Investigating relationships between mathematics teachers' content knowledge, their pedagogical knowledge and their learnes' achievement in terms of functions and graphs
- Authors: Stewart, Joyce
- Date: 2009
- Subjects: Mathematics -- Study and teaching -- South Africa , Mathematics teachers -- Training of -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:9515 , http://hdl.handle.net/10948/1100 , Mathematics -- Study and teaching -- South Africa , Mathematics teachers -- Training of -- South Africa
- Description: This study used diagnostic tests, questionnaires and interviews to investigate explore teachers’ subject content knowledge (SCK) and pedagogical subject knowledge (PCK). It also explored teachers’ and learners’ misconceptions within the topic of graphicacy and how teachers’ SCK and PCK possibly affect learner achievement. A small sample of teachers were drawn from the Keiskammahoek region; a deep rural area of the Eastern Cape. These teachers were part of the Nelson Mandela Metropolitan University (NMMU) Amathole Cluster Schools Project who were registered for a three-year BEd (FET) in-service programme in mathematics education. As part of the programme they studied mathematics 1 and 2 at university level and received quarterly non-formal workshops on teaching mathematics at FET level. The findings of this study suggest that teachers with insufficient SCK will probably have limited PCK, although the two are not entirely dependent on each other. In cases where teachers’ displayed low levels of SCK and PCK, their learners were more likely to perform poorly and their results often indicated similar misconceptions as displayed by their teachers. This implies that we have to look at what teachers know and what they need to know in terms of SCK and PCK if we are to plan effectively for effective teacher development aimed at improving learner performance.
- Full Text:
- Date Issued: 2009
- Authors: Stewart, Joyce
- Date: 2009
- Subjects: Mathematics -- Study and teaching -- South Africa , Mathematics teachers -- Training of -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:9515 , http://hdl.handle.net/10948/1100 , Mathematics -- Study and teaching -- South Africa , Mathematics teachers -- Training of -- South Africa
- Description: This study used diagnostic tests, questionnaires and interviews to investigate explore teachers’ subject content knowledge (SCK) and pedagogical subject knowledge (PCK). It also explored teachers’ and learners’ misconceptions within the topic of graphicacy and how teachers’ SCK and PCK possibly affect learner achievement. A small sample of teachers were drawn from the Keiskammahoek region; a deep rural area of the Eastern Cape. These teachers were part of the Nelson Mandela Metropolitan University (NMMU) Amathole Cluster Schools Project who were registered for a three-year BEd (FET) in-service programme in mathematics education. As part of the programme they studied mathematics 1 and 2 at university level and received quarterly non-formal workshops on teaching mathematics at FET level. The findings of this study suggest that teachers with insufficient SCK will probably have limited PCK, although the two are not entirely dependent on each other. In cases where teachers’ displayed low levels of SCK and PCK, their learners were more likely to perform poorly and their results often indicated similar misconceptions as displayed by their teachers. This implies that we have to look at what teachers know and what they need to know in terms of SCK and PCK if we are to plan effectively for effective teacher development aimed at improving learner performance.
- Full Text:
- Date Issued: 2009
The phenomenolgoical experience of posttraumatic growth in the context of a traumatic bereavement
- Authors: Acheson, Kerry
- Date: 2009 , 2013-07-15
- Subjects: Post-traumatic stress disorder -- Case studies Bereavement -- Psychological aspects Death -- Psychological aspects Phenomenological psychology Grief
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3102 , http://hdl.handle.net/10962/d1004456
- Description: The present study involves an exploration of the phenomenological expenence of posttraumatic growth in the context of a traumatic bereavement. An idiographic case study of a student who had witnessed her mother's death twelve years previously was conducted. Semi-structured interviews elicited data which was analysed using interpretative phenomenological analysis (IP A). Posttraumatic growth was found to have developed with regards to self-perception, relationships, and also in a broader spiritual and existential domain. The findings of this study shed light on the extant posttraumatic growth literature. In particular, findings were discussed in relation to the posttraumatic growth model as proposed by Calhoun and Tedeschi (2006). As posttraumatic growth is a relatively young concept, further research is needed in order to understand the meaning of reported growth more fully. While posttraumatic growth has been investigated in the context of bereavement, future research should distinguish more clearly between growth following traumatic and non-traumatic bereavement. Posttraumatic growth has received minimal empirical attention in South Africa, and therefore exploration of this area is suggested in the future. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2009
- Authors: Acheson, Kerry
- Date: 2009 , 2013-07-15
- Subjects: Post-traumatic stress disorder -- Case studies Bereavement -- Psychological aspects Death -- Psychological aspects Phenomenological psychology Grief
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3102 , http://hdl.handle.net/10962/d1004456
- Description: The present study involves an exploration of the phenomenological expenence of posttraumatic growth in the context of a traumatic bereavement. An idiographic case study of a student who had witnessed her mother's death twelve years previously was conducted. Semi-structured interviews elicited data which was analysed using interpretative phenomenological analysis (IP A). Posttraumatic growth was found to have developed with regards to self-perception, relationships, and also in a broader spiritual and existential domain. The findings of this study shed light on the extant posttraumatic growth literature. In particular, findings were discussed in relation to the posttraumatic growth model as proposed by Calhoun and Tedeschi (2006). As posttraumatic growth is a relatively young concept, further research is needed in order to understand the meaning of reported growth more fully. While posttraumatic growth has been investigated in the context of bereavement, future research should distinguish more clearly between growth following traumatic and non-traumatic bereavement. Posttraumatic growth has received minimal empirical attention in South Africa, and therefore exploration of this area is suggested in the future. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2009
Molecular and biochemical analysis of the diet of the black rhinoceros
- Authors: Kgopa, Ananias Hodi
- Date: 2009 , 2013-07-15
- Subjects: Black rhinoceros -- South Africa -- Eastern Cape , Browse (Animal food) -- South Africa -- Eastern Cape -- Analysis , Black rhinoceros -- Manure -- Analysis , Phenols , Antioxidants , Plant ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4064 , http://hdl.handle.net/10962/d1004721 , Black rhinoceros -- South Africa -- Eastern Cape , Browse (Animal food) -- South Africa -- Eastern Cape -- Analysis , Black rhinoceros -- Manure -- Analysis , Phenols , Antioxidants , Plant ecology -- South Africa -- Eastern Cape
- Description: The black rhinoceros, Diceros bicornis, is listed as critically endangered. The black rhinoceros population in the Great Fish River Reserve (GFRR) has increased steadily to a current estimate of one hundred animals since the re-introduction of four animals in 1986. In an effort to contribute to the effective conservation and management of this species, dietary composition was studied in the medium Portulcaria thicket vegetation of the GFRR. This study used a molecular approach to determine the diet of the black rhinoceros of the GFRR by sequencing the ribulose bisphosphate carboxylase large subunit (rbcL) gene in plants and dung. Twenty-three plant species were collected from the reserve, and 802 bp of the rbcL gene were sequenced. These plant sequences were used as a reference database for the identification of plant sequences generated from black rhinoceros dung. Initial studies investigated the amplification, cloning and sequencing of DNA extracted from the dung samples which indicated the viability of the molecular approach. Thereafter, dung generated rbcL DNA was analyzed by GS FLX sequencing. Of the plant sequences identified by comparison to the GenBank database, Carissa bispinosa was the most prevalent. The study further characterized the antioxidant activities and phenolic content of plants eaten by the black rhinoceros using four different assays. Phyllanthus verrucosus, Putterlickia pyracantha, Maytenus capitata, Euclea undulata and Ozoroa mucrunata consistently had high antioxidant activities when assayed against 2,2-azinobis (3-ethyl benzothiazolium-6-sulfonic acid) (ABTSʹ⁺), 2,2-diphenyl-1-picrylhydrazyl (DPPHʹ), and ferric reducing antioxidant potentials (FRAP) and phenolic content when evaluated using the Folin-Ciocalteu assay. The majority of plants investigated showed low antioxidant potentials and low phenolic content. The extent to which antioxidants influenced the browse selection by the black rhinoceros remains inconclusive.
- Full Text:
- Date Issued: 2009
- Authors: Kgopa, Ananias Hodi
- Date: 2009 , 2013-07-15
- Subjects: Black rhinoceros -- South Africa -- Eastern Cape , Browse (Animal food) -- South Africa -- Eastern Cape -- Analysis , Black rhinoceros -- Manure -- Analysis , Phenols , Antioxidants , Plant ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4064 , http://hdl.handle.net/10962/d1004721 , Black rhinoceros -- South Africa -- Eastern Cape , Browse (Animal food) -- South Africa -- Eastern Cape -- Analysis , Black rhinoceros -- Manure -- Analysis , Phenols , Antioxidants , Plant ecology -- South Africa -- Eastern Cape
- Description: The black rhinoceros, Diceros bicornis, is listed as critically endangered. The black rhinoceros population in the Great Fish River Reserve (GFRR) has increased steadily to a current estimate of one hundred animals since the re-introduction of four animals in 1986. In an effort to contribute to the effective conservation and management of this species, dietary composition was studied in the medium Portulcaria thicket vegetation of the GFRR. This study used a molecular approach to determine the diet of the black rhinoceros of the GFRR by sequencing the ribulose bisphosphate carboxylase large subunit (rbcL) gene in plants and dung. Twenty-three plant species were collected from the reserve, and 802 bp of the rbcL gene were sequenced. These plant sequences were used as a reference database for the identification of plant sequences generated from black rhinoceros dung. Initial studies investigated the amplification, cloning and sequencing of DNA extracted from the dung samples which indicated the viability of the molecular approach. Thereafter, dung generated rbcL DNA was analyzed by GS FLX sequencing. Of the plant sequences identified by comparison to the GenBank database, Carissa bispinosa was the most prevalent. The study further characterized the antioxidant activities and phenolic content of plants eaten by the black rhinoceros using four different assays. Phyllanthus verrucosus, Putterlickia pyracantha, Maytenus capitata, Euclea undulata and Ozoroa mucrunata consistently had high antioxidant activities when assayed against 2,2-azinobis (3-ethyl benzothiazolium-6-sulfonic acid) (ABTSʹ⁺), 2,2-diphenyl-1-picrylhydrazyl (DPPHʹ), and ferric reducing antioxidant potentials (FRAP) and phenolic content when evaluated using the Folin-Ciocalteu assay. The majority of plants investigated showed low antioxidant potentials and low phenolic content. The extent to which antioxidants influenced the browse selection by the black rhinoceros remains inconclusive.
- Full Text:
- Date Issued: 2009
The impact of macroeconomic and financial factors on the performance of the housing property market in South Africa
- Authors: Kwangware, Debra
- Date: 2009
- Subjects: Microeconomics , Housing -- South Africa , Housing -- Prices -- South Africa , Real property -- South Africa , Interest rates -- South Africa , Foreign exchange rates -- South Africa
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1042 , http://hdl.handle.net/10962/d1005641 , Microeconomics , Housing -- South Africa , Housing -- Prices -- South Africa , Real property -- South Africa , Interest rates -- South Africa , Foreign exchange rates -- South Africa
- Description: This study exammes the impact of macroeconomic and financial variables on the performance of the housing property market in South Africa using monthly data for the period January 1996 to June 2008. Orthogonalised and non-orthogonalised house price returns and real estate returns are utilised as proxies for the housing property market in separate models. Three main issues were empirically analysed in relation to the linkage between selected variables and the housing property market. The first aspect examined the relationship between selected macroeconomic and financial factors and property returns. Secondly, the study examined the influence that a unit shock to each variable has on property returns over a period of time. The third aspect focused on determining the proportion of property returns variation that results from changes in the macroeconomic and financial variables. VAR modelling was thus adopted to empirically analyse these three aspects. The results reveal that house price returns are influenced by most of the macroeconomic and financial variables used in this study. Specifically, the real effective exchange rate, interest rate spread and manufacturing production positively impact on house price returns while the domestic interest rate, the dividend yield and expected inflation have a negative effect. Furthermore, manufacturing production has a lagged effect on house price returns while the real effective exchange rate and domestic interest rate have a contemporaneous effect. Real estate returns are not influenced by most of the variables except for the domestic interest rate and dividend yield which have a negative effect.
- Full Text:
- Date Issued: 2009
- Authors: Kwangware, Debra
- Date: 2009
- Subjects: Microeconomics , Housing -- South Africa , Housing -- Prices -- South Africa , Real property -- South Africa , Interest rates -- South Africa , Foreign exchange rates -- South Africa
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1042 , http://hdl.handle.net/10962/d1005641 , Microeconomics , Housing -- South Africa , Housing -- Prices -- South Africa , Real property -- South Africa , Interest rates -- South Africa , Foreign exchange rates -- South Africa
- Description: This study exammes the impact of macroeconomic and financial variables on the performance of the housing property market in South Africa using monthly data for the period January 1996 to June 2008. Orthogonalised and non-orthogonalised house price returns and real estate returns are utilised as proxies for the housing property market in separate models. Three main issues were empirically analysed in relation to the linkage between selected variables and the housing property market. The first aspect examined the relationship between selected macroeconomic and financial factors and property returns. Secondly, the study examined the influence that a unit shock to each variable has on property returns over a period of time. The third aspect focused on determining the proportion of property returns variation that results from changes in the macroeconomic and financial variables. VAR modelling was thus adopted to empirically analyse these three aspects. The results reveal that house price returns are influenced by most of the macroeconomic and financial variables used in this study. Specifically, the real effective exchange rate, interest rate spread and manufacturing production positively impact on house price returns while the domestic interest rate, the dividend yield and expected inflation have a negative effect. Furthermore, manufacturing production has a lagged effect on house price returns while the real effective exchange rate and domestic interest rate have a contemporaneous effect. Real estate returns are not influenced by most of the variables except for the domestic interest rate and dividend yield which have a negative effect.
- Full Text:
- Date Issued: 2009
Gains derived from illegal activities :an analysis of the taxation consequences
- Mtshawulana, Lungiswa Bukeka
- Authors: Mtshawulana, Lungiswa Bukeka
- Date: 2009
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:886 , http://hdl.handle.net/10962/d1001640
- Description: Income Tax in South Africa is levied in terms of the Income Tax Act 58 of 1962 on taxable income, which, by definition, is arrived at by deducting from "gross income" receipts and accruals that are exempt from tax as well as deductions and allowances provided for in the Act. The Income Tax Act provides no guidance with regard to the taxation of illegal activities, except to prohibit the deduction of expenditure incurred in paying fines or in relation to corrupt activities, as defined. An analysis of the taxation of income derived from theft, fraud and prostitution and the deductibility of expenses relating to that income, is the question addressed in this thesis. In this thesis, an analysis was made of relevant case law in relation to the provisions of the Income Tax Act in an attempt to provide clarity. A brief comparison was also macie of American, United Kingdom and South African tax law. Similarities were found between the American, United Kingdom and South African tax regimes in relation to the taxation of income, but there appeared to be more certainty in America and the United Kingdom in relation to the deduction of expenses. The thesis concludes that recent case decisions have provided certainty in relation to income from illegal activities, but the tax status of the deduction of expenses remains uncertain.
- Full Text:
- Date Issued: 2009
- Authors: Mtshawulana, Lungiswa Bukeka
- Date: 2009
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:886 , http://hdl.handle.net/10962/d1001640
- Description: Income Tax in South Africa is levied in terms of the Income Tax Act 58 of 1962 on taxable income, which, by definition, is arrived at by deducting from "gross income" receipts and accruals that are exempt from tax as well as deductions and allowances provided for in the Act. The Income Tax Act provides no guidance with regard to the taxation of illegal activities, except to prohibit the deduction of expenditure incurred in paying fines or in relation to corrupt activities, as defined. An analysis of the taxation of income derived from theft, fraud and prostitution and the deductibility of expenses relating to that income, is the question addressed in this thesis. In this thesis, an analysis was made of relevant case law in relation to the provisions of the Income Tax Act in an attempt to provide clarity. A brief comparison was also macie of American, United Kingdom and South African tax law. Similarities were found between the American, United Kingdom and South African tax regimes in relation to the taxation of income, but there appeared to be more certainty in America and the United Kingdom in relation to the deduction of expenses. The thesis concludes that recent case decisions have provided certainty in relation to income from illegal activities, but the tax status of the deduction of expenses remains uncertain.
- Full Text:
- Date Issued: 2009
Corruption and its effects on the development of the construction industry in Malawi
- Chiocha, Charles Injess Martin
- Authors: Chiocha, Charles Injess Martin
- Date: 2009
- Subjects: Contruction industry -- Corrupt practices -- Malawi
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:9692 , http://hdl.handle.net/10948/933 , Contruction industry -- Corrupt practices -- Malawi
- Description: The purpose of this study was to investigate corruption and its effects on the development of the construction industry in Malawi. The major causes were identified and probable solutions as well as preventive measures suggested for all stakeholders in the construction industry in Malawi and neighbouring countries to follow in order to combat bribery and corruption. This treatise consisted of a literature review for the causes of bribery, fraud and corruption, effects of corruption on the construction industry, preventive measures, probable solutions to corruption and a descriptive survey involving responses from building and civil engineering contractors, the built environment professionals, home owners, developers, public works officers amongst others from the construction industry in Malawi. According to the literature study, the construction industry is one of the most corrupt industries in the world, which is a huge concern and threat both to governments, investors and humanity at large. This must be addressed by all the official players in the construction industry, from the innovator of a project to the tradesmen employed on that site. The research showed that all players in the construction industry are aware of the impact of corruption on the development of the construction industry in Malawi. Furthermore, there is room for improvement as far as prevention, reduction and elimination of corruption is concerned.
- Full Text:
- Date Issued: 2009
- Authors: Chiocha, Charles Injess Martin
- Date: 2009
- Subjects: Contruction industry -- Corrupt practices -- Malawi
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:9692 , http://hdl.handle.net/10948/933 , Contruction industry -- Corrupt practices -- Malawi
- Description: The purpose of this study was to investigate corruption and its effects on the development of the construction industry in Malawi. The major causes were identified and probable solutions as well as preventive measures suggested for all stakeholders in the construction industry in Malawi and neighbouring countries to follow in order to combat bribery and corruption. This treatise consisted of a literature review for the causes of bribery, fraud and corruption, effects of corruption on the construction industry, preventive measures, probable solutions to corruption and a descriptive survey involving responses from building and civil engineering contractors, the built environment professionals, home owners, developers, public works officers amongst others from the construction industry in Malawi. According to the literature study, the construction industry is one of the most corrupt industries in the world, which is a huge concern and threat both to governments, investors and humanity at large. This must be addressed by all the official players in the construction industry, from the innovator of a project to the tradesmen employed on that site. The research showed that all players in the construction industry are aware of the impact of corruption on the development of the construction industry in Malawi. Furthermore, there is room for improvement as far as prevention, reduction and elimination of corruption is concerned.
- Full Text:
- Date Issued: 2009
A knowledge-oriented, context-sensitive architectural framework for service deployment in marginalized rural communities
- Authors: Thinyane, Mamello P
- Date: 2009
- Subjects: Information technology Expert systems (Computer science) Software architecture User interfaces (Computer systems) Ethnoscience Social networks Rural development Technical assistance -- Developing countries Information networks -- Developing countries
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4599 , http://hdl.handle.net/10962/d1004843
- Description: The notion of a global knowledge society is somewhat of a misnomer due to the fact that large portions of the global community are not participants in this global knowledge society which is driven, shaped by and socio-technically biased towards a small fraction of the global population. Information and Communication Technology (ICT) is culture-sensitive and this is a dynamic that is largely ignored in the majority of ICT for Development (ICT4D) interventions, leading to the technological determinism flaw and ultimately a failure of the undertaken projects. The deployment of ICT solutions, in particular in the context of ICT4D, must be informed by the cultural and socio-technical profile of the deployment environments and solutions themselves must be developed with a focus towards context-sensitivity and ethnocentricity. In this thesis, we investigate the viability of a software architectural framework for the development of ICT solutions that are context-sensitive and ethnocentric1, and so aligned with the cultural and social dynamics within the environment of deployment. The conceptual framework, named PIASK, defines five tiers (presentation, interaction, access, social networking, and knowledge base) which allow for: behavioural completeness of the layer components; a modular and functionally decoupled architecture; and the flexibility to situate and contextualize the developed applications along the dimensions of the User Interface (UI), interaction modalities, usage metaphors, underlying Indigenous Knowledge (IK), and access protocols. We have developed a proof-of-concept service platform, called KnowNet, based on the PIASK architecture. KnowNet is built around the knowledge base layer, which consists of domain ontologies that encapsulate the knowledge in the platform, with an intrinsic flexibility to access secondary knowledge repositories. The domain ontologies constructed (as examples) are for the provisioning of eServices to support societal activities (e.g. commerce, health, agriculture, medicine) within a rural and marginalized area of Dwesa, in the Eastern Cape province of South Africa. The social networking layer allows for situating the platform within the local social systems. Heterogeneity of user profiles and multiplicity of end-user devices are handled through the access and the presentation components, and the service logic is implemented by the interaction components. This services platform validates the PIASK architecture for end-to-end provisioning of multi-modal, heterogeneous, ontology-based services. The development of KnowNet was informed on one hand by the latest trends within service architectures, semantic web technologies and social applications, and on the other hand by the context consideration based on the profile (IK systems dynamics, infrastructure, usability requirements) of the Dwesa community. The realization of the service platform is based on the JADE Multi-Agent System (MAS), and this shows the applicability and adequacy of MAS’s for service deployment in a rural context, at the same time providing key advantages such as platform fault-tolerance, robustness and flexibility. While the context of conceptualization of PIASK and the implementation of KnowNet is that of rurality and of ICT4D, the applicability of the architecture extends to other similarly heterogeneous and context-sensitive domains. KnowNet has been validated for functional and technical adequacy, and we have also undertaken an initial prevalidation for social context sensitivity. We observe that the five tier PIASK architecture provides an adequate framework for developing context-sensitive and ethnocentric software: by functionally separating and making explicit the social networking and access tier components, while still maintaining the traditional separation of presentation, business logic and data components.
- Full Text:
- Date Issued: 2009
- Authors: Thinyane, Mamello P
- Date: 2009
- Subjects: Information technology Expert systems (Computer science) Software architecture User interfaces (Computer systems) Ethnoscience Social networks Rural development Technical assistance -- Developing countries Information networks -- Developing countries
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4599 , http://hdl.handle.net/10962/d1004843
- Description: The notion of a global knowledge society is somewhat of a misnomer due to the fact that large portions of the global community are not participants in this global knowledge society which is driven, shaped by and socio-technically biased towards a small fraction of the global population. Information and Communication Technology (ICT) is culture-sensitive and this is a dynamic that is largely ignored in the majority of ICT for Development (ICT4D) interventions, leading to the technological determinism flaw and ultimately a failure of the undertaken projects. The deployment of ICT solutions, in particular in the context of ICT4D, must be informed by the cultural and socio-technical profile of the deployment environments and solutions themselves must be developed with a focus towards context-sensitivity and ethnocentricity. In this thesis, we investigate the viability of a software architectural framework for the development of ICT solutions that are context-sensitive and ethnocentric1, and so aligned with the cultural and social dynamics within the environment of deployment. The conceptual framework, named PIASK, defines five tiers (presentation, interaction, access, social networking, and knowledge base) which allow for: behavioural completeness of the layer components; a modular and functionally decoupled architecture; and the flexibility to situate and contextualize the developed applications along the dimensions of the User Interface (UI), interaction modalities, usage metaphors, underlying Indigenous Knowledge (IK), and access protocols. We have developed a proof-of-concept service platform, called KnowNet, based on the PIASK architecture. KnowNet is built around the knowledge base layer, which consists of domain ontologies that encapsulate the knowledge in the platform, with an intrinsic flexibility to access secondary knowledge repositories. The domain ontologies constructed (as examples) are for the provisioning of eServices to support societal activities (e.g. commerce, health, agriculture, medicine) within a rural and marginalized area of Dwesa, in the Eastern Cape province of South Africa. The social networking layer allows for situating the platform within the local social systems. Heterogeneity of user profiles and multiplicity of end-user devices are handled through the access and the presentation components, and the service logic is implemented by the interaction components. This services platform validates the PIASK architecture for end-to-end provisioning of multi-modal, heterogeneous, ontology-based services. The development of KnowNet was informed on one hand by the latest trends within service architectures, semantic web technologies and social applications, and on the other hand by the context consideration based on the profile (IK systems dynamics, infrastructure, usability requirements) of the Dwesa community. The realization of the service platform is based on the JADE Multi-Agent System (MAS), and this shows the applicability and adequacy of MAS’s for service deployment in a rural context, at the same time providing key advantages such as platform fault-tolerance, robustness and flexibility. While the context of conceptualization of PIASK and the implementation of KnowNet is that of rurality and of ICT4D, the applicability of the architecture extends to other similarly heterogeneous and context-sensitive domains. KnowNet has been validated for functional and technical adequacy, and we have also undertaken an initial prevalidation for social context sensitivity. We observe that the five tier PIASK architecture provides an adequate framework for developing context-sensitive and ethnocentric software: by functionally separating and making explicit the social networking and access tier components, while still maintaining the traditional separation of presentation, business logic and data components.
- Full Text:
- Date Issued: 2009
The choice of idols from a social psychological perspective
- Authors: Lupke, Lynette M
- Date: 2009
- Subjects: Identity (Psychology) , Idols and images , Social interaction
- Language: English
- Type: Thesis , Masters , M Soc Sc (Psych)
- Identifier: vital:11606 , http://hdl.handle.net/10353/132 , Identity (Psychology) , Idols and images , Social interaction
- Description: The study of adolescents’ idols has an over 100-year tradition. The meta-analysis of Teigen, Normann, Bjorkheim and Helland (2000) showed that idols, which are commonly understood as role models, changed over the last century which is attributed to changes in the social context. The present paper argues that Social Identity Theory (Tajfel & Turner, 1979, 1986) offers an appropriate theoretical framework to conceptualize social context by hypothesising a functional relationship between idols and identity management strategies moderated by the status position of the adolescent’s group s/he belongs to. The hypothesised functional relationship was tested in two studies with white and black adolescent South Africans. The results of the two studies supported our assumptions that the functional relationship between idols and identity management strategies is indeed moderated by status position. The results also indicate that Social Identity Theory seems to be an appropriate theoretical framework when social context is particularly conceptualised as social change.
- Full Text:
- Date Issued: 2009
- Authors: Lupke, Lynette M
- Date: 2009
- Subjects: Identity (Psychology) , Idols and images , Social interaction
- Language: English
- Type: Thesis , Masters , M Soc Sc (Psych)
- Identifier: vital:11606 , http://hdl.handle.net/10353/132 , Identity (Psychology) , Idols and images , Social interaction
- Description: The study of adolescents’ idols has an over 100-year tradition. The meta-analysis of Teigen, Normann, Bjorkheim and Helland (2000) showed that idols, which are commonly understood as role models, changed over the last century which is attributed to changes in the social context. The present paper argues that Social Identity Theory (Tajfel & Turner, 1979, 1986) offers an appropriate theoretical framework to conceptualize social context by hypothesising a functional relationship between idols and identity management strategies moderated by the status position of the adolescent’s group s/he belongs to. The hypothesised functional relationship was tested in two studies with white and black adolescent South Africans. The results of the two studies supported our assumptions that the functional relationship between idols and identity management strategies is indeed moderated by status position. The results also indicate that Social Identity Theory seems to be an appropriate theoretical framework when social context is particularly conceptualised as social change.
- Full Text:
- Date Issued: 2009
Relative deprivation and relative gratification as predictors of intergroup discrimination: can prejudice be reduced by equality?
- Authors: Neuwenhuis, Bridgitte
- Date: 2009
- Subjects: Collective behavior , Social perception , Intergroup relations , Deprivation (Psychology)
- Language: English
- Type: Thesis , Masters , M Soc Sc (Psych)
- Identifier: vital:11608 , http://hdl.handle.net/10353/147 , Collective behavior , Social perception , Intergroup relations , Deprivation (Psychology)
- Description: It has long been identified that relative deprivation increases prejudice. Guimond and Dambrun (2002) demonstrated that relative gratification, as the opposite of relative deprivation, is also an important variable in predicting intergroup discrimination. Guimond and Dambrun (2002), further suggest that in order to prevent destructive conflicts between groups, such as intergroup discrimination, the goal of equality rather than economic improvements has to be kept in mind. The present paper will report three experiments which aimed to replicate Guimond and Dambrun’s (2002) findings on relative deprivation and relative gratification and which further aimed to test their proposal that equality would reduce prejudice. The results of the three experiments confirmed the predicted effects of relative deprivation and relative gratification on intergroup discrimination. However, the results did not confirm that equality reduces prejudice. Methodological and theoretical reasons for these results are provided and discussed in detail.
- Full Text:
- Date Issued: 2009
- Authors: Neuwenhuis, Bridgitte
- Date: 2009
- Subjects: Collective behavior , Social perception , Intergroup relations , Deprivation (Psychology)
- Language: English
- Type: Thesis , Masters , M Soc Sc (Psych)
- Identifier: vital:11608 , http://hdl.handle.net/10353/147 , Collective behavior , Social perception , Intergroup relations , Deprivation (Psychology)
- Description: It has long been identified that relative deprivation increases prejudice. Guimond and Dambrun (2002) demonstrated that relative gratification, as the opposite of relative deprivation, is also an important variable in predicting intergroup discrimination. Guimond and Dambrun (2002), further suggest that in order to prevent destructive conflicts between groups, such as intergroup discrimination, the goal of equality rather than economic improvements has to be kept in mind. The present paper will report three experiments which aimed to replicate Guimond and Dambrun’s (2002) findings on relative deprivation and relative gratification and which further aimed to test their proposal that equality would reduce prejudice. The results of the three experiments confirmed the predicted effects of relative deprivation and relative gratification on intergroup discrimination. However, the results did not confirm that equality reduces prejudice. Methodological and theoretical reasons for these results are provided and discussed in detail.
- Full Text:
- Date Issued: 2009
Restoration of degraded subtropical thickets in the Baviaanskloof Megareserve, South Africa: the role of carbon stocks and Portulacaria afra survivorship
- Authors: Powell, Michael John
- Date: 2009
- Subjects: Portulacaria afra -- South Africa -- Eastern Cape , Portulacaceae -- South Africa -- Eastern Cape , Biodiversity conservation -- South Africa -- Eastern Cape , Plant conservation -- South Africa -- Eastern Cape , Shrubs -- South Africa -- Eastern Cape , Succulent plants -- South Africa -- Eastern Cape , Baviaanskloof (South Africa)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4764 , http://hdl.handle.net/10962/d1007164 , Portulacaria afra -- South Africa -- Eastern Cape , Portulacaceae -- South Africa -- Eastern Cape , Biodiversity conservation -- South Africa -- Eastern Cape , Plant conservation -- South Africa -- Eastern Cape , Shrubs -- South Africa -- Eastern Cape , Succulent plants -- South Africa -- Eastern Cape , Baviaanskloof (South Africa)
- Description: The semi-arid forms of subtropical thicket in the Eastern and Western Cape have been heavily degraded through unsustainable pastoralism over the last century or more. The degraded areas exhibit a significant loss of above-ground and belowground carbon stocks, and consequently provide an opportunity for restoration through the formal and informal carbon markets. A prerequisite for the attainment of carbon credits is to ensure sound carbon stock baselines prior to effecting restoration. I report on the carbon stocks (including sub-pools) for a number of intact subtropical thicket types, as well as the differentials between the intact and degraded states (including the sub-pools). Total carbon stocks (TCS in t C ha⁻¹) for intact vegetation (to a soil depth 0–25 cm), ranged from 87.73±6.51 to 70.64±17.24. For degraded vegetation (including old lands), TCS (t C ha⁻¹) ranged from 34.05±3.61 to 21.03±2.70. For all vegetation types, the differentials in TCS along the degradation gradient (0–25 cm) are highly significant and strengthen the possibility for carbon credit financing to catalyse the restoration of the degraded semi-arid subtropical thickets. This study has shown a mean loss of 57.23 t C ha⁻¹ in Baviaanskloof spekboom thickets, when measured to a soil depth of 25 cm. Portulacaria afra is a key species within the semi-arid subtropical thickets, being a canopy dominant and a driver of soil nutrient status, but has been largely lost from the degraded landscapes. Degraded semi-arid subtropical thicket vegetation lacks regeneration via seedling recruitment; restoration therefore requires the manual replanting of P. afra using cut truncheons. Survivorship trials were undertaken infield in 2005 to establish restoration protocols for P. afra, with survivorship being recorded in 2006 and 2008. Overall survivorship for all treatments was found to be 43.2±2.8% in 2006, dropping to 35.8±2.7% in 2008. Planting posture (flat or upright) showed the most significant results of all the factors tested in 2006 and 2008. Micro-damming also influenced survivorship in that micro-damming was associated with marginally higher survivorship (47.4 ±2.0% with damming vs. 39.1±1.5% without damming in 2006, and 39.3±1.9% vs. 32.3±1.5% in 2008). Higher planting density only showed a significant positive impact on survivorship in 2008. Neither stem diameter nor clumping significantly affected degree of survival. A key finding in the study has been the non-static nature of P. afra truncheon survivorship, even after being well established (three years since planting). The results from the study will guide the restoration protocols for the restoration of degraded subtropical thickets, where P. afra requires replanting.
- Full Text:
- Date Issued: 2009
- Authors: Powell, Michael John
- Date: 2009
- Subjects: Portulacaria afra -- South Africa -- Eastern Cape , Portulacaceae -- South Africa -- Eastern Cape , Biodiversity conservation -- South Africa -- Eastern Cape , Plant conservation -- South Africa -- Eastern Cape , Shrubs -- South Africa -- Eastern Cape , Succulent plants -- South Africa -- Eastern Cape , Baviaanskloof (South Africa)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4764 , http://hdl.handle.net/10962/d1007164 , Portulacaria afra -- South Africa -- Eastern Cape , Portulacaceae -- South Africa -- Eastern Cape , Biodiversity conservation -- South Africa -- Eastern Cape , Plant conservation -- South Africa -- Eastern Cape , Shrubs -- South Africa -- Eastern Cape , Succulent plants -- South Africa -- Eastern Cape , Baviaanskloof (South Africa)
- Description: The semi-arid forms of subtropical thicket in the Eastern and Western Cape have been heavily degraded through unsustainable pastoralism over the last century or more. The degraded areas exhibit a significant loss of above-ground and belowground carbon stocks, and consequently provide an opportunity for restoration through the formal and informal carbon markets. A prerequisite for the attainment of carbon credits is to ensure sound carbon stock baselines prior to effecting restoration. I report on the carbon stocks (including sub-pools) for a number of intact subtropical thicket types, as well as the differentials between the intact and degraded states (including the sub-pools). Total carbon stocks (TCS in t C ha⁻¹) for intact vegetation (to a soil depth 0–25 cm), ranged from 87.73±6.51 to 70.64±17.24. For degraded vegetation (including old lands), TCS (t C ha⁻¹) ranged from 34.05±3.61 to 21.03±2.70. For all vegetation types, the differentials in TCS along the degradation gradient (0–25 cm) are highly significant and strengthen the possibility for carbon credit financing to catalyse the restoration of the degraded semi-arid subtropical thickets. This study has shown a mean loss of 57.23 t C ha⁻¹ in Baviaanskloof spekboom thickets, when measured to a soil depth of 25 cm. Portulacaria afra is a key species within the semi-arid subtropical thickets, being a canopy dominant and a driver of soil nutrient status, but has been largely lost from the degraded landscapes. Degraded semi-arid subtropical thicket vegetation lacks regeneration via seedling recruitment; restoration therefore requires the manual replanting of P. afra using cut truncheons. Survivorship trials were undertaken infield in 2005 to establish restoration protocols for P. afra, with survivorship being recorded in 2006 and 2008. Overall survivorship for all treatments was found to be 43.2±2.8% in 2006, dropping to 35.8±2.7% in 2008. Planting posture (flat or upright) showed the most significant results of all the factors tested in 2006 and 2008. Micro-damming also influenced survivorship in that micro-damming was associated with marginally higher survivorship (47.4 ±2.0% with damming vs. 39.1±1.5% without damming in 2006, and 39.3±1.9% vs. 32.3±1.5% in 2008). Higher planting density only showed a significant positive impact on survivorship in 2008. Neither stem diameter nor clumping significantly affected degree of survival. A key finding in the study has been the non-static nature of P. afra truncheon survivorship, even after being well established (three years since planting). The results from the study will guide the restoration protocols for the restoration of degraded subtropical thickets, where P. afra requires replanting.
- Full Text:
- Date Issued: 2009
Legal access to our musical history: an investigation into the copyright implications of archived musical recordings held at the International Library of African Music (ILAM) in South Africa
- Authors: McConnachie, Boudina
- Date: 2009
- Subjects: Tracey, Hugh International Library of African Music South Africa. Copyright Act 1978 Copyright -- Music -- South Africa Music -- History and criticism
- Language: English
- Type: Thesis , Masters , MMus
- Identifier: vital:2648 , http://hdl.handle.net/10962/d1002313
- Description: This thesis explores the South African Copyright Act No. 98 of 1978 as it pertains to the archived holdings at the International Library of African Music (ILAM) situated at Rhodes University, Grahamstown, South Africa. The purpose of analysing this law is to advise and assist ILAM in fulfilling royalty payment obligations as stipulated in a contract signed between ILAM and the Smithsonian Global Sound (formally Global Sound Network) in 2001. In order to clearly comprehend the scope of the royalty payment clause in the Smithsonian Institution’s contract with ILAM, this research includes an examination of: the history and nature of South African copyright as a sub-structure of intellectual property; specific internationally documented copyright infringement cases; the recording and documentation practices of Hugh Tracey (ILAM’s founder and director from 1954 to 1977); the contract between Global Sound Network and ILAM; and contentious issues surrounding collective ownership and indigenous knowledge. In conclusion, this research suggests equitable solutions to ILAM’s copyright concerns and proposes the Eastern Cape Music Archiving Project (ECMAP) as a practical vehicle to assist the South African Department of Trade and Industry in implementation of the South African Intellectual Property Amendment Bill (2008) if, and when, it is passed.
- Full Text:
- Date Issued: 2009
- Authors: McConnachie, Boudina
- Date: 2009
- Subjects: Tracey, Hugh International Library of African Music South Africa. Copyright Act 1978 Copyright -- Music -- South Africa Music -- History and criticism
- Language: English
- Type: Thesis , Masters , MMus
- Identifier: vital:2648 , http://hdl.handle.net/10962/d1002313
- Description: This thesis explores the South African Copyright Act No. 98 of 1978 as it pertains to the archived holdings at the International Library of African Music (ILAM) situated at Rhodes University, Grahamstown, South Africa. The purpose of analysing this law is to advise and assist ILAM in fulfilling royalty payment obligations as stipulated in a contract signed between ILAM and the Smithsonian Global Sound (formally Global Sound Network) in 2001. In order to clearly comprehend the scope of the royalty payment clause in the Smithsonian Institution’s contract with ILAM, this research includes an examination of: the history and nature of South African copyright as a sub-structure of intellectual property; specific internationally documented copyright infringement cases; the recording and documentation practices of Hugh Tracey (ILAM’s founder and director from 1954 to 1977); the contract between Global Sound Network and ILAM; and contentious issues surrounding collective ownership and indigenous knowledge. In conclusion, this research suggests equitable solutions to ILAM’s copyright concerns and proposes the Eastern Cape Music Archiving Project (ECMAP) as a practical vehicle to assist the South African Department of Trade and Industry in implementation of the South African Intellectual Property Amendment Bill (2008) if, and when, it is passed.
- Full Text:
- Date Issued: 2009
Pseudopolydora species associated with mollusc shells on the south coast of South Africa, with the description of Ps. dayii, sp nov
- Authors: Simon, Carol A
- Date: 2009
- Language: English
- Type: text , Article
- Identifier: vital:6875 , http://hdl.handle.net/10962/d1011623
- Description: Two species of the genus Pseudopolydora, Ps. dayii, sp. nov. and Ps. antennata, were associated with gastropods on the south and south-east coasts of South Africa. Pseudopolydora dayii is characterized by prominent post-chaetal notopodial lobes on chaetiger 1 with very long chaetae, a prominent occipital tentacle, having hooded hooks that start on chaetiger 9, branchiae that start on chaetiger 6, stout hooks and lobes placed latero-posteriorly to the hooded hooks in posterior chaetigers. It is a surface-fouler and was found on several species of wild gastropods at four of the five sites sampled and from additional material from the south-west coast and on cultured abalone (Haliotis midae) at a farm on the south-west coast. Three individuals of Ps. antennata were found only with oysters at the easternmost site. This was the first record of this species outside of the Western Cape Province and it is possible that their association with the oysters was fortuitous.
- Full Text:
- Date Issued: 2009
- Authors: Simon, Carol A
- Date: 2009
- Language: English
- Type: text , Article
- Identifier: vital:6875 , http://hdl.handle.net/10962/d1011623
- Description: Two species of the genus Pseudopolydora, Ps. dayii, sp. nov. and Ps. antennata, were associated with gastropods on the south and south-east coasts of South Africa. Pseudopolydora dayii is characterized by prominent post-chaetal notopodial lobes on chaetiger 1 with very long chaetae, a prominent occipital tentacle, having hooded hooks that start on chaetiger 9, branchiae that start on chaetiger 6, stout hooks and lobes placed latero-posteriorly to the hooded hooks in posterior chaetigers. It is a surface-fouler and was found on several species of wild gastropods at four of the five sites sampled and from additional material from the south-west coast and on cultured abalone (Haliotis midae) at a farm on the south-west coast. Three individuals of Ps. antennata were found only with oysters at the easternmost site. This was the first record of this species outside of the Western Cape Province and it is possible that their association with the oysters was fortuitous.
- Full Text:
- Date Issued: 2009
Environmental education policy support in Southern Africa: a case story of SADC REEP
- Gumede, Sibusisiwe Marie-Louise
- Authors: Gumede, Sibusisiwe Marie-Louise
- Date: 2009
- Subjects: SADC Regional Environmental Education Programme Environmental education -- Africa, Southern Education -- Africa, Southern Education and state -- Africa, Southern Teaching -- Aids and devices -- Africa, Southern
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1515 , http://hdl.handle.net/10962/d1003397
- Description: The study takes place in the context of the Southern African Development Community’s Regional Environmental Education Programme (SADC REEP). The SADC REEP is a programme of the Food Agriculture and Natural Resources Directorate of the SADC Secretariat. The programme is implemented through four components namely policy, networking, training and learning support materials development. The bulk of the policy budget is in the form of seed funding to support policy initiatives in the member states. The intention of this study is to illuminate factors that influence the deployment and use of seed funding to support environmental education policy processes within the SADC REEP. To sharpen the understanding of the context within which these activities take place, the study looks at the global and regional landscape of policy events and their influence on policy in the sub-region. The study also looks at the landscape of the fields within which environmental education is embedded, the power relations, and the notion of agency in environmental education policy processes. The discourse in environmental education policy processes is analyzed by drawing on Bourdieu’s constructivist structuralism to highlight some of the social and institutional complexities in dynamic fields, capital and policy context. The research takes a qualitative interpretative approach using case study methodology to explore the processes and influences that have a bearing on the SADC REEP policy sub-component, specifically the deployment and use of seed funding for policy initiatives. The findings show the complexity of the variables at play in shaping the processes of developing and reviewing environmental education policies in the sub-region. These variables include discourse that is used, economics and politics of the responsible institutions and actors, as well as relationships between the environmental field and education field. The results point towards a need to clearly understand the policy context within which the SADC REEP is operating in order to make correct assumptions, to develop realist expectations, and to put in place appropriate mechanisms that will effect the expectations. The study recommends further probing of the relationship between the actors and networks in relation to the success of policy processes. It also recommends a further exploration of the SADC REEP’s open-ended approach with respect to articulating the monitoring and consolidation of the successes in supporting environmental education policy processes.
- Full Text:
- Date Issued: 2009
- Authors: Gumede, Sibusisiwe Marie-Louise
- Date: 2009
- Subjects: SADC Regional Environmental Education Programme Environmental education -- Africa, Southern Education -- Africa, Southern Education and state -- Africa, Southern Teaching -- Aids and devices -- Africa, Southern
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1515 , http://hdl.handle.net/10962/d1003397
- Description: The study takes place in the context of the Southern African Development Community’s Regional Environmental Education Programme (SADC REEP). The SADC REEP is a programme of the Food Agriculture and Natural Resources Directorate of the SADC Secretariat. The programme is implemented through four components namely policy, networking, training and learning support materials development. The bulk of the policy budget is in the form of seed funding to support policy initiatives in the member states. The intention of this study is to illuminate factors that influence the deployment and use of seed funding to support environmental education policy processes within the SADC REEP. To sharpen the understanding of the context within which these activities take place, the study looks at the global and regional landscape of policy events and their influence on policy in the sub-region. The study also looks at the landscape of the fields within which environmental education is embedded, the power relations, and the notion of agency in environmental education policy processes. The discourse in environmental education policy processes is analyzed by drawing on Bourdieu’s constructivist structuralism to highlight some of the social and institutional complexities in dynamic fields, capital and policy context. The research takes a qualitative interpretative approach using case study methodology to explore the processes and influences that have a bearing on the SADC REEP policy sub-component, specifically the deployment and use of seed funding for policy initiatives. The findings show the complexity of the variables at play in shaping the processes of developing and reviewing environmental education policies in the sub-region. These variables include discourse that is used, economics and politics of the responsible institutions and actors, as well as relationships between the environmental field and education field. The results point towards a need to clearly understand the policy context within which the SADC REEP is operating in order to make correct assumptions, to develop realist expectations, and to put in place appropriate mechanisms that will effect the expectations. The study recommends further probing of the relationship between the actors and networks in relation to the success of policy processes. It also recommends a further exploration of the SADC REEP’s open-ended approach with respect to articulating the monitoring and consolidation of the successes in supporting environmental education policy processes.
- Full Text:
- Date Issued: 2009
Characterization of polymeric film of a new manganese phthalocyanine complex octa-substituted with 2-diethylaminoethanethiol, and its use for the electrochemical detection of bentazon
- Akinbulu, Isaac A, Nyokong, Tebello
- Authors: Akinbulu, Isaac A , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262568 , vital:53534 , xlink:href="https://doi.org/10.1016/j.electacta.2009.07.074"
- Description: Manganese acetate octakis-(2-diethyaminoethanethiol) phthalocyanine (AcMnODEAETPc) was newly synthesized and characterized by spectroscopic and electrochemical methods. Solution electrochemistry of the complex showed three redox processes assigned to MnIIIPc−1/MnIIIPc−2, MnIIIPc−2/MnIIPc−2 and MnIIPc−2/MnIIPc−3 species. The new molecule was polymerized onto a glassy carbon electrode (GCE) to form thin films of different thickness, giving poly-10-AcMnODEAETPc-GCE, poly-20-AcMnODEAETPc-GCE and poly-30-AcMnODEAETPc-GCE, where 10, 20 and 30 represent the number of voltammetry scans during polymerization. Three distinct redox processes were observed on the modified electrode in 0.1 M phosphate buffer solution, pH 5, which confirmed the formation of the polymer. The current signal due to the herbicide, bentazon, was dependent on film thickness; the best signal was obtained on poly-20-AcMnODEAETPc-GCE while poly-10-AcMnODEAETPc-GCE gave the least signal. However, the signals due to the herbicide were better on the different films compared to the bare electrode. Electrochemical impedance spectroscopy (EIS) technique revealed that differences in film thickness offered different charge transfer resistances, Rct, hence difference in current signals for bentazon oxidation were observed on these films. A Tafel slope of 77 mV/decade, obtained for the herbicide on poly-20-AcMnODEAETPc-GCE, denotes a fast one electron transfer followed by a slow chemical step in the electro-oxidation of bentazon. The voltammetry signals of the herbicide on the films indicated the likely involvement of ring-based redox processes in the detection of the herbicide. A plot of background corrected current response, on this film, versus the concentration of bentazon was linear within the range 50–750 μM with a detection limit of 2.48 × 10−7 M.
- Full Text:
- Date Issued: 2009
- Authors: Akinbulu, Isaac A , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262568 , vital:53534 , xlink:href="https://doi.org/10.1016/j.electacta.2009.07.074"
- Description: Manganese acetate octakis-(2-diethyaminoethanethiol) phthalocyanine (AcMnODEAETPc) was newly synthesized and characterized by spectroscopic and electrochemical methods. Solution electrochemistry of the complex showed three redox processes assigned to MnIIIPc−1/MnIIIPc−2, MnIIIPc−2/MnIIPc−2 and MnIIPc−2/MnIIPc−3 species. The new molecule was polymerized onto a glassy carbon electrode (GCE) to form thin films of different thickness, giving poly-10-AcMnODEAETPc-GCE, poly-20-AcMnODEAETPc-GCE and poly-30-AcMnODEAETPc-GCE, where 10, 20 and 30 represent the number of voltammetry scans during polymerization. Three distinct redox processes were observed on the modified electrode in 0.1 M phosphate buffer solution, pH 5, which confirmed the formation of the polymer. The current signal due to the herbicide, bentazon, was dependent on film thickness; the best signal was obtained on poly-20-AcMnODEAETPc-GCE while poly-10-AcMnODEAETPc-GCE gave the least signal. However, the signals due to the herbicide were better on the different films compared to the bare electrode. Electrochemical impedance spectroscopy (EIS) technique revealed that differences in film thickness offered different charge transfer resistances, Rct, hence difference in current signals for bentazon oxidation were observed on these films. A Tafel slope of 77 mV/decade, obtained for the herbicide on poly-20-AcMnODEAETPc-GCE, denotes a fast one electron transfer followed by a slow chemical step in the electro-oxidation of bentazon. The voltammetry signals of the herbicide on the films indicated the likely involvement of ring-based redox processes in the detection of the herbicide. A plot of background corrected current response, on this film, versus the concentration of bentazon was linear within the range 50–750 μM with a detection limit of 2.48 × 10−7 M.
- Full Text:
- Date Issued: 2009
Racism and law : implementing the right to equality in selected South African equality courts
- Authors: Krüger, Rósaan
- Date: 2009
- Subjects: South Africa Promotion of Equality and Prevention of Unfair Discrimination Act, 2000 , Equality -- South Africa , Discrimination -- Law and legislation -- South Africa , Racism -- Law and legislation -- South Africa , Apartheid -- Law and legislation -- South Africa , Constitutional law -- South Africa , South Africa -- Politics and government -- 1994-
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3677 , http://hdl.handle.net/10962/d1003192 , South Africa Promotion of Equality and Prevention of Unfair Discrimination Act, 2000 , Equality -- South Africa , Discrimination -- Law and legislation -- South Africa , Racism -- Law and legislation -- South Africa , Apartheid -- Law and legislation -- South Africa , Constitutional law -- South Africa , South Africa -- Politics and government -- 1994-
- Description: Racism has informed South African society since colonial times. Racist beliefs found expression in the laws of colonial and apartheid South Africa and shaped both state and society. The constitutional state that South Africa has become since 1994, is based on the values of ‘human dignity’, ‘the achievement of equality’ and ‘nonracialism’, among others. Law formed the basis of the racist state prior to 1994, and now law has a fundamental role to play in the transformation of the state and society in an egalitarian direction by addressing socio-economic inequalities on the one hand, and by changing patterns of behaviour based on racist beliefs forged in the past, on the other. This thesis examines one of the legal instruments that is intended to contribute to transformation in the latter sense, namely the Promotion of Equality and Prevention of Unfair Discrimination Act 4 of 2000 (the Equality Act), with specific reference to the issue of racism. The provisions of this Act and the framework for its operation against the background of South Africa’s racist past, and within the broader framework of international and constitutional law, are examined. These two legal frameworks are analysed for the purpose of determining the standards set by international and constitutional law regarding racial equality in order to determine whether the Equality Act measures up. This thesis also incorporates an analysis of the practical application of the provisions of the Equality Act to complaints of racism in selected equality courts. The theoretical analysis of the Act’s provisions and their application in the equality courts point to various problematic formulations and obstacles which negatively affect the application of the provisions and thus hamper social change. The thesis concludes with recommendations for refining the Act’s provisions and its application.
- Full Text:
- Date Issued: 2009
- Authors: Krüger, Rósaan
- Date: 2009
- Subjects: South Africa Promotion of Equality and Prevention of Unfair Discrimination Act, 2000 , Equality -- South Africa , Discrimination -- Law and legislation -- South Africa , Racism -- Law and legislation -- South Africa , Apartheid -- Law and legislation -- South Africa , Constitutional law -- South Africa , South Africa -- Politics and government -- 1994-
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3677 , http://hdl.handle.net/10962/d1003192 , South Africa Promotion of Equality and Prevention of Unfair Discrimination Act, 2000 , Equality -- South Africa , Discrimination -- Law and legislation -- South Africa , Racism -- Law and legislation -- South Africa , Apartheid -- Law and legislation -- South Africa , Constitutional law -- South Africa , South Africa -- Politics and government -- 1994-
- Description: Racism has informed South African society since colonial times. Racist beliefs found expression in the laws of colonial and apartheid South Africa and shaped both state and society. The constitutional state that South Africa has become since 1994, is based on the values of ‘human dignity’, ‘the achievement of equality’ and ‘nonracialism’, among others. Law formed the basis of the racist state prior to 1994, and now law has a fundamental role to play in the transformation of the state and society in an egalitarian direction by addressing socio-economic inequalities on the one hand, and by changing patterns of behaviour based on racist beliefs forged in the past, on the other. This thesis examines one of the legal instruments that is intended to contribute to transformation in the latter sense, namely the Promotion of Equality and Prevention of Unfair Discrimination Act 4 of 2000 (the Equality Act), with specific reference to the issue of racism. The provisions of this Act and the framework for its operation against the background of South Africa’s racist past, and within the broader framework of international and constitutional law, are examined. These two legal frameworks are analysed for the purpose of determining the standards set by international and constitutional law regarding racial equality in order to determine whether the Equality Act measures up. This thesis also incorporates an analysis of the practical application of the provisions of the Equality Act to complaints of racism in selected equality courts. The theoretical analysis of the Act’s provisions and their application in the equality courts point to various problematic formulations and obstacles which negatively affect the application of the provisions and thus hamper social change. The thesis concludes with recommendations for refining the Act’s provisions and its application.
- Full Text:
- Date Issued: 2009
A psychobiographical study of Helen Keller
- Van Genechten, Désirée Martina
- Authors: Van Genechten, Désirée Martina
- Date: 2009
- Subjects: Keller, Helen, 1880-1968 , Developmental psychology , Life cycle, Human -- Psychological aspects , Deafblind people
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9897 , http://hdl.handle.net/10948/1101 , Keller, Helen, 1880-1968 , Developmental psychology , Life cycle, Human -- Psychological aspects , Deafblind people
- Description: This psychobiographical study of Helen Keller’s life is exploratory-descriptive in nature. The subject was chosen through purposive sampling. The choice was based on the researcher’s personal interest and the remarkable impact this profoundly handicapped woman had within her society. Helen Keller also meets the psychobiographical requirements. These include that she is historically well known, inspirational, and her life has been completed. The study uses a qualitative, single case, interpretive research design. The design is employed to study Helen Keller’s entire life span within a formal psychological theory. The theory used in this study is Daniel Levinson’s (1996) Life Structure theory of adult development. Data for this study were collected from a variety of primary and secondary sources which provided alternative perspectives on her life. In addition, the data have been corroborated by historical texts, and newspaper and journal articles. Levinson’s (1996) theory divides the lifespan into four developmental eras, each with its own biopsychosocial character. Each era in turn is divided into shorter periods of development, each with particular developmental tasks. Cross-era transitions separate the eras. By describing and exploring the data according to this theory, Helen Keller as a profoundly handicapped person is shown to display universal patterns of development as suggested by Levinson. At the same time, the Life Structure she developed, her life components, and Satisfactoriness illuminated her uniqueness. Through the application of the theory to Helen Keller’s life, this psychobiographical study facilitated an examination of the theory. This led to suggestions for potential development of the theory.
- Full Text:
- Date Issued: 2009
- Authors: Van Genechten, Désirée Martina
- Date: 2009
- Subjects: Keller, Helen, 1880-1968 , Developmental psychology , Life cycle, Human -- Psychological aspects , Deafblind people
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9897 , http://hdl.handle.net/10948/1101 , Keller, Helen, 1880-1968 , Developmental psychology , Life cycle, Human -- Psychological aspects , Deafblind people
- Description: This psychobiographical study of Helen Keller’s life is exploratory-descriptive in nature. The subject was chosen through purposive sampling. The choice was based on the researcher’s personal interest and the remarkable impact this profoundly handicapped woman had within her society. Helen Keller also meets the psychobiographical requirements. These include that she is historically well known, inspirational, and her life has been completed. The study uses a qualitative, single case, interpretive research design. The design is employed to study Helen Keller’s entire life span within a formal psychological theory. The theory used in this study is Daniel Levinson’s (1996) Life Structure theory of adult development. Data for this study were collected from a variety of primary and secondary sources which provided alternative perspectives on her life. In addition, the data have been corroborated by historical texts, and newspaper and journal articles. Levinson’s (1996) theory divides the lifespan into four developmental eras, each with its own biopsychosocial character. Each era in turn is divided into shorter periods of development, each with particular developmental tasks. Cross-era transitions separate the eras. By describing and exploring the data according to this theory, Helen Keller as a profoundly handicapped person is shown to display universal patterns of development as suggested by Levinson. At the same time, the Life Structure she developed, her life components, and Satisfactoriness illuminated her uniqueness. Through the application of the theory to Helen Keller’s life, this psychobiographical study facilitated an examination of the theory. This led to suggestions for potential development of the theory.
- Full Text:
- Date Issued: 2009
The art of addiction : a phenomenological study of the lived experiences of cocaine dependents
- Authors: Plumb, Sarah
- Date: 2009
- Subjects: Cocaine abuse , Cocaine -- Social aspects , Drugs -- Physiological effect
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9912 , http://hdl.handle.net/10948/902 , Cocaine abuse , Cocaine -- Social aspects , Drugs -- Physiological effect
- Description: Addiction is a complex social phenomenon resulting from psychological and physiological dependence. The aim of the study was to create a clinical impression of the lived experiences of cocaine dependents. A transcendental phenomenological approach was used to elicit the essence of addiction as experienced by the participants. Theoretical sampling ensured relevant participants were selected through haphazard sampling procedures. Data was collected through the use of biographical questionnaires and individual, semi-structured interviews with three cocaine dependents. Data was processed according to the four phenomenological principles epoche, phenomenological reduction, imaginative variation and synthesis using Tesch’s eight steps. The essence of cocaine dependency is contained in the psychological experiences of the drug which define and perpetuate that addiction. The psychological addiction develops prior to physical dependence resulting in an entrenched addiction before treatment is sought by the cocaine dependents.
- Full Text:
- Date Issued: 2009
- Authors: Plumb, Sarah
- Date: 2009
- Subjects: Cocaine abuse , Cocaine -- Social aspects , Drugs -- Physiological effect
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9912 , http://hdl.handle.net/10948/902 , Cocaine abuse , Cocaine -- Social aspects , Drugs -- Physiological effect
- Description: Addiction is a complex social phenomenon resulting from psychological and physiological dependence. The aim of the study was to create a clinical impression of the lived experiences of cocaine dependents. A transcendental phenomenological approach was used to elicit the essence of addiction as experienced by the participants. Theoretical sampling ensured relevant participants were selected through haphazard sampling procedures. Data was collected through the use of biographical questionnaires and individual, semi-structured interviews with three cocaine dependents. Data was processed according to the four phenomenological principles epoche, phenomenological reduction, imaginative variation and synthesis using Tesch’s eight steps. The essence of cocaine dependency is contained in the psychological experiences of the drug which define and perpetuate that addiction. The psychological addiction develops prior to physical dependence resulting in an entrenched addiction before treatment is sought by the cocaine dependents.
- Full Text:
- Date Issued: 2009
Redress : debates informing exhibitions and acquisitions in selected South African public art galleries (1990-1994)
- Authors: Cook, Shashi Chailey
- Date: 2009
- Subjects: South African National Gallery Exhibitions Durban Art Gallery Exhibitions Joahnnesburg Art Gallery Exhibitions Art -- South Africa -- Exhibitions Art, South African Exhibitions South Africa History Exhibitions
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2399 , http://hdl.handle.net/10962/d1002195
- Description: This thesis centres on the debates informing the progress of three public art galleries in South Africa between 1990 and 1994. This was a period of great change in the country, spanning from the unbanning of left-wing political parties and Nelson Mandela’s release from prison, to the first democratic elections which resulted in his inauguration as President of South Africa. The study focuses specifically on the Johannesburg Art Gallery, the South African National Gallery, and the Durban Art Gallery, delineating the events and exhibitions held, the programmes initiated, and the artists represented by these galleries during this post-apartheid/pre-democracy phase of the country’s history. The debates relevant to these galleries linked to those prevalent in the arts, museology, and politics at the time. Many contemporary South African artists called attention to apartheid oppression and human rights abuses during the 1980s. After 1990, with these pressures alleviating, there was a stage of uncertainty as to the role, responsibility, and focus of visual art in a post-‘struggle’ context, however there was also an unprecedented upswing in interest and investment in it. On a practical level, the administration of the arts was being re-evaluated and contested by both independent and politically-aligned arts groups. Public art museums and sponsored art competitions and exhibitions made increasing efforts to be ‘representative’ of South Africans of all races, cultures, creeds, sexes and genders. The many conferences, committees, and conventions created during this transitional era focused on the creation of policies that would assist in nation-building; historical and cultural redress and regeneration; and the education and representation of previously disadvantaged groups. This coincided with a revolution in museological discourses internationally, from the theorization of a museum as a place of commemoration and conservation, to a forum for discussion and revision between both academic and non-academic communities. With the sharing of the process of constructing history and knowledge, came the challenging dynamics involved in the representation of identity and history. In all of these groups - the arts, museology, and South African politics - the predominant issue seemed to be a negotiation between the bid to open up control to more parties, and the reluctance of some parties to relinquish control. While the emphasis is on significant changes that were implemented in the transitional period, the study locates the changes at the Johannesburg Art Gallery, the South African National Gallery and the Durban Art Gallery within their historical, geographical, and socio-political context. Various artists working in these locations during this era are also discussed, as the changes in their status, and the progressions in their subject matter, materials, and concerns are interesting to examine more nuanced definitions of the ‘political’, probing the politics of identity, sexuality, gender, race, geography, and belief systems. Some artists also focused specifically on post-apartheid preoccupations with territory, trauma, conflict, memory and freedom. This kind of artwork was assiduously acquired during the early ‘90s by public art galleries, whose exhibitions and collecting focus and policies were undergoing considerable revision and redress. This thesis examines these changes in light of their socio-political contexts, as well as in light of shifting national and international imperatives and conceptions of museums and museum practice.
- Full Text:
- Date Issued: 2009
- Authors: Cook, Shashi Chailey
- Date: 2009
- Subjects: South African National Gallery Exhibitions Durban Art Gallery Exhibitions Joahnnesburg Art Gallery Exhibitions Art -- South Africa -- Exhibitions Art, South African Exhibitions South Africa History Exhibitions
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2399 , http://hdl.handle.net/10962/d1002195
- Description: This thesis centres on the debates informing the progress of three public art galleries in South Africa between 1990 and 1994. This was a period of great change in the country, spanning from the unbanning of left-wing political parties and Nelson Mandela’s release from prison, to the first democratic elections which resulted in his inauguration as President of South Africa. The study focuses specifically on the Johannesburg Art Gallery, the South African National Gallery, and the Durban Art Gallery, delineating the events and exhibitions held, the programmes initiated, and the artists represented by these galleries during this post-apartheid/pre-democracy phase of the country’s history. The debates relevant to these galleries linked to those prevalent in the arts, museology, and politics at the time. Many contemporary South African artists called attention to apartheid oppression and human rights abuses during the 1980s. After 1990, with these pressures alleviating, there was a stage of uncertainty as to the role, responsibility, and focus of visual art in a post-‘struggle’ context, however there was also an unprecedented upswing in interest and investment in it. On a practical level, the administration of the arts was being re-evaluated and contested by both independent and politically-aligned arts groups. Public art museums and sponsored art competitions and exhibitions made increasing efforts to be ‘representative’ of South Africans of all races, cultures, creeds, sexes and genders. The many conferences, committees, and conventions created during this transitional era focused on the creation of policies that would assist in nation-building; historical and cultural redress and regeneration; and the education and representation of previously disadvantaged groups. This coincided with a revolution in museological discourses internationally, from the theorization of a museum as a place of commemoration and conservation, to a forum for discussion and revision between both academic and non-academic communities. With the sharing of the process of constructing history and knowledge, came the challenging dynamics involved in the representation of identity and history. In all of these groups - the arts, museology, and South African politics - the predominant issue seemed to be a negotiation between the bid to open up control to more parties, and the reluctance of some parties to relinquish control. While the emphasis is on significant changes that were implemented in the transitional period, the study locates the changes at the Johannesburg Art Gallery, the South African National Gallery and the Durban Art Gallery within their historical, geographical, and socio-political context. Various artists working in these locations during this era are also discussed, as the changes in their status, and the progressions in their subject matter, materials, and concerns are interesting to examine more nuanced definitions of the ‘political’, probing the politics of identity, sexuality, gender, race, geography, and belief systems. Some artists also focused specifically on post-apartheid preoccupations with territory, trauma, conflict, memory and freedom. This kind of artwork was assiduously acquired during the early ‘90s by public art galleries, whose exhibitions and collecting focus and policies were undergoing considerable revision and redress. This thesis examines these changes in light of their socio-political contexts, as well as in light of shifting national and international imperatives and conceptions of museums and museum practice.
- Full Text:
- Date Issued: 2009
Solvent-free synthesis of bisferrocenylimines and their coordination to rhodium (I)
- Authors: Kleyi, Phumelele Eldridge
- Date: 2009
- Subjects: Organic compounds -- Synthesis , Organic solvents , Solution (Chemistry) , Chemistry, Organic , Coordination compounds
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10393 , http://hdl.handle.net/10948/1053 , Organic compounds -- Synthesis , Organic solvents , Solution (Chemistry) , Chemistry, Organic , Coordination compounds
- Description: Solvent-free reactions possess advantages compared to the solvent route, such as shorter reaction times, less use of energy, better yields, etc. Herein, the synthesis and characterization of bisferrocenylimines and arylbisamines are described. Reduction of the above compounds with LAH resulted in the formation of bisferrocenylamines and arylbisamines, respectively. The coordination chemistry of all the above compounds to rhodium(I) is also discussed in the prepared complexes [Rh(COD)(NN)]ClO4, where NN = bisferrocenylimines, and [Rh(COD)(NN)]BF4, where NN = bisferrocenylamines and arylbisamines. X-ray crystal structures of the complexes [Rh(COD)(NN)]ClO4 ([3.2] and [3.3]) have been obtained. Complexes of the type [Rh(COD)(NN)]BF4 were characterized with IR and UV-vis spectroscopy, cyclic voltammetry and conductometry. The catalytic activity of the complexes was also investigated: [Rh(COD)(NN)]ClO4 for the polymerization of phenylacetylene and [Rh(COD)(NN)]BF4 for the hydroformylation of styrene.
- Full Text:
- Date Issued: 2009
- Authors: Kleyi, Phumelele Eldridge
- Date: 2009
- Subjects: Organic compounds -- Synthesis , Organic solvents , Solution (Chemistry) , Chemistry, Organic , Coordination compounds
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10393 , http://hdl.handle.net/10948/1053 , Organic compounds -- Synthesis , Organic solvents , Solution (Chemistry) , Chemistry, Organic , Coordination compounds
- Description: Solvent-free reactions possess advantages compared to the solvent route, such as shorter reaction times, less use of energy, better yields, etc. Herein, the synthesis and characterization of bisferrocenylimines and arylbisamines are described. Reduction of the above compounds with LAH resulted in the formation of bisferrocenylamines and arylbisamines, respectively. The coordination chemistry of all the above compounds to rhodium(I) is also discussed in the prepared complexes [Rh(COD)(NN)]ClO4, where NN = bisferrocenylimines, and [Rh(COD)(NN)]BF4, where NN = bisferrocenylamines and arylbisamines. X-ray crystal structures of the complexes [Rh(COD)(NN)]ClO4 ([3.2] and [3.3]) have been obtained. Complexes of the type [Rh(COD)(NN)]BF4 were characterized with IR and UV-vis spectroscopy, cyclic voltammetry and conductometry. The catalytic activity of the complexes was also investigated: [Rh(COD)(NN)]ClO4 for the polymerization of phenylacetylene and [Rh(COD)(NN)]BF4 for the hydroformylation of styrene.
- Full Text:
- Date Issued: 2009
Exploring Learner Participation in Waste-Management Activities in a Rural Botswana Primary School
- Authors: Silo, Nthalivi
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386509 , vital:68148 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122820"
- Description: In Botswana, participation in environmental learning activities has been perceived as a central component of environmental education in formal education. Driven by the need to implement the objective of making the participatory approach part of the infusion of environmental education in the school curriculum as prescribed by the infusion policy, Botswana schools have come up with initiatives to involve learners in environmental education activities that seem to have ‘a direct, perceived benefit to the learners’ (NEESAP, 2007:9). Within this approach it is expected that learners should participate in these activities. However, Ketlhoilwe (2007) revealed that there has been a normalisation of environmental education into existing school culture through equating waste-management activities with environmental education. This generally entails cleaning activities by learners to maintain ‘clean schools’, which is directly associated with environmental education. Drawing from detailed case study data in one rural primary school with Standard 6 learners, I used Cultural Historical Activity Theory to investigate and explain how learners participate in these waste-management activities. Findings from this study revealed that attempts by teachers to meet the policy imperative through prescription of rules, and ascribing roles to learners in waste-management activities, create tensions. This gave rise to an elusive object of learner participation, as the purpose for their participation in these activities is not clear.
- Full Text:
- Date Issued: 2009
- Authors: Silo, Nthalivi
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386509 , vital:68148 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122820"
- Description: In Botswana, participation in environmental learning activities has been perceived as a central component of environmental education in formal education. Driven by the need to implement the objective of making the participatory approach part of the infusion of environmental education in the school curriculum as prescribed by the infusion policy, Botswana schools have come up with initiatives to involve learners in environmental education activities that seem to have ‘a direct, perceived benefit to the learners’ (NEESAP, 2007:9). Within this approach it is expected that learners should participate in these activities. However, Ketlhoilwe (2007) revealed that there has been a normalisation of environmental education into existing school culture through equating waste-management activities with environmental education. This generally entails cleaning activities by learners to maintain ‘clean schools’, which is directly associated with environmental education. Drawing from detailed case study data in one rural primary school with Standard 6 learners, I used Cultural Historical Activity Theory to investigate and explain how learners participate in these waste-management activities. Findings from this study revealed that attempts by teachers to meet the policy imperative through prescription of rules, and ascribing roles to learners in waste-management activities, create tensions. This gave rise to an elusive object of learner participation, as the purpose for their participation in these activities is not clear.
- Full Text:
- Date Issued: 2009