Wild vegetables of the Eastern Cape of South Africa: the nutritional value and domestication of solanum nigrum l
- Authors: Bvenura, Callistus
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Ethnobotany)
- Identifier: vital:11885 , http://hdl.handle.net/10353/d1015514
- Description: An ethnobotanical survey was conducted in Alice and Willowvale in the Nkonkobe and Mbashe municipalities of the Eastern Cape Province, South Africa to identify and document wild vegetables growing in the areas. The survey documented 22 vegetable species belonging to 12 different families. The Amaryllidaceae, Amaranthaceae, Apiaceae, Asteraceae, Caryophyllaceae, Chenopodiaceae, Convolvulaceae, Cruciferae, Cucurbitaceaea, Euphorbiaceae, Tiliaceae, Solanaceae, Polygonaceae and Urticaceae were the families that were recorded. The species were Tulbaghia violacea Harv., Amaranthus blitoides S., Amaranthus blitum L., Amaranthus hybridus L., Centella coriacea Nannfd., Bidens pilosa L, Cotula heterocarpa DC., Sonchus oleraceus L., Galinsoga parviflora Cav., Taraxacum officinale Weber, Hypochaeris radicata L., Stellaria media L., Chenopodium album L., Chenopodium murale L., Ipomoea batatas L., Sisymbrium thellungii O. Schulz, Cucurbita pepo L., Rumex crispus L., Acalypha virginica L., Nicandra physalodes L., Physalis peruviana L., Solanum nigrum L., Urtica urens L. and Corchorus olitorius L. About 27 % of the wild vegetables were native to South Africa and about 45 % were also used as medicinal plants in the areas. Sun drying was the most common method of preserving the wild vegetables for the off season months. This study also revealed that, men and the younger generation knew less about wild vegetables than the women. The study also revealed a loss of knowledge of wild vegetables and their use by the rural dwellers who are more in favour of the exotic types such as spinach and cabbage.
- Full Text:
- Date Issued: 2014
- Authors: Bvenura, Callistus
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Ethnobotany)
- Identifier: vital:11885 , http://hdl.handle.net/10353/d1015514
- Description: An ethnobotanical survey was conducted in Alice and Willowvale in the Nkonkobe and Mbashe municipalities of the Eastern Cape Province, South Africa to identify and document wild vegetables growing in the areas. The survey documented 22 vegetable species belonging to 12 different families. The Amaryllidaceae, Amaranthaceae, Apiaceae, Asteraceae, Caryophyllaceae, Chenopodiaceae, Convolvulaceae, Cruciferae, Cucurbitaceaea, Euphorbiaceae, Tiliaceae, Solanaceae, Polygonaceae and Urticaceae were the families that were recorded. The species were Tulbaghia violacea Harv., Amaranthus blitoides S., Amaranthus blitum L., Amaranthus hybridus L., Centella coriacea Nannfd., Bidens pilosa L, Cotula heterocarpa DC., Sonchus oleraceus L., Galinsoga parviflora Cav., Taraxacum officinale Weber, Hypochaeris radicata L., Stellaria media L., Chenopodium album L., Chenopodium murale L., Ipomoea batatas L., Sisymbrium thellungii O. Schulz, Cucurbita pepo L., Rumex crispus L., Acalypha virginica L., Nicandra physalodes L., Physalis peruviana L., Solanum nigrum L., Urtica urens L. and Corchorus olitorius L. About 27 % of the wild vegetables were native to South Africa and about 45 % were also used as medicinal plants in the areas. Sun drying was the most common method of preserving the wild vegetables for the off season months. This study also revealed that, men and the younger generation knew less about wild vegetables than the women. The study also revealed a loss of knowledge of wild vegetables and their use by the rural dwellers who are more in favour of the exotic types such as spinach and cabbage.
- Full Text:
- Date Issued: 2014
Aggregate stability, crust formation, steady state infiltration and mode of seedling emergence in soils with various texture and mineralogy
- Authors: Nciizah, Adornis Dakarai
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Crop Science)
- Identifier: vital:11871 , http://hdl.handle.net/10353/d1015539
- Description: The general objective of this study was to quantify the interactive effects of soil texture and mineralogy on soil crusting, infiltration and erosion and the subsequent effects on maize seedling emergence and early development using soils collected from 14 ecotopes in the Eastern Cape Province. The specific objectives were to determine; i) particulate organic matter, soil texture and mineralogy relations, ii) aggregate stability and breakdown mechanisms as affected by soil texture and organic matter, iii) crust formation and steady state infiltration, iv) rainfall pattern effects on crusting, infiltration and erodibility and v) rainfall intensity effects on crusting and mode of seedling emergence. Particulate organic matter (POM) was fractionated into litter POM, coarse POM and fine POM. Both total soil organic matter (SOM) and the POM in each fraction were determined using the weight loss on ignition procedure. Most ecotopes were either sandy loam or sandy clay loam and primary minerals especially quartz dominated the soil mineralogy. The clay content was significantly related to the total SOM (r = 0.78), hematite (r = 0.83) and quartz (r = -0.74). Aggregate stability was determined following methods described by Le Bissonnais (1996) i.e. fast wetting (FW), slow wetting (SW) and wet stirring (WSt). Aggregate breakdown followed the order; slaking < mechanical breakdown < micro-cracking for most ecotopes except Lujiko Leeufontein and Amatola Jozini where SW and WSt resulted in the least MWD respectively. Aggregate stability was significantly correlated to POM only for FW and SW and only positive but not significant for WSt. To study crust formation, aggregate sizes <2, 2 to 3, 3 to 5 mm were exposed to 60 mm hr-1 simulated rainfall. Sieving structural crusts, ~0.2 to ~0.8 mm thick with a surface layer of loose grains overlying a thin plasmic layer, formed in all ecotopes. Crusts with strengths between 0.25 and 3.42 10-4 kg m-2 developed on the <2 mm compared to <2.23 10-4 kg m-2 in the >2 mm aggregates. The reverse occurred in Alice Jozini, which had relatively low clay content of 120 g kg-1. Two significantly different groups of the SSIR were observed. The SSIR was between 1.24 and 3.60 mm hr-1 in the group of ecotopes dominated by primary minerals and relatively lower clay content. In the second group, consisting one ecotope dominated by kaolinite and relatively higher clay content, the SSIR was 15.23 mm hr-1. Rainfall pattern i.e. rainfall applied either as an eight minute single rainstorm (SR) or four-two minute intermittent rainstorms (IR) separated by a 48 h drying period significantly (p < 0.05) affected crust strength, SSIR and erosion. The IR resulted in higher crust strength and SSIR than SR. The effect of rainfall pattern on SSIR was mostly influenced by the primary minerals namely, quartz. Three maize seeds of equal size were planted in plastic pots, pre-wetted by capillary action and then subjected to simulated rainfall at three intensities for 5 min. Rainfall intensity (30, 45 and 60 mm h-1) significantly (P < 0.05) affected crust strength and mean emergence day (MED) but not emergence percentage (EMP) and shoot length (P > 0.05). The 60 mm h-1 rainfall intensity resulted in the highest crust strength and MED.
- Full Text:
- Date Issued: 2014
- Authors: Nciizah, Adornis Dakarai
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Crop Science)
- Identifier: vital:11871 , http://hdl.handle.net/10353/d1015539
- Description: The general objective of this study was to quantify the interactive effects of soil texture and mineralogy on soil crusting, infiltration and erosion and the subsequent effects on maize seedling emergence and early development using soils collected from 14 ecotopes in the Eastern Cape Province. The specific objectives were to determine; i) particulate organic matter, soil texture and mineralogy relations, ii) aggregate stability and breakdown mechanisms as affected by soil texture and organic matter, iii) crust formation and steady state infiltration, iv) rainfall pattern effects on crusting, infiltration and erodibility and v) rainfall intensity effects on crusting and mode of seedling emergence. Particulate organic matter (POM) was fractionated into litter POM, coarse POM and fine POM. Both total soil organic matter (SOM) and the POM in each fraction were determined using the weight loss on ignition procedure. Most ecotopes were either sandy loam or sandy clay loam and primary minerals especially quartz dominated the soil mineralogy. The clay content was significantly related to the total SOM (r = 0.78), hematite (r = 0.83) and quartz (r = -0.74). Aggregate stability was determined following methods described by Le Bissonnais (1996) i.e. fast wetting (FW), slow wetting (SW) and wet stirring (WSt). Aggregate breakdown followed the order; slaking < mechanical breakdown < micro-cracking for most ecotopes except Lujiko Leeufontein and Amatola Jozini where SW and WSt resulted in the least MWD respectively. Aggregate stability was significantly correlated to POM only for FW and SW and only positive but not significant for WSt. To study crust formation, aggregate sizes <2, 2 to 3, 3 to 5 mm were exposed to 60 mm hr-1 simulated rainfall. Sieving structural crusts, ~0.2 to ~0.8 mm thick with a surface layer of loose grains overlying a thin plasmic layer, formed in all ecotopes. Crusts with strengths between 0.25 and 3.42 10-4 kg m-2 developed on the <2 mm compared to <2.23 10-4 kg m-2 in the >2 mm aggregates. The reverse occurred in Alice Jozini, which had relatively low clay content of 120 g kg-1. Two significantly different groups of the SSIR were observed. The SSIR was between 1.24 and 3.60 mm hr-1 in the group of ecotopes dominated by primary minerals and relatively lower clay content. In the second group, consisting one ecotope dominated by kaolinite and relatively higher clay content, the SSIR was 15.23 mm hr-1. Rainfall pattern i.e. rainfall applied either as an eight minute single rainstorm (SR) or four-two minute intermittent rainstorms (IR) separated by a 48 h drying period significantly (p < 0.05) affected crust strength, SSIR and erosion. The IR resulted in higher crust strength and SSIR than SR. The effect of rainfall pattern on SSIR was mostly influenced by the primary minerals namely, quartz. Three maize seeds of equal size were planted in plastic pots, pre-wetted by capillary action and then subjected to simulated rainfall at three intensities for 5 min. Rainfall intensity (30, 45 and 60 mm h-1) significantly (P < 0.05) affected crust strength and mean emergence day (MED) but not emergence percentage (EMP) and shoot length (P > 0.05). The 60 mm h-1 rainfall intensity resulted in the highest crust strength and MED.
- Full Text:
- Date Issued: 2014
Synthesis, characterization, and biological studies of pyrazolone Schiff bases and their transition metal complexes
- Authors: Idemudia, Omoruyi Gold
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11340 , http://hdl.handle.net/10353/d1016068
- Description: Some new acylpyrazolone Schiff bases have been synthesized from the condensation reaction of two acylpyrazolone diketone precursors with phenylhydrazine, 2,4-dinitrophenylhydrazine and sulfanilamide. They have been fully characterized by elemental analysis and spectroscopic techniques (IR,1H and 13C NMR, and mass-spectra). The single crystal structure of the benzoyl derivative acylpyrazolone Schiff bases have been obtained and analyzed by X-ray crystallography technique. Solid state X-ray diffraction revealed a keto tautomer Schiff base in solid state. Mn(II), Co(II), Ni(II) and Cu(II) complexes with the Schiff bases have been synthesized and characterized by elemental analysis, IR and UV-VIS spectroscopy, magnetic susceptibility measurements, and thermal studies (TGA and DTG). An octahedral geometry around the transition metal ion, consisting of two bidentate Schiff base ligands bonding through the azometine nitrogen and ketonic oxygen have been proposed based on careful interpretation of available analytical and spectroscopic characterization results. Two water molecules as ligands complete the octahedral geometry in all cases. Using the invitro disc diffusion method for screening synthesized compounds against selected gram positive and gram negative bacterial at 40 mg/mL, and the DPPH free radical scavenging methods at 0.50, 0.25 and 0.13 mg/mL, the synthesized Schiff base and metal complexes showed varying biological activities. 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one sul29 fanilamide showed more activity generally, exhibiting a broad spectrum activity against all selected bacterial in some cases. Mn(II), Co(II) and Ni(II) complexes of sulfanilamide Schiff base with the acetylpyrazolone derivative 4-acetyl-3-methyl-1-phenyl-2-pyrazolin-5-one sulfanilamide, exhibited a stronger and very good DPPH radical scavenging activity as good as ascorbic acid on comparing, but not with Cu(II). As such they could be important antitumour candidates.
- Full Text:
- Date Issued: 2014
- Authors: Idemudia, Omoruyi Gold
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11340 , http://hdl.handle.net/10353/d1016068
- Description: Some new acylpyrazolone Schiff bases have been synthesized from the condensation reaction of two acylpyrazolone diketone precursors with phenylhydrazine, 2,4-dinitrophenylhydrazine and sulfanilamide. They have been fully characterized by elemental analysis and spectroscopic techniques (IR,1H and 13C NMR, and mass-spectra). The single crystal structure of the benzoyl derivative acylpyrazolone Schiff bases have been obtained and analyzed by X-ray crystallography technique. Solid state X-ray diffraction revealed a keto tautomer Schiff base in solid state. Mn(II), Co(II), Ni(II) and Cu(II) complexes with the Schiff bases have been synthesized and characterized by elemental analysis, IR and UV-VIS spectroscopy, magnetic susceptibility measurements, and thermal studies (TGA and DTG). An octahedral geometry around the transition metal ion, consisting of two bidentate Schiff base ligands bonding through the azometine nitrogen and ketonic oxygen have been proposed based on careful interpretation of available analytical and spectroscopic characterization results. Two water molecules as ligands complete the octahedral geometry in all cases. Using the invitro disc diffusion method for screening synthesized compounds against selected gram positive and gram negative bacterial at 40 mg/mL, and the DPPH free radical scavenging methods at 0.50, 0.25 and 0.13 mg/mL, the synthesized Schiff base and metal complexes showed varying biological activities. 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one sul29 fanilamide showed more activity generally, exhibiting a broad spectrum activity against all selected bacterial in some cases. Mn(II), Co(II) and Ni(II) complexes of sulfanilamide Schiff base with the acetylpyrazolone derivative 4-acetyl-3-methyl-1-phenyl-2-pyrazolin-5-one sulfanilamide, exhibited a stronger and very good DPPH radical scavenging activity as good as ascorbic acid on comparing, but not with Cu(II). As such they could be important antitumour candidates.
- Full Text:
- Date Issued: 2014
The impact of export diversification on economic performance in South Africa: 1980-2012
- Authors: Choga, Ireen
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , Doctor of Commerce (in Economics)
- Identifier: vital:11489 , http://hdl.handle.net/10353/d1018223
- Description: A widely held view is that export diversification constitutes an important component of export led growth, and poses a major challenge for many developing countries. Given this, the role of export diversification on economic growth warrants a fresh analysis in South Africa. The primary objective of this study is to determine the impact of export diversification on economic growth in South Africa. In this context, the study seeks to establish the relationship between export diversification, export stability and export growth. Initially, the study examines the extent and structure of export diversification in South Africa; it then empirically establishes the link between export diversification, export stability and export growth. Finally, it develops a model and investigates the effects of export diversification on economic growth in South Africa. As an attempt to fulfill the proposed objectives, this study uses quarterly data for the period 1980 to 2012 as well as data for 28 selected groups of commodities to investigate the effects of export diversification on economic growth in South Africa. Measures of export diversification and structural changes in exports in the context of South Africa were discussed. The findings of this study are that the Commodity Specific Cumulative Experience function showed that plots for manufactured commodities are shifted to the right indicating that the commodities are non-traditional in nature whereas, plots for primary commodities are shifted to the left. Results also indicated that South Africa relies more on traditional exports than manufactured exports. Various measures of export instability were used to calculate the export instability index in South Africa. The results of the study reveal that the South African export basket is slightly diversified, and the less diversified or primary commodities are associated with high instability VECM approach was used to allow us to establish the extent of influence of export diversification and other explanatory variables on economic growth. Consistent with other researchers, the study found that export diversification plays significant roles to economic growth in South Africa. A number of diagnostic checks were employed to validate the parameter evaluation of the outcomes achieved by the model. The model passed all the diagnostic checks. On the whole, the results to a larger extent painted a pictured that export diversification is important or drives economic growth in South Africa. Corroborating our findings with work of other scholars, we conclude that our results are complementary.
- Full Text:
- Date Issued: 2014
- Authors: Choga, Ireen
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , Doctor of Commerce (in Economics)
- Identifier: vital:11489 , http://hdl.handle.net/10353/d1018223
- Description: A widely held view is that export diversification constitutes an important component of export led growth, and poses a major challenge for many developing countries. Given this, the role of export diversification on economic growth warrants a fresh analysis in South Africa. The primary objective of this study is to determine the impact of export diversification on economic growth in South Africa. In this context, the study seeks to establish the relationship between export diversification, export stability and export growth. Initially, the study examines the extent and structure of export diversification in South Africa; it then empirically establishes the link between export diversification, export stability and export growth. Finally, it develops a model and investigates the effects of export diversification on economic growth in South Africa. As an attempt to fulfill the proposed objectives, this study uses quarterly data for the period 1980 to 2012 as well as data for 28 selected groups of commodities to investigate the effects of export diversification on economic growth in South Africa. Measures of export diversification and structural changes in exports in the context of South Africa were discussed. The findings of this study are that the Commodity Specific Cumulative Experience function showed that plots for manufactured commodities are shifted to the right indicating that the commodities are non-traditional in nature whereas, plots for primary commodities are shifted to the left. Results also indicated that South Africa relies more on traditional exports than manufactured exports. Various measures of export instability were used to calculate the export instability index in South Africa. The results of the study reveal that the South African export basket is slightly diversified, and the less diversified or primary commodities are associated with high instability VECM approach was used to allow us to establish the extent of influence of export diversification and other explanatory variables on economic growth. Consistent with other researchers, the study found that export diversification plays significant roles to economic growth in South Africa. A number of diagnostic checks were employed to validate the parameter evaluation of the outcomes achieved by the model. The model passed all the diagnostic checks. On the whole, the results to a larger extent painted a pictured that export diversification is important or drives economic growth in South Africa. Corroborating our findings with work of other scholars, we conclude that our results are complementary.
- Full Text:
- Date Issued: 2014
Training of teachers in multigrade teaching: integration of vertical and horizontal knowledge in post -training
- Authors: Ganqa, Ncumisa Hazel
- Date: 2014
- Subjects: Combination of grades -- Cross-cultural studies Teachers -- In-service training Teachers
- Language: English
- Type: Thesis , Doctoral , PhD (Education)
- Identifier: http://hdl.handle.net/10353/6158 , vital:29496
- Description: The purpose of this study was to examine the training and development of teachers in multi-grade teaching in selected Eastern Cape primary schools with a particular focus on the integration of vertical and horizontal knowledge in post-training. Multigrade teaching is the combining of learners of different grade levels in one classroom taught by one teacher. To gain better understanding of the construct of vertical and horizontal integration of knowledge within post-training environment, this qualitative case study design sampled eight teachers, four school principals and three trainers, purposively. In order to evaluate the training and development provided for teachers in multi-grade classrooms the researcher examined the training programmes, the training curriculum and transfer of training inputs. The results of the study indicate that post-training is the determinant of the extent of the effectiveness of the transfer of training skills, knowledge and attitudes gained in multi-grade teaching training. The study found a massive gap that currently exists between training in multi-grade teaching and the actual transferability of such training in multi-grade contexts. Positive transfer of training in multi-grade teaching strategies was found to be skills related to teaching strategies, lesson management, curriculum integration and social components of multi-grade teaching. Negative transfer of training included classroom organisation, lesson planning, timetabling, curriculum adaptation and assessment. Although multi-grade teacher training programme is assumed to change behaviours, attitudes, impart knowledge and improve teaching skills, the results of the study indicate that training inputs might not necessarily transform into classroom practice. In order to facilitate and ensure vertical and horizontal integration of knowledge and skills and transfer of training to classroombased teaching, recurrent training in multi-grade teaching is therefore, suggested.
- Full Text:
- Date Issued: 2014
- Authors: Ganqa, Ncumisa Hazel
- Date: 2014
- Subjects: Combination of grades -- Cross-cultural studies Teachers -- In-service training Teachers
- Language: English
- Type: Thesis , Doctoral , PhD (Education)
- Identifier: http://hdl.handle.net/10353/6158 , vital:29496
- Description: The purpose of this study was to examine the training and development of teachers in multi-grade teaching in selected Eastern Cape primary schools with a particular focus on the integration of vertical and horizontal knowledge in post-training. Multigrade teaching is the combining of learners of different grade levels in one classroom taught by one teacher. To gain better understanding of the construct of vertical and horizontal integration of knowledge within post-training environment, this qualitative case study design sampled eight teachers, four school principals and three trainers, purposively. In order to evaluate the training and development provided for teachers in multi-grade classrooms the researcher examined the training programmes, the training curriculum and transfer of training inputs. The results of the study indicate that post-training is the determinant of the extent of the effectiveness of the transfer of training skills, knowledge and attitudes gained in multi-grade teaching training. The study found a massive gap that currently exists between training in multi-grade teaching and the actual transferability of such training in multi-grade contexts. Positive transfer of training in multi-grade teaching strategies was found to be skills related to teaching strategies, lesson management, curriculum integration and social components of multi-grade teaching. Negative transfer of training included classroom organisation, lesson planning, timetabling, curriculum adaptation and assessment. Although multi-grade teacher training programme is assumed to change behaviours, attitudes, impart knowledge and improve teaching skills, the results of the study indicate that training inputs might not necessarily transform into classroom practice. In order to facilitate and ensure vertical and horizontal integration of knowledge and skills and transfer of training to classroombased teaching, recurrent training in multi-grade teaching is therefore, suggested.
- Full Text:
- Date Issued: 2014
Dialogic pedagogical innovation for liberating learning practices: a case of one programme in a higher education institution in South Africa
- Authors: Mudehwe, Florence Rutendo
- Date: 2014
- Subjects: Educational change -- South Africa , School improvement programs -- South Africa , Critical pedagogy , Curriculum evaluation -- South Africa , Education --Study and teaching
- Language: English
- Type: Thesis , Doctoral , PhD (Education)
- Identifier: vital:16225 , http://hdl.handle.net/10353/d1019737 , Educational change -- South Africa , School improvement programs -- South Africa , Critical pedagogy , Curriculum evaluation -- South Africa , Education --Study and teaching
- Description: The past two to three decades have seen unprecedented expansion in enrolments in Universities across the world. Increased participation rates in Higher Education, however, has not been matched by a corresponding increase in success rates as reflected in students' poor retention rates and unsatisfactory outcomes. One strand of explanation claims that students, for a variety of reasons, come to university `unprepared' and suffer an articulation gap in the transition between high school and university; the other explanation seeks to move away from the deficit perspective and puts emphasis on the need to enrich experiences of students to enable them to exercise agency and change constraining circumstances in order to succeed. This study reports on one programme, a grounding programme known as the Life, Knowledge and Action (LKA) in one South African university. One of the central purposes of the LKA is to enrich students' first year experiences through liberating dialogue embedded in its pedagogical architecture. A sequential mixed methods study was carried out. A survey of first year students who had been exposed to the LKA was first carried out. This was followed by a case study of purposively selected first year students. Findings show that LKA promoted dialogue in varied ways depending on the level of the pedagogical architecture. At Umzi level students as peers across disciplines exchanged ideas freely about their circumstances and social issues. At the Ekhaya level where the abakwezeli (facilitators) were active, power dynamics emerged between students and the facilitators which had the effect of diminishing dialogical moments. At village level, there was not much discussion; instead there was a lot of lecturing. Dialogue was limited to a few minutes of discussion at the end of the lecture. The other finding was that seen from Archer's lens of morphogenetic analysis, the `articulation gap' can be seen as a structural constraint, that can be addressed through liberating dialogue which enables the students to question the status quo. There was evidence that through dialogue in the LKA, students felt that it liberated them in the sense that it exposed them to different perspectives as well as enabled them to explore alternatives. It can be concluded that through an appropriately designed dialogical pedagogy, students can be empowered to transform the structural constraints to their education and create enablers that can help them succeed in their learning. There is evidence that within the LKA pedagogical architecture, the students have the opportunity to take responsibility for their learning and thus enabled to exercise agency. It is recommended that the processes that take place at each level of the LKA architecture must be further studied with a view to discovering mechanisms at work that may undermine the liberating thrust of the programme. As a liberating core curriculum, LKA must not be limited to first year students; consideration must be given to roll it out across the levels of the undergraduate offerings.
- Full Text:
- Date Issued: 2014
- Authors: Mudehwe, Florence Rutendo
- Date: 2014
- Subjects: Educational change -- South Africa , School improvement programs -- South Africa , Critical pedagogy , Curriculum evaluation -- South Africa , Education --Study and teaching
- Language: English
- Type: Thesis , Doctoral , PhD (Education)
- Identifier: vital:16225 , http://hdl.handle.net/10353/d1019737 , Educational change -- South Africa , School improvement programs -- South Africa , Critical pedagogy , Curriculum evaluation -- South Africa , Education --Study and teaching
- Description: The past two to three decades have seen unprecedented expansion in enrolments in Universities across the world. Increased participation rates in Higher Education, however, has not been matched by a corresponding increase in success rates as reflected in students' poor retention rates and unsatisfactory outcomes. One strand of explanation claims that students, for a variety of reasons, come to university `unprepared' and suffer an articulation gap in the transition between high school and university; the other explanation seeks to move away from the deficit perspective and puts emphasis on the need to enrich experiences of students to enable them to exercise agency and change constraining circumstances in order to succeed. This study reports on one programme, a grounding programme known as the Life, Knowledge and Action (LKA) in one South African university. One of the central purposes of the LKA is to enrich students' first year experiences through liberating dialogue embedded in its pedagogical architecture. A sequential mixed methods study was carried out. A survey of first year students who had been exposed to the LKA was first carried out. This was followed by a case study of purposively selected first year students. Findings show that LKA promoted dialogue in varied ways depending on the level of the pedagogical architecture. At Umzi level students as peers across disciplines exchanged ideas freely about their circumstances and social issues. At the Ekhaya level where the abakwezeli (facilitators) were active, power dynamics emerged between students and the facilitators which had the effect of diminishing dialogical moments. At village level, there was not much discussion; instead there was a lot of lecturing. Dialogue was limited to a few minutes of discussion at the end of the lecture. The other finding was that seen from Archer's lens of morphogenetic analysis, the `articulation gap' can be seen as a structural constraint, that can be addressed through liberating dialogue which enables the students to question the status quo. There was evidence that through dialogue in the LKA, students felt that it liberated them in the sense that it exposed them to different perspectives as well as enabled them to explore alternatives. It can be concluded that through an appropriately designed dialogical pedagogy, students can be empowered to transform the structural constraints to their education and create enablers that can help them succeed in their learning. There is evidence that within the LKA pedagogical architecture, the students have the opportunity to take responsibility for their learning and thus enabled to exercise agency. It is recommended that the processes that take place at each level of the LKA architecture must be further studied with a view to discovering mechanisms at work that may undermine the liberating thrust of the programme. As a liberating core curriculum, LKA must not be limited to first year students; consideration must be given to roll it out across the levels of the undergraduate offerings.
- Full Text:
- Date Issued: 2014
Determinants of psycho-social well-being of informal caregivers of physically challenged children in South-Western Nigeria
- Authors: Oyeleke, Isaac Ajiboye
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Social Work)
- Identifier: vital:11767 , http://hdl.handle.net/10353/d1015356
- Description: Informal caregiving denotes care that is provided by a family member or friend rather than by a professional who is reimbursed for services. Assuming a caregiving role can be stressful and burdensome. The effects of caregiving on the caregiver's health are moderated by individual differences in resources and vulnerabilities, such as socioeconomic status, prior health status, and level of social support. This work describes the determinant of psycho-social well-being of informal caregivers of physically challenged children in southwest of Nigeria. This study is guided theoretically by Ryff”s psychosocial well-being theory, The study adopted expo facto research design. Multistage samplings involving the use of random and purposive techniques were used to select 812 respondents who are informal caregivers. Social support questionnaire, Social support satisfaction level, Ryff’s psychological well-being scale were used. Findings indicated that social support predicted psycho-social well-being of informal caregivers of physically challenged children. Social support and satisfaction level combine together have impact on psycho-social well-being of informal caregivers of physically challenged children. More also, socio-economic factors such as occupation, educational level and income also predict psycho-social well-being of informal caregivers. Finally, marital status and gender also contribute to well-being of caregivers. It was therefore, recommended that social inclusion should be pursued with de-institutionalization of children with disability. Parents of children with disability should be encouraged to form support group and as well as encouraging fathers of children with disability to take an active part in ensuring their children with disability well-being. More also, there is need to empower informal caregivers through training and education. More importantly governments at the three levels ( Federal, State and local) should assist caregivers at ensuring their own and that of their children with disability well-being through improvement on various existing social welfare services in the country.
- Full Text:
- Date Issued: 2014
- Authors: Oyeleke, Isaac Ajiboye
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Social Work)
- Identifier: vital:11767 , http://hdl.handle.net/10353/d1015356
- Description: Informal caregiving denotes care that is provided by a family member or friend rather than by a professional who is reimbursed for services. Assuming a caregiving role can be stressful and burdensome. The effects of caregiving on the caregiver's health are moderated by individual differences in resources and vulnerabilities, such as socioeconomic status, prior health status, and level of social support. This work describes the determinant of psycho-social well-being of informal caregivers of physically challenged children in southwest of Nigeria. This study is guided theoretically by Ryff”s psychosocial well-being theory, The study adopted expo facto research design. Multistage samplings involving the use of random and purposive techniques were used to select 812 respondents who are informal caregivers. Social support questionnaire, Social support satisfaction level, Ryff’s psychological well-being scale were used. Findings indicated that social support predicted psycho-social well-being of informal caregivers of physically challenged children. Social support and satisfaction level combine together have impact on psycho-social well-being of informal caregivers of physically challenged children. More also, socio-economic factors such as occupation, educational level and income also predict psycho-social well-being of informal caregivers. Finally, marital status and gender also contribute to well-being of caregivers. It was therefore, recommended that social inclusion should be pursued with de-institutionalization of children with disability. Parents of children with disability should be encouraged to form support group and as well as encouraging fathers of children with disability to take an active part in ensuring their children with disability well-being. More also, there is need to empower informal caregivers through training and education. More importantly governments at the three levels ( Federal, State and local) should assist caregivers at ensuring their own and that of their children with disability well-being through improvement on various existing social welfare services in the country.
- Full Text:
- Date Issued: 2014
The establishment of a mobile phone information security culture: linking student awareness and behavioural intent
- Authors: Bukelwa, Ngoqo
- Date: 2014
- Subjects: Information security awareness -- Mobile phone security , Information safety
- Language: English
- Type: Thesis , Doctoral , PhD (Information Systems)
- Identifier: http://hdl.handle.net/10353/657 , vital:26485 , Information security awareness -- Mobile phone security , Information safety
- Description: The information security behaviour of technology users has become an increasingly popular research area as security experts have come to recognise that while securing technology by means of firewalls, passwords and offsite backups is important, such security may be rendered ineffective if the technology users themselves are not information security conscious. The mobile phone has become a necessity for many students but, at the same time, it exposes them to security threats that may result in a loss of information. Students in developing countries are at a disadvantage because they have limited access to information relating to information security threats, unlike their counterparts in more developed societies who can readily access this information from sources like the Internet. The developmental environment is plagued with challenges like access to the Internet or limited access to computers. The poor security behaviour exhibited by student mobile phone users, which was confirmed by the findings of this study, is of particular interest in the university context as most undergraduate students are offered a computer-related course which covers certain information security-related principles. During the restructuring of the South African higher education system, smaller universities and technikons (polytechnics) were merged to form comprehensive universities. Thus, the resultant South African university landscape is made up of traditional and comprehensive universities as well as universities of technology. Ordinarily, one would expect university students to have similar profiles. However in the case of this study, the environment was a unique factor which had a direct impact on students’ learning experiences and learning outcomes. Mbeki (2004) refers to two economies within South Africa the first one is financially sound and globally integrated, and the other found in urban and rural areas consists of unemployed and unemployable people who do not benefit from progress in the first economy. Action research was the methodological approach which was chosen for the purposes of this study to collect the requisite data among a population of university students from the ‘second economy’. The study focuses on the relationship between awareness and behavioural intention in understanding mobile phone user information security behaviour. The study concludes by proposing a behaviour profile forecasting framework based on predefined security behavioural profiles. A key finding of this study is that the security behaviour exhibited by mobile phone users is influenced by a combination of information security awareness and information security behavioural intention, and not just information security awareness.
- Full Text:
- Date Issued: 2014
- Authors: Bukelwa, Ngoqo
- Date: 2014
- Subjects: Information security awareness -- Mobile phone security , Information safety
- Language: English
- Type: Thesis , Doctoral , PhD (Information Systems)
- Identifier: http://hdl.handle.net/10353/657 , vital:26485 , Information security awareness -- Mobile phone security , Information safety
- Description: The information security behaviour of technology users has become an increasingly popular research area as security experts have come to recognise that while securing technology by means of firewalls, passwords and offsite backups is important, such security may be rendered ineffective if the technology users themselves are not information security conscious. The mobile phone has become a necessity for many students but, at the same time, it exposes them to security threats that may result in a loss of information. Students in developing countries are at a disadvantage because they have limited access to information relating to information security threats, unlike their counterparts in more developed societies who can readily access this information from sources like the Internet. The developmental environment is plagued with challenges like access to the Internet or limited access to computers. The poor security behaviour exhibited by student mobile phone users, which was confirmed by the findings of this study, is of particular interest in the university context as most undergraduate students are offered a computer-related course which covers certain information security-related principles. During the restructuring of the South African higher education system, smaller universities and technikons (polytechnics) were merged to form comprehensive universities. Thus, the resultant South African university landscape is made up of traditional and comprehensive universities as well as universities of technology. Ordinarily, one would expect university students to have similar profiles. However in the case of this study, the environment was a unique factor which had a direct impact on students’ learning experiences and learning outcomes. Mbeki (2004) refers to two economies within South Africa the first one is financially sound and globally integrated, and the other found in urban and rural areas consists of unemployed and unemployable people who do not benefit from progress in the first economy. Action research was the methodological approach which was chosen for the purposes of this study to collect the requisite data among a population of university students from the ‘second economy’. The study focuses on the relationship between awareness and behavioural intention in understanding mobile phone user information security behaviour. The study concludes by proposing a behaviour profile forecasting framework based on predefined security behavioural profiles. A key finding of this study is that the security behaviour exhibited by mobile phone users is influenced by a combination of information security awareness and information security behavioural intention, and not just information security awareness.
- Full Text:
- Date Issued: 2014
Integrating information and communications technology (ICT) into teaching and learning: the case of mathematics, science and technology education in one higher education institution
- Authors: Addam, Billey Bright Kwadwo
- Date: 2014
- Subjects: Educational teaching -- South Africa , Computer-assisted instruction -- South Africa , Mathematics -- Study and teaching -- South Africa , Science -- Study and teaching -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD (Education)
- Identifier: vital:16224 , http://hdl.handle.net/10353/d1019736 , Educational teaching -- South Africa , Computer-assisted instruction -- South Africa , Mathematics -- Study and teaching -- South Africa , Science -- Study and teaching -- South Africa
- Description: This study explores the integration of Information and Communication Technologies (ICT) into teaching and learning within one Higher Education institution. The main question driving the study was: How is ICT integrated in the teaching and learning of mathematics, science and technology education (MSTE) in a Bachelor of Education programme? This is a case study of lecturers and students in Mathematics, Science and Technology Education. It makes use of questionnaires, interviews, field notes and document analyses to collect data. MSTE lecturers and students were assumed to be well versed in ICT usage and, therefore, well placed to assess its integration into teaching and learning. There were five main findings: First, that Mathematics, Science and Technology Education lecturers showed some ambivalence in their ontological and epistemological orientation to using ICT. Some leaned towards the instruction paradigm and used ICT as a tool for the transmission of knowledge; others leaned towards the learning paradigm, showing an awareness of the need to elicit discovery through ICT. Secondly, that lecturers’ understanding of ICT integration was oriented towards teaching and learning from technologies rather than with technologies. Thirdly, that processes of ‘pedagogical evolution’ were taking place, in terms of which there was a gradual but perceptible shift in the teaching and learning practice of both students and lecturers. Fourthly, there was no evidence to show that lecturers used ICT to promote innovative and creative teaching; in fact, students appeared to be more creative in using ICT resources, than lecturers. Fifthly, and finally, lecturers did not assign ICT-based tasks that promote conceptual understanding. They assigned tasks that asked students to extract and reproduce information from computers, without demonstrating understanding. When used in this way, ICT can, in fact, be de-skilling. From these findings, it can be concluded that ICT integration cannot be understood without exploring the ontological and epistemological orientations, as well as the theoretical orientations, at play in the teaching and learning situation. It is on the basis of these that people, that is, lecturers and students, make use of, ICTs to achieve desired goals. It is therefore recommended that, for the improvement of integration, there should be a greater emphasis on developing and sharing pedagogical expertise concerning ICT use in teaching and learning. It is recommended that a country-wide research survey should be undertaken, based on probability sampling and focussing on pedagogical issues in ICT integration in teaching and learning.
- Full Text:
- Date Issued: 2014
- Authors: Addam, Billey Bright Kwadwo
- Date: 2014
- Subjects: Educational teaching -- South Africa , Computer-assisted instruction -- South Africa , Mathematics -- Study and teaching -- South Africa , Science -- Study and teaching -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD (Education)
- Identifier: vital:16224 , http://hdl.handle.net/10353/d1019736 , Educational teaching -- South Africa , Computer-assisted instruction -- South Africa , Mathematics -- Study and teaching -- South Africa , Science -- Study and teaching -- South Africa
- Description: This study explores the integration of Information and Communication Technologies (ICT) into teaching and learning within one Higher Education institution. The main question driving the study was: How is ICT integrated in the teaching and learning of mathematics, science and technology education (MSTE) in a Bachelor of Education programme? This is a case study of lecturers and students in Mathematics, Science and Technology Education. It makes use of questionnaires, interviews, field notes and document analyses to collect data. MSTE lecturers and students were assumed to be well versed in ICT usage and, therefore, well placed to assess its integration into teaching and learning. There were five main findings: First, that Mathematics, Science and Technology Education lecturers showed some ambivalence in their ontological and epistemological orientation to using ICT. Some leaned towards the instruction paradigm and used ICT as a tool for the transmission of knowledge; others leaned towards the learning paradigm, showing an awareness of the need to elicit discovery through ICT. Secondly, that lecturers’ understanding of ICT integration was oriented towards teaching and learning from technologies rather than with technologies. Thirdly, that processes of ‘pedagogical evolution’ were taking place, in terms of which there was a gradual but perceptible shift in the teaching and learning practice of both students and lecturers. Fourthly, there was no evidence to show that lecturers used ICT to promote innovative and creative teaching; in fact, students appeared to be more creative in using ICT resources, than lecturers. Fifthly, and finally, lecturers did not assign ICT-based tasks that promote conceptual understanding. They assigned tasks that asked students to extract and reproduce information from computers, without demonstrating understanding. When used in this way, ICT can, in fact, be de-skilling. From these findings, it can be concluded that ICT integration cannot be understood without exploring the ontological and epistemological orientations, as well as the theoretical orientations, at play in the teaching and learning situation. It is on the basis of these that people, that is, lecturers and students, make use of, ICTs to achieve desired goals. It is therefore recommended that, for the improvement of integration, there should be a greater emphasis on developing and sharing pedagogical expertise concerning ICT use in teaching and learning. It is recommended that a country-wide research survey should be undertaken, based on probability sampling and focussing on pedagogical issues in ICT integration in teaching and learning.
- Full Text:
- Date Issued: 2014
The implementation of inclusion policy for learners with special education needs in primary schools in Fort beafort district :Towards a rights based approach to education
- Authors: Adewumi, Toyin Mary
- Date: 2014
- Subjects: Inclusive education Education and state -- South Africa -- Eastern Cape Children with disabilities -- Education -- South Africa -- Eastern Cape Special education -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Degree
- Identifier: http://hdl.handle.net/10353/5873 , vital:29413
- Description: The implementation of inclusion policy for learners with special education needs as stipulated in the Education White Paper 2001has been an issue of concern for South African schools. This study sheds light on the implementation of inclusion policy for learners with special education needs in the selected primary schools in the Fort Beaufort District in the Eastern Cape Province in South Africa. The aim of the study is to examine the implementation of inclusion policy for learners with special education needs. The study was placed within the post-positivism paradigm and used a mixed method research approach that integrated concurrent procedures in the collection, analysis and interpretation of the data. Questionnaires were used to collect quantitative data while qualitative data were collected through interviews, and document analysis. A total number of 30 teachers completed the questionnaires. The researcher conducted interviews with ten principals and eight teachers. She also held interviews with four education district officials and one provincial official. Data were analysed by statistical and non-statistical procedures. The study revealed that the inclusion policy is being implemented in the selected schools. However, there are challenges that are being encountered. Firstly, some teachers have not received adequate training with regards to inclusive education policy. Staff development workshops put in place to address this challenge are minimal, and there is not enough joint effort being established by the different stakeholders with regards to support and monitoring the implementation process. Despite the challenges that accompany implementation of inclusion of learners with special education needs, as well as the difficult working conditions, this study reveals that there are pockets of good practice of inclusion policy in some of the selected schools in the Fort Beaufort District. For instance, it was found that teachers implement inclusion of learners with special education needs, even though the majority of them do not have qualifications in special education. It was also revealed that teachers used learner-centred teaching methods to accommodate all learners, which include group and individual teaching, group demonstration, discussions, question-and-answer sessions, and practical activities.
- Full Text:
- Date Issued: 2014
- Authors: Adewumi, Toyin Mary
- Date: 2014
- Subjects: Inclusive education Education and state -- South Africa -- Eastern Cape Children with disabilities -- Education -- South Africa -- Eastern Cape Special education -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Degree
- Identifier: http://hdl.handle.net/10353/5873 , vital:29413
- Description: The implementation of inclusion policy for learners with special education needs as stipulated in the Education White Paper 2001has been an issue of concern for South African schools. This study sheds light on the implementation of inclusion policy for learners with special education needs in the selected primary schools in the Fort Beaufort District in the Eastern Cape Province in South Africa. The aim of the study is to examine the implementation of inclusion policy for learners with special education needs. The study was placed within the post-positivism paradigm and used a mixed method research approach that integrated concurrent procedures in the collection, analysis and interpretation of the data. Questionnaires were used to collect quantitative data while qualitative data were collected through interviews, and document analysis. A total number of 30 teachers completed the questionnaires. The researcher conducted interviews with ten principals and eight teachers. She also held interviews with four education district officials and one provincial official. Data were analysed by statistical and non-statistical procedures. The study revealed that the inclusion policy is being implemented in the selected schools. However, there are challenges that are being encountered. Firstly, some teachers have not received adequate training with regards to inclusive education policy. Staff development workshops put in place to address this challenge are minimal, and there is not enough joint effort being established by the different stakeholders with regards to support and monitoring the implementation process. Despite the challenges that accompany implementation of inclusion of learners with special education needs, as well as the difficult working conditions, this study reveals that there are pockets of good practice of inclusion policy in some of the selected schools in the Fort Beaufort District. For instance, it was found that teachers implement inclusion of learners with special education needs, even though the majority of them do not have qualifications in special education. It was also revealed that teachers used learner-centred teaching methods to accommodate all learners, which include group and individual teaching, group demonstration, discussions, question-and-answer sessions, and practical activities.
- Full Text:
- Date Issued: 2014
Basin analysis of the Soutpansberg and Tuli Coalfields, Limpopo Province of South Africa
- Authors: Malaza, Ntokozo
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Geology)
- Identifier: vital:11531 , http://hdl.handle.net/10353/d1021279
- Description: The Soutpansberg and Tuli Coalfields are both hosted in the Karoo Basin, Limpopo Province of South Africa. The Soutpansberg Coalfield is situated north of the Soutpansberg Mountain Range and has a strike length of about 200 km and width of about 80 km which is fault controlled and extends from Waterpoort in the west to the Kruger National Park in the east. The Tuli Coalfield occurs in a small intracratonic, east-west trending fault-controlled sedimentary basin with a preserved width of 80 km and length of 120 km. The east to west trend of the Tuli Coalfield parallels that of the Soutpansberg Coalfield further east, and the two coalfields link up with the north-south trending Lebombo Basin. The Tuli Coalfield occurs in the Tuli Basin, while the Soutpansberg Coalfield occurs in the Soutpansberg Basin. The two basins preserve a heterogeneous succession of the Upper Paleozoic to Lower Mesozoic sedimentary and volcanic rocks of the Karoo Supergroup. Because the area is largely covered by the Quaternary Kalahari Group sands, the stratigraphy of the succession is not as well understood as the Main Karoo Basin in South Africa. This study deals with the intra-basinal stratigraphic correlation, facies and depositional environments, petrography, geochemistry, provenance, geophysics, structural geology, diagenesis of sandstone, subsidence history and coal quality in the Soutpansberg and Tuli Coalfields. Based on the field work and detailed sedimentological analyses of over 2000 borehole data, seven facies associations (FAs) comprising sixteen major lithofacies were identified. The facies associations are: Glacial diamictite and sandstone (FA 1), Clast supported conglomerate and sandstone (FA 2), Tabular cross-bedded sandstone (FA 3), Trough and planar cross-bedded sandstone (FA 4), Fine calcareous and micaceous siltstone and mudstone (FA 5), Sandy shale/mudstone (FA 6), Laminated or thin-bedded Carbonaceous shale/mudstone and coal (FA 7). The facies associations (FA 1 to FA 7) correspond to the lithostratigraphic sub-divisions of the Tshidzi, Madzaringwe and Mikambeni Formations. The Madzaringwe Formation in this study is informally sub-divided into the Lower, Middle and Upper Members while the Mikambeni Formation is informally sub-divided into the Lower and Upper Members. Sedimentological characteristics of the identified facies associations indicate the following depositional environments: Fluvioglacial (braided streams) depositional environment (FA 1, Tshidzi Diamictite Formation); Floodplain ponds, lakes, marshes and backswamps (FA 6 and FA 7, Lower Member of the Madzaringwe Formation); Meandering and braided channels, crevasse splays, levees and crevasse channels (FA 2, FA 3, FA 4 and FA 5, Middle Member of the Madzaringwe Formation); Floodplain ponds, lakes and backswamps (FA 6 and FA 7, Upper Member of the Madzaringwe Formation); Meandering and braided channels, crevasse splays, swamps and shallow lakes (FA 5, FA 6 and FA 7, Lower Member of the Mikambeni Formation) and lastly braided channels, meandering channels, levees and crevasse channels (FA 2, FA 3, FA 4 and FA 5, Upper Member of the Mikambeni Formation). Paleocurrent directions were measured using directional structures (cross-bedding and asymmetric ripple marks). The paleocurrent analysis shows that the direction of the channels was from south-west to north-east in both coalfields. Based on the structural study and geophysical interpretations, the structural and tectonic settings of the two coalfields have been revealed, both coalfields are normal fault-bounded. The geological evolution of the Karoo strata, at least since the Upper Carboniferous, essentially follows the type model for passive continental margin terrain. Paleostress inversion techniques have been employed to interpret the stress regime of the two coalfields. The Soutpansberg Basin is characterised by W-E to ENE-WSW extension and N-S to NNW-SSE compression. The Tuli Basin is characterised by N-S to NNW-SSE compression and W-E to ENE-WSE extension. This stress field reflects the established structural trend of the two shear belts (the Tshipise and Siloam shear zones) bounding the Central Zone of the Limpopo Mobile Belt. The geophysical interpretations were focused on outlining structures, contacts and on the delineation of gravity, magnetic and radiometric signatures in areas defined as anomalous. The magnetic, gravity and radiometric data showed low amplitudes in the sedimentary strata compared to the surrounding and basement geological bodies. The E-N-E fault system has a notable signature, defining two magnetic domains on both southern and northern sides of the Soutpansberg Coalfield. The intrusive emplacements are mainly fault controlled and they trend in the same direction as the two fault systems. Jurassic volcanics (Letaba and Jozini Formations) follow a SW-NE trend, outcropping in the east (Soutpansberg Basin), producing a strong magnetic response in this area, and partly buried in the west, where magnetic intensity tends to be reduced. Petrographic and geochemical analyses of the Soutpansberg sandstones revealed immature sub-litharenite, sub-arkose and minor arkosic arenites in nature, dominated by sub-angular to rounded detrital grains, sourced from recycled orogens, craton interior to transitional continental. The sandstones of the Tuli Coalfield are classified as sub-arkoses and minor sub-litharenites and sourced from the craton interior and recycled orogen provenances. Both petrographic and geochemical results suggest a passive continental margin source. Petrographic and geochemical results of the samples of the Soutpansberg Coalfield suggest uplifted basement source areas dominated by sedimentary rocks with minor granite-gneiss rocks. The petrography and geochemistry of the Tuli sandstones suggest source areas dominantly composed of plutonic (granites) and metamorphic (gneisses and schists) rocks with a component from a sedimentary (quartz-arenites, quartzites, shales, arkoses and meta-arkoses) rocks. Diagenetic features of Mikambeni and Madzaringwe sandstones are subdivided into early, middle and late stages. Time is relative with the earliest diagenetic event occurring shortly after deposition and the latest occurring up until present time. The main diagenetic processes that have affected the sandstones include mechanical compaction, cementation and the dissolution of framework grains and cements. Early diagenetic processes include mechanical compaction, silica and calcite cementation, clay minerals (pore lining and pore-filling kaolinite, illite and smectite), feldspar authigenesis and the formation of hematite cements and coatings. Late diagenesis includes quartz and feldspar overgrowths, seritisation, chlorite alteration, grain deformation, pressure-solution and fracturing and albitisation. The subsidence of the basins is believed to be initiated and thermally controlled by tectonics (i.e. faults of basements blocks) rather than sedimentary burial. The subsidence within the basins supports the primary graben system which must have been centered within the present basins, and later became a region of major faulting. This gave way to the Late Carboniferous rapid subsidence, with areas of greater extension subsiding more rapidly. The Early Permian (last phase) is characterised by a slow subsidence representing the post-rift thermal subsidence. The rift flanks were gradually uplifted and, and then generally subsided as a results of thermal contraction after the extension terminated. Based on the coal analysis, both coalfields are characterised by coking bituminous coal. The study has revealed that the eastern Soutpansberg Coalfield is likely to present better opportunities for identification of potentially exploitable coal deposits as compared to the Tuli Coalfield.
- Full Text:
- Date Issued: 2014
- Authors: Malaza, Ntokozo
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Geology)
- Identifier: vital:11531 , http://hdl.handle.net/10353/d1021279
- Description: The Soutpansberg and Tuli Coalfields are both hosted in the Karoo Basin, Limpopo Province of South Africa. The Soutpansberg Coalfield is situated north of the Soutpansberg Mountain Range and has a strike length of about 200 km and width of about 80 km which is fault controlled and extends from Waterpoort in the west to the Kruger National Park in the east. The Tuli Coalfield occurs in a small intracratonic, east-west trending fault-controlled sedimentary basin with a preserved width of 80 km and length of 120 km. The east to west trend of the Tuli Coalfield parallels that of the Soutpansberg Coalfield further east, and the two coalfields link up with the north-south trending Lebombo Basin. The Tuli Coalfield occurs in the Tuli Basin, while the Soutpansberg Coalfield occurs in the Soutpansberg Basin. The two basins preserve a heterogeneous succession of the Upper Paleozoic to Lower Mesozoic sedimentary and volcanic rocks of the Karoo Supergroup. Because the area is largely covered by the Quaternary Kalahari Group sands, the stratigraphy of the succession is not as well understood as the Main Karoo Basin in South Africa. This study deals with the intra-basinal stratigraphic correlation, facies and depositional environments, petrography, geochemistry, provenance, geophysics, structural geology, diagenesis of sandstone, subsidence history and coal quality in the Soutpansberg and Tuli Coalfields. Based on the field work and detailed sedimentological analyses of over 2000 borehole data, seven facies associations (FAs) comprising sixteen major lithofacies were identified. The facies associations are: Glacial diamictite and sandstone (FA 1), Clast supported conglomerate and sandstone (FA 2), Tabular cross-bedded sandstone (FA 3), Trough and planar cross-bedded sandstone (FA 4), Fine calcareous and micaceous siltstone and mudstone (FA 5), Sandy shale/mudstone (FA 6), Laminated or thin-bedded Carbonaceous shale/mudstone and coal (FA 7). The facies associations (FA 1 to FA 7) correspond to the lithostratigraphic sub-divisions of the Tshidzi, Madzaringwe and Mikambeni Formations. The Madzaringwe Formation in this study is informally sub-divided into the Lower, Middle and Upper Members while the Mikambeni Formation is informally sub-divided into the Lower and Upper Members. Sedimentological characteristics of the identified facies associations indicate the following depositional environments: Fluvioglacial (braided streams) depositional environment (FA 1, Tshidzi Diamictite Formation); Floodplain ponds, lakes, marshes and backswamps (FA 6 and FA 7, Lower Member of the Madzaringwe Formation); Meandering and braided channels, crevasse splays, levees and crevasse channels (FA 2, FA 3, FA 4 and FA 5, Middle Member of the Madzaringwe Formation); Floodplain ponds, lakes and backswamps (FA 6 and FA 7, Upper Member of the Madzaringwe Formation); Meandering and braided channels, crevasse splays, swamps and shallow lakes (FA 5, FA 6 and FA 7, Lower Member of the Mikambeni Formation) and lastly braided channels, meandering channels, levees and crevasse channels (FA 2, FA 3, FA 4 and FA 5, Upper Member of the Mikambeni Formation). Paleocurrent directions were measured using directional structures (cross-bedding and asymmetric ripple marks). The paleocurrent analysis shows that the direction of the channels was from south-west to north-east in both coalfields. Based on the structural study and geophysical interpretations, the structural and tectonic settings of the two coalfields have been revealed, both coalfields are normal fault-bounded. The geological evolution of the Karoo strata, at least since the Upper Carboniferous, essentially follows the type model for passive continental margin terrain. Paleostress inversion techniques have been employed to interpret the stress regime of the two coalfields. The Soutpansberg Basin is characterised by W-E to ENE-WSW extension and N-S to NNW-SSE compression. The Tuli Basin is characterised by N-S to NNW-SSE compression and W-E to ENE-WSE extension. This stress field reflects the established structural trend of the two shear belts (the Tshipise and Siloam shear zones) bounding the Central Zone of the Limpopo Mobile Belt. The geophysical interpretations were focused on outlining structures, contacts and on the delineation of gravity, magnetic and radiometric signatures in areas defined as anomalous. The magnetic, gravity and radiometric data showed low amplitudes in the sedimentary strata compared to the surrounding and basement geological bodies. The E-N-E fault system has a notable signature, defining two magnetic domains on both southern and northern sides of the Soutpansberg Coalfield. The intrusive emplacements are mainly fault controlled and they trend in the same direction as the two fault systems. Jurassic volcanics (Letaba and Jozini Formations) follow a SW-NE trend, outcropping in the east (Soutpansberg Basin), producing a strong magnetic response in this area, and partly buried in the west, where magnetic intensity tends to be reduced. Petrographic and geochemical analyses of the Soutpansberg sandstones revealed immature sub-litharenite, sub-arkose and minor arkosic arenites in nature, dominated by sub-angular to rounded detrital grains, sourced from recycled orogens, craton interior to transitional continental. The sandstones of the Tuli Coalfield are classified as sub-arkoses and minor sub-litharenites and sourced from the craton interior and recycled orogen provenances. Both petrographic and geochemical results suggest a passive continental margin source. Petrographic and geochemical results of the samples of the Soutpansberg Coalfield suggest uplifted basement source areas dominated by sedimentary rocks with minor granite-gneiss rocks. The petrography and geochemistry of the Tuli sandstones suggest source areas dominantly composed of plutonic (granites) and metamorphic (gneisses and schists) rocks with a component from a sedimentary (quartz-arenites, quartzites, shales, arkoses and meta-arkoses) rocks. Diagenetic features of Mikambeni and Madzaringwe sandstones are subdivided into early, middle and late stages. Time is relative with the earliest diagenetic event occurring shortly after deposition and the latest occurring up until present time. The main diagenetic processes that have affected the sandstones include mechanical compaction, cementation and the dissolution of framework grains and cements. Early diagenetic processes include mechanical compaction, silica and calcite cementation, clay minerals (pore lining and pore-filling kaolinite, illite and smectite), feldspar authigenesis and the formation of hematite cements and coatings. Late diagenesis includes quartz and feldspar overgrowths, seritisation, chlorite alteration, grain deformation, pressure-solution and fracturing and albitisation. The subsidence of the basins is believed to be initiated and thermally controlled by tectonics (i.e. faults of basements blocks) rather than sedimentary burial. The subsidence within the basins supports the primary graben system which must have been centered within the present basins, and later became a region of major faulting. This gave way to the Late Carboniferous rapid subsidence, with areas of greater extension subsiding more rapidly. The Early Permian (last phase) is characterised by a slow subsidence representing the post-rift thermal subsidence. The rift flanks were gradually uplifted and, and then generally subsided as a results of thermal contraction after the extension terminated. Based on the coal analysis, both coalfields are characterised by coking bituminous coal. The study has revealed that the eastern Soutpansberg Coalfield is likely to present better opportunities for identification of potentially exploitable coal deposits as compared to the Tuli Coalfield.
- Full Text:
- Date Issued: 2014
Stakeholders' participation in curriculum development in four secondary schools in Fort Beaufort education district, Eastern cape province: towards a participatory curriculum model
- Authors: Obi, Uloma Nkpurunma
- Date: 2014
- Subjects: Curriculum planning Educational planning -- South Africa -- Eastern Cape Education -- Curricula -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Degree
- Identifier: http://hdl.handle.net/10353/5840 , vital:29401
- Description: The new democratic government came to power in 1994 and one of its major missions was to change the system of education inherited from the apartheid regime by laying a foundation for a single national core syllabus to replace the erstwhile multi-tier system, which discriminated among racial groups. Under the apartheid regime, the curriculum was flawed by ‘racially, offensive and outdated content’ and the government embarked on a bold programme to cleanse it of these elements. The democratic government went about this through curriculum reforms. In 1997, it introduced Curriculum 2005 fondly called “C2005”, with the Outcome-based Education (OBE) principles. Despite the initial overwhelming support for C2005, it soon ran into trouble. In 2000, the Minister appointed a committee that reviewed the curriculum and in 2002, the Revised National Curriculum Statement (RNCS) was born. These curriculum reforms have been met with a lot of criticism and the government felt it was not serving its purpose. Some key stakeholders still felt that their non-involvement, non-participation and the lack of proper consultation in the curriculum process were partly responsible for teachers and subject advisers misinterpreting the curriculum and implementing it from their own perspectives. Subsequently, another review was done and the National Curriculum Statement (NCS) was launched in 2002. But the complaints did not cease, probably due to continuing poor performance at the Matric Examination which continues to feature low pass rates for many provinces, especially the Eastern Cape. Against this backdrop, the government streamlined the NCS curriculum yield, and an amended Curriculum and Assessment Policy Statement (CAPS) emerged. The key issue raised by critics is the lack of sufficient involvement of stakeholders in the curriculum review processes. At the same time, government continues to insist that it has been consulting adequately with all relevant stakeholders. There are iii obviously different interpretations of stakeholder involvement and participation and there is urgent need to reconcile whatever differences of opinion and definition exist, in order to gain common understanding, which is the first step in reaching a solution. For instance, how are the stakeholders involved? More importantly, what is meant by “involvement”? Even if there is no disagreement about the meaning of “involvement”, is the stage in the process at which the stakeholders are involved an important element in whether or not the process is an inclusive and participatory one?.
- Full Text:
- Date Issued: 2014
- Authors: Obi, Uloma Nkpurunma
- Date: 2014
- Subjects: Curriculum planning Educational planning -- South Africa -- Eastern Cape Education -- Curricula -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Degree
- Identifier: http://hdl.handle.net/10353/5840 , vital:29401
- Description: The new democratic government came to power in 1994 and one of its major missions was to change the system of education inherited from the apartheid regime by laying a foundation for a single national core syllabus to replace the erstwhile multi-tier system, which discriminated among racial groups. Under the apartheid regime, the curriculum was flawed by ‘racially, offensive and outdated content’ and the government embarked on a bold programme to cleanse it of these elements. The democratic government went about this through curriculum reforms. In 1997, it introduced Curriculum 2005 fondly called “C2005”, with the Outcome-based Education (OBE) principles. Despite the initial overwhelming support for C2005, it soon ran into trouble. In 2000, the Minister appointed a committee that reviewed the curriculum and in 2002, the Revised National Curriculum Statement (RNCS) was born. These curriculum reforms have been met with a lot of criticism and the government felt it was not serving its purpose. Some key stakeholders still felt that their non-involvement, non-participation and the lack of proper consultation in the curriculum process were partly responsible for teachers and subject advisers misinterpreting the curriculum and implementing it from their own perspectives. Subsequently, another review was done and the National Curriculum Statement (NCS) was launched in 2002. But the complaints did not cease, probably due to continuing poor performance at the Matric Examination which continues to feature low pass rates for many provinces, especially the Eastern Cape. Against this backdrop, the government streamlined the NCS curriculum yield, and an amended Curriculum and Assessment Policy Statement (CAPS) emerged. The key issue raised by critics is the lack of sufficient involvement of stakeholders in the curriculum review processes. At the same time, government continues to insist that it has been consulting adequately with all relevant stakeholders. There are iii obviously different interpretations of stakeholder involvement and participation and there is urgent need to reconcile whatever differences of opinion and definition exist, in order to gain common understanding, which is the first step in reaching a solution. For instance, how are the stakeholders involved? More importantly, what is meant by “involvement”? Even if there is no disagreement about the meaning of “involvement”, is the stage in the process at which the stakeholders are involved an important element in whether or not the process is an inclusive and participatory one?.
- Full Text:
- Date Issued: 2014
Computational studies, synthesis and characterization of ruthenium (ii) anticancer complexes
- Authors: Adeniyi, Adebayo Azeez
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11338 , http://hdl.handle.net/10353/d1015577
- Description: This thesis is centred on the application of Ru-based complexes as a promising alternative to cis-platin in cancer chemotherapy. Cis-platin is known to be the most prescribed chemotherapy which has more than 70% application in cancer cases especially the testicular cancer. An insight is provided in Chapter One and Two into the literatures reports on the application of Ru(II)-based complexes in cancer chemotherapy. In order to address some of the pressing challenges in rational design of Ru-based anticancer complexes, section 3.3 and 3.4 deal with efforts to elucidate the complication of their chemistry and instability while in section 3.5 efforts are made to find solution to the lack of proper knowledge of their targets using different theoretical approaches as presented in Chapter Three. In addition to the theoretical study, this thesis also comprises of the synthesis of the bis-pyrazole derivatives type of ligands and the derivatives of their Ru(II)-based complexes as provided in Chapter Four and Five respectively. Also the computational methods were used to elucidate the structural and spectroscopic properties of the synthesised ligands and their Ru(II)-based complexes. The geometrical and electronic properties are studied in relation to the stability and the reported anticancer activities of Ru(II)-based complexes in section 3.3. In subsection 3.3.1, several quantum properties including the natural energy decomposition analysis (NEDA) and quantum theory of atoms in a molecule (QTAIM) are computed on three models of RAPTA-C complexes using DFT with hybrid functional and basis set with ECP and without ECP. The higher stability of Carbo-RAPTA-C and Oxalo-RAPTA-C over RAPTA-C comes from the lower exchange repulsion and higher polarization contributions to their stability which gives insight into experimental observation. A similar study was carried out in subsection 3.3.2 on half-sandwich Ru(II)-based anticancer complexes with 6-toluene and 6-trifluorotoluene.
- Full Text:
- Date Issued: 2014
- Authors: Adeniyi, Adebayo Azeez
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11338 , http://hdl.handle.net/10353/d1015577
- Description: This thesis is centred on the application of Ru-based complexes as a promising alternative to cis-platin in cancer chemotherapy. Cis-platin is known to be the most prescribed chemotherapy which has more than 70% application in cancer cases especially the testicular cancer. An insight is provided in Chapter One and Two into the literatures reports on the application of Ru(II)-based complexes in cancer chemotherapy. In order to address some of the pressing challenges in rational design of Ru-based anticancer complexes, section 3.3 and 3.4 deal with efforts to elucidate the complication of their chemistry and instability while in section 3.5 efforts are made to find solution to the lack of proper knowledge of their targets using different theoretical approaches as presented in Chapter Three. In addition to the theoretical study, this thesis also comprises of the synthesis of the bis-pyrazole derivatives type of ligands and the derivatives of their Ru(II)-based complexes as provided in Chapter Four and Five respectively. Also the computational methods were used to elucidate the structural and spectroscopic properties of the synthesised ligands and their Ru(II)-based complexes. The geometrical and electronic properties are studied in relation to the stability and the reported anticancer activities of Ru(II)-based complexes in section 3.3. In subsection 3.3.1, several quantum properties including the natural energy decomposition analysis (NEDA) and quantum theory of atoms in a molecule (QTAIM) are computed on three models of RAPTA-C complexes using DFT with hybrid functional and basis set with ECP and without ECP. The higher stability of Carbo-RAPTA-C and Oxalo-RAPTA-C over RAPTA-C comes from the lower exchange repulsion and higher polarization contributions to their stability which gives insight into experimental observation. A similar study was carried out in subsection 3.3.2 on half-sandwich Ru(II)-based anticancer complexes with 6-toluene and 6-trifluorotoluene.
- Full Text:
- Date Issued: 2014
Alternative methods used by small-holder farmers to control ticks and bovine dermatophilosis and the impact of a changing interface of Amblyomma ticks on dermatophilosis in Zimbabwe
- Authors: Ndhkovu, Daud Nyosi
- Date: 2014
- Subjects: Ticks -- Control -- Africa, Southern , Dermatophilosis
- Language: English
- Type: Thesis , Doctoral , PhD (Animal Science)
- Identifier: vital:11830 , http://hdl.handle.net/10353/d1019764 , Ticks -- Control -- Africa, Southern , Dermatophilosis
- Description: This study was carried out to document the ethno-veterinary plants and non-plant remedies that farmers used to control dermatophilosis and ticks, and validate these in vitro and in vivo, as well as determine how the interface of Amblyomma variegatum and A. hebraeum affected the epidemiology of bovine dermatophilosis at selected small-holder areas in North-West Zimbabwe. A structured questionnaire survey was used to collect information on the control methods used by farmers for the control of bovine dermatophilosis and ticks. A total of 39 plants were used by farmers for various diseases, eleven of these plants were used for the control of dermatophilosis while three were for tick control. Across the study sites, dermatophilosis was controlled using eleven plants. Among these plants; six plants; Cissus quadrangularis, Catunaregan spinosa, Pterocarpus angolensis Carica papaya, Manihot esculenta and Blumea decurrens which were frequently used were selected for further studies. In vitro and in vivo studies were conducted to validate the efficacy of these plants. The minimum inhibitory concentration and bactericidal concentration assays were used for the in vitro validation of C. quadrangularis, C. spinosa and P. angolensis. Dermatophilus congolensis was more sensitive to P. angolensis average MIC = 0.63 mg/ml than to C. quadrangularis average MIC = iii 1.25 mg/ml and C. spinosa average MIC = 2.08 mg/ml. Cissus quadrangularis was selected for in vivo studies as this plant was the one most frequently used by farmers. Its therapeutic efficacy was compared to conventional antibiotics that farmers used to treat dermatophilosis infection. In the in vivo trials C. quadrangularis did not lead to appreciable reduction in clinical disease compared to the conventional drugs. The larval packet assay was the in vitro assay used to validate the efficacy of Carica papaya, Manihot esculenta and Blumea decurrens against larvae of A. hebraeum and Rhipicephalus appendiculatus. Manihot esculenta at 20 % w/v exhibited the highest larvicidal activity against R. appendiculatus. In the in vivo study, efficacy of the plants were investigated on naturally tick-infested cattle. Mannihot esculenta exhibited the largest tick load reduction compared to the other two plants but its performance was lower than that of conventional acaricides. The effect of A. variegatum and A. hebraeum on bovine dermatophilosis was investigated by evaluating how the presence or absence of these ticks and other herd level risk factors predicted clinical dermatophilosis and its prevalence at herd level. A structured questionnaire survey was carried out to collect data on potential risk factors. At the same time, cattle were physically examined for the presence of bovine dermatophilosis, according to a pre-defined case definition, and presence or absence of Amblyomma ticks was also recorded. The multivariable binary logistic model was developed with disease status as outcome, tick presence and infestion and herd level risk factors as predictors. Of the herds examined clinical bovine dermatophilosis was detected in 45% (84/185; 95% CI: 38.2, 52.6%) of them. Herds infested with Amblyomma variegatum were associated with higher odds (OR= 6.8; iv 95% CI: 1.71, 27.10) of clinical dermatophilosis while the association was not significant (P > 0.05) in A. hebraeum infested herds. It was concluded that management practices aimed at movement and tick control would help reduce the prevalence of clinical dermatophilosis in herds.
- Full Text:
- Date Issued: 2014
- Authors: Ndhkovu, Daud Nyosi
- Date: 2014
- Subjects: Ticks -- Control -- Africa, Southern , Dermatophilosis
- Language: English
- Type: Thesis , Doctoral , PhD (Animal Science)
- Identifier: vital:11830 , http://hdl.handle.net/10353/d1019764 , Ticks -- Control -- Africa, Southern , Dermatophilosis
- Description: This study was carried out to document the ethno-veterinary plants and non-plant remedies that farmers used to control dermatophilosis and ticks, and validate these in vitro and in vivo, as well as determine how the interface of Amblyomma variegatum and A. hebraeum affected the epidemiology of bovine dermatophilosis at selected small-holder areas in North-West Zimbabwe. A structured questionnaire survey was used to collect information on the control methods used by farmers for the control of bovine dermatophilosis and ticks. A total of 39 plants were used by farmers for various diseases, eleven of these plants were used for the control of dermatophilosis while three were for tick control. Across the study sites, dermatophilosis was controlled using eleven plants. Among these plants; six plants; Cissus quadrangularis, Catunaregan spinosa, Pterocarpus angolensis Carica papaya, Manihot esculenta and Blumea decurrens which were frequently used were selected for further studies. In vitro and in vivo studies were conducted to validate the efficacy of these plants. The minimum inhibitory concentration and bactericidal concentration assays were used for the in vitro validation of C. quadrangularis, C. spinosa and P. angolensis. Dermatophilus congolensis was more sensitive to P. angolensis average MIC = 0.63 mg/ml than to C. quadrangularis average MIC = iii 1.25 mg/ml and C. spinosa average MIC = 2.08 mg/ml. Cissus quadrangularis was selected for in vivo studies as this plant was the one most frequently used by farmers. Its therapeutic efficacy was compared to conventional antibiotics that farmers used to treat dermatophilosis infection. In the in vivo trials C. quadrangularis did not lead to appreciable reduction in clinical disease compared to the conventional drugs. The larval packet assay was the in vitro assay used to validate the efficacy of Carica papaya, Manihot esculenta and Blumea decurrens against larvae of A. hebraeum and Rhipicephalus appendiculatus. Manihot esculenta at 20 % w/v exhibited the highest larvicidal activity against R. appendiculatus. In the in vivo study, efficacy of the plants were investigated on naturally tick-infested cattle. Mannihot esculenta exhibited the largest tick load reduction compared to the other two plants but its performance was lower than that of conventional acaricides. The effect of A. variegatum and A. hebraeum on bovine dermatophilosis was investigated by evaluating how the presence or absence of these ticks and other herd level risk factors predicted clinical dermatophilosis and its prevalence at herd level. A structured questionnaire survey was carried out to collect data on potential risk factors. At the same time, cattle were physically examined for the presence of bovine dermatophilosis, according to a pre-defined case definition, and presence or absence of Amblyomma ticks was also recorded. The multivariable binary logistic model was developed with disease status as outcome, tick presence and infestion and herd level risk factors as predictors. Of the herds examined clinical bovine dermatophilosis was detected in 45% (84/185; 95% CI: 38.2, 52.6%) of them. Herds infested with Amblyomma variegatum were associated with higher odds (OR= 6.8; iv 95% CI: 1.71, 27.10) of clinical dermatophilosis while the association was not significant (P > 0.05) in A. hebraeum infested herds. It was concluded that management practices aimed at movement and tick control would help reduce the prevalence of clinical dermatophilosis in herds.
- Full Text:
- Date Issued: 2014
Evaluating the implementation of the principles of good governance in Zimbabwe local government system : a case of Marondera local municipality
- Authors: Muswaka, Phyllis
- Date: 2014
- Subjects: Local government -- Zimbabwe Public administration -- Zimbabwe
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/13068 , vital:39453
- Description: Participatory budgeting currently occupies centre stage in Public and Municipal financial management Acts. The principle of participatory budgeting ushers in a broader public forum in which crucial principles in Public financial management such as accountability and transparency are observed, thereby automatically ensuring effective governance. The efficacy of participatory budgeting is to improve service delivery through opening up structures that will combat the spread of mal administrative practices such as corruption and financial fraud whilst enhancing democratic participation and upholding the rule of law by fostering transparency and accountability and making the governments more responsive to the needs of the people. The main objective of this study is to explore the pernicious effects of having limited citizen participation in Public finance management. It seeks to examine whether the poor service delivery by local municipalities can be attributed to the lack of effective citizen participation. This will be done through assessing whether the seeds of participatory budgeting have led to the fruits of efficient and effective service delivery in the public sector both in theory and in practice at Nkonkobe local municipality. It has been discovered that the inability to provide effective service delivery is a complex challenge facing many municipalities in South Africa, and although such a situation has been co-determined by many other factors including financial restraints, the root cause of service delivery incapability’s can be traced back to weather the citizens are actually participating in the management of public finances through participatory budgeting or not. More often than not, the failure to accommodate the citizens in local government affairs has been the spark that has been responsible for setting alight strikes and service delivery protest marches in most of South Africa’s Provinces. However, due to this, this study aims to reveal that participatory budgeting is an ambitious issue that requires local authorities to focus on in order to improve service delivery through embracing active citizen participation. Recommendations as well as consequences of lack of citizen participation in the budget process were thereby highlighted.
- Full Text:
- Date Issued: 2014
- Authors: Muswaka, Phyllis
- Date: 2014
- Subjects: Local government -- Zimbabwe Public administration -- Zimbabwe
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/13068 , vital:39453
- Description: Participatory budgeting currently occupies centre stage in Public and Municipal financial management Acts. The principle of participatory budgeting ushers in a broader public forum in which crucial principles in Public financial management such as accountability and transparency are observed, thereby automatically ensuring effective governance. The efficacy of participatory budgeting is to improve service delivery through opening up structures that will combat the spread of mal administrative practices such as corruption and financial fraud whilst enhancing democratic participation and upholding the rule of law by fostering transparency and accountability and making the governments more responsive to the needs of the people. The main objective of this study is to explore the pernicious effects of having limited citizen participation in Public finance management. It seeks to examine whether the poor service delivery by local municipalities can be attributed to the lack of effective citizen participation. This will be done through assessing whether the seeds of participatory budgeting have led to the fruits of efficient and effective service delivery in the public sector both in theory and in practice at Nkonkobe local municipality. It has been discovered that the inability to provide effective service delivery is a complex challenge facing many municipalities in South Africa, and although such a situation has been co-determined by many other factors including financial restraints, the root cause of service delivery incapability’s can be traced back to weather the citizens are actually participating in the management of public finances through participatory budgeting or not. More often than not, the failure to accommodate the citizens in local government affairs has been the spark that has been responsible for setting alight strikes and service delivery protest marches in most of South Africa’s Provinces. However, due to this, this study aims to reveal that participatory budgeting is an ambitious issue that requires local authorities to focus on in order to improve service delivery through embracing active citizen participation. Recommendations as well as consequences of lack of citizen participation in the budget process were thereby highlighted.
- Full Text:
- Date Issued: 2014
An integrated approach for the delineation of arable land and its cropping suitability under variable soil and climatic conditions in the Nkonkobe municipality, Eastern Cape, South Africa
- Authors: Manyevere, Alen
- Date: 2014
- Subjects: Soils -- Classification -- South Africa -- Eastern Cape , Soil degradation -- South Africa -- Eastern Cape , Ethnoscience -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD (Soil Science)
- Identifier: vital:11965 , http://hdl.handle.net/10353/d1019856 , Soils -- Classification -- South Africa -- Eastern Cape , Soil degradation -- South Africa -- Eastern Cape , Ethnoscience -- South Africa -- Eastern Cape
- Description: Arable crop production in Nkonkobe Municipality is low due to abandonment of potentially productive land and low productivity of the cultivated land. Little attention has been given to farmers perspectives with regards to crop production and land abandonment. Understanding the relationships of indigenous knowledge systems, where local approaches to soil classification, appraisal, use and management and land evaluation, and scientific approaches could be important for the effective use of available soil resources while avoiding those resources that are vulnerable to degradation. In addition, the interactions between soil factors and climate could be useful in understanding the erodibility of soils. The intergration of scientific research and indigenous knowledge systems could help in the identification and delineation of high potential land and on crop suitability evaluation. The objectives of the study were: (i) to determine farmers‟ perspectives with regards to land utilisation and abandonment, constraints on crop production and crop preferences, (ii) to integrate and compare indigenous knowledge systems with scientific approaches of soil classification and potential, (iii) to determine the effect of climate and soil factors on erodibilities of soils in the Municipality (iv) to delineate arable land and evaluate its suitability for maize, potato, sorghum and cowpea under rainfed agriculture. Using semi-structured and open-ended interviews, information on limitations to crop production, cropping preferences, indigenous soil classifications, cropping potential ratings and erosion was captured. Descriptive and correlation statistics were used to analyse farmers‟ responses. The information was later used for a pilot participatory mapping and the determination of the agricultural potential of the soils in three selected villages of the Municipality. Field boundaries of soil texture, colour, depth, and slope position were captured using global positioning systems (GPS). The relationship between the degree of erosion and soil and slope factors was analysed by step-wise regression. Crop suitability for rainfed agriculture was done using the FAO guidelines for Land evaluation for rainfed agriculture. The spatially referenced crop suitability classes were produced by applying the Law of Limiting Combinationusing GIS Boolean Logic. The major biophysical factors, affecting crop production and land utilisation were soil degradation and low and erratic rainfall, while other factors included lack of farming equipment and security concerns. Maize, spinach and cabbage were the main crops grown, with maize sorghum and wheat the most abandoned crops. While it was difficult to accurately correlate indigenous classification with international scientific classification, the importance of colour, texture and soil depth for both classification and soil potential, suggests that some form of correlation is possible which enabled communication and other extension information to be conveyed. The shallow and stony soil (urhete) correlated well with the Leptosols in World Reference Base (WRB) or Mispah and shallow Glenrosa soils in the South African system. The red structured clays (umhlaba obomvu) matched the Nitisols in WRB or Shortlands in the South African system. The non-swelling black clayey soils (umhlaba omnyama) matched soils with melanic A horizons in both the WRB and South African soil classification systems. The dongwe and santi soils developed in alluvial sediments belonged to the Dundee, Oakleaf or Augrabies soils in the South African classification system and fluvisols or Cambisols in the WRB system. There was good agreement between farmers assessment of the cropping potential and scientific approaches but scientifically high potential red soils were rated lowly by the farmers due to difficulties in management caused by shortages of farm machinery, especially under dryland farming. Overall, the soil factors affecting erosion were influenced largely by climate, while parent material was also important. Climate had a dominant influence on soil factors most notably fine sand and very fine sand fractions and exchangeable sodium percentage being more important on soil forms occurring in arid and semi-arid climate and less in the sub-humid and humid areas, where clay mineralogy, particularly kaolinite and sesquioxide dominated. Dolerite derived soils were the most stable and should be given the highest priority for cropping development while mudstone and shale derived soils had a lower cropping potential. While slope gradient and length had some effect on soil erosion in arid and semi arid environments its influence was generally overshadowed by soil factors especially in humid zones. Cow pea and sorghum were the most adapted crops in the region while potato and maize were marginally suitable under rainfed agriculture. The study revealed that most adapted crops were not necessarily the most preferred crops by the farmers. A small percentage of the land was delineated as arable and therefore optimisation of this available land should be prioritized.
- Full Text:
- Date Issued: 2014
- Authors: Manyevere, Alen
- Date: 2014
- Subjects: Soils -- Classification -- South Africa -- Eastern Cape , Soil degradation -- South Africa -- Eastern Cape , Ethnoscience -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD (Soil Science)
- Identifier: vital:11965 , http://hdl.handle.net/10353/d1019856 , Soils -- Classification -- South Africa -- Eastern Cape , Soil degradation -- South Africa -- Eastern Cape , Ethnoscience -- South Africa -- Eastern Cape
- Description: Arable crop production in Nkonkobe Municipality is low due to abandonment of potentially productive land and low productivity of the cultivated land. Little attention has been given to farmers perspectives with regards to crop production and land abandonment. Understanding the relationships of indigenous knowledge systems, where local approaches to soil classification, appraisal, use and management and land evaluation, and scientific approaches could be important for the effective use of available soil resources while avoiding those resources that are vulnerable to degradation. In addition, the interactions between soil factors and climate could be useful in understanding the erodibility of soils. The intergration of scientific research and indigenous knowledge systems could help in the identification and delineation of high potential land and on crop suitability evaluation. The objectives of the study were: (i) to determine farmers‟ perspectives with regards to land utilisation and abandonment, constraints on crop production and crop preferences, (ii) to integrate and compare indigenous knowledge systems with scientific approaches of soil classification and potential, (iii) to determine the effect of climate and soil factors on erodibilities of soils in the Municipality (iv) to delineate arable land and evaluate its suitability for maize, potato, sorghum and cowpea under rainfed agriculture. Using semi-structured and open-ended interviews, information on limitations to crop production, cropping preferences, indigenous soil classifications, cropping potential ratings and erosion was captured. Descriptive and correlation statistics were used to analyse farmers‟ responses. The information was later used for a pilot participatory mapping and the determination of the agricultural potential of the soils in three selected villages of the Municipality. Field boundaries of soil texture, colour, depth, and slope position were captured using global positioning systems (GPS). The relationship between the degree of erosion and soil and slope factors was analysed by step-wise regression. Crop suitability for rainfed agriculture was done using the FAO guidelines for Land evaluation for rainfed agriculture. The spatially referenced crop suitability classes were produced by applying the Law of Limiting Combinationusing GIS Boolean Logic. The major biophysical factors, affecting crop production and land utilisation were soil degradation and low and erratic rainfall, while other factors included lack of farming equipment and security concerns. Maize, spinach and cabbage were the main crops grown, with maize sorghum and wheat the most abandoned crops. While it was difficult to accurately correlate indigenous classification with international scientific classification, the importance of colour, texture and soil depth for both classification and soil potential, suggests that some form of correlation is possible which enabled communication and other extension information to be conveyed. The shallow and stony soil (urhete) correlated well with the Leptosols in World Reference Base (WRB) or Mispah and shallow Glenrosa soils in the South African system. The red structured clays (umhlaba obomvu) matched the Nitisols in WRB or Shortlands in the South African system. The non-swelling black clayey soils (umhlaba omnyama) matched soils with melanic A horizons in both the WRB and South African soil classification systems. The dongwe and santi soils developed in alluvial sediments belonged to the Dundee, Oakleaf or Augrabies soils in the South African classification system and fluvisols or Cambisols in the WRB system. There was good agreement between farmers assessment of the cropping potential and scientific approaches but scientifically high potential red soils were rated lowly by the farmers due to difficulties in management caused by shortages of farm machinery, especially under dryland farming. Overall, the soil factors affecting erosion were influenced largely by climate, while parent material was also important. Climate had a dominant influence on soil factors most notably fine sand and very fine sand fractions and exchangeable sodium percentage being more important on soil forms occurring in arid and semi-arid climate and less in the sub-humid and humid areas, where clay mineralogy, particularly kaolinite and sesquioxide dominated. Dolerite derived soils were the most stable and should be given the highest priority for cropping development while mudstone and shale derived soils had a lower cropping potential. While slope gradient and length had some effect on soil erosion in arid and semi arid environments its influence was generally overshadowed by soil factors especially in humid zones. Cow pea and sorghum were the most adapted crops in the region while potato and maize were marginally suitable under rainfed agriculture. The study revealed that most adapted crops were not necessarily the most preferred crops by the farmers. A small percentage of the land was delineated as arable and therefore optimisation of this available land should be prioritized.
- Full Text:
- Date Issued: 2014
Evaluation of the efficacy of Carpobrotus edulis (L.) bolus leaf as a traditional treatment for the management of HIV/AIDS
- Authors: Omoruyi, Beauty Etinosa
- Date: 2014
- Subjects: AIDS (Disease) -- Treatment -- South Africa -- Eastern Cape , Phytochemicals -- South Africa -- Eastern Cape , Traditional medicine -- South Africa -- Eastern Cape , Carpobrotus
- Language: English
- Type: Thesis , Doctoral , PhD (Biochemistry)
- Identifier: http://hdl.handle.net/10353/744 , vital:26493 , AIDS (Disease) -- Treatment -- South Africa -- Eastern Cape , Phytochemicals -- South Africa -- Eastern Cape , Traditional medicine -- South Africa -- Eastern Cape , Carpobrotus
- Description: The human immunodeficiency virus (HIV) is one of the most common and dreaded diseases of the 21th century. Today, the disease is still spreading with increasing incidence. “Since the beginning of the epidemic, almost 75 million people have been infected with the HIV virus and about 36 million people have died of HIV. Globally, 35.3 million [32.2–38.8 million] people were living with HIV at the end of 2012” (http://www.who.int/gho/hiv/en/). Several studies have been conducted on herbs under a multitude of ethnobotanical grounds. The use of medicinal plants for the management of HIV has become a common practice especially, in the Eastern Cape Province of South Africa (Wilfred Otang Mbeng, 2013 PhD thesis, UFH). At the beginning of this programme, an ethnomedicinal survey of plants used for the management of HIV infection was carried out in targeted areas of the Province and information on the names of plants, the parts and the methods of preparation were collected. The survey revealed that 18 species representing 12 families were found to be commonly used for the management of HIV, as well as other opportunistic diseases such as tuberculosis, diabetes mellitus, sores, high blood pressure, etc. Carpobrotus edulis was selected for this research because it was the most frequently used in the Province. The foliar micro morphological contents of the plant, its phytochemical and antioxidant activity, in vitro antimicrobial activity, inhibitory effect against HIV-1 protease and reverse transcriptase, mechanisms of action and cytotoxicity were investigated. In terms of the foliar micro morphological contents in plants, an electron microscopy scanning (SEM) was completed. Investigation revealed that both glandular tricomes and calcium oxalate crystals (CaOX) were observed. Consequently, it is hypothesized that the bioactive therapeutic compounds secreted by C. edulis may be produced in the glandular trichomes. An investigation of phytochemical content of the plant extracts (C. edulis) was completed using four solvent extracts (hexane, acetone, ethanol and water). Results of the phytochemical analysis showed that proanthocyanidins (86.9 ± 0.005%) where highest in the aqueous extract with phenolics at 55.7 ± 0.404% in acetone extract, tannin at 48.9 ± 0.28% in ethanol extract, while the hexane extract had the highest levels of flavonoids (0.12 ± 0.05%) and flavonols (0.12 ± 0.05%). Antioxidant studies of the various extracts revealed that aqueous and ethanol extracts were found to be the best solvents for antioxidant activity in C. edulis leaves. GC-MS analysis of the essential oil from C. edulis leaves revealed that the essential oil contained at least 28 compounds. These included, in order of abundance: Oxygenated monoterpenes (36.61%); fatty acids esters (19.25%); oxygenated diterpenes (19.24%); monoterpenes (10.6%); sesquiterpenes (3.58%); and diterpenes (1.43%). Similarly, a GC-MS analysis of the crude hexane, acetone and ethanol extracts from C. edulis leaves identified a total of 59 compounds. Of the 59 compounds, 12 major phyto-metabolites that are active against infectious diseases were identified. To comfirm the potential use of C. edulis to treat infectious disease, antifungal activity of the crude essential oil extract and the four solvent extracts were tested against Candida albicans, Candida krusei, Candida glabrata, Candida rugosa and Cryptococcus neoformans strains. The essential oil extract was found to be the most active against all the fungal strains tested and performed better than the four extracts used various solvents used to extract (hexane, acetone, ethanol and water) the C. edulis leaves were tested for antibacterial and anti HIV-1 reverse transcriptase (RT) activity. The results indicated that both gram-positive and gram-negative isolates were inhibited by the extracts (hexane, acetone and ethanol) but antimicrobial activity was observed for the water extract. The lowest minimum inhibitory concentration values were obtained for the ethanol extract, followed by acetone and hexane extracts. No inhibition of HIV-1 reverse transcriptase was observed for any of the leaf extracts, even up to concentrations of 16 mg/ml. The potential inhibitory activities of the various solvent extracts against HIV-1 protease were evaluated at four different concentrations (16, 1.6, 0.16 and 0.016 mg/ml). Results indicated that the water extract showed almost 100% inhibition of HIV-1 protease activity, with an IC50 of 0.86 mg/ml leaf extract. Other solvent extracts (hexane, acetone and ethanol) however, did not show any inhibition activity above that observed for the DMSO control. The metabolic components in the water extract were subjected to LC-MS/MS analysis, which identified at least 91 compounds present in the water extract. Further studies involving the molecular modelling need to be carried out to confirm the inhibitory potential of these compounds. The cytotoxicity of the water extract of C. edulis leaves was also screened using human Chang liver cells at concentrations ranging bewteen 0.005 mg/ml and 1 mg/ml. Results indicated that the water extracts were not toxic. In conclusion the results from this study support the use of water extracts of C. edulis leaves by traditional healers to treat HIV infections and have identified possible mechanisms of action of the water extracts of C. edulis.
- Full Text:
- Date Issued: 2014
- Authors: Omoruyi, Beauty Etinosa
- Date: 2014
- Subjects: AIDS (Disease) -- Treatment -- South Africa -- Eastern Cape , Phytochemicals -- South Africa -- Eastern Cape , Traditional medicine -- South Africa -- Eastern Cape , Carpobrotus
- Language: English
- Type: Thesis , Doctoral , PhD (Biochemistry)
- Identifier: http://hdl.handle.net/10353/744 , vital:26493 , AIDS (Disease) -- Treatment -- South Africa -- Eastern Cape , Phytochemicals -- South Africa -- Eastern Cape , Traditional medicine -- South Africa -- Eastern Cape , Carpobrotus
- Description: The human immunodeficiency virus (HIV) is one of the most common and dreaded diseases of the 21th century. Today, the disease is still spreading with increasing incidence. “Since the beginning of the epidemic, almost 75 million people have been infected with the HIV virus and about 36 million people have died of HIV. Globally, 35.3 million [32.2–38.8 million] people were living with HIV at the end of 2012” (http://www.who.int/gho/hiv/en/). Several studies have been conducted on herbs under a multitude of ethnobotanical grounds. The use of medicinal plants for the management of HIV has become a common practice especially, in the Eastern Cape Province of South Africa (Wilfred Otang Mbeng, 2013 PhD thesis, UFH). At the beginning of this programme, an ethnomedicinal survey of plants used for the management of HIV infection was carried out in targeted areas of the Province and information on the names of plants, the parts and the methods of preparation were collected. The survey revealed that 18 species representing 12 families were found to be commonly used for the management of HIV, as well as other opportunistic diseases such as tuberculosis, diabetes mellitus, sores, high blood pressure, etc. Carpobrotus edulis was selected for this research because it was the most frequently used in the Province. The foliar micro morphological contents of the plant, its phytochemical and antioxidant activity, in vitro antimicrobial activity, inhibitory effect against HIV-1 protease and reverse transcriptase, mechanisms of action and cytotoxicity were investigated. In terms of the foliar micro morphological contents in plants, an electron microscopy scanning (SEM) was completed. Investigation revealed that both glandular tricomes and calcium oxalate crystals (CaOX) were observed. Consequently, it is hypothesized that the bioactive therapeutic compounds secreted by C. edulis may be produced in the glandular trichomes. An investigation of phytochemical content of the plant extracts (C. edulis) was completed using four solvent extracts (hexane, acetone, ethanol and water). Results of the phytochemical analysis showed that proanthocyanidins (86.9 ± 0.005%) where highest in the aqueous extract with phenolics at 55.7 ± 0.404% in acetone extract, tannin at 48.9 ± 0.28% in ethanol extract, while the hexane extract had the highest levels of flavonoids (0.12 ± 0.05%) and flavonols (0.12 ± 0.05%). Antioxidant studies of the various extracts revealed that aqueous and ethanol extracts were found to be the best solvents for antioxidant activity in C. edulis leaves. GC-MS analysis of the essential oil from C. edulis leaves revealed that the essential oil contained at least 28 compounds. These included, in order of abundance: Oxygenated monoterpenes (36.61%); fatty acids esters (19.25%); oxygenated diterpenes (19.24%); monoterpenes (10.6%); sesquiterpenes (3.58%); and diterpenes (1.43%). Similarly, a GC-MS analysis of the crude hexane, acetone and ethanol extracts from C. edulis leaves identified a total of 59 compounds. Of the 59 compounds, 12 major phyto-metabolites that are active against infectious diseases were identified. To comfirm the potential use of C. edulis to treat infectious disease, antifungal activity of the crude essential oil extract and the four solvent extracts were tested against Candida albicans, Candida krusei, Candida glabrata, Candida rugosa and Cryptococcus neoformans strains. The essential oil extract was found to be the most active against all the fungal strains tested and performed better than the four extracts used various solvents used to extract (hexane, acetone, ethanol and water) the C. edulis leaves were tested for antibacterial and anti HIV-1 reverse transcriptase (RT) activity. The results indicated that both gram-positive and gram-negative isolates were inhibited by the extracts (hexane, acetone and ethanol) but antimicrobial activity was observed for the water extract. The lowest minimum inhibitory concentration values were obtained for the ethanol extract, followed by acetone and hexane extracts. No inhibition of HIV-1 reverse transcriptase was observed for any of the leaf extracts, even up to concentrations of 16 mg/ml. The potential inhibitory activities of the various solvent extracts against HIV-1 protease were evaluated at four different concentrations (16, 1.6, 0.16 and 0.016 mg/ml). Results indicated that the water extract showed almost 100% inhibition of HIV-1 protease activity, with an IC50 of 0.86 mg/ml leaf extract. Other solvent extracts (hexane, acetone and ethanol) however, did not show any inhibition activity above that observed for the DMSO control. The metabolic components in the water extract were subjected to LC-MS/MS analysis, which identified at least 91 compounds present in the water extract. Further studies involving the molecular modelling need to be carried out to confirm the inhibitory potential of these compounds. The cytotoxicity of the water extract of C. edulis leaves was also screened using human Chang liver cells at concentrations ranging bewteen 0.005 mg/ml and 1 mg/ml. Results indicated that the water extracts were not toxic. In conclusion the results from this study support the use of water extracts of C. edulis leaves by traditional healers to treat HIV infections and have identified possible mechanisms of action of the water extracts of C. edulis.
- Full Text:
- Date Issued: 2014
Assessment of the anti-Listerial properties of Garcinia kola (Heckel) seeds
- Authors: Penduka, Dambudzo
- Date: 2014
- Subjects: Microbial sensitivity tests , Garcinia , Medicinal plants , Traditional medicine
- Language: English
- Type: Thesis , Doctoral , PhD (Microbiology)
- Identifier: vital:11278 , http://hdl.handle.net/10353/d1015527 , Microbial sensitivity tests , Garcinia , Medicinal plants , Traditional medicine
- Description: A follow-up of traditional medicinal plants uses is an important tool in highlighting their therapeutic potentials, as they have been found to be a source of a wide range of bioactive compounds that can be used as base compounds for new pharmaceutical drugs. This study therefore focuses on assessing the anti-Listerial properties of the seeds of Garcinia kola (Heckel) plant, which is a traditional medicinal plant of west and central African origin, and was and is still used to traditionally treat several ailments. Four different solvents crude extracts of the seeds were assessed for their anti-Listerial activities in-vitro, against a panel of 42 Listeria bacteria, which included Listeria monocytogenes, Listeria ivanovii and Listeria grayi species. At 10 mg/ml concentration the aqueous extract had activity against 29% of the test isolates while the other three crude extracts namely dichloromethane, n-hexane and the methanol extracts had activity against 45% of the test bacteria. The minimum inhibitory concentration (MIC) ranges of the extracts were 0.079-0.313 mg/ml for the dichloromethane extract; 0.079-0.625 mg/ml for the n-hexane extract; 0.157-0.625 mg/ml for the methanol extract; and 10->10 mg/ml for the aqueous extract. The minimum bactericidal concentration (MBC) ranges of the extracts were 0.625–10 mg/ml for both the n-hexane and the dichloromethane extract; 5-10 mg/ml for the methanol extract; and those for the aqueous extract were above 10 mg/ml against all the susceptible Listeria isolates. The rate of kill analysis was then determined for the three most active crude extracts that is excluding the aqueous extract and it was assessed against four representative Listeria species namely L. monocytogenes (LAL 8), L. grayi (LAL 15), L. ivanovii (LEL 30) and L. ivanovii (LEL 18). All the three extracts showed a general trend of being concentration and time dependent in their rate of kill profiles such that most bacteria cells were killed at the highest test concentration of 4× MIC value after the maximum exposure time of 2 h. The n-hexane, dichloromethane and methanol extracts were bactericidal against 4, 3 and 1 isolates out of the four test Listeria isolates respectively.
- Full Text:
- Date Issued: 2014
- Authors: Penduka, Dambudzo
- Date: 2014
- Subjects: Microbial sensitivity tests , Garcinia , Medicinal plants , Traditional medicine
- Language: English
- Type: Thesis , Doctoral , PhD (Microbiology)
- Identifier: vital:11278 , http://hdl.handle.net/10353/d1015527 , Microbial sensitivity tests , Garcinia , Medicinal plants , Traditional medicine
- Description: A follow-up of traditional medicinal plants uses is an important tool in highlighting their therapeutic potentials, as they have been found to be a source of a wide range of bioactive compounds that can be used as base compounds for new pharmaceutical drugs. This study therefore focuses on assessing the anti-Listerial properties of the seeds of Garcinia kola (Heckel) plant, which is a traditional medicinal plant of west and central African origin, and was and is still used to traditionally treat several ailments. Four different solvents crude extracts of the seeds were assessed for their anti-Listerial activities in-vitro, against a panel of 42 Listeria bacteria, which included Listeria monocytogenes, Listeria ivanovii and Listeria grayi species. At 10 mg/ml concentration the aqueous extract had activity against 29% of the test isolates while the other three crude extracts namely dichloromethane, n-hexane and the methanol extracts had activity against 45% of the test bacteria. The minimum inhibitory concentration (MIC) ranges of the extracts were 0.079-0.313 mg/ml for the dichloromethane extract; 0.079-0.625 mg/ml for the n-hexane extract; 0.157-0.625 mg/ml for the methanol extract; and 10->10 mg/ml for the aqueous extract. The minimum bactericidal concentration (MBC) ranges of the extracts were 0.625–10 mg/ml for both the n-hexane and the dichloromethane extract; 5-10 mg/ml for the methanol extract; and those for the aqueous extract were above 10 mg/ml against all the susceptible Listeria isolates. The rate of kill analysis was then determined for the three most active crude extracts that is excluding the aqueous extract and it was assessed against four representative Listeria species namely L. monocytogenes (LAL 8), L. grayi (LAL 15), L. ivanovii (LEL 30) and L. ivanovii (LEL 18). All the three extracts showed a general trend of being concentration and time dependent in their rate of kill profiles such that most bacteria cells were killed at the highest test concentration of 4× MIC value after the maximum exposure time of 2 h. The n-hexane, dichloromethane and methanol extracts were bactericidal against 4, 3 and 1 isolates out of the four test Listeria isolates respectively.
- Full Text:
- Date Issued: 2014
Investigation of the NFC technology for mobile payments and the development of a prototype payment application in the context of marginalized rural areas
- Authors: Gurajena, Caroline
- Date: 2014
- Subjects: Mobile commerce -- South Africa Mobile communication systems -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/14071 , vital:39802
- Description: The Internet of Things (IoT) environment involves the interaction of numerous ‘things’. These ‘things’ are embedded with different kinds of technologies such as RFID technology, NFC technology and sensors. This causes IoT to bring into play many security risks apart from the ones that already exist in the current Internet, for example, embedded RFID tags can be easily triggered and send their content which could be private information. IoT also introduces internal attacks such as on-off attack, bad mouthing and white washing attacks into networks that already exist. These internal attacks cannot be solved by hard security mechanisms such as cryptographic algorithms and firewalls because they guarantee total trust. This eliminates uncertainty which should always be available where trust exist. That is, hard security mechanisms enable IoT ‘things’ to either trust another ‘thing’ completely or not and this makes them unsuitable for the IoT environment. When objects in any network are communicating, there is some element of uncertainty. Also, hard security mechanisms such as public key cryptography cause communication overheard in the already resource-constrained IoT devices and these conventional cryptography methods cannot deal with internal attacks. This brings about the need for a middleware that includes functions that will manage trust, privacy and security issues of all data exchange, communications and network connections. For IoT to be successful, the provision of trust, security and privacy measures are essential. Trust management may enhance the adoption and security measures in IoT. Trust helps in identifying trustworthy ‘things’ in the network and give ‘things’ in the network the ability to reason in all aspects concerning trust in the environment. Trust can be administered through a trust management model. This research notes that most of the trust models that have been proposed fail to address scalability challenges and lack suitable computation methods. It is on that premise that this research focuses on developing a suitable trust model for the IoT environment. The research also introduces new ways of creating relationships in IoT. This enables the creation of new cooperation opportunities in the environment. In overall, this research aimed to design and develop a generic trust and authority delegation model for the heterogonous IoT environment that is scalable and generalized to cater for the heterogeneous IoT environment. This research was conducted in three phases. The first phase reviewed literature in order to identify outstanding issues in IoT trust management and also identify the suitable computational method. This provided a critical analysis of different computational methods highlighting their advantages and limitations. In the second phase of the research, the proposed trust model was designed and tested. In the last phase, the feasibility of the proposed model was evaluated. The proposed model is based on fuzzy logic. Fuzzy logic was selected for trust computation because it is able to imitate the process of the human mind through the use of linguistic variables and it can handle uncertainty. The proposed model was tested in a simulated environment. The simulation results showed that the proposed model can identify selfish and malicious entities effectively. The results also showed that the model was able to deal with different types of behaviours of entities. The testing proved that the proposed trust model can support decision making in IoT based on trust. The results from the evaluation show that this research ameliorates the design and development of trust management solutions for the IoT environment.
- Full Text:
- Date Issued: 2014
- Authors: Gurajena, Caroline
- Date: 2014
- Subjects: Mobile commerce -- South Africa Mobile communication systems -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/14071 , vital:39802
- Description: The Internet of Things (IoT) environment involves the interaction of numerous ‘things’. These ‘things’ are embedded with different kinds of technologies such as RFID technology, NFC technology and sensors. This causes IoT to bring into play many security risks apart from the ones that already exist in the current Internet, for example, embedded RFID tags can be easily triggered and send their content which could be private information. IoT also introduces internal attacks such as on-off attack, bad mouthing and white washing attacks into networks that already exist. These internal attacks cannot be solved by hard security mechanisms such as cryptographic algorithms and firewalls because they guarantee total trust. This eliminates uncertainty which should always be available where trust exist. That is, hard security mechanisms enable IoT ‘things’ to either trust another ‘thing’ completely or not and this makes them unsuitable for the IoT environment. When objects in any network are communicating, there is some element of uncertainty. Also, hard security mechanisms such as public key cryptography cause communication overheard in the already resource-constrained IoT devices and these conventional cryptography methods cannot deal with internal attacks. This brings about the need for a middleware that includes functions that will manage trust, privacy and security issues of all data exchange, communications and network connections. For IoT to be successful, the provision of trust, security and privacy measures are essential. Trust management may enhance the adoption and security measures in IoT. Trust helps in identifying trustworthy ‘things’ in the network and give ‘things’ in the network the ability to reason in all aspects concerning trust in the environment. Trust can be administered through a trust management model. This research notes that most of the trust models that have been proposed fail to address scalability challenges and lack suitable computation methods. It is on that premise that this research focuses on developing a suitable trust model for the IoT environment. The research also introduces new ways of creating relationships in IoT. This enables the creation of new cooperation opportunities in the environment. In overall, this research aimed to design and develop a generic trust and authority delegation model for the heterogonous IoT environment that is scalable and generalized to cater for the heterogeneous IoT environment. This research was conducted in three phases. The first phase reviewed literature in order to identify outstanding issues in IoT trust management and also identify the suitable computational method. This provided a critical analysis of different computational methods highlighting their advantages and limitations. In the second phase of the research, the proposed trust model was designed and tested. In the last phase, the feasibility of the proposed model was evaluated. The proposed model is based on fuzzy logic. Fuzzy logic was selected for trust computation because it is able to imitate the process of the human mind through the use of linguistic variables and it can handle uncertainty. The proposed model was tested in a simulated environment. The simulation results showed that the proposed model can identify selfish and malicious entities effectively. The results also showed that the model was able to deal with different types of behaviours of entities. The testing proved that the proposed trust model can support decision making in IoT based on trust. The results from the evaluation show that this research ameliorates the design and development of trust management solutions for the IoT environment.
- Full Text:
- Date Issued: 2014
Modelling payment systems for environmental services in the Mt Elgon ecosystem of Kenya
- Authors: Kisaka, Lily
- Date: 2014
- Subjects: Ecological disturbances -- Kenya , Freshwater ecology -- Kenya , Water quality biological assessment -- Kenya , Land degradation -- Kenya , Ecosystem health -- Kenya
- Language: English
- Type: Thesis , Doctoral , PhD (Agricultural Economics)
- Identifier: vital:11206 , http://hdl.handle.net/10353/d1013123 , Ecological disturbances -- Kenya , Freshwater ecology -- Kenya , Water quality biological assessment -- Kenya , Land degradation -- Kenya , Ecosystem health -- Kenya
- Description: Unsustainable patterns of consumption by humankind have increased the rate of change in the natural ecosystems and consequently the levels of stress experienced within the environment. Access to sufficient good quality water is essential and a requirement to meet a number of the Millennium Development Goals (MDGs). However, poor land management and untenable agricultural practices have become the main drivers of the declining watershed services. Upstream farmers often have little or no incentives to take these impacts into account in their decision-making process. Therefore, without investment in ensuring proper land management, the trend in watersheds degradation will continue. Payment for Environmental Services (PES) has emerged as an incentive–based tool that is expected to motivate farmers to improve their agricultural practices. PES is set up to facilitate the process whereby the beneficiaries of environmental services pay compensation to providers of environmental services for conserving the ecosystem. This tool has received increasing attention as a means of creating incentive measures for managing the ecosystem, addressing livelihood issues for the rural poor, and providing sustainable financing for protected areas. The Government of Kenya, as part of its efforts to improve water resource management, is considering use of economic incentive. However, there is insufficient information to guide policy making in that direction. Little is known about the farmers’ preferences for management schemes that will affect land use patterns, their willingness to accept compensation and the willingness of potential buyers to pay for the services. This study evaluates the willingness to accept and the willingness to pay for environmental services with a view to assessing the viability of a PES scheme for the Kuywa Watershed in particular, as well as the Mt. Elgon Ecosystem and other areas with similar conditions. The objectives of the study are threefold (i) to examine respondents preferences for management options for the provision of environmental services in the watershed of River Kuywa of Mt. Elgon Ecosystem; (ii) to evaluate households’ willingness to pay (WTP) and willingness to accept (WTA) payment for improved environmental services from the River Kuywa watershed; and (iii) to propose viable PES approaches for the management of the natural resource of the Kuywa watershed and the Mt. Elgon ecosystem in general. Using six land management attributes relevant to the local situation, the study applied the conjoint method to evaluate farmers’ preferences for management options for the provision of environmental service and assess farmers’ willingness to pay and willingness to accept payment for environmental services. To enable assessment of viability, an analysis was done of the institutional and legal framework within which the PES scheme would operate. Data were collected using literature review and document analysis, questionnaires, focus group discussions and key informant interviews. Results indicate that poor water quality was the most acute problem, followed by deforestation. Results from the conjoint models show that the length of commitment period and land size that is 40% or more of the total land holding influence the farmers’ rating of the management scenarios. The study found that a management contract that requires use of 20% of land holding for a period of 5 years, combined with a cash incentive, harvesting partially permitted, administered by a local NGO and requiring contribution of free labour for two days had the highest likelihood of being selected. The conjoint valuation exercise also came up with a WTA by farmers upstream of KSh. 7,080/= per year. The corresponding value downstream was KSh. 43/= per month over and above their regular water bill. In terms of the institutional and regulatory framework, Kenya has a wide range of policies, laws and regulation on water and other natural resources which provide an enabling environment for PES. With the decentralized institutional setup implemented in both the water sector and the agricultural sector, the institutional setting also provides an enabling environment for PES. With a positive WTA and WTP coupled with an enabling legal and institutional environment, the study concludes that PES is a viable environmental management tool for the Kuywa water shed and similar watersheds.
- Full Text:
- Date Issued: 2014
- Authors: Kisaka, Lily
- Date: 2014
- Subjects: Ecological disturbances -- Kenya , Freshwater ecology -- Kenya , Water quality biological assessment -- Kenya , Land degradation -- Kenya , Ecosystem health -- Kenya
- Language: English
- Type: Thesis , Doctoral , PhD (Agricultural Economics)
- Identifier: vital:11206 , http://hdl.handle.net/10353/d1013123 , Ecological disturbances -- Kenya , Freshwater ecology -- Kenya , Water quality biological assessment -- Kenya , Land degradation -- Kenya , Ecosystem health -- Kenya
- Description: Unsustainable patterns of consumption by humankind have increased the rate of change in the natural ecosystems and consequently the levels of stress experienced within the environment. Access to sufficient good quality water is essential and a requirement to meet a number of the Millennium Development Goals (MDGs). However, poor land management and untenable agricultural practices have become the main drivers of the declining watershed services. Upstream farmers often have little or no incentives to take these impacts into account in their decision-making process. Therefore, without investment in ensuring proper land management, the trend in watersheds degradation will continue. Payment for Environmental Services (PES) has emerged as an incentive–based tool that is expected to motivate farmers to improve their agricultural practices. PES is set up to facilitate the process whereby the beneficiaries of environmental services pay compensation to providers of environmental services for conserving the ecosystem. This tool has received increasing attention as a means of creating incentive measures for managing the ecosystem, addressing livelihood issues for the rural poor, and providing sustainable financing for protected areas. The Government of Kenya, as part of its efforts to improve water resource management, is considering use of economic incentive. However, there is insufficient information to guide policy making in that direction. Little is known about the farmers’ preferences for management schemes that will affect land use patterns, their willingness to accept compensation and the willingness of potential buyers to pay for the services. This study evaluates the willingness to accept and the willingness to pay for environmental services with a view to assessing the viability of a PES scheme for the Kuywa Watershed in particular, as well as the Mt. Elgon Ecosystem and other areas with similar conditions. The objectives of the study are threefold (i) to examine respondents preferences for management options for the provision of environmental services in the watershed of River Kuywa of Mt. Elgon Ecosystem; (ii) to evaluate households’ willingness to pay (WTP) and willingness to accept (WTA) payment for improved environmental services from the River Kuywa watershed; and (iii) to propose viable PES approaches for the management of the natural resource of the Kuywa watershed and the Mt. Elgon ecosystem in general. Using six land management attributes relevant to the local situation, the study applied the conjoint method to evaluate farmers’ preferences for management options for the provision of environmental service and assess farmers’ willingness to pay and willingness to accept payment for environmental services. To enable assessment of viability, an analysis was done of the institutional and legal framework within which the PES scheme would operate. Data were collected using literature review and document analysis, questionnaires, focus group discussions and key informant interviews. Results indicate that poor water quality was the most acute problem, followed by deforestation. Results from the conjoint models show that the length of commitment period and land size that is 40% or more of the total land holding influence the farmers’ rating of the management scenarios. The study found that a management contract that requires use of 20% of land holding for a period of 5 years, combined with a cash incentive, harvesting partially permitted, administered by a local NGO and requiring contribution of free labour for two days had the highest likelihood of being selected. The conjoint valuation exercise also came up with a WTA by farmers upstream of KSh. 7,080/= per year. The corresponding value downstream was KSh. 43/= per month over and above their regular water bill. In terms of the institutional and regulatory framework, Kenya has a wide range of policies, laws and regulation on water and other natural resources which provide an enabling environment for PES. With the decentralized institutional setup implemented in both the water sector and the agricultural sector, the institutional setting also provides an enabling environment for PES. With a positive WTA and WTP coupled with an enabling legal and institutional environment, the study concludes that PES is a viable environmental management tool for the Kuywa water shed and similar watersheds.
- Full Text:
- Date Issued: 2014