disappearance of the major bonds of PVA and sucrose materials, as well as by the appearance of C=C stretches. Carbonisation was also confirmed by the XRD diffractogram that demonstrated two broad amorphous peaks that corresponded to the planes of the graphite structure. The broadness of the peaks confirmed the amorphous nature of the carbon fibres. The morphological studies demonstrated that upon blending PVA with increasing quantities of sucrose, the uniformity of the fibres was altered into beaded fibrous structures with large diameters due to the increased viscosity of the electrospinning solution. The behaviour of the Pb deposits on the carbon surfaces was influenced by the high quantity of PVA present on the blend and the fibrous structure of the carbonised material. The Pb had high affinity towards the fibrous carbon derived from 75:25 as it deposited widely across the surface. Whereas, the absence of Pb deposits on the surface of the carbon derived from the 25:75 ratio was an indication that the high sucrose content and the bulky non-fibrous structure hindered the electrodeposition. The electrochemical study findings demonstrated that the bare Pb electrode had two distinct current peaks corresponding to the anodic (discharge) and cathodic (charge) reactions of Pb/PbSO4. Upon the inclusion of the electrospun carbon materials on the Pb electrode, the intensities of the anodic and cathodic peaks were reduced. Implying that none of the carbon materials enhanced the electrochemical redox reactions of the Pb/PbSO4 couple in the H2SO4 electrolyte.
- Full Text:
- Date Issued: 2018
Energy maximisation strategies of different African herbivores in a fire dominated and nutrient poor grassland ecosystem
- Authors: Brooke, Christopher
- Date: 2018
- Subjects: Grassland ecology -- South Africa -- Eastern Cape , Animals -- Food -- South Africa -- Eastern Cape , Herbivores -- Ecology -- South Africa -- Eastern Cape , Fire ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/21961 , vital:29807
- Description: Fire and herbivory are both major drivers in grassland ecosystems throughout the world. Although these two driving forces act independently from one another the relationship between fire and herbivory may be more significant than either acting on their own. Heterogeneity within the landscape as a result of fire results in herbivores having to adapt their behaviour in space and time. My research focussed on 1) characterising the fire regime on Mkambati Nature Reserve (hereafter Mkambati) and 2) determining the foraging choices and energy maximisation principles displayed by herbivores in relation to the biomass of vegetation and post fire vegetation age. Fire regimes were characterised between 2007-2016 in the low nutrient coastal grasslands of Mkambati in terms of fire season, seasonality of fire-prone weather conditions, fire return interval (FRI) and influence of poaching-related ignitions. Based on these results I then assessed foraging choices in terms of energy maximisation of four large herbivore species. I explored what energy maximisation strategy was employed, i.e. maximisation of daily digestible energy (DDE) (recently burnt low biomass vegetation) or instantaneous digestible energy (IDE) (older high biomass vegetation), by herbivore species with different morpho-physiological traits. Common reedbuck (Redunca arundinum), red hartebeest (Alcelaphus buselaphus subsp. caama), zebra (Equus quagga) and eland (Tragelaphus oryx subsp. oryx) were fitted with GPS satellite tracking collars, and hourly GPS locations (observed) were taken between 2008 and 2016. Using mixed effects models, I compared observed and an associated set of random locations to determine the energy maximisation strategy employed by each species. Our results indicated that fires were concentrated in winter when monthly fire danger weather (FDI) was highest. The mean FRI at Mkambati was <3 years, but varied according to vegetation type, and whether censoring (for open ended FRIs) was applied to estimate mean FRIs. Poachers, with the intention of attracting ungulates, are an important source of ignition at Mkambati. Accordingly FRIs were shorter (approximately 2 years) in areas within 3 km of likely poacher entry points. Although all fires recorded at Mkambati during the study period were of anthropogenic origin, mean FRI still fell within the natural range reported for interior grasslands in South Africa. Based on these findings, underpinned by the fire regime information, I showed that red hartebeest and zebra maximised DDE inside and outside of fire seasons and frequently foraged in low biomass recently burnt grasslands. Eland generally favoured areas where they could maximise IDE outside of the fire season, however during the fire season they switched strategy to maximise DDE. Reedbuck did not maximise IDE or DDE at the same scale (patch scale) as the other species, but at a landscape (broader) scale they maximised both IDE and DDE. Through this research I have shown how regular fire affects the foraging and energy maximisation behaviour of large African herbivores and how morpho-physiological traits affect these decisions. In response to these results I recommend that the management of Mkambati implement a focused monitoring program comparing the frequently and less frequently burnt areas of the reserve in order to understand the complex effects of anthropogenic fire and its subsequent effects on the biota of Mkambati.
- Full Text:
- Date Issued: 2018
- Authors: Brooke, Christopher
- Date: 2018
- Subjects: Grassland ecology -- South Africa -- Eastern Cape , Animals -- Food -- South Africa -- Eastern Cape , Herbivores -- Ecology -- South Africa -- Eastern Cape , Fire ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/21961 , vital:29807
- Description: Fire and herbivory are both major drivers in grassland ecosystems throughout the world. Although these two driving forces act independently from one another the relationship between fire and herbivory may be more significant than either acting on their own. Heterogeneity within the landscape as a result of fire results in herbivores having to adapt their behaviour in space and time. My research focussed on 1) characterising the fire regime on Mkambati Nature Reserve (hereafter Mkambati) and 2) determining the foraging choices and energy maximisation principles displayed by herbivores in relation to the biomass of vegetation and post fire vegetation age. Fire regimes were characterised between 2007-2016 in the low nutrient coastal grasslands of Mkambati in terms of fire season, seasonality of fire-prone weather conditions, fire return interval (FRI) and influence of poaching-related ignitions. Based on these results I then assessed foraging choices in terms of energy maximisation of four large herbivore species. I explored what energy maximisation strategy was employed, i.e. maximisation of daily digestible energy (DDE) (recently burnt low biomass vegetation) or instantaneous digestible energy (IDE) (older high biomass vegetation), by herbivore species with different morpho-physiological traits. Common reedbuck (Redunca arundinum), red hartebeest (Alcelaphus buselaphus subsp. caama), zebra (Equus quagga) and eland (Tragelaphus oryx subsp. oryx) were fitted with GPS satellite tracking collars, and hourly GPS locations (observed) were taken between 2008 and 2016. Using mixed effects models, I compared observed and an associated set of random locations to determine the energy maximisation strategy employed by each species. Our results indicated that fires were concentrated in winter when monthly fire danger weather (FDI) was highest. The mean FRI at Mkambati was <3 years, but varied according to vegetation type, and whether censoring (for open ended FRIs) was applied to estimate mean FRIs. Poachers, with the intention of attracting ungulates, are an important source of ignition at Mkambati. Accordingly FRIs were shorter (approximately 2 years) in areas within 3 km of likely poacher entry points. Although all fires recorded at Mkambati during the study period were of anthropogenic origin, mean FRI still fell within the natural range reported for interior grasslands in South Africa. Based on these findings, underpinned by the fire regime information, I showed that red hartebeest and zebra maximised DDE inside and outside of fire seasons and frequently foraged in low biomass recently burnt grasslands. Eland generally favoured areas where they could maximise IDE outside of the fire season, however during the fire season they switched strategy to maximise DDE. Reedbuck did not maximise IDE or DDE at the same scale (patch scale) as the other species, but at a landscape (broader) scale they maximised both IDE and DDE. Through this research I have shown how regular fire affects the foraging and energy maximisation behaviour of large African herbivores and how morpho-physiological traits affect these decisions. In response to these results I recommend that the management of Mkambati implement a focused monitoring program comparing the frequently and less frequently burnt areas of the reserve in order to understand the complex effects of anthropogenic fire and its subsequent effects on the biota of Mkambati.
- Full Text:
- Date Issued: 2018
Environmental management of wetlands on an urban periphery: the case of Bay West
- Authors: Domoney, Nicola Leah
- Date: 2018
- Subjects: Wetland management -- South Africa -- Nelson Mandela Bay Municipality , Remote sensing Chlorophyll
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/30854 , vital:31183
- Description: South Africa is a semi-arid country and thus depends on sound management of its water resources. Wetlands, despite their importance to water resource storage and water quality, among their other ecological and social significance, remain the most threatened of South Africa’s ecosystems. One of their greatest threats is encroachment by urbanisation. This occurs because wetlands, and especially ephemeral urban periphery wetlands, are overlooked. This study’s main objective was to determine the water quality and health of the wetlands adjacent to the newly established Bay West development on the western urban periphery of Nelson Mandela Bay. Wetlands are difficult to access and it is time-consuming to assess them. Remote sensing, however, overcomes this challenge and is cost-effective and time-considerate. It was the aim of this study to assess the health of the peri-urban wetlands on the Bay West periphery in order to formulate an appropriate environmental management plan, and remote sensing was tested as an effective method for wetland health management. It was found that the wetlands closer to the urban residential area (Sherwood suburb) were far more impacted than the wetlands nearer to Bay West Mall. Wetlands Six to Eight were higher in all parameters of pH, total dissolved solutes (TDS), salinity, conductivity and chlorophyll a concentration than Wetlands One to Five located further away from the urban area. A correlation with distance away from the urban area found a strong inverse relationship with between distance and the water quality factor, yielding a correlation coefficient of (<-0.7) in 2017 and (<-0.9) in 2018 with regard to TDS, salinity and conductivity. This, therefore, suggests that the wetlands’ health deteriorates towards the urban area. TDS, salinity, pH and conductivity correlate highly with chlorophyll a concentration at (>0.70). There was significant difference in pH in the year 2017 between the Bay West wetlands and the reference wetland (p<0.05; df=19; f= 3.56; n=3) and in 2018 (p<0.01; df=22; f= 8.90; n=3). No significant difference was found between the wetlands for dissolved oxygen. TDS between the wetlands was found to be significantly different in the year 2017 (p<0.01; df=23; f= 44.16; n=3) and 2018 (p<0.05; df=22; f=2.62; n=3), where conductivity and salinity returned the same p value for 2017 and 2018 as TDS respectively. There was a significant difference in chlorophyll a between the Bay West wetlands in 2017 (p<0.05; df=20; f=3.29; n=3) and Wetland Seven measured eutrophic at 22.45 mg/L-1. Remote sensing red band values and the field sample absorption values were highly correlated at R2= 0.5. Chlorophyll a content of wetland water correlated with NDVI data at R2= 0.6. Thus, remote sensing proved to be a successful estimator for wetlands health analysis and a proxy for wetland management. These results yielded an environmental management plan where monitoring water quality via chlorophyll a indicated health levels of the wetlands via trophic state.
- Full Text:
- Date Issued: 2018
- Authors: Domoney, Nicola Leah
- Date: 2018
- Subjects: Wetland management -- South Africa -- Nelson Mandela Bay Municipality , Remote sensing Chlorophyll
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/30854 , vital:31183
- Description: South Africa is a semi-arid country and thus depends on sound management of its water resources. Wetlands, despite their importance to water resource storage and water quality, among their other ecological and social significance, remain the most threatened of South Africa’s ecosystems. One of their greatest threats is encroachment by urbanisation. This occurs because wetlands, and especially ephemeral urban periphery wetlands, are overlooked. This study’s main objective was to determine the water quality and health of the wetlands adjacent to the newly established Bay West development on the western urban periphery of Nelson Mandela Bay. Wetlands are difficult to access and it is time-consuming to assess them. Remote sensing, however, overcomes this challenge and is cost-effective and time-considerate. It was the aim of this study to assess the health of the peri-urban wetlands on the Bay West periphery in order to formulate an appropriate environmental management plan, and remote sensing was tested as an effective method for wetland health management. It was found that the wetlands closer to the urban residential area (Sherwood suburb) were far more impacted than the wetlands nearer to Bay West Mall. Wetlands Six to Eight were higher in all parameters of pH, total dissolved solutes (TDS), salinity, conductivity and chlorophyll a concentration than Wetlands One to Five located further away from the urban area. A correlation with distance away from the urban area found a strong inverse relationship with between distance and the water quality factor, yielding a correlation coefficient of (<-0.7) in 2017 and (<-0.9) in 2018 with regard to TDS, salinity and conductivity. This, therefore, suggests that the wetlands’ health deteriorates towards the urban area. TDS, salinity, pH and conductivity correlate highly with chlorophyll a concentration at (>0.70). There was significant difference in pH in the year 2017 between the Bay West wetlands and the reference wetland (p<0.05; df=19; f= 3.56; n=3) and in 2018 (p<0.01; df=22; f= 8.90; n=3). No significant difference was found between the wetlands for dissolved oxygen. TDS between the wetlands was found to be significantly different in the year 2017 (p<0.01; df=23; f= 44.16; n=3) and 2018 (p<0.05; df=22; f=2.62; n=3), where conductivity and salinity returned the same p value for 2017 and 2018 as TDS respectively. There was a significant difference in chlorophyll a between the Bay West wetlands in 2017 (p<0.05; df=20; f=3.29; n=3) and Wetland Seven measured eutrophic at 22.45 mg/L-1. Remote sensing red band values and the field sample absorption values were highly correlated at R2= 0.5. Chlorophyll a content of wetland water correlated with NDVI data at R2= 0.6. Thus, remote sensing proved to be a successful estimator for wetlands health analysis and a proxy for wetland management. These results yielded an environmental management plan where monitoring water quality via chlorophyll a indicated health levels of the wetlands via trophic state.
- Full Text:
- Date Issued: 2018
Extraction of diallyl sulfides and other similar compounds from tulbaghia violacea, a South African plant, for potential use as devulcanizing agents
- Authors: Sonti, Thembela Celia
- Date: 2018
- Subjects: Violaceae -- South Africa , Plant extracts Plant products Traditional medicine
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: http://hdl.handle.net/10948/23338 , vital:30533
- Description: Tulbaghia violacea is a plant that is commonly used for traditional medicine in the Eastern Cape and Kwa-Zulu Natal Provinces of South Africa for treatment of ailments, such as fever, colds, asthma, tuberculosis, stomach-ache and cancer of the oesophagus. This plant has been found to be rich in sulfur-containing compounds that may display good potential as devulcanizing agents. Commonly used chemical devulcanizing agents are disulfides, such as diphenyl disulfide. These have been found to be relatively expensive compared to other methods of devulcanization. This study aimed to show that the sulfur- containing compounds extracted from the readily available Tulbaghia violacea plant can be used as devulcanizing agents. The presence of sulfur-containing compounds in the plant was positively identified by qualitative phytochemical analysis. Extraction of sulfur-containing compounds from the bulk plant material was successfully performed using the Soxhlet extraction method with a 2% 2-propanol in n-hexane solvent mixture. There was a positive identification of sulfur compounds in the crude extracts of the bulbs, roots and leaves. Diallyl disulfides (DADS) extracted from the plant were successfully quantified using normal phase high-performance liquid chromatography (HPLC). The results showed that in a bulb crude extract of 9.89 mg/mL concentration, there was 7.74X10-2 mg/mL concentration of DADS. In the roots crude extract of 10.26 mg/mL concentration, there was 2.93X10-2 mg/mL concentration of DADS; and in leaves crude extract of 10.47 mg/mL concentration, there was 3.69X10-2 mg/mL concentration of DADS. The crude extracts were evaluated for their effectiveness as devulcanizing agents by reacting them with vulcanized 2,3-dimethyl-2-butene (TME), which was used as a model compound. A reverse phase HPLC method was used to identify crosslink species formed during vulcanization, and to monitor the broken crosslinks during devulcanization. It was observed that the di- and polysulfidic crosslinked vulcanized model compound species were not present in the devulcanized product. Furthermore monosulfidic crosslink species, a common end species of devulcanization, were observed to increase in concentration from the HPLC chromatograms. It was observed that the extracts from the bulbs and leaves of Tulbaghia violacea were more effective than the extract from the roots when applied to the vulcanized model compound. This study demonstrates that Tulbaghia violacea can be used as alternatives to petroleum-derived chemicals as devulcanizing agents.
- Full Text:
- Date Issued: 2018
- Authors: Sonti, Thembela Celia
- Date: 2018
- Subjects: Violaceae -- South Africa , Plant extracts Plant products Traditional medicine
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: http://hdl.handle.net/10948/23338 , vital:30533
- Description: Tulbaghia violacea is a plant that is commonly used for traditional medicine in the Eastern Cape and Kwa-Zulu Natal Provinces of South Africa for treatment of ailments, such as fever, colds, asthma, tuberculosis, stomach-ache and cancer of the oesophagus. This plant has been found to be rich in sulfur-containing compounds that may display good potential as devulcanizing agents. Commonly used chemical devulcanizing agents are disulfides, such as diphenyl disulfide. These have been found to be relatively expensive compared to other methods of devulcanization. This study aimed to show that the sulfur- containing compounds extracted from the readily available Tulbaghia violacea plant can be used as devulcanizing agents. The presence of sulfur-containing compounds in the plant was positively identified by qualitative phytochemical analysis. Extraction of sulfur-containing compounds from the bulk plant material was successfully performed using the Soxhlet extraction method with a 2% 2-propanol in n-hexane solvent mixture. There was a positive identification of sulfur compounds in the crude extracts of the bulbs, roots and leaves. Diallyl disulfides (DADS) extracted from the plant were successfully quantified using normal phase high-performance liquid chromatography (HPLC). The results showed that in a bulb crude extract of 9.89 mg/mL concentration, there was 7.74X10-2 mg/mL concentration of DADS. In the roots crude extract of 10.26 mg/mL concentration, there was 2.93X10-2 mg/mL concentration of DADS; and in leaves crude extract of 10.47 mg/mL concentration, there was 3.69X10-2 mg/mL concentration of DADS. The crude extracts were evaluated for their effectiveness as devulcanizing agents by reacting them with vulcanized 2,3-dimethyl-2-butene (TME), which was used as a model compound. A reverse phase HPLC method was used to identify crosslink species formed during vulcanization, and to monitor the broken crosslinks during devulcanization. It was observed that the di- and polysulfidic crosslinked vulcanized model compound species were not present in the devulcanized product. Furthermore monosulfidic crosslink species, a common end species of devulcanization, were observed to increase in concentration from the HPLC chromatograms. It was observed that the extracts from the bulbs and leaves of Tulbaghia violacea were more effective than the extract from the roots when applied to the vulcanized model compound. This study demonstrates that Tulbaghia violacea can be used as alternatives to petroleum-derived chemicals as devulcanizing agents.
- Full Text:
- Date Issued: 2018