The weekly newsletter for COSATU - Affiliates and Regions
- COSATU
- Authors: COSATU
- Date: 2001
- Subjects: COSATU
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/109802 , vital:33191
- Description: The largest nursing organisation in the country, the Democratic Nursing Organisation of South Africa (DENOSA), has taken a historic decision to join COSATU at its recent congress held last week in Pretoria. The 200 delegates at the congress voted in favour of the move. The congress was held between under theme: ’’Nursing facing challenges. Development and HIV/Aids." COSATU campaigns secretary, Mcedisi Nontseie, said the union’s affiliation is a step forward in the consolidation of public sector unions within the federation. "This also consolidates white collar workers within the federation and further demystifies the long held reactionary notion that COSATU only represents workers in the lower ranks,” said Nontseie. South African Football Players Organisation (SAPPU) and Performing Arts Workers Equity (PAWE) joined the federation last year. DONOSA’s affiliation is set to boost the federation’s membership from its present of 1.8 million.
- Full Text:
- Date Issued: 2001
- Authors: COSATU
- Date: 2001
- Subjects: COSATU
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/109802 , vital:33191
- Description: The largest nursing organisation in the country, the Democratic Nursing Organisation of South Africa (DENOSA), has taken a historic decision to join COSATU at its recent congress held last week in Pretoria. The 200 delegates at the congress voted in favour of the move. The congress was held between under theme: ’’Nursing facing challenges. Development and HIV/Aids." COSATU campaigns secretary, Mcedisi Nontseie, said the union’s affiliation is a step forward in the consolidation of public sector unions within the federation. "This also consolidates white collar workers within the federation and further demystifies the long held reactionary notion that COSATU only represents workers in the lower ranks,” said Nontseie. South African Football Players Organisation (SAPPU) and Performing Arts Workers Equity (PAWE) joined the federation last year. DONOSA’s affiliation is set to boost the federation’s membership from its present of 1.8 million.
- Full Text:
- Date Issued: 2001
Syntheses and photochemical properties of octasubstituted phthalocyaninato zinc complexes
- Maree, Suzanne, Nyokong, Tebello
- Authors: Maree, Suzanne , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/304841 , vital:58495 , xlink:href="https://doi.org/10.1002/jpp.388"
- Description: In this work a selection of octasubstituted phthalocyaninato zinc complexes were synthesized and their photochemistry studied. The substituents included cholesterol (3a), estrone (3b), naphthol (3c) and phenoxy groups substituted with CH3 (3d), C(CH3)3 (at two positions, 3e), C(CH3)3 (3f), NO2 (3g), NH2 (3h), COH (3i), COOH (3j), and H (3k). In general, complexes containing electron-donating groups attached to the phenoxy ring (e.g. 3e and 3f) were found to be photochemically unstable with photobleaching quantum yields of the order of 10−3. In the presence of electron-withdrawing groups (3g, 3i, and 3j) the photobleaching quantum yields were of the order of 10−6 to 10−5. Singlet oxygen quantum yields (ΦΔ) ranged from 0.01 to 0.73. The lowest ΦΔ was observed for the highly aggregated complex 3c. All the complexes showed aggregation at high concentrations. Electrochemical reduction using a thin-layer spectroelectrochemistry cell showed that the complexes become more monomeric following reduction.
- Full Text:
- Date Issued: 2001
- Authors: Maree, Suzanne , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/304841 , vital:58495 , xlink:href="https://doi.org/10.1002/jpp.388"
- Description: In this work a selection of octasubstituted phthalocyaninato zinc complexes were synthesized and their photochemistry studied. The substituents included cholesterol (3a), estrone (3b), naphthol (3c) and phenoxy groups substituted with CH3 (3d), C(CH3)3 (at two positions, 3e), C(CH3)3 (3f), NO2 (3g), NH2 (3h), COH (3i), COOH (3j), and H (3k). In general, complexes containing electron-donating groups attached to the phenoxy ring (e.g. 3e and 3f) were found to be photochemically unstable with photobleaching quantum yields of the order of 10−3. In the presence of electron-withdrawing groups (3g, 3i, and 3j) the photobleaching quantum yields were of the order of 10−6 to 10−5. Singlet oxygen quantum yields (ΦΔ) ranged from 0.01 to 0.73. The lowest ΦΔ was observed for the highly aggregated complex 3c. All the complexes showed aggregation at high concentrations. Electrochemical reduction using a thin-layer spectroelectrochemistry cell showed that the complexes become more monomeric following reduction.
- Full Text:
- Date Issued: 2001
Solvent-free axial ligand substitution in octaphenoxyphthalocyaninato silicon complexes using microwave irradiation
- Maree, M David, Nyokong, Tebello
- Authors: Maree, M David , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/304830 , vital:58494 , xlink:href="https://journals.sagepub.com/doi/epdf/10.3184/030823401103168974"
- Description: Several axially substituted octaphenoxy silicon phthalocyanines were prepared by condensation of the complexes used as axial ligands with octaphenoxyphthalocyaninato (dichloro) silicon under microwave irradiation.
- Full Text:
- Date Issued: 2001
- Authors: Maree, M David , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/304830 , vital:58494 , xlink:href="https://journals.sagepub.com/doi/epdf/10.3184/030823401103168974"
- Description: Several axially substituted octaphenoxy silicon phthalocyanines were prepared by condensation of the complexes used as axial ligands with octaphenoxyphthalocyaninato (dichloro) silicon under microwave irradiation.
- Full Text:
- Date Issued: 2001
Effect of oligomerization on the photochemical properties of silicon octaphenoxyphthalocyanine
- Maree, M David, Nyokong, Tebello
- Authors: Maree, M David , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291542 , vital:56885 , xlink:href="https://doi.org/10.1016/S1010-6030(01)00485-3"
- Description: The photochemical properties of silicon octaphenoxyphthalocyanines (SiOPPc) oligomerized were studied in dimethylsulfoxide (DMSO) solutions. Oligomers containing 2–5 and 9 SiOPPc rings linked with terephthalate linkages were synthesized. Singlet oxygen quantum yields were found to be in the range 0.11–0.34, and increased with the number of rings up to five rings, a decrease in the quantum yield was observed for nine rings. This is explained in terms of the high aggregation of the oligomer containing nine rings.
- Full Text:
- Date Issued: 2001
- Authors: Maree, M David , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291542 , vital:56885 , xlink:href="https://doi.org/10.1016/S1010-6030(01)00485-3"
- Description: The photochemical properties of silicon octaphenoxyphthalocyanines (SiOPPc) oligomerized were studied in dimethylsulfoxide (DMSO) solutions. Oligomers containing 2–5 and 9 SiOPPc rings linked with terephthalate linkages were synthesized. Singlet oxygen quantum yields were found to be in the range 0.11–0.34, and increased with the number of rings up to five rings, a decrease in the quantum yield was observed for nine rings. This is explained in terms of the high aggregation of the oligomer containing nine rings.
- Full Text:
- Date Issued: 2001
Working conditions agreement for SACCAWU employees
- SACCAWU
- Authors: SACCAWU
- Date: 2001
- Subjects: SACCAWU
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/175924 , vital:42641
- Description: As a SACCAWU Staff Member it is important to know exactly what your Conditions of Service are hence this booklet. The Union believes in the principle of good and fair treatment of Staff and sees this as encouraging motivated and dedicated Officials. We have therefore tried to make Conditions as favourable as possible within the constraints of being a no-profit making organisation. In return, however the organisation does expect diligence, commitment and efficiency. Staff have the right before 1st March, every year to put forward proposals to* National Finance Committee in order to improve Working Conditions. Two Representatives elected from each Region will attend National Discussions/Engagements which shall put together a national mandate and elect Representatives to meet with NFC.
- Full Text:
- Date Issued: 2001
- Authors: SACCAWU
- Date: 2001
- Subjects: SACCAWU
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/175924 , vital:42641
- Description: As a SACCAWU Staff Member it is important to know exactly what your Conditions of Service are hence this booklet. The Union believes in the principle of good and fair treatment of Staff and sees this as encouraging motivated and dedicated Officials. We have therefore tried to make Conditions as favourable as possible within the constraints of being a no-profit making organisation. In return, however the organisation does expect diligence, commitment and efficiency. Staff have the right before 1st March, every year to put forward proposals to* National Finance Committee in order to improve Working Conditions. Two Representatives elected from each Region will attend National Discussions/Engagements which shall put together a national mandate and elect Representatives to meet with NFC.
- Full Text:
- Date Issued: 2001
Study abroad in South Africa
- International Education Association of South Africa (IEASA), Mason, Andy
- Authors: International Education Association of South Africa (IEASA) , Mason, Andy
- Date: 2001
- Subjects: Education, Higher -- South Africa , Education and globalization -- South Africa Student mobility -- Africa International education -- South Africa Education, Higher -- International cooperation , Universities and colleges -- South Africa , Technical Institutes -- South Africa , Vocational guidance -- South Africa
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/65375 , vital:28753 , ISBN 0620247290
- Description: [Message from the Honorable Minister of Education, Prof. Kader Asmal]: I am pleased to provide a message for this important Guide to South African Universities and Technikons so soon after my appointment as Minister of Education. Each country depends on the higher education system to meet high human resource needs and to be the engine for the creation of new knowledge and innovation, and critical discourse. Our system offers students a wide choice of career options in a variety of differing environments of a world-class standard. Our universities and technikons play a vital role in preparing students, by equipping them with the necessary knowledge and skills, to take up their rightful place in society and to contribute to the socio-economic development of our country and the many other countries from which students come to study in South Africa. This also affords them the opportunity of making a substantial contribution to the development of human resources in their specialised fields. Like schools, our universities, technikons and other third level institutions must become vibrant centres of community and cultural life. We are looking at the ways in which universities can contribute to the responsibility of citizenship - within an atmosphere of voluntary help. This may be in the form of community service, which many institutions are already involved in, or, for instance, in the form of assisting with a national literacy campaign. In addition they must provide a safe and secure environment conducive to promoting their mission of teaching and learning, scholarship and research, and community service. Proper preparation for the challenges of a fast globalising world is essential if our students are to contribute to the development of the societies and the countries in which they live. Therefore I am committed to building a responsive higher education system of high quality. Such a system should demonstrate its readiness to meet the challenges of the 20st Century. , 1st Edition
- Full Text:
- Date Issued: 2001
- Authors: International Education Association of South Africa (IEASA) , Mason, Andy
- Date: 2001
- Subjects: Education, Higher -- South Africa , Education and globalization -- South Africa Student mobility -- Africa International education -- South Africa Education, Higher -- International cooperation , Universities and colleges -- South Africa , Technical Institutes -- South Africa , Vocational guidance -- South Africa
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/65375 , vital:28753 , ISBN 0620247290
- Description: [Message from the Honorable Minister of Education, Prof. Kader Asmal]: I am pleased to provide a message for this important Guide to South African Universities and Technikons so soon after my appointment as Minister of Education. Each country depends on the higher education system to meet high human resource needs and to be the engine for the creation of new knowledge and innovation, and critical discourse. Our system offers students a wide choice of career options in a variety of differing environments of a world-class standard. Our universities and technikons play a vital role in preparing students, by equipping them with the necessary knowledge and skills, to take up their rightful place in society and to contribute to the socio-economic development of our country and the many other countries from which students come to study in South Africa. This also affords them the opportunity of making a substantial contribution to the development of human resources in their specialised fields. Like schools, our universities, technikons and other third level institutions must become vibrant centres of community and cultural life. We are looking at the ways in which universities can contribute to the responsibility of citizenship - within an atmosphere of voluntary help. This may be in the form of community service, which many institutions are already involved in, or, for instance, in the form of assisting with a national literacy campaign. In addition they must provide a safe and secure environment conducive to promoting their mission of teaching and learning, scholarship and research, and community service. Proper preparation for the challenges of a fast globalising world is essential if our students are to contribute to the development of the societies and the countries in which they live. Therefore I am committed to building a responsive higher education system of high quality. Such a system should demonstrate its readiness to meet the challenges of the 20st Century. , 1st Edition
- Full Text:
- Date Issued: 2001
Configuring convergence : southern African websites looking at American experience
- Authors: Berger, Guy
- Date: 2001
- Language: English
- Type: text
- Identifier: vital:535 , http://hdl.handle.net/10962/d1008553 , ISBN 0-86810-379-9
- Description: I want the Web to win. Africa’s news sites on the Internet need to succeed and survive. They’re a small guarantee against global marginalisation, and a critical intersection across our continent’s domestic divides. But the outlook is not good. At a conference I went to in Berkeley in April 2001, a venture capitalist had this to say: "If I were to make a speech on when there’ll be investment in new media again, it would be a rather short topic." The alarming closures and retrenchments at news websites in the USA are sending scary signals to our fledgling efforts back here. Starting and growing media enterprises of any sort in African conditions has never been easy. Long starved of investment, our cyberpublishing now faces even greater pressures as old media – newspapers, radio and TV – try to make ends meet under mounting threats. Advertising is shrinking, local costs are rising and currency falls are fuelling the price of imported production factors. Consumers have less cash to spend. Governments are giving even greater problems in some cases. Will we still be here in the morning, and in what condition? This booklet suggests the way forward is for new media to converge with selected partners, old media and new.
- Full Text:
- Date Issued: 2001
- Authors: Berger, Guy
- Date: 2001
- Language: English
- Type: text
- Identifier: vital:535 , http://hdl.handle.net/10962/d1008553 , ISBN 0-86810-379-9
- Description: I want the Web to win. Africa’s news sites on the Internet need to succeed and survive. They’re a small guarantee against global marginalisation, and a critical intersection across our continent’s domestic divides. But the outlook is not good. At a conference I went to in Berkeley in April 2001, a venture capitalist had this to say: "If I were to make a speech on when there’ll be investment in new media again, it would be a rather short topic." The alarming closures and retrenchments at news websites in the USA are sending scary signals to our fledgling efforts back here. Starting and growing media enterprises of any sort in African conditions has never been easy. Long starved of investment, our cyberpublishing now faces even greater pressures as old media – newspapers, radio and TV – try to make ends meet under mounting threats. Advertising is shrinking, local costs are rising and currency falls are fuelling the price of imported production factors. Consumers have less cash to spend. Governments are giving even greater problems in some cases. Will we still be here in the morning, and in what condition? This booklet suggests the way forward is for new media to converge with selected partners, old media and new.
- Full Text:
- Date Issued: 2001
Economic review 2001
- DITSELA
- Authors: DITSELA
- Date: 2001
- Subjects: Development Institute for Training,Support and Education for Labour (DITSELA)
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/178602 , vital:42958
- Description: This volume of Bargaining Indicators for 2002 comes in the context of the September 11 attacks on the World Trade Center in New York, the United States’ war on Afghanistan, the collapse of the economy of Argentina and with it the biggest sovereign bankruptcy in history. All these historic events are unfolding within the first synchronised global recession since the 1970s, and have in turn deepened this recession. Within South Africa, this edition of Bargaining Indicators comes in the context of the first anti-government national strike by organised labour since the 1994 elections, and a deepening of the economic slowdown that we noted in the last edition of Bargaining Indicators. In this review of economic developments during 2001 we shine the spotlight on the global recession and its dynamics, and we look in particular at the slide of the world’s largest economy - that of the United States - into its first serious economic crisis since the end of the cold war, and we take a look at the significance of the attacks of September 11 and their aftermath on the dynamics of the global recession. We conclude our discussion of the global recession by discussing the responses of the Bush government and its allies, and at the meaning of these responses for neoliberal economic orthodoxy. We continue our analysis by looking at developments within the South African economy. In particular, we look at the implications of the global recession on the South African economy, and at how the currency crisis that has unfolded since the last quarter of 2001 forms an important moment in the dynamics of the unfolding global recession. Within this context we look at the main economic indicators (GDP; GDE; fixed capital formation, operating surpluses, wages, employment, savings and so on). Lastly, we look at the year ahead, and in particular at the implications of the global and domestic economic developments for the 2002 bargaining season.
- Full Text:
- Date Issued: 2001
- Authors: DITSELA
- Date: 2001
- Subjects: Development Institute for Training,Support and Education for Labour (DITSELA)
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/178602 , vital:42958
- Description: This volume of Bargaining Indicators for 2002 comes in the context of the September 11 attacks on the World Trade Center in New York, the United States’ war on Afghanistan, the collapse of the economy of Argentina and with it the biggest sovereign bankruptcy in history. All these historic events are unfolding within the first synchronised global recession since the 1970s, and have in turn deepened this recession. Within South Africa, this edition of Bargaining Indicators comes in the context of the first anti-government national strike by organised labour since the 1994 elections, and a deepening of the economic slowdown that we noted in the last edition of Bargaining Indicators. In this review of economic developments during 2001 we shine the spotlight on the global recession and its dynamics, and we look in particular at the slide of the world’s largest economy - that of the United States - into its first serious economic crisis since the end of the cold war, and we take a look at the significance of the attacks of September 11 and their aftermath on the dynamics of the global recession. We conclude our discussion of the global recession by discussing the responses of the Bush government and its allies, and at the meaning of these responses for neoliberal economic orthodoxy. We continue our analysis by looking at developments within the South African economy. In particular, we look at the implications of the global recession on the South African economy, and at how the currency crisis that has unfolded since the last quarter of 2001 forms an important moment in the dynamics of the unfolding global recession. Within this context we look at the main economic indicators (GDP; GDE; fixed capital formation, operating surpluses, wages, employment, savings and so on). Lastly, we look at the year ahead, and in particular at the implications of the global and domestic economic developments for the 2002 bargaining season.
- Full Text:
- Date Issued: 2001
The many faces of racism:
- Garman, Anthea, Baumann, Melissa
- Authors: Garman, Anthea , Baumann, Melissa
- Date: 2001
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158729 , vital:40223 , https://hdl.handle.net/10520/EJC144727
- Description: Last year South African journalists reluctantly agreed to examine themselves under the public spotlight when the Human Rights Commission decided to hold hearings into racism in the media.
- Full Text:
- Date Issued: 2001
- Authors: Garman, Anthea , Baumann, Melissa
- Date: 2001
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158729 , vital:40223 , https://hdl.handle.net/10520/EJC144727
- Description: Last year South African journalists reluctantly agreed to examine themselves under the public spotlight when the Human Rights Commission decided to hold hearings into racism in the media.
- Full Text:
- Date Issued: 2001
Language policy, symbolic power and the democratic responsibility of the post-apartheid university
- Authors: Alexander, Neville
- Date: 2001
- Subjects: Academic Freedom -- South Africa Universities and colleges -- South Africa Equality Liberty Education and state -- South Africa Education, Higher -- South Africa
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/696 , vital:19982
- Description: Recent articles by John Higgins (1999) and André du Toit (2000), both of the University of Cape Town and a forthcoming article by Roger Southall and Julian Cobbing have contextualised the discussion of this perennial question in both time and place. Du Toit, in particular, has put the cat among the pigeons by querying the relevance in the era of globalisation and the corporatisation of institutions of higher learning, of the classic liberal interpretation of the T.B. Davie formula deriving from the 1950s, i.e., the freedom of "the university" to decide whom to teach, what to teach, how to teach and who should teach. The gist of his argument is that the danger no longer comes from outside the walls of the university, in the guise of the racist apartheid state, for instance. Instead, the threat comes from inside the institutions themselves as the result of the so-called managerial revolution, which is a manifestation of the shift of power from the collegium academicum to the administrative officials, since the curricular and pedagogical, i.e., academic, freedom of the lecturing and research staff is thereby put at risk. He maintains that the manner in which Higgins and others have addressed the question is anachronistic in that the political terrain and the institutional dynamics in which universities operate in post-apartheid South Africa are light years removed from the apartheid university. At the very least, one-quarter of the composite formula, that which refers to "whom to teach" has been rendered irrelevant, since there is no longer any barrier to access to tertiary education, besides those that operate in any "normal" capitalist democracy.
- Full Text:
- Date Issued: 2001
- Authors: Alexander, Neville
- Date: 2001
- Subjects: Academic Freedom -- South Africa Universities and colleges -- South Africa Equality Liberty Education and state -- South Africa Education, Higher -- South Africa
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/696 , vital:19982
- Description: Recent articles by John Higgins (1999) and André du Toit (2000), both of the University of Cape Town and a forthcoming article by Roger Southall and Julian Cobbing have contextualised the discussion of this perennial question in both time and place. Du Toit, in particular, has put the cat among the pigeons by querying the relevance in the era of globalisation and the corporatisation of institutions of higher learning, of the classic liberal interpretation of the T.B. Davie formula deriving from the 1950s, i.e., the freedom of "the university" to decide whom to teach, what to teach, how to teach and who should teach. The gist of his argument is that the danger no longer comes from outside the walls of the university, in the guise of the racist apartheid state, for instance. Instead, the threat comes from inside the institutions themselves as the result of the so-called managerial revolution, which is a manifestation of the shift of power from the collegium academicum to the administrative officials, since the curricular and pedagogical, i.e., academic, freedom of the lecturing and research staff is thereby put at risk. He maintains that the manner in which Higgins and others have addressed the question is anachronistic in that the political terrain and the institutional dynamics in which universities operate in post-apartheid South Africa are light years removed from the apartheid university. At the very least, one-quarter of the composite formula, that which refers to "whom to teach" has been rendered irrelevant, since there is no longer any barrier to access to tertiary education, besides those that operate in any "normal" capitalist democracy.
- Full Text:
- Date Issued: 2001
Recruiters Guidelines
- COSATU
- Authors: COSATU
- Date: 2001
- Subjects: COSATU
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/109753 , vital:33186
- Description: The purpose of this booklet is to touch in number of areas, which are important at this point for the recruitment campaign of the federation. It is not meant even by implication to provide details of how to handle the campaign what it does is to highlight issues and areas that we must think in the preparation for this campaign. More importantly is the fact that COSATU remains the biggest federation in South Africa and fastest growing international. Beside a loss of membership from + 2 million to + 1.8 million members. The decrease in membership is mostly because of retrenchments. The well known fact is that only about 40% of the workforce that is unionized. The aim of the recruitment drive is to access this 60% that is not unionized. The mistake must not be committed to think that the 40%, which is unionized, belong to COSATU. There are two other federations plus number of non-affiliated unions. Our commitment to One Country One Federation does not stop us to recruit from other unions as long as we remain under different bodies. This October campaign coincides with Red October campaign of the SACP and Health and Safety month of the federation this must be seen as strength than lack of co-ordination. One area that is link to recruitment is the servicing of membership. It is useless to recruit and fail to service membership because every campaign that we will take around recruitment we may find ourselves had to fight with disgruntled members and obviously it will be difficult to attract new members. This must say to us that members come first.
- Full Text:
- Date Issued: 2001
- Authors: COSATU
- Date: 2001
- Subjects: COSATU
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/109753 , vital:33186
- Description: The purpose of this booklet is to touch in number of areas, which are important at this point for the recruitment campaign of the federation. It is not meant even by implication to provide details of how to handle the campaign what it does is to highlight issues and areas that we must think in the preparation for this campaign. More importantly is the fact that COSATU remains the biggest federation in South Africa and fastest growing international. Beside a loss of membership from + 2 million to + 1.8 million members. The decrease in membership is mostly because of retrenchments. The well known fact is that only about 40% of the workforce that is unionized. The aim of the recruitment drive is to access this 60% that is not unionized. The mistake must not be committed to think that the 40%, which is unionized, belong to COSATU. There are two other federations plus number of non-affiliated unions. Our commitment to One Country One Federation does not stop us to recruit from other unions as long as we remain under different bodies. This October campaign coincides with Red October campaign of the SACP and Health and Safety month of the federation this must be seen as strength than lack of co-ordination. One area that is link to recruitment is the servicing of membership. It is useless to recruit and fail to service membership because every campaign that we will take around recruitment we may find ourselves had to fight with disgruntled members and obviously it will be difficult to attract new members. This must say to us that members come first.
- Full Text:
- Date Issued: 2001
The myth of authenticity : folktales and nationalism in the 'new South Africa'
- Authors: Naidu, Samantha
- Date: 2001
- Language: English
- Type: Article , text
- Identifier: vital:26378 , http://hdl.handle.net/10962/54047 , https://orcid.org/0000-0001-9456-8657
- Description: Folktales texts are published in glorious, polychromatic, innovative forms that promote the texts as both culturally educational and entertaining.
- Full Text: false
- Date Issued: 2001
- Authors: Naidu, Samantha
- Date: 2001
- Language: English
- Type: Article , text
- Identifier: vital:26378 , http://hdl.handle.net/10962/54047 , https://orcid.org/0000-0001-9456-8657
- Description: Folktales texts are published in glorious, polychromatic, innovative forms that promote the texts as both culturally educational and entertaining.
- Full Text: false
- Date Issued: 2001
Electrooxidation of cresols on carbon electrodes modified with phthalocyaninato and octabutoxyphthalocyaninato cobalt (II) complexes
- Grootboom, Natasha, Nyokong, Tebello
- Authors: Grootboom, Natasha , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293207 , vital:57065 , xlink:href="https://doi.org/10.1016/S0003-2670(00)01351-9"
- Description: Glassy carbon electrodes (GCE) modified with cobalt(II) phthalocyanine (CoPc-GCE) and cobalt(II) octabutoxyphthalocyanine (CoOBuPc-GCE) were employed for the electrochemical analysis of ortho-, meta-, and para-cresols. The oxidation potential of p-cresol was shifted towards less positive values to a larger extent, when compared to m- and o-cresols, on CoOBuPc-GCE. However, the GCE was less stable when modified with CoOBuPc than with CoPc. This is explained using the possible differences in the orientation of the adsorbed phthalocyanine molecules on the electrode. Bulk electrolysis of p-cresol at anodic potentials (1.0 V versus Ag|AgCl) on carbon electrodes modified with CoPc resulted in the formation of radicals which coupled to form trimeric products. On unmodified carbon electrodes, coupling of the radicals resulted in dimeric products following bulk electrolysis. The products formed following bulk electrolysis were characterized by liquid chromatography coupled with mass spectrometry.
- Full Text:
- Date Issued: 2001
- Authors: Grootboom, Natasha , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293207 , vital:57065 , xlink:href="https://doi.org/10.1016/S0003-2670(00)01351-9"
- Description: Glassy carbon electrodes (GCE) modified with cobalt(II) phthalocyanine (CoPc-GCE) and cobalt(II) octabutoxyphthalocyanine (CoOBuPc-GCE) were employed for the electrochemical analysis of ortho-, meta-, and para-cresols. The oxidation potential of p-cresol was shifted towards less positive values to a larger extent, when compared to m- and o-cresols, on CoOBuPc-GCE. However, the GCE was less stable when modified with CoOBuPc than with CoPc. This is explained using the possible differences in the orientation of the adsorbed phthalocyanine molecules on the electrode. Bulk electrolysis of p-cresol at anodic potentials (1.0 V versus Ag|AgCl) on carbon electrodes modified with CoPc resulted in the formation of radicals which coupled to form trimeric products. On unmodified carbon electrodes, coupling of the radicals resulted in dimeric products following bulk electrolysis. The products formed following bulk electrolysis were characterized by liquid chromatography coupled with mass spectrometry.
- Full Text:
- Date Issued: 2001
Simultaneous voltammetric determination of dopamine and serotonin on carbon paste electrodes modified with iron (II) phthalocyanine complexes
- Oni, Joshua, Nyokong, Tebello
- Authors: Oni, Joshua , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291603 , vital:56891 , xlink:href="https://doi.org/10.1016/S0003-2670(01)00822-4"
- Description: Carbon paste electrodes (CPE) containing iron(II) phthalocyanine (FePc) and iron(II) tetrasulfophthalocyanine ([FeTSPc]4−) were used for the detection of dopamine (DA) and serotonin (5-HT). Both complexes showed catalytic activity towards the detection of DA and 5-HT. The catalytic activities of [FeTSPc]4− and FePc are compared with those of [CoTSPc]4−, [NiTSPc] 4−, CoPc and NiPc complexes and with those of metal(II) tetraaminophthalocyanines (MTAPc, where M=Ni, Co or Fe) complexes. A significant improvement in the reversibility of the DA oxidation couple was observed on [FeTSPc]4− and FePc modified CPE. [FeTSPc]4− and other [MTSPc]4− modified electrodes inhibited the detection of ascorbic acid (AA), a major interferent in the detection of DA. Simultaneous detection of DA and 5-HT on [FeTSPc]4− modified CPE, in the presence of AA, showed that AA does not interfere with the determination of both species. Also no interference between DA and 5-HT was observed.
- Full Text:
- Date Issued: 2001
- Authors: Oni, Joshua , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291603 , vital:56891 , xlink:href="https://doi.org/10.1016/S0003-2670(01)00822-4"
- Description: Carbon paste electrodes (CPE) containing iron(II) phthalocyanine (FePc) and iron(II) tetrasulfophthalocyanine ([FeTSPc]4−) were used for the detection of dopamine (DA) and serotonin (5-HT). Both complexes showed catalytic activity towards the detection of DA and 5-HT. The catalytic activities of [FeTSPc]4− and FePc are compared with those of [CoTSPc]4−, [NiTSPc] 4−, CoPc and NiPc complexes and with those of metal(II) tetraaminophthalocyanines (MTAPc, where M=Ni, Co or Fe) complexes. A significant improvement in the reversibility of the DA oxidation couple was observed on [FeTSPc]4− and FePc modified CPE. [FeTSPc]4− and other [MTSPc]4− modified electrodes inhibited the detection of ascorbic acid (AA), a major interferent in the detection of DA. Simultaneous detection of DA and 5-HT on [FeTSPc]4− modified CPE, in the presence of AA, showed that AA does not interfere with the determination of both species. Also no interference between DA and 5-HT was observed.
- Full Text:
- Date Issued: 2001
Construction and characterization of carbon paste ultra-microelectrodes
- Oni, Joshua, Westbroek, Philippe, Nyokong, Tebello
- Authors: Oni, Joshua , Westbroek, Philippe , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291531 , vital:56884 , xlink:href="https://doi.org/10.1016/S1388-2481(01)00212-0"
- Description: The construction and characterization of carbon paste ultra-microelectrodes is reported. Besides a disc-shaped electrode, a carbon paste band electrode is studied. It was found that for both electrode configurations steady-state currents were obtained but that with the type of electrode material used for the band electrode, the upper limit of ultra-microelectrode dimensions, which could be used was 100–150 μm. Smaller dimensions for the band electrodes resulted in a high resistance due to the limited conductivity of the carbon paste, when using the optimal paste composition. With cyclic voltammetry, the oxidation of [Fe(CN)6]4− was studied at individual constructed electrodes and at ensembles of individual electrodes. Detection limits of less than 10−6moll−1 were obtained. Using the data of the same curves it was possible to test if the electrodes have errors and about 20% of the constructed electrodes did not pass this test. Finally it was found that these electrodes show good stability.
- Full Text:
- Date Issued: 2001
- Authors: Oni, Joshua , Westbroek, Philippe , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291531 , vital:56884 , xlink:href="https://doi.org/10.1016/S1388-2481(01)00212-0"
- Description: The construction and characterization of carbon paste ultra-microelectrodes is reported. Besides a disc-shaped electrode, a carbon paste band electrode is studied. It was found that for both electrode configurations steady-state currents were obtained but that with the type of electrode material used for the band electrode, the upper limit of ultra-microelectrode dimensions, which could be used was 100–150 μm. Smaller dimensions for the band electrodes resulted in a high resistance due to the limited conductivity of the carbon paste, when using the optimal paste composition. With cyclic voltammetry, the oxidation of [Fe(CN)6]4− was studied at individual constructed electrodes and at ensembles of individual electrodes. Detection limits of less than 10−6moll−1 were obtained. Using the data of the same curves it was possible to test if the electrodes have errors and about 20% of the constructed electrodes did not pass this test. Finally it was found that these electrodes show good stability.
- Full Text:
- Date Issued: 2001
Rhodes University Graduation Ceremony 2001
- Authors: Rhodes University
- Date: 2001
- Language: English
- Type: text
- Identifier: vital:8146 , http://hdl.handle.net/10962/d1007296
- Description: Rhodes University Graduation Ceremonies 1820 Settlers National Monument Friday, 6 April 2001 at 10:30; 18:00 [and] Saturday, 7 April 2001 at 10:30 , Graduation Ceremony Christian Centre, Wyse Street, East London Friday, 1 May 2001 at 18:00
- Full Text:
- Date Issued: 2001
- Authors: Rhodes University
- Date: 2001
- Language: English
- Type: text
- Identifier: vital:8146 , http://hdl.handle.net/10962/d1007296
- Description: Rhodes University Graduation Ceremonies 1820 Settlers National Monument Friday, 6 April 2001 at 10:30; 18:00 [and] Saturday, 7 April 2001 at 10:30 , Graduation Ceremony Christian Centre, Wyse Street, East London Friday, 1 May 2001 at 18:00
- Full Text:
- Date Issued: 2001
A dinocephalian therapsid fauna on the Ecca–Beaufort contact in Eastern Cape Province, South Africa
- Modesto, S P, Rubidge, B S, de Klerk, William J, Welman, J
- Authors: Modesto, S P , Rubidge, B S , de Klerk, William J , Welman, J
- Date: 2001
- Language: English
- Type: text , Article
- Identifier: vital:6999 , http://hdl.handle.net/10962/d1008355
- Description: Systematic exploration of outcrops of the lowermost Beaufort Group for fossils of the oldest terrestrial vertebrates of South Africa, known only from the Permian age Eodicynodon Assemblage Zone in Western Cape Province, has resulted in the discovery of a therapsid fauna in Eastern Cape Province that is dominated by advanced dinocephalians. The new discoveries include the skull and partial skeleton of a juvenile Anteosaurus, skull and skeletal elements of tapinocephalids, as well as the skull of a scylacosaurid therocephalian. The combined presence of advanced tapinocephalid dinocephalians, the anteosaur Anteosaurus, and scylacosaurid therocephalians suggests that the rocks of the lowermost Beaufort Group in the Eastern Cape Province can be assigned to the Tapinocephalus Assemblage Zone, rather than to the Eodicynodon Assemblage Zone, which appears to be restricted to the southwestern part of the Karoo Basin. This biozone identity permits the recognition of a younger age for the Ecca-Beaufort contact eastwards along the southern margin of the basin, thus demonstrating the diachronous nature of the Ecca-Beaufort contact in the southern Karoo.
- Full Text:
- Date Issued: 2001
- Authors: Modesto, S P , Rubidge, B S , de Klerk, William J , Welman, J
- Date: 2001
- Language: English
- Type: text , Article
- Identifier: vital:6999 , http://hdl.handle.net/10962/d1008355
- Description: Systematic exploration of outcrops of the lowermost Beaufort Group for fossils of the oldest terrestrial vertebrates of South Africa, known only from the Permian age Eodicynodon Assemblage Zone in Western Cape Province, has resulted in the discovery of a therapsid fauna in Eastern Cape Province that is dominated by advanced dinocephalians. The new discoveries include the skull and partial skeleton of a juvenile Anteosaurus, skull and skeletal elements of tapinocephalids, as well as the skull of a scylacosaurid therocephalian. The combined presence of advanced tapinocephalid dinocephalians, the anteosaur Anteosaurus, and scylacosaurid therocephalians suggests that the rocks of the lowermost Beaufort Group in the Eastern Cape Province can be assigned to the Tapinocephalus Assemblage Zone, rather than to the Eodicynodon Assemblage Zone, which appears to be restricted to the southwestern part of the Karoo Basin. This biozone identity permits the recognition of a younger age for the Ecca-Beaufort contact eastwards along the southern margin of the basin, thus demonstrating the diachronous nature of the Ecca-Beaufort contact in the southern Karoo.
- Full Text:
- Date Issued: 2001
Synthesis, spectroscopy and electrochemistry of octaphenoxyphthalocyaninato silicon complexes
- Maree, M David, Nyokong, Tebello
- Authors: Maree, M David , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/304863 , vital:58497 , xlink:href="https://doi.org/10.1002/jpp.361"
- Description: A number of octaphenoxyphthalocyaninato silicon complexes containing a variety of axial ligands, represented by (OPh)8PcSi(X)2 (where X = chloro 3, hydroxy 4, (4-carboxybenzene) acetato 5, isonicatinato 6, propionato 7, nitrophenoxy 8 and dimethylaminoxy 9) have been synthesized using a convenient route starting with the 4,5-diphenoxy-1,2-dicyanobenzene. 1H NMR and UV/vis spectra, and the cyclic voltammetry of the complexes are reported. The complexes are obtained in high yield and are soluble in many organic solvents. Cyclic voltammetry revealed two reduction couples and one oxidation couple for these complexes. Analysis of the cyclic voltammograms showed that compounds 6 and 8 were easier to oxidize and more difficult to reduce than the rest. Also cyclic voltammetry data suggested that electron transfer was not governed only by diffusion.
- Full Text:
- Date Issued: 2001
- Authors: Maree, M David , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/304863 , vital:58497 , xlink:href="https://doi.org/10.1002/jpp.361"
- Description: A number of octaphenoxyphthalocyaninato silicon complexes containing a variety of axial ligands, represented by (OPh)8PcSi(X)2 (where X = chloro 3, hydroxy 4, (4-carboxybenzene) acetato 5, isonicatinato 6, propionato 7, nitrophenoxy 8 and dimethylaminoxy 9) have been synthesized using a convenient route starting with the 4,5-diphenoxy-1,2-dicyanobenzene. 1H NMR and UV/vis spectra, and the cyclic voltammetry of the complexes are reported. The complexes are obtained in high yield and are soluble in many organic solvents. Cyclic voltammetry revealed two reduction couples and one oxidation couple for these complexes. Analysis of the cyclic voltammograms showed that compounds 6 and 8 were easier to oxidize and more difficult to reduce than the rest. Also cyclic voltammetry data suggested that electron transfer was not governed only by diffusion.
- Full Text:
- Date Issued: 2001
Assessment of the monkfish Lophius vomerinus resource off Namibia
- Maartens, Lima, Booth, Anthony J
- Authors: Maartens, Lima , Booth, Anthony J
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123863 , vital:35509 , https://doi.10.2989/025776101784528926
- Description: Monkfish (Lophius vomerinus and L. vaillanti) constitute a commercially important resource off Namibia. During 1998, the Lophius resource was the fourth most important commercial resource in terms of landed mass (c. 17 000 tons) and the fifth most important commercial resource in terms of export value (U$19.8 million) of the Namibian fishing sector (Ministry of Fisheries and Marine Resources, Namibia, unpublished data). Historically, monkfish constituted an important bycatch in the trawl fishery directed at hake (Merluccius spp.), but due to increasing market demand since the early 1990s, a fishery directed at monkfish and sole (Austroglossus microlepis) has developed. The Namibian Ministry of Fisheries and Marine Resources has identified the need to develop a management plan to ensure the resource’s medium and longterm sustainability (Maartens et al. 1999). Long-term resource management plans include the identification of an assessment model to represent reality so that the implications of managing the resource in future under a range of assumptions about its present status and its future dynamics (Cochrane et al. 1998) can be examined. The aim of this study was, therefore, to assess the status of at least part of the monkfish resource using a length-based cohort assessment (Jones 1979, 1984, Sparre and Venema 1998) and an age structured production model (Punt 1994, Punt and Japp 1994, Booth and Punt 1998).
- Full Text:
- Date Issued: 2010
- Authors: Maartens, Lima , Booth, Anthony J
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123863 , vital:35509 , https://doi.10.2989/025776101784528926
- Description: Monkfish (Lophius vomerinus and L. vaillanti) constitute a commercially important resource off Namibia. During 1998, the Lophius resource was the fourth most important commercial resource in terms of landed mass (c. 17 000 tons) and the fifth most important commercial resource in terms of export value (U$19.8 million) of the Namibian fishing sector (Ministry of Fisheries and Marine Resources, Namibia, unpublished data). Historically, monkfish constituted an important bycatch in the trawl fishery directed at hake (Merluccius spp.), but due to increasing market demand since the early 1990s, a fishery directed at monkfish and sole (Austroglossus microlepis) has developed. The Namibian Ministry of Fisheries and Marine Resources has identified the need to develop a management plan to ensure the resource’s medium and longterm sustainability (Maartens et al. 1999). Long-term resource management plans include the identification of an assessment model to represent reality so that the implications of managing the resource in future under a range of assumptions about its present status and its future dynamics (Cochrane et al. 1998) can be examined. The aim of this study was, therefore, to assess the status of at least part of the monkfish resource using a length-based cohort assessment (Jones 1979, 1984, Sparre and Venema 1998) and an age structured production model (Punt 1994, Punt and Japp 1994, Booth and Punt 1998).
- Full Text:
- Date Issued: 2010
Spectroscopic studies of the interaction of cobalt (II) N, N', N ″, N‴-tetramethyltetra-3, 4-pyridinoporphyrazine with amino acids and nitrogen oxides
- Thamae, Mamothibe A, Nyokong, Tebello
- Authors: Thamae, Mamothibe A , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291617 , vital:56892 , xlink:href="https://doi.org/10.1002/jpp.551"
- Description: The interaction of histidine, cysteine, NO and nitrite with cobalt(II) N,N',N″,N‴-tetramethyltetra-3,4-tetrapyridinoporphyrazine ([CoIItmtppa]4+) is reported. Metal-based autoreduction of [CoIItmtppa]4+ occurs with the formation of the [CoItmtppa(-2)]3+ species in the presence of histidine and cysteine. Kinetic data for the auto reduction of [CoIItmtppa]4+ in the presence of these amino acids gave the rate constants kf = 2.1 × 101 and 2.8 dm3 mol-1 s-1, for cysteine and histidine, respectively. One molecule of NO or nitrite was found to coordinate to the [CoIItmtppa]4+ species. The equilibrium and rate constants for the coordination of the nitric oxide were K = 2.3 × 104dm3mol-1 and kf = 7.5 dm3mol-1s-1, respectively. The coordination of nitrite to [CoIItmtppa]4+ occurred with an equilibrium constant of K = 2.0 × 102dm3mol-1 and a rate constant of kf = 4.0 × 10-3dm3mol-1s-1. There was no evidence for the coordination of two molecules of nitrite to the [CoIItmtppa]4+ species.
- Full Text:
- Date Issued: 2001
- Authors: Thamae, Mamothibe A , Nyokong, Tebello
- Date: 2001
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/291617 , vital:56892 , xlink:href="https://doi.org/10.1002/jpp.551"
- Description: The interaction of histidine, cysteine, NO and nitrite with cobalt(II) N,N',N″,N‴-tetramethyltetra-3,4-tetrapyridinoporphyrazine ([CoIItmtppa]4+) is reported. Metal-based autoreduction of [CoIItmtppa]4+ occurs with the formation of the [CoItmtppa(-2)]3+ species in the presence of histidine and cysteine. Kinetic data for the auto reduction of [CoIItmtppa]4+ in the presence of these amino acids gave the rate constants kf = 2.1 × 101 and 2.8 dm3 mol-1 s-1, for cysteine and histidine, respectively. One molecule of NO or nitrite was found to coordinate to the [CoIItmtppa]4+ species. The equilibrium and rate constants for the coordination of the nitric oxide were K = 2.3 × 104dm3mol-1 and kf = 7.5 dm3mol-1s-1, respectively. The coordination of nitrite to [CoIItmtppa]4+ occurred with an equilibrium constant of K = 2.0 × 102dm3mol-1 and a rate constant of kf = 4.0 × 10-3dm3mol-1s-1. There was no evidence for the coordination of two molecules of nitrite to the [CoIItmtppa]4+ species.
- Full Text:
- Date Issued: 2001